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Page 1: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

1

2012 Annual Report

Southeast Saskatchewan

Airshed Association

Page 2: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

2

Prepared by:

AMEC Environment & Infrastructure

5681 - 70th Street

Edmonton, Alberta

T6B 3P6

For more information, please contact:

Terry Gibson

Executive Director

The Southeast Saskatchewan Airshed Association

Phone: (306) 371-2478

E-mail: [email protected]

Page 3: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

3

TABLE OF CONTENTS

MESSAGE FROM THE EXECUTIVE DIRECTOR ........................................................................................5

EXECUTIVE SUMMARY .......................................................................................................................7

1.0 INTRODUCTION ......................................................................................................................8

2.0 AIR QUALITY MONITORING ................................................................................................... 10

2.1 CONTINUOUS AIR QUALITY MONITORING ............................................................................................ 10

2.1.1 airpointer® ..................................................................................................................... 10

2.1.2 Wind............................................................................................................................... 12

2.1.3 Sulphur Dioxide .............................................................................................................. 14

2.1.4 Nitrogen Dioxide ............................................................................................................ 17

2.1.5 Ozone ............................................................................................................................. 20

2.1.6 Hydrogen Sulphide ......................................................................................................... 23

2.1.7 Fine Particulate Matter (PM2.5) ...................................................................................... 26

2.1.8 Air Quality Index (AQI) ................................................................................................... 28

2.1.9 Air Quality Health Index (AQHI) ..................................................................................... 30

2.2 PASSIVE MONITORING NETWORK....................................................................................................... 31

2.2.1 Sulphur Dioxide .............................................................................................................. 32

2.2.2 Nitrogen Dioxide ............................................................................................................ 34

2.2.3 Ozone ............................................................................................................................. 36

2.2.4 Hydrogen Sulphide ......................................................................................................... 38

2.2.5 Ammonia ....................................................................................................................... 40

2.2.6 Benzene, Toluene, Ethylbenzene, and Xylene (BTEX) .................................................... 41

3.0 AUDITED FINANCIAL STATEMENT .......................................................................................... 42

LIST OF TABLES

Table 1. Summary statistics for airpointer® monitoring data for 2012 ................................................ 11

Table 2. Summary statistics for continuous SO2 monitoring data for 2012 .......................................... 15

Table 3. Summary statistics for continuous NO2 monitoring data for 2012 ......................................... 18

Table 4. Summary statistics for continuous O3 monitoring data for 2012 ........................................... 21

Table 5. Summary statistics for continuous H2S monitoring data for 2012 .......................................... 24

Table 6. Summary statistics for continuous PM2.5 monitoring data for 2012 ....................................... 27

Table 7. AQI rating and effect description ............................................................................................ 28

Table 8. Summary of occurrence statistics for AQI rating .................................................................... 29

Table 9. Summary of occurrence statistics for AQHI rating .................................................................. 30

Table 10. Sample capture rates for the SESAA passive monitoring network ......................................... 31

Table 11. 30-Day average concentration for passive NH3 samples for 2012 .......................................... 40

Table 12. 30-Day average concentration for passive BTEX samples for 2012 ........................................ 41

Table 13. SESAA financial summary for the year of 2012 ....................................................................... 42

Page 4: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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LIST OF FIGURES

Figure 1. The ambient air quality monitoring network and airshed boundary for the Southeast

Saskatchewan Airshed Association ........................................................................................... 9

Figure 2. Wind rose charts for the SESAA continuous monitoring stations for 2012 ............................ 13

Figure 3. SO2 pollutant rose charts for the SESAA continuous monitoring station for 2012 ................. 16

Figure 4. NO2 pollutant rose charts for the SESAA continuous monitoring station for 2012 ................ 19

Figure 5. O3 pollutant rose charts for the SESAA continuous monitoring station for 2012 ................... 22

Figure 6. H2S pollutant rose charts for the SESAA continuous monitoring station for 2012 ................. 25

Figure 7. PM2.5 pollutant rose chart for the Weyburn station for 2012 ................................................. 27

Figure 8. AQHI rating and heath message .............................................................................................. 30

Figure 9. Passive SO2 monitoring results for the years from 2008 to 2012 ........................................... 32

Figure 10. Spatial distribution of passive SO2 concentration within the SESAA airshed zone ................. 33

Figure 11. Passive NO2 monitoring results for the years from 2008 to 2012 .......................................... 34

Figure 12. Spatial distribution of passive NO2 concentration within the SESAA airshed zone ................ 35

Figure 13. Passive O3 monitoring results for the years from 2008 to 2012 ............................................. 36

Figure 14. Spatial distribution of passive O3 concentration within the SESAA airshed zone ................... 37

Figure 15. Passive H2S monitoring results for the years from 2010 to 2012 ........................................... 38

Figure 16. Spatial distribution of passive H2S concentration within the SESAA airshed zone ................. 39

LIST OF APPENDICES

APPENDIX A. Saskatchewan Ambient Air Quality Standards

APPENDIX B. Weyburn Station: Continuous Monitoring Data

APPENDIX C. Glen Ewen Station: Continuous Monitoring Data

APPENDIX D. Weyburn Station: Exceedance Summary

APPENDIX E. Glen Ewen Station: Exceedance Summary

APPENDIX F. Passive Monitoring Data

APPENDIX G. 2012 Financial Statements

APPENDIX H. SESAA Board of Directors

APPENDIX I. SESAA Member Companies

Page 5: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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Message from the Executive Director

2012 has once again been a very exciting and busy year for the Association.

Plans were made to implement two continuous air quality monitoring stations in 2009. The

plan was to locate one air monitoring station in the Weyburn area and one in the southeastern

part of the region. SESAA has since installed these two continuous air monitoring stations and

plans to aggressively install additional air monitoring stations in the very near future. These

stations plus the passive monitoring network will provide high quality data and information

regarding regional air quality. The continuous data is available live on the internet; it includes

hourly concentrations of SO2, H2S, NO/NO2/NOx, PM2.5 and O3. The data was made available in

early 2011 on the SESAA website: http://www.sesaa.ca/AirQuality/index.php.

In the fall of 2011, the Association ordered a new airpointer® for March 2012 delivery. SESAA’s

Science Committee selected a site for the next airpointer®. It was purchased and placed in the

southeast part of the region near Glen Ewen. It has been operating since April 20, 2012. The

Science Committee developed its 5 year plan for the deployment of more continuous air

monitoring equipment. The SESAA Board will continue to look at ways of providing more and

better value and service to its members.

In the fall of 2011 the Board of Directors decided to make public presentations and events that

showcase SESAA and the members of SESAA a priority. To that end the Executive Director and

the Communications and Membership Committee hosted a Clean Air Day Workshop on June 6,

2012 in Estevan at the Saskatchewan Energy Training Institute. The Saskatchewan Ministry of

Environment, the Ministry of the Economy, the Canadian Association of Petroleum Producers

(CAPP) and others presented on topics regarding air quality. It was a successful workshop. The

presentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ

1280 Radio covered the Workshop and highlighted SESAA and the work we do.

On June 6, 2012 SESAA held its Annual General Meeting at the Saskatchewan Energy Training

Institute in Estevan immediately following the Clean Air Day Workshop.

The Governance Committee reviewed the SESAA bylaws and made revisions. They were

approved at the 2012 Annual General Meeting.

The Science Committee worked on a 5 year review of the SESAA passive data. There were

recommendations from the review for a different data collection protocol which was

implemented in 2012. The 5 year report is on the SESAA website.

SESAA had enjoyed very good Board of Director development in 2010 with the addition of some

key Directors. In 2012, we were actively seeking an even broader representation by soliciting

for new Board members in local newspapers and by asking specific organizations for their

Page 6: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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involvement. This has resulted in three new Board members: one from the City of Estevan and

two members of the public; one from Weyburn and one from Estevan. Please see the complete

list of the Board in Appendix F.

A great deal of effort has gone into securing sustainable funding and developing a fair and

equitable funding formula. 2012 saw a substantial improvement in the financial picture of the

Association as a result of additional memberships. The Saskatchewan Ministry of Environment

and the Saskatchewan Ministry of the Economy have made considerable steps to ensure

funding sustainability for the Airshed. SESAA thanks SaskPower, Saskatchewan Ministries of

Environment, the Economy and Health and all of our members for their support.

SESAA is proud to mention that we served on the Committee to help write the Industrial “Air”

Source Chapter of the new Saskatchewan Environmental Code. We have forged many new

relationships while working in this capacity.

Future plans include the placement of the next continuous air monitoring stations,

development of more communication materials, presentations to municipalities, Chambers of

Commerce, high school classes, home and school meetings, etc.

Our goal is to collect credible and defensible air quality data and provide excellent service to

our members.

Page 7: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

7

Executive Summary

The Southeast Saskatchewan Airshed Association (SESAA), established in October 2005, is

Saskatchewan’s first airshed association with a mandate to monitor ambient air quality in the

southeast region of the Province. SESAA is a collaborative group of industry, government, non-

government organizations, and private citizens. The airshed covers an area of 36,800 square

kilometres and includes 45 municipalities. Major economic activities in the region include

agriculture, oil & gas, mining, power generation, and transportation.

The SESAA ambient air quality monitoring network consists of two airpointers® at the Weyburn

and Glen Ewen stations, as well as a passive monitoring network. Both airpointers® measure

real-time data for SO2, H2S, NO/NO2/NOx, O3, ambient temperature, relative humidity,

accumulated precipitation, and wind speed/wind direction. The Weyburn airpointer® also

measures fine particulate matter (PM2.5). Real-time monitoring data of the airpointers® is

available on the SESAA website, which marks an important milestone in the SESAA’s

development. The passive network operated 30 stations until August 2013; it was then reduced

to 19 stations. The network measures 30-day average SO2, NO2, O3, and H2S. Passive NH3 and

BTEX (benzene, toluene, ethylbenzene, and xylene) were added after August.

The airpointers® were greater than 90% operational for the year of 2012, with the exception of

the Weyburn NOx analyzer for the months of June and July. Since June, the analyzer could not

measure ambient concentration correctly after the daily Automatic Instrument Check. The

affected data was tagged with a flag indicating it was invalid. The analyzer was taken offline for

factory repair on July 14 and resumed service on July 25.

The air quality at both airpointer® stations was within the Saskatchewan Ambient Air Quality

Standards (SAAQS), with the exception of hydrogen sulphide (H2S). According to the Air Quality

Index and Air Quality Health Index, the air quality was rated Good and Low Risk for more than

95% of the time at both stations. The Weyburn station detected 111 exceedance events for 1-

hour average H2S and 28 exceedance events for 24-hour average H2S. The exceedances were

associated with winds from the E-to-S (east to south) directions. It has yet to be determined if

the cause of H2S emissions are associated with localized industrial or natural sources. The Glen

Ewen station detected 8 exceedance events for 1-hour average H2S. As the number of

exceedance events was low, a source-receptor relationship has not yet been determined.

For the passive network, the sample capture rate was greater than 99% for all parameters. The

measured concentrations were low in comparison with the SAAQS. The maximum

concentrations for SO2, NO2, O3, H2S, and NH3 were 3.2 ppb, 10.2 ppb, 36 ppb, 1.8 ppb, and 1.9

ppb, respectively. The passive SO2 concentrations seemed to exhibit a spatial trend: higher

concentrations were detected in the central and southern part of the airshed zone, where more

industrial activities exist. There was no apparent spatial trend for passive NO2 and O3. The

measured benzene and toluene concentrations were less than 1 ppb. All ethylbenzene and

xylene samples were less than the method detection limit of 0.2 ppb.

Page 8: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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1.0 Introduction

The Southeast Saskatchewan Airshed Association (SESAA) was established in October 2005 to

manage ambient air quality in southeast Saskatchewan. The SESAA is a consortium of

government, industry, non-government organizations, and private citizen stakeholders. The

goal of the association is to collect credible, scientifically defensible air quality data for the

southeast region of Saskatchewan, and to make this data freely available to all stakeholders.

The SESAA objective is to bring together stakeholders from all backgrounds to identify local air

quality issues and to develop innovative solutions for managing these issues.

The Southeast Saskatchewan airshed is Saskatchewan’s first airshed. It covers an area of 36,800

square kilometres, including 45 municipalities. The airshed boundaries were established based

on common history, meteorology, and funding considerations. Major economic activities in the

region include agriculture, oil and gas, mining, power generation, and transportation.

Membership in the SESAA is currently voluntary. The current membership includes members of

the agriculture, oil & gas, mining and power generation sectors, as well as the public. The

Government of Saskatchewan Ministries of Environment, Energy & Resources, and Health, as

well as representatives of the City of Estevan and Rural Municipality of Enniskillen Number 3

also participate as members of the Board of Directors. SESAA’s operating budget consists of

membership fees, environmental footprint, and emissions-based fees assessed to facilities

operating within the airshed zone (Figure 1).

Page 9: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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Figure 1. The ambient air quality monitoring network and airshed boundary for the Southeast

Saskatchewan Airshed Association

Page 10: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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2.0 Air Quality Monitoring

2.1 Continuous Air Quality Monitoring

2.1.1 airpointer®

The Southeast Saskatchewan airshed operates two airpointers® at the Weyburn station and

Glen Ewen station. The Weyburn station is situated approximately 12 kilometres south of the

City of Weyburn, just east of highway 35. This station has been in place and operating since

March 2010. The Glen Ewen station started operations in May 2012. This station is situated

approximately 2 km southeast of the Village of Glen Ewen, and approximately 0.5 km south of

highway 18. Real-time air monitoring data is available on the SESAA website at: www.sesaa.ca.

The airpointer® introduces a new concept in air quality monitoring. In the past, a multi-gas and

particle pollution monitoring system would have been housed in a large walk-in shelter;

sometimes in a trailer-type unit. The airpointer® makes it possible to acquire real-time data in a

small vault type, self-contained unit. The airpointer® has very low operating costs compared to

other analyzers in the industry. This is important to our members because we can provide

quality data collection at a considerable saving. Furthermore, it is easy to access the monitoring

data. A standard internet connection and web browser is all that is required.

The airpointer® measures a wide variety of pollutants. Both SESAA airpointer® stations measure

SO2, H2S, NO/NO2/NOX, O3, and meteorological parameters including ambient temperature,

relative humidity, precipitation, wind speed and wind direction. The Weyburn airpointer® also

monitors fine particulate matter (PM2.5). These parameters can be used to calculate hourly Air

Quality Index (AQI) and Air Quality Health Index (AQHI).

Table 1 summarizes the annual statistics for 1-hour average measurements for the SESAA air

monitoring network. The annual uptime was greater than 90% for all analyzers. The measured

concentrations were lower than the applicable Saskatchewan Ambient Air Quality Standards

(SAAQS, Appendix A), with the exceptions for H2S. Please refer to the following Sections for

detailed monitoring results.

Page 11: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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Table 1. Summary statistics for airpointer® monitoring data for 2012

Station Monitoring

Parameters

Conc.

Unit

Annual

Average

Conc.

Percentage

Instrument

Uptime

Maximum Conc. and Occurrence Time

1-hour Max. 24-hour Max.

Conc. Time Conc. Date

Weyburn

NO ppb 1.5 95.5% 17.5 Mar-28 13:00 3.4 Dec-20

NO2 ppb 2.5 95.5% 15.9 Mar-28 13:00 8.8 Nov-18

NOx ppb 4.0 95.5% 33.4 Mar-28 13:00 11.8 Dec-20

SO2 ppb 2 99.9% 38 Aug-22 06:00 10 Dec-27

O3 ppb 29 99.9% 68 Sep-28 17:00 45 Jun-8

H2S ppb 2.1 99.9% 92.3 Mar-22 00:00 8.5 Nov-13

PM2.5 µg/m3 4 100.0% 62 Jul-13 09:00 45 Jul-13

Glen Ewen

NO ppb 0.7 98.9% 17.9 May-30 00:00 2.3 Dec-31

NO2 ppb 2.7 98.9% 23.9 Jun-03 23:00 9.0 Nov-17

NOx ppb 3.4 98.9% 34.0 May-30 00:00 10.5 Nov-17

SO2 ppb 2 98.7% 35 Nov-23 16:00 6 Dec-25

O3 ppb 28 99.0% 70 Aug-28 19:00 45 Jun-8

H2S ppb 0.7 97.2% 33.9 Dec-10 07:00 2.9 Jul-1

Page 12: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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2.1.2 Wind

Wind plays an important role in the transportation and dilution of air pollutants. Wind speed

and wind direction are main factors that influence regional air quality. The diffusion and

dispersion of emissions are greatly impacted by variations in wind speed and corresponding air

turbulence.

Figure 2 presents the wind roses for the Weyburn and Glen Ewen stations. At the Weyburn

station, prevailing wind was from the E-to-SE (east to southeast) and WSW-to-WNW (west-

northwest to west-southwest) directions. According to the international wind classification

chart, the wind consisted of 19% Light Air (<1.4 m/s), 35% Light Breeze (<3.1 m/s), and 40%

Moderate Breeze (<7.8 m/s). Stronger winds (>7.8 m/s) were primarily from the prevailing wind

directions.

