a sensitivity study on low salinity...

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Modern Environmental Science and Engineering (ISSN 2333-2581) April 2017, Volume 3, No. 4, pp. 231-236 Doi: 10.15341/mese(2333-2581)/04.03.2017/003 Academic Star Publishing Company, 2017 www.academicstar.us A Sensitivity Study on Low Salinity Waterflooding Barham S. Mahmood 1 , Jagar Ali 2 , Shirzad B. Nazhat 2 , and David Devlin 2 1. Department of Petroleum Engineering, Koya University, Kurdistan Region, Iraq 2. Department of Petroleum Engineering, Soran University, Kurdistan Region, Iraq Abstract: It is widely accepted that different salinity brines injection may increase the oil recovery. However, the mechanisms by which low salinity flooding increases oil recovery are not yet fully understood. This work is to run simulation on ECLIPSE 100 simulator to show the effect of injecting low salinity into a reservoir. A three dimensional synthetic model was created to mimic a real reservoir. The effect of low salinity on oil recovery was observed by conducting sensitivity study on; injecting brine salinity, slug injection of low salinity, and endpoint saturations. A difference of 22% in oil recovery observed when the low salinity water is injected compared to the high salinity water only in the threshold range between 0 kg/m 3 to 5 kg/m 3 . Performing slug injection can reduce the requirement for low salinity water and recovers approximately the same percentage of oil. This can indeed give better cost saving when opting for low salinity injection. The brine option in ECLIPSE 100 indicated to be very sensitive to the saturation endpoint and relative permeability. Thus, it is important to be aware of this during simulation of such augmented waterflooding, and input from experimental data is needed for accurate simulations. Key words: improved oil recovery, low salinity waterflooding, Salinity, Slug injection, wettability 1. Introduction The concept of injecting low-salinity water (LoSal) into the oil reservoir is not a new topic. The first observation of the LoSal effect on oil recovery goes back to Martin (1957) and Bernard (1967), who demonstrated that the injection of fresh water can improve the macroscopic sweep efficiency in sandstone containing clay due to mobilization of fine clay particles [1, 2]. However, this work did not draw the attention of the oil industries. Three decades later a new phase of research activities initiated to optimize the composition of injected water during waterflooding and its effect on oil recovery enhancement. The literature on low salinity waterflooding has increasingly become rich in last few year [3-13] are among the numerous studies which have been Corresponding author: Jagar Ali, Researcher, research areas/interests: reservoir simulation, history matching, petrophysics, reservoir characterization. E-mail: [email protected]. published during last 10-15 years. In these studies many different microscopic mechanisms behind low salinity waterflooding process have been proposed. However, there is not an agreement on the primary mechanisms that work to enhance oil recovery. Tang and Morrow in their experiments on LoSal waterflooding identified the movement of fine clay particles. According to their understanding when contacted with low salinity brine, clay particles detach from the pore walls, as a result an intermediate wet phase becomes unstable and attains the ability to detach from the surface of the rock and expose the water wet. They also reported that when the salinity of the injected brine is less than 1550 TDS this causes a reduction in permeability [5]. However, in the experiment conducted by Lager et al. seems to have witnessed the low salinity effect even without fines migration or reduction in permeability [10]. The studies [8, 10-15] on LoSal waterflooding have demonstrated experimentally the low salinity effect on the pH value, claiming an increase of pH. This rise in

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Page 1: A Sensitivity Study on Low Salinity Waterfloodingacademicstar.us/UploadFile/Picture/2017-8/201781811431519.pdf · petrophysics, reservoir characterization. E-mail: jagar.ali@soran.edu.iq

Modern Environmental Science and Engineering (ISSN 2333-2581) April 2017, Volume 3, No. 4, pp. 231-236 Doi: 10.15341/mese(2333-2581)/04.03.2017/003 Academic Star Publishing Company, 2017 www.academicstar.us

