3.7 chem. eqs 3.8 balancing chem. eqs - department of...

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3.7 Chem. Eqs & 3.8 Balancing Chem. Eqs

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Page 1: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

3.7 Chem. Eqs&

3.8 Balancing Chem. Eqs

Page 2: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–2

Chemical Equations

A chemical equation gives the chemical formulas of the reactants on the left of the arrow and the products on the right.

Reactants Product

C(s)

O2 (g)CO2 (g)

Page 3: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–3

Symbols Used in Equations

Symbols used in chemicalequations show

• the states of the reactants.

• the states of the products.

• the reaction conditions.

TABLE

Page 4: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–4

Chemical Equations are Balanced

In a balancedchemical reaction• atoms are not

gained or lost.

• the number of reactant atoms is equal to the number of product atoms.

Page 5: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–5

A Balanced Chemical Equation

In a balanced chemical equation,• there must be the same number of each type of atom on

the reactant side and on the product side of a balanced equation.

• numbers called coefficients are used in front of one or more formulas.

Al + S Al2S3 Not Balanced2Al + 3S Al2S3 Balanced

2 Al = 2 Al3 S = 3 S

Page 6: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–6

Learning Check

State the number of atoms of each element on thereactant side and the product side for each of thefollowing balanced equations.

A. P4(s) + 6Br2(l) 4 PBr3(g)

B. 2Al(s) + Fe2O3(s) 2Fe(s) + Al2O3(s)

Page 7: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–7

Solution

A. P4(s) + 6Br2(l) 4 PBr3(g)4 P 4 P12 Br 12 Br

B. 2Al(s) + Fe2O3(s) 2Fe(s) + Al2O3(s)2 Al 2 Al2 Fe 2 Fe3 O 3 O

Page 8: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–8

Learning Check

Determine if each equation is balanced or not.

A. Na(s) + N2(g) Na3N(s)

B. C2H4(g) + H2O(l) C2H5OH(l)

Page 9: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–9

Solution

Determine if each equation is balanced or not.

A. Na(s) + N2(g) Na3N(s)No. 2 N on reactant side, 1 N on product side.

1 Na on reactant side, 3 Na on product side.

B. C2H4(g) + H2O(l) C2H5OH(l)Yes. 2 C = 2 C

6 H = 6 H1 O = 1 O

Page 10: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–10

Guide to Balancing a Chemical Equation

Copyright © 2005 by Pearson Education, Inc.Publishing as Benjamin Cummings

Page 11: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–11

To balance the following equation, Fe3O4(s) + H2(g) Fe(s) + H2O(l)

• work on one element at a time.• use only coefficients in front of formulas.• do not change any subscripts.Fe: Fe3O4(s) + H2(g) 3Fe(s) + H2O(l)

O: Fe3O4(s) + H2(g) 3Fe(s) + 4H2O(l)

H: Fe3O4(s) + 4H2(g) 3Fe(s) + 4H2O(l)

Steps in Balancing an Equation

Page 12: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–12

1. Write the equation with the correct formulas.NH3(g) + O2(g) NO(g) + H2O(g)

2. Determine if the equation is balanced.No, not all atoms are balanced.

3. Balance with coefficients in front of formulas. 4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g)

4. Check that atoms of each element are equal in reactants and products.

4 N (4 x 1 N) = 4 N (4 x 1 N)12 H (4 x 3 H) = 12 H (6 x 2 H)10 O (5 x 2 O) = 10 O (4 O + 6 O)

Balancing Chemical Equations

Page 13: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–13

Equation for A Chemical Reaction

Page 14: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–14

Checking a Balanced Equation

Reactants Products1 C atom = 1 C atom4 H atoms = 4 H atoms4 O atoms = 4 O atoms

Page 15: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–15

Check the balance of atoms in the following.

Fe3O4(s) + 4H2(g) 3Fe(s) + 4H2O(l)

A. Number of H atoms in products.

1) 2 2) 4 3) 8

B. Number of O atoms in reactants.

1) 2 2) 4 3) 8

C. Number of Fe atoms in reactants.

1) 1 2) 3 3) 4

Learning Check

Page 16: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–16

Fe3O4(s) + 4H2(g) 3Fe(s) + 4H2O(l)

A. Number of H atoms in products.3) 8 (4H2O)

B. Number of O atoms in reactants.2) 4 (Fe3O4)

C. Number of Fe atoms in reactants.2) 3 (Fe3O4)

Solution

Page 17: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–17

Balance each equation and list the coefficients in the balanced equation going from reactants to products:

A. __Mg(s) + __N2(g) __Mg3N2(s)

1) 1, 3, 2 2) 3, 1, 2 3) 3, 1, 1

B. __Al(s) + __Cl2(g) __AlCl3(s)

1) 3, 3, 2 2) 1, 3, 1 3) 2, 3, 2

Learning Check

Page 18: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

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A. 3) 3, 1, 13Mg(s) + 1N2(g) 1Mg3N2(s)

B. 3) 2, 3, 2

2Al(s) + 3Cl2(g) 2AlCl3(s)

Solution

Page 19: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–19

Equations with Polyatomic Ions

Page 20: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

Copyright © Houghton Mifflin Company. All rights reserved. 3–20

Balancing with Polyatomic IonsMgCl2(aq) + Na3PO4(aq) NaCl(aq) + Mg3(PO4)2(s)

Balance PO43- as a unit

MgCl2(aq) + 2Na3PO4(aq) NaCl(aq) + Mg3(PO4)2(s)2 PO4

3- = 2 PO43-

Balance Mg and Cl3MgCl2(aq) + 2Na3PO4(aq) 6NaCl(aq) + Mg3(PO4)2(s)

3 Mg2+ = 3 Mg2+

6 Na+ = 6 Na+

6 Cl- = 6 Cl-

Page 21: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

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Balance and list the coefficients from reactants to products.

A. __Fe2O3(s) + __C(s) __Fe(s) + __CO2(g)

1) 2, 3, 2, 3 2) 2, 3, 4, 3 3) 1, 1, 2, 3

B. __Al(s) + __FeO(s) __Fe(s) + __Al2O3(s)

1) 2, 3, 3, 1 2) 2, 1, 1, 1 3) 3, 3, 3, 1

C. __Al(s) + __H2SO4(aq) __Al2(SO4)3(aq) + __H2(g)

1) 3, 2, 1, 2 2) 2, 3, 1, 3 3) 2, 3, 2, 3

Learning Check

Page 22: 3.7 Chem. Eqs 3.8 Balancing Chem. Eqs - Department of ...chemistry.csudh.edu/faculty/krodriguez/CHEM110/Ch3_Stoic...the reactant side and on the product side of a balanced equation

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A. 2) 2, 3, 4, 3 2Fe2O3(s) + 3C(s) 4Fe(s) + 3CO2(g)

B. 1) 2, 3, 3, 1 2Al(s) + 3FeO(s) 3Fe(s) + 1Al2O3(s)

C. 2) 2, 3, 1, 3 2Al(s) + 3H2SO4(aq) 1Al2(SO4)3(aq) + 3H2(g)

Solution