At the Glen Ewen station, prevailing wind was from the E-to-SE (east to southeast) and W-to-

NNW (west to north-northwest) directions. The wind consisted of 20% Light Air, 37% Light

Breeze, and 39% Moderate Breeze. Stronger winds (>7.8 m/s) were primarily from the

prevailing wind directions.

The detail frequency distribution tables are presented in Appendix B: Table B-12 and Appendix C:

Table C-11.

Page 13: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

13

Figure 2. Wind roses for the SESAA continuous monitoring stations for 2012

(a) Weyburn Station

0%

5%

10%

15%

20%

N

E

S

W

Calm (<0.3 m/s) = 0.8%

(b) Glen Ewen Station

0%

5%

10%

15%

20%

N

E

S

W

> 13.6

10.6 - 13.6

7.8 - 10.6

3.1 - 7.8

1.4 - 3.1

0.3 - 1.4

Wind Speed Class (m/s)

Calm (<0.3 m/s) = 2.0%

Page 14: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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2.1.3 Sulphur Dioxide

Sulphur dioxide (SO2) is a colourless gas with a strong suffocating odour. It smells like burnt

matches. At concentrations above 300 ppb, it can be detected by taste and odour. The health

effects caused by exposure to high levels of SO2 include breathing problems, respiratory illness,

changes in lung function, and worsening respiratory and cardiovascular disease. People with

asthma or chronic lung or heart disease are the most susceptible to SO2. SO2 also damages

trees and crops.

SO2, along with nitrogen oxides, are the main precursors of photochemical smog and acid rain,

which contributes to the acidification of lakes and streams, accelerated corrosion of buildings,

and reduced visibility. SO2 in the air can form microscopic acid aerosols, which have serious

health implications, as well as, contributing to climate change.

Anthropogenic SO2 emission sources are primarily from combustion of sulphur containing fuels

(e.g. gasoline, natural gas and coal) and processing of sulphur containing ores. The major

emission sources for SO2 include large industrial sources such as power plants, petroleum

refineries, iron and steel mills, fertilizer plants, pulp and paper mills, and smelters, as well as

small industries, such as small oil and gas plants, battery and well flares.

The Saskatchewan Ambient Air Quality Standards (SAAQS) for sulphur dioxide are:

• 0.17 ppm (172 ppb) averaged over a 1-hour period;

• 0.06 ppm (57 ppb) averaged over a 24-hour period; and

• 0.01 ppm (11 ppb) as an annual arithmetic average.

Table 2 summarizes the monthly statistics for SO2 monitoring data. The instrument uptime was

greater than 90% throughout this year. The annual average uptime was 99.9% and 98.7% at

the Weyburn and Glen Ewen stations, respectively.

The measured concentration was quite low at both stations, in comparison with the SAAQS.

There was no exceedance of 1-hour or 24-hour SAAQS in 2012. The annual average

concentration of 2 ppb was lower than the annual SAAQS. The monthly average concentrations

ranged from 2 ppb to 4 ppb. There was no significant monthly or seasonal trend. The maximum

1-hour concentrations were 38 ppb and 35 ppb at the Weyburn and Glen Ewen stations

respectively. The maximum 24-hour concentrations were 10 ppb and 6 ppb, respectively.

Figure 3 presents the pollutant roses for 1-hour average concentration of SO2. At the Weyburn

station, the high concentration petals (>10 ppb) generally indicate that sources are located in

the E-to-S (east to south) directions, where more industrial activities exist, such as coal-fired

power plants and upstream oil and gas industry. At the Glen Ewen station, the high

concentration petals (>10 ppb) generally indicate that sources are located in the W-to-NW

Page 15: 2012 Annual Report - SESAApresentations are all posted on the SESAA website. The Estevan Mercury Newspaper and CJ 1280 Radio covered the Workshop and highlighted SESAA and the work

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(west to northwest) directions, where more industrial activities exist, such as upstream oil and

gas industry.

The detailed frequency distribution table for the pollutant rose is presented in Appendix B:

Table B-2 and Appendix C: Table C-2.

Table 2. Summary statistics for continuous SO2 monitoring data for 2012

Month

of 2012

Instrument Average Maximum 1-Hour Maximum 24-Hour

Station Uptime Conc. 1-Hr Conc. Exceedance 24-Hr Conc. Exceedance

(%) (ppb) (ppb) (no.) (ppb) (no.)

Weyburn

January 100.0% 2 20 0 5 0

February 100.0% 2 27 0 7 0

March 100.0% 2 26 0 6 0

April 100.0% 2 23 0 5 0

May 100.0% 2 28 0 6 0

June 99.9% 2 17 0 5 0

July 99.7% 2 14 0 4 0

August 100.0% 2 38 0 6 0

September 99.9% 2 29 0 6 0

October 99.7% 2 25 0 5 0

November 100.0% 3 24 0 6 0

December 99.9% 4 35 0 10 0

Annual 99.9% 2 38 0 10 0

Glen Ewen

May 97.6% 2 29 0 4 0

June 93.2% 2 9 0 4 0

July 99.9% 2 11 0 3 0

August 99.9% 2 24 0 4 0

September 99.9% 2 25 0 4 0

October 99.9% 2 19 0 4 0

November 99.9% 2 35 0 5 0

December 99.7% 3 19 0 6 0

Annual 98.7% 2 35 0 6 0

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Figure 3. SO2 pollutant roses for the SESAA continuous monitoring stations for 2012

(a) Weyburn Station

0%

5%

10%

15%

20%

N

E

S

W

(b) Glen Ewen Station

0%

5%

10%

15%

20%

N

E

S

W

> 172

57 - 172

10 - 57

5 - 10

1 - 5

0 - 1

Concentration Class (ppb)

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2.1.4 Nitrogen Dioxide

Nitrogen oxides, also known as oxides of nitrogen (NOX), is a collective term for nitric oxide

(NO) and nitrogen dioxide (NO2). Nitric oxide is a colorless, flammable gas with a slight odour.

Nitrogen dioxide is a reddish brown, non-flammable gas with a pungent irritating odour. NO2 is

of more interest than NO from both a health and acid rain perspective.

NOX can cause respiratory disease, damage vegetation, and reduce visibility. The primary

concern with NOX emissions is their contribution to formation of ground-level ozone, smog and

acid rain. To a lesser extent, some NOX compounds (e.g. N2O) contribute to stratospheric ozone

layer depletion and global warming.

NOX emissions are mainly produced by fossil fuel combustion. High temperature conditions

during combustion result in the formation of NOX as a by-product. The major anthropogenic

emission sources for NOX are associated with fuel combustion, including both stationary

sources, such as power plants, oil and gas industries, incinerators, as well as mobile sources

such as automobiles. Non-combustion sources, for example nitric acid manufacture, welding

processes and the use of explosives, comprise the smaller emission sources. In large cities,

motor vehicle emission is the major source of NOX.

The Saskatchewan Ministry of Environment regulates ambient air concentration for nitrogen

dioxide. The Saskatchewan Ambient Air Quality Standards for nitrogen dioxide are:

• 0.2 ppm (212 ppb) averaged over a 1-hour period; and

• 0.05 ppm (53 ppb) as an annual arithmetic average.

Table 3 summarizes the monthly statistics for continuous NO2 monitoring data. The instrument

was greater than 90% operational at both stations with the exception of June and July at the

Weyburn station. In June and July, the NOx analyzer was experiencing a slow recovery time,

taking longer than usual to correctly measure ambient air concentration following the daily

Automatic Instrument Check (AIC). As such, the affected data was tagged with a flag indicating

the data was invalid. The analyzer was taken offline for factory repair on July 14 and resumed

service on July 25.

The measured NO2 concentration was low in comparison with the SAAQS. There was no

exceedance of the 1-hour SAAQS in 2012. The annual average concentrations were 2.5 ppb and

2.7 ppb at the Weyburn and Glen Ewen stations. The monthly average concentrations ranged

from 1.7 ppb to 4.1 ppb. There was no significant monthly or seasonal trend. The maximum 1-

hour average concentrations were 15.9 ppb and 23.9 ppb at the Weyburn and Glen Ewen

stations. The maximum 24-hour average concentrations were 8.8 ppb and 8.9 ppb, respectively.

Figure 4 presents the pollutant roses for 1-hour average NO2. The measured concentration was

low; approximately 91% of the data was less than 5 ppb (the blue color petals). The remaining

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9% of data fell between 5 ppb and 15 ppb. At the Weyburn station, the higher concentration

data tended to be associated with the E-to-SE (east to southeast) directions. At the Glen Ewen

station, the higher concentration data tended to be associated with the W-to-NNW (north to

north-northwest) directions. The direction trends were aligned with the area where more

industrial activities exist such as upstream oil and gas industry and/or coal-fired power plants.

The detailed frequency distribution table for the NO2 pollutant roses are presented in Appendix

B: Table B-4, and Appendix C: Table C-4. The tables for NO and NOx are in Tables B-3, B-5, and

Tables C-3, C-5.

Table 3. Summary statistics for continuous NO2 monitoring data for 2012

Month

of 2012

Instrument Average Maximum 1-Hour Maximum

Station Uptime Conc. 1-Hr Conc. Exceedance 24-Hr Conc.

(%) (ppb) (ppb) (no.) (ppb)

Weyburn

January 100.0% 2.0 13.8 0 5.0

February 100.0% 2.6 12.6 0 5.8

March 99.9% 2.4 15.9 0 5.6

April 99.9% 1.7 6.8 0 3.6

May 99.9% 1.7 12.5 0 4.0

June 87.4% 2.1 9.3 0 4.1

July 60.3% 2.2 11.0 0 4.1

August 100.0% 2.1 8.0 0 2.9

September 99.9% 2.2 10.6 0 3.7

October 99.9% 2.4 12.1 0 4.8

November 99.7% 3.9 15.7 0 8.8

December 99.6% 4.1 15.8 0 8.5

Annual 95.5% 2.5 15.9 0 8.8

Glen Ewen

May 100.0% 2.3 16.1 0 4.3

June 92.9% 2.7 23.9 0 6.7

July 99.3% 1.9 9.2 0 2.4

August 99.6% 2.2 13.5 0 3.7

September 100.0% 2.7 10.6 0 3.9

October 99.9% 2.5 9.9 0 4.7

November 99.7% 3.7 19.0 0 9.0

December 99.5% 3.5 13.5 0 5.8

Annual 98.9% 2.7 23.9 0 9.0

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Figure 4. NO2 pollutant roses for the SESAA continuous monitoring stations for 2012

(a) Weyburn Station

0%

5%

10%

15%

20%

N

E

S

W

(b) Glen Ewen Station

0%

5%

10%

15%

20%

N

E

S

W

> 212

100 - 212

30 - 100

15 - 30

5 - 15

0 - 5

Concentration Class (ppb)

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2.1.5 Ozone

Ozone (O3) is a pale blue gas, slightly soluble in water. Most people can detect a sharp odour

resembling chlorine bleach at about 10 ppb concentration. Ozone can be formed by electrical

discharges and high energy electromagnetic radiation. In the indoor environments, ozone can

be present as a result of electronic equipment such as ionic air purifiers, laser printers,

photocopiers, and arc welders.

In the ambient air, O3 is a “secondary” pollutant, meaning it is not directly emitted from a

source. Instead, ozone is produced from photochemical reactions between oxides of nitrogen

(NOX) and volatile organic compounds (VOC) in the presence of sunlight. Some research

suggests that ground-level ozone could be from intrusion of ozone from the stratosphere,

mixing from the upper troposphere, local photochemistry and the medium and long-range

transport. There are split opinions regarding relative importance of these mechanisms. A study

in Regina suggested that high ozone events could be due to downward transport from the

stratosphere for the reviewed data.

Exposure to ozone has been linked to premature mortality and a range of morbidity health end-

points, such as hospital admissions and asthma symptoms. Acute exposure to high

concentrations of ozone can cause eye irritation and breathing difficulty. Ozone can

significantly impact vegetation and decrease the productivity of some crops. It damages cotton,

acetate, nylon, polyester and other textile materials. Ozone can also damage other synthetic

materials, cause cracks in rubber, accelerate fading of dyes, and speed deterioration of some

paints and coatings.

The Saskatchewan ambient air quality standard for ozone is:

• 0.08 ppm (82 ppb) averaged over a 1-hour period;

The Canada-Wide Standard (CWS) for ozone is:

• 65 ppb averaged over an 8-hour period (the achievement statistics is based on the

fourth highest measurement annually averaged over three consecutive years).

Table 4 summarizes the monthly statistics for O3 monitoring data. The instrument uptime was

greater than 90% throughout this year. The annual average uptime was 99.9% and 99.0% at

the Weyburn and Glen Ewen stations, respectively.

There was no exceedance of the SAAQS for 1-hour averages at both stations. The monthly

average concentrations ranged from 26 ppb to 35 ppb. The data seemed to exhibit a seasonal

trend, with high O3 concentration occurring in the spring and summer. The maximum 1-hour

average concentration of 68 ppb (Weyburn) and 71 ppb (Glen Ewen) were detected in

August/September. The 4th

highest concentration of 8-hour running average was 62 ppb at

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21

both stations, which is less than the CWS standard (note: exceedance evaluation for the CWS

standard is based on the average of three consecutive years).

Figure 5 presents the pollutant roses for 1-hour average concentration of O3. The pollutant

roses did not show a directional trend for high concentration events. The detailed frequency

distribution table for the pollutant roses are presented in Appendix B: Table B-6, and Appendix C:

Table C-6.

Table 4. Summary statistics for continuous O3 monitoring data for 2012

Month

of 2012

Instrument Average Maximum 1-Hour Maximum

Station Uptime Conc. 1-Hr Conc. Exceedance 24-Hr Conc.

(%) (ppb) (ppb) (no.) (ppb)

Weyburn

January 100.0% 26 38 0 35

February 100.0% 26 42 0 36

March 100.0% 32 54 0 42

April 100.0% 34 57 0 41

May 100.0% 35 61 0 45

June 99.9% 32 63 0 45

July 99.7% 30 66 0 40

August 100.0% 31 68 0 45

September 99.9% 30 68 0 40

October 99.9% 21 44 0 33

November 100.0% 25 40 0 36

December 99.9% 26 41 0 34

Annual 99.9% 29 68 0 45

Glen Ewen

May 100.0% 32 63 0 44

June 93.2% 31 66 0 45

July 99.9% 28 66 0 39

August 99.9% 28 70 0 43

September 100.0% 28 65 0 39

October 99.9% 22 48 0 34

November 99.9% 26 43 0 38

December 99.6% 26 40 0 34

Annual 99.0% 28 70 0 45

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Figure 5. O3 pollutant roses for the SESAA continuous monitoring stations for 2012

(a) Weyburn Station

0%

5%

10%

15%

20%

N

E

S

W

(b) Glen Ewen Station

0%

5%

10%

15%

20%

N

E

S

W

> 82

60 - 82

40 - 60

20 - 40

10 - 20

0 - 10

Concentration Class (ppb)

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2.1.6 Hydrogen Sulphide

Hydrogen sulphide (H2S) is a colourless gas with a characteristic “rotten egg” odour. It is

produced both naturally and through anthropogenic emission sources. H2S occurs naturally in

coal, crude oil, natural gas, oil, sulphur hot springs, volcanic gases, sloughs, swamps and lakes.

The major anthropogenic emission sources include natural gas and petroleum production,

wastewater treatment, pulp and paper mills, rayon textile manufacturing, and tar and asphalt

manufacturing. Decomposition of organic matter by bacteria under anaerobic conditions

releases H2S as well, forming the characteristic odour commonly associated with sewers,

sewage lagoons, and swamps.

Hydrogen sulphide is an acutely toxic gas at high levels. Exposure to hydrogen sulphide can

irritate the eyes, nose, throat, and lungs and can cause serious health effects, including death.

The Saskatchewan Ambient Air Quality Standards for hydrogen sulphide are:

• 10.8 ppb averaged over a 1-hour period; and

• 3.6 ppb averaged over a 24-hour period;

Table 5 summarizes the monthly statistics for continuous H2S monitoring data. The instrument

uptime was greater than 90% throughout this year at both stations.

The measured H2S concentration at both stations was lower than the SAAQS for the majority of

the time. However, there were occasional spikes causing exceedances of the 1-hour and 24-

hour SAAQS. At the Weyburn station, there were a total of 111 hours (or 1.3% of the total

monitoring hours) and 28 days when average H2S concentrations exceeded the SAAQS. The

maximum 1-hour and 24-hour average concentrations were 92.3 ppb and 8.5 ppb, respectively.

A complete list of the exceedance events can be found in Appendix D.

There were eight exceedance events for 1-hour average H2S at the Glen Ewen station, while all

the 24-hour averages were within the SAAQS. The maximum 1-hour and 24-hour average

concentrations were 33.9 ppb and 2.9 ppb, respectively. A complete list of the exceedance

events can be found in Appendix E.