A Sensitivity Study on Low Salinity Waterflooding

Barham S. Mahmood1, Jagar Ali2, Shirzad B. Nazhat2, and David Devlin2

1. Department of Petroleum Engineering, Koya University, Kurdistan Region, Iraq

2. Department of Petroleum Engineering, Soran University, Kurdistan Region, Iraq

Abstract: It is widely accepted that different salinity brines injection may increase the oil recovery. However, the mechanisms by which low salinity flooding increases oil recovery are not yet fully understood. This work is to run simulation on ECLIPSE 100 simulator to show the effect of injecting low salinity into a reservoir. A three dimensional synthetic model was created to mimic a real reservoir. The effect of low salinity on oil recovery was observed by conducting sensitivity study on; injecting brine salinity, slug injection of low salinity, and endpoint saturations. A difference of 22% in oil recovery observed when the low salinity water is injected compared to the high salinity water only in the threshold range between 0 kg/m3 to 5 kg/m3.

Performing slug injection can reduce the requirement for low salinity water and recovers approximately the same percentage of oil. This can indeed give better cost saving when opting for low salinity injection.

The brine option in ECLIPSE 100 indicated to be very sensitive to the saturation endpoint and relative permeability. Thus, it is important to be aware of this during simulation of such augmented waterflooding, and input from experimental data is needed for accurate simulations.

Key words: improved oil recovery, low salinity waterflooding, Salinity, Slug injection, wettability

1. Introduction

The concept of injecting low-salinity water (LoSal)

into the oil reservoir is not a new topic. The first

observation of the LoSal effect on oil recovery goes

back to Martin (1957) and Bernard (1967), who

demonstrated that the injection of fresh water can

improve the macroscopic sweep efficiency in

sandstone containing clay due to mobilization of fine

clay particles [1, 2]. However, this work did not draw

the attention of the oil industries. Three decades later a

new phase of research activities initiated to optimize

the composition of injected water during waterflooding

and its effect on oil recovery enhancement. The

literature on low salinity waterflooding has

increasingly become rich in last few year [3-13] are

among the numerous studies which have been

Corresponding author: Jagar Ali, Researcher, research

areas/interests: reservoir simulation, history matching, petrophysics, reservoir characterization. E-mail: [email protected].

published during last 10-15 years. In these studies

many different microscopic mechanisms behind low

salinity waterflooding process have been proposed.

However, there is not an agreement on the primary

mechanisms that work to enhance oil recovery.

Tang and Morrow in their experiments on LoSal

waterflooding identified the movement of fine clay

particles. According to their understanding when

contacted with low salinity brine, clay particles detach

from the pore walls, as a result an intermediate wet

phase becomes unstable and attains the ability to detach

from the surface of the rock and expose the water wet.

They also reported that when the salinity of the injected

brine is less than 1550 TDS this causes a reduction in

permeability [5]. However, in the experiment

conducted by Lager et al. seems to have witnessed the

low salinity effect even without fines migration or

reduction in permeability [10].

The studies [8, 10-15] on LoSal waterflooding have

demonstrated experimentally the low salinity effect on

the pH value, claiming an increase of pH. This rise in

Page 2: A Sensitivity Study on Low Salinity Waterfloodingacademicstar.us/UploadFile/Picture/2017-8/201781811431519.pdf · petrophysics, reservoir characterization. E-mail: jagar.ali@soran.edu.iq

232

the pH could

dissolution a

a reduction i

in a highe

waterfloodin

waterflood.

reduces the

water and oi

toward more

Lager et a

(MIE) to b

improved oi

same view i

experiments

been observ

salinity brin

interaction

magnesium

connate brin

Mg2+, the M

adsorbed by

Expansion

possible mec

waterfloodin

layer effect

electrical d

interfaces; i

potential. T

repulsion be

to a desorpti

an increase i

Hence, th

Oil Simulato

and recorde

work and th

logical mann

2. Synthet

Three di

using ECLIP

by 50×50×6

d be due to tw

and cation ex

in the H+ ion

er pH. Con

ng would sta

In addition to

surface ten

il reservoir, a

e water wet

al. claimed m

be the major

il recovery b

is held by B

s on the Nort

ved that the

ne, the rock su

resulted in

Mg2+ ions.

