841 chestnut building - united states environmental ... · enclosed are copies of the completed...

CORPORATIONEnvironmental Services

Public Ledger BuildingIndependence Square6th and Chestnut StreetsSuite 872Philadelphia, PA 19106

Telephone: 215-440-7340Fax: 215-440-7346

September 18, 1991

HAND DELIVERY

Ms. Christine ChulickU.S. Environmental Protection Agency841 Chestnut BuildingPhiladelphia, PA 19107

RE: Data Validation ReportsSaegertown SiteWork Assignment No. C03045

Dear Ms. Chulick:

Enclosed are copies of the completed case # 15741 SDGs MCBB99 and MCDP 87, and #15536 SDGs MCDP 80 which was approved by Region ffl Central Laboratory fordistribution. Also enclosed are copies of the data summary forms for cases SAS 5951-C andSAS 6004-C. The validation for these cases has been completed and sent to Diann Suns inRegion in Central Laboratory.

Should you have any questions, please do not hesitate to call me at (215) 440-7340.

Sincerely,

Costa, P.E.Engineering Manager

cc: Mr. Robert E. Stecik, Dynamac, Philadelphia Operations (letter only)Ms. Donna McGowan, EPA, Regional Project Officer (letter only)

Enclosure1130261*5

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Corporate Headquarters: The Dynamac Building, 2275 Research Boulevard, Suite 500, Rockviile, MD 20850-3268

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Date : July 8, 1991

Subject : Inorganic Data Validation, Case 15741, SDG MCDP87

From : Nasser Massoomzaden// Darline F.Data reviewer, /\s/0j&/'' Project Manager

To : Ms. Diann SimsEPA Region III TES Contract Coordinator

Overview

The set of samples for case 15741 contained 6 watersamples which were analyzed through the contractLaboratory Program Routine Analytical Services.The sample set included 2 field blanks, and onefield duplicate pair.

Summary

All elements, were successfully analyzed in allsamples. Areas of concern with respect to datausability are listed according to the seriousnessof the problem. Note that the summary of the DataQualifiers (Table 1) lists the specific sampleswhich were affected. These include:

Major Problems

No major problems were identified in this casepackage .

Minor Issues

Contamination in the initial and/or continuingcalibration and preparation blanks indicates thatthe qualitative identification of the analytes maybe questionable in those samples with aconcentration less than 5 times the amount presentin the blank. The affected elements are Aluminum,Antimony, Barium, Calcium, Chromium, Copper, Iron,Lead, Silver, Sodium, Thallium, Vanadium, and Zinc.

HR3G2652

Attachment 2Data Svmary Poras

AR302653

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Appendix ALaboratory Results of all Target Analyti

4003

4

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/H ~ a j. / ' e , '.'o ". e r. '

-sum . 38 . 9 ; B440-36-0 'Anrnnonv ; Li. 37440-38-2 iArsenic7440-39-3 Sari urn7440-41-7 .'Bervliium7440-43-"? I Cadmium7440-70-2 . Calciu.n'440-47-3 ICnromium7440-48-4 .Cobalt7440-50-8 iCopper743^-y9-t; , Iron"T4o9-?2-i ! Lead

! Magnesium743'7!-96-5 ! Manganese7<i39-97-6 i Mercury744O-02-0 iNickel7440-09-7 ;Potassium7782-49-2 [Selenium7440-22-4 [Silver7440-23-5 ! Sodium""7440-28-0 ! Thallium7440-62-2 1 Vanadium744O-66-6 IZinc______,_ ! C y a n i d e

2.0.5.41 .0•2.0

4840O10. 13.018.529.8i . 1

71501 .0

0.204 ,010802.04.5

1.04 .314.93.5

ij

<rPpcvppFPPFPPA3

'. olor Before: OOLORLESS Claritv Sefors: OLEAR Texture:

Color After: COLORLESS Claritv After: CLEAR Artifact'

Comments:

AR302656FORM I - IN

" =3

4004

.N-I -~ . ,i^ _ i'-p k -i

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3 - -' J-. i • ^ .

^ - a i v c, s ' c> r-.c e r, t, r 3 11 o n ; C ,

742c>-<3(j-3 . Alu.ninu ' 25.5.8"440-35-0 Anni:ronv 11.SIBT44C-33-2 In'senic."440-39-3 .Barium^440-41-7 ;8ervlliurr"440-43-'5 '.Cadmium7440-70-2 ! Calcium"440-47-3 ; Cnr-rmium"440-43-4 ; Cobalt"440-5O-3 :Cooper7439-8°-fc .Iron•"43'?-l32-i iLead"439-=?5-4 IMagnesiu.T"T43':)-96-5 IMangane-ss"7439-97-6 I Mercury440-02-O I Nickel7440-09-7 {Potassium7782-49-2 [Selenium7440-22-4 [Silver

! 7440-23-5 [Sbdium7440-28-0 iThallium[7440-62-2 [Vanadium744O-66-6 [Zinc

2.o|u:16.8 I 3i.oiu;2.0[U

46800! !8.9IB3.01U14.21824 . 1 . B

0 I U I W69801 !I.OIU!

0.20!U!4 . 0 I U [

107013 I2 . 0 ! U !3.4IB16250! I1.018!3.418;14.7!8!

[ __________ [Cyanide . 3.5!U

P .

P '

CV 'p 'P :F ;p Ip ;F IP ',p IAS!

Sefore: COLORLESS Claricy Before: CLEAR Texture:

C.-iur Aftsr: COLORLESS Clarity After: CLEAR Artifacts

rORM I - IN

AR302657

4005

C PITTSBURGH

'.'nivs 'UQ/L -r m _!.•••'.3 or1

, C.-iS No .

. 42^-^0-57440-36-07440-38-2"440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-39-67439-92-1743^-95-47439-^6-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-2744O-66-6

i . ,, .

: Analvte

! Aluminum; An t imony! ArsenicI Barium[BerylliumI Cadmium! Calcium! ChromiumiCobalt: CopperI IronI Lead[ Magnesium! Manganese! MercuryiNickel! Potassium'[ Selenium[Silver[Sodium[ Thallium[ Vanadium[Zinc[Cyanidei

Ccr.csr.tr a t ion I C '

=? . 0 ! U8 . 0 I U2 . 0 I U2.1131.0!U2 . 0 [ U106 !B5 . 0 1 ij3.0 [U1 2 . 0 ! 813.9!81 . 0 ! U

12.0 [U1 .0[U

0.20!U4 . 0 ! U

si.o;u2.0 [U"3.0 [U41.6|81 . 0 ! 82 . 0 ! U4.3[8

"~ "3.5!U

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PcvppFPPcppAS

Color Before: COLORLESS Clarity Before: CLEAR 'extur=:i

Color After: COLORLESS Claritv After: CLEAR . Artifacts

Comments:

M302658

FORM I - IN

4006

_ J ,

- a r.

: Cc •.-!•_- 2 -• t - a c i o n ! >l, I

; -429--3C--5 ;A_>jni-'j-! 14718."440-36-0 ' Anti.i!-:ry , ^ . 1 [ 8'7440-38-2 iArseoi. : 2 . 0 ! L11*440-39-3 Barium : 25.0,'B•7440-41-7 , Saryll i'j - ' 1.0[U: -440-43-9 :Cadmi'..in ; 2.3[U. -'440-7C-2 !Calciu-n 2760O [, '440-47-3 : CnroiTH -in ; 5.0 [U• -744Q-4C-4 l cobalt 3.0[U7440-fO-3 Copper ; 11.5IB

ppFoPPPpPP

L.-on ; 374[ P, "43 5---'i- : Lead ; i.o;u^439-95-4 I Magnesium 521017439-96-5 !Manganase, 42.8]

; 7439-97-6 [Mercurv ; 0 . 20 ] U; "440-02-0 I Nickel ! 4.0 1U, 7440-0 -7 [Potassium! 15401B7732-49-2 [Selenium ! 2 . 0 ! U7440-22-4 [Silver ! 3.01U7440-23-5 [Sodium ; 6420!7440-28-0 IThalliun ! 1.0[U7440-62-2 [Vanadium [ 2.1187440-66-6 [Zinc i 4.6 IB

_ __ _ [Cyanide I 3.51U

p ,o IAS ;

i-r jafore: COLORLESS Clarity Sefore: CLEAR rextur-5:

lcr After: COLORLESS Clarity After: CLEAR Artifacts:

ts ;

AR302659

£ - IN

t w

Anal v tf>

; 742c'-90-5 [Aluminum,"440-36-0 ,Antin:cnv,7440-33-2 [Arsenic,'"440-39-3 8-arium7440-41-7 [Beryllium

; •'440-43-9 I Cadmium!7440-70-2 [Calcium; "440-47-3 I Chromium;7440-43-4 I Cobalt•-"440-50-3 ; Copper,743^-89-6 Iron;743^-92-1 I Lead17439-95-4 I Magnesium:7439-^6-5 ;Manganese17439-97-6 I Mercury,7440-02-0 !Nickel17440-09-7 !Potassium17732-49-2 [Selenium17440-22-4 [Silver;7440-23-5 jSodium[7440-28-O [ThalliumI744O-62-2 [Vanadium!744O-66-6! ______ [Cyanide

C Dncer c

171:3 : : ?3.0; u2 . o! u2 5 . 8 ! 31 .0!U2 .0 '.U

27800!5. "IB

OIU11.8184011 . O ! U

5160 I41.3!0.2CIU4 . 0 I U

1470182.0! U3.318

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Color Before: COLORLESS Clarity Before: CLEAR Texture:

Color After: COLORLESS Clarity After: CLEAR Artifacts

Comments:

AR30266Q

FORM I - IN

4008

I NO PC.-'

Lac. • j.' c : T . , -

--•••' L a _= -'e'. -?: .••_ j •

I CAS •*•: .

, "429-9C-5: 7440-36-0I 7440-33-2! -440-39-3; 7440-41-7; 744O-43-9; -M4C-70-2-440-47-37440-48-4

i 744C-50-S7439-39-6

, 7439—2-11 7439-55-4I :7A39- °6-57439-=?7-6

; 744O-O2-0i 7440-09-71 7732-49-27440-22-4[7440-23-51 7440-28-0[7440-62-2[ 7440-66-6iii

« r, a L * 1 =

A lurni "^u.nA n 1 i n o n yAr sen !•_•S a r i u mBery* i lU'nCadiT; iumCalCiJ'TiCnr Dm iumCobaltCopperT f /~\ «^

i_eadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concen tr a t ion [ C

9 . 0 [ U3 . 0 I U2 . 0 ,' U2.1!81.0!U2 . o : u129!S5 . o ; u3.0!U10.01813.5181 . 0 ! U

12.0[U1 .0!U

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AS;

•'"Dior- fefcre: COLORLESS Clarity Before: CLEAR Textura:

Color After: COLORLESS Claritv After: CLEAR Artifacts

Comments:

266

rORM I - IN' .33

Appendix BDPO Report

HR302662

I>0«CAMC ftCCIONAL DATA ASSCSSMC.NT

_________ SITE __ _____LABORATORY J TftS - Pi ITsta r*h NO or SAMPLES/

MATRIXJtEVlC»CR t'.r NOT £50)

SC'* " ————7/fT*r——————————————————— *EVt£»tins4MC **yt%lSSs4j&30t», Ku&t

*CT:CN ———— FY! ^_____ CCMPL£7iCs DATE

IC> A* H| CYANIDEI. HOLDING TIMES O ® O &

2. CALIBRATIONS £ O Q1. ILANKJ g> 0 i?

4. H3

5. LCS«. DfPLlCATZ ANALYSIS

7. MATRIX SPDCt O _£I. MSA S/ O

9. SERIAL DILUTION10. SAMPLE VERIFICATION g> <g> ^

11. OTHER QC ^ g

12. OVERALL ASSESSMENT _^_

O • Data had oo prob!ins/or Quaiined due to nieor protUnu.M • Din qualifod d«» to major problem.Z • Data vBKCtptabto.X • Problems. Virt do aoc a/fKt dan.

fTTM*

AREAS OF CONCERN:

NOTABLE PERFORMANCE:.

Attachment CSupport Documentation

ftR30266*.

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flB302665

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FORM III - IN

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ftR3Q2666FORM III - IN

4017

?crcar cr j t .on '.'n;.-. £ jn/:_ ; r :-o.' - 3

>Analy te

AluminumAntimonyA r s e n i o3ar lU'iiSary 1 1 '. _m1'adm IUITI

. Ca lo ium

'. ;pperIronLeaclaqnesiumrtdiqa-nesef-iar our^•\ic--elPo.a-5-Sium3 a 1 e n i u 'TiSi Iver3oaiu;nf ;i a L 1 L u mv anadiurnr i n oC van Ida

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FORM III - IN

Sit. Ha».Data Revitv worksheet! Reference »uxber

*tCIOV Z MTItW Of t*0*6AJfXCCOTTIUCT LAftCJUrOtY DATA

?:t- :*rcr«-.cr> r.aa.) A~ lfZfafctj *«ta package r»ce:vejI has t««n r«v;ew«d *n« th« qpj«iity «$sur*nc« «nd p«rfsr=*nct

^ .t i*ta rtv;«w

Ci»« He. SAS No. " S*»plinq C«t«(«) IrSOC. »o. /tfene>*7 Matrix tts#6r' Shipping C*t«(g) j~so. of Saaples r Date Roc'd by Lab 7-

Traffic Report Hos:

Trip vianx HO.: wen pEquipment Blank Ho.; Me

Dup Hos:

sew HO. r«<juir«« that specific analytical work b« don* and thatassociated reports b« provided by the laboratory to th« Regions, EMSL-"-V. and SMO. The general criteria used to deterair.e the perforsance were

en an exaair.ation of:-Data CoBpIetencss -Field Duplicates-Holding Tises -Lab Control Saaple Results-Calibrations -Furnace AA Results-Blanks -ICP Serial Dilution Results-ICP Interference Check Results -Detection Limit Results-Matrix Spike Recoveries -Saaple Quantitation-Laboratory Duplicates

Overall Coaaents:

Definitions and Qualifiers:L - 'j - Approximate data due to quality control criteria.R - Reject data due to quality control criteria.K -

Reviewer: "fJKr?** w-Jr* 0c<0r/ i- ^ r Oat.

ftR302668

Data Review wor* sheets

IX. HO ID 1 MO TXXtf Complete table for all sasples and circle th.analysis data for samples not within criteria.

* »* V

:/Wrr: "fcp/jr\tf£Qpg<f\/v1CDptf°i /Y<# /1 AtggZyii

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1j ——————

; :ATE

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?———————

———————

——————

———————

MC . CYAJ« I DECATE DATE

ANALYSIS ANALYSIS

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ACTION "

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METALS - 180 DAYS PROM SAMPLE COLLCCTXO*MERCURY - 2t DAYS FROM SAMPLE COLLECTXOVCYAHIDE - 14 DAYS FROM SAMPLE COLLECTION

ACTJOH: , ' #**-1. If holding times are exceeded all positive results are

estimated (J) and non-detects are estimated (UJ) .2. If holding times are grossly exceeded, the reviewer may

determine that non-detects ar. unusable (R) .

RR302669

Cat* R.vicv worksha.ts

i. DATA commons

yrssms !Nr;&*ATTQi» GATE LAS c -ft gs CAT?

rata Rev.tw worksheets

XXX A. XNSTftUXXVT CAU1JUTIO* (Section 1)

1. Recovery Criteria:.:st the »-«'.yt«s -.htc^ did rot seet the percent reccv«ry :%R) cr;ter:afsr I.-.:t;jl or :c.-.t:.-.u:r.? Calibration.

:ATS :r.'/ccv« ANALYTS JL Acrrcs SAMPLES Arygrrr;

If any ar.alyte does not seet the %R criteria follow the actions statedbelow:

For Positive Results:

AR30267I

Cat a Review Worksheets

XXX B. XVSTRCXDr? CALIIAATIOM (Section a}

2. Analytical Sequence •

A. :ii t.-.e :*bcr»tsry -se the prcper .-ur er ofstandards for calibration as described in thesew?

B. v«re calibrations perforsed at the beginning ef /^veach analysis? /Yes/or He

C. were calibration standards analyzed at the be-ginning ef sample analysis and at a minisua fre-quency of tan percent or every two hours during /~ ~\analysis, whichever is sera frequent? /Yes/or No

D. were the correlation coefficients for th. call*bration curves for AA, Hg, and Of i O.ffSt /Yes/or Ho

E. vas a standard at 2xCROL analyzed for all XC»analyses? / Xes}or He

• ^-_ -^If Ko,

The data may te affected. Use professional judgement to determinethe severity of the effect and qualify the data accordingly. Discussany actions below and list the samples affected.

(SB

ftR302672

Data Review Worksheet

XT A. BUUfI XXAIYIII UJOLTI (Sections 1-3)

List th« blank contamination in Sections 1 i 2 be lew. A separate-erfcshee; sneyld be sed for soil and water blanks.

Later*:sry •:*.-.** »»jkTRrx-

2. Equipment/Trip Blanks

EOf:? SLJ AMALYTE COMC./CNTT

'/

3. Frequency Requirements

A. Was a preparation blank analyzed for each matrix,for every 20 samples and for each digestionbatch? . Vet or Ho

B. Was a calibration blank run every 10 samples orevery 2 hours whichever is aore frequent? Yes 'or No

If Mo,

The data cay be affected. Use professional judgement to determinethe severity of the effect and qualify the data accordingly. Discussany actions below, and list the samples affected.

2. Equipment/Trip Blanks

DATE EQUIP SLI ANALYTE CONC./UNTTS

pat*

IV A. BLA*K ANALYSIS WMWt (Stc.____,

1. Laboratory aianxs

j%g/<33?2<2??:

'*•/

Af

pata Review Worksheet

IV A. BLAKX ANALYSIS ftimrf (Sector., !-;,,

List the blar.x cs.-.ta«inatian ,« «•-orxsheec sneuld t. us'd fOP ,01? aV/?iCns l * 2 -*icv- A ,„>«a«a tor soil and water tiar.Xs. separate!• Laboratory aiar.xs

MATRIX:- PRgP

Cy>&6

u7

2.3

3-3

AR302676


XT B. BLAXE AXALYtXf USOLTS (Section 4)

4. Blank Actions •

The Act:c.-. Levels for any a.^alyte is eqv;a; -s five tires t-e -•— .*-cs.-c.--. ration :.' -..-.at tlesei-.'s contaair.at.sr ..- any blann 4. I!:*?:level fcr sary.es which have been concentrated or diluted si-ou_Y":i'r-w*t;?.i.d by the csncantratisn/diluticn factcr. He posit ve sa-e:Iresuit should be reported unless the concentration of the analyte nsample exceeds the Action Level (AL) . Specific actions are ai fsf

1. when th. concentration is greater than th. IDL. but less t«i*« tAction Level, report the sampl. concentration detected with a 0

2. When the sample concentration is greater than th. Actionreport the sampl. concentration unqualified.

ELEMENT MAX. CCMC./ AL/ ELEMENT MAX. CQHC./UNITS UHITS

NOTE: Blanks .analyzed during a soil case must b. converted-to eg/kg inorder to compare them with th. sampl. results.' ' . .'.Cone, in ug/L X Volume diluted to f200n>H X 1L X IQOOqn X lug » »g/kg

''eight digested (Igraa ) 1000ml Ikg lOOOugMultiplying this result by S to arrive at the action level gives a finalresult in mg/kg which can then be compared to sampl. resuLtf-^ oc -.