Figure 6 presents the pollutant roses for 1-hour average concentration of H2S. At both stations,

H2S concentration was less than 3.6 ppb the majority of the time. The red petals represent the

concentration data exceeding the 1-hour SAAQS. At the Weyburn station, the exceedances

were primarily (93% of the exceedance events) associated with the E-to-S (east to south)

directions. The projected area is where more industrial activities exist, such as upstream oil and

gas industry. Eighty-six percent (86%) of the exceedance events were detected during light

wind conditions (<1.4 m/s). It has yet to be determined if the cause of H2S emissions are related

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to localized industrial or biogenic sources. Further investigation is warranted by SESAA’s Science

Committee.

At the Glen Ewen station, the red petals are not visible due to a small number of the

exceedance events. The exceedance events were associated with a number of wind directions.

It has yet been determined if a spatial trend was existent with the high concentration events.

The detailed frequency distribution table for the pollutant roses are presented in Appendix B:

Table B-7 and Appendix C: Table C-7.

Table 5. Summary statistics for continuous H2S monitoring data for 2012

Month

of 2012

Instrument Average Maximum 1-Hour Maximum 24-Hour

Station Uptime Conc. 1-Hr Conc. Exceedance 24-Hr Conc. Exceedance

(%) (ppb) (ppb) (no.) (ppb) (no.)

Weyburn

January 100.0% 1.1 15.3 5 2.9 0

February 100.0% 2.1 33.4 22 8.1 5

March 100.0% 1.8 92.3 9 5.1 2

April 100.0% 1.5 10.5 0 3.0 0

May 100.0% 1.6 26.7 7 3.6 0

June 99.9% 1.9 11.8 1 3.0 0

July 99.7% 2.6 28.9 8 5.5 2

August 100.0% 2.9 60.6 19 5.3 6

September 99.7% 2.5 20.9 7 5.0 3

October 99.7% 2.2 16.8 9 4.9 2

November 100.0% 2.4 22.9 14 8.5 3

December 99.6% 2.7 32.4 10 6.0 5

Annual 99.9% 2.1 92.3 111 8.5 28

Glen Ewen

May 100.0% 0.2 6.3 0 0.4 0

June 93.2% 0.5 17.5 1 1.4 0

July 99.9% 1.1 12.1 1 2.9 0

August 99.9% 1.0 17.5 3 2.3 0

September 98.9% 1.1 12.9 2 2.2 0

October 93.7% 0.5 7.1 0 1.9 0

November 96.4% 0.6 5.5 0 2.4 0

December 96.0% 0.7 33.9 1 2.0 0

Annual 97.2% 0.7 33.9 8 2.9 0

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25

Figure 6. H2S pollutant rose charts for the SESAA continuous monitoring station for 2012

(a) Weyburn Station

0%

5%

10%

15%

20%

N

E

S

W

(b) Glen Ewen Station

0%

5%

10%

15%

20%

N

E

S

W

> 10.8

8 - 10.8

5 - 8

3.6 - 5

1 - 3.6

0 - 1

Concentration Class (ppb)

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2.1.7 Fine Particulate Matter (PM2.5)

Particulate matter is unique among air pollutants, as it is identified by its size rather than by its

composition. The major concern for particulate matter deals with small particles referred to as

inhalable particulate, or PM10. PM10 is defined as particles that have an aerodynamic diameter

less than 10 microns (or 0.01 mm). PM10 can be divided into two groups of particles based on

size: fine particles and coarse particles. The fine particles are those particles with an

aerodynamic diameter smaller than 2.5 microns (0.0025 mm) and are identified as PM2.5. In

contrast, coarse particles are those with aerodynamic diameter greater than 2.5 microns and

less than 10 microns.

Fine particles are generally emitted from activities such as industrial and residential

combustion, and from vehicle exhaust. Fine particles are also formed in the atmosphere when

gases such as sulphur dioxide, nitrogen oxides, and volatile organic compounds, emitted by

combustion activities, are transformed by chemical reactions in the air.

Adverse health effects from breathing air with a high PM2.5 concentration include: premature

death, increased respiratory symptoms and disease, chronic bronchitis, and decreased lung

function particularly for individuals with asthma. Particulate matter can clog stomatal openings

of plants and interfere with photosynthesis functions, leading to growth stunting or mortality in

some plant species.

Saskatchewan endorses the Canada-Wide Standards (CWS) for fine particulate matters (PM2.5):

• 30 µg/m3 averaged over a 24-hour period from midnight to midnight; the standard is

based on the 98th

percentile annually, averaged over three consecutive years.

Table 6 summarizes the summary statistics for continuous PM2.5 monitoring data. The

instrument uptime was greater than 99% throughout the year. The monthly average

concentrations for 1-hour average PM2.5 ranged from 1 µg/m3 to 10 µg/m

3. The maximum 1-

hour and 24-hour average concentration of 62 µg/m3 and 45 µg/m

3 were detected in July,

which were potentially due to wildfire smoke. The maximum 24-hour average was higher than

the CWS of 30 µg/m3. This event did not comprise an exceedance because the CWS is based on

the 98th

percentile of annual measurements, averaged over three consecutive years. The 98th

percentile for 24-hour PM2.5 was 15 µg/m3

for this year.

The 1-hour average PM2.5 data exhibited a seasonal trend. Between June and September, 60%

of the data was greater than the annual average of 4 µg/m3

. The percentage was significantly

higher than the remaining months (7% to 28%) indicating extraordinary source or

environmental factors were existent leading to an increased concentration. Wildfire smoke

could be one of the potential causes. Between June and September, the SESAA airshed zone

was occasionally affected by wildfire smoke. A number of high concentration events were

detected. On the other hand, the lower particulate concentration during winter and spring

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seasons might be related to environmental factors, e.g. snow covering or rain washout would

suppress dust suspension.

Figure 7 presents the pollutant rose for 1-hour average concentration of PM2.5. Generally, the

high concentration events (e.g. >10 µg/m3

in the yellow, orange and red petals) were detected

from all wind directions. There was no significant directional trend. The detailed frequency

distribution table for the pollutant rose is presented in Appendix B, Table B-8.

Table 6. Summary statistics for continuous PM2.5 monitoring data for 2012

Month

of 2012

Instrument Average Maximum Maximum 24-Hour

Station Uptime Conc. 1-Hr Conc. 24-Hr Conc. Exceedance

(%) (ppb) (ppb) (ppb) (no.)

Weyburn

January 100.0% 1 7 5 0

February 100.0% 2 13 7 0

March 100.0% 3 41 13 0

April 100.0% 2 10 6 0

May 100.0% 3 18 8 0

June 99.9% 5 48 25 0

July 99.7% 10 62 45a 0

August 100.0% 7 48 13 0

September 100.0% 6 55 17 0

October 99.9% 3 16 9 0

November 100.0% 3 17 10 0

December 100.0% 8 48 14 0

Annual 100.0% 4 62 45a 0

a. The event does not comprise an exceedance because the CWS is based on 98th percentile of annual measurement,

averaged over three consecutive years. The 98th

percentile concentration for 24-hour PM2.5 was 15 µg/m3 for 2012.

Figure 7. PM2.5 pollutant rose chart for the Weyburn station for 2012

0%

5%

10%

15%

20%N

E

S

W

> 30

20 - 30

10 - 20

5 - 10

2 - 5

0 - 2

Concentration Class (ppb)

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2.1.8 Air Quality Index (AQI)

The Air Quality Index (AQI) is a system developed to provide the public with a meaningful and

comparable measure of outdoor air quality. The AQI uses readings from five major air

pollutants: SO2, NO2, O3, PM2.5, and carbon monoxide (CO), to calculate the AQI. A minimum of

three pollutants is required to calculate AQI. The AQI is rated in four categories: Good (0 to 25),

Fair (26 to 50), Poor (51 to 100), and Very Poor (>100). Table 7 summarizes the effects

associated with the AQI ratings.

Table 8 summarizes the occurrence hours and frequency by the AQI rating for the SESAA

continuous monitoring stations. The Weyburn AQI is calculated based on SO2, NO2, O3, and

PM2.5, as the airpointer® does not measure CO. The Glen Ewen AQI is calculated from SO2, NO2,

and O3, as the airpointer® does not measure CO or PM2.5.

The air quality at the Weyburn station was rated Good for 95.0% of the time and Fair 5.0% of

the time. In 2012, the AQI rating never fell in the Poor or Very Poor categories. During the

winter months, the AQI rating was always Good, while Fair air quality occurred between March

and September.

The air quality at the Glen Ewen station was rated Good for 96.0% of the time and Fair 4.0% of

the time. The AQI rating never fell in the Poor or Very Poor categories. In the winter months,

the AQI was rated Good, while Fair air quality occurred between May and September (note:

Glen Ewen station started operations on May 1).

Table 7. AQI rating and effect description

AQI Air Quality Rating Effect Description

0 – 25 Good

Desirable Range: No known harmful effects to soil, water,

vegetation, animals, materials, visibility or human health. The

long-term goal is for air quality to be in this range all of the time

in Canada.

26 – 50 Fair

Acceptable Range: Adequate protection against harmful effects

to soil, water, vegetation, animals, materials, visibility and human

health.

51 – 100 Poor

Tolerable Range: Not all aspects of human health or the

environment are adequately protected from possible adverse

effects. Long-term control action may be necessary, depending

on the frequency, duration and circumstances of the readings.

>100 Very Poor Intolerable Range: Continued high readings could pose a risk to

public health.

Source: Clean Air Strategic Alliance (CASA) - www.casadata.org/airqualityindex/aqi/whatis.asp

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Table 8. Summary of occurrence statistics for AQI rating

Monitoring

Station Occurrence Statistics

Number of Occurrence Hours and Frequency by AQI Rating

Good Fair Poor Very Poor

Weyburn Occurrence Hours 8304 435 0 0

Occurrence Frequency 95.0% 5.0% 0.0% 0.0%

Glen Ewen Occurrence Hours 5530 231 0 0

Occurrence Frequency 96.0% 4.0% 0.0% 0.0%

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2.1.9 Air Quality Health Index (AQHI)

The Air Quality Health Index (AQHI) is a health protection tool that is designed to help the

public make decisions to protect their health by limiting short-term exposure to air pollution,

and adjusting their activity levels during increased levels of air pollution. The AQHI uses

readings from three air pollutants to calculate a single numerical value as the indicator of

health risk. The three pollutants are fine particulate matter (PM2.5), nitrogen dioxide (NO2), and

ground-level ozone (O3). All three pollutants are required to calculate the AQHI. Figure 8

summarizes the AQHI rating and the health messages for the at-risk population and the general

population. The health risk is classified in categories by AQHI: Low Risk (1 to 3), Moderate Risk

(4 to 6), High Risk (7 to 10), and Very High Risk (higher than 10).

Only the Weyburn station was eligible for AQHI reporting. The Glen Ewen station does not

record the PM2.5 parameter. Table 9 summarizes the occurrence statistics for AQHI rating. For

98.6% of the time, the air quality was rated Low Risk; and 1.4% was rated Moderate Risk.

Moderate Risk rating was reported between May and September.

Figure 8. AQHI rating and heath message

Source: http://www.ec.gc.ca/cas-aqhi/default.asp?lang=En&n=79A8041B-1

Table 9. Summary of occurrence statistics for AQHI rating

Occurrence Statistics Number of Occurrence Hours and Frequency by AQHI Rating

Low Risk Moderate Risk High Risk Very High Risk

Occurrence Hours 8254 118 0 0

Occurrence Frequency 98.6% 1.4% 0.0% 0.0%

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2.2 Passive Monitoring Network

The SESAA passive monitoring program was initiated in June 2006. The objective of this

program was to collect scientifically credible air quality data for the airshed zone. The passive

monitoring network consists of 30 sampling stations, as shown in Figure 1. Among the 30

sampling stations, the two ATCO stations (No. 29 and No. 30) are in close proximity to the

Kisbey facility of the ATCO Midstream Limited for near-source monitoring; while the remaining

28 passive stations are selected for receptor and/or environmental monitoring. The AEMC

Multi-Gas Passive Samplers (MGPS) have been used in the SESAA passive monitoring program

since 2008.

The passive network was revised on August 2012. The original network included 30 stations for

SO2, 28 stations for NO2, 12 stations for O3, and 2 stations for H2S. From August, SO2, NO2, and

O3 were reduced to 15, 9, and 9 stations, respectively. H2S was increased to 6 stations. The

revised passive network added NH3 at the Creelman station (No. 20) and BTEX at the Macoun

(No. 8) and Oxbow (No. 11) stations.

The SESAA passive sampling program includes QA/QC samples to warrant the data quality. In

addition to the formal passive samples for ambient air quality monitoring, one field blank and

one replicate sample was collected each month. The field blank sample monitors filter

contamination that could be introduced during sample shipment/collection/deployment and

laboratory processes. The replicate sample is used to quantify sample variability during the

sampling and analytical procedures.

Table 10 summarizes the sample capture rate for the year of 2012. There was only one failure

sample in July due to a damaged MGPS. The sample capture rate was greater than 99% for all

parameters. The detailed passive monitoring results are presented in Appendix F.

Table 10. Sample capture rates for the SESAA passive monitoring network

Pollutant

No. of Stations Number of Valid Passive Samples (no.) Capture

Rate

(%) Before

Aug.

After

Aug. Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

SO2 30 15 30 30 30 30 30 30 29 15 15 15 15 15 99.6%

NO2 28 9 28 28 28 28 28 28 27 9 9 9 9 9 99.6%

O3 12 9 12 12 12 12 12 12 11 9 9 9 9 9 99.2%

H2S 2 6 2 2 2 2 2 2 2 6 6 6 6 6 100.0%

NH3 0 1 - - - - - - - 1 1 1 1 1 100.0%

BTEX 0 2 - - - - - - - 2 2 2 2 2 100.0%

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2.2.1 Sulphur Dioxide

Figure 9 presents the 30-day average concentration for the passive SO2 network for the years

from 2008 to 2012. The concentrations within the airshed zone were quite low in comparison

to the SAAQS. There was no exceedance of the annual SAAQS (11 ppb) during the past five

years. The chart seems to show a seasonal trend that SO2 concentration was higher in winter

and early spring. In addition, it seemed to exhibit a deceasing trend over the past five years for

most months. More data is needed to validate the trends.

Figure 10 presents a bubble chart showing spatial distribution of the annual average

concentration for passive SO2. The two sampling stations near the Kisbey facility of the ATCO

Midstream Limited detected the highest concentrations of 1.2 ppb and 1.7 ppb, likely due to a

close proximity of the emission sources. For the remaining passive stations, the concentration

range was between 0.1 ppb to 0.4 ppb. Although the range of concentration was small, a spatial

trend seemed to be existent. The higher concentrations sites tended to be primarily situated in

the southern and central parts of the airshed. In this area, more industrial activities are

operating, such as coal-fired power plants and upstream oil and gas industry. In contrast, lower

concentrations were observed in the northern part of the airshed, where there is less industrial

activity.

The measured 30-day average concentrations ranged from <0.1 ppb to 3.2 ppb. Please refer to

Table F-1 for the concentrations of individual samples.

Figure 9. Passive SO2 monitoring results for the years from 2008 to 2012

0.0

1.0

2.0

3.0

4.0

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

30

-Da

y A

ve

rag

e C

on

c. f

or

Pa

ssiv

e S

O2

(pp

b)

2008 2009 2010 2011 2012

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33

Figure 10. Spatial distribution of passive SO2 concentration within the SESAA airshed zone

0.20.40.30.4

0.40.2

0.40.2 0.4

0.4 0.2 0.4

0.30.2

0.30.40.30.3

0.4

0.30.3

0.4 0.2

0.40.30.3

0.1

0.3

1.21.7

SESAA Passive SO2 Network 2012

Annual Average Conc. in ppb

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2.2.2 Nitrogen Dioxide

Figure 11 presents the 30-day average concentrations for the passive NO2 network for the years

from 2008 to 2012. NO2 concentration within the airshed zone was quite low in comparison to

the SAAQS. There was no exceedance of the annual SAAQS (53 ppb) during the past five years.

The chart does not show an apparent monthly or seasonal trend.

Figure 12 presents a bubble chart showing spatial distribution of annual average concentration

for passive NO2. The annual average concentrations ranged from 0.6 ppb to 3.4 ppb. The spatial

trend was not as apparent as the passive SO2. The Roche Percee station (5.1 ppb) and the

Huntoon station (5.2 ppb) tended to detect a higher concentration among the network.

The 30-day average concentrations ranged from 0.3 ppb to 10.2 ppb. Please refer to Table F-2

for the concentrations of individual samples.