nes containe

Mg2+ ions w

y the clay part

n of the elec

chanism to im

ng. Ligthelm

t, which is

double layer

ncreases in t

This in turn y

etween the cla

ion of oil com

in water wetn

his research w

or. A differen

d. The input

his will help

ner.

tic Model a

imensional s

PSE 100. The

grids. Each g

A Sen

wo chemical r

xchange. This

ns in the liquid

sequently, th

art performin

o the fact tha

nsion betwee

also, it chang

multi-compon

r mechanism

by LoSal wa

BP. After carr

th Slope core

interaction

urface and th

a sharp re

Although bo

ed a similar

was believed

ticles in the ro

ctrical double

mprove oil re

m et al. discu

the expansio

between th

the absolute

yields increa

ay particles an

mponents from

ness [14].

will use ECL

nt sensitivity c

ts based on p

p to run the

nd Propert

simulations

e synthetic mo

grid measures

nsitivity Study

reactions: Car

s process lead

d phase, resul

he low sali

ng as an alka

at LoSal floo

en the forma

es the wettab

ent ion excha

m leading to

aterflooding.

rying out sev

e samples, it

among the

he crude oil.

eduction of

oth injected

composition

d to be stron

ock matrix [1

e layer is ano

ecovery by Lo

ussed the do

on of the i

he clay and

level of the

ased electros

nd the oil, lead

m the surface

LIPSE 100 B

case will be te

previous rese

simulations

ties

were perfor

odel is sector

s 3 m × 3 m ×

y on Low Sal

rbon

ds to

lting

inity

aline

ding

ation

bility

ange

the

The

veral

t has

low

This

the

and

n of

ngly

10].

other

oSal

uble

ionic

oil

zeta

tatic

ding

e and

Black

ested

arch

in a

rmed

rized

3 m

in X

hete

to 5

0.30

hav

diag

wel

they

volu

T

wat

kg/m

for

acti

curv

diff

LSA

a co

The

with

high

corr

extr

for

wei

rela

wer

(Fig

3. S

T

perf

Fig.synt

inity Waterflo

X, Y and Z d

erogeneous, t

525 mD and

05. Two acti

ve been adde

gonally with

lls are compl

y are set to

ume rate (RE

The active ph

ter. The salin

m3 (TDS), thi

regular sea w

ivated, two d

ves should b

ferent salini

ALTFNC key

onstant that re

e value of the

h a constant

h salinity

responding c

reme of low

any fraction

ighting factor

ative permeab

re taken from

g. 2) [16].

Sensitivity

The main s

formed in thi

. 1 Permeabthetic model.

ooding

directions, re

the permeabi

the porosity

ive wells; a p

ed to the mo

respect to e

leted from th

be controlle

ESV), with a f

hases in the re

nity of connat

is is approxim

water. When th

different sets

be assigned

ties; high

yword is auto

epresents the

e weighting f

weighting fr

properties

constant of “

salinity floo

n ranging b

r is used, resp

bility profile

m Kossac Chu

Analyses

sensitivity s

s paper are th

bility distribut

espectively. T

lity range is

range is betw

producer and

odel and they

each other (F

he top to the

ed by the re

flow rate of 1

eservoir mode

te water was

mately the sam

he LOWSAL

s of relative

with respect

and low s

omatically us

assigned spe

factor ranges

raction of “0

to be a

“1” represen

ods. Interpola

etween 0 an

pectively. In th

for high and

uck, Schlumbe

studies that

he injection o

tion and well

The model is

between 275

ween 0.23 to

d an injector,

y are located

Fig. 1). Both

e bottom and

eservoir fluid

100 m3/day.

el are oil and

set to be 35

me salinity as

LT keyword is

permeability

t to the two

alinity. The

sed to choose

cific salinity.

