2004 fall natl acs meeting - polyacs.org

2004 Fall meeting

2004FallNATIONALACSMEETINGPhiladelphia,PA(Aug.22-27,2004)

ProgramMeetingChair:AllanGuymon

DeadlineforAbstractsandPolymerPreprints:April20,2004.*

*forgeneralpapersandsomesymposia(somesymposiumorganizersmaysetanearlierdeadline).

6thInternationalBiorelatedPolymersSymposiumR.M.Ottenbrite,DepartmentofChemistry,VirginiaCommonwealthUniversity,Richmond,VA23284,804-828-7502,e-mail:ottenbri@saturn.vcu.eduAdvancesinPhotoinitiatedPolymerizationC.N.Bowman,DepartmentofChemicalEngineering,UniversityofColorado,Boulder,ECCH111,Boulder,CO80309-0424,303-492-3247,fax303-492-4341,e-mail:[email protected];A.B.Scranton,DepartmentofChemicalandBiochemicalEngineering,UniversityofIowa,4133SC,IowaCity,IA52242-1219,(319)335-1414,fax319-335-1415,e-mail:[email protected](co-sponsoredwithPMSEandFederationofSocietiesofCoatingsTechnology)P.Zarras,MaterialsSynthesisBranch,NAWCWD,Code4T4220D,1AdministrationCircle,ChinaLake,CA93555,760-939-1396,fax760-939-1617,e-mail:[email protected];B.C.Benicewicz,NYSCenterforPolymerSynthesisandDepartmentofChemistry,RensselaerPolytechnicInstitute,CogswellLaboratory,Troy,NY12180,518-276-2534,fax518-276-6434,e-mail:[email protected];T.G.Wood,RohmandHaasCompany,727NorristownRd.,SpringHouse,PA19477-0904,215-641-7199,fax215-619-1658,e-mail:[email protected];B.Richey,RohmandHaasCompany,727NorristownRd.,SpringHouse,PA19477-0904,215-641-7178,fax215-619-1648,e-mail:[email protected]:FromTheorytoApplicationW.T.Ford,DepartmentofChemistry,OklahomaStateUniv,PS107,Stillwater,OK74078,405-744-5946,e-mail:[email protected];C.L.McCormick,DepartmentofPolymerScience,TheUniversityofSouthernMississippi,S.S.Box10076,Hattiesburg,MS39406,601-266-4221,fax601-266-6075,e-mail:[email protected],GroupTechnologyOffice,ICI,WindsorCourt,KingsmeadBusinessPark,LondonRoad,HighWycombe,Bucks,HP111JU,UnitedKingdom,441494467801,e-mail:[email protected];C.Pugh,DepartmentofPolymerScience,TheUniversityofAkron,Akron,OH44325-3909,330-972-6614,fax330-972-8864,e-mail:[email protected];R.S.Moore,EastmanKodakCo.(Retired),25CranstonRd.,Pittsford,NY14534,716-3813366,e-mail:[email protected];A.B.Salamone,RochalIndustries,740NW6thSt.,BocaRaton,FL33432,561-866-0930,e-mail:[email protected],ChemonicsInternational,EgyptMVE,113320thStreet,Suite600,Washington,DC20036,202-955-7593,fax202-955-7570,e-mail:[email protected],SchoolofDentistry/BiomaterialsResearchCenter,UniversityofColoradoHealthSciencesCenter,12635EastMontviewBlvd/Suite155,P.O.Box6508/MailStopF436,Aurora,CO80045-0508,303-724-1044,fax720-859-4110,e-mail:[email protected];J.M.Antonucci,PolymersDivision,NationalInstituteofStandardsandTechnology,100BureauDriveStop8545,Gaithersburg,MD20899,301-975-6794,fax301-963-9143,e-mail:joe.antonucci@nist.govIndustrialSponsorsAwardUnileverAwardGeneralPapersD.Garcia,ASR,AtofinaChemicalsInc,900FirstAvenue,KingofPrussia,PA19406,610-878-6731,e-mail:[email protected]

2004 Fall meeting

DIVISIONOFPOLYMERCHEMISTRY

Times,days,andpapernumbersmaynotbefinal.

C.A.Guymon,ProgramChair

SUNDAYMORNING

SectionAMarriott--SalonI&J

PolyelectrolytesandPolyampholytes:FromTheorytoApplication

Tutorial

C.L.McCormick,OrganizerW.T.Ford,Organizer,Presiding8:30—1.Polyelectrolytesolutions.Phenomenaandinterpretation.H.Morawetz9:10—2.Applicationsofpolyelectrolytesinaqueousmedia:Tutorial.R.S.Farinato9:50—3.PolyelectrolytesandPolyampholytes:Anoverviewofmajorstructuralfeaturesandmethodsofsynthesis.C.L.McCormick10:20—4.Polybetaines:Synthesis,solutionproperties,andapplications.A.B.Lowe10:50—5.Anoverviewofamphiphilicpolyelectrolytes:Characterizationoftheirassociativepropertiesandself-assemblednanostructuresinaqueousmedia.Y.Morishima11:20—6.Theoreticalmodelsofpolyelectrolytesandpolyampholytes.M.Rubinstein

SectionBMarriott--SalonH

GeneralPapers

PolymerSynthesis

D.Garcia,OrganizerS.Harrisson,Presiding8:00—7.Synthesisofstrontiumtitanate/polyanilinenanocompositesandthestudyoftheirelectrorheologicaleffect.K.Su,N.L.Yang8:20—8.Sulfonationofpoly(ethylenevinylalcohol)forelectroactivemembraneapplications.A.K.Phillips,A.Domenech,M.Wolbert,R.B.Moore8:40—9.Synthesisandcharacterizationofsubstitutedoligomersofphenyleneethynylenes.S.Percec,R.Getty,R.H.French,S.Lustig

2004 Fall meeting

9:00—10.Synthesisandcharacterizationofnovelcyclosiloxanesandtheirself-andco-condensationwithsilanol-terminatedpolydimethylsiloxane.J.Daum,G.Erdõdi,J.P.Kennedy9:20—11.Transitionfromlivingtochaingrowtholefinpolymerizationbyasingle-sitehomogeneousgroup4catalystinabatchreactor.S.V.Maddipati,J.Haq,A.E.Fenwick,K.Phomphrai,I.P.Rothwell,N.Delgass,J.M.Caruthers9:40—12.Room-temperatureatom-transferradicalpolymerisationofmethacrylatesinethyleneglycolsolvents.S.C.Moratti,S.M.Kimani10:00—13.Productionofω-primaryaminefunctionalizedpolymersbyatomtransferradicalpolymerization.S.Harrisson,K.L.Wooley10:20—14.BlockcopolymersbytheconversionoflivinglithiumanionicpolymerizationintolivingrutheniumROMP.T.C.Castle,E.Khosravi,L.R.Hutchings10:40—15.Synthesisofendfunctionalmultiplehydrogenbondedpolystyrenesandpoly(alkylacrylates)usingcontrolledradicalpolymerization.B.D.Mather,J.R.Lizotte,T.E.Long11:00—16.AEI:Endfunctionalizedpoly(3-alkylthiophenes)asbuildingblocksforthesynthesisofblockcopolymers.M.Jeffries-EL,M.C.Iovu,E.E.Sheina,G.Sauvé,R.D.McCullough11:20—17.Hyperbranchedpolymersynthesisbycontrolledterminationinananionicpolymerizationof4-(chlorodimethylsilyl)styrene.T.Huang,D.M.Knauss11:40—18.SynthesisofamphiphilicstarcopolymerA2B2ofpolystyreneandpoly(ethyleneoxide).M.Liu,P.F.Britt,J.W.Mays

