2013_4_life9
TRANSCRIPT
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BEANS Laboratory Life BEANS
BEANS Project Seminar
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2013
BEANS
Life BEANS
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BEANS Laboratory Life BEANS
ME MS
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EL
EL
0 nm
20 nm
1 m
!"#$%!$%'(##$% !)#$%!*#+#$%
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BEANS Laboratory Life BEANS
BEANS
D
BEANS
"
()
()
EL
BEANS
Life BEANS
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BEANS Laboratory Life BEANS
#
$
%&$'%&$'
(&&$'
2
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BEANS Laboratory Life BEANS
ITO)
$'"
1.6 10
EL
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BEANS Laboratory Life BEANS
100nm
2
MEMS
( b )( a )
-(2B)-2-3-2.1 (a) P3HT (b)F4-TCNQ
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BEANS Laboratory Life BEANS
C70
ClAlPc
b-axis
!4.2
BCP
DBP
TPTPA
1. 2. HOMO
3.
5.3%
2.2
)$' *+,%
-.
/0,
123456&7 289
:);< )&$'"(&$' 253
2.
6.9
10
)$' *+,%
-.
/0,
123456&7 289
:);< )&$'"3052/ 4 253
6.9% 14.5
/0,
*+,%
5=&>);1235?@
5=&
>);123253
-.
C70
CRZEL
1.85
/
C70/ClAlPc
C70/DBPBHJ
2
4
6
8
10
1
ABC)B%
=BD
%BC
C70/ClAlPc
310
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BEANS Laboratory Life BEANS
CuPc (p)
PTCDA ()
JSC(mA/cm2) VOC(V) FF !(%)
-1.77 0.61 0.43 0.47
-1.61 0.56 0.37 0.33
ITO
CuPc30nm, 100nm
#
$
%&$'%&$'
(&&$'
TEM
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10
ITO
CuPc
30nm, 100nm
Si
CuPc
50nm
Au
Cathode Anode
SOI
Au
3cm
NIR44
0
2
4
6
8
10
12
14
16
18
20
1000 1100 1200 1300 1400 1500
Wavelength[nm]
Responsivity[mA/W]
b)
a)
(Au/n-Si Schottky
diode)
0
2
4
6
8
10
12
14
16
18
20
1000 1100 1200 1300 1400 1500
Wavelength[nm]
Responsivity[mA/W]
b)
a)
(Au/n-Si Schottky
diode)
IR
E"
E"F"
CuPcAu
10
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EL
2025
"
"
"
"
"
10-3 103
Current density (mA/cm2)
10-2
100
102
10-1 101
Externalqua
ntume
fficiency(%)
101
10-1
10010-2 102
10-2mA/cm2(3.8 V) !EQE= 15.8%=GH;>.(/04'53 :C& $'"
5016
1.6
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BEANS Laboratory Life BEANS
EL
PTCDA CuPC
Glass/PTCDA (3nm )/CuPC(3nm )/CuPC(30nm )
EB
Glass
substrate
w ater
substrate
Glass
IF$+ JHKLMHLKN
OPFJJ
-PQ%:R $'"
*+,%:%&$'"I31 :D&$'"
/0,:())$'"
-P:(&&$'"1ST0*:C&$'"
:720nm
1.31
0.0
0.20.4
0.6
0.8
1.0
1.2
1.4
1.6
20 30 40 50 60 70 80 90
Alq3[nm]
EQE[%]
()
1.23
1.33%1.41%
1.08%
31EL
1.6
1.3
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BEANS Laboratory Life BEANS
pZT1.nZT1.5
Bi2Te3
197.5 V/K 400S/cm 0.25 W /(m K)1/5
ZT=1.8
100nm
80nm
ZT1.8
BCP
-
ZT = 1.5
BCP
Mn52100g/mol
Mw54700g/mol
PDI1.05
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BEANS Laboratory Life BEANS
2
Ag electrode
V
cooling
Celln
Celln
Cellp
Cellp
heating
5 mm
25 mm
10 mm 10 mm
Substrate
C60 (50 nm)
Cs2CO3 (5 nm)
HMDS
Celln :
Substrate
Pentacene(8 nm)
F4-TCNQ (5 nm)
HMDS
Cellp :
Substrate
C60
Cs2CO3
Ag Ag
DPh-BDT
12"34567-/&84-89:;/2< *# =>-%?*
Substrate
/&84
2"34567
Ag Ag
89:;
$5@*5A&- 5B#- :/C3D:4/2< *E =>-%?*
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BEANS Laboratory Life BEANS /
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BEANS Laboratory Life BEANS
!!
211,000(5)
(FIRST)
30
iPS
EL(32.4)
(OPERA)H22.4
224
(OPERA/)
OPERA20(200)EL
EL
iPS
FIRST
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BEANS Laboratory Life BEANS
8F1.GHIJG.@K.$K.
Hyperfluore
scence
but
C,N,H,O
but25
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8F1.GHIJG.@K.$K.
ST1Est
T1SS(Hyperfluorescence)
Hyperfluore
scence
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100! Hyperfluorescence
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BEANS Laboratory Life BEANS
2012.12.13
Hyperfluorescence
(~100%
~25%
(1/10)
Hyper-
fluorescence()
!"#$% '()%$*+$,+$
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L&ML3KIN.O P Q$RI@0GFS Q$0.G$TUJ$TVS Q$KINTUJ$
20134
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i3 -OPERA
! ! ! !
**
SIIQ*
(PHOENICS) (ISIT)
OPERA
EL
U 7 VW#744GGGBJXPXM+$>JNFENPHB+K.4X$YNZ[NBVH'PU 7 VW#744GGGB$F$+>\L]L+]FB^#4N$.PXJV4N$.PXJVBVH'PU _// 7 VW#744GGGBJXXQB #4N$4X$YNZBVH'P
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BEANS Laboratory Life BEANS
EL
PCE=7
EL
EQE>%
2011.1.24:
M EM S