s from 0 to 1

0”, indicating

assigned. A

nts the other

ation is made

nd 1, and a

his study, the

d low salinity

erger advisor

have been

of brine with

placement in

s

5

o

,

d

h

d

d

d

5

s

s

y

o

e

e

.

g

A

r

e

a

e

y

r

n

n

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Fig. 2 Relasalinities [16]

different sal

endpoint sa

interpolation

4. Results

4.1 Injection

To study t

recovery, eig

injection of b

set a base ca

of brines wi

Table 1 Effe

Fig. 3 Field

ative permeab.

inities, the ef

aturations an

n.

and Discus

n of Brine wit

the effect of b

ght different c

brine with 35

ase oil recover

ith 10, 5, 4, 3

ect of Brine sa

Brine salinity

Oil recover

oil efficiency (

A Sen

bility profile f

ffect of slug s

nd the relati

ssions

th Different S

brine salinity

cases were ex

kg/m3 TDS w

ry. Subsequen

3, 2, 1, and 0

linity on oil re

(Kg/m3)

ry (%)

(FOE) with bri

nsitivity Study

for high and

size, the effec

ive permeab

Salinities

on improving

xamined. Init

was carried ou

ntly, the injec

kg/m3 TDS w

covery.

0

59

ine salinities of

y on Low Sal

low

ct of

bility

g oil

ially,

ut to

ction

were

und

Fig

oil

TD

star

reco

mai

In o

wet

satu

resu

wat

cut

4.2

D

the

LoS

proh

pro

slug

dem

1

56

f 35, 10, 5, 4, 3

inity Waterflo

dertaken. The

. 3. As expect

recovery for

S. This is bec

rt at salinities

overy is expe

inly due to the

other words, l

ttability shif

uration (Sor)

ult in a m

ter-flooding,

is observed.

Effect of Slug

During the Lo

amount of w

Sal water fo

hibitive and

fits. In this s

g sizes on o

monstrates the

2

51.7 4

, 2, 1, and 0 kg

ooding

e results are d

ted, there was

the injection

cause the low

less than 5 k

erienced, whe

e reduction in

low salinity b

ft that mini

and water r

more efficien

hence, slow

g Size

oSal process,

water injected

or the entire

has the pot

ensitivity stu

oil recovery

e results of di

3 4

47 42

g/m3.

displayed in

s no observed

n of brines ab

salinity effec

kg/m3 TDS. A

en LoSal wat

n water produ

rine injection

imizes the

relative perm

nt oil displ

er developm

it is importan

into a reserv

e production

ential to affe

udy, the effec

was conduc

ifferent scena

5 1

37 3

233

Table 1 and

d incremental

bove 5 kg/m3

cts were set to

An increase in

ter is injected

uction (Fig. 4)

n creates a net

residual oil

meability that

lacement by

ment of water

nt to consider

voir. Injecting

life is cost

fect company

ct of different

cted. Fig. 5

arios of

10 35

37 37

3

d

l 3

o

n

d

).

t

l

t

y

r

r

g

t

y

t

5

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234

Fig. 4 Field

injecting low

11, 12, 13 an

by injecting

results demo

oil recovery

indication on

and the amo

better to illu

Table 2.

When the

37613 Rm3,

approximate

Fig. 5 Oil re

water cut (FW

w salinity brin

nd 15 time st

brine with a

onstrate a stro

y on slug size

n the relation

unt of fluids b

ustrate it by vo

e injected brin

the increme

e value of

ecovery for diff

A Sen

WCT) with diff

ne with 0 kg/m

eps of 30 day

salinity of 35

ong dependen

es. However,

nship between

being injecte

olume calcula

ne volume ro

ental oil recov

8.8%. Whe

fferent slug size

nsitivity Study

ferent brine sal

m3 TDS for 6

ys each, follo

5 kg/m3 TDS.

nce of increme

there is no c

n the oil recov

d. Therefore,

ation as show

se from 1747

very recorded

ereas, when

es during low s

y on Low Sal

linities injectio

, 10,

owed

The

ental

clear

very

, it is

wn in

71 to

d an

the

inje

Rm

4.3

Per

T

con

high

rela

inje

add

mad

salinity injectio

inity Waterflo

on.