Figure 11. Passive NO2 monitoring results for the years from 2008 to 2012

0.0

2.0

4.0

6.0

8.0

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

30

-Da

y A

ve

rag

e C

on

c. f

or

Pa

ssiv

e N

O2

(pp

b)

2008 2009 2010 2011 2012

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35

Figure 12. Spatial distribution of passive NO2 concentration within the SESAA airshed zone

1.51.82.43.0

2.21.6

2.42.1 1.7

2.1 1.5 1.9

1.81.7

2.01.63.42.3

1.9

1.91.4

1.7 1.6

1.80.62.1

1.0

1.9

SESAA Passive NO2 Network 2012

Annual Average Conc. in ppb

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2.2.3 Ozone

Figure 13 presents 30-day average concentration for passive O3 for the years from 2008 to

2012. The data set seems to exhibit a seasonal trend that O3 concentration tended to be higher

in the spring and early-summer months. The concentration of ground-level ozone is the net

result of atmospheric formation, transport, and destruction processes. During spring and

summer, vertical mixing is stronger and could promote downward movement of upper air

ozone to the ground. However, some research suggests that there are split viewpoints as to the

relative importance of contributions of ozone from the stratosphere, mixing from the upper

troposphere, local photochemistry, and the medium and long-range transport. Further

investigation is required.

Figure 14 presents a bubble chart showing spatial distribution of annual average concentration

for passive O3. The annual average concentrations ranged from 24 ppb to 28 ppb. There was no

clear spatial trend within the airshed zone.

The 30-day average concentrations ranged from 15 ppb to 36 ppb. Please refer to Table F-3 for

the concentrations of individual samples.

Figure 13. Passive O3 monitoring results for the years from 2008 to 2012

0

15

30

45

60

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

Mo

nth

ly A

ve

rag

e C

on

c. f

or

Pas

siv

e O

3(p

pb

)

2008 2009 2010 2011 2012

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Figure 14. Spatial distribution of passive O3 concentration within the SESAA airshed zone

2425

27

28 24

2826

28

28

2727

28

SESAA Passive O3 Network 2012

Annual Average Conc. in ppb

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2.2.4 Hydrogen Sulphide

Figure 15 presents 30-day average concentration for passive H2S for the years from 2010 to

2012. The data set does not show an apparent monthly or seasonal trend.

Figure 16 presents a bubble chart showing spatial distribution of annual average concentration

for passive H2S. The annual average concentrations ranged from 0.6 ppb to 0.9 ppb. Excluding

the samples between January and July (only monitored at the two ATCO stations), there was no

apparent concentration differences among the six monitoring stations.

The 30-day average concentrations ranged from 0.3 ppb to 1.8 ppb. Please refer to Table F-4 for

the concentrations of individual samples.

Figure 15. Passive H2S monitoring results for the years from 2010 to 2012

0.0

1.0

2.0

3.0

4.0

Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

30

-Da

y A

ve

rag

e C

on

c. f

or

Pa

ssiv

e H

2S

(p

pb

)

2010 2011 2012

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Figure 16. Spatial distribution of passive H2S concentration within the SESAA airshed zone

0.7

0.6

0.7

0.7

0.80.9

SESAA Passive H2S Network 2012

Annual Average Conc. in ppb

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2.2.5 Ammonia

Ammonia is a colourless gas with a characteristic pungent acrid-smelling odour. Ammonia is

used in industry and commerce, and also exists naturally in humans and in the environment.

Ammonia is essential for many biological processes and serves as a precursor for amino acid

and nucleotide synthesis. In the environment, ammonia is part of the nitrogen cycle and is

produced in soil from bacterial processes. Ammonia is also produced naturally from

decomposition of organic matter, including plants, animals and animal wastes.

In addition to odour nuisance, two types of potential health effects are considered important

for ammonia. Acute exposure of high concentration ammonia can cause coughing and irritation

to eyes, nasal and throat. Chronic exposure to a low concentration can reduce pulmonary

function, coughing, phlegm, wheezing or dyspnea.

The SESAA passive network started monitoring passive NH3 from August 2012 at the Creelman

station. Table 11 summarizes 30-day average concentrations for passive NH3 samples. The

measured concentrations ranged from 0.3 ppb to 1.9 ppb. More data is needed to investigate if

a temporal trend is existent.

Table 11. 30-Day average concentration for passive NH3 samples for 2012

Passive Station 30-Day Passive Concentration (ppb) AVG MAX MIN

No. Name Aug Sep Oct Nov Dec

20 Creelman 1.9 1.5 1.4 0.3 1.1 1.2 1.9 0.3

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2.2.6 Benzene, Toluene, Ethylbenzene, and Xylene (BTEX)

Benzene, toluene, ethylbenzene, and xylene are volatile aromatic compounds. These

compounds are among the most abundantly produced chemicals in the world. These

compounds occur naturally in crude oil. Other natural sources include gas emissions from

volcanoes and forest fires. The primary anthropogenic sources are through emissions from

motor vehicles, aircrafts, and cigarette smoke. BTEX compounds are created and used during

the processing of petroleum products and during the production of consumer goods such as

paints and lacquers, thinners, rubber products, adhesives, inks, cosmetics and pharmaceutical

products.

BTEX exposures have been associated with skin and sensory irritation, central nervous system

depression, and effects on the respiratory system. Prolonged exposure to these compounds can

affect kidney, liver and blood systems. Benzene is a known carcinogen. Workers exposed to

high levels of benzene were found to have an increased incidence of leukemia.

THE SESAA passive network started monitoring passive BTEX from August 2012 at the Macoun

and Oxbow stations. Table 12 summarizes 30-day average concentrations of passive BTEX

samples. The measured concentrations were less than 1 ppb for benzene and toluene. All

ethylbenzene and xylene samples were less the method detection limit of 0.2 ppb.

Table 12. 30-Day average concentration for passive BTEX samples for 2012

Pollutants Passive Station 30-Day Passive Concentration (ppb) AVG MAX MIN

No. Name Aug Sep Oct Nov Dec

Benzene 8 Macoun 0.4 0.3 0.3 <0.1 0.5 0.3 0.5 <0.1

11 Oxbow 0.4 0.2 0.3 0.1 0.4 0.3 0.4 0.1

Toluene 8 Macoun <0.1 0.2 0.4 <0.1 0.5 0.3 0.5 <0.1

11 Oxbow 0.6 0.3 0.6 0.1 0.1 0.3 0.6 0.1

Ethylbenzene 8 Macoun <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2

11 Oxbow <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2

Xylene 8 Macoun <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2

11 Oxbow <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2

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3.0 Audited Financial Statement

The 2012 audited financial summary for the SESAA is presented in the following table. The

complete audited report is presented in Appendix E.

Table 13. SESAA financial summary for the year of 2012

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APPENDIX A. SASKATCHEWAN AMBIENT AIR QUALITY STANDARDS

Table A-1. Saskatchewan Ambient Air Quality Standards

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APPENDIX B. WEYBURN STATION: CONTINUOUS MONITORING DATA

Table B-1. Weyburn Station: Summary of airpointer® monitoring results for the year 2012

Parameter Unit Hours of

Calibration & AIC

Hours of Valid Data

Percent Capture

Summary Statistics for 1-Hour Average Data

Average Minimum Maximum

SO2 ppb 36 8740 99.9% 2 < 1 38

NO ppb 35 8352 95.5% 1.5 1 17.5

NO2 ppb 35 8353 95.5% 2.5 0 15.9

NOx ppb 35 8353 95.5% 4.0 1 33.4

O3 ppb 36 8739 99.9% 29 < 1 68

H2S ppb 36 8733 99.9% 2.1 < 0.1 92.3

PM2.5 µg/m3 18 8760 100.0% 4 < 1 62

Ambient Temperature °C 0 8780 100.0% 5.3 -31 34.7

Relative Humidity % 0 8780 100.0% 69.0 15 95.0

Wind Speed m/s 0 8780 100.0% 3.4 Calm 15.9

Precipitation mm 0 8780 100.0% 312.8* (* annual total)

0.0

23.0

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Table B-2. Weyburn Station: Summary of airpointer® SO2 monitoring results for the year 2012

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a.

24-Hr Conc. Exceedance b.

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=1 >1-5 >5-10 >10-57 >57-172 >172

January 744 100.0% 2 20 0 5 0 64.0 30.1 3.9 2.0 0.0 0.0

February 696 100.0% 2 27 0 7 0 46.8 40.4 9.6 3.2 0.0 0.0

March 744 100.0% 2 26 0 6 0 31.3 60.6 5.5 2.6 0.0 0.0

April 713 100.0% 2 23 0 5 0 38.3 56.7 3.8 1.3 0.0 0.0

May 743 100.0% 2 28 0 6 0 59.4 35.1 3.8 1.7 0.0 0.0

June 719 99.9% 2 17 0 5 0 40.2 53.0 5.6 1.3 0.0 0.0

July 736 99.7% 2 14 0 4 0 21.6 72.8 4.6 1.0 0.0 0.0

August 744 100.0% 2 38 0 6 0 19.5 73.7 5.5 1.3 0.0 0.0

September 719 99.9% 2 29 0 6 0 19.1 71.6 6.0 3.3 0.0 0.0

October 735 99.7% 2 25 0 5 0 3.3 91.7 3.7 1.4 0.0 0.0

November 720 100.0% 3 24 0 6 0 7.6 79.3 9.9 3.2 0.0 0.0

December 727 99.9% 4 35 0 10 0 5.2 68.6 16.4 9.8 0.0 0.0

Annual 8740 99.9% 2 38 0 10 0 29.7 61.2 6.5 2.7 0.0 0.0

a. 1-hour Saskatchewan Ambient Air Quality Standard = 172 ppb

b. 24-hour Saskatchewan Ambient Air Quality Standard = 57 ppb

c. Annual Saskatchewan Ambient Air Quality Standard = 11 ppb

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Table B-3. Weyburn Station: Summary of airpointer® NO monitoring results for the year 2012

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a

24-Hr Conc. Exceedance b

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=5 >5-15 >15-30 >30-100 >100-212 >212

January 744 100.0% 1.6 8.1 - 2.7 - 99.5 0.5 0.0 0.0 0.0 0.0

February 696 100.0% 1.5 5.4 - 2.1 - 99.7 0.3 0.0 0.0 0.0 0.0

March 743 99.9% 1.4 17.5 - 2.7 - 99.6 0.3 0.1 0.0 0.0 0.0

April 712 99.7% 1.2 3.4 - 1.6 - 100.0 0.0 0.0 0.0 0.0 0.0

May 743 99.9% 1.5 13.1 - 2.1 - 99.7 0.3 0.0 0.0 0.0 0.0

June 629 87.4% 1.4 5.0 - 1.8 - 100.0 0.0 0.0 0.0 0.0 0.0

July 443 60.3% 1.7 4.2 - 2.0 - 100.0 0.0 0.0 0.0 0.0 0.0

August 744 100.0% 1.2 6.6 - 1.6 - 99.9 0.1 0.0 0.0 0.0 0.0

September 719 99.9% 1.3 4.0 - 1.5 - 100.0 0.0 0.0 0.0 0.0 0.0

October 736 99.9% 1.7 12.8 - 2.3 - 99.9 0.1 0.0 0.0 0.0 0.0

November 718 99.7% 2.0 7.6 - 2.6 - 98.5 1.5 0.0 0.0 0.0 0.0

December 725 99.6% 1.7 17.2 - 3.4 - 97.2 2.6 0.1 0.0 0.0 0.0

Annual 8352 95.5% 1.5 17.5 - 3.4 - 99.5 0.5 0.0 0.0 0.0 0.0

a. No 1-hour Saskatchewan Ambient Air Quality Standard

b. No 24-hour Saskatchewan Ambient Air Quality Standard

c. No annual Saskatchewan Ambient Air Quality Standard

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Table B-4. Weyburn Station: Summary of airpointer® NO2 monitoring results for the year 2012

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a.

24-Hr Conc. Exceedance b

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=5 >5-15 >15-30 >30-100 >100-212 >212

January 744 100.0% 2.0 13.8 0 5.0 - 93.7 6.3 0.0 0.0 0.0 0.0

February 696 100.0% 2.6 12.6 0 5.8 - 92.5 7.5 0.0 0.0 0.0 0.0

March 743 99.9% 2.4 15.9 0 5.6 - 93.4 6.5 0.1 0.0 0.0 0.0

April 713 99.9% 1.7 6.8 0 3.6 - 98.3 1.7 0.0 0.0 0.0 0.0

May 743 99.9% 1.7 12.5 0 4.0 - 97.4 2.6 0.0 0.0 0.0 0.0

June 629 87.4% 2.1 9.3 0 4.1 - 94.0 6.0 0.0 0.0 0.0 0.0

July 443 60.3% 2.2 11.0 0 4.1 - 96.4 3.6 0.0 0.0 0.0 0.0

August 744 100.0% 2.1 8.0 0 2.9 - 97.7 2.3 0.0 0.0 0.0 0.0

September 719 99.9% 2.2 10.6 0 3.7 - 96.2 3.8 0.0 0.0 0.0 0.0

October 736 99.9% 2.4 12.1 0 4.8 - 91.4 8.6 0.0 0.0 0.0 0.0

November 718 99.7% 3.9 15.7 0 8.8 - 74.0 25.8 0.3 0.0 0.0 0.0

December 725 99.6% 4.1 15.8 0 8.5 - 69.9 29.9 0.1 0.0 0.0 0.0

Annual 8353 95.5% 2.5 15.9 0 8.8 - 91.1 8.9 0.0 0.0 0.0 0.0

a. 1-hour Saskatchewan Ambient Air Quality Standard = 212 ppb

b. No 24-hour Saskatchewan Ambient Air Quality Standard

c. Annual Saskatchewan Ambient Air Quality Standard = 53 ppb

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Table B-5. Weyburn Station: Summary of airpointer® NOx monitoring results for the year 2012

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a

24-Hr Conc. Exceedance b

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=5 >5-15 >15-30 >30-100 >100-212 >212

January 744 100.0% 3.7 17.6 - 7.2 - 80.9 18.7 0.4 0.0 0.0 0.0

February 696 100.0% 4.1 16.8 - 7.7 - 71.7 28.2 0.1 0.0 0.0 0.0

March 743 99.9% 3.8 33.4 - 7.4 - 84.0 15.7 0.1 0.1 0.0 0.0

April 713 99.9% 3.0 8.4 - 5.0 - 92.7 7.3 0.0 0.0 0.0 0.0

May 743 99.9% 3.2 16.7 - 5.9 - 91.7 8.2 0.1 0.0 0.0 0.0

June 629 87.4% 3.5 12.4 - 5.8 - 86.5 13.5 0.0 0.0 0.0 0.0

July 443 60.3% 3.9 12.3 - 6.1 - 86.2 13.8 0.0 0.0 0.0 0.0

August 744 100.0% 3.3 10.2 - 4.4 - 90.3 9.7 0.0 0.0 0.0 0.0

September 719 99.9% 3.4 13.8 - 5.0 - 88.6 11.4 0.0 0.0 0.0 0.0

October 736 99.9% 4.1 15.6 - 6.8 - 76.8 23.1 0.1 0.0 0.0 0.0

November 718 99.7% 5.9 18.5 - 11.1 - 54.6 44.2 1.3 0.0 0.0 0.0

December 725 99.6% 5.9 33.1 - 11.8 - 50.3 47.9 1.7 0.1 0.0 0.0

Annual 8353 95.5% 4.0 33.4 - 11.8 - 79.3 20.3 0.3 0.0 0.0 0.0

a. No 1-hour Saskatchewan Ambient Air Quality Standard

b. No 24-hour Saskatchewan Ambient Air Quality Standard

c. No annual Saskatchewan Ambient Air Quality Standard

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Table B-6. Weyburn Station: Summary of airpointer® O3 monitoring results for the year 2012

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a.

24-Hr Conc. Exceedance b

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=10 >10-20 >20-40 >40-60 >60-82 >82

January 744 100.0% 26 38 0 35 - 0.5 16.7 82.8 0.0 0.0 0.0

February 696 100.0% 26 42 0 36 - 0.6 23.6 74.7 1.1 0.0 0.0

March 743 99.9% 32 54 0 42 - 0.1 9.6 69.3 21.0 0.0 0.0

April 713 99.9% 34 57 0 41 - 0.0 6.9 64.7 28.5 0.0 0.0

May 743 99.9% 35 61 0 45 - 0.4 9.8 56.9 32.3 0.5 0.0

June 719 99.9% 32 63 0 45 - 1.7 20.9 52.4 22.7 2.4 0.0

July 735 100.0% 30 66 0 40 - 9.5 22.2 39.9 26.5 1.9 0.0

August 744 100.0% 31 68 0 45 - 4.8 21.5 44.6 27.3 1.7 0.0

September 719 99.9% 30 68 0 40 - 0.6 18.4 64.3 15.7 1.1 0.0

October 736 99.9% 21 44 0 33 - 12.5 33.3 52.6 1.6 0.0 0.0

November 720 100.0% 25 40 0 36 - 3.9 26.4 69.3 0.4 0.0 0.0

December 727 99.9% 26 41 0 34 - 2.6 16.0 80.9 0.6 0.0 0.0

Annual 8739 99.9% 29 68 0 45 - 3.1 18.7 62.6 14.9 0.6 0.0

a. 1-hour Saskatchewan Ambient Air Quality Standard = 82 ppb

b. No 24-hour Saskatchewan Ambient Air Quality Standard

c. No annual Saskatchewan Ambient Air Quality Standard

d. 8-hour Canada-Wide Standard = 65 ppb (4th

highest concentration annually, averaged over three consecutive years). The 4th

highest concentration for

8-hour O3 was 62 ppb for 2012.