SectionCMarriott--SalonG

PolymerScienceofEverydayThings

C.Pugh,R.S.Moore,andA.B.Salamone,OrganizersD.BottandK.J.Wynne,Organizers,Presiding8:30—19.Petcalves:Thescienceofdrums.N.Clarke9:10—20.ThescienceofBosesound.B.Lituri9:50—21.ChemistryandtheStradivarius.J.Nagyvary10:30—22.Theacousticguitar:FromclassicaltoIndierock.S.K.Pollack11:10—23.Reedsandlipsasvibrators(or"motorlipsandvibrators").T.C.B.McLeish11:50—24.Polymersandguitars:Sightsandsounds.D.Bott,G.E.Wnek

EmergingFrontiersinPolyolefins

Tutorial

CosponsoredwithSPE,andPMSE

SUNDAYAFTERNOON

2004 Fall meeting



PhysicalProperties

W.T.FordandC.L.McCormick,OrganizersV.KabanovandF.M.Winnik,Presiding1:30—25.Polyelectrolytesolutionrheology.S.Dou,R.H.Colby2:00—26.Studyofpolyelectrolyteintrinsicviscosityvs.solutionionicstrength:Experimentandtheory.T.S.Rushing,R.D.Hester2:20—27.SolutionbehaviorofpH-responsivepolyzwitterions:Acomparativestudyofpolyampholytesandpolybetaines.M.J.Fevola,J.K.Bridges,M.G.Kellum,R.D.Hester,C.L.McCormick2:40—28.Effectoftopologyontheaqueoussolutionbehaviorofamphiphilicblockandgraftcopolymersofn-butylacrylateandacrylicacid.A.H.E.Müller,Y.Cai,M.Hartenstein,M.Gradzielski,M.Zhang,H.Mori,D.V.Pergushov3:10—Intermission.3:25—29.Surfaceactivityandcolloidalpropertiesofhydrophobicallymodifiedpolyvinylamineinaqueoussolution.X.Chen,R.Pelton3:45—30.Analysisofsphericalpolyelectrolytebrushesbyanomaloussmall-angleX-rayscattering.M.Ballauff,M.Patel,S.Rosenfeldt,N.Dingenouts,D.Pontoni,T.Narayanan4:15—31.Titrationofpolycarboxylicacidsinmethanol.Polymerchainextension,ionizationequilibriaandconformationalmobility.S.K.Pearsall,M.M.Green,H.Morawetz4:35—32.Aboundaryintegral/statisticalmechanicalmethodforcomputingmacromoleculartitrationcurves.J.R.Feldkamp4:55—33.Ionicconductivity,electrochemicalandviscoelasticpropertiesofnetworksingleionconductorsbasedonpolyepoxideethersandlithiumbis(allylmalonato)borate.X.G.Sun,J.B.Kerr,G.Liu,C.L.Reeder,Y.Han


PolymersinDentalMaterials

NewMaterialsandAnalyticalApproaches

J.M.Antonucci,OrganizerJ.W.Stansbury,Organizer,Presiding1:30—IntroductoryRemarks.1:35—34.Firstcationicallycuringoxiranebaseddentalfillingmaterial.A.S.Eckert,K.Dede,S.Ehbrecht,T.Klettke,A.Spenkuch,A.Stippschild,C.Thalacker,W.Weinmann1:55—35.Thiol-enedentalmaterials.C.N.Bowman,H.Lu,J.W.Stansbury2:15—36.Thiol-eneoligomersasdentalrestorativematerial.J.A.Carioscia,H.Lu,J.W.Stansbury,C.N.Bowman

2004 Fall meeting

2:35—37.Organogelatorsandtheirapplicationindentalmaterials.E.A.Wilder,J.B.Quinn,J.M.Antonucci2:55—Intermission.3:15—38.AnalysisoftheinteractionsoftrialkoxysilaneswithdentalmonomersbyMALDI-TOFmassspectrometry.M.Farahani,J.M.Antonucci,C.M.Guttman3:35—39.Opticaldensityanddepthofcureinvisiblelight-curedfilled-resindentalrestorativematerials.B.W.Darvell,L.Musanje4:00—40.Simultaneouscharacterizationsofpolymerizationkineticsandvolumeshrinkageindimethacrylate/divinyletherhybridsystems.Y.Lin,J.W.Stansbury4:20—41.Glasstransitionregionofaphoto-cureddimethacrylate-effectofdegreeofcureandcontinuedpolymerizationduringmeasurement.W.D.Cook,T.Scott,S.Quay-Thevenon,J.Forsythe,W.Xia4:45—42.Effectofexternalheatingduringphotopolymerizationonstructureandpropertiesofdentalresins.M.Trujillo,J.W.Stansbury


PolymerScienceofEverydayThings

K.J.Wynne,D.Bott,andC.Pugh,OrganizersR.S.MooreandA.B.Salamone,Organizers,Presiding1:30—43.Polymersandtheartofcommunication:fromelectronicsandphotonicstodisplaysandstoragemedia.E.Reichmanis2:10—44.Polymers,particlesandpits:Theevolutionofrecordingmedia.A.J.Ryan2:50—45.Electronicpolymersandnanoscience-smarttags.A.G.MacDiarmid,J.VonEhr3:30—46.Boostinglithium-ionbatteries.M.Burchill4:10—47.Polymericmaterialsinwirelesstelecommunicationdevices.G.Kim

SectionDMarriott--SalonK

GeneralPapers

PolymerCharacterization

D.Garcia,OrganizerS.Manohar,Presiding1:00—48.NMRinvestigationonthecomplexationofPPI-3withzinc(II)ions.M.Chai,M.Ignash,A.K.Holley1:20—49.3D-NMRcharacterizationofbenzylketoneendgroupsofapolystyrenemacroinitiator.F.J.Wyzgoski,S.K.Sahoo,T.V.Holland,H.J.Harwood,P.L.Rinaldi1:40—50.CharacterizationofblendheterogeneityusingsynchrotronsmallangleX-rayscattering.G.C.Gemeinhardt,A.K.Phillips,K.A.Page,R.B.Moore2:00—51.Emergentnanostructuresinconductingpolymers.S.K.Manohar,X.Zhang,A.Wu,H.Kolla

2004 Fall meeting

2:20—52.Chemicalsynthesisofcarbonmicrobeads.L.Ding,S.V.Olesik2:40—53.Anomalousphaseseparationinmicro-tubes.X.Wang,N.Mashita3:00—54.Preparationofpolymericnanocapsuleswithperfluoroalkylwhiskersinsupercriticalcarbondioxide.Y.Z.Menceloglu,N.Bilgin,O.Akbulut,H.Taskent,K.Goren,B.Erman3:20—55.Sol-gelderivedhybridnanocompositesinporoussemicrystallinepolymers.S.H.Jain,H.Goossens,F.Picchioni,M.vanDuin,P.Lemstra3:40—56.Environmentalagingeffectsonpoly(ester-urethane)andpoly(vinylchloride-co-chlorotrifluoroethylene)polymericbinders.W.A.Rodin4:00—57.Changeofrheologicalpropertiesofpolystyrenee-b-poly(ethylene-alt-propylene)/squalanesolutionsbysulfonation.Z.Liu,M.T.Shaw4:20—58.Withdrawn.4:40—59.Modelassociativepolymernetworksgeneratedbyinclusioninteractionbetweenpolymerswithcyclodextrinandhydrophobicgrafts.X.Guo,A.A.Abdala,R.K.Prud'homme,S.F.Lincoln,S.A.Khan