ected brine vo

m3, the increm

Effect of

rmeability Int

Table of low

ncentration (L

h salinity an

ative permeab

ected brine s

dition to of the

de, as shown

on with brine s

ooding

olume increa

mental oil reco

Endpoint Sa

terpolation

w-salt weigh

SALTFNC) i

nd low salinit

bility that hav

salinities. In

e base case, tw

in Table 3. C

salinity of 0 kg

ased from 376

overy was on

aturations a

hting factors

indicates the a

ty saturation

ve been used

this sensitiv

wo other LSA

ase one was c

g/m3 TDS.

613 to 39580

nly 1.2%.

and Relative

versus salt

amount of the

profiles and

for different

ity study, in

LTFNC were

conducted

0

e

t

e

d

t

n

e

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such that wh

data from th

high salinity

kg/m3. In ca

is used when

to the base c

Table 2 Oil

Total P

Injection t

(time step

6

10

11

12

13

15

Table 3 Diff

Salt conce(kg/m

0

1

4

5

35

45

Fig. 6 Illustr

hen a salinity

he low salinity

y profiles wh

ase two, less d

n injected dif

case.

recovery and

V 1

time T

ps) (

ferent tables o

Base case

entration m3)

5

5

rates the oil re

A Sen

y below 5 kg

y profiles wer

hen salinity o

data from low

fferent brine

pore volume (P

12942

Time T

(day)

30

30

30

30

30

30

f low-salt weig

F1 F2

1 1

0.8 1

0.2 1

0 0

0 0

0 0

ecovery for diff

nsitivity Study

g/m3 occurs,

re used, yet u

of brine abov

w salinity pro

salinity com

PV) injected fo

(Rm3)

Total time

(day)

180

300

330

360

390

450

ghting factors v

Salt conce(kg/m

0

1

4

5

35

45

ferent low-salt

y on Low Sal

only

using

ve 5

files

mpare

A

reco

Thi

wat

pro

pro

to th

or different slu

Rate

(Rm3/day)

100

100

100

100

100

100

versus salt con

Case I

entration m3)

5

5

t weighting fac

inity Waterflo

As shown in

overy compar

is can be pr

ter-flooding p

file is used. A

files the oil re

he same degr

ug sizes with in

Inject

(Rm

174

291

320

349

376

395

ncentration for

F1 F2

1 1

1 1

1 1

0 0

0 0

0 0

tors versus.

ooding

Fig. 6, case

red to both th

redicted as

performance i

A reduction in

ecovery was

ree as in case

njection brine s

t vol. Injec

m3)

71 0.

17 0.

29 0.

40 0.

13 0.

80 0.

the synthetic m

Salt conce(kg/m

0

1

4

5

35

45

one gave th

he base case a

the effect o

is high when

n the amount

found to decr

one.

salinity of 0 kg

ct PV Tot

15

26

28

31

33

35

model.

Case II

ntration m3)

5

5

235

he highest oil

and case two.

of the LoSal

the optimum

of the LoSal

rease, but not

g/m3 TDS.

tal recovery

(%)

46.2

52.5

53.5

53.7

55

56.2

F1 F2

1 1

0.6 1

0.4 1

0 0

0 0

0 0

5

l

.

l

m

l

t

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A Sensitivity Study on Low Salinity Waterflooding

236

5. Conclusions

Sensitivity studies of LoSal water-flooding on a

synthetic model were carried out using ECLIPSE 100.

The obtained results are based on the properties used in

the simulation model, clearly showed a significant

salinity dependence. An increase in oil recovery can be

observed in conjunction with a reduction in the salinity

of injected brine, where only in the threshold range

between 0 kg/m3 (0.0 ppm) to 5 kg/m3 (5000 ppm).