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50

Table B-7. Weyburn Station: Summary of airpointer® H2S monitoring results for the year 2012

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a.

24-Hr Conc. Exceedance b.

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=1 >1-3.6 >3.6-5 >5-8 >8-10.8 >10.8

January 744 100.0% 1.1 15.3 5 2.9 0 77.4 17.3 2.0 2.0 0.5 0.7

February 696 100.0% 2.1 33.4 22 8.1 5 58.0 28.7 4.7 3.3 2.0 3.2

March 742 99.7% 1.8 92.3 9 5.1 2 37.1 55.0 3.6 2.0 1.1 1.2

April 712 99.7% 1.5 10.5 0 3.0 0 22.2 73.2 2.1 2.0 0.6 0.0

May 743 99.9% 1.6 26.7 7 3.6 0 19.4 76.3 1.6 1.2 0.5 0.9

June 719 99.9% 1.9 11.8 1 3.0 0 2.1 92.2 2.8 2.4 0.4 0.1

July 735 100.0% 2.6 28.9 8 5.5 2 0.0 85.6 6.5 5.0 1.6 1.2

August 744 100.0% 2.9 60.6 19 5.3 6 0.0 81.5 8.9 5.6 1.5 2.6

September 718 99.7% 2.5 20.9 7 5.0 3 0.0 87.0 5.3 4.3 2.4 1.0

October 735 99.7% 2.2 16.8 9 4.9 2 0.0 92.7 2.0 3.4 0.7 1.2

November 720 100.0% 2.4 22.9 14 8.5 3 0.0 91.4 2.9 2.6 1.1 1.9

December 725 99.6% 2.7 32.4 10 6.0 5 0.0 87.7 6.6 3.0 1.2 1.4

Annual 8733 99.9% 2.1 92.3 111 8.5 28 18.0 72.4 4.1 3.1 1.1 1.3

a. 1-hour Saskatchewan Ambient Air Quality Standard = 10.8 ppb

b. 24-hour Saskatchewan Ambient Air Quality Standard = 3.6 ppb

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Table B-8. Weyburn Station: Summary of airpointer® PM2.5 monitoring results for the year 2012

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a

24-Hr Conc. Exceedance b.

(no.) (%) (µg/m

3) (µg/m

3) (no.) (µg/m

3) (no.) <=2 >2-5 >5-10 >10-20 >20-30 >30

January 744 100.0% 1 7 - 5 0 85.6 11.2 3.2 0.0 0.0 0.0

February 696 100.0% 2 13 - 7 0 62.8 27.4 8.9 0.9 0.0 0.0

March 744 100.0% 3 41 - 13 0 52.3 31.6 11.4 3.8 0.7 0.3

April 714 99.9% 2 10 - 6 0 65.0 29.0 5.9 0.1 0.0 0.0

May 743 99.9% 3 18 - 8 0 39.2 43.2 14.8 2.8 0.0 0.0

June 719 99.9% 5 48 - 25 0 26.7 39.9 25.3 4.2 3.3 0.6

July 736 100.0% 10 62 - 45 d.

0 d.

17.8 19.8 29.9 21.5 6.5 4.5

August 744 100.0% 7 48 - 13 0 15.1 23.1 34.1 25.4 1.7 0.5

September 720 100.0% 6 55 - 17 0 20.6 38.3 19.7 18.1 2.4 1.0

October 736 99.9% 3 16 - 9 0 34.9 53.3 10.2 1.6 0.0 0.0

November 720 100.0% 3 17 - 10 0 43.3 34.4 17.1 5.1 0.0 0.0

December 744 100.0% 8 48 - 14 0 10.1 22.7 36.7 28.2 1.6 0.7

Annual 8760 100.0% 4 62 - 45 d.

0 d.

39.3 31.1 18.2 9.4 1.4 0.6

a. No 1-hour Saskatchewan Ambient Air Quality Standard

b. 24-hour Canada-Wide Standard = 30 µg/m3

(98th

percentile annually, averaged over three consecutive years).

c. No annual Saskatchewan Ambient Air Quality Standard

d. Although the concentration was higher than the 24-hour CWS, the event did not comprise an exceedance as the CWS is based on 98th

percentile of

annual measurement, averaged over three consecutive years. The 98th

percentile concentration for 24-hour PM2.5 was 15 µg/m3for 2012.

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Table B-9. Weyburn Station: Summary of airpointer® precipitation monitoring results for the year 2012

Valid

1-Hr data

Operational

Time

Total

Precip.

Maximum

1-Hr Precip.

Maximum

24-Hr Precip. Percent of Data in each Precipitation Range

Month

(no.) (%) (mm) (mm) (mm) <=0 >0-5 >5-10 >10-30 >30-60 >60

January 744 100.0% 2.8 2.4 2.4 99.2 0.8 0.0 0.0 0.0 0.0

February 696 100.0% < 0.1 < 0.1 < 0.1 100.0 0.0 0.0 0.0 0.0 0.0

March 744 100.0% 2.0 1.5 1.5 98.4 1.6 0.0 0.0 0.0 0.0

April 719 99.9% 29.6 2.0 6.9 88.2 11.8 0.0 0.0 0.0 0.0

May 744 100.0% 85.1 7.9 29.9 84.7 14.9 0.4 0.0 0.0 0.0

June 719 99.9% 90.2 23.0 23.4 85.4 14.2 0.3 0.1 0.0 0.0

July 742 100.0% 33.1 8.0 9.3 85.8 13.9 0.3 0.0 0.0 0.0

August 744 100.0% 28.7 19.3 22.8 95.3 4.6 0.0 0.1 0.0 0.0

September 720 100.0% 4.8 2.1 3.5 97.5 2.5 0.0 0.0 0.0 0.0

October 744 100.0% 27.6 16.5 22.4 94.6 5.2 0.0 0.1 0.0 0.0

November 720 100.0% 7.6 1.7 3.4 96.7 3.3 0.0 0.0 0.0 0.0

December 744 100.0% 1.2 1.0 1.1 99.5 0.5 0.0 0.0 0.0 0.0

Annual 8780 100.0% 312.8 23.0 29.9 93.8 6.1 0.1 0.0 0.0 0.0

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Table B-10. Weyburn Station: Summary of airpointer® ambient temperature monitoring results for the year 2012

Valid Operational Average Minimum Maximum

Percent of Data in each Temperature Range Month 1-Hr data Time Temp. 1-Hr Temp. 1-Hr Temp.

(no.) (%) (°C) (°C) (°C) <=-30 >-30--15 >-15-0 >0-15 >15-30 >30

January 744 100.0% -7.3 -29.3 10.4 0.0 23.9 50.1 25.9 0.0 0.0

February 696 100.0% -6.5 -24.0 6.9 0.0 10.6 79.9 9.5 0.0 0.0

March 744 100.0% 2.0 -21.2 20.7 0.0 2.0 34.3 59.4 4.3 0.0

April 719 99.9% 5.9 -6.9 27.3 0.0 0.0 14.0 76.4 9.6 0.0

May 744 100.0% 11.2 1.8 29.2 0.0 0.0 0.0 78.1 21.9 0.0

June 719 99.9% 17.4 6.8 29.7 0.0 0.0 0.0 38.1 61.9 0.0

July 742 100.0% 22.0 11.4 34.6 0.0 0.0 0.0 5.8 89.1 5.1

August 744 100.0% 19.3 8.2 34.7 0.0 0.0 0.0 28.1 68.1 3.8

September 720 100.0% 13.8 -3.7 30.5 0.0 0.0 1.5 56.3 41.8 0.4

October 744 100.0% 3.3 -11.3 19.5 0.0 0.0 29.8 64.8 5.4 0.0

November 720 100.0% -5.0 -20.3 11.9 0.0 5.7 70.7 23.6 0.0 0.0

December 744 100.0% -13.5 -30.8 6.6 0.1 40.3 56.0 3.5 0.0 0.0

Annual 8780 100.0% 5.3 -30.8 34.7 0.0 6.9 27.8 39.2 25.3 0.8

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Table B-11. Weyburn Station: Summary of airpointer® relative humidity monitoring results for the year 2012

Valid Operational Average Minimum Maximum

Percent of Data in each Relative Humidity Range Month 1-Hr data Time RH 1-Hr RH 1-Hr RH

(no.) (%) (%) (%) (%) <=15 >15-30 >30-60 >60-80 >80-90 >90

January 744 100.0% 72.0 38.0 91.0 0.0 0.0 9.3 71.4 18.8 0.5

February 696 100.0% 76.0 31.0 93.0 0.0 0.0 9.6 48.7 36.4 5.3

March 744 100.0% 70.0 24.0 93.0 0.0 3.0 23.7 35.1 31.9 6.5

April 719 99.9% 67.0 22.0 94.0 0.0 7.1 26.4 31.6 26.7 8.2

May 744 100.0% 67.0 18.0 95.0 0.0 6.6 29.3 26.1 27.6 10.5

June 719 99.9% 66.0 28.0 93.0 0.0 0.6 33.1 39.4 23.9 3.1

July 742 100.0% 67.0 26.0 93.0 0.0 1.1 35.7 29.2 26.0 8.0

August 744 100.0% 60.0 17.0 92.0 0.0 9.0 39.0 28.1 20.3 3.6

September 720 100.0% 49.0 15.0 88.0 0.0 20.8 47.4 24.0 7.8 0.0

October 744 100.0% 71.0 27.0 93.0 0.0 0.9 22.6 40.5 29.0 7.0

November 720 100.0% 81.0 52.0 92.0 0.0 0.0 1.8 37.5 55.4 5.3

December 744 100.0% 81.0 61.0 92.0 0.0 0.0 0.0 39.2 57.0 3.8

Annual 8780 100.0% 69.0 15.0 95.0 0.0 4.1 23.2 37.6 30.0 5.1

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Table B-12. Weyburn Station: airpointer® wind frequency table for the year 2012

Wind Direction

Sector

Percent of Data in each Wind Speed Range, wind speed unit m/s

>0.3-1.4 >1.4-3.1 >3.1-7.8 >7.8-10.6 >10.6-13.6 >13.6 Totals

North NorthEast 0.4% 0.4% 0.7% 0.0% 0.0% 0.0% 1.6%

NorthEast 0.5% 0.8% 0.9% 0.0% 0.0% 0.0% 2.3%

East NorthEast 0.6% 1.4% 1.6% 0.3% 0.0% 0.0% 3.8%

East 1.7% 4.3% 5.8% 0.6% 0.2% 0.0% 12.7%

East SouthEast 2.9% 4.7% 2.0% 0.0% 0.0% 0.0% 9.7%

SouthEast 3.2% 4.1% 0.8% 0.0% 0.0% 0.0% 8.0%

South SouthEast 2.2% 1.4% 0.1% 0.0% 0.0% 0.0% 3.7%

South 1.4% 1.7% 0.5% 0.0% 0.0% 0.0% 3.7%

South SouthWest 1.2% 2.2% 1.3% 0.0% 0.0% 0.0% 4.7%

SouthWest 1.1% 1.8% 2.5% 0.1% 0.0% 0.0% 5.4%

West SouthWest 0.7% 2.6% 4.0% 0.4% 0.2% 0.0% 7.9%

West 0.9% 3.1% 5.4% 1.0% 0.3% 0.0% 10.7%

West NorthWest 0.6% 2.8% 8.2% 1.6% 0.4% 0.1% 13.7%

NorthWest 0.6% 1.9% 3.1% 0.1% 0.0% 0.0% 5.6%

North NorthWest 0.5% 1.1% 1.8% 0.0% 0.0% 0.0% 3.3%

North 0.4% 0.7% 1.3% 0.0% 0.0% 0.0% 2.5%

Total 19.0% 34.8% 40.0% 4.2% 1.2% 0.1% 99.2%

Percent Calm (<0.3 m/s) 0.8%

Number of Valid Hourly-Average Data 8780

Total Workable Hours in Time Period 8782

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56

APPENDIX C. GLEN EWEN STATION: CONTINUOUS MONITORING DATA

Table C-1. Glen Ewen Station: Summary of airpointer® monitoring results for the year 2012

Parameter Unit Hours of

Calibration & AIC

Hours of Valid Data

Percent Capture

Summary Statistics for 1-Hour Average Data

Average Minimum Maximum

SO2 ppb 33 5773 98.7% 2 1 35

NO ppb 34 5780 98.9% 0.7 < 0.1 17.9

NO2 ppb 34 5780 98.9% 2.7 0.8 23.9

NOx ppb 34 5780 98.9% 3.4 1.1 34.0

O3 ppb 33 5791 99.0% 28 1 70

H2S ppb 33 5685 97.2% 0.7 < 0.1 33.9

Ambient Temperature °C 1 5826 99.1% 7.8 -31 35.5

Relative Humidity % 1 5826 99.1% 69.0 15 96.0

Wind Speed m/s 0 5826 99.1% 3.0 Calm 18.8

Precipitation mm 1 5826 99.1% 237.3* (* annual total)

0.0 20.7

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Table C-2. Glen Ewen Station: Summary of airpointer® SO2 monitoring results for the year 2012 (program started on May 1, 2012)

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a.

24-Hr Conc. Exceedance b.

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=1 >1-5 >5-10 >10-57 >57-172 >172

May 726 97.6% 2 29 0 4 0 6.6 89.5 2.6 1.2 0.0 0.0

June 671 93.2% 2 9 0 4 0 3.4 93.4 3.1 0.0 0.0 0.0

July 735 99.9% 2 11 0 3 0 9.7 89.1 1.1 0.1 0.0 0.0

August 743 99.9% 2 24 0 4 0 14.8 83.3 1.6 0.3 0.0 0.0

September 719 99.9% 2 25 0 4 0 19.5 76.5 2.4 1.7 0.0 0.0

October 736 99.9% 2 19 0 4 0 15.6 80.6 3.0 0.8 0.0 0.0

November 719 99.9% 2 35 0 5 0 30.6 65.9 2.1 1.4 0.0 0.0

December 724 99.7% 3 19 0 6 0 5.1 85.1 8.1 1.7 0.0 0.0

Annual 5773 98.7% 2 35 0 6 0 13.2 82.9 3.0 0.9 0.0 0.0

a. 1-hour Saskatchewan Ambient Air Quality Standard = 172 ppb

b. 24-hour Saskatchewan Ambient Air Quality Standard = 57 ppb

c. Annual Saskatchewan Ambient Air Quality Standard = 11 ppb

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Table C-3. Glen Ewen Station: Summary of airpointer® NO monitoring results for the year 2012 (program started on May 1, 2012)

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a

24-Hr Conc. Exceedance b

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=5 >5-15 >15-30 >30-100 >100-212 >212

May 744 100.0% 0.7 17.9 - 1.4 - 99.9 0.0 0.1 0.0 0.0 0.0

June 669 92.9% 0.8 10.2 - 1.2 - 99.4 0.6 0.0 0.0 0.0 0.0

July 731 99.3% 0.6 8.1 - 1.1 - 99.5 0.5 0.0 0.0 0.0 0.0

August 741 99.6% 0.7 4.9 - 1.0 - 100.0 0.0 0.0 0.0 0.0 0.0

September 720 100.0% 0.6 3.8 - 0.9 - 100.0 0.0 0.0 0.0 0.0 0.0

October 736 99.9% 0.7 11.7 - 1.4 - 99.7 0.3 0.0 0.0 0.0 0.0

November 718 99.7% 0.8 7.5 - 1.7 - 99.0 1.0 0.0 0.0 0.0 0.0

December 721 99.5% 1.0 12.6 - 2.3 - 98.9 1.1 0.0 0.0 0.0 0.0

Annual 5780 98.9% 0.7 17.9 - 2.3 - 99.6 0.4 0.0 0.0 0.0 0.0

a. No 1-hour Saskatchewan Ambient Air Quality Standard

b. No 24-hour Saskatchewan Ambient Air Quality Standard

c. No annual Saskatchewan Ambient Air Quality Standard

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Table C-4. Glen Ewen Station: Summary of airpointer® NO2 monitoring results for the year 2012 (program started on May 1, 2012)

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a.