Catalysts/Processes


SUNDAYEVENING

SectionAPennsylvaniaConventionCenter--HallD

GeneralPapers

PolymerSynthesisandCharacterization

D.Garcia,Organizer5:00-7:0060.Synthesisandcharacterizationofamphiphilicpoly(beta-alanine-block-beta-n-butylpeptiod).H.Xu,N.L.Gall,L.Jia61.Templatesynthesisofanovelmesoporouscross-linkedsulfonatedpoly(etheretherketone)membrane.C.Liu,J.Wang,J.Economy62.Synthesisofdiphenylethynyldiphenyletherandstudyofcuringreaction.F.Wang,J.Huang,F.Huang63.Livingcationicpolymerizationofvariouspolarfunctionalmonomersinthepresenceofaddedbases.M.Yonezumi,T.Tsujino,S.Sugihara,S.Kanaoka,S.Aoshima64.Precisionsynthesisofpoly(vinylether)sforsensitiveUCST-typephaseseparationinvarioussolvents.K.I.Seno,M.Inaoka,S.Kanaoka,S.Aoshima65.Precisionsynthesisofstimuli-responsivestar-shapedpolymersbylivingcationicpolymerization.T.Shibata,S.Kanaoka,S.Aoshima

2004 Fall meeting

66.Synthesisofblockcopolymerswithazobenzeneforphoto-responsiveandnewclassofsurfacemodification.T.Yoshida,S.Kanaoka,S.Aoshima67.Precisionsynthesisandthermosensitivebehaviorofdiblockandtriblockcopolymersofvinylethers.K.Nishikawa,Y.Hirabaru,S.Kanaoka,S.Aoshima68.Anovelopticallyactiverod-coil-rodtriblockcopolymerformsvesiclesindioxane/water.J.Zhang,Y.Yu,X.Wan,X.Chen,Q.Zhou69.Synthesisandopticalpropertiesofamacrocyclictrichromophorebundlewithparallel-aligneddipolemoments.Y.Liao,K.A.Firestone,B.H.Robinson,P.J.Reid,L.R.Dalton70.ReversibleDielsAldertypecross-linkableelectro-opticpolymerswithpendantTCF-basedchromophore.S.Bhattacharjee,J.Luo,M.Haller,A.K.Y.Jen,L.R.Dalton71.Synthesisandcharacterizationofpoly(3-hexylthiophene)-b-polystyrenedi-blockcopolymers.M.Iovu,M.Jeffries-EL,E.E.Sheina,A.Krankowski,G.Sauvé,R.D.McCullough72.Synthesisandopticalpropertiesoforgano-solublehyperbranchedpolybenzthiazolesfromA3+B2monomers.J.B.Baek,C.B.Lyons,L.S.Tan73.Synthesisofwell-definedDNA-basecontainingpolymersbyATRP.H.Tang,S.Ding,M.Radosz,Y.Shen74.Propargyl-terminatedhyperbranchedpoly(arylene-ether-ketone-imide)withvariousmolecularweightsandblendswithanethynyl-terminatedbisimideresin.D.H.Wang,J.B.Baek,H.Qin,P.T.Mather,F.E.Arnold,L.S.Tan75.Polymerizationofstyrenefrommultiwallcarbonnanotubes.B.Cheng,Y.Li,C.Shen76.Synthesisofhyperbranchedaromaticpolyamideswithfunctionalizations.W.Huh,J.Y.Kim,S.W.Lee,J.B.Baek77.Polymergraftingandcross-linkingbasedonradicalexchangereactionofalkoxyamines.H.Otsuka,Y.Higaki,A.Takahara78.Synthesisofaferrocenylmethylphosphine-containingpolymer.Q.S.Hu,C.G.Dong,Z.Y.Tang79.Amphiphilicpoly(meta-phenylene)s:Anovelconjugatedpolysoap;apossiblefoldamer?A.Som,S.Ramakrishnan80.Synthesisandcharacterizationofpoly(perfluoro-2-methylene-1,3-dioxolanes).W.Liu,Y.Koike,Y.Okamoto81.Helix-sense-selectivefreeradicalpolymerizationofachiralpromesogenicmonomer.Z.Yu,H.Cao,X.Chen,X.Wan,Q.Zhou82.Synthesisandcharacterizationofhighperformancepoly(thiophene).J.Graham,S.Jin,F.W.Harris,S.Z.D.Cheng,T.J.Bunning83.Synthesisandcharacterizationofsubstitutedortho-phenyleneethynyleneoligomers.G.N.Tew,T.V.Jones,R.Laos84.Synthesisofpolycarbosilaneelastomersviachain-internalandchain-endlatentcrosslinking.P.P.Matloka,J.C.Sworen,F.Zuluaga,K.B.Wagener85.Synthesisofpolyimidematerialsforradiationshielding.Y.Hu,S.Yang,C.S.Park,R.A.Orwoll,B.J.Jensen86.Useof9-bromoanthracenephotodimersintheatomtransferradicalpolymerizationofstyrene.A.C.Roof,L.J.Bayne,E.S.Tillman87.Synthesisofgradientcopolymerbrushesviasurfaceinitiatedatomtransferradicalcopolymerization.C.Xu,T.Wu,C.M.Drain,J.D.Batteas,K.L.Beers88.Synthesisandcharacterizationofterpyridine-containingpolymerwithblock-randomarchitectureviaRAFTpolymerization.K.Aamer,G.N.Tew

2004 Fall meeting

89.Irondiiminecomplexes:Robust,lowtoxiccatalystsforatomtransferradicalpolymerization(ATRP).V.C.Gibson,R.K.O'Reilly90.SynthesisofstarblockcopolymersviaSR&NIATRPinminiemulsion.K.Min,M.Li,N.M.Jahed,K.Matyjaszewski91.Reversibleaddition-fragmentationchain-transferpolymerizationoft-butylacrylate.B.C.Benicewicz,M.J.Nasrullah,R.Vajjula92.Randomandperfectlyalternatingpoly(ethyleneoxide)-polyisobutyleneamphiphilicconetworks.G.Erdõdi,B.Iván93.Carbocationicpolymerizationofisobutyleneinbenzotrifluoride,anenvironmentallyadvantageoussolvent.P.GrohWerner,B.Iván,F.deJong,T.Graaflland94.Supramolecular,telechelicpoly(etherketones)bearingbarbituricacidashydrogenbondingunit.L.Petraru,D.Farnik,R.Saf,W.H.Binder95.ConnectingpolymericfragmentsbySharpless-typeclick-reactions.W.H.Binder,D.Machl,C.Kluger96.Sidechain-functionalizedpoly(norbornenes)bearingnewhydrogenbondingmotivesviaROMP.C.Kluger,W.H.Binder97.Synthesisofamphiphiliccopolymerscontainingpendentsubstitutedcyclotriphosphazenesviaringopeningmetathesispolymerization.D.T.Welna,D.A.Stone,H.R.Allcock98.Controlledcopolymerizationofvinylacetatewitha-olefinsbydegenerativetransfer.S.Borkar,A.Sen99.Reversibleaddition-fragmentationchain-transferpolymerizationofN-phenylmethacrylamide.B.C.Benicewicz,R.Vajjula,M.J.Nasrullah100.Synthesisandcharacterizationofamethyl-substitutedortho-para-polyanilinederivativeviapalladiumcatalyzedC–Ncoupling.K.A.Cutler,T.Y.Meyer101.SynthesisandcharacterizationofL-tyrosinefunctionalizedpolyphosphazenes.A.Singh,W.R.Laredo,H.R.Allcock102.Synthesisandcharacterizationofcopolymerpoly(bis-trifluoromethylstyrene)andPMMAfornanowireapplications.S.Murugesan,S.R.Venumbaka,P.E.Cassidy,H.C.Galloway,J.Jarl,F.Abrego,D.Koeck,L.Martinez103.Copolymerizationofmethylacrylateandmethylmethacrylatewithalpha-olefinsinthepresenceofscandium(III)triflate.M.L.Majcher,A.Sen104.Encapsulationofaredox-responsiveguestbyamodifiedpoly(propyleneimine)dendrimer.W.Ong,R.McCarley105.PreparationandcharacterizationofPLAmicrospheres.W.Jiang,H.Na,Z.Wang106.Selectiveandsequentialnucleophilicaromaticsubstitutionreactionforthesynthesesoflinearandhyperbranchedpoly(aryleneether)s.Y.J.Kim,S.Y.Kim107.Synthesisandcharacterizationofanovelphenoxyresincontainingbiphenylgroups.C.Hongli,N.Hui108.Synthesis,characterizationandperipheralderivatizationofhyperbranchedpolybenzyl.A.Som,S.Ramakrishnan109.Distributionofcarboxylgroupsonmicron-sizecrosslinkedmicrospheresobtainedbydispersioncopolymerization.H.Zhang,H.Huang,R.Lv,M.Chen110.Particlesizedistributionandmorphologyofalkoxysilane-functionalizedacryliccopolymerlatexes.S.Huang,D.Fan,Y.Lei,H.Huang111.Opticalpropertiesofanamorphouster-polysilanecontainingvinylsidegroups.S.Huang,Y.Lei,J.Zhu,F.Yu,H.Huang112.Controlledalternatingcopolymerizationofmethylacrylateand1-alkenewithdegenerativetransfer