Furthermore, continuous LoSal injection gives higher

oil recovery. However, when economic aspects were

considered, slug injection can reduce the requirement

for LS water and approximately recovers, the same

percentage of oil. Moreover, the simulation results,

also, indicate that the potential recovery in low salinity

waterflooding was very sensitive to endpoint saturation.

Therefore, it is important to be aware of such input data

in order to obtain accurate simulation results.

References

[1] J. C. Martin, The effect of clay on the displacement of heavy oil by water, in: Venezuelan Annual Meeting, Caracas, Venezuela, 14-16 October 1959.

[2] G. G. Bernard, Effect of floodwater salinity on recovery of oil from cores containing clays, in: SPE California Regional Meeting, California, USA, 26-27 October 1967.

[3] P. Jadhunandan and N. R. Morrow, Effect of wettability on waterflood recovery for crude oil/brine/rock systems, Society of Petroleum Engineering 10 (1995) (1) 40-46.

[4] G.Q.Tang and N.R. Morrow, Wetting behavior of selected crude oil/brine/rock systems, 1997,available online at: http://www.osti.gov/scitech/servlets/purl/772382.

[5] G. Q. Tang and N. R. Morrow, Influence of brine composition and fine migration on crude oil/brine/rock interaction and oil recovery, Petroleum Science and Engineering 24 (1999a) (2) 99-111, doi: 10.1016/S0920-4105(99)00034-0.

[6] G. Q. Tang and N. R. Morrow, Oil Recovery by waterflooding and imbibition — Invading brine cation

valency and salinity, in: International Symposium of the Society of Core Analysts, Colorado, USA, 1-4 August 1999.

[7] K. J. Webb, C. J. J. Black and H. Al-Ajeel, Low salinity oil recovery — Log-Inject-Log, in: SPE 13th Middle East Oil Show & Conference, Bahrain, 5-8 April 2003, pp. 1-8.

[8] P. L. McGuire, J. R. Chatham, F. K. Paskvan, D. M. Sommer and F. H. Carini, Low salinity oil recovery: An exciting new EOR opportunity for Alaska’s North Slope, in: SPE Western Regional Meeting, California, USA, 30 March-1 April 2005, pp. 1-15.

[9] G. R. Jerauld, C. Y. Lin, K. J. Webb and J. C. Seccombe, Modeling low-salinity waterflooding, in: SPE Annual Technical Conference and Exhibition, Texas, USA, 24-27 September 2006, pp. 1-12.

[10] A. Lager, K. J. Webb, C. J. J. Black, M. Singleton and K. S. Sorbie, Low salinity oil recovery — An experimental investigation, in: International Symposium of the Society of Core Analysts, Trondheim, Norway, 12-16 September 2006.

[11] Y. Wu and B. Bai, Efficient simulation for low-salinity waterflooding in porous and fractured reservoirs, in: SPE Reservoir Simulation Symposium, Texas, USA, 2-4 February 2009, pp. 1-13.

[12] S. Berg, A. W. Cense, E. Jansen and K. Bakker, Direct experimental evidence of wettability modification by low salinity, Petrophysics 51 (2010) (5) 314-322.

[13] A. Aladasani and B. Bai, Investigating low-salinity waterflooding recovery mechanisms in Sandstone Reservoirs, in: SPE Improved Oil Recovery Symposium, Oklahoma, USA, 14-18 April 2012, pp. 1-16.

[14] D. J. Ligthelm, J. Gronsveld, J. P. Hofiman, N. J. Brussee, F. Marcelis and H. A. Van der Linde, Novel waterflooding strategy by manipulation of injection brine composition, in: SPE EUROPEC/EAGE Annual Conference and Exhibition, Amsterdam, the Netherlands, 8-11 June 2009. pp. 1-22.

[15] S. Rivet, L. W. Lake and G. A. Pope, A coreflood investigation of low-salinity enhanced oil recovery, in: SPE Annual Technical Conference and Exhibition, Florence, Italy, 19-22 September 2010.

[16] C. Kossack, Eclipse Black Oil Simulator Advanced Options: Low Salinity Water Flooding, Denver, Colorado, 2012.