24-Hr Conc. Exceedance b

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=5 >5-15 >15-30 >30-100 >100-212 >212

May 744 100.0% 2.3 16.1 0 4.3 - 95.4 4.4 0.1 0.0 0.0 0.0

June 669 92.9% 2.7 23.9 0 6.7 - 93.3 6.0 0.7 0.0 0.0 0.0

July 731 99.3% 1.9 9.2 0 2.4 - 99.3 0.7 0.0 0.0 0.0 0.0

August 741 99.6% 2.2 13.5 0 3.7 - 97.7 2.3 0.0 0.0 0.0 0.0

September 720 100.0% 2.7 10.6 0 3.9 - 95.0 5.0 0.0 0.0 0.0 0.0

October 736 99.9% 2.5 9.9 0 4.7 - 93.6 6.4 0.0 0.0 0.0 0.0

November 718 99.7% 3.7 19.0 0 9.0 - 76.5 23.1 0.4 0.0 0.0 0.0

December 721 99.5% 3.5 13.5 0 5.8 - 81.1 18.9 0.0 0.0 0.0 0.0

Annual 5780 98.9% 2.7 23.9 0 9.0 - 91.5 8.3 0.2 0.0 0.0 0.0

a. 1-hour Saskatchewan Ambient Air Quality Standard = 212 ppb

b. No 24-hour Saskatchewan Ambient Air Quality Standard

c. Annual Saskatchewan Ambient Air Quality Standard = 53 ppb

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Table C-5. Glen Ewen Station: Summary of airpointer® NOx monitoring results for the year 2012 (program started on May 1, 2012)

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a

24-Hr Conc. Exceedance b

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=5 >5-15 >15-30 >30-100 >100-212 >212

May 744 100.0% 3.1 34.0 - 5.5 - 90.1 9.7 0.1 0.1 0.0 0.0

June 669 92.9% 3.5 27.4 - 7.9 - 88.5 10.2 1.3 0.0 0.0 0.0

July 731 99.3% 2.5 16.0 - 3.5 - 96.4 3.4 0.1 0.0 0.0 0.0

August 741 99.6% 2.9 15.6 - 4.7 - 94.9 5.0 0.1 0.0 0.0 0.0

September 720 100.0% 3.2 14.1 - 4.7 - 89.9 10.1 0.0 0.0 0.0 0.0

October 736 99.9% 3.2 20.0 - 6.1 - 86.5 13.3 0.1 0.0 0.0 0.0

November 718 99.7% 4.5 21.0 - 10.5 - 64.5 34.4 1.1 0.0 0.0 0.0

December 721 99.5% 4.4 20.0 - 7.3 - 69.5 29.8 0.7 0.0 0.0 0.0

Annual 5780 98.9% 3.4 34.0 - 10.5 - 85.1 14.4 0.4 0.0 0.0 0.0

a. No 1-hour Saskatchewan Ambient Air Quality Standard

b. No 24-hour Saskatchewan Ambient Air Quality Standard

c. No annual Saskatchewan Ambient Air Quality Standard

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61

Table C-6. Glen Ewen Station: Summary of airpointer® O3 monitoring results for the year 2012 (program started on May 1, 2012)

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a.

24-Hr Conc. Exceedance b

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=10 >10-20 >20-40 >40-60 >60-82 >82

May 744 100.0% 32 63 0 44 - 0.7 17.1 55.6 25.5 1.1 0.0

June 671 93.2% 31 66 0 45 - 2.4 16.1 57.5 22.2 1.8 0.0

July 735 99.9% 28 66 0 39 - 7.3 24.1 48.6 19.0 1.0 0.0

August 743 99.9% 28 70 0 43 - 10.6 22.1 46.4 19.5 1.3 0.0

September 720 100.0% 28 65 0 39 - 4.0 22.5 58.8 14.0 0.7 0.0

October 736 99.9% 22 48 0 34 - 9.9 31.9 56.3 1.9 0.0 0.0

November 719 99.9% 26 43 0 38 - 1.3 21.1 76.6 1.0 0.0 0.0

December 723 99.6% 26 40 0 34 - 1.2 15.4 83.3 0.1 0.0 0.0

Annual 5791 99.0% 28 70 0 45 - 4.7 21.3 60.3 12.9 0.7 0.0

a. 1-hour Saskatchewan Ambient Air Quality Standard = 82 ppb

b. No 24-hour Saskatchewan Ambient Air Quality Standard

c. No annual Saskatchewan Ambient Air Quality Standard

d. 8-hour Canada-Wide Standard = 65 ppb (4th

highest concentration annually, averaged over three consecutive years). The 4th

highest concentration for

8-hour O3 was 62 ppb for 2012.

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Table C-7. Glen Ewen Station: Summary of airpointer® H2S monitoring results for the year 2012 (program started on May 1, 2012)

Valid Operational Average Maximum 1-Hour Maximum 24-Hour Percent of Data in each Concentration Range

Month 1-Hr data Time Conc. 1-Hr Conc. Exceedance a.

24-Hr Conc. Exceedance b.

(no.) (%) (ppb) (ppb) (no.) (ppb) (no.) <=1 >1-3.6 >3.6-5 >5-8 >8-10.8 >10.8

May 744 100.0% 0.2 6.3 0 0.4 0 93.4 6.0 0.3 0.3 0.0 0.0

June 671 93.2% 0.5 17.5 1 1.4 0 89.4 8.9 0.7 0.6 0.1 0.1

July 735 99.9% 1.1 12.1 1 2.9 0 68.2 26.9 1.6 2.3 0.8 0.1

August 743 99.9% 1.0 17.5 3 2.3 0 67.7 30.0 0.4 0.8 0.7 0.4

September 712 98.9% 1.1 12.9 2 2.2 0 68.1 27.9 1.8 1.1 0.7 0.3

October 690 93.7% 0.5 7.1 0 1.9 0 87.8 11.2 0.9 0.1 0.0 0.0

November 694 96.4% 0.6 5.5 0 2.4 0 84.0 14.7 0.7 0.6 0.0 0.0

December 696 96.0% 0.7 33.9 1 2.0 0 82.9 16.7 0.3 0.0 0.0 0.1

Annual 5685 97.2% 0.7 33.9 8 2.9 0 80.0 17.9 0.8 0.7 0.3 0.1

a. 1-hour Saskatchewan Ambient Air Quality Standard = 10.8 ppb

b. 24-hour Saskatchewan Ambient Air Quality Standard = 3.6 ppb

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Table C-8. Glen Ewen Station: Summary of airpointer® precipitation results for the year 2012 (program started on May 1, 2012)

Valid

1-Hr data

Operational

Time

Total

Precip.

Maximum

1-Hr Precip.

Maximum

24-Hr Precip. Percent of Data in each Precipitation Range

Month

(no.) (%) (mm) (mm) (mm) <=0 >0-5 >5-10 >10-30 >30-60 >60

May 744 100.0% 63.2 9.0 19.9 88.0 11.3 0.7 0.0 0.0 0.0

June 671 93.2% 63.2 8.6 17.0 91.4 7.9 0.7 0.0 0.0 0.0

July 744 100.0% 73.8 20.7 21.1 90.1 9.4 0.1 0.4 0.0 0.0

August 743 99.9% 19.1 3.0 6.9 92.3 7.7 0.0 0.0 0.0 0.0

September 720 100.0% 8.2 3.5 5.9 96.1 3.9 0.0 0.0 0.0 0.0

October 742 99.9% 7.5 2.4 3.9 96.1 3.9 0.0 0.0 0.0 0.0

November 720 100.0% 2.3 0.8 1.3 98.2 1.8 0.0 0.0 0.0 0.0

December 742 99.7% 0.1 0.1 0.1 99.7 0.3 0.0 0.0 0.0 0.0

Annual 5826 99.1% 237.3 20.7 21.1 94.0 5.8 0.2 0.1 0.0 0.0

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Table C-9. Glen Ewen Station: Summary of airpointer® ambient temperature results for the year 2012 (program started on May 1, 2012)

Valid Operational Average Minimum Maximum

Percent of Data in each Temperature Range Month 1-Hr data Time Temp. 1-Hr Temp. 1-Hr Temp.

(no.) (%) (°C) (°C) (°C) <=-30 >-30--15 >-15-0 >0-15 >15-30 >30

May 744 100.0% 10.9 1.0 27.0 0.0 0.0 0.0 76.1 23.9 0.0

June 671 93.2% 16.8 5.1 28.7 0.0 0.0 0.0 41.6 58.4 0.0

July 744 100.0% 21.2 8.6 33.5 0.0 0.0 0.0 9.7 87.5 2.8

August 743 99.9% 18.3 5.5 35.5 0.0 0.0 0.0 32.4 64.3 3.2

September 720 100.0% 13.0 -5.8 30.8 0.0 0.0 3.5 57.8 38.2 0.6

October 742 99.9% 3.2 -12.0 20.5 0.0 0.0 29.6 64.6 5.8 0.0

November 720 100.0% -6.1 -22.3 8.6 0.0 7.1 77.4 15.6 0.0 0.0

December 742 99.7% -14.4 -30.7 4.0 0.5 50.3 47.3 1.9 0.0 0.0

Annual 5826 99.1% 7.8 -30.7 35.5 0.1 7.3 19.8 37.4 34.6 0.8

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Table C-10. Glen Ewen Station: Summary of airpointer® relative humidity results for the year 2012 (program started on May 1, 2012)

Valid Operational Average Minimum Maximum

Percent of Data in each Relative Humidity Range Month 1-Hr data Time RH 1-Hr RH 1-Hr RH

(no.) (%) (%) (%) (%) <=15 >15-30 >30-60 >60-80 >80-90 >90

May 744 100.0% 66 15 95 0.1 7.7 29.7 26.2 21.4 14.9

June 671 93.2% 70 28 96 0.0 1.2 27.6 32.6 28.0 10.6

July 744 100.0% 72 37 96 0.0 0.0 31.0 25.8 24.2 19.0

August 743 99.9% 63 17 95 0.0 7.7 37.4 23.4 19.4 12.1

September 720 100.0% 51 17 91 0.0 19.6 44.7 26.0 9.4 0.3

October 742 99.9% 70 27 95 0.0 0.5 24.4 44.6 20.5 10.0

November 720 100.0% 81 57 92 0.0 0.0 0.4 39.4 53.8 6.4

December 742 99.7% 79 68 92 0.0 0.0 0.0 60.2 36.4 3.4

Annual 5826 99.1% 69 15 96 0.0 4.6 24.4 34.8 26.6 9.6

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Table C-11. Glen Ewen Station: airpointer® wind frequency table for the year 2012 (program started on May 1, 2012)

Wind Direction

Sector

Percent of Data in each Wind Speed Range, wind speed unit m/s

>0.3-1.4 >1.4-3.1 >3.1-7.8 >7.8-10.6 >10.6-13.6 >13.6 Totals

North NorthEast 1.4% 1.1% 0.5% 0.0% 0.0% 0.0% 3.1%

NorthEast 1.4% 0.9% 0.1% 0.0% 0.0% 0.0% 2.4%

East NorthEast 1.3% 1.2% 0.1% 0.0% 0.0% 0.0% 2.6%

East 2.3% 2.4% 1.6% 0.0% 0.0% 0.0% 6.4%

East SouthEast 1.4% 3.1% 2.5% 0.0% 0.0% 0.0% 7.1%

SouthEast 0.8% 3.0% 5.0% 0.1% 0.0% 0.0% 9.0%

South SouthEast 0.8% 1.6% 2.0% 0.1% 0.0% 0.0% 4.5%

South 0.5% 1.0% 0.9% 0.1% 0.0% 0.0% 2.6%

South SouthWest 0.6% 1.0% 0.4% 0.0% 0.0% 0.0% 2.0%

SouthWest 0.9% 1.5% 0.8% 0.0% 0.0% 0.0% 3.2%

West SouthWest 1.3% 2.6% 1.6% 0.0% 0.0% 0.0% 5.5%

West 1.6% 3.7% 5.4% 0.1% 0.0% 0.0% 10.8%

West NorthWest 1.4% 3.6% 7.4% 0.3% 0.1% 0.0% 12.9%

NorthWest 1.3% 3.7% 5.3% 0.6% 0.0% 0.0% 10.9%

North NorthWest 1.5% 3.3% 3.8% 0.3% 0.0% 0.0% 8.9%

North 1.4% 3.0% 1.7% 0.0% 0.0% 0.0% 6.1%

Total 20.0% 36.8% 39.2% 1.7% 0.2% 0.1% 98.0%

Percent Calm (<0.3 m/s) 2.0%

Number of Valid Hourly-Average Data 5826

Total Workable Hours in Time Period 5879

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67

APPENDIX D. WEYBURN STATION: EXCEEDANCE SUMMARY

Table D-1. Weyburn Station: Summary of exceedances for 1-hour SAAQS for the year 2012

1-Hour Exceedance Pollutant Other Parameters During the Exceedance Event

Pollutant Conc. Exceedance Time WS WD AQI Rain SO2 NO2 O3 H2S PM2.5

ppb mmm-dd hh:mm m/s deg - mm ppb ppb ppb ppb µg/m3

H2S 13.3 Jan-03 01:00 1.1 119 11 0.0 8 2 22 13 0.6

H2S 14.9 Jan-03 02:00 0.9 118 11 0.0 8 2 22 15 0.7

H2S 15.3 Jan-23 08:00 1.2 127 9 0.0 10 3 17 15 0.7

H2S 12.2 Jan-30 06:00 2.1 119 6 0.0 15 5 13 12 3.2

H2S 11.9 Jan-31 09:00 0.5 121 3 0.0 1 3 7 12 2.7

H2S 15.6 Feb-01 20:00 0.8 104 10 0.0 2 3 21 16 2.5

H2S 11.1 Feb-01 22:00 1.1 103 8 0.0 5 4 17 11 2.7

H2S 13.8 Feb-04 05:00 0.9 139 6 0.0 5 3 13 14 4.0

H2S 13.4 Feb-04 06:00 1.0 135 6 0.0 5 4 12 13 3.6

H2S 28.5 Feb-04 07:00 0.9 136 6 0.0 8 4 12 28 3.3

H2S 33.4 Feb-04 08:00 0.9 144 5 0.0 8 5 10 33 3.1

H2S 24.3 Feb-04 09:00 1.0 123 4 0.0 6 6 9 24 2.5

H2S 17.2 Feb-04 10:00 1.2 98 6 0.0 7 4 11 17 2.1

H2S 11.1 Feb-04 12:00 1.1 151 8 0.0 7 5 16 11 2.7

H2S 21.4 Feb-11 09:00 0.6 131 6 0.0 2 2 12 21 0.0

H2S 13.2 Feb-11 10:00 1.1 155 6 0.0 3 5 12 13 1.0

H2S 17.7 Feb-21 22:00 0.5 113 9 0.0 6 4 17 18 2.2

H2S 15.4 Feb-27 07:00 0.9 147 14 0.0 3 1 28 15 0.0

H2S 19.2 Feb-27 08:00 1.0 129 13 0.0 6 2 26 19 0.0

H2S 21.9 Feb-27 09:00 0.9 119 12 0.0 6 3 24 22 0.1

H2S 15.7 Feb-27 22:00 1.2 127 17 0.0 19 4 34 16 0.6

H2S 14.9 Feb-28 08:00 1.7 135 12 0.0 27 7 24 15 0.9

H2S 11.0 Feb-28 09:00 1.1 133 12 0.0 17 6 24 11 0.4

H2S 12.5 Feb-29 00:00 0.6 149 11 0.0 5 8 23 12 3.6

H2S 13.5 Feb-29 04:00 0.7 95 11 0.0 4 7 21 13 0.7

H2S 18.0 Feb-29 05:00 0.8 92 10 0.0 5 6 20 18 0.6

H2S 13.6 Feb-29 06:00 1.5 90 10 0.0 5 7 21 14 0.8

H2S 11.2 Mar-01 08:00 2.2 87 15 0.0 4 5 30 11 11.9

H2S 12.7 Mar-04 00:00 0.9 105 19 0.0 14 4 37 13 4.8

H2S 21.1 Mar-12 00:00 0.6 119 9 0.0 1 7 17 21 6.5

H2S 12.2 Mar-12 01:00 1.4 87 8 0.0 1 7 16 12 6.1

H2S 15.1 Mar-13 02:00 1.1 107 12 0.0 5 1 24 15 1.2

H2S 19.7 Mar-13 22:00 2.0 163 12 0.0 8 3 25 20 5.6

H2S 92.3 Mar-21 23:00 1.0 133 10 0.0 12 3 20 92 2.1

H2S 22.9 Mar-22 00:00 0.7 129 8 0.0 21 7 17 23 3.3

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68

Table D-1. Weyburn Station: Summary of exceedances for 1-hour SAAQS for the year 2012

(continued)

1-Hour Exceedance Pollutant Other Parameters During the Exceedance Event

Pollutant Conc. Exceedance Time WS WD AQI Rain SO2 NO2 O3 H2S PM2.5

ppb mmm-dd hh:mm m/s deg - mm ppb ppb ppb ppb µg/m3

H2S 16.3 Mar-22 01:00 0.1 63 9 0.1 20 4 19 16 5.4

H2S 11.1 May-09 23:00 0.9 140 9 0.0 9 7 18 27 10.8

H2S 26.7 May-10 00:00 2.3 267 12 0.1 4 5 25 13 9.0

H2S 13.1 May-10 01:00 0.7 144 20 0.0 1 2 40 1 6.4

H2S 14.6 May-17 03:00 1.0 93 7 0.0 2 4 14 12 9.0

H2S 11.9 May-17 04:00 0.6 108 7 0.0 2 5 10 3 8.1

H2S 11.7 May-21 22:00 1.2 87 17 0.0 2 3 34 4 11.8

H2S 12.8 May-28 02:00 1.0 158 8 0.0 3 2 17 3 1.3

H2S 11.8 Jun-02 05:00 0.4 112 7 0.0 3 8 14 12 4.4

H2S 13.1 Jul-03 06:00 1.2 38 5 0.0 1 5 3 13 6.1

H2S 18.1 Jul-11 02:00 1.1 105 12 0.0 13 3 24 10 7.5

H2S 14.8 Jul-11 05:00 1.2 149 10 0.0 7 0 19 12 6.8

H2S 11.9 Jul-11 06:00 1.3 130 10 0.0 6 0 20 7 5.9

H2S 12.1 Jul-19 07:00 1.2 216 5 0.0 2 0 9 7 6.3

H2S 28.9 Jul-27 04:00 0.4 181 3 0.0 4 4 5 24 3.2

H2S 23.8 Jul-27 05:00 0.3 93 3 0.0 2 3 5 8 3.5

H2S 19.5 Jul-27 07:00 0.9 87 4 0.0 3 2 7 10 5.0

H2S 60.6 Aug-06 01:00 0.6 287 9 0.0 2 8 4 14 11.0

H2S 13.9 Aug-06 02:00 0.9 335 8 0.0 2 7 4 9 10.0

H2S 13.4 Aug-08 00:00 0.7 157 11 0.0 2 5 6 10 12.9

H2S 30.8 Aug-17 00:00 0.7 145 20 0.0 3 7 15 5 24.0

H2S 12.7 Aug-17 02:00 0.9 123 9 0.0 8 3 17 10 8.0

H2S 13.6 Aug-17 04:00 0.8 166 9 0.0 5 2 18 4 2.4

H2S 12.7 Aug-19 01:00 0.5 118 10 0.0 1 3 20 4 9.9

H2S 12.5 Aug-19 04:00 1.2 88 8 0.0 2 3 14 8 9.5

H2S 10.9 Aug-19 08:00 1.7 106 7 0.0 3 2 15 8 8.7

H2S 17.5 Aug-20 22:00 0.6 36 16 0.0 1 5 32 25 18.2

H2S 25.2 Aug-20 23:00 0.3 193 12 0.0 1 7 24 11 14.8

H2S 10.9 Aug-21 00:00 0.4 245 13 0.0 1 5 19 6 15.8

H2S 16.7 Aug-21 08:00 0.8 121 13 0.0 5 3 12 29 15.5

H2S 28.8 Aug-21 09:00 2.1 82 16 0.0 3 3 33 7 18.0

H2S 11.8 Aug-22 03:00 0.6 90 12 0.0 5 3 24 12 10.3

H2S 12.1 Aug-22 04:00 1.3 114 10 0.0 6 3 20 8 11.7

H2S 17.2 Aug-22 06:00 1.0 128 13 0.0 27 3 26 9 10.1

H2S 13.0 Aug-28 21:00 0.8 113 26 0.0 1 3 49 2 31.8

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69

Table D-1. Weyburn Station: Summary of exceedances for 1-hour SAAQS for the year 2012

(continued)

1-Hour Exceedance Pollutant Other Parameters During the Exceedance Event

Pollutant Conc. Exceedance Time WS WD AQI Rain SO2 NO2 O3 H2S PM2.5

ppb mmm-dd hh:mm m/s deg - mm ppb ppb ppb ppb µg/m3

H2S 14.6 Aug-30 23:00 0.8 117 13 0.0 15 3 26 6 11.4

H2S 15.7 Sep-08 22:00 0.4 125 14 0.0 2 2 22 9 17.3

H2S 15.2 Sep-09 03:00 1.1 120 8 0.0 10 3 16 8 4.1

H2S 12.7 Sep-09 22:00 1.2 134 16 0.0 7 3 31 4 19.1

H2S 13.3 Sep-10 00:00 0.9 137 14 0.0 20 2 28 17 8.6

H2S 17.1 Sep-10 01:00 1.1 121 14 0.0 13 2 29 10 8.8

H2S 11.8 Sep-10 08:00 2.7 266 12 0.0 2 3 23 4 10.7

H2S 20.9 Sep-22 05:00 0.6 104 7 0.0 1 2 14 10 1.8

H2S 12.1 Oct-14 21:00 1.1 129 9 0.0 14 7 18 16 4.0

H2S 15.9 Oct-14 22:00 1.2 137 9 0.1 25 5 19 5 3.1

H2S 14.8 Oct-20 06:00 1.3 111 3 0.0 3 6 5 7 2.7

H2S 16.8 Oct-22 00:00 1.0 155 6 0.0 4 6 12 12 3.4

H2S 11.8 Oct-22 01:00 0.8 139 6 0.0 15 5 13 13 4.0

H2S 13.1 Oct-22 02:00 0.9 106 6 0.0 5 5 12 10 3.4

H2S 16.0 Oct-22 04:00 0.7 116 4 0.0 1 6 7 7 2.8

H2S 14.9 Oct-31 00:00 1.4 86 3 0.0 2 3 5 12 2.5

H2S 12.3 Oct-31 01:00 1.1 93 3 0.0 2 3 6 4 2.8

H2S 18.8 Nov-13 05:00 0.8 147 13 0.0 5 4 25 21 2.5

H2S 20.7 Nov-13 06:00 1.3 46 13 0.0 5 3 26 18 2.4

H2S 18.1 Nov-13 07:00 0.8 154 11 0.0 3 5 22 21 1.3

H2S 21.4 Nov-13 08:00 0.6 206 7 0.0 5 13 14 14 0.6

H2S 13.5 Nov-13 09:00 1.3 167 9 0.0 2 11 18 5 0.5

H2S 21.6 Nov-13 12:00 1.9 102 13 0.0 11 6 26 18 3.0

H2S 18.2 Nov-13 13:00 1.6 134 15 0.0 9 5 31 4 2.6

H2S 11.4 Nov-14 10:00 1.3 163 13 0.0 7 11 26 6 1.3

H2S 14.5 Nov-15 09:00 1.2 162 11 0.0 2 9 22 6 1.7

H2S 15.7 Nov-16 14:00 1.1 159 15 0.0 13 4 31 3 2.1

H2S 12.9 Nov-17 03:00 1.2 99 10 0.0 4 5 19 19 1.9

H2S 19.0 Nov-17 04:00 1.1 94 7 0.0 3 7 15 18 2.3

H2S 17.8 Nov-17 05:00 1.3 104 7 0.0 2 9 14 23 2.2

H2S 22.9 Nov-17 06:00 1.5 125 9 0.0 2 8 17 8 2.3

H2S 12.6 Dec-10 06:00 1.0 131 15 0.0 11 2 30 26 6.4

H2S 26.2 Dec-10 07:00 1.1 150 14 0.0 9 2 28 10 6.8

H2S 14.9 Dec-11 11:00 2.9 99 9 0.0 13 6 18 4 9.6

H2S 25.4 Dec-20 03:00 1.1 126 10 0.0 11 5 20 20 7.6

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70

Table D-1. Weyburn Station: Summary of exceedances for 1-hour SAAQS for the year 2012

(continued)

1-Hour Exceedance Pollutant Other Parameters During the Exceedance Event

Pollutant Conc. Exceedance Time WS WD AQI Rain SO2 NO2 O3 H2S PM2.5

ppb mmm-dd hh:mm m/s deg - mm ppb ppb ppb ppb µg/m3

H2S 19.9 Dec-20 04:00 1.2 124 9 0.0 5 6 19 8 7.4

H2S 11.8 Dec-26 10:00 1.7 97 14 0.0 4 3 28 8 3.5

H2S 32.4 Dec-28 23:00 1.1 163 14 0.0 9 7 18 15 16.7

H2S 15.3 Dec-29 00:00 1.5 126 15 0.0 8 6 19 8 17.7

H2S 12.0 Dec-29 02:00 1.4 141 12 0.0 3 8 17 7 14.0

H2S 12.5 Dec-29 13:00 0.9 141 12 0.0 15 5 24 4 10.2

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Table D-2. Weyburn Station: Summary of exceedances for 24-hour SAAQS for the year 2012

24-Hour Exceedance Pollutant Other Parameters During the Exceedance Event

Pollutant Conc. Exceedance Date WS WD AQI Rain SO2 NO2 O3 H2S PM2.5

ppb mmm-dd m/s deg - mm ppb ppb ppb ppb µg/m3

H2S 8.1 Feb-4 1.2 148 9 0.0 5 4 17 8.1 2.6

H2S 3.7 Feb-11 1.0 169 12 0.0 3 2 24 3.7 -

H2S 5.0 Feb-27 1.4 147 16 0.0 5 2 32 5.0 -

H2S 4.2 Feb-28 1.5 113 15 0.0 7 6 30 4.2 2.8

H2S 4.4 Feb-29 1.8 110 15 0.0 4 6 30 4.4 3.8

H2S 5.1 Mar-21 4.0 220 19 0.0 2 1 37 5.1 -

H2S 4.2 Mar-22 2.5 86 16 0.0 5 3 32 4.2 5.0

H2S 5.0 Jul-11 1.9 209 22 0.0 4 2 31 5.0 24.1

H2S 5.5 Jul-27 1.3 124 21 0.0 3 2 30 5 21.5

H2S 5.3 Aug-6 1.8 192 14 0.0 1 3 24 5.3 8.0

H2S 3.7 Aug-17 2.0 230 18 0.0 3 3 35 3.7 4.3

H2S 5.0 Aug-19 1.6 107 18 0.0 2 2 34 5.0 9.4

H2S 4.7 Aug-20 2.0 172 19 0.0 2 3 37 5 7.7

H2S 5.1 Aug-21 1.2 173 20 0.0 2 3 38 5 10.1

H2S 4.9 Aug-22 1.7 170 19 0.0 6 3 36 5 13.3

H2S 4.8 Sep-9 1.7 139 16 0.0 6 2 32 4.8 7.5

H2S 3.7 Sep-10 3.3 222 20 0.0 4 2 40 3.7 9.1

H2S 5.0 Sep-22 1.5 107 13 0.0 3 2 26 5.0 5.6

H2S 4.9 Oct-14 1.7 182 10 0.0 5 4 18 4.9 4.9

H2S 4.4 Oct-22 3.2 106 10 0.0 3 4 21 4.4 3.6

H2S 8.5 Nov-13 1.4 128 14 0.0 6 6 28 9 2.5

H2S 4.0 Nov-16 1.3 143 13 0.0 6 6 25 4 1.7

H2S 6.2 Nov-17 1.5 124 11 0.0 4 9 22 6 4.4

H2S 4.1 Dec-10 3.4 246 14 0.0 4 4 28 4 8.9

H2S 6.0 Dec-20 1.8 113 10 0.0 7 8 19 6 8.2

H2S 4.6 Dec-26 1.3 119 15 0.0 9 3 29 5 3.4

H2S 4.1 Dec-28 1.7 229 15 0.0 4 4 24 4 13.1

H2S 4.6 Dec-30 4.4 285 18 0.0 2 3 32 2 7.7

24-Hour Exceedance Pollutant Other Parameters During the Exceedance Event

Pollutant Conc. Exceedance Date WS WD AQI Rain SO2 NO2 O3 H2S PM2.5

µg/m3 mmm-dd m/s deg - mm ppb ppb ppb ppb µg/m

3

PM2.5 45 Jul-13 1.7 218 34 0.0 2 3 35 3 45.0

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APPENDIX E. GLEN EWEN STATION: EXCEEDANCE SUMMARY

Table E-1. Glen Ewen Station: Summary of exceedances for 1-hour SAAQS for the year 2012

1-Hour Exceedance Pollutant Other Parameters During the Exceedance Event

Pollutant Conc. Exceedance Time WS WD AQI Rain SO2 NO2 O3 H2S

ppb mmm-dd hh:mm m/s deg - mm ppb ppb ppb ppb

H2S 17.5 Jun-01 06:00 2.3 201 16 0.0 0 4 31 17.5

H2S 11.9 Jul-30 03:00 1.7 290 8 0.0 0 2 16 11.9

H2S 17.3 Aug-22 05:00 0.7 300 8 0.0 0 2 16 17.3

H2S 11.0 Aug-26 23:00 0.2 46 7 0.0 0 3 14 11.0

H2S 13.6 Aug-27 08:00 0.7 119 3 0.0 0 2 6 13.6

H2S 12.6 Sep-10 00:00 1.5 114 11 0.0 3 2 23 12.6

H2S 11.6 Sep-23 04:00 2.8 342 3 0.0 0 1 7 11.6

H2S 33.9 Dec-10 06:00 2.5 130 18 0.0 2 2 35 33.9

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APPENDIX F. PASSIVE MONITORING DATA

Table F-1. 30-day average concentration for passive SO2 samples for the year 2012

Passive Site 30-Day Passive SO2 Concentration (ppb) AVG MAX MIN

No. Name Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

1 Carnduff 0.3 0.2 0.1 0.1 0.2 0.3 0.2 - - - - - 0.2 0.3 0.1

2 Glen Ewan 0.5 0.3 0.2 0.2 0.2 0.2 0.1 0.3 0.6 0.8 0.3 0.7 0.4 0.8 0.1

3 North Portal 0.6 0.3 0.3 0.2 0.2 0.6 0.2 - - - - - 0.3 0.6 0.2

4 Roche Percee 0.4 0.4 0.1 0.2 0.1 0.3 F 0.4 0.6 0.8 0.3 1 0.4 1.0 0.1

5 Estevan 0.3 0.4 0.3 0.3 0.2 0.1 0.3 0.3 0.9 0.7 0.1 0.6 0.4 0.9 0.1

6 Torquay 0.2 0.2 <0.1 0.2 0.2 0.2 0.2 - - - - - 0.2 0.2 <0.1

7 Tribune 0.2 0.3 0.4 0.5 0.3 0.1 0.2 0.3 0.5 0.9 0.3 1.1 0.4 1.1 0.1

8 Macoun 0.3 0.3 0.2 0.2 0.4 0.1 0.2 - - - - - 0.2 0.4 0.1

9 Kingsford 0.7 0.2 0.1 0.9 0.1 0.3 0.4 - - - - - 0.4 0.9 0.1

10 Alameda 0.5 0.3 0.3 0.4 0.3 0.2 0.3 0.2 0.6 0.5 0.2 0.6 0.4 0.6 0.2

11 Oxbow 0.4 0.2 0.2 0.1 0.2 0.2 0.2 - - - - - 0.2 0.4 0.1

12 Storthoaks 0.3 0.3 0.5 0.5 0.4 0.2 0.2 0.3 0.7 0.7 0.3 0.7 0.4 0.7 0.2

13 Redvers 0.2 0.2 0.1 0.1 0.2 0.2 0.4 0.5 0.6 0.7 0.2 0.6 0.3 0.7 0.1

14 Steppes 0.3 0.3 0.1 0.2 0.3 0.1 0.4 - - - - - 0.2 0.4 0.1

15 Wordsworth 0.5 0.3 0.1 0.1 0.3 0.3 0.4 - - - - - 0.3 0.5 0.1

16 Kisbey 0.5 0.3 0.2 0.1 0.3 <0.1 1.1 - - - - - 0.4 1.1 <0.1

17 Huntoon 0.3 0.3 0.1 0.2 0.4 0.1 0.2 0.3 0.7 0.4 0.2 0.6 0.3 0.7 0.1

18 Ralph 0.5 0.3 0.1 0.2 0.4 0.1 0.2 - - - - 0.3 0.5 0.1

19 Talmage 0.5 0.3 0.2 0.1 0.4 0.1 0.1 <0.1 0.6 0.6 0.3 0.8 0.4 0.8 <0.1

20 Creelman 0.3 0.3 0.2 0.1 0.6 0.2 0.2 - - - - - 0.3 0.6 0.1

21 Warmley 0.4 0.3 0.2 0.2 0.4 0.3 0.2 - - - - - 0.3 0.4 0.2

22 Kenosse Lake 0.3 0.3 0.5 0.2 0.4 0.6 0.2 0.6 0.7 0.4 0.3 0.7 0.4 0.7 0.2

23 Ryerson 0.3 0.3 0.3 0.1 0.3 0.3 0.1 - - - - - 0.2 0.3 0.1

24 Wapella 0.2 0.3 0.2 0.1 0.2 0.3 0.2 0.5 0.8 0.6 0.2 0.6 0.4 0.8 0.1

25 Baring 0.6 0.3 0.1 0.1 0.1 0.4 0.2 - - - - - 0.3 0.6 0.1

26 Odessa 0.4 0.3 0.3 0.2 0.1 <0.1 0.1 0.3 0.5 0.6 0.2 0.6 0.3 0.6 <0.1

27 Esterhazy 0.2 0.3 0.1 <0.1 0.1 <0.1 0.2 - - - - - 0.1 0.3 <0.1

28 Bangor 0.2 0.2 0.1 0.1 0.2 0.2 0.1 0.7 0.5 0.5 0.1 0.4 0.3 0.7 0.1

29 ATCO 1.2 2.2 2.7 0.7 0.9 1.2 1.8 1.4 0.4 0.7 0.2 1.1 1.2 2.7 0.2

30 ATCO 1.5 3.0 1.0 3.0 1.8 3.2 2.4 1.6 0.4 0.9 0.2 0.9 1.7 3.2 0.2

Network Average 0.4 0.4 0.3 0.3 0.3 0.4 0.4 0.6 0.6 0.7 0.2 0.7 0.4 3.2 <0.1

F: Sample Failure

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Table F-2. 30-day average concentration for passive NO2 samples for the year of 2012

Passive Site 30-Day Passive NO2 Concentration (ppb) AVG MAX MIN

No. Name Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

1 Carnduff 1.5 0.8 1.1 1.2 2.5 2.2 1.4 - - - - - 1.5 2.5 0.8

2 Glen Ewan 2.0 0.9 1.2 1.6 2.3 2.1 1.8 0.9 2.7 3.8 1.2 1.1 1.8 3.8 0.9

3 North Portal 2.6 1.6 2.1 1.9 2.9 3.8 2.2 - - - - - 2.4 3.8 1.6

4 Roche Percee 3.5 2.6 3.3 2.2 2.5 2.8 F 1.1 3.9 3.3 3.8 3.5 3.0 3.9 1.1

5 Estevan 1.5 0.9 1.3 2.2 3.5 3.9 2.4 - - - - - 2.2 3.9 0.9

6 Torquay 1.2 0.7 1.0 1.9 0.9 2.9 2.5 - - - - - 1.6 2.9 0.7

7 Tribune 1.0 0.6 0.9 3.5 3.5 3.3 2.6 2.3 3.5 2.8 2.7 2.4 2.4 3.5 0.6

8 Macoun 2.0 1.4 1.9 1.6 2.6 2.8 2.2 - - - - - 2.1 2.8 1.4

9 Kingsford 1.5 0.8 1.2 1.8 2.2 2.2 1.9 - - - - - 1.7 2.2 0.8

10 Alameda 2.3 1.2 1.6 1.9 3.5 2.2 2 - - - - - 2.1 3.5 1.2

11 Oxbow 0.9 1.2 1.6 1.0 2.7 1.8 1.6 - - - - - 1.5 2.7 0.9

12 Storthoaks 2.0 1.0 1.3 1.0 2.7 2.2 1.9 2.4 2.2 2.5 1.8 1.4 1.9 2.7 1.0

13 Redvers 2.4 1.1 1.5 0.9 3.0 2.0 1.4 - - - - - 1.8 3.0 0.9

14 Steppes 1.8 1.3 1.8 1.3 2.3 2.0 1.4 - - - - - 1.7 2.3 1.3

15 Wordsworth 1.5 2.1 2.8 1.1 3.0 2.1 1.6 - - - - - 2.0 3.0 1.1

16 Kisbey 1.4 1.2 1.7 1.0 2.1 1.8 1.9 - - - - - 1.6 2.1 1.0

17 Huntoon 10.2 1.6 2.1 0.8 3.7 2.7 2.5 3.5 3.7 3.4 3.3 3.7 3.4 10.2 0.8

18 Ralph 2.8 1.5 1.9 1.9 2.8 2.8 2.6 - - - - - 2.3 2.8 1.5

19 Talmage 1.9 1.0 1.3 1.9 2.1 2.7 2.4 - - - - - 1.9 2.7 1.0

20 Creelman 2.5 1.3 1.7 1.4 2.6 2.3 1.4 - - - - - 1.9 2.6 1.3

21 Warmley 2.0 1.5 2 0.8 1.0 1.2 1.5 - - - - - 1.4 2.0 0.8

22 Kenosse Lake 1.5 0.7 1.0 1.3 1.4 1.4 1.9 2.5 2.5 2.1 1.8 1.9 1.7 2.5 0.7

23 Ryerson 2.3 1.1 1.5 0.9 2.1 1.5 1.6 - - - - - 1.6 2.3 0.9

24 Wapella 1.9 1.0 1.4 1.3 1.5 1.5 1.7 1.9 2.9 2.0 1.9 2.5 1.8 2.9 1.0

25 Baring 0.8 0.3 0.4 0.3 0.6 0.5 1.6 - - - - - 0.6 1.6 0.3

26 Odessa 1.7 3.2 4 1.1 1.4 1.8 0.9 1.3 3 1.9 2.5 1.8 2.1 4.0 0.9

27 Esterhazy 1.0 0.3 0.5 0.6 2.2 1.3 1.3 - - - - - 1.0 2.2 0.3

28 Bangor 1.8 0.8 1.2 1.4 2.5 1.8 1.7 1.9 3.2 2.8 1.6 2 1.9 3.2 0.8

Network Average 2.1 1.2 1.6 1.4 2.4 2.2 1.8 2.0 3.1 2.7 2.3 2.3 1.9 10.2 0.3

F: Sample Failure

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Table F-3. 30-day average concentration for passive O3 samples for the year of 2012

Passive Site 30-Day Passive O3 Concentration (ppb) AVG MAX MIN

No. Name Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

2 Glen Ewan 20 24 26 27 26 30 30 25 20 18 20 26 24 30 18

4 Roche Percee 22 22 27 25 27 27 F 29 19 20 26 30 25 30 19

7 Tribune 25 24 19 27 32 31 32 29 22 22 26 33 27 33 19

10 Alameda 22 26 24 30 31 29 30 - - - - - 28 31 22

12 Storthoaks 21 23 25 17 29 30 28 25 17 24 22 31 24 31 17

14 Steppes 25 26 27 31 31 36 23 - - - - - 28 36 23

17 Huntoon 23 24 28 15 31 32 27 27 20 24 25 31 26 32 15

19 Talmage 26 26 27 29 33 32 23 - - - - - 28 33 23

22 Kenosse Lake 33 27 29 30 34 31 25 28 21 26 26 32 28 34 21

24 Wapella 26 26 27 30 32 30 23 25 22 25 26 30 27 32 22

26 Odessa 25 26 25 30 30 32 19 22 27 24 28 32 27 32 19

28 Bangor 26 25 28 31 32 31 22 25 22 28 30 29 28 32 22

Network Average 25 25 26 27 31 31 26 26 21 23 25 30 27 36 15

F: Sample Failure

Table F-4. 30-day average concentration for passive H2S samples for the year of 2012

Passive Site 30-Day Passive H2S Concentration (ppb) AVG MAX MIN

No. Name Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

5 Estevan - - - - - - - 0.7 0.7 0.5 0.5 1.1 0.7 1.1 0.5

10 Alameda - - - - - - - 0.5 0.5 0.7 0.7 0.9 0.6 0.9 0.5

13 Redvers - - - - - - - 0.8 0.8 0.6 0.6 0.8 0.7 0.8 0.6

19 Talmage - - - - - - - 0.7 0.7 0.5 0.5 1.0 0.7 1.0 0.5

29 ATCO 0.6 0.8 1.0 0.4 0.3 1.5 1.3 0.5 0.6 0.6 0.6 1.0 0.8 1.5 0.3

30 ATCO 0.8 1.1 0.9 0.9 0.5 1.7 1.8 0.6 0.7 0.8 0.6 0.9 0.9 1.8 0.5

Network Average 0.7 0.9 0.9 0.6 0.4 1.6 1.5 0.6 0.7 0.6 0.6 0.9 0.7 0.2 0.1

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Table F-5. 30-day average concentration for passive NH3 and BTEX samples for 2012

Pollutants Passive Site 30-Day Passive Concentration (ppb) AVG MAX MIN

No. Name Aug Sep Oct Nov Dec

NH3 20 Creelman 1.9 1.5 1.4 0.3 1.1 1.2 1.9 0.3

Benzene 8 Macoun 0.4 0.3 0.3 <0.1 0.5 0.3 0.5 <0.1

11 Oxbow 0.4 0.2 0.3 0.1 0.4 0.3 0.4 0.1

Toluene 8 Macoun <0.1 0.2 0.4 <0.1 0.5 0.3 0.5 <0.1

11 Oxbow 0.6 0.3 0.6 0.1 0.1 0.3 0.6 0.1

Ethylbenzene 8 Macoun <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2

11 Oxbow <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2

Xylene 8 Macoun <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2

11 Oxbow <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2

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APPENDIX G. 2012 FINANCIAL STATEMENTS

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APPENDIX H. SESAA BOARD OF DIRECTORS

Board of Directors and Alternates

Terry Gibson Executive Director

Mr. Gibson brings nearly 30 years of Public Health/Environmental Health experience to

the position. He has held the positions of President of the Saskatchewan Public Health

Association and Vice-Chair of the Saskatchewan Epidemiology Association. He teaches

Public Health Protection at the University of Saskatchewan Master of Public Health

Program and has served on many provincial and national boards and committees.

Terry is committed to working with industry and regulators in a consensus decision

making process to ensure that the health of the environment of south east Saskatchewan is

always protected.

Chuck Bosgoed Director (Saskatchewan Environment)

Mr. Bosgoed is an Environmental Engineer who has worked with Saskatchewan

Environment for over 25 years. He is involved in the airshed because he believes

airshed management is an excellent approach to better understand air issues and one

more way to resolve regional air quality problems. Mr. Bosgoed writes, “Being a

member of the Board provides me, as an environmental regulator, with a new and

effective way of dealing with air quality issues.”

Alternate: Murray Hilderman

Debbie Nielsen Manager, Environmental Programs, SaskPower

Ms. Nielsen has worked with SaskPower in a variety of capacities dealing with

environmental issues and programs for the past 19 years. In her current capacity she

manages SaskPower's corporate environmental department which provides technical,

analytical, environmental and regulatory decision-making support to the company's

business units and support groups.

Engaging with key environmental stakeholders to develop a better understanding of

issues is also a key responsibility of her position. She is a strong believer that by working in

collaborative partnerships such as the airshed association, more sustainable outcomes can be

achieved.

Alternate: David Smith

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Dean Pylypuk Saskatchewan Industry & Resources

Dean Pylypuk is the Regional Manager for Area 4 with The Ministry of Energy and

Resources. Dean began his career in the oil and gas industry in 1972 working

throughout Western Canada and the Arctic Islands. In 1980 the Pylypuk family moved

overseas where Dean was employed as a Rig Manager with Kenting Drilling UK.

Returning to Canada, Dean joined the Petroleum Development Branch of the then

Department of Energy and Mines in July of 1984 and has been head quartered in

Estevan from that time to present. A graduate of the University of Regina Extension Program,

Mr. Pylypuk has two certificates in Administration and has been a member of Saskatchewan

Applied Science Technologists and Technicians since 1987.

Alternate: Todd Han

Darlene Sakires Director (Canadian Natural Resources Limited)

Ms. Sakires is an Environmental Coordinator who is responsible for CNRL’s

Environmental Management Plan and Environmental Operating Guidelines. She

manages site decommissioning and remediation projects across the prairies, ensuring

compliance with environmental regulatory requirements in all aspects of the

company’s operations. She is active on a variety of committees, including the

Saskatchewan Petroleum Industry Government Environmental Committee and the

Saskatchewan Environmental Managers Association.

Alternate: John Hutt

Chris Seeley Saskatchewan Health

Mr. Seeley is the Public Health Engineer with the Ministry of Health. He provides

technical and policy advice to Regional Health Authorities in many environmental

health areas including drinking water, wastewater, and swimming pools. He is

involved with the airshed association to support its activities in providing information

about air quality.

Alternate: Grant Paulson

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Shane Boyes Councillor, Rural Municipality of Enniskillen Number 3

Mr. Boyes represents the R. M. of Enniskillen No.3. He has lived in this area for most of

his life. He brings the concerns and experiences of living in an area with heavy oil and

gas production from both the standpoint of a landowner and resident as well as that of

someone who works in the oil and gas industry. He provides input to the Board

regarding the people in rural southeast Saskatchewan.

Rose McInnes

Rose has experience in air quality monitoring and laboratory testing on water and soils. She has

experience with all general laboratory duties. Rose brings her practical environmental skills to the Board.

Rose is an A.Sc.T; as an Environmental Technologist, her business, Blue Earth Environmental, deals with

water/wastewater issues and will soon expand to recycling/waste management.

Marge Young

Marge is a retired teacher who lives in Estevan. She taught for 32.5 years, most of them in Estevan. She

has lived in Estevan since she was 16 years old. She has been interested in the air quality in this area for

many years.

Brian Johnson

Brian has served as an Estevan City Councillor for the past 12 years and recently re-elected for another

term. He presently works at SaskPower at BDPS as an Electrical Supervisor, he has been working with

this Crown Corporation for 36 years now.

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APPENDIX I. SESAA MEMBER COMPANIES

SESAA would like to express our gratitude to our members in good standing for their support of

SESAA, for their very strong support regarding quality air data collection, and for their

commitment to the citizens and environment of south east Saskatchewan.

• 101033165 Saskatchewan Ltd.

• 618555 Saskatchewan Ltd. TDL Petroleum

• Abenteuer Resources Corp.

• Admiralty Oils

• Advantage Oil and Gas

• Aldon Oils

• Antoinway Resources

• Apache Canada Ltd.

• ARC Resources

• ATCO Midstream Ltd.

• AvenEx Energy

• Barracuda Energy

• Base Resources Inc.

• Baytex

• Black Rider Resources Inc.

• Bluebird Resources

• Bonterra Energy

• Border Energy Ltd

• Brown Bros. Resources

• Bulldog Oil and Gas

• Caje Holdings Ltd.

• Canada Capital Energy

• Canadian Natural Resources Limited

• Caprice Resources

• Cenovus Energy Inc.

• Chinook Iteration

• Coast Resources

• Condor Canada

• Conoco Phillips

• Contact Exploration

• Crescent Point Resources Partnership

• Daylight Energy

• Devon Canada Corporation

• Diaz Resources Ltd.

• EERG Energy ULC

• Elkhorn Resources

• Elswick Energy Ltd.

• Enermark Inc.

• Enerplus Corporation

• Fairborne Energy Ltd.

• Firesky Energy

• Flagstone Energy

• Frank R. Lee Investments

• Freemantle Petroleum

• GKN Resources Ltd.

• Gold River Oil and Gas

• Grand Bow Petroleum Limited

• Halvar Resources

• Highrock Energy

• Hillsdale Drilling

• Hummingbird Energy Inc (Virtus group)

• Husky Oil Operations Limited

• JDM Petroleum

• Jedi Exploration & Development

• K and S Investments Ltd.

• Kenwood Resources Ltd.

• Keystone Royalty

• Kinwest 2008 Energy

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• Kiwi Resources Ltd.

• Kootenay Energy

• Lakeco Holdings

• Legacy Oil and Gas

• Long Fortune

• Longview Oil

• Magellan Resources Ltd.

• Mancal Energy Inc.

• Marquee Energy LTD

• Midale Petroleums Ltd.

• Molopo Energy

• Mosaic

• NAL Resources Limited

• Nexxtep Resources

• Noramera Bioenergy

• Novus Energy Inc.

• Nuloch Resources Inc.

• Omatius Oil & Gas Ltd.

• Oneex Operations

• Openfield Ventures

• Painted Pony Petroleum

• Pemoco Ltd.

• Penn West Petroleum Ltd.

• Petrex Energy

• PetroBakken Energy Ltd.

• Petro One Energy

• Pinecrest Energy

• Pinto Resources

• Plains Midstream

• Primrose Drilling Ventures Ltd.

• Questerre Energy Corporation

• Regent Resources Ltd.

• Renegade Petroleum

• Rife Resources

• Runcible Oil Corp.

• Saskatchewan Environmental Industry and

Managers Association SEIMA

• SaskEnergy Incorporated/ TransGas Limited

• Sask Power

• Prairie Mines and Royalty (Sherritt Coal)

• Silver Bay Resources Ltd.

• Skywest Energy

• Southern Exploration

• Spartan Exploration

• Spectrum Resource Group

• Sure Energy Inc.

• T-45 Oil Corporation

• TAQA North

• T. Bird Oil Ltd.

• Tetonka Resources

• Texalta Petroleum Ltd.

• TransGas/SaskEnergy

• Triwest Exploration

• Valleyview Petroleums Ltd.

• Villanova Resources Inc.

• Viterra Inc.

• Williston Hunter Canada Inc.

• Zargon Oil & Gas Ltd..

How to Become a Member

For information on how to become a member, please contact Terry Gibson, Executive Director

at (306) 371 2478.