Cat a Review worksheets

T A. XCP XtfTtX/tttNCt OIECE SAMPLi (Sections I 4 J,

i. Recsvery Criteria

in the ICS AB »o»ution which du *«*• -».t .*. ...-••i „.,» criter:i

CATE £LZ.1£MT |RSAMPLES

ACTIONS:

If an eleaent does not se.t the IR criteria , fellow the actions statedb.low:PERCEMT RECOVERY

<50% 50-7f% >120%


were Interference QC samples run at theend of each sampl. analysis run or a miper B hour working shift, whichever is _*..« nr.tjuen*.' vx*s/or No

If no.

th. .»ny actions b.lev and ll.t th. s?mpl.« affmlid

fiR302678

Cata Review Worksheets

T •. XC» nrrmmiWl CltCE SUPL1 (Section 3)3.

AL CA

Estisate the concentration produced by th.f 1ESTIMATED

(ug/L) AL CA FE MC

ACTICNS:

In general, the sample data can b. accepted without»,__ ....i- ——————,___ - .- _ »g ar.

Civ. explanations for any actions taken below:

Data Rev;tv

VI. HATRXlO— /—

TR •

Jecrvery Cr;'.enaList the persest recoveries for analyses which did net reet therequired sritern.S • asount ef spike added$$R • spikes f.spl. resultSR • sasple result

Analyt. SS*i—— | ———————

— | ———————— i ———————— ; ———————— j ———————

SRi———————

———————

S1

—————————1 ————

IX1

————————————

Actioni1 ————————1 ————————. ————————————————————————————————————— = ——————————

Matrix Spike Actions apply to all samples of the same matrix.

1. If the sacple concentration exceeds the spike concentration by atsr of 4 *r aor'e. no action is taken.

2. If any analyt. do.s not s..t th. %X criteria follow th. actionsstated below:

PERCENT<3Q% 3Q%«74%

2. Frequency .Criteria" " """- .- "-— - .=A. Was a matrix spik. prepared at the required fr.n

quency? (I«5>r MoB. was a post digestion spik. analyzed for elements

that did not aeet required criteria for aatrixspike recovery? (fes>»r No

A separate worksheet should be used for each matrix

Data R.VI.W worksfcms

LJUIORATCBT DOPtXCATfS

List the concentrations ef any analyte not seeting the criteria forduplicate prec:*;on, for soil duplicates, calculate the CROL ..i »^/kg-s.ng ve s«rp.» wtiqht. voiwse and percent solids data for t.-.e sasple.:-s:cate what criteria w«$ -j«c ts ev«uate precision by circl.r.s .ith.rthe RPD cr CRO'. far each eltsent. , S >7~

MATRIX:£• t"*1S

AluminasAn ti sonyArsenicBariumBerylliuaCadaiucCalciueChroaiuzCobaltCcccerIronLeadMaqnesivaManganeseMercuryNickelrotassiuaSeleniusSilverSodiuaTh.il:"-VanadiusZincCyanid.

£1waterug/t20040102005S

500010'so25100S

.5000.15

—0.2.40

_5000510

500010SO20

__ ,10_

QLsoil

1

————

————

————

————

Sasple J_ /dfvO fry

\

———————————————————

————————————————————————————————————————————————————————————

———————————————————————————————————————

Dup), icatji/*4£prr7S}

i

•

-

—————————————————————————————————

———————————

——————————————————————

—————————— .

•»O Act:an

Laboratory Duplicate Actions should b. applied to all other samples ofth. sac. matrix typ.,ACTIONS:

1. Estiaat.. (J). positiy. results for elements which have an RPO >20%for wat.rs and >35% for soils.

2. If sample results are less than Sx th. CROL, estimate (J) positiveresults for elements whose absolut. difference is >CRDL, (2XCROL forsoils). If both samples are non-detected, the RPO is not calculated(NC).

AB30268I

REGION ZData Review worksheets

VIII. FIELD OOPLICAT8I

List the concentrations of all analytes in the field duplicate pair.For soil duplicates,"calculate the CRDL in ag/kg using the sample weight,volume and percent solids data for the sample. Indicate what criteriawas used to evalute the precision by circling either the RPD cr CROL foreach elerent. - /'~

MATRIX: (SOW

RPD ActionElement

AluminumAntiaonvArsenicBariua , , ,BerylliuaCadmiumCalciuaChromiumCobaltCopperIronLeadMagnesiumManaaneseMercurvSickelPotassiumSeleniumSilverSodiuaThalliuoVanadiuaZincCyanid.

CRIwategug/L20060.w.20055

500C1050251005

= 000is.0.2.4Q_

5000510

:00010302010

21*soil*3/kg———

——————

———

Samp if £/u&W fo

— — ———————1 . , , . , . , „ 1 ——————————————— .

————————————————————

————————————————————————————————————————

"i•

Duplicate^MCfiP 40 D

i

i——————————————————————————————

• '

Field Duplicate Actions should be applied to all other samples of thesame matrix type.

ACTIONS:1. Estiaat. (J) positive results for elements which have an RPD >30%-

for waters and >50% for soils.

2. If sample results ar. less than 5x th. CRDL, estimate (J) positiveresults and (UJi nondetected results for elements whose absolutedifference is >2xCRDL, (4XCRDL for soils). If both samples are non-detected, the RPD is not calculated (NC).

RR302682

Cata Review worksheets

VXXX. mW DCniCATEB

List t.".t c one t.*t rat ions ef all analytes in the field duplicate pair."sr se:l 4*;pl.:ates. 'calculate t.*.e CRDL in ag/kg using the saoplc weight.vel-?e arc ?«r:tnt soliis data fer the sasple. Indicate what criteria.as -see tc eval^te the precisicr. ty circling either the *?: cr OCL fcreach eltrent.

MATRIX:

£££L **?9lm f PuPlieate* »»O Actionvat«r •' ---TA-- ——r t-- — - «**««

Aluminum_„Antimony_ArsenicBarium___Beryllium^.CadmiumCalciumChromiumCobaltCopp.rIron____,LeadMagnesium_Manganese !Mercury 'NickelPotassium_Selenium__Silver___Sodium___Thalliufl__Vanadium_.Zinc____Cyanide__mFi.ld Duplicate Actions should b. applied to all other samples of thesame matrix typ..

1. Estiaat. (J) 'po'sitiv. results for elements which hav. an RPO >30%for waters and >SO% for soils.

2. If sample results are less than Sx th. CRDL, estimate (J) positiveresults and (UJ) nond.tected results for elements whose absolutedifference is >2xCROL, (4xCRDL for soils). If both samples are non-detected, the RPO is not calculated (HC).

AR3G2.6S3

Data Review Worksheets

XX. ULJORATORY CONTROL

LCf

List anyaffected

LCS rtcevenes net within the ie-12Ct criteria and t."t samples

r.i SM _f ACTftffft SAMPLE? Afff.TEr

2. Sail;

List anyCPA forevaluateELEMENT

analytes that were net within th. control windows set by th.th. solid LCS sample. Th. BO-120% criteria is not used tosolid LCS results.LCS CONC. CONTROL WINDOWS ACTIOlf SAMPLES AFFECTED

ACTIOHS: 5Percent Recovery

SOLID LCS <£PA Control Windows >EPA Centre! Windeva

3. Frequency Criteria

A. Was an LCS analyzed for every matrix, everydigestion batch, and every 20 samples? /Yes/or No

Sata Review Worksheets

X A. rORJtACf ATOMIC AMOftPTXO* AtfALYfXf

1. Duplicate Precision........ euplicate infection* and or.e-peint analytical spikes were per-

f erred fcr all samples: duplicate inactions agreed wtxMn -;o».

........ ;uplicate injections and/or spikes were ret perfcrsea fir thefollowing samples/elesents:______________________am

........ Duplicate injections did net agree within * 201 for sanples/e 1 esents:._______________________- .__ ______

2. Post Digestion Spik. RecoveriesSpike recoveries met the iS-llSI recovery criteria for allsamples.Spike recoveries did net aeet the 85*115* criteria but didnot require MSA for the following samples/elements:

ACTIONS:

MSA was used to quantitate analytical results when con-tractually required.

___ Correlation coefficients >0.99S, accept results.____ Correlation coefficients <0.t§5 for samplenur-sers/e 1 eaents: _____________________________

Method of Standard Addition (MSA) was not performed as re-quired »cr saaples/eleaents:_______________________

1. Estimate (J) positive results if duplicate injections ar. outsid.* 20 % RSO or CV.

2. If the sample absorbanc. is <50I of post digestion spike absorianc.the following actions should b. applied: .

PERCENT RECOVER*"

3. Estiaate (J) sample results if MSA was required and not performed.

4. Estiaate (J) sample results if correlation coefficient was <0.995V rtCftR30268b


XX XX. SAMPLI

Saaple results fall within the linear range for ICP and withinthe calibrated range for all other paraseters.

£«=?!• results •••r« te.«c.-d the l.r.ear ra.rge/ calitraticr ra-seof the instr.rtent for the f clicking sarp.es/«l t^e.rts:

In the space fceicw, please shew a miniaum ef one sample calculationper method:

CYAN15E

N. *• r

For soil samples, th. following equation may b. necessary to convertraw data values (usually reported in ug/L) to actual sampl. pon-centrations (mg/kg):Th. lab is required to us. 1 gram sanpl. (wet weight) to 200 •!.Wet weight concentration » "~ ' —- - ...

digest cone, in as X 200ml X 11__ X IQQOgil X lag—— - 19* L 1 ga 1000 ml 1kg lOOOug kgIn addition the sample results are converted to dry weight using thepercent solids calculations:

Wat weight cone. X 100 » final concentration, dry\solids

Date : July 9, 1991

Subject : Inorganic Data Validation, Case 15741, SDG MCBB99

From : Nasser Massoomzade&y Darline F. TerrellData reviewer, ffl5w~ Project Manager


Overview

The set of samples for case 15741 contained 2 soilsamples which were analyzed through the contractLaboratory Program Routine Analytical Services.

Summary


Major Problems

No major problems were identified in this casepackage.

Minor Issues

Contamination in the initial and/or continuingcalibration and preparation blanks indicates thatthe qualitative identification of the analytes maybe questionable in those samples with aconcentration less than 5 times the amount presentin the blank. The affected elements are Antimony,Cadmium, Chromium, Copper, and Thallium.

AR302687

Ms. Diann Sims July 9, 1991Page 2

Low spike recoveries indicate that the quantitationis biased low , and that the detection limit may behigher than reported. The affected elements areAntimony, Manganese.

High variability in laboratory duplicate analysisindicate that the quantitation is less precise thanexpected for the method employed. The reportedresults and/or the detection limits are anestimate. The affected element is Calcium.

Low post digestion spike recoveries indicate thatquantitation is biased low, and that detectionlimit may be higher than reported. The affectedelement is Selenium.

Notes

The data was reviewed according to the NationalFunctional Guidelines for Evaluating InorganicAnalysis in conjunction with the Region III SOP.The text of this report addresses only thoseproblems affecting usability.

Information Regarding Report Content

Table 1 is a summary of qualifiers added to thelaboratory's results during data validation. Ifthere is more than one qualifier for a particularanalyte the qualifier applied is the one which•takes precedence.

Attachments:

1. Glossary of data qualifier codes.2. Data Summary. This includes:

a) All positive results which qualifier codes,if applicable;b) All unusable detection limits qualifiedwith an "R"; andc) All estimated detection limits qualifiedwith UJ or UL.

3. Appendix A - results as reported by thelaboratory ( no correction were made duringdata validation).

4. Appendix B - DPO Report addresses laboratorycompliance to the Statement of Work.

5. Appendix C - Support Documentation includesdetails to support the statementan-bir *his


Table 1Summary of Data Qualifiers

Analyte

Sb

Cd

CaCrCuMnSeAgTl

SamplesAffected

MCBB99MCEE01

MCBB99,MCEE01

MCBB99,MCEE01

MCBB99,MCEE01

MCBB99,MCEE01

MCBB99,MCEE01

MCBB99

MCBB99

MCEE01

Qualifier

Positive Non-Values Detected

ValuesB

UL

B

J

B

B

L

UL

B

B

Bias

highLowHigh

HighHighLowLowHighHigh

Comments*

AB(66.9%)

A

C

A

A

B(50.9%)

D

A

A

*See explanation of comments.

AR302689


Codes Used in Comments Columnt

A - One or more of the blanks associated with these samplesgave a positive response greater than the IDL (instrumentdetection limit). The reported results may be biasedhigh.

B - Due to low spike recovery (% recovery in parentheses ),indicating a possible matrix interference, the reportedresults may be biased low. Detection limits may behigher than reported.

C - Based on absolute difference of the analysis of thesample and the laboratory duplicates (>2xCRDL), thequantitation may be less precise than indicated for themethod employed.

D - Due to low post digestion spike recoveries, indicatingthat quantitation is biased low, and that detection limitmay be higher than reported.

RR302690

t t

Attachment lData Qualifier Codes


GLOSSARY OF DATA QUALIFIER (INORGANIC)

CODES RELATING TO IDENTIFICATION(Confidence concerning presence or absence of compounds):

U = Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) =Confirmed identification.

B = Not detected substantially above the level reportedin laboratory or field blanks.

R = Unreliable results. Analyte may or may not bepresent in the sample. Supporting data necessaryto confirm result.

CODES RELATED TO QUANTITATION(can be used for both positive results and sample quantitationlimits):

J = Analyte present. Reported value may not beaccurate or precise.

K = Analyte present. Reported value may be biasedhigh. Actual value is expected to be lower.

L = Analyte present. Reported value may be biased low.Actual value is expected to be higher.

UJ = Not detected, quantitation limit may beinaccurate or imprecise.

UL = Not detected, quantitation limit is probablyhigher.

OTHER CODES

Q = No analytical result.

ftR3Q2692

\

AttachMnt 2Data Summary Fo

AR302693

Appendix ALaboratory Results of all Target Analyt.s

AR302695

U.S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

I MCBB99ab Name: IT«S_PITTSBURGH_________ Contract: 68-09-13087 I___

Lab Code: ITPP_ Case No.: 15741 SAS No.: _____ SDG No.: MCBB99

Matrix (soil/water): SOIL_ Lab Sample ID: MCBB99___

Level Uow/med): LOW_ Date Received: 01/

% Sol ids : _74. 8

Concentration Units <ug/L or mg/kg dry weight): MG/KG

1ICAS No.117429-90-51 7440-36-017440-38-217440-39-317440-41-717440-43-91 7440-70-217440-47-3| 7440-48-41 7440-50-817439-89-617439-92-117439-95-417439-96-517439-97-61 7440-02-01 7440-09-71 7782-49-21 7440-22-41 7440-23-51 7440-28-0I 7440-62-21 7440-66-61 ,- t1 *. .

11 Analyte1lAluninuai1 Ant i nony1 Arsen ic1 Bariu*1 Beryl 1 iu«1 Cad* i u*1 Calciu*1 Chroniu*ICobalt1 Coooer1 Iron(Lead1 Magnesia*1 Manganese1 MercuryINickelIPotassiu*1 Seleniu*(Silver1 Sodiu*IThalliu*1 Vanadiu*(Zinc(Cyanide1

i iConcentrat ion 1 C 1 Q

1 13 1 00 1 I2. 1 IUI N5. 6 1 1

21.7IBI0. 26 IUI1.51 1

52701 1 *l.QIBI3.4IBI

15.11 18250 1 111.31 116701 11471 1 N

0. 12IUI5.3IBI415IBI

0. 53IUI W0.96IBI61.4IBI0.27 IUI6.5IBI

28.61 1 E0.47 IUI

1 1

1 lIM1IPIPIFIPIPIPIPIPIPIPIPIFIPIPICVIPIPIFIPIPIFIPIPIAS1

r

Color Before:

Color After:

Comments :ARTIFACTS:

BRQllfr

BROWN

FREE WATER,

Clarity Before:

Claritv After:

LEAVES. AND STONES

Texture: MED!

Artifacts: YES1

SR3026967/88

U.S. EPA - CLP 40Q4

EPA SAMPLE NO.INORGANIC ANALYSES DATA SHEET

II MCEE01

Lab Na*e: ITAS_PITTSBURGH_________ Contract: 6S-D9-00S7 I

Lab Code: ITPA_ Case No. : 15741 SAS No. : _____ SDG No. : MCBB99ft

Matrix (soil/water): SOIL_ Lab Saaple ID: MCEE01___

Level (low/»ed): LOW__ Date Received: 01/24/91

% Solids: _80. 7

Concentration Units (ug/L or *g/kg dry weight): MG/KG

1ICAS No.11 7429-90-51 7440-36-01 7440-38-21 7440-39-317440-41-71 7440-43-91 7440-70-2I 7440-47-3| 7440-48-41 7440-50-81 7439-89-617439-92-117439-95-41 7439-96-51 7439-97-61 7440-02-01 7440-09-71 7782-49-21 7440-22-41 7440-23-51 7440-28-01 7440-62-81744%-46-fci JjjL.i__! E~_

i1 Analyte11 Alu*inu*1 Ant i*ony1 Arsenic1 Bariu*IBerylliua1 Cad*iu*1 Calciu*1 Chro*iu*(CobaltICoooer1 Iron(LeadIMagnesiu*1 Manganese1 Mercury(Nickel1 Potassiu*1 Seleniu*(SilverISodiu*IThalliu*1 Vanad i uagWlIC*f CyanideJb.

1 IConcentrat ion 1 C 1 Q

1 134901 14.2IBI N5.21 1

22. 51 Bl0. 281 Bl0. 77IBI155001 1 *3.31 14. 31 Bl

23.41 f121001 1

9. 31 118101 1205 1 1 N

0. 12IUI7.3IBI4551 Bl

0.49 IUI0. 74 IUI62. 41 Bl0. 25IBI7. 6IBI

32. 41 1 E0. 43IUI

1 1

1IM1IPIPIFIPIPIPIPIPIPIPIPIFIPIPICVIPIPIFIPIPIFIPIPIAS1

Color Before: BflfiBC—— - Clarity Before: _____ Texture: MEDIUM

Color After: BROWN___ Clarity After: _____ Artifacts: YES.l

Consents:ARTIFACTS:_FREE_WATER, _LEAVES, _AND_STONES______________________

8B30Z697FORM I - IN

7/88

I-O«C».MC MCIONU *"*"

I. HOLD1NO TIMESL CALIBRATIONSJ. SIAWU

4. K55. LCS«. OUFLICATT ANALVS87. MATRIX S?DCI

f. MSA

>. SERIAL DILUTION10. SAMPLE VERIFICATIONII. OTHER QC

12. OVERALL ASSESSMENT

O • Data htd oe problems/orM • D>n qualified du« to major problem.Z • Data vaacceptabb.X • Probkos, bwt <to aoc a/ftct tfaOL

ACTION ITEMS

AREAS OF CONCERN:

NOTABLE PERFORMANCE-

302699 -

AttactUMnt CSupport DocuMntation

JIR3G2

U.S. EPA - CLP

3BLANKS

4012

Lab Name: ITAS_PITTSBURGH_______ Contract: 6S-D9-0087

Lab Code: ITPA_ Case No.: 15741 SAS No.: _____ SDG No.: MCBB99

Preparation Blank Matrix ( soi1/water) : SOIL_

Preparation Blank Concentration Units (ug/L or *g/kg): MG/KG

IAnalyteI________IAlu* inu*_I Ant i *ony_I Arsenic_IBariu*__f Beryl 1iu*ICad*iu*_ICalciu*_IChro*iu*_I Cobalt__I Copper__I IronI Lead!IMagnesi u*I ManganeseI Mercury_INickel__IPotassiu*ISel@niu«_(Silver__ISodiu*__IThalliu«_IVanadiu*_I Zinc____I Cyanide_I

Initial ICalib. I Continuing CalibrationBlank I Blank (ug/L)<ug/L) Cl 1 C 2 C

9.0_IUI8. 0_IUI2. e~IUI3 IBL

Prepa-rat ionBlank

_0. 2001U Mj0. 4001UI

vsa. ft9,01 aJ IT*?-1.SL3.1B I I P

.._i^g[BJ IP_.12.95*}, IB LiP_0.2001UI IF_2. 400 IUM P0. 200IUI IPPI IPlgimi ICV

10.200IUI IP_0.400IUI IF_

i IP591 I BLIP

0. 200 IUI IF.-0.JL9A1B I IP__0. 2001U M P_0.3501UI I AS

I I I .

FORM i n - I N flR30270l7/88

U.S. EPA - CLP

3BLANKS

40)3

Lab Name : I TAS_PITTSBURGH_________ Contract : 68-09-0087t

Lab Code: ITPA__ Case No. : 15741 SAS No. : _____ SDG No. : MCBB99

Preparation Blank Matrix (soi1/water): ____

Preparation Blank Concentration Units (ug/L or *g/kg):

11111 Analyte11 Alu*inu*_1 Ant i*ony_1 Arsenic1 Bariu*tBery 1 1 iu*Kad*iu*rcalciu*1 Chro*iu*_(Cobalt1 Copper1 Iron(Lead1 Magnes iu*1 Manganese1 MercuryINickelIPotassiu*1 Seleniu*ISilver1 Sodiu*IThalliu*1 Vanad iu*_1 Zinc1 Cyanide1

InitialCalib.Blank(ug/L) C

&

__

__

~

KJL^(•__

1

Continuing CalibrationBlank (ug/L)

1 C 2 C 3 C

9.0 IUI" us i rtft

2.0 IUI 2.0-r7i,fr IRT1.0 IUIV\fr ij>

a~a_iuii i

i.aB iyiCL-» i . A i a iCJ.A ilj,

.14.0 IU

1

k , ij.^-a IU

K--7*'ia'll

1.0

u

__

~__

u

—

"

2.0 U

~

~"

_

-

Prepa-rat ionBlank C

\£14 1f______

~_~_

_

—

IIIII MIIPIPIFIPIPIPIPIPIPIPINR_IF ~~IPIPINRIPINR_IFIPIPIFIPIPINR_I

"3027027/88

U. S. EPA - CLP 4074

3BLANKS

Lab Nai»e: I TAS_PITTSBURGH_________ Contract: 68-D9-0087

Lab Code: ITPA_ Case No. : 15741 SAS No. : _____ SDG No. : MCBB99

Preparation Blank Matrix (soi1/water): ____

Preparation Blank Concentration Units (ug/L or iig/kg): ____

11111 Analyte11 Alu*inu*1 Ant i*ony_1 Arsenic1 Bariu*1 Beryl 1 iu*(Cad*iu*ICalciu*1 Chro*iu*_(Cobalt1 Copoer1 Iron(Lead1 Magnesiu*1 Manganese1 Mercury(Nickel1 Potassiu*ISeleniu*1 Si 1 ver1 Sodiu*IThalliu*1 Vanadiu*1 Zinc1 Cyanide1


^-" — - —— «J^ -2.0

&.j*

——— 3y&

_

B

l""

c


1 C 2 C 3 C

2.0

-1. 1

'• • t*_*.•'•

.,.

U

_~~~B

~_

1.0

—

—

—

U

~~_

-

11__

~~

Prepa-rat ionBlank C

iiiI MI __INRINR"INR

INR_INR_INR_INR_IF _INR_INR_INR_INR_INR_INR_INR~INR_INR_INR_INR_INR_I __

ftR302703FORM III - IN

7/8f

U.S. EPA - CLP

3BLANKS

4075

Lab Name: ITAS_PITTSBURGH_________ Contract:, 68-D9-0087

Lab Code: ITPA_ Case No. : 15741 SAS No. i _______ SDG No. : MCBB99

Preparation Blank Matrix (soi1/water>: _____

Preparation Blank Concentration Units (ug/L or *g/kg):

Analyte

Al u*inu*Ant i*ony_ArsenicBariu*LBeryl 1 iu*Ead*iu*rCalciu*1 Chro*iu*CobaltCopper

1 Iron(Lead1 Magnesia*1 Manganese1 Mercury(Nickel! Potass iu*1 Seleniu*(Silver1 Sodiu*IThalliu*_1 Vanadiu*_1 Zinc1 Cyanide1


2.0

—————— £M—— «P

_u

_

_

-

~"~Ct-_tri_i

ii


1 C 2 C 3 C

2.0

YI

—

U

—

____~~

~

~__

~

2.0

—

U

—

__~__

—

_

__

-

-

_

__

—

-

Prepa-rationBlank C

1f

V—

__~

~_

—

11111 M1INR_INRIFINR_INR_INR_INR_INRINRINRINRINR_INRINRINRINR_INR_INR~INRINRINRINR!INR_INR~1

FORM III - IN7/88

u. s. EPA - CLP 40775A

SPIKE SAMPLE RECOVERY

Lab Nane: ITAS_PITTSBURGH_________ Contract : 68-D9-0087

•


Matrix: _SOIL_________ Level (low/wed): _LOW___

% Solids for Sample: _80. 7

Concentration Units (ug/L or *g/kg dry weight): MG/KG

Consents:

1 11 11 11 Analyte 11 11 A Ijj* i_nuji_l1 Ant tinny F1 Arsenic 1IBariu* 11 Bery 1 1 i u* 1ICad*iu* 1

Contro 1Li*it*R

75-125_75-12575-12575-12575-125

ICalciu* 1(Chro*iu* 1(Cobalt 1ICooper 11 Iron 1(Lead 11 [email protected]* 11 Manganese 11 Mercury 1(Nickel 11 Potassiu* 11 Se 1 eniu* 1(Silver 1(Sodiu* 1(Thalliu* 11 Vanadiu*_l(Zinc 1(Cyanide 11 1

75-12575-12575-125_

75-125_

75-12575-12575-125_

75-12575-125_

75-123.J75-123-75-1233

Spiked SaapleResult (SSR) C

86. 301312. 5143

470. 101010.812811.0015

45. 3338112.300571.2258

13.5939

267. 67390. 6770

110.6791

2. 208410.0693

1 -1*. 3328

mm lg?L 8774|ffi S. 0704_

~__

_

~_

_

_

_

_

~

11

Saiple 1Result (SR) Cl

11 1

4. 2087 IBI5.15291 122. 4552 IBI0. 27531 Bl0. 77071 Bl

1 13. 2640 1 14. 3029 IBI

23. 3857 1 11 1

9.29981 11 1

205. 2587 1 10. 1239 IUI7. 3459 IBI

1 10.4908 IUI0.7361 IUI

1 10.2454 IBI7. 6386 1 B 1

32. 3656 1 10. 4328 1 U 1

1 1..._.. _ ——— .... — — y— —————— » - •• - —

11

Spike 1Added (SA) 1

1(

122. 69 K9. 821

' 490.76112.27112.271

149.081122.6916 1 . 34 1

14. 91 1

1122.691 s0.561

122.6911

2.45112.271

112.271122.691122.6916. 181

1

1*R Q Ml

1- ——— -~L NRI^,fefeT^JNlP

?|p' IPIP

1 INR85. 7 1 1 JM|88.0) <•78.01 lJ^

1 INR87.51 IF

.- ———— — k-JNR• -sa- iMLP120.91 ICV84.21 IP

1 INR90.11 IF82. 1 1 IP

1 INR92.01 IF87.3I_IP77.81 IP82. 0 1 1 AS

1 1

FORM V (Part 1) - IN 7/88

ftR302705

U. S. EPA - CLP 4079

6 EPA SAMPLE NO.DUPLICATES

I It l MCEE01D Iab Name: ITAS_PITTSBURSH_________ Contract: 68-D9-0087 I______________l


Matrix (soi1/water): SOIL_ Level (low/med): _LOW_

* Solids for Sample: _80. 7 % Solids for Duplicate: _80.7

Concentration Units (ug/L or mg/kg dry weight): MG/KG

111 Analyte11 Aluminum1 Ant imony1 Arsen ic1 Barium1 Bery 1 1 i u*1 CadmiumJ.rjil^iu» J1 Chromi u*(Cobalt1 Copper1 Iron(Lead1 Magnes iu*1 Manganese1 Mercury(Nickel1 Potass iu*1 Seleniu*ISilver1 Sodiu*1 Thallium1 Vanadiu*1 Zinc1 Cyanide1

ControlLimit

2.5

1 _1 226.9..

6. 1

_ 1226. 9_

-ii. ',<j L j» ri—— JHBEZ.1™ '

f

11

Sample (S) Cl1

3489.55531 14. 20871 Bl5. 15291 1

22. 45521 Bl0.2753 IBI0. 77071 Bl

r 15535.29031 13.26401 14. 3029 1 B 1

23. 3857 1 112095.66641 1

9.29981 1____ 1806. 6559 l_l

205. 2587 1 10. 1239IUI7. 3459 IBI

455. 2399 IBI0. 4908 1 U 10.7361 IUI62. 3981 IBI0.2454 IBI7. 6386 1 B 1

(VSpC* 32. 3656 1 1^5 0. 4328 1 U 11 " ^ I I

11

Duplicate (D) Cl1

3078.62931 13. 5091 IBI7.11601 1

21. 2887 IBI0. 2454IUI0. 7840 1 B 1

5634.58431 I<J1.4193IBI4. 26981 Bl18.33241 1

11802.92761 110. 4776 1 1

____ 1542. 08321 _l172.31771 10. 1127IUI7. 28651 Bl

446. 0147 IBI0. 4908 1 U 10. 736 1 1 U 156.9171 IBI0. 2454 1 B 16. 82521 Bl29.07821 10. 4337 1 U 1

1 1

RPD

12.518. 132.05.3

200.0- 1.7.

d 93.578.80.824.22.4

11.9_ 15. 8_

17. 4

0.82.0

9.20.011.210.7

Q M

PPF\jph*>

_u>»ifcIPIPIPIPIFIPIPICVIP

-IP-IFIP-IPIFIPIPIASI1 1

7/88

Cat,* fftvitv vorkshaats SittJ **faranea

.No. of Saaplas

Cate(s).„—, Cate(*)

Data Xac'd by Lab

Traffic Report Ho*:

Trip flank Mo.:Cqvipaent flank Ho.: ______ _______Fiald Dup »o«: - - - ~ —_____________~ 7

SCW Mo. 7/tf'X' raquiras that specific analytical vbrk be dona and thatassociated reports be provided by the laboratory to tlse Ration*. E.MSL-LV. and SMO. The general critaria used to determine the performance werecased on an examination of:

-Data Completeness -Field Duplicates-Holding Tisa* -Lab Control Sample Results-Calibrations -Furnace AA Result*•Blank* -ICP Serial Dilution Results-ICP Interference Check Results -Detection Liait Results-Matrix Spike Recoveries -Saaple Quantitation-Laboratory Duplicates

Oafinitions and Qualifiars:L -

„,_ __—— r * S •*+*} &V1**' *~* *****'' +f - -*£/ i*r -• •*— *—- ' —•

J - Approxiaata data dua to quality control critaria.R - Reject data dua to quality control critaria.K — tfeS zSs g/a^*^JJ>ii»

Reviewer: . . — -~ ,*,f r owr - ^ *- Date:

AR302707

Data Rev;ev Worksheet*

X. DATA CCXfLtmZf*

yyssivs rvr ;V>TTQ» CA rt LA l cc N TA cr go CAT?

Data Review w

ZX. aOLDIHO TIXII Coaplete table for all sasple* and circle theanalysis data for saaples not vitlun cr:teria.

1

; WC8Mf

1

itI( ————ill ————I•i•ii•it1l

:

11 ——————

; :ATE, » W . r ww «r

/ — 2 *? -» £f i

hV- 11

————————

-, i

MC , CYAJ< I DCCATE CATE

ANALYSTS A.VA»YS:S

LM*- */*,.>«-?/„1 —— . —— i( ————— .1 1———— I ————1

11————— .1 ————— .111

——————— ; ———————1i

i1

————— i —————Ii1iJ—————— • —————11 - -„•

OTHERS pMCATE '

ice j /)/y*

n*-*4-4, J <*#$e j -

r* \&4-1I '

i—— i ———— i ——

iii*ii•i•ii• — — -_,«

ACT: ON

i

METALS - 110 DAYS FROM SAMPLE COLLECTIOffMESOJRY - 21 DAYS FROM SAMPLE COLLZCTXO*CYANIDE - 14 DAYS FROM SAMPLE COLLECTIOH

ACTIOM: 'fafrtftf\. If holding times are exceeded all positive results are

estiaated (J) and non-detects are estiaated (UJ).

2. If holding tiaes are grossly exceeded, the reviewer maydetermine that non-detects ar* unusable (R).

SR3027G9

Cat a Jtev.ew worksheet*

XXZ ft. XXSTHCX2VT CALIIRATIOW (Section 1)

1. Recevery Criteria•_:st t.-.e t-alytes -.ntc.-. «:d rot =eet the percent reccvery :\*) cr:ter:af:r r.-it.j; or ?:rt;-w;rc Cal;tration.

-AT£ !TV'Cr-« ANALYTS J2 ACTICN

ACTIONS:

If any a.-.alyte doe* not seat the %* critaria follow the action* statedbelow:For Positive Result*:

RR3027IO

Data Review Worksheet*

xxx B. iviTBcrxxyr CAUBJUTXOI (Section *)

2. Analytical Sequence

A. r.i t.*:t lafccratsry wse the prcpar .•".r.ser efstandards for calibration as described in the

'es /fcr NOwere calibrations perfacted at the beginning ofeach analysi*? /Yes or NO

C. "ere calibration standards analyzed at the be-ginning of sajiple analysi* and at a ainiaua fre-quency of ten percent or every two hours duringanalysis, whichever is aore frequent? / Yes ?r No

D. were the correlation coefficient* for the cali-bration curve* for AA, Hg, and Of i O.MS? ( Ye* pr No

E. vas a standard at 2xCftOL analyzed for all XCPanalyse*? /Ye* or No

If No,

The data way be affected. Cse professional judgesent to deterain'the severity of the effect and qualify the data accordingly. Discussany acticr.s below and list the saaples affected

£ wis

AR3027II

Cata Revitv Vorkshttt

XT A. 8UUIK AJIAIYIII AfSOLTS (Section* 1-3)

List the blank contaaination. in Sections i ft 2 below. A separate• orksheet should be vsed for soil and water blanks. 7 - /•

ATS

ccs,

&A

2. Equip=ent/Trip Blanks

L*;? 8Lf ANALYTE

3. Frequency Requireaent*

A. Was a preparation blank analyzed for aach aatrix,for every 20 saaples and for each digestion / v)batch? . ( Ye*/or No

8. Was a calibration blank run every 10 sample* or / ~\every 2 hour* whichever is aore frequent? /Yesyor Mo

If No,The data cay be affected. Use professional judgement to determine

the severity of the effect and qualify the data accordingly. Discussany actions below, and list the saaples affected.

• 9

pata Review Wor<

IV A. BLA*K ANALYSIS RESOLTS (Sectors 1-3)

List the blarx cs.-.taaination in Sec-ens i t - w -vorxsheet should t. used for soil and Vat.r blanks. ' Ai. Laboratory 31anxs

S?5,'C-?i PREP

^

'i CA

pata Review Worxsheac

IV A. BLANK ANALYSIS RESOLTB (Secti.n,

?c&Lec$,<2C0.2C0J

L- «tf

Pi

A "P'rate1. Laboratory 21anxs * -/

f MATRIX: $9*C-All K5, -.! gpgp n

** "**

Data R*v;tw Worksheets

" B. BLUI WltTSXB JttSOLTS (Section 4)

«• Blank Actions

^- - -. >« u.. e»r oth.

MATKlXi———————

«»«

/ 4

cone- iB U9/t

SR3027I5

rid

MOZOW tData Review worksheet*

XT B. BUUff ANALYSIS RfSOLTS (Section 4)

4. Blank Action*

The Act is.-. Leve.f for any «.r«;yte is eqv;a: tc five ti=es the • ;*es-cs-ce-trjtior. :.' t.fc.at tlesent's csntaair.at ;s.-. ..-. *ny fcla.".*. r>.t »ct---levei fcr sar:.«s which have been concentrated or diluted sf;5«;d"*'er^it;?:;ed ty tr.e conce.itraticn/diiuticn factsr. No positive sase'eresuit should be reported unless the concentration of the analyte ;n t*esaaple exceeds the Action Level (AL). Specific actions are as fsllevs:

1. Whan tha concentration is greater than tha IDL, but la** than thaAction Level, report the saapla concentration detected with a U.

2. Whan tha saapla concentration is greater than tha Action Levelreport the saapla concentration unqualified. '

HAT*IX; J v~ MATRIX:

ELEMENT MAX. C1NC.7 AL/ ELEMENT XAX. CQMC./UNITS

*•?>**/£

NOTE: Blank* analyzed during a soil case Bust fc« converted -.to eg/kg inorder to coapara them with tha sample result*.

Cone, in ug/L X Volume diluted to f200ml) X U^. X IQOOag X Ifflfl » mg/kgWeight digested (Igraa ) 1000ml 1kg IQOOug

Multiplying this result by 5 to arrive at tha action level gives a finalresult in rog/kg which can then be compared to sample result*.

J.R3027I6

Cat a Review worksheets

* *• XC» X»Ttft/mxci ClIECf SA*FH (Section, l 4 2)I. Recovery Criteria

in th. ICS'A.

5ATE E.£.M£NT |X AC— CMACT.CN

ACTIONS :doe, not ae.t th. |R crit.pU §

actions statPERCENT RECOVERY

<50% 50-79% >120%

2. Frequency Requirement*

Were Interference QCs fjfjgetIf no,

^

thaany action* below and list tha

/IR3027I7

5ata Review Worksheet*

r-r-NT CMC. CIT-TE:,, IN rttf T« C-NC

££4C&>

SXMPLE ELXXENTAFFECTED AFFECTED S f NTERFERIHT UT»UTIO

respective level, ill t t i < '.iu "» "*

Give explanation, for any action* taken below:

Cat a Review Worksheet*

*X. HATBX1

TR ,MATRIX;

Peccvery Criteria

list the per:..-:: recoveries for ana^v-** • *.-* ^ ^required criteria. «n».y..s .hich did not r..t the

S - aaou.it o. spike addedSS* • spikes saaple resultSft - sazple result

Matrix spike Action, apply to .11 sample, of the same matrix.

ACTICNS:

I. If the sacpit concentration exceeds the «^v. , __factsr of ; cr aore, no action iV takan. concentration by a

2. If any anaiyte does not seet the %R crit.ri. *«n,~, *wstated below: criteria follow tha actions

2. Frequency .Criteria " •--- . -^. . .

at the required fr«-or No


Data Review Worksheet*

VII. LAJOJUTCIT DOFLJCATIJ

List the conctitration* of any analyte not s.eting the criteria fori-jplirat* precision. For soil duplicate,, calculate the CROL „?» wg/kg.s.r.c v.« sarp.t we.aht. veiwse and percent solids data for the sa»p:..:- = ic*:e ..-.at cr.t.ria was .sec ts evaluate precision by cirs:..-.s .;t.*.erthe RP£ cr CR01 far *ach element.

MATRIX:

^ ____ azctoil -"'•-'--• . - - _ _

AluminasAn ti sony .ArsenicBariumBerylliuaCadmiueCalciueChroaius .CobaltCcccerIronLeadMagr.esiuaManganeseMercury.vickel?oeassiuaSelenius _SilverSod i usThailiui .vanadiumZincCyanide

ug/L200.•0102003*5

.5000.,.io

__ 50.__ 25.100S

soco" 15*0.240

500050

5000105020r10

i

• — """ —— *H03^ — *"

i

i

.1 .————————

I5f3£*23*f

———————————

n • •

*

j i

££34*.&ftYf

—————————————————————————————————————————————————————————————————————————————

~_ -

Laboratory Duplicate Action* should ba applied to all other sample, oftha sasa matrix type).ACTIONS:

1. Estiaata (J) positive result* for element* which have an RPD >20%for water* and >35| for soil*.

2. If sample result* ara less than Sx the) CROL, estimate (J) positiveresults for elements whose absolute difference i* >CRDL, (2xCRDL forsoils). If both sample* are non-detected, the RPO is not calculated(NC).

AR302720


vixx. nut DOLXCATSS

Element

AluminumAntiaony _ArsenicBariuaBeryl liua.CadaiuaCalciuaChromiumCobaltCopperIronLeadMagr.esiuaManganeseMercuryMicxelPotassiusSeleniumSilverSodiumThalliusVanadiuaZincCyanide __

£2.vaterwg/t

-1— *oo.- — *°-- — lo-• 200" I s "s.1.5000._! __ 10.1——50..j __ 2S.1 100

1 g.1-5000.. __ 15.. _o.2.J _ «.-I-5000.

: .,10rOOO

.i _ 10.

.! __ 50.20

.L— 10.

BLB9.1

, -f/kf_ ____

—————___________ |

Saatpif |

———————————

MATRIX:

DuDl|f |f f |

11- —————! ———————— .

*FD Action

i i

J — . ———j —————j ————I ———1 ' ""'l

• ~^"j» injtj

j

•jj1

Field Duplicate Action* should ba applied to all other samples of thesame natrix type*

ACTIONS*

for *1"">t' whlch '2. If sample results ara les* than Sx tha CRDl, estimate (J) positive

results and (UJ) nondetected results for element* whose KsolutIdiff.rtnce is >2xCRDL. (4xCROL for soil*). If both samples are non-detected, the RPO is not calculated (HC) .

AR30272I

Data Ravitw Worksheets

XI. LAJOIUTCIT COVTROL IAXPU

1. Ag\;eeu« Lgf

List any LCS recoveries not'within the IC-1261 criteria and t-e samplesaffected.

U ACTION SAMPLE* i>r*f~~t'*

List any analytes that were not within thai control window* set by theEPA for the solid LCS saapla. Tha BO-120% critaria is not used toevaluate solid LCS results.ELEMENT LCS CQMC, COMTSOL WINDOWS ACTICM SAMPLES AFFfCTED

Percent Recovery

SOLID LCS <EPA Control Window* >EPA Control Vindevs

3. Frequency CritariaWas an LCS anadigestion batchi and every 20 sample*? ~ ( Yes/'or Mo

A. Was an LCS analyzed for every raatrix, every ^ ,

data Review Worksheets

S A. rCJUACt AfCNXe ASSOftmoV VHAITIIS

1. Duplicate Precisionduplicate infections and ore-point analytical spikes vert per-forred for all saaples: duplicate infections agreed -itMn -.91.

rupiicat. injections and/or spikes --ere rot perfsr=ea fsr t.-.efollowing saaples/elesents: _____________________ _

Duplicate injections did not agree within » 20% for samples/• l.s.nts: _______________________ „

2. Post Digestion Spika RecoveriesSpike recoveries met tha iS-1151 recovery criteria for allsample*.

<*"- Spike recoverie* did not aeet tha SS-11SI criteria but didnot require MSA for the following samples/el.o.nts:

MSA vas used to quantitate analytical result, when con-tractually required.

___ Correlation coefficient, >0..9S, accept results.___ Correlation coefficients <0.99S for samplenurxers/elements:_____________________________

Method of Standard Addition (MSA) vas not performed as re-quired for samples/elements:

ACTIONS •* w™^ »

1. Estiaata (J) positive result* if duplicate injection, are outside* 20 % RSD or CV.

2. If the sample absorbanca i, <SO% of post digestion spike absoriancetha following actions should ba applied: .

PERCENT RECOVERY"

3. Estimate (J) sample result* if MSA was required and not performed.

4. Estimate (J) sample result* if correlation coefficient wa, <0.99S.AR302723

Data Review tforksheats

ix. ixt>ocTinu eeoftie PLASMA <xc?) SERIAL DXLUTXOV AXALYSIS

Serial Dilutions were performed for each aatrix and resultsof the diluted sample analysis agreed within ten percent ofthe original undiluted analysis.

Serial "ilutions ver. not performed for the following:

S.rial Dilutions vera performed, but analytical results didnot agree within 10% for analyte concentrations greater thanSOx Use IDL before dilution.

Report all result* below that do not Beet the required laboratorycriteria for 1C? serial dilution analysis.MATRIX:

ELEMENT IDL SOxXOL SAMPtC SERIAL %D ACTIONRESULT DILUTION

AluminumBariumBeryl 1 iuaCadaiuaCalciumChromiumCobaltTopperIronLeadMagnesiua,ManganeseNickelPotass iuaSilverSod iuaVanadiua.Zinc

i "i

————————————

i

———— il-o !jro

————————————————————————————————————————————————————————————————————————

—————————

//*• &

i————— i————— !————— 1————— j————— 1————— 1—— T3 —— '1 *VS>~£

Actions apply to all sample* of the same aatrix.

ACTIONS:

1. Estimate (J) positive result* if *D >1S.


IXZ. DtTBCfZOV 11*IT AXIOLTS

1. Instruaent Detection Limitsr.-.str.zent detection Liait results wer. present and fswnd ts ttless t.-.a.r the Ccntract .".quired Cetectis- Lisits.

:SLs -ere not includes in the data package on For: x..

I£Ls »«re pr.s.nt. but th. criteria vas not r.et fsr t.-.efellowir.j el.c.nts:______________________________

2. Reporting Requireaent,

If No,

w.r* saaple result* on Fora X reported down to / ~> ^tha XDL not the CROL for all analyte*? /Yes/or NoWere saapla result* that were analyzed by ICPfor Sa, Tl, A*, or Pb at least Sx XOL. Yes or NoWere sample weight*, voluaes, and dilutionstaken into account when reporting detection /^limit* on Fora X. /Yesjbr No

(/

Tha reported results may be inaccurate. Make the necessary changeson the data suasary tables and request that the laboratory resubait thecorrected data.

AR302725


IX XX. SAXPLB CCAXTXTJ-TIOM

Sample results fall within the linear range for TCP and --ithinthe calibrated range for all other parameters.

«*=?:« results .«re te.c.-d the l.rear r_.-;e ealibrat--- -»--eof tr.e instr.-ent for the following sarp.es/elerc.-.ts :

In th. spac. b.icv, pleas, shew a minimum of on. saaple calculationper method:

^_w

For soil samples, tha following equation may be necessary to convertraw data values (usually reported in ug/L) to actual sample con-centrations (ag/kg) :

Th* lab i* required to us* 1 gram sample (wet weight) to 200 al.Wet weight concentration * -- - — ... .._

digest cone, in ya X 200n>l X 1L __ X lOOOcni X IngL 1 ga 1000 al ikg lOOOug kg

In addition the sample results are converted to dry weight using thapercent solids calculations:

Wet veioht cone, X 100 » final concentration, dry weight (ntg/kg)*sclids &R302726

Date : July 9, 1991

Subject : Inorganic Data Validation, Case 15536, SDG MCDP80

From : Nasser Massoomzafa^^ Darline F. TerrellData reviewer, /fa$&t/ Project Manager

To : Ms. Diann Sims /EPA Region III TES Contract Coordinator

Overview

The set of samples for case 15536 contained 5 soiland 1 water samples which were analyzed through thecontract Laboratory Program Routine AnalyticalServices. The sample set included 1 field blank.

Summary


Manor Problems

Sodium is biased high since the results in samplesMCDP81 and MCDP82 were entirely due to interferencefrom Iron.

Minor Issues

A low correlation coefficient for a calibrationcurve indicates that results may not fall withinthe linear range of the curve. The affectedelements are Lead and Selenium.

Contamination in the initial and/or continuingcalibration and preparation blanks indicates thatthe qualitative identification of the analytes maybe questionable in those samples with aconcentration less than 5 times the amount presentin the blank. The affected elements are Aluminum,Beryllium, Chromium, Copper, Manganese, Cadmium,Nickel, Lead, Sodium, and Zinc.

AR302727


The possibility of false positive exists forelements which are not present in the EPA providedICS solution and are present in the samples. Thesamples with comparable or higher levels ofinterferents and with analyte concentrations thatapproximate those levels found in the ICS solutionwere biased high. The affected elements areBeryllium, and Vanadium.

The possibility of false negative exists forelements, when negative results are observed forelements that are not present in the EPA ICSsolution, and their absolute value is >IDL. Theresults of the affected analytes in the samples<IDL, are qualified biased low. The affectedelement is Cadmium.

Low spike recoveries indicate that the quantitationis biased low , and that the detection limit may behigher than reported. The affected elements areAntimony, Arsenic, Cadmium, Lead, and Selenium.

High variability in laboratory duplicate analysisindicate that the quantitation is less precise thanexpected for the method employed. The reportedresults and/or the detection limits are anestimate. The affected element is Cadmium.

Low post digestion spike recoveries indicate thatquantitation is biased low, and that detectionlimit'may be higher than reported. The affectedelements are Arsenic and Selenium.

Low correlation coefficient for the Method ofStandard Addition analysis (MSA), indicates thatthe result is not within the linear range of thecalibration curve. The affected element isSelenium.

Notes

According to USEPA Contract Laboratory ProgramStatement of Work for Inorganic Analysis 7/88, thewater samples must be preserved at PH of <2 formetals. The PH for water sample was not in therequired range as outlined for preservation of thesamples. The PH of the water sample for metals was7. No qualification is made to the sample sinceRegion III does not specify any Guide!ines forqualification. HB3u2/28


Several samples had elevated detection limits dueto the dilution of the sample. These dilutionswere performed to overcome the effects of thematrix interferences.



Table 1 is a summary of qualifiers added to thelaboratory's results during data validation. Ifthere is more than one qualifier for a particularanalyte the qualifier applied is the one whichtakes precedence. Table 2 is a summary of allsamples which required dilution but for which theanalyte was not detected.

Attachments:





5. Appendix C - support Documentation includesdetails to support the statements in thisreport.

AR302729



Analyte

AlSb

As

Be

Cd

CrCuPb

MnNi

SamplesAffected

MCDP83

MCDP80-MCDP82,MCDP84,MCDP85

MCDP83MCDP80-MCDP82,MCDP84,MCDP85

MCDP80-MCDP82,MCDP84,MCDP85,MCDP83MCDP81

MCDP80-MCDP82,MCDP84,MCDP85MCDP85MCDP81,MCDP82MCDP85

MCDP83

MCDP83

MCDP83MCDP80-MCDP82,MCDP84,MCDP85,MCDP83MCDP80-MCDP82,MCDP84,MCDP85

MCDP83

MCDP83,MCDP84

Qualifier


ValuesB

UL

UL

L

BK

ULB

ULJ

B

B

B

J

J

B

B

Bias

high

LowLow

Low

LowHigh

LOWHighLow

HighHighHigh

HighHigh

Comments*

B

E(62.8%)

G

E(47.5%)

BC

E(49%)BDF

B

B

BAr=0.989,r=0.9884,r=0.990

E(30.1%)

B

B

&R30273Q


se

Na

V

Zn

MCDP80,MCDP82,MCDP84,MCDP85MCDP81MCDP80,MCDP82,MCDP84,MCDP85MCDP81MCDP80,MCDP82,MCDP84,MCDP85MCDP83

MCDP83MCDP81,MCDP82

MCDP81

MCDP83

UJJ

UJJ

ULUL

BK

K

B

HighHigh

HighHigh

A(r=0.788A(r=0.788

E(45%)E(45%)

GH

BC

C

B*See explanation of comments.

Codes Used in Comments Column

A - Due to low correlation coefficient (value inparentheses), indicating that the reported results maynot fall within the linear range of the calibrationcurve.

B - One or more of the blanks associated with these samplesgave a positive response greater than the IDL (instrumentdetection limit). The reported results may be biasedhigh.

C - Due to interference from Iron possibility of falsepositive exists for elements which are not present in theEPA provided solution and are present in the samples.Analytes with concentrations that approximate thoselevels found in the ICS solution were biased high.

D - Due to negative results observed for elements that arenot present in the EPA ICS, possibility of false negativeexists for those elements. The affected sample results<IDL are qualified biased low.

E - Due to low spike recovery (% recovery in parentheses ),indicating a possible matrix interference, the reportedresults may be biased low. Detection limits may behigher than reported.

F - Based on high variability in laboratory duplicateanalysis the indicated quantitation may be less precisethan indicated for the method employed.

RR30273I


G - Due to low post digestion spike recoveries, indicatingthat quantitation is biased low, and that detection limitmay be higher than reported.

H - Due to low correlation coefficient for MSA, indicatingthat results is not within the linear range of thecalibration curve.

Table 2Summary of Sample Dilution

Analyte Samples Affected ResultantQuantitation Limit(ug/L)

Se MCDP83 1.1 ug/L

AR3G2732

AttacIiMnt 1Data Qualifier Code*

IH302733




U - Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) Confirmed identification.


R = Unreliable results. Analyte may or may not bepresent in the sample. Supporting data necessaryto confirm result.

CODES RELATED TO QUANTITATION(can be used for both positive results and sample quantitationlimits):

J = Analyte present. Reported value may not beaccurate or precise.

K = Analyte present. Reported value may be biasedhigh. Actual value is expected to be lower.


UJ = Not detected, quantitation limit may beinaccurate or imprecise.

UL = Not detected, quantitation limit is probablyhigher.

OTHER CODES

Q = No analytical result.

AR3G273**

Attachaant 2Data Suaaary Pora*

HR302735

134) -HO *M

£2It

m • eCU -H

muH

z

4J *>

a 3« -o

e a

ao

2

a- ¥ ^ o <» t?\ no

* n

to

ee

CO 2

e S* o S

_ u. at U

Is «*IU

I/I —

K

vS

\

•

^ ». -*j .-. <a?

Cadki

u ¥

V.

V

Vo

1

PTN

•h

J*32

a «<|*e «a

I4>

58

' S3

CDroCO

••

rjto

r,e e3 I

ss

1

=

SSK

1

=

=

=

___ — __

Sanplt No.

Dilution Factor

Location

CROL

ANALYTE

(.1

S

\ Aluminum

\

§

\ Antimony

j

S

5.

[ *Ara*nic

\

o

§um

1

Ofl

N

\ Beryllium

\

"*

S1u

in

£

\ Calcium

\

in

«a

V

|

*Chro«iu» |

o

ioin

<o

*

J!C

£

%

§

<3

iX

1«

•"

§

i

cc

«..

!in

|

N«rcury

1

(Vo

*

r<

•

Ufo>r

[ Potass JI

M |

in

§8S

in

*.

iV)

o

CQ

5

f

I

Io

§1s

«C5

^

|(M

Orw

U

o

7

Appendix ALaboratory Result* of all Target Analytaa

IR302738

I. - i:::!"1'-! 5AMI--L1: WC I.INCRCAHK. •-•;-'../. s:: •.. DAT.. - .

I MCDP60:..,.b ;-.!,:•., n.? : CEI^c . Con t r *..:: t n . . :.„.....„.„_

L.-b C. .,<::;••?•: C El MIC Case No,, 3 1.55 V. .. SAS Wo . i SDG No., s MCDP SO

'i.,iti'i. x >' .*._•. LI... uater,, ;; SOIL !_*_ d;,<mp.l .!.'£> 5 00?5'?--0'L3

-sv-r.-j. • io /.(i.~d ,' :; LOW ;>.., i.e Ke'.: ive...l 3 .1. i'l-'l VL.-'VI.)

"; '.ol ids :: 89 ,,3

Concentration Units (ug/L or rnq/''Kq dry weight): MG/KG,;

ICAS Wo,.i;

:7a29-?o-S! 7440-36-0! 7440-38-2! 7440-39--3! 7440-41-7! 7440-43-9! 7440-70-2! 7440-47-3; 7440-48-4! 7 40- 30-3! 7439-89-6! 7-139-92-117439-9 3-4!7 39-96-5i 7439-97-6; 7440-02-0: 7 40-09-717792-49-2! 7440-22-4! 7440-23-5I 7440-23-0; 7440-62-2! 7440-66-6|i

ii

; An^lytei. <....,...„ ...„_._......_.! Aluminum! An timon/! Arsenic,' Bar ium! Beryl Hum! Cadmium! Calcium! Chromium! Cobalt! Cop per! Iron! Lead! Raqnesium; Manganese! Mercury! Nickel! Pot as si urn! Se 1 en i urn[Silver! Sod ium! Tha 11 ium! Van ad iumIZinc! Cyanide•

itConcen t rat ion ! C

it7460 . 00 1

4.80IU7,10!14.60IB0.89!0 . 53 1 U

490.00,'B3 . 90 :5 . 50 ! 314.40!

1 5300 .-00 !9 . 40 !

L 94O.OO:476.00!0 . 09 ! U13.20!569 . 00 ! B0.18IU0.71IU

4 58. 00 IB0.18IU10.00!34 . 70 !

;i

i<Q ; n

11

!PN !PW |F

- IPIP

N* I F'IPIP,'PIPIF

N ; FIP!P! CVIPIP

NW ! FIPIPIFIPIPINR

Color Before s BROWN Clarity Before:: Texture: COARSE

Color Afters YELLOW Clarity Afters Artifacts:

Commen ts:;

FORM I - IN 7/88

'J. 3 , EPA - CLP

l r.'.'i-'.?. 'INORGANIC <".HALf":>[3 DATA '.MEET

MCDF81N.-.IHVJ: CElMliC Con traces

L-?h Codex CEIMC Case No.: 15536 SAS No. x SD'j No,: MCDP80

M.AL'-1;. * ". »o LI/-M.A I'.er .< •; JJOI.'L Lab Sam,.4'.- I": 00 ""••'"'-0,2:3

'....-.-el. :.lo'*-'''ii-::" :!;••: LOW 0 * !>•/ K1,.;.?.; 3 i-e'J :; I..:,' !,2/?v

r,; Sol. i...:!•»:: 36.1

Concentration Units (ug/L or mg/Kg dry weignt).; MC"'KG

;ICAS No.i

! 7429-90-5! 7440-36-0! 7440-33-2! 7440-39-3; 7440-4 1-7! 7440-43-9! 7440-70-2! 7440-47-3; 7440-48-417440- 50-8I 7439-89-6! 7439-92-117439-95-4! 7439-96-3! 7439-97-6! 7-440-02-01 7440-09-7! 7782-49-2! 7440-22-4! 7440-23-5; 7440-28-0! 7440-62-2I 7440-66-6t

i1 —__.__.— — -

i

! Analytei

, l _

I Aluminum! An tiiiionyI Arsen i c:[Barium', Beryllium! CadmiumICalcium! ChromiumICoba.ltICopper! I ron!Lead! Magnesium! Manganese! MercuryINicksl[Potassium! Selenium1 Silver1 Sod iumIT hall ium1 Van ad iumIZincI CyanideI

1t

Concentration |Cl

8200.0016 . oo ; u

78 „ 90 I74.401 "1.10!0.67IU

16400.00!82.60! --8 . 00 ! B23,90!

41100,00!142.00!2940 . 00 !699 . 00 !0,84!25,00!659,00!B

0 . 43 I B0.89IU

1260.00!0 . 32 1 B10 .70 IB

T>Qf) An '.C-OV . '-./_' ;

111__.._ __ ..... __ ._ ._ 1

;Q in

i

:PN |pN ! F

|P! P

H* ; pIPIPIP;?;P

N ; F' 01 ';Pi CV;pIP

N |FIPIPIFIPIP' KIPi iTPv

1._.._._ I _

Color Be-fore s GREY Clarity Before: Texture: FINE

Color After 3 YELLOW Clarity Afters Artifacts a

CommentS3

FORM 1 - IN -).OC

* : CELVLC . .. .. . ...„..„.„.____..„._.....

•::•••; de;: CEPiJC Case No.. -. '•..•?'~:-Z6 • SAS No,:;. . __ SDG M.o , •: •-•IC

M.'i-.ri. - ( so !..!..•-.:•.'>:?:••.<•: SOIL _. !._ ,*,'.> 6ampi* .[!)•; O-.. ->:j ; -O.

' 'T?>..••••!. i.: lom. 'M. 'i . ; LOW .. . .Date ;:\ece i.r.'vl:: I. ?/!. : -'';>'.

".. Sol. L<:!:•>;: O4..7

C i:.- n c e n 11- a t j. o n U n i t s ( u g / L o r m g / K g dry w e i g h t > - M 0 / K G

1I

ICAS No.i1

[7429 -90- 3[7440-36-0; 7440-38-2! 7440-39-3:7-*40-41-~1! 7440-43-9[ 7440-70-217440-47-3; 7440-48-4! 7440-50-8! 7439-89-617439-92-1! 7439-9 5-4! 7439-96- 5: 7439-97-6! 7440-02-0; 7440-09-7! 7782-49-2[ 7440-22-4[7440-23-5[ 7440-28-0! 7440-62-2I 7440-66-6|!

ri

! Analytef;

! Aluminum1 Antimony[Arsenic1 Bar ium[Beryl li'.'.,n[ Cadmium1 Cal<:: ium; Chromium! Co bait! Copper! Ironi Lead! Magnesium! Manganese1 Mercury[Nickel[ Potassium! Selenium1 SilverI Sod ium[ThalliumI Vanadium1 ~7 -i r* t-i £. i n (.! Cyanide

. i

iiCon centra tion [ C

il

13 100, CO!4 ,. 80 [ U3.70!

90.9011.1') 10 „ 53 [ U

1660,00!i 5 . 50 !9 ,. 00 [14,30!

20300 ,. 00 !1 1 . 90 !

2490.001661, .00!0 .11! U18 ,,70!

988.0010 ,. 20 ! U0 . 70 ! U

614.001B0 . 20 ! U13, .30!,; —,' ".T A ''._• .' ,1 •._• \f ;

11

....... ..... ___ ____ ........... '

I

Q ! M,

iPhi ! pN |F

;PIP

N* ; pIPIP•IP;PIP

N ! FIPIP! CVIP;P

NW 1 1~IPIPIFIP" i_.f !

[ NKii „ t

Color Before: BROWN Clarity Before;; Textures FINE

Color Afters YELLOW Clarity After:; Artifacts;:

Commen ts;:

FORM I - IN 7/8S

1 1

1 EPA SAMPLE NOINORGANIC .-iNALfSlL. OAT- SHEET

MCDP83Lab Name: CEIlirc Contract::

L-ib Code a CEIM'L'C Case No.? 15536 SAS No,.:: SDG No. : MCDP80

Ma !• r •. < (uioi !./>*'.. t .r ;. :: w,:. TEF L-^b Cample CDs 0'"/r5'?-04S

L- '-e !, t Low •''lived .1 •! LOW - 0-* L •.-.-> Rec-.:.M.'-ea: 1.2- J.2/'•''.'

",; O. l i.d<_;; 0..0

Concentration Units (ug/L or ing/Kg dry weight;: UG/L

CAS No,.

7429-90-5""7440-36-074-3O--33--27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-5O-87439-39-67439-92-1'7439-95-47439-96-57439-97-67440-02-07440-09-7 •7782-49-2744O-22-4744O-23-57440-28-07440-62-27440-66-6

[! Analyte|I Aluminum1 An timony1 Arsen ic! BariumI .Eery 11 ium! Cadmium1 Calcium! Chromium[Cobalt[ Copper1 I ron[ Lead[ MagnesiumI ManganeseI Mercury[Nickel[ Potassium[ Selenium[Silver[Sodium1 ThalliumI VanadiumIZincI Cyanidei

i ii iC o n c e n t. r a t i o n | C ! Q__ _ _ ___ __ ! _ ;

86"."ooi"i":27 „ OO ! U !2.00IU! W2 „ 00 ! U [4 , 00 ! B !3 ,. 00 ! i.J [

226 . 00 [ B [4,00!3|6 , 00 : U !5 . 00 1 B I

214,00! [i , 50 ; B :

136, 00 ill!3 „ 00 [ B [0.20IUI

12.0O |H I273,00|U[

1.10IUI •+•4 . 00 I B !

483 . 00 I B !i . oo ; u i3 . 00 I U 15 „ 00 [ B [

1 t1 lt l

|

illt1

: PIPIFIPIPIPIPIPIPIPi I-.; 1IFIP! P:cvIPIPIF! PIPIFIP! P[ NRtt 1

Co i o r Befo re: f OLORLESS Clarity Befo re: CLEAR Te x ture 5

Color After: COLORLESS Clarity After: CLEAR Artifacts-

Commentss

FORM I - IN 7/88

AR3027I+2

|J ,S, EPA - CLF

1INORGANIC ANALYSIS OA T,-

Lab Name"! CE1M1C Contract?

L.-tb Cod.-2.3 CEIMIC Case No.: 15536 3A3 No,- SDG No . :

!•!-:. t:-•!.:< (soi L/ivate.-)..: SOIL Lab S mp.!..? ED;; 0095>:.: -ji-i-i

(lo^-'med ;• s LOUi Da to Received: 12/.L3.- ">.:•

Lids: . . 78.5

Concentration Units (ug/L or mg/Kg dry weight.':: MG/KG,1

ICAS No.i(

1 7429-90-51 7440-36-0! 7440-38-21 7440-39-317440-41-71 7440-43-9! 7440-70-21 7440-47-31 7440-48-41 7440-50-81 7439-89-6[7439-92-117439-95-417439-96-5[ 7439-97-6! 7440-02-0I 7440-09-717782-49-2! 7440-22-41 7440-23-5[ 7440-28-01 7440-62-21 7440-46-6

I

i1! Analyteti

I Aluminum1 Antimony! ArsenicIBarium{Beryllium[Cadmium1 Calcium1 Chromium[CobaltICopper1 1 ron1 Lead[ Magnesium! Manganese1 Mercury[Nic'kel{Potassium[Selenium[Silver1 Sod ium1 Tha ilium1 VanadiumIZincI Cyanidei

•iCon cen t rat ion ! C

ii

7760 . DO 15.90IU9.101

. 44.00!1.1010.65IU

1270.00110.0016 . 30 1 B36.10!

15000.0011 5 . 80 !

1850.001475.001

0.11IU14.40!

409. 00 [B0 u 23 1 U0.87IU

4 53. 00 |B0.23IU10 .20 IBISA 1 Ci 'O\J a .1 \f i

1!1

1

Q I Mi_._. _ .'._._IP

N IPNS I F

IP11='

N* I PIPIPIPIPIP

N ! FIPIP

• 1 CVIPIP

NW 1 FIPIPIFIP1 Pi *INRi_ i

Color Before: BROWN Clarity Before: Texture. MEDIUM

Color After: YELLOW Clarity After: Artifacts:

Comments;:

FORM 1 - IN ' 7/88

HR'3027l*3

[NGRGANIC A

LI . S . EPA - CLF

.'.;on tr AC t;;

Case No.s .1. 55. .k> SAS No - •; ;/' G No,.1: !T'CDP.?0

L--b ':?:'. u l

L .M:- H- ..a: CELMIC.

'..,..!::. ..:.-f.-?s CE1M.C

M.i l-.i- ;. -• • so i. i/.*i .'. ter .' •:

Level <, low/med ,';: LOW D :• te Rec-^ivcid •; j/.;/:i. ;.>, ?o

".; '3o LI.JS;: 77,,6

Concentration Units (ug/L or nig/Kg dry weight): MO, KG

1

: c,-s NO .!: 7429-90- 517440-36-0! 7440-38-2[ 7440-39-317440-4 1-71 7440-43-9! 7440-70-2; 7440-47-3! 7440-48-417440- 50-8. 743V-.89-6; 743 ?~92-li 7439-95-4.! 7439-96-51 7439-97-6! 7440-02-0; 74*0-09-7! 7782-49-2! 7*40-22-4! 7440-23-5I 7440-28-0! 7440-62-2! 7440-66-6: __ __i

;[ Analyte•• _._..., ...._ .....! Aluminum! Antimony[Arsenic! Barium! Beryllium! Cad en ium! Calcium! Chromium[Cobalt! Copper! I ron! Lead! Magnesium! Manganese1 Mercury! Nickel! Potassium1 Selenium1 Silver[SodiumI Thallium1 Van ad iumIZincI Cyanide1

;Concentration ! C

;8230 .,00:

•a . 90 ! U7 , 50 !

47 ..CO!0 .. 73 ! 02 . 40 [

1490,00!10.1017 . 30 ! B38 . 90 [

1-7500.001.1. -.-} .10!

1890,00! ~491,001

0.111 U15 ,40!

487, 00 [B0 . 22 [ U0 , 73 I U

494 ,. 00 ! B0 . 2.2 I U1 1 . 30 I55.601

;•

i.;> ; Mi___„__.__

N [ PN : F- IP

IPN* ; F1

IPIPI p:PIPN : F! PIP[CVIPI p

NW i FIPIPIFIPIP1 kipt iMr\i

Color Be-fore;: BROWN Clarity Bef ores Textures MEDIUM

Color After;: YELLOW Clarity After;: __ Artifacts:

Commentss

FORM I - IN 7/83

Appendix BOPO Report

W3027U5

INOtCAMC MCIONAL DATA ASSESSMENT

LABORATORY

*_MCDP&-t _

DPC

O • Data had BO prob!«m/or qualified du* to minor problems.M • Din qualified dw« to major problem*Z • Data voacceptablt.X • Probl«ou, o«t do oot aSf*ct laa.

ITTM*

AREAS OF CONCERM

•C' AA H| CYANIDEI. HOLDING TIMES & _Q_ "^2. CALIBRATIONS3. ILANKS O

4. ICS

S. LCS /> <g __£i. DUPLICATE ANALY38 0 & __^_7. MATRIXSPDCI O G __O

t. MSA9. SERIAL DILUTION CP

10. SAMPLE VERIFICATION O _£_

11. OTHER QC ^ _£_

12. OVERALL ASSESSME.NTT ^ __0

NOTABLE PERFORMANCE:.

Attachment cSupport Documentation

AR3027i.7

Pi I AH !<•-.

L*o N«'.m'." CEI'MIC - _ - Contract;:

-. -,!•;. Co, !../.; C EIM T. C .. C *'.:_,* No,.:: 1'7.336 3f-V. No.- 3 DO No. •;

P !-•••?!::• :\ra t :.on Blank Matrix ( soii/wa ter) s SOIL

i-'-'eDai'v:'. U.on Blank Concentration Units (ug/L or mg/kg)s MG/KG

t

1

1

1

I Anal/' t:s!, Alum:i.nui;i! An timony! Arseni c! Bar i.um! 3ery l.liu.ri! 3 ad mi urn' Ca.L c'i i i i »! ChromiumI Cabal t! Co i- per! Iron! Lead! M acmes.!, urn! Man q an ess! Mercury! Nickel! Potassium! Selen ium! Silver! Sodium! Thallium! Vanadium! Z :;. n c! Cyanidet

1

Initial("a 1 i b .Blank(uq/L) C

—— — — j^ W " '1 'i • ''-*

27.0 !U2 . o : u2.0: u

.-""""4 ,012.__3.~JD ! B100.0 ! U3.0!U6 ,. 0 ! U3.0 IB.

^-VTO I U1.0! U

136.0 I U1 . 0 1 U0.2! UIjGSTET

273.JLLLLX ~T» ' f-4.0JU98.0!U

>j-l ._QJJjc*3.0

._L_ **

3 . 0 IB!

Con t i n u i n q Ca 1 i b r a t i onBlank (ug/L j

1 C 2 ' C 3 C

y 34 .0 Up? .J30 ;. 0 ! B t 67 „ 0 [ B 4-27-0!U; 27,OJ.U•-2.3.1BT . -2.6.JB

~"-3,a,!B! 2.0!U5.0[ ! 5.013.0 |U! " 'r?T!B

10O.OIUI lvX>»O|U5 „ 0 ! B ! 3 „ 0 ! U6 . 0 I U ! 6 .JLLU.3 . Q 1 B I -2"» 0 JBj"9.0 lui VroTu1 . 0 1 U 1 !

136.OIU! 136.0 !U1 . O 1 U I 1 „ 0 ! U0 . 2 1 U ! 0 ,. 2 I U9 . 0 I U ! 9 „ 0 ! U

*L / O • O t U i .si / O » *w> i U

h 1 . 0 ! U ! !4 . 0 1 U 1 4.0! U98 . 0 1 U ! 98 . 0 1 U1 . O I U 1 1 . 0 I U3 . 0 I U I 3,0! U2 . 0 I U ! 2 ,. 0 ! U

I ! !

27 . 0 | U__ -.* H 1 T%

•> •.i-lllbl'- 1 &

Z ,. 1B1

3 . 0 ! U1OO._O|U

6 ,. 0 ! U- <STO ! B_.

9.01 U1

136..0IU1 . 0 1 U0 . 2 I U

""i 3 „ o ' 273.OIU

tIt

98 . 0 I Ui 'xm.

< * t i"> ' n2.0: u

ti

1 1 1 1 i i i1 —— .,...«.—— ,«,.......__.«-. ' ——....„-.... .„.-....„_.„..,. * .„. i ....._..m™.... __ „.„.„ 1 „.. l ™ __-..„„ __ ,——._„.«.-.. '• ™ 1 «.._....„„..».....__...._.... ' „«

[

i

Prep*- !ration !eiank G:

- •- !T 19. 300 IB I.

5. 4001 U!0.40O!_U!

.— r* 'T / /" ' '£/ ''_/ • '"T i_ **..* i X? r

b 3OO ! B !0 . 600 I U !

20 , ooo ; u ;TT20O ! B-f1 . 20O ! U I

a TT^OO ' B ,'2.40O_Uli0 . 200"! U !

•'"7 OAA Ml'il/ a A^W i U i

0 . 200 ! U 10.10OIU!1.800IU!

-'4_»_.£Qiil U Iv2l.45 -UB-!-Q. . 800JJJ|

^23 . 2jyj ! &-! •2.00. !U !

CO .600 IB!,0 . 4OO I U I

I 1i ri i

..„.....— ......- — .-.-*_— l ™. '

|

M

kPF'F1"'PIII'

!-'rii"'pF'FPPCVPPFr-1c*iFPPNP: !

18> ^

FORM III - IN 7/88

U.S. E'"'.-' - C-...:;-

•JBLANKS

Lab Name: CEIM1C Con i;r_._":;:

Lab Code: CEIM1C L^se No,. 3 15536 3,-tS Nc, - 3.0G Nc „ :; M(.:OP30

'-•repara'-.Ion Blank Ma.tr.L.< ( so.i. I/water J s WA V'FP.

Preparation Blank Concentration Units (uq/L or mu,v !'.g ) x UG/L

Analyte

AluminumAntimonyrsenic<sen i criumrv 11 :irvIlium

I CadmiumI CalciumI ChromiumiCobaltI CopperI Iron; LeadI MagnesiumI Manganesei Mercury!Nickel! PotassiumI SeleniumISilverI SodiumI ThalliumI VanadiumIZinc!Cyanide

Initial ICalib. I Continuing CalibrationBlank I Blank (ug/L)(uq/L) CI 1 C 2 C..————«rn7.:.:....j~-!..^ 110..iUja:

27.0IUI 27.0IUI 27.0IU! 27.0i i 2.0IU: %*.o.:y: 2.0

3,,0!U! ^iUa-J-B-h 3,0;tJ!loo.oiu: loo.oiu; loo.oiui

.ri,,o.;.j&-i. szJoJ : r7.oi.ai6 . 0 ! U ! 6 „ 0 1 U I 6 ,. 0 1 U 1

'3.0 IF; . '3 0 :S!? „ 0 ! U ! 9 . 0 1 U 1 9 . 0 ! U !1 . 0 1 U 1 1 . 0 I U 1 1 .. 0 1 U I

.L36.0IUI 136.0 !U Ii.o lui0.2IU!

9.0! U| 9.0 !U!273. o i

4.0JUI 4.0IUI 4.0IUI 4.0I I 98.01U! I Ii i . 1,0:u: 1.04UI i.o

3.0IUI 3.0JJJI2.0IUI

uu

Prepa-rationBlank C!|M

IP"•2Z*JlUB I IP2.0 ! U ! ! F

•mag . CI.HB : : P1-..OJ.U 1 1 F

v^2 „ 0 i B ! |Pi i i Nr'-

ftR3021U919

FORM III - IN 7/88

L ,-•- ham-?1: C Eli'! 1C - - " Con'/.i-Act:;

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31

Sita Mata.Sat* Jtevitv worksheets Reference"

fttcxov z ftiTxtv or x»o»exvxeCCKTJUC-r lAftCHATOlY DATA >ACXA4t

Tfc.e ."«riccr:t. :*rcri.:r/ r.asei . -'^ '- - - - data package r*.«:v«d«t Pegior. I has seen rev.eved and the^quality assurance and perftrsance

c**« HO. ^~- SAS HO.$OC. Ho. ''•'-?£?-' Matrix *Zr.<(. x-i.--^rshiepinq Cate(s) / .Mo. of Saaples <•-/ Date Hec'd by Lab

Traffic Report Hos:Trip Blank Ho.:Equipaent Blank Ho.:Field Dup Mos:

SCW Ho. y r«<?uir«« that specific analytical work b« dona and thatassociated reports fe« provided by the laboratory to tha Rations, EMSL-I.V. and SMO. T>.a <;anaral critaria usad to datarair.* tha parforsanct wara';as«d on an txaair.ation of:

•Data Coaplacar.ass -Field Duplicates-Holding Ti=es -lab Control Saapla Results-Calibrations -Furnace AA Results-Bl»n)c$ -ICP Serial Dilution Results-ICP Interference Check Results -Detection Li»it Results-Matrix SpiXe Recoveries -Sa»ple Cuantitation-Laboratory duplicates

eve rail Coaaents:

Definitions and Qualifiers:

J - Approxiaata data dua to quality control critaria.R - Reject data dua to quality control critaria.K -

Reviewer: 1 ' / t - ^ r ^ r « ' Date:

SR302760


X. DATA CCNPllTtVtiS

CAT?

ftR30276l

REGION XData Review worksheets

XZ. HOLDXHO TXMIS Complete table for all saaples and circle theanalysis date for saaples not within criteria.

' i H M C ' , CYANIDE ! OTHERS pM———ACTION——SX-PLE ; :ATE CATE CATE J DATE •s• r •> xui've'c IW»'YS*S AN A * i S * S '

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ACTION:1. If holding times ara exceeded all positive results are

estimated (J) and non-detects are estimated (UJ) .

2. If holding times are grossly exceeded, the reviewer may .determine that non-detects are unusable (R) .

AR302762

tata Jtev.ew worksheets

XXX A. XXSTUCXZVT CALIIJUTIO» (Section 1)

1. Recovery Criterial:st v*.e §-«:y.ts -.htc.* d:d rot seet the percent recovery :*R) cr:ter:tf:r :.-.;t.i. or rir.ti.-.w;r.« Calibration.

:ATE rr.'/cc"? ANALYTS n ACT;CN SX^PLSS *ryg~g;

ACTICHS

If any analyte dees not seat the %R criteria follcv tha actions statedbelov:For Positive Results:

AR302763

Cata Review Worksheets

xxx B. ivmcxxy? CALUJUTIO* (Section 2}


A. :ii t..e l»bcr«tsry <-*« t.-.t prc?er .-ur.ser ofstandards for calibration as described in the ,-SOW? vt$ cr Nc

B. were calibrations performed at tha beginning of 'each analysis? Yes or No

C. Were calibration standards analyzed at tha be-ginning of staple analysis and at a ainiaua fre-quency of ten percent or every tvo hours during ^~ -analysis, whichever is acre frequent? Yes or No

^___

0. were the correlation coefficients for tha call-bration curves for AA, Hg, and Of & 0.99S? Yes oc/Ho~

If

theany

e. "as a s^anoara at *XVKanalyses?

No,

The data may be affected.severity of the effect andacticr.s below and list the

01. anaiyzeo i or ei

»

Use professionalqualify tha datasaaples affected.

A tCF /Yes or No

judgesent to deterrainliaccordingly. Siscuss

"vv t'Rf.i -:."->/-•/ / -n. •''»•.• t * _ ,\ • -.--x -,'.<_• TV*"/ <-,-»:.-,-4--" E*r-_hLf* &<.-»* A»*.'y£7: ?#*</;«:& te v/J-c./•>

/ / , •£«' ^ // J '/ /V ^•>1<- jX,,/ ^^ / u c ^ -£&;£,„.

. y

AR302765

Cats Rev;aw Worksheet

XT A. BLAJfl JUALYIXJ KISOITS (Sections l-J)

list the blank contaeinat ion in Sections 1(2 be lew. A separatakeet *Me-jli t« vs«d for »c;l and water blanks.

2. Equiprent/Trip Blanks

3. Frequency Requireaents

A. Was a preparation blank analyzed for each matrix, ^^for every 20 saaples and for each digestionbatch? . Yes or No

B. was a calibration blank run every 10 saaples orevery 2 hours whichever ii more frequent? Yes 'or Ho

If No,

The data cay be affected. Use professional judgement to determinetha severity of the effect and qualify tha data accordingly. Discuss,any actions below, and list tha saaples affected. AR302766

•2- Equipssant/Trip Blanks

£ EC'.T? gLf

.-;- n"'-' ?

-1

AB302767

Review Worksheet

IV A. 8LXHK ANALYSIS RESOLTi (Sections 1-3}

List the blar.x contamination in Sections 1 i 2 fcelcw iworxsheac should be used for soil ar.d water blanXs. A s*P«rate

1. Laboratory SUr.xs MATRIX- *- -'*

// /?£* 6VC-

Review Workshttt

XV A. BUUfX VfALYIII RISOlTf (Sections 1-3}

List tha blar.x csr.taaination in Sections 1(2 below. A separitt•worksheet should be used for soil and vater blanks.

* ' /1. Uborttcry 5PAT* rc;/..;t PREP JL ANALYT?

•- p '"''"•

<

<. L

;Vc

7 -'O.

A'/ ' '

_ ^ /; '*-

AR3027.69


IV A. ILAJfX AXALYIII IISOLII (Sections 1-3)

List tha blar.x cs.-.taaination in Sections l i 2 ctlow. i «.„,„_,..werkshaat should be used for soil and vater blanks. ««P*rita

1. Uborater/ 3Unxs MATRIX-j^ '^

11 ANALYT^

:.'?, '']

AR302770

(pata Review Worksheet

IV A. BLANK ANALYSIS RESULTS (Sections 1-3)

List the blank contamination in Sections 1.2 below. Aworksheet sncuid be used for soil and vater blanks.

1. Lxabora.cry 31anxs MATRIX ;

£AIS IC3/CC3* P3EP 5L ANALYTS

•I it

AR30277I

Cats Review worksheets

XV B. BLANK AXAUflt AXSOLTf (Section 4)

4. Blank Actions «

Tne Act:s.-. l«vt.s for any analyte is eq-jal :z five tires the .- --•*•cc-ce-tratier :f t.-.et tl«r«.ifs csntasirat .c.-. ..-. «hy fclan*. rr.til--.z-:level for sarr.ts which hav« been concentrated or diluted shauld* "-a•;.;t;pl;ed fcy :.'.e csncentrsticn/dilutien factsr. Ho positive saspTeresult should te reported unless the concentration of the analyte :n thesanple exceeds the Action Lave! (AL) . Specific actions are as fellow's:

1. when the concentration is greater than the IDL. but less than theAction Level, report the saapla concentration detected with a U.

2. When the saaple concentration is greater than tha Action Level,report the saaple concentration unqualified.

KAT* X X:

CLEMENT MAX. CCNC./ AL/ ELEMENT MAX. COMC./UH1TS L'NlT-f UNITS

At /ft % £*» «$6 // //17

NOTE: Blanks .analyzed during a soil casa oust ba converted -.to og/kg inorder to compare thea with tha saapla results.

Cone, in ug/L X Volume diluted to f200mH._. X Ik, X lOOOga X Ipg • mg/XgWeight digested (Igraa ) lOOOal Ikg lOOOug

Multiplying this result by S to arrive at the action level gives a finalresult in rag/kg which can then be compared to sample results.

SR302772

..£<3ION IData Review Worksheets

IV B. BLANK ANALYSIS RESULTS (Section 4)

.. •!.„* Actions -

The Action Levels for any analyte is equal to five times the highestconcentration of that element's contamination in any blank. The actionlevel for samples which have been concentrated or diluted should wemultiplied by the concentration/dilution factor. No positive sampleresult should be reported unless the concentration of the analyte in thesample exceeds the Action Level (AL) . Specific actions are as follows:

1. When the concentration is greater than the IDL, but less than theAction Level, report the sample concentration detected with a u/

2. When the sample concentration is greater than the Action Level,report the sample concentration unqualified.

MATRIX: - MATRIX:

SLEMENT MAX. CONC./ AL/ ELEMENT MAX. CONC./ AL/UNITS UNITS UNITS UNITS

MOTE: Blanks analyzed during a soil case must be converted to mg/kg inorder to compare them with tha sample results.

Cone, in ug/L X Volume diluted to (200ml) X 1LL X IQOOgm, X lag » mg/kgWeight digested (Igram ) 1000ml 1kg lOOOug

Multiplying this result by 5 to arrive at the action level gives a finalresult in mg/kg which can then be compared to sample results.

AR302773


IV B. BLANK ANALYSIS RESULTS (Section 4)

4. Blank Actions —

The Action Levels for any "analyte is equal to five times the highestconcentration of that element's contamination in any blank. The actionlevel for samples which have been concentrated or diluted should bemultiplied by the concentration/dilution factor. No positive sampleresult should be reported unless the concentration of the analyte in thesample exceeds the Action Level (AL). Specific actions are as follows:

1. when the concentration is greater than the IDL, but less than theAction Level, report the sample concentration detected with a U.

2. When the sample concentration is greater than the Action Level,report the sample concentration unqualified.

MATRIX; s*? ^ MATRIX:__

ELEMENT MAX. CONC./ AL/ ELEMENT MAX. CONC./UNITS UNITS UNITS UNITS,

f

3*

MOTE: Blanks analyzed during a soil case must be converted to mg/kg inorder to compare them with tha sample results.

Cone, in ug/L X Volume diluted to (200ml) X jj^ X lOOQqTq X lag » mg/kgWeight digested (igram ) 1000ml 1kg lOOOug

Multiplying this result by 5 to arrive at the action level gives a finalresult in mg/kg which can then be comp'ared to sample results.

AR30277U

Cats Review Worksheets

V A. XC» imW-UMCI CUCCt SAXFLt (Sections 1 4 2)

1. Recovery Criteria•_;st any «:«-t-ts in the ICS A» solution -.h;ch did not seet the enter- 1for \*.

ATC C'-atCMT %Jl ACTICJI SAflPLCS Afr£CT£3

-, J&eri&ri*ACTIONS:If an elexent does not seat the !R criteria , follow the actions statedbelow:

PERCENT RECOVERY<50% 50-79% >120%


Were Interference QC samples run at tha beginning andend of each saaple analysis run or a ainiaua of twiceper I hour working shift, whichever is more frequent? / Yes ir No

If no,Tha data aay ba affected!. Use professional judgement to determine

tha severity of tha effect and qualify tha data accordingly. Discussany actions below and list the saaples affected).

ftR302775

Cata Review Worksheets 4 ~L

XCF XirrcAFcunct c«ci SAMPL* (section j)

;r;?SulVB y..tlPv.v.V,.<utt«*<' iB «• '<* *CCNC. cf IN

TH£ ICS

Estimate the concentration produced by tha interfering *i..A.» taffected saaples. See guidelines tlr exa.plea Li.i *X™ ln *Uaffected by interferences below: «x*»pies. List tha saaples

.affected by interferences below:

SX1PLC ELEMENT SA«PLX SAMPLX XNTEftfEftCM*AFFECTED AFFECTED CCNC. LJE IJITERFERUrr

(«o/U AL CA* Ft MG

ACTICNS:

1. In general, the saaple data can ba accepted without qualification ifthe saaple concentrations of Al, Ca, Fa, and Kg ara less than-f-3**their respective levels in the ICS solution.

Give explanations for any actions taken belowAEM2U6

:a. Review Worksheets

V 3. 1C? INTERTERENCZ CHZCX SAMPLE 'Section 3) —

I. .-.epcrt the rcr.centratisn c: ..-.y .iements ie.ectadsoiuticr. > Ixl"l that snouli r.ct re present.

k

Data Review Worksheets -

* •. let XVTCA/tUVeS CltCI UM»Lt (Section 3)

3. »eport the concentration of any eleaents detected in tie ?<?«solwtion > ;»IOL that should not be present. XCS

cf?!c- J7?;;1' C-NC- «' iNTtun+ •* Zo • »

Estimate tha concentration produced by tha

(ug/t) AL CA n m

ACTICNS:

1. In general, the *«»ple data can ba accepted without qualification iftha saapla concentrations of Al, Ca, Fa, and Mg ara less than i"thair respectiva levels in tha ICS solution.

Giva explanations for any actions taken below:————————————————________ 5R3Q2778

. .. ca,Review Worksheets

7 B. 1C? INTSRTZRZJICZ CHZCX SAMPLE (Section 3)— >

•epcrt t.*.t :cr.=antraticn of ..-•/ -aieaents ietectsd ir. t.-.« ::? .;solution > :x::i that snould r.:t re present.

CCNC. :F :NTS'?ERS;:TS:N THE ics :N THE :cs

AL CA f£ :^

23

^2779

SAMPLE CLEMENT SAMPLE SAMPLE INTESFERXNTAFFECTED AFFECTED CCNC. CCNC 'twlT

g/L) AL

- ** I _ 4- _ JL__ __ I __ -/£

K

//

AR302780

SA.VPLE ELEMENT SA.MPLE SAMPLE INTERFERED ESTIMATEDAFFECTED AFFECTED CONC. CCNC. INTEAF

_

R

'f

r

ftB30278l

Data Review worksheets

Vt. XATJUl

TR t ' "-is rt> ?> MATRIX: ______?ecsv*ry Criteria

List the percent recoveries for analyses which did not reet t!-.erequirei criteria.S - aaow.it of spike addedSSR • spikes saaple resultSR - sasple result

Analyte SSR SR S %R Action* • i t i

Matrix Spike Actions apply to all saaples of the saaa matrix.

ACTICNS:

1. If the sacele concentration exceeds the spike concentration by afactsr of 4 cr acre, no actisn is taken.

2. If any analyte does not =eet the %R criteria follow tha actionsstated telcw:

PERCENT RECOVERY<30% 30%«74t >12S%

2. Frequency.CriteriaA. was a aatrix spika prepared at the required fre-

quency? /'Yes/br No

B. Was a post digestion spike analyzed for elementsthat did not seet required criteria for aatrixspike recovery? /^Yesyor No



"XX. LAJORATOftT MUKATU

List t.he concentrations of any analyte not seeting the criteria for_-jpl:s*.« precision, For soil duplicates, calculate the CROL ..-> no/kg.s.rc •_*« s.rp.e v«i9ht. velv.se and percent solids data for t.fc.e sa»e:e.r-sicate what criteria v«$ ,se<s tc ev«i_«t« precision by circl..-- eit.-.ethe RPS «r CRDL far each elesant. ;-. -/ '

MATRIX:Ele-ent Sifil Saaale I Duelieatei I»P Ae.i sn

AluminasAn ti sonyArsenicBariuaBerylliuaCadaiueCalciusChromiusCobaltCceeerIronLeadMagr.es i usManganeseMercurySickelPotassiuaSeleniusSilverSod iuaTha Hi —vanadiumZincCyanida

ug/L200to10

200sssooo50-2S100s

50CO" 1S~0.240

5000~ 3

10.SOOO

105020

__ 10.

•oil, Bf/kf

Y" ——— -Hd»9 _]r — L \

———,

_ McDfxgi?*

\

————————————

2.-3763

———————————

.

/viCDPX p

———————————— 1———————————— I

o -r3£*/ 1*-

—————————————————————————————————

i

"——————————————————————

Laboratory Duplicate Actions should ba applied to all other saaples oftha saca aatrix typa.

ACTIONS:

1. Estiaata (J). positive results for elements which have an RPD >20%for waters and >35% for soils. ' - -

2. If sample results ara less than Sx tha CRDL, estimate (J) positiveresults for eleaents whose absolute difference is >CRDL, (2xCRDL forsoils). If both saaples ara non-detected, the RPO is not calculated(NC) .

HR302783


VIXX. FIJIC DCHICATtt

List the concentrations of all analytes in the field duplicate pair-cr scil .up:.rates,'calculate the CRDL in >g/kg using the saaplt weight.C...T. e.-s ?«r:.nt soliis data fcr the saspie. Indicate what :rite- ..as^-.seo^ts^eva.jte th. pr.c.s.c- fey circling either the *?: cr C*5L fcr

KATRIX:__________Element CROy. Saaple f Duplicate*

vat eg

Aluainua__!_200 }Antiaony__! «« 'Arsenic__.,Bariua___iBerylliua^ __S~Cadaiua__ __SCalciua__.5000.Chroaiua ! 10Cobalt ——!"~SO*Coppar___!__25Iron____j_ 100Lead____| __S.Magnesius!. fOOO.Manganese^i_.15Mercury__ _°-2lNickel___!__40.Potass iua_!_5000_Seleniua__:~_,.5"Silver___:__10Sodium___• SOOOTha 11 iua_• ~ 10*Vanad iua_; __50Zinc_____ __20"Cyanida__}__10 }

#/ / /

I/ /' /

Fiald Duplicate Actions should ba applied to all other saaples of thesaaa matrix type.

ACTIONS:1. Estiaata (J) "po'sitiva results for eleaents which have an RPO >30%

for waters and >SO% for soils.2. If sample results ara less than Sx tha CRDL, estimate (J) positive

results and (UJ) nondetected results for eleaents whose absolutedifference is >2xCRDL, (4xCSDL for soils). If both samples ara non-detected, the RPO is not calculated (NC).


XI. LAJOAATC1T COVTROl l*M»Lf —

1. Aa^eous LCS _ /r

List any LCS. recoveries not within the IC-12CI criteria and the samplesaffected.

CLSytNT LE ACTION SAMPLE* A.rr;:rE2

2. SaildLMS—~ O

List any analytes that wera not within tha control windows set by theEPA for the solid LCS saapla. Tha 80-120% critaria is net used toevaluate solid LCS results.

LCS CONC. CONTROL WINDOWS ACTIOM SAMPLES

ACTIONS:Percent Recovery

SOLID LCS <EPA Control Windows >EPA Control Windeva

3. Frequency Criteria

A. Was an LCS analyzed for every matrix, everydigestion batch, and every 20 saaples? ftB^A


I A. FORJiACC ATCNXC AJtOAPTXOJf AXAbYtXf

1. Duplicate Precisionduplicate injections and ore-point analytical spikes were performed fcr all saaples: duplicate infections agreed within

cj.e infections and/or spikes were r.et perfsrreo fcr these»ples/eie3ents:_ _ ____________________ ___

........ Duplicate injections did not agree within • 201 for satsples/eleaents: ________________________ __ _ _________ _

2. Post Digestion Spika Recoveriesspika recoveries aat tha tS-llSt recovery critaria for allsaaples.Spike recoveries did not aeet the 4S-11SI criteria but didnot. require MSA for the following saaples/aleaents;

MSA vas used to quant itate analytical results when con-tractually required.

Torrelation coefficients >0.99S. accept results.^ Correlation coefficients <0.995 for sample

nu=rers/elementsi g£- (M££>P8 r e-q/7.? ) ________

ACTICHS:

Method of Standard Addition (MSA) vas not performed as re-quired fcr saa'ples/elesents: _______________________

1. Estiaata (J) positiva results if duplicata injections ara outsida* 20 % RSD or CV.

2. If the saaple absorbanca is <50I of post digestion spika absoriancatha following actions should ba applied: .

PERCENT RECOVERY

3. Estimate (J) sample results if MSA was required and not performed.

4. Estimate (J) sample results if correlation coefficient was <0.995.AR302786


IX. XXBOCTXTtLT CCOftlO PLASKA <IC?) fCRXAL DIIUT10W ANALYSIS

Serial dilutions weri performed for each aatrix and resultsof the diluted sa»ple analysis agreed within ten percent ofthe or:?ir.al undil-ted analysis.Serial Siiutions were not perforsed for tha following:

Serial Dilutions were performed, but analytical results did———— not agree within 10% for analyta concentrations greater than

SOx tha IDL before dilution.Report all results balow that de not seat tha required laboratorycritaria for 1C? serial dilution analysis.MATRIX:

tUHINT IDt SOrtOt SAKJU D-IAl %0 ACTION

AluminumSariuaBerylliuaCadmiumCalciua _ChromiumCobaltCscper_ " ^IronLeadMagnasiuaManganeseNickalPotassiuaSilver .Sod iuaVanadiuaZinc ...__._

-———— .

————

——— .

""

~~-~

1 ————————

1 ————i •- -

it———————————————————————————————————————————————————————————————

————————— .

————— .————— .—————

Actions apply to all samples of tha same matrix.

1. Estimata (J) positive results if %D >15.

AB302787

Sata Review Worksheets

III. DtTtCTXOB LIMIT RISOIT0

1. Instrjaent detection Limits

:.-.str.:ent Detection Liait results vere present and fs-jnsl :s fct:«$$ t.-.a.t the Contract Sequired Cetectis.-. Lisits.

:*Ls were not includeo in the data pacxage on For: x:.

ISLs were present, but the criteria was not .ret fcrfellowir.? elements:______________________________

2. Reporting Requirements

If No,

w«re saapla results on Fora I reported down to / \tha XDL not the CRDL for all analytes? nres/or HoWere saapla results that were analyzed by XCPfor Sa, Tl, As, or Pb at least Sx XOL. Yes or Now«re sample weights, volumes, and dilution*taken into account when reporting detection /^\liaits en Fora X. Yesxor No

Tha reported results may be inaccurate. Make the necessary changeson the data summary tables and request that the laboratory resubmit thecorrected data.

HR302788

ALM

Cata Ravitv Worksheets^

• XXX. SAMPLE QCAIfTXTATXOV

Saaple results fall within the linear range for ICP and withinthe calibrated range for all other paraseters.

S*=?lt results wtre te:e.-d the l.r.ear r*.r?e/ caliirafs- -»-ceof the instr_.tent fcr the fcllcwing **r?.ts/« .«-«-'.*:

In the space fceicw, please shew a minimum of one saaple calculation

MERCL'RY

CYAN15E

For soil samples, tha following equation may be necessary to convertrav data values (usually reported in ug/L) to actual sample con-centrations (mg/kg):

Tha lab is required to usa 1 graa sample (wet weight) to 200 al.Wet weight concentration « ~~ • —-. . ...

digest cone, in us X 200ml X U__ X 1000cm X Imo » maL 1 ga 1000 al 1kg lOOOug kg

In addition tha sample results are converted to dry weight using thapercent solids calculations:

Wet veiqht cone.. X 100 » final concentration, dry weight (mg/kg)*solids AR302789

Date : June IS, 1991

Subject : Inorganic Data Vaidation, Case 15804, SDG MCEE15

From : Nasser Massoomzaroan, Darline F.Data Reviewer,//K9K»^ Project Manager


Overview

The set of samples for case 15804, SDG MCEE15contained 4 water samples which were analyzed fortotal metals, through the contract LaboratoryProgram Routine Analytical Services. The sampleset included 1 field blanks, and one fieldduplicate pair.


Major Problems

No major problems were identified in this casepackage.

Minor Issues

A low correlation coefficient for a calibrationcurve indicates that results may not: fall withinthe linear range of the curve. The affectedelement is Selenium.

Contamination in the initial and/or continuingcalibration and preparation blanks indicates thatthe qualitative identification of the analytes maybe questionable in those samples with aconcentration less than 5 times the amount presentin the blank. The affected elements are Aluminum,Copper, Lead, Iron, and Zinc.

AR30279Q


Negative concentrations in tha initial and/orcontinuing calibration and preparation blanksindicates that the qualitative identification ofthe analyses aay be questionable in those sampleswith a concentration less lOxCRDL. The affectedelement is Silver.

Duplicate injection for analyte concentrationgreater than the CRDL did not agree within + and -20% RSD, the results may not be reliable due topoor duplicate injection reading. The affectedelement is Lead.

Low post digestion spike recoveries indicate thatthe quantitation is biased low, and that detectionlimit may be higher than reported. The affectedelements are Selenium and Thallium.

Notes



Table 1 is a summary of qualifiers added to thelaboratory's results during data validation. Ifthere is more than one qualifier for a particularanalyte the qualifier applied is the one whichtakes precedence.

AR3Q279I


Attachments:





5. Appendix C - Support Documentation includesdetails to support the statements in thisreport.

RR302792



Analyte

AL

Cu

FePb

Se

Ag

Tl

Zn

SamplesAffected

MCEE15,MCEE17,MCEE19MCE El 5, MCE El 9,MCEE21

MCEE17,MCEE19MCEE15,MCEE17,MCEE19MCEE15

MCEE15,MCEE17,MCEE19,MCEE21MCEE17,MCEE19,MCEE21

MCEE15,MCEE17,MCEE19,MCEE21

MCEE19

MCEE15

Qualifier


ValuesB

B

B

B

LDJ

UL

UL

UL

B

Bias

high

High

HighHigh

Low

Low

Low

LowHigh

Comments*

C

c

ccD

A(r»0.988)E

B

EC

* See explanation of comments.

58302793


Codes Used j_Q Comments g<?l*nn

A - Due to low correlation coefficient (value inparentheses), indicating that the reported results maynot fall within the linear range of the calibrationcurve.

B - One or more of the blanks associated with these samplesgave a negative response greater than the IDL (instrumentdetection limit). The reported results may be biasedLow.

C - One or more of the blanks associated with these samplesgave a positive response greater than the IDL (instrumentdetection limit) . The reported results may be biased.high.

D - Based on relative standard deviation of the analysis ofduplicate injection ( >20%), the reported value for thesample may not reflect the true average concentration.

E - Due to low post digestion spike recoveries, indicatingthat quantitation is biased low, and that detection limitmay be higher than reported.

Attachment 1Data Qualifier Codaa

AR3Q2795




U «= Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) -Confirmed identification.


R - Unreliable results. Analyte may or may not bepresent in the sample. Supporting data necessaryto confirm result.

CODES RELATED TO OUANTITATION(can be used for both positive results and sample quantitationlimits):

J - Analyte present. Reported value may not beaccurate or precise.

K - Analyte present. Reported value may be biasedhigh. Actual value is expected to be lower.


UJ » Not detected, quantitation limit may beinaccurate or imprecise.

UL - Not detected, quantitation limit is probablyhigher.

OTHER CODES

Q - No analytical result.

AR302796

Attachment 2Data Suaaary Foraa

AR3Q2797

IX

I

,Q

V ™1*IsSI•rf h

i!H «g4*28• •*5^^3I"rir

0*»

o S I

CO • -.. - *

j

V

N.

• *- f3 o o• S S1 «

^VM

3

^a

N

o

V)

£

to

Appendix ALaboratory Results of all Target Analyses

AR302799

U.S. EPA - CLP

1 ERA SAMPLE NO.INORGANIC ANALYSIS DATA SHEET

MCEE151 ab Nam- : SK INNER & SHFPÂN LABf.. Cont-ract: t>8-OO-OlO8 : ___________

... Css-e Mr.. • t c. = "w °A- N'.-. . • -,nr. N,- :

Ma-- . • ' - ' 1 WB: <?•-; : WATFP u at f.amrl-?- TO- 02C14-C:?

Lev*-: ' low • "• r '• .- LOUi Date "*••: * i »-_ : 02/01 /•=>:

O.O

Concentration Units. fu-s/L or mg/Kg dry weignt): UG/L

J

CAS No.

7<i29-<:9O-5744O-36-O74.40-38-2744O-39-37440-41-77440-41-77440-7O-2744O-47-3744O-48-4-iiO-SO-ST4 -?,Q_pQ_,fc

7 i ». Q _ Q 2 - 17i?o_<95-47439-<56-5743'5-c'7-67440-Q2-O7440-O9-77782-49-2744O-22-474.4O-23-5744O-28-O7440-62-27440-66-6

'

: Analytel

! Aluminum! Ant imony! Arsenic! Barium! Beryl lium,' Cadmium! Calcium! Chromium! Cobalti Cooper! Iron! Lead! Ma-sês i u"!! flsnân^se! MercuryINicêl! Potassium! Selenium! SilverI Sodium! Thallium! VanadiumIZinc! Cyanidei• i

i jt iCon-rent rat i r-n ] c ! Q

i l

SS.ÔIB:17.00JU!9 . 5O ! B !34. 7O!B!1 . OO ! U !1.0OIU!

2O5OO.OO! !4.0OIU!2 . DO ! U !1. 50 IB!

383O.OC1 1i . v D ; : M

1 1^0 . no I B !34. <50.no; ;

0 . 20 1 U I4 . 00 I U I

132O.OOIB!4.0OIU!2.OOIU!

4760. OO!B!3 . OO ! U !3 . OO ! U !7 . OO I B !

i ii ii ii i

iIM1

IPIPIFIPIPIPIPIPIPIPIPIF;p< D

1 cvIPIPIFIPIPIFIPIPINRii


Color After: COLORLESS Clarity After: CLEAR Artifacts

Comment 3:

FORM I - IN 3/90

AR302800

U.S. EPA - CLP

1 EPA SAMPLE NINORGANIC ANALYSIS DATA SHEET _____________

I MCEE17Lair Nan-;- : SKINNEP 4 SHEPMAN LA8=. Contra.-1 : 68-OO-OlOS '. ___________

SDG No. : MCEE1'

l*- 1C: 02C i<i-021

'_*• -f '. ( i ow/med '.• : LOUI Date Peceivtd: 02/Ol/°2.

* Solids: O.O

Concentration Units ''ug/'_ or mg/K'g dry weight): UG/L

•1 CAT No.t1

; 7429-9O-5! 744O-36-O'7440-38-2! 7440-39-317440-41-717440-41-7I7440-7O-2! 744O-47-3! 744O-48-4; 440-50-8; ~7ij9-?9-£,1 7^. 5Q-92- 1; 7ii3Q_<55_4| 7439-96-5! 7439-97-6! 7440-O2-OI744O-O9-717782-49-2I 7440-22-41 7440-23-5I744O-28-OI744O-62-217440-66-6I

t

COLORLESS

COLORLESS

i i*! A n s i >• r e ;i t! A Ium inum J1 Antimony I!Ar-senic !iBarium 'I Bery 1 lium !I Cadmium I{Calcium iI Chromium !1 Cobalt !! Coc-pe- 'll-on! Lead! Magnes i-jrr '.I Manganese !I Mercur-yI Nick el II Potassium '.1 Selenium |ISilver I[Sodium JI Tha I.1 ium !I Vanadium ![Zinc !1 Cyanide Ii ti :

Clan it

Clarit

11

Cone entrationlC;

28. 7O!B17.00IU2 . OO I U

11. 20 IB1.OOIU1 . OO I U

401OO.OO!4 . OO I U2 . OO I Ui . oo : u

2?. _.G:B7 . 20 '

6O9O . OC '.28. 5O!0 . 2O ! 'J4 . OO 1 U

777.OOIB4.00IU2 . 00 1 U

6820. OOI3. QO 1 U3.OOIU2 . OO I U

I|

1 _ ,

1t

0 !M!IPIPIFIPIPIPIPI n

IP!PIP!FIPIPlevIPIP

W IFIPIPi jri iIPIPINR11

x Before : CLEAR Texture :

y After: CLEAR Artifacts

Comment s :

fi.R3Q2.80(OOOC03

FORM I - IN 3/9O

U S. EPA - CLP

1 EPA SAMPLE NO.INORGANIC ANALV«,I = PA'A SHEET ________________

! MCEE19Lah Mam*: SKINNEP % SHE^MAN LAB11.. Contr-a.-t • *...-DO-OlO?. ' __________

Ma*"*" i ' ' i :•:;' —'-t «'•;: UATFP _a>- Same .' " 1C1: 0201^-07-

'.*•.*•! '-ow/med'i: ._ ._ LOW Date Peceivedr 02/01/Qi

\ S-->1 id. : 0.0

Concentration Units (ug/L or mg/-«'_ •?•-.« -/eight): UG/L

:

1

Color Before: C

CiT f-'c .

7429-9Q-5744O-36-O744O-3S-2744O-39-.3744O-41 -7744O-41-77440-7O-27440-47-37440-42-47440-50-8743'"-* -£•=!— _.74 rQ-<=2-l7439-95-47439-96-57439-97-67440-C2-07440-09-777S2-49-2744O-22-4744O-23-5744O-2S-0744O-62-2744O-66-6

;OLORLESS

Color After: COLORLESS

Comment s :

| ——————————————————————

i ii >! Analyt* ' Concent •• at i| 'I Alum inum1 Ant imonyI Arsenic1 BariumI Beryllium1 CadmiumICalciumI ChromiumI Cobalt1 CopperI Iron!Lead! MagnesiumI Manganese1 MercuryI NickelI PotassiumI Selenium[SilverI SodiumI Thallium! VanadiumiZincI Cyanidet' _ _„_

i9.17.2.

1 11.1.

41OOO.4 .*- .

— .

— *w .

3.6I'."~

3O.O.4.

869.4.2 .

7010.3.3.2.

Clarity Before: C

1 f 1l < l

r - ' r : c i Mi i t

40 IBOOIUOO I U6O ! BOOIUOOIU00!OO 1 U00 I 'J1O ! 5-•C '. ECO'.00 !30!20 I UOOIU00 IBOO I UOOIUOOIOOIUOOIUOOIU

1111

IPIPIFIPIPIPIPIPIPIPIPIFIPIPlevIPIP

W IFIPIP

w IFIPIPINR1

LEAR Texture:

Clarity After: CLEAR Artifacts:

AB302802OntM'.W

FORM I - IN 3/9O

U.S. EPA - CLP

i EPA SAMPLE NO.INORGANIC ANALYSI* DATA SHEET ___________

Lab Nam~ : Si-INNEP 4 SHERMAN L*B~r Cont r »•: t :- <:•* -DO -01O8MCEE21

Case N<- . t 1S?-04 « AC N - . • *•!"><? Nc .: MCEE1 "r

P* - , ' --- \ \ ••~-3: -<~'. : WATEF . _a«- l.amp.e 1C: C2Q14-O-.

-•>•=•! ' ] .--w 'T>-^--' •. LOW Oate Received: CT/Ol,'0!

Sol ids: 0. O

Concentration Units f'.jg'L or mg/h c dry weight): UC-/L

CAS NO.

7429-9O-57440-36-0744O-38-2744O-39-37440-41-77440-41-7744O-7O-2744O-47-3744O-48-4744O-5O-87439-89-67a39-92-l"74?<a -9 5 -47439-96-5- 439-97-67440-O2-07440-O9-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

t1

! Ara) yte11 Aluminum! Ant imonyI Arseni c1 BariumI Beryl 1 iumI Cadmium! Calcium! ChromiumI CobaltI Copper; ir_-iLead1 Magnesi u-! Manganese' Mercury!NicKel! PotassiumI Selenium[SilverI SodiumI Thai liumI Vanadium!ZincI Cyanideii

Conc<?r~'t'~?t i

2O.17.2.^1.1.83.4.-2.1 .

!->.4. .

_j~?£,

O.4.

1O1.4.2.

183.;l

.3.8.

1 l

on I C ; oI I

OOIU!OOIU!ooluiOO I U IOOIU I00 ! U !40 ;B;oo :u:OOIU!1 0 ! B !OO ! LI !10 : ;oo i U :OOIU!20IUIOOIU!OOiU!OOIU! W00 !U!OOIB!00 ! U 100 I U I9O|B|

1 11 11 11 1

f1

1 r'IPIPIFIPIPIPIPIP!P! PIPIFIPIPlevIPIPIFIPIPIFIP;p!NRt


Color Afte>~: COLORLESS Clarity After: CLEAR Artifacts:

Comment s:

FORM I - IN 3/9Q

AR302803

*«!••• HLI.NOICAMC ItClONU DATA ASSCSSMCVT

CASE NO / Vf0*7___________ SITCNO Of $A%mts/MATRIX• EVtE^CR (IF NOT

NAMEFY! >^"^______ CCMPLtTlC** DATE

ICP AA H| CYANIDE

I. HOLDINO TIMES ° ° °

2. CALIflUnONS G _ 0 __cP,J. BLANKS

4. KSJ. LCS4. DUPLICATE ANALYSIS

7. MATRIX SPIXt

I. MSA9. SEXIAL DILUTION _£.10. SAMPLE VERIFICATION O O

II. OTHER QC ° _£_12. OVERALL ASSESSMENT O O

O • Data had ao preblcma/or quabTird du« to mioerM • Dan qualifed dw» to major probtcoc.Z • Data v&acctpobb.X • Probteos, Hi do MI a/tot 4aOL

PERFORMANCE:

Attachment CSupport Documentation

U.S. EPA - CLP

3BLANKS

'. ar C - tie • ^ I*4EP rair'? *! • '.5301, ^^-r N - • SDC- No. : MCEE.r

P-- *>.,- er-at i o-i Blank Matrix (s:ii/water): UIATEC

Pret-af a». i :>n Blank Cor.entr at . o--< Units (ug/L or mg/t--g}: UC-/L

t

11

1

1 AnalyteiiI Aluminum! Antimony! Arsenic! Barium!B-f~ylli urn' c. a-TiTi • unI Calcium1 Chromium[CobaltI CopoerI IronI LeadI Magnesium! ManganeseI MercuryiNickelI Potassium! SeleniumI Si 1 verI SodiumI Thai 1 iumI VanadiumI ZincI Cyanideii

Initial I !Calib. ! Continuing Calibration |Blank I Blank (ug/L) I(ug/L) Cl 1 C 2 C 3 C|

1 I1 i

oQ.Qlu! c.U77!B- H 5>n.n!ii17. 01 U I 17.OIU2.0IU! 2. OIU3 . n ; u | 1 . 0 ! 'Ji.c:'j: i.o".'1 . O ! U ! ^^^ - ~-U '

i o . o i u : -CH Zi-4. OIU' 4. OIU2 . 0 I U ! 2 . 0 i Ui.oiui CiLJLiJ

17. OIU! 17. OIUI.OIU! 1 .OIU

27. OIU 1 C31-3IB"16 . o l u ! e . b I u0.2IU! 0.2IU4. OIU! 4. OIU

101. OIU! 101. OIU> . O U.I ! 4 „ Q } U

G2. 61BJ- C 3 . 5 IB^39.0!U! C40.9r§]3.0IU! 3.b!U3. OIU! 3. OIU2.0IU! 2. OIU

1 t 1I l 11 1 fI 1 I

1 7 . O ' U2.c:u1 . O ' ; '

L ' Ti~' R

'•±G~r34 . C i U2. 0 !U

S I.OIU17.CIUI.OIU

^ 27. OIU6 . 0 I U0 . 2 1 U4 . 0 i U

101. OI'JJlLu

<^3 . 9 IB1i# 3* . b ; U

3.0IU3. OIU2 . 0 ! U

t

<5*>. 6Lgf17. OIU!2 . 0 I U Ii . o : u i1 . O 1 'J I1 n ' i |

4 . o ! u !2 . 0 I U IgrTTil?17. OIU!I.OIU!

27. OIU!6. OIU!0.2IUI4 . 0 ! U I

101. O|U|4. OIU!

^"-— ' n * R '

3."o!U!3 . 0 1 U !2 . 0 I U I

1 11 1I |i _ l

1 I1 It 1t I

Prepa- I Iration I 1Blank C! |M

t 1

C ^2 « 3j ^ aBn i PiTToooiu! |pj2.OOOIUI !F^1 . OOO I U ! IP1 . 000 I U ! 1 P •1 . OOP I Ui IP

4.000IU! IP :2 . 000 I U ! 1 P 'i-oogju! IP

r^4.07Qjp^P !l.flQQjH! !F

' «>S Q &< 1 p6.0OO!U| !PO.20O!U! !CV4.OOOIUI IP

101.0OOIU! |P4.pog;u! IF

< ~2 90 84 I P<33.240l£>i IP3.OOO1U! |F3. OOQ|y 1 !P

^o.cnraio! IPI I INRl i t it i l '

FORM III - IN 3/90

~ - CLP

"J

1 ar"'l-

t1

Aoalyteti

A i urn i numfcknt i mnny

^^ — '" ^ > i rrF ' .' .' •>' •• jrr,•' ----T : -Tr. Z i ' ; ~n

CobaltCcope'"I -onLeadMagnesiumMangar.es eMercur yNickelPotassiumSeleniumSilverSodiumThaJ 1 iumVanadi urnZi noC y •? n i c! e

t

InitialCalib.Blankfug/L) C

1t

|

1

;\

III

I.OIUt11

t

t

1I1

t1ti11t

1

1

Cor t

1

1 .O

O. 2

BC

LI

U

..•in<= Calibrlank (ug/L

2

1. 0

C-.

C

u

3 cPrepa-rat ionBlank

AB3028JOOOtlJ

1 1

- 1 •t1 „,,,

I NP; NP' N-

' ' '•!-

' »-. C :

; . ' .=

: :NF:; ; NR :1 INR!; IF :1 1 NR !1 1 NR :•• > t- w i

! I NR I1 INR!1 INR!1 INR!1 ;NR:1 INR i! INR;I ; NR :I INR;i t ii

"1 OJ y&

FORM ITI - IN 3/9O

$it«Data ••viav Horkshatts JUftrtnca a

«cio» x «Tirtr orCONTRACT LX»CJUrOftT DATA FACXAOI

?-*risrr;t-

SKIS.d by

Traffic Xoport Moa:

Trip ilanX no.: _tqvip»ant IlanJc Ho.;field Dup »oa» <*&££"£/ 7 /

$CW No. J racfuira* that specific analytical work fc« dona and thatto tha *

tarfaranc. C c* »..ult.-««P1. Qu.ntit.tion

Svarall Coaatncs:

Definitions and Qualifiarss

2at\du« to quality control critaria.data dua to quality control critaria.

Reviewer: s ^ / ^ ^r Oatt.

Data ft*v;tv tforkshattc

X. DATA CCMPLirtVtSf

R3028IO

Data Heview

tx. IOLDIXO Tl«i complete table for all saaples and circle thaanaly*i» data for saaple* not within criteria

r : " " ] EC, or AX IDE ; CTXEM PNSW.E • :ATt CATt ' CATt ! CATt '

:: SAMPLE: A.«AL.S:S ANALYSIS

METALS - 180 DAYS FROM SAMPLE COLLECTIONMERCURY -21 DAYS FROM SAMPLE COLLECTIONCYANIDE - 14 DAYS FROM SAMPLE COLLECTION

ACTIOH:

AR3Q281 I

IXX *. XMT»CXE*T CALXIHAfXON (SactiOA 1)

i. Bac every Criterialist t .e i-«;y.e* •.nic.*. «:d rot seet the percent recovery :%») cr:ter;afsr :.-it.ai cr t;.-.t :r ;r? Cal.tra

!r.'/Cr'f ANALYTS IB ACTTCN SAMPLES A.rfgrrtr

We,ACTIONS:

If any ar.alyta ices not seat rha %X critaria folicv tha actions statedbalov:For Positive Results:

6ata Review worksheets

xxi t. iM«T»cxurr cj.uftju.tiov (Section 2)


A. :ii t.».« lafccratsry »st t.-.* prc?«r .-.rvser ofstandards fcr cal.tr»t:on as described in the /-t\sew /fty er Nc

• . Vere calibrations perf»rxed at the t*?inninf of XT-Neach analysis? /Yes/or No

C. vere calibration standards analyzed at tha ba-•g inning of staple analysis and at a ainiaua fre-<juency of ten percent or every tvo hours during /x~xanalysis, whichever is more frequent? fYeT'or No

g/x*0. Were the correlation coefficients for tha cali- -*J5~

bration curves for AA, 119, and Of & O.S9ST Yes or (No'E. was a standard at 2xCROL analyzed for all ICP ^±

analyses? /Ves) or MoIf Me,

Tha data »ay b* affected. Csa professional judgesent to determine*the severity of the effect and qualify the data accordingly. Discussany acticr.s belov and list the saaples affected.

& A

HR3028I3

Cat a *ev;t* worksheet

XT A. BLUft AJIAlYfll USOLTS (Sections 1-3)

list tfte blank contamination in Sections 1*2 belev. A separate!2 i« vsed for sc;l and vater blanks.

2. Equi;£*nt/?rip Slanks? 8LJ AMALYTt


A. Was a preparation blank analyzed for each matrix,for every 20 samples and for each digestion /-""Nbatch? . f Yes) or No

8. Was a calibration blank run every 10 saaples or /"">\every 2 hours whichever is »ore frequent? /Yes/or Mo

If Mo,The data cay be affected. Use professional judgement to determine

tha severity of the effect and qualify tha data accordingly. Discussany actions below, and list tha samples affected.__————————————————————————HR3028U——


ZV A. BULNX ANALYSIS RESULTS (Sections 1-3)

List tha bUnx contamination in Sections 142 telcw. Aworksheet should be used for soil and water blanks.

1. Laboratory Blar.xs MATRIX-

ICg/CC;« PBEP 9L ANALVTS CONC. •«

Cat a *ev;ev Worksheets

XT §. ILAJII AM.LYSX* AISOLTS (Section 4)

4. flank Actions

The Act::-. Levels for any a.-alyte is eq--al ts five t;zes t.-a • ".*•cs-ce-tnt:or :f that elese.-f s csntasi.-at.tr .- 4fty tlanV £. **~ *:.evei fcr sart.ei which have been concentrated or diluted s'/s«id""-e^4t;p.;ed ty :..e concentrat.cn/dilwt.cn factsr. He posit ve sa-erlresult should fee reported unless the concentration of the analyte *saaple exceeds the Action Lavei (AL) . Specific actions are •• ?«fn t*iov.'?

1. when the concentration is greater than the IDL. but less tiaiiAction Level, report the saapla concentration detected Twith \

2. When the saaple concentration is greater than the Actionreport the sample concentration unqualified.

MAXWITS UMTj

NOTE: Blanks analyzed during a soil case must be converted -to DO/XQ inordar to compare them with tha sample results. ^' 9

Cone, in ug/L X Volmne dUut^d ^ flAMlL. X 1L_ X IQOOcn, X l»g «weight digested (Igraa ) 1000ml .kg lOOOug

Multiplying this result by 5 to arrive at the action level gives a finalresult in mg/Xg which can then be compared to sample results

A83028I6

f°r

AR3028I7


T A. ICt irtlUtllVCl CltCf SAM'LS (Sections 1 ft 2)

1. Recovery Criteria•_.«t ar>.y elements in the ICS At solution -.n:ch did not seet the criteria

%*

DATE ELttEXT %R ACTION SAX»US AFFICTE3

ACT:If an element does not seet the %R criteria , follow the actions statedbelow:

PESCEMT RECOVERY<50% 50-79% >120%

2. Frequency RequirementsVere Interference QC samples run at the beginning andend of each sample analysis run or a minimua of twiceper • hour working shift, whichever is mora frequent? ^Yes^or Mo

If no,Tha data may ba affected. Use professional judgement to determine

tha severity of tha effect and qualify tha data accordingly. Discussany actions below and list the samples affected.

ftR3028i8


v •. xc> xrmmEiKt cites SAMFL* (Section

/A

ZCS// tf/t AL CA rr

x o

Estimate the concentration producad by tha

(»VM At. CA rt M6

ACT:C«! / !„+. one.

& qualification ifless than *;

Give explanations for any actions taken below:

Review Worfcs.-.sets

7 B. 1C? IHTZRTIRIHCZ CHZCX SAXfLE (Section 3)

:. Stpcr: t*e :=r.c«ntratisn of ar.y eieoents zececied in t.-.e ::j Aticr. > :xi:i that snould r.ot se present.

"*'ic nr < '""'"r!3 C"MC. CF.^•IV». W&*vW»«»W \.«**'S». •* •

-»r 'trp '/-C "*! ~VC ^f^-.1 iHt .V.5 -•• «..«. -wSir "X ~yA^ ^4% • m»

AR302 =

Data Revitw worksheets

VI. XATRIX SMSJ

Jecsvtry Cr:-.tna

List ^.t percent recoveries_-_..._A4 •»••••'«.

S - amount of spike addedSSR - spikes s»aple resultSit * sasple result

Analyte ( $«» ( s*———————— .,. ——————————— . —— l —————————————— I- —————————————— 1 —————— ————

for analytes ••hio.k>. did not r««-

•

S %ft Actioni i i—— | —————— ————— —————————— , —————— ————— —————————— , —————— ————— —————————— j —————— ————— ————————

i• •i

Matrix Spike Actions apply to all samples of the same matrix.

ss- • d £ &fi&tf'(* C*wJ*£ ~ACTIONS: /S° sff > /J ^ '

•« if t.w.e saecle concentration exceeds the spike concentrationfact"-- e* ; cr more, no action is taken.

2. If any analyte does not seet the %R criteria follow tha acstated belcv:

PERCENT RECOVERY00% 30t-74% M2S*

2. Frequency . Criteria " " ""- .- '~-~ ••'• ' • - .= -- ~..A. Was a matrix spike prepared at the required fre- ~ ,

quency? (J**/B. Was a pest digestion spike analyzed for elements

that did not seet required criteria for aatrix /""%spike recovery? C^f

_-_,..,»•.• uA«-v«x<»«fc should be used for each matrix SDlXv *e4MYJ

• • •» m• *. . « •

by a

tions

>or Ho

or No21

Data Revitw worksheets

ffl. LAJOIUTCII XPLICATtS

List t>.e concentrations ef any analyte not aeeting the criteria for__pl:c.-.t precision, for soil duplicates, calculate the CRDL in r^/k^.s.rq •_-1 sarp.« weight, veiwse an<s percent sol;ds data for t.re sample.:-sica:e -.-.at criteria was ^sec ts evaluate precision by ctroi.r? eit.-.ertr-.e RP5 cr CROL for each tltsent. <**-~~-

Element C*D{. Saaple | Dual ieateiwatef soi^ _^

Aluminus _An ti aony __,Arsenic ,BariuaBerylliuaCadmiue .CalciueChromiumCobaltCcpper.IronLeadMagnesiuaManganeseMercuryNickelrotassiuaSeleniusSilverSod i usTha ili"-vanadiusZincCyanide _

200«010200S's

.500010

_2$-_.100.ssoeoIS*0.2.40

SOOOs

iOsooo

10so20

_ 10.

• •—————

———————

-<

I —— ———

——————————————————————————————

_______

^M

•

1

•

—————————————————————————————— ;

Laboratory Duplicate Actions should be applied to all other samples ofthe sace matrix type.

ACTIONS l

1. Estiaata (J) positive results for elements which have an RPO >20%for waters and >35% for soils. •

2. If sample results are less than Sx tha CROL, estimate (J) positiveresults for eleaents whose absolute difference is >CRDL, (2xCROL forsoils). If both samples are non-detected, the RPO is not calculated(NC) .

fli302822


VIII. fl.Lt DCniCATtS

List the concentrations of all analytes in the field duplicate pair-or soil i,?..:.tt« calculate the CROL in sg/k9 using the saaelc veief.tvol.re arc ?«r:tnt solids data 'or the sasple. Indicate what criteria.as .seo ts evaljte the precis.cr. by circl.n? either the *?: or C«L foreach elerent.

HATRIX:.CHfii Sample

vater soil

Aluminum_mAntimony_.Arsenic__Bariua.__mBerylliua^.Cadaiua__„Calcium__Chromium__Cobalt___Copper___IronLeadMagnesiua_jManganese__MercuryNickelPotassium^<J[SeleniumSilver_SodiuaThallivus.Vanadiua*Zinc___"Cyanide__}__Field Duplicate Actions should be applied to all other samples of thesame matrix type.ACTIONS!

1. Estimate (J) 'positive results for elements which have an RPO *>30%for waters and >50% for soils.

2. If sample results ara less than Sx the CRDL, estimate (J) positiveresults and (UJ) nondetected results for eleaents whose absolutedifference is >2xCRDL, (4xCRDL for soils). If both samples are non-detected, the RPO is not calculated (NC).

&R302823

Oats Review Worksheets

XS. LAJORATCIT COtfTftOL lAXPLt

I. Aa^»ou« LM _- O ~\\

List any LCS recoveries net within the SC-12CI criteria and the samplesa;fected.

\2 ACT icy SA.M»LE« Aff;:rE2

LCS

List any analytes that were not within tha control windows set by theEPA for the solid LCS saaple. The to-120% criteria is not used toevaluate solid LCS results.

LgS CQMC. gQMTaOL WINDOWS ACTION SAM»LM

ACTIONS:Percent Recovery

SOLID LCS <EPA Control Windeva >EPA Control Windeva

3. Frequency CriteriaA. Was an LCS analyzed for every matrix, every

digestion batch, and every 20 samples? (Je /or Mo


I A. rORJlACS ATOMIC AJSOAmOV AtfAlYSXS

1. Duplicate Precision........ Duplicate infections and ort-point analytical spikes vere per-

forred for all sasples: duplicate .n^ectiar.s agreed ••ithin -:o%.

........ rgplicate injections and/or spikes were rot perforseo for thefollcwir.f samples/eleaents:______________________

...<V... Duplicate injections did not agree vitMn • 201 for saeples/e 1 esents: pL f rt ere L£ »/^'32-£ *)___________________

•••(• ^ ^ ^ ^ H ^ ^ ^ ^ WHI —— ^ M— ^ ^ ^ ^ ^ H H ^ ^ ^ ^ H ^ M MMMM M MM M MMMMM ^

2. Post Digestion Spika Recoveries....... spike recoveries met the iS-113% recovery criteria for ell

samples..<<--..- Spike recoveries did not seet the tS-1131 criteria but did

not require MSA for the following samples/elements:(

MSA was used to quant itate analytical results when con*tractually required.

___ Correlation coefficients >0.99S, accept results.___ __ Correlation coefficients <0.99S for sampler/ur^ers/el ements : _____________________________

y«thod of Standard Addition (MSA) vas not performed as re*quired *cr samples/elements: ________________________

ACTIONS:1. Estimate (J) positive results if duplicate injections are outside

* 20 % RSO or CV.2. If the sample absorbance is <SO% of post digestion spike absortance

the following actions should be applied: .PERCENT RECOVERY ~~

3. Estimate (J) sample results if MSA was required and not performed.4. Estimate (J) sample results if correlation coefficient was <0.99S.

SR302825

Cat a He view worksheets

IX. XWCtXTltT COO'Ut PLASH* <ICf) ftRIAt DXIOTXOM AJfAlYSXS

____ Serial dilutions were performed for each matrix and resultsof the diluted sample analysis agreed within ten percent ofthe er:;ir.al undil.ted analysis.

____, Serial dilutions vere not performed for the following:

___m__m Serial Dilutions vere performed, but analytical results didnot agree within 10% for analyte concentrations greater thanSOx the IDL before dilution.

Report all results below that do not meet the required laboratorycriteria for 1C? serial dilution analysis,MJkTHXX:ELTMEMT IDt SOxIDt SAMPLI SEXXAL ID ACTXOMtub**** RESULT oiurrio*

Aluainum !.Barium__}.Beryllium;.Cadmium!.Calcium_jChromium :Cobalt__

Iron___Lead___Magnesium1ManganeseNickel_PotassiuaSilver__Sodium__Vanadium.Zinc

Actions apply to all samples of the same matrix.

ACTIONS:1. Estimate (J) positive results if %0 >1S.

ftR302826

Sets Revnw Worksheets

EXX. DETICTXOl UXXf HI JOLTS

1. Instrument Detection Limits

r.-.str.ient detection Liait results were present and fsund to beless tha.-. the Contract Required Cetect;cr. Limits.

ISLs -ere not incljdeo in the data pacxaqe on For: XI.

:?Ls vere present, but the criteria was not set fcr thefellcwir.5 elements:_____________________________,

2. Reporting Requirements

Xf No.

Were sample results on Form X reported down to / "the XDL not the CROL for all analyses? (Yes/or MoWere saaple results that were analyzed by ICPfor Se, Tl, As, or Pb at least Sx XDL. Yes or NoWere sample weights, volumes, and dilutionstaken into account when reporting detection /*~\limits en Form X. /Yesyor Mo

The reported results may be inaccurate. Make the necessary changeson the data sumsary tables and request that the laboratory resubmit thecorrected data.

8B302827


IXXX. SAXPU eCAXTXTATXOV

Sample results fall within the linear range for ICP and vithinthe calibrated range for all other ;araseters.««r?:t results -.*re te.c.-d the lir.ear ra.-?e/ caliirat--- -a--«of the instr.sent fcr the fcl loving sa?p:es/eleze.-.ts:

In the space below, please shew a minimum of one saaple calculationper method:

1SZ

CY ANISE

For soil samples, tha following equation may be necessary to convertraw data values (usually reported in ug/L) to actual saaple con-centrations (ag/kg):Tha lab is required to use 1 gram saaple (wet weight) to 200 ml.Wet weight concentration » — - —... ._

digest cone, in as X 200«1 X Ufc__ X IQOOcr^ x lag - BSL 1 gm 1000 ml 1kg lOOOug kg

In addition the sample results are converted to dry weight using thepercent solids calculations:

Wet weight cone. X 100 » final concentration, dry weight (a»g/kg)tsolids

AR302828

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