2004 Fall meeting

polymerization.S.Liu,B.Gu,D.Leber,A.Sen113.Nitroxidemediatedcopolymerizationofmethylacrylatewith1-alkenesandnorbornenes.B.Gu,S.Liu,J.D.Leber,A.Sen114.Controlledcopolymerizationofmethylacrylatewith1-alkenebyRAFTpolymerization.S.Liu,B.Gu,D.Leber,A.Sen115.Easysynthesisandcharacterizationofconjugatedenergytransfercassettes.W.G.Skene,S.Dufresne116.Partiallyfluorinatedamorphousringcontainingpolymers.Y.Yang,Y.Kioke,Y.Okamoto117.Emulsioncopolymerizationofvinylacetateandchlorotrifluoroethylenewithafunctionalmonomersurfactant.S.Zhang,B.Geng,A.Xu,X.Z.Kong118.Determinationofpropagationrateconstantinthecationicpolymerizationofp-chlorostyrene.P.De,R.Faust119.Livingcarbocationicpolymerizationofp-methoxystyreneusingp-methoxystyrenehydrochloride/SnBr4initiatingsystem.P.De,R.Faust120.Preparationandcharacterizationofpolyimide/aromaticsilsesquioxanehybridnanocomposites.C.S.Ha,I.Kim,H.W.Jeong121.Synthesisofferrocenylmethyl-containingdendrimers.Q.S.Hu,Y.Lu122.Anewapproachforthepolymerizationofcyano-substitutedpoly(p-phenylenevinylene)s.J.Liao,Q.Wang123.Mechanisticaspectsof[Rh(nbd)Cl]2initiatedoligomerizationofnewacetylenicmonomers.C.G.Densmore,P.G.Rasmussen124.Self-templationsynthesisofmesoporousorganosilicascontainingcovalentlyboundcyclodextrins.C.Liu,J.B.Lambert125.Novelcopolymersofvinylacetatewithtrisubstitutedethylenes.G.B.Kharas,R.Bernal,L.Kallal,V.Thomas,S.Tokman,M.Trnka,L.A.Hyland,P.Hughes,J.Carney,A.M.Trujillo,J.Yedlinsky,K.Watson126.Livingcationicpolymerizationofcyclohexylvinyletheranditsblockcopolymerizationwithisobutylene.Y.Zhou,R.Faust127.Livingcationicpolymerizationoftert-butyldimethylsilylvinyletheranditsblockcopolymerizationwithisobutylene.Y.Zhou,R.Faust128.Reactivecompatibilizationofnylon6/ABSblends.R.Wang,W.Wang,Z.Shi,Y.Xia129.Functionalizablecyclicsiloxanesencapsulants.C.Yun,K.Rahimian,N.J.Shah130.Encapsulantbasedonmeta–substitutedphenylenebridgedbyclicsiloxanes.C.Yun,K.Rahimian,N.J.Shah,D.A.Loy131.ChemicalchangesinNafionmembranesundersimulatedfuelcellconditions.C.Zhou,T.Zawodzinski,D.Schiraldi132.Developingrigidpolymerelectrolytes.J.F.Snyder133.Nanoscalehierarchicalstructuresofaseriesofliquidcrystalline“rod-coil”blockcopolymers.K.K.Tenneti,C.Y.Li,D.Zhang,H.Zhang,X.Wan,E.Q.Chen,Q.F.Zhou,C.Avila-Orta,S.Igos,B.S.Hsiao134.Ti(III)Cp2Clcatalyzedlivingradicalpolymerizationofstyreneinitiatedfrombenzaldehydes.A.D.Asandei,Y.Chen135.Graftingofpolystyrenefrompoly(glycidylmethacrylate)initiatedbyTicatalyzedepoxideradicalringopening.A.D.Asandei,G.Saha136.Preparationofdrugdeliverybiodegradablenanocompositesbyrapidexpansionfromsupercriticalsolutions.A.D.Asandei,C.Erkey,D.J.Burgess,C.Saquing,G.Saha,B.S.Zolnik

2004 Fall meeting

137.Livingringopeningpolymerizationofε-caprolactonecatalyzedbyTialkoxidesderivedfromradicalringopeningofepoxides.A.D.Asandei,I.W.Moran,G.Saha,K.Juzyn138.Orthogonalnon-covalentcrosslinkingandsmallmoleculeself-assemblyonto‘universalpolymerbackbones’viamulti-sitemolecularrecognition.J.M.Pollino,K.P.Nair,M.Weck139.Poly(glutamicacid)nanospheresforbiomedicalapplications.E.Dibbern,F.Jean-JacquesToublan,K.S.Suslick140.Polyestersandpolyester-amideswithphoto-regulatedchiropticalbehavior:Tuningresponsiveoutputwithdifferentsolvents.G.D.Jaycox141.Macromoleculeswithsidechainterpyridinemotifsforuseinsupramolecularmaterials.R.Shunmugam,G.N.Tew142.Subcriticaldampedoscillationsinthermalfreeradicalmethod.K.R.Sharma143.Polystyrene/claynanocompositespreparedbyheterocoagulation.S.H.Lee,W.J.Brittain144.Preperationofconductingpolymercompositesforphotonicapplications.B.A.Higgins,Y.Xu,W.J.Brittain145.Diffusionofproteininpolymersolutions:Acomparisonbetweenneutronspin-echospectroscopyandNMRmeasurements.X.Guo,R.Biehl,C.R.Pacheco,M.Monkenbusch,D.Richter,L.Fu,R.K.Prud'homme146.SelfdiffusionofN,N-dimethylformamideinpolystyrenesolutionsmeasuredbypulsed-fieldgradientNMR.M.O.Okuom,F.D.Blum147.CooperativemotionaroundinsideandendsegmentsofPMMAattheglasstransitionasstudiedbytheESRtechnique.Y.Miwa,K.Yamamoto,M.Sakaguchi,S.Shimada148.Ionmobilitytime-of-flightmeasurements:Isolatingthemobilityofchargecarriersduringanepoxy-aminereaction.Z.Guo,J.D.Warner,P.Best,D.Kranbuehl149.SynthesisofhollowTiO2nanoparticlespreparedbycolloidaltemplating.Y.K.Kwon,J.P.Kang,T.H.Kim150.Electrospunhollowfibersofpoly(e-caprolactone).D.H.Y.Kim,K.W.Kim,K.H.Lee,E.S.Yoo,R.J.Farris,S.F.Fennessey151.ElectricalpropertiesofhighlyconductiveEDOTbasedcopolymers.E.E.Sheina,R.D.McCullough152.Mechanicaldegradationofpartialhydrolyzedpolyacrylamideinsolution(I).J.Niu,X.Jiang153.Studyonthemechanicaldegradationofpartialhydrolyzedpolyacrylamideinaqueoussolution(II).L.Wang,Z.Han,J.Zhou,F.Liu,J.Niu154.Polymericnanocompositeshavingblockcopolymersasintercalants.N.Nugay,S.Sen,T.Nugay155.Layeredsilicamodificationwithreactivegroupsforpolystyrenenanocomposites.N.Nugay,T.Nugay,M.Memesa,Y.Menceloglu156.Effectoffillershapeandcompatibilizeronweldlinemorphologyofpolypropyleneandpolyamide-6blendcomposite.N.Nugay,T.Nugay,O.G.Ersoy157.Preparationofhighlyuniformlowdensitypolystyrenefoamsandtheircharacterization.W.P.SteckleJr.,M.E.Smith,R.J.Sebring,K.V.WilsonJr.,A.Nobile158.MonteCarlosimulationoforientationorderingingraftedrodlikepolymers.C.Y.Shew,R.M.Peetz,J.Q.Wang159.Spontaneous1DarrangementofsphericalAunanoparticleswithliquidcrystalligands.I.In,S.Y.Kim160.GatelessAlGaN/GaNHEMTresponsetoblockcopolymers.S.Bernard,C.Mathieu,B.S.Kang,G.Louche,Y.Gnanou,F.Ren,R.S.Duran

2004 Fall meeting

161.Opticallyactivepolyacetylene:synthesisandchiropticalpropertiesofpoly(phenylacetylene)containingL-valine(1S,2R,5S)-(+)-menthylesterpendants.L.M.Lai,K.K.L.Cheuk,J.W.Y.Lam,B.Z.Tang162.Hyperbrancedpoly(aryleneethynylene)s:Synthesisandcharacterization.H.Peng,J.W.Y.Lam,D.Jia,B.Z.Tang163.Photoluminescenceandopticallimitingofhyperbranchedpoly(aryleneethynylene)s.H.Peng,J.W.Y.Lam,D.Jia,B.Z.Tang164.Thermochromismofhexaphenylsiloleanditsblendswithpoly(methylmethacrylate).Y.Q.Dong,J.W.Y.Lam,Z.Li,H.Peng,C.C.W.Law,X.D.Feng,B.Z.Tang165.Developmentofnewmethodsfortheconstructionofregioselectivehyperbranchedmacromolecules:Synthesisoffunctionalhyperbranchedpoly(aroylarylene)s.H.Dong,R.Zheng,J.W.Y.Lam,M.Häußler,B.Z.Tang166.Hyperbranchedcobalt-containingpolyynesasprecursorstonanostructuredmagnetoceramics.M.Häußler,J.W.Y.Lam,H.Dong,H.Tong,B.Z.Tang167.Stabilityofsubstitutedpoly(acetylene)s.C.C.W.Law,J.W.Y.Lam,Y.Dong,B.Z.Tang168.Synthesisofahyperbranchedpolyarylenewithphenylenevinylenechromophore.H.Dong,Y.P.Dong,J.W.Y.Lam,M.Häußler,H.Peng,B.Z.Tang169.Novelhyperbranchedpolymerscontainingsecondordernonlinearopticalchromophores.Z.Li,J.W.Y.Lam,Y.P.Dong,Y.Q.Dong,B.Z.Tang,A.J.Qin,C.Ye170.Poly(1-phenyl-1-alkyne)sbearingcarboxylicacidMoieties:Sensitivechemosensorformetalions.H.Tong,J.W.Y.Lam,M.Häußler,B.Z.Tang171.Synthesisandlight-emittingpropertiesofwater-solubledisubstitutedpolyacetylene.H.Tong,J.W.Y.Lam,M.Häußler,B.Z.Tang172.Poly(diphenylacetylene)s:Synthesisandtheirthermalandlight-emittingproperties.C.W.Law,J.W.Y.Lam,Y.Dong,B.Z.Tang

SectionBPennsylvaniaConventionCenter--HallD


W.T.FordandC.L.McCormick,Organizers5:00-7:00173.Electrostaticadhesionofpolyelectrolytesandcolloidsonproteinmicrospheres.F.Jean-JacquesToublan,E.Dibbern,H.M.Argadine,J.F.Greenleaf,R.D.Simari,K.S.Suslick174.Aminoacid-based,ion-containingterpolymerswithpH-andsalt-responsivebehavior.R.G.Ezell,N.Ayers,C.L.McCormick175.ControlledpolymerizationofneutralandcationicmethacrylamidesinaqueousmediabyRAFT.Y.A.Vasilieva,C.W.Scales,D.B.Thomas,N.Ayres,C.L.McCormick176.Chemicalfunctionalizationofsingle-wallcarbonnanotubeswithpoly(4-vinylpyridine).S.Qin,D.Qin,W.T.Ford,J.E.Herrera,D.E.Resasco177.Binarycopolymerreactivityoftert-butylmethacrylate,N,N-dimethylaminoethylmethacrylateandsolketalmethacrylate.L.N.Miranda,W.T.Ford178.Studyoftheinteractionbetweenpoly(acrylicacid)andbivalentcations.J.G.Soos,R.M.Molnar,J.F.Hartmann,J.Borbely

2004 Fall meeting

179.Nanoparticlesfromchitosan.M.Bodnar,J.F.Hartmann,J.Borbely180.Poly(3-thiopheneaceticacid)surfactantcomplexes:Synthesis,self-assemblybehaviorandphotoluminescenceproperty.K.H.Park,Y.S.Yoon,H.Kang,J.C.Lee181.Polyelectrolytesbasedonsulfonatedpoly(1,3-cyclohexadiene)blockcopolymers.K.Hong,P.Britt,J.W.Mays182.Structuresandredoxactivitiesofpoly(m-methoxyaniline).Y.T.Xu,L.Z.Dai,J.F.Chen,J.Y.Gal,H.H.Wu183.Studiesonoxygenreductiononthering-substitutedpolyanilinesmembraneelectrodes.L.Z.Dai,Y.T.Xu,J.F.Chen,J.Y.Gal,H.H.Wu184.Surfacemodificationofglassbypolyampholyte:Applicationtoanti-fogging.S.I.Kabashima,E.Ogura,T.Maruyama,M.Komatsu185.Synthesisandcharacterizationofcombshapesingleionconductorsbasedonpolyepoxideethersandperfluorinatedlithiumsalts.X.G.Sun,C.L.Reeder,J.B.Kerr,D.D.DesMarteau186.Synthesisofblockcopolymersviareversibleadditionfragmentationchaintransfer(RAFT)using4vinylpyridineandtert-butylacrylateasapolyampholyteprecursor.B.S.Lokitz,N.Ayres,A.J.Convertine,C.L.McCormick187.Synthesisofpolyureaoligomersandtheirantibacterialstudy.H.Tang,G.Tew

MONDAYMORNING



Synthesis

W.T.Ford,OrganizerM.J.Fevola,PresidingC.L.McCormick,Organizer,Presiding8:30—188.Polymerizationofsodium4-styrenesulfonateviaatomtransferradicalpolymerization.P.D.Iddon,K.L.Robinson,S.P.Armes8:50—189.Switchableamphiphiles.S.Basu,D.Vutukuri,S.Shyamroy,S.Thayumanavan9:10—190.Well-definedbiomimeticpolymersfromRAFTpolymerization:Carbohydrateandnucleosidefunctionalizedpoly(methacrylate)s.L.Albertin,N.K.Allen,M.Stenzel,C.Barner-Kowollik,J.L.Foster,T.P.Davis9:40—191.AqueousRAFTpolymerizationofvalinecontainingacrylamidocopolymers.N.Ayres,R.G.Ezell,C.L.McCormick10:00—Intermission.10:15—192.Synthesisandcharacterizationofpolyelectrolytebrushes.S.G.Boyes,B.K.Mirous,W.J.Brittain10:45—193.Synthesisofwell-defined(co)polymerswithionicorionizablegroupsbyatomtransferradicalpolymerization.N.V.Tsarevsky,K.Matyjaszewski11:05—194.Synthesisandpolymerizationofliquidionic1-methyl-3-alkyl-5-vinylimidazoliumsalts.J.Wang,T.W.Smith11:35—195.Anovelapproachtoregioselectively-functionalizedamphiphilicblockcopolymersandnanoparticles.R.K.

2004 Fall meeting

O'Reilly,M.J.Joralemon,A.K.Nugent,J.B.Matson,C.Hawker,K.L.Wooley11:55—196.Synthesisofdoubly-responsivediblockcopolymersbyambienttemperatureRAFT.A.J.Convertine,L.J.Myrick,A.B.Lowe,C.L.McCormick



Bonding,AdditivesandFillers

J.W.Stansbury,OrganizerJ.M.Antonucci,Organizer,Presiding8:30—197.Hydrolyticallystablemonomersforself-etchingenamel-dentinadhesives.U.Salz,J.Zimmermann,F.Zeuner,N.Moszner8:50—198.Determinationofadhesivedistributionindentin-adhesivebondusingRamanmicroscopy.Y.Zou,S.R.Armstrong,J.L.P.Jessop9:10—199.Effectofresincompositiononmechanicalandphysicalpropertiesofcalciumphosphatefilledbondingsystems.S.Dickens,G.M.Flaim,C.J.E.Floyd9:30—200.Effectofresinstructureandcore-shellreinforcementontheyieldingandfracturebehaviourofdentalresinsandtheircomposites.W.D.Cook,M.Forrest,A.Goodwin9:55—Intermission.10:15—201.Antimicrobialreleasefromasalicylate-basedpoly(anhydride-ester).K.A.Whitaker-Brothers,K.E.Uhrich10:35—202.Structure-propertyrelationshipsofthermosetmethacrylatecompositesfordentalmaterials:Studyoftheinterfacialphaseofsilicananoparticle-filledcomposites.K.S.Wilson,J.M.Antonucci10:55—203.UHMWPEasnovelfillerfordentalcomposites.R.Ranade,S.Wunder,G.Baran11:15—204.Polymer-brushmodifiedfillersfordentalcomposites.X.Ding,J.W.Stansbury11:35—205.Epoxy-brushmodifiedfillersfordentalcomposites.J.W.Stansbury,X.Ding


NewDevelopmentsinCoatingsTechnology

Tutorial:NewDevelopmentsinCoatingsTechnology

CosponsoredwithFederationofSocietiesforCoatingsTechnology,andPMSEB.C.BenicewiczandB.Richey,OrganizersP.ZarrasandT.G.Wood,Organizers,Presiding8:00—IntroductoryRemarks.8:05—206.Electronicpolymers:Newmaterialsandnanofiberfilmsforthe21stcentury.A.G.MacDiarmid8:50—207.Antimicrobialcoatings:Introduction,progress,andchallenges.K.J.Wynne9:35—Intermission.

2004 Fall meeting

9:45—208.Tutorial:Organicandpolymericcoatingsforcorrosionprotection.P.Zarras10:30—209.Coatingtechnologyforcombattingmarinefouling.T.E.Ready11:15—ConcludingRemarks.


GeneralPapers

PolymerCharacterizationB

D.Garcia,OrganizerJ.C.Swartz,Presiding8:00—210.Preparationofbiocompatablehydrogeladhesivescontrolledbyrheologicalmethod.X.Guo,R.K.Prud'homme,F.Deng,S.J.Leth,N.Nunalee,K.R.Shull8:20—211.Sorptionofpoly(hexamethylenebiguanide)oncellulose:Mechanismofbindingandmolecularrecognition.R.S.Blackburn,A.Harvey,J.Payne,L.L.Kettle8:40—212.DevelopmentofanaqueouspolymerforDNApurificationandreleaseforuseinPCR.J.C.Swartz9:00—213.Antimicrobialsyntheticpolymers:Amphiphilicpolymethacrylatederivatives.K.Kuroda,W.F.DeGrado9:20—214.Recognition-inducedformationofpolymericmicrospheresbyself-complementaryhydrogenbondinginteractions.O.Uzun,A.Sanyal,R.J.Thibault,H.Nakade,V.M.Rotello9:40—215.Improvingtheresistanceofpolylactidetohydrolysisbasedontheconfigurationandarrangementofthemolecules.D.T.Karst,Y.Yang10:00—216.Controlleddispersionandassemblyofquantumdotsusingpolymers:Poly(para-phenylene)-quantumdotcomposites.H.Skaff,K.Sill,T.Emrick10:20—217.Reversibledynamicpolymers.W.G.Skene,J.M.Lehn10:40—218.Modulardesignofphoto-regulatedchiropticalswitches:Oligomersandpolymers.G.D.Jaycox11:00—219.Poly(etherketone)-poly(isobutylene)pseudoblock-copolymers:PhasebehaviorviaSAXS.W.H.Binder,M.J.Kunz,C.Kluger,L.Petraru,S.Bernstorff,V.Torma11:20—220.ChargepercolationmechanismofheterogeneousAl-basedcatalystsforolefinepolymerization.L.S.Korugic-Karasz,D.B.Stoiljkovic,B.M.Pilic


Structure-PropertyRelation/Characterization/Application


StateoftheArtinPolymerAnalysis

2004 Fall meeting

CosponsoredwithANYL

MONDAYAFTERNOON



BiologicalProperties

W.T.FordandC.L.McCormick,OrganizersT.P.DavisandA.B.Lowe,Presiding1:30—221.Anew“smart”polyelectrolytedrugcarrierresponsivetopHandglutathioneforintracellulardeliveryofantisenseoligonucleotides.A.S.Hoffman,V.Bulmus,N.Murthy,P.S.Stayton2:00—222.Cationicpolymersasgenetransferagents:Effectsofpolymertopologyandmolecularweightontransfectionefficiency.A.N.Rudisin,B.D.Mather,T.E.Long2:20—223.ChiraldiscriminationinDNAcompactionbystereoisomericdications.A.Zinchenko,V.G.Sergeyev,S.Murata,K.Yoshikawa,V.A.Kabanov2:50—224.Themultifacetedchemistryofhyaluronan:Applicationsinbiomaterials.S.Gouin,C.Yan,Y.Yang,F.M.Winnik3:20—Intermission.3:35—225.Mucoadhesivepolymersfromlivingradicalpolymerisation.D.M.Haddleton,A.K.Rullay,A.J.Limer,S.Carrington,S.Keely,D.Brayden4:05—226.Polyelectrolytesasself-assemblers:Nanocompositesandhydrogelsproducedfromchargedpolypeptides.D.J.Pochan,T.J.Deming4:25—227.Amphiphilicnanoparticlesandpolyanions.J.E.FleischerRadu,L.Novak,J.F.Hartmann,J.Borbely4:45—228.ConformationaltransitionsvisualizedinsinglepolyelectrolytemoleculeAFMexperiments.S.Minko,A.Kiriy,G.Gorodyska,R.Lupitskyy,C.Tsitsilianis,M.Stamm5:05—229.Smartpoly(methacrylicacid)-1-polyisobutylenepolyelectrolyteamphiphilicconetworks.M.Haraszti,B.Iván


6thInternationalBiorelatedPolymersSymposium

BiorelatedPolymerSynthesisandCharacterization

R.M.Ottenbrite,OrganizerS.J.Huang,PresidingK.E.Uhrich,Organizer,Presiding1:30—230.Biocompatibilitystudiesofnoveldendriticpolyisobutylene-basedblockcopolymers.J.E.Puskas1:50—231.Effectofthelinkerstructureonsalicylicacid-derivedpoly(anhydride-esters).A.Prudencio,R.C.Schmeltzer,K.E.Uhrich

2004 Fall meeting

2:10—232.Functionalpolymersfromitaconicanhydride.S.J.Huang,J.A.Wallach2:30—233.Synthesisanddegradationofantiseptic-derivedpoly(anhydride-esters).R.C.Schmeltzer,K.E.Uhrich2:50—Intermission.3:10—234.Biocompatiblepolymerblendsderivedfromthephotopolymerizationofpolyethyleneglycoldimethacrylate-polylactidemixtures.K.Zhang,S.Lin-Gibson,C.Simon,J.M.Antonucci,N.R.Washburn3:30—235.Synthesisandcharacterizationofacombcopolymerwithacellulosebackboneandwithradialhydrophilicbrushesonamphiphillicteeth.C.Zhang,L.M.Price,W.H.Daly3:50—236.Fromstructuralprotienstosyntheticpolymers.L.Ayres,K.Koch,M.Vos,H.Adams,J.C.M.vanHest



CorrosionResistantCoatings

CosponsoredwithFederationofSocietiesforCoatingsTechnology,andPMSEP.Zarras,T.G.Wood,B.Richey,andB.C.Benicewicz,OrganizersN.AndersonandB.C.Benicewicz,Presiding1:00—IntroductoryRemarks.1:05—237.CoatingschallengesforprotectingU.S.NavyandMarineaircraft.C.Matzdorf1:35—238.NewdevelopmentsinCr-freeprimersforaerospacealloys.G.P.Bierwagen,D.E.Tallman,M.Nanna,D.Battocchi,A.Stamness,V.J.Gelling2:05—239.Corrosionprotectionofaluminumalloysbycontrolledreleaseofinhibitorsfrominherentlyconductivepolymercoatings.P.J.Kinlen,C.R.Graham,Y.Ding2:35—240.UseofCe-modifiedbentoniteclayasapigmentforcorrosioninhibitionandsensing.S.Chrisanti,R.G.Buchheit3:05—Intermission.3:15—241.Poly(2,5-bis(N-methyl-N-hexylamino)phenylene)vinylene))(BAM-PPV)asreplacementsforchromateconversioncoatings(CCCs).J.D.Stenger-Smith,N.Anderson,C.Webber,P.Zarras3:45—242.Newelectroactivepolymersforanti-corrosioncoatings.R.Chen,V.Raghunadh,B.C.Benicewicz4:15—243.Novelenvironmentallycompliantself-primingcoatingsystemsforcorrosionprotectionofmetals.W.J.vanOoij4:45—244.Cavitationresistanceofpolyamide-11powdercoatings.T.P.McAndrew,M.Audenaert,J.Petersheim,D.Garcia,T.Richards5:15—ConcludingRemarks.


IndustrialPolymerScientistAward:SymposiuminHonorofBillCulbertson

2004 Fall meeting

P.Cassidy,Organizer1:30—IntroductoryRemarks.1:40—245.Acrylicwaterbornecoatingsbasedonoxazolinemethacrylatemonomer.H.A.A.Rasoul,D.L.Trumbo2:10—246.Customdesignofbiodegradableelastomersthroughbis-oxazolinecoupling.P.Bonsignore,M.Gurin2:40—247.Oxidatively-stablecobalt-polymercomplexes.J.S.Riffle,V.V.Baranauskas,M.Vadala,M.S.Thompson,M.Zalich,T.G.St.Pierre3:10—248.Synthesisandcharacterizationofphenylethynylterminatedpolybenzoxazoleandwhollyaromaticpolyimides.J.E.McGrath,W.D.Joseph,K.Elahi,Y.Watanabe3:40—249.PolymerChemistry:Contributionsoveratwenty-seven-yearindustrialcareer.B.M.Culbertson

StateoftheArtinPolymerAnalysis

CosponsoredwithANYL

MONDAYEVENING


Sci-Mix

C.A.Guymon,Organizer8:00-10:0061-62,68-69,75,78-81,83,85,88,96-98,100,104-108,112,114-115,118-119,121,123-124,126-127,131,134-139,141-143,148,150-157,159,166.Seepreviouslistings.323,327,343,346,348,350,352-353,356,360-363,367,370-371,379.Seesubsequentlistings.

TUESDAYMORNING



Applications

W.T.FordandC.L.McCormick,OrganizersY.MorishimaandA.Eisenberg,Presiding8:00—250.Polyelectrolytesgraftedtosinglewallcarbonnanotubes.W.T.Ford,S.Qin,M.Tchoul,X.Jiang,A.Mamedov,S.Gupta,G.Lian8:30—251.Supramolecularextensionofpi-conjugationinconjugatedoligomer.T.Sai,K.Levon8:50—252.Characterizationandapplicationofamphiphilicpolyacetylenesinmethanol/watermixture.B.C.Ku,K.Yang,D.W.Kim,A.Blumstein,L.Samuelson,J.Kumar

2004 Fall meeting

9:10—253.Uniqueassociativebehaviorinwaterofcopolymersofsodiumacrylateandoligo(ethyleneoxide)alkylethermethacrylates.I.Tomatsu,A.Hashidzume,Y.Morishima9:40—254.Novel″core-shell-corona″architecturesviacomplexationofmicellesofionicamphiphilicdiblockcopolymerswithoppositelychargedpolyelectrolytes.D.V.Pergushov,M.Gradzielski,M.Burkhardt,E.V.Remizova,A.B.Zezin,V.A.Kabanov,A.H.E.Müller10:00—Intermission.10:15—255.Tuningthesizeofpolymericvesiclesusingionicadditives.A.Choucair,C.Lavigueur,A.Eisenberg10:45—256.Synthesisandpropertiesofpolymermicellesformedfromsubstitutedpolystyrene-poly(acrylicacid)diblockcopolymers.J.M.Pickel,P.F.Britt11:05—257.Synthesis,solutionandpigmentdispersionstabilizationpropertiesofamphipolarmethylmethacrylate/methacrylicacidcopolymers.H.Arndt,T.Schauer,K.Dirnberger,C.D.Eisenbach11:35—258.Solublenanoparticlesfromblockionomermicellesandoppositelychargedcomplexatingagents.E.A.Lysenko,P.S.Chelushkin,T.K.Bronich,A.Eisenberg,V.A.Kabanov,A.V.Kabanov

SectionBMarriott--SalonL


BiorelatedPolymerAnalysisandProcessing

R.M.OttenbriteandK.Uhrich,OrganizersA.CouryandT.Wada,Presiding8:30—259.Acomputationalstudyonthering-openingpolymerizationoflactideinitiatedbyb-diketiminatemetalalkoxides:2.Theoriginofheterotacticstereocontrol.V.C.Gibson,E.L.Marshall,H.S.Rzepa8:50—260.Metabolicandcomputationalanalysisofthetotalenzymaticsynthesisofpoly-(β)-hydroxybutyricacid.K.L.Burns,J.D.Lane,J.R.Thompson,M.Lubarsky,S.W.May9:10—261.Crystalandmolecularstructuresofpolylactones.E.Kim,T.Iwata,Y.Doi,H.Uyama,C.S.Ha9:30—262.Enzymaticsynthesisofaskinscaffold.K.Omrane,M.Mandalaywala,C.Folts,C.D.Woodworth,A.Mueller9:50—263.Electrospinningofabiodegradablepolyurethaneforuseintissueengineering.D.N.Rockwood,J.Fromstein,K.A.Woodhouse,D.B.Chase,J.F.Rabolt10:10—Intermission.10:30—264.Effectoffluidenvironmentonionreleasefromamorphouscalciumphosphatefilledrestorativematerials.W.F.Regnault,R.M.Fitzgerald,J.M.Antonucci,D.Skrtic10:50—265.Ultrahighmolecularweightpolyethylenewithimprovedprocessabilityformedicalimplants.K.S.Garkhail,R.Duchateau,G.J.G.J.M.Gruter,S.Rastogi11:10—266.Structureofnovelcellulosicfibersfromcornhusks.N.Reddy,Y.Yang



2004 Fall meeting

BioresistantCoatings

CosponsoredwithFederationofSocietiesforCoatingsTechnology,andPMSEP.Zarras,B.C.Benicewicz,T.G.Wood,andB.Richey,OrganizersN.AndersonandK.J.Wynne,Presiding8:00—IntroductoryRemarks.8:05—267.Surfacemodificationofpolypropylenemicroporousmembranewithbiomimeticpolymers.Z.K.Xu,X.J.Huang,Q.Yang,H.T.Deng8:40—268.Theinfluenceofsurfacewettabilityontheadhesionofthesoft-foulingalgaUlva.J.A.Callow,M.E.Callow,L.K.Ista,G.P.Lopez,M.K.Chaudhury9:15—269.Nanoscopically-resolvedamphiphiliccoatings:Treacherousterraintoinhibitbiofouling.G.O.Brown,C.Cheng,C.S.Gudipati,J.Johnson,K.T.Powell,K.L.Wooley9:50—Intermission.10:05—270.Unusualwettingbehaviorofpolyurethanecoatingscontainingpoly(oxetane)softblocks.U.Makal,T.Fujiwara,K.J.Wynne10:35—271.Hyperbranchedfluoropolymers–poly(ethyleneglycol)crosslinkednetworks:Novelmaterialsfortheencapsulationandreleaseofhydrophobicandhydrophilicsmallmolecules.G.O.Brown,K.L.Wooley11:05—ConcludingRemarks.


IndustrialPolymerScientistAward:SymposiuminHonorofCraigHawker

K.R.Carter,Organizer8:00—272.Beyondsupramolecularassembly:Shapingofnanostructures.K.L.Wooley8:30—273.“Living”radicalpolymerizationasatoolforthepreparationoffunctionalpolymersandcopolymers.R.B.Grubbs9:00—274.StructuredmicellesfromABCtriblockcopolymer"tryptych"surfactants.M.A.Hillmyer,T.P.Lodge9:30—275.Hybridinorganic-organiccopolymers:Macromolecular,mesoscopicandmacroscopicstructures.E.B.Coughlin10:00—276.Polymerbioconjugatesbycontrolledradicalpolymerization.H.D.Maynard10:30—277.Structuralcontrolofwater-solublehomopolymersandblockcopolymersviaRAFTpolymerization:Stimuliresponsivenessinaqueousmedia.C.L.McCormick11:00—278.Amorphouscopolyestersmodifiedtoenhancetheglasstransitiontemperature.S.R.Turner11:30—279.Designingdendrimersanddendronizedpolymersforcatalysisandmoleculartransport.J.M.J.Fréchet,C.O.Liang,B.Helms12:00—280.Controlledpolymericstructuresforadvancedstorageandmicroelectronicdevices.C.J.Hawker

TUESDAYAFTERNOON

SectionA

2004 Fall meeting

Marriott--SalonI&J

AdvancesinPhotoinitiatedPolymerization

PhotoinitiationandOxygenInhibition

C.N.BowmanandA.B.Scranton,Organizers1:00—281.Photoinitiationandphotopolymerizationofnovelself-initiatingmonomers.T.Y.Lee,C.A.Guymon,S.E.Jönsson,C.Hoyle1:35—282.Modelingofphotoinitiationforthickpolymersystems.N.Stephenson,D.Kriks,A.B.Scranton2:00—283.Influenceofphotoinitiatormobilityandsolubilityonthepolymerizationbehaviorinlyotropicliquidcrystallinesystems.M.A.DePierro,A.J.Olson,C.A.Guymon2:25—284.1,5-Diphenyl-1,4-diyn-3-one,anewandhighlyefficientPhotoinitiator.R.Liska,B.Seidl3:00—Intermission.3:15—285.Newwaytoapproachthephotoinitiatorreactivity.X.Allonas,J.Lalevee,J.P.Fouassier3:50—286.Withdrawn.4:15—287.Whymulti-functionalacrylatescanbelightcuredwithoutanoxygeninhibitedlayer?L.Feng,B.I.Suh4:40—288.Reductionofoxygeninhibitioninfree-radicalphotopolymerization.L.Gou,C.N.Coretsopoulos,A.B.Scranton



BiorelatedHydrogelSystems

R.M.OttenbriteandK.Uhrich,OrganizersN.RaviandJ.C.Salamone,Presiding1:30—289.Molecularlyengineeredhydrogelsforimplantbiocompatibility.A.Guiseppi-Elie,S.Brahim,S.Abraham1:50—290.Preparationandcharacterizationofhydrogelnanocompositesforopthalmicapplications.N.Ravi,H.A.Aliyar,P.D.Hamilton2:10—291.DiffusionofcalciumionsandformationofcalciumphosphatedepositsinradiationcrosslinkedPVA/PVPhydrogels...Zainuddin,D.J.T.Hill,A.K.Whittaker,K.Strounina,T.V.Chirila2:30—292.CovalentlyattachedCu(II)-complexhydrogelasnovelhemocompatiblematerials.S.Y.Hwang,M.E.Meyerhoff2:50—293.Polysaccharide-derivatizedpolymerscaffoldsforproteindelivery.N.Yamaguchi,K.L.Kiick3:10—Intermission.3:30—294.Structure-propertyrelationshipsofphotopolymerizablePEGDMhydrogels.S.Lin-Gibson,R.Jones,N.R.Washburn,F.Horkay

2004 Fall meeting

3:50—295.SynthesisandcharacterizationofbioactivePEGDMhydrogels.S.Lin-Gibson,M.L.Becker,K.S.Wilson,N.Washburn4:10—296.SynthesisofNanogelcarriersfordeliveryofactivephosphorylatednucleosideanalogues.S.V.Vinogradov,A.V.Kabanov4:30—297.Patterningofstimuli-responsivehydrogels.D.Schmaljohann,M.Nitschke,R.Schulze,C.Werner,K.Eichhorn



TechniquesforEvaluationofCoatingPerformance

CosponsoredwithFederationofSocietiesforCoatingsTechnology,andPMSEB.C.BenicewiczandT.G.Wood,OrganizersP.ZarrasandB.Richey,Organizers,Presiding1:30—IntroductoryRemarks.1:35—298.Polypyrrolecoatingsforcorrosioncontrolofaluminumalloys:Scanningvibratingelectrodestudiesofpolymer-metalinteractions.D.E.Tallman,J.He,G.P.Bierwagen2:05—299.Positronmetrologyforcorrosionanalysisofcoatings.J.Xu,R.Zhang,N.Anderson,C.Webber,P.Zarras2:35—300.Anewmethodforcharacterizingcoatings:Simultaneousmeasurementsofheatflow,masschangeandviscoelasticchangesinthinfilmsamplesexposedtogasesandliquