40620060 liquid green 2006

SAFETY DATA SHEETKEYSTONE LIQUID GREEN 2006

Issued: 05/12/2008

Revision No: 2

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

Product name: KEYSTONE LIQUID GREEN 2006

CAS number: LISTED

Product code: 406 200 60

Synonyms: MIXTURE

Use of substance / preparation: Industrial Colourant

Company name: Keystone Europe Ltd

Units 1-2 Beckview Business Parks

Bradley Junction Ind Est

Leeds Rd

Huddersfield

HD2 1UR

Tel: 01484 341 466

Fax: 01484 341 544

Email: [email protected]

2. HAZARDS IDENTIFICATION

Main hazards: Limited evidence of a carcinogenic effect. Toxic to aquatic organisms, may

cause long-term adverse effects in the aquatic environment. Harmful: may

cause lung damage if swallowed.

Workplace exposure limit: This substance does not have a workplace exposure limit.

PBT: This substance is not identified as a PBT substance.

Directive 1999/45/EC: This preparation meets the criteria for classification as dangerous in

accordance with Directive 1999/45/EC.

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous ingredients: KEROSINE - UNSPECIFIED - SOLVENT NAPHTHA (PETROLEUM), HEAVY

AROM. 30-50%

EINECS: 265-198-5 CAS: 64742-94-5

[Xn] R65; [N] R51/53

• NAPHTHALENE 1-10%

EINECS: 202-049-5 CAS: 91-20-3

[Xn] R22; [Xn] R40; [N] R50/53

• DIPROPYLENE GLYCOL MONOMETHYL ETHER 1-10%

EINECS: 252-104-2 CAS: 34590-94-8

[Xi] R36/37/38

• ETHYLHEXYLAMINE 1-10%

EINECS: 203-233-8 CAS: 104-75-6

[Xn] R20/21/22; [C] R34; [-] R10[cont...]


Issued: 05/12/2008

4. FIRST AID MEASURES

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to

skin. Drench the affected skin with running water for 10 minutes or longer if

substance is still on skin. Consult a doctor.

Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.

Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a

litre of water to drink immediately. Consult a doctor.

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so.

Consult a doctor.

5. FIRE-FIGHTING MEASURES

Extinguishing media: Suitable extinguishing media for the surrounding fire should be used. Use

water spray to cool containers.

Exposure hazards: In combustion emits toxic fumes.

Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent

contact with skin and eyes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not

approach from downwind. If outside keep bystanders upwind and away from

danger point. Mark out the contaminated area with signs and prevent access

to unauthorised personnel. Turn leaking containers leak-side up to prevent

the escape of liquid.

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage

container for disposal by an appropriate method.

7. HANDLING AND STORAGE

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation

of the area. Do not handle in a confined space. Avoid the formation or spread

of mists in the air.

Storage conditions: Store in cool, well ventilated area. Keep container tightly closed. The floor of

the storage room must be impermeable to prevent the escape of liquids.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Hazardous ingredients: NAPHTHALENE

UK - 8 hour TWA: 50 mg/m3

Engineering measures: Ensure there is sufficient ventilation of the area. The floor of the storage

room must be impermeable to prevent the escape of liquids.

Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.

[cont...]


Issued: 05/12/2008

Hand protection: Impermeable gloves.

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Impermeable protective clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES

State: Liquid

Colour: Green

Odour: Aromatic

Evaporation rate: Negligible

Solubility in water: Insoluble

Also soluble in: Most organic solvents.

Flash point°C: 95

10. STABILITY AND REACTIVITY

Stability: Stable under normal conditions.

Conditions to avoid: Heat.

Materials to avoid: Strong oxidising agents. Strong acids.

Haz. decomp. products: In combustion emits toxic fumes.

11. TOXICOLOGICAL INFORMATION

Acute effects: May cause lung damage if swallowed.

CMR effects: Limited evidence of a carcinogenic effect.

11. TOXICOLOGICAL INFORMATION (SYMPTOMS)

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat. Nausea and

stomach pain may occur. There may be vomiting.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.

12. ECOLOGICAL INFORMATION

Mobility: Insoluble in water.

Persistence and degradability: Not readily biodegradeable

Bioaccumulative potential: No data available.

Other adverse effects: Toxic to aquatic organisms. Toxic to soil organisms.

PBT identification: This substance is not identified as a PBT substance.

13. DISPOSAL CONSIDERATIONS

NB: The user's attention is drawn to the possible existence of regional or national

regulations regarding disposal.

[cont...]


Issued: 05/12/2008

14. TRANSPORT INFORMATION

ADR / RID

UN no: 3082 ADR Class: 9

Packing group: III Classification code: M6

Shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Naptha,

Napthalene)

Labelling: 9 Hazard ID no: 90

IMDG / IMO

UN no: 3082 Class: 9

Packing group: III EmS: F-A,S-F

Marine pollutant: . Labelling: 9

IATA / ICAO

UN no: 3082 Class: 9

Packing group: III Packing instructions: 914

Labelling: 9

15. REGULATORY INFORMATION

Hazard symbols: Harmful.

Dangerous for the environment.

Risk phrases: R40: Limited evidence of a carcinogenic effect.

R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

R65: Harmful: may cause lung damage if swallowed.

Safety phrases: S36/37: Wear suitable protective clothing and gloves.

S61: Avoid release to the environment. Refer to special instructions / safety

data sheets.

S62: If swallowed, do not induce vomiting: seek medical advice immediately

and show this container or label.

Haz. ingredients (label): KEROSINE - UNSPECIFIED - SOLVENT NAPHTHA (PETROLEUM), HEAVY

AROM.; NAPHTHALENE

[cont...]


Issued: 05/12/2008

Note: The regulatory information given above only indicates the principal

regulations specifically applicable to the product described in the safety data

sheet. The user's attention is drawn to the possible existence of additional

provisions which complete these regulations. Refer to all applicable national,

international and local regulations or provisions.

16. OTHER INFORMATION

Other information: This safety data sheet is prepared in accordance with Regulation (EC) No

1907/2006.

* indicates text in the SDS which has changed since the last revision.

Risk phrases used in s.3: R65: Harmful: may cause lung damage if swallowed.

R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in

the aquatic environment.

R22: Harmful if swallowed.

R40: Limited evidence of a carcinogenic effect.

R50/53: Very toxic to aquatic organisms, may cause long-term adverse

effects in the aquatic environment.

R36/37/38: Irritating to eyes, respiratory system and skin.

R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.

R34: Causes burns.

R10: Flammable.

Legal disclaimer: The above information is believed to be correct but does not purport to be all

inclusive and shall be used only as a guide. This company shall not be held

liable for any damage resulting from handling or from contact with the above

product.

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40620060 liquid green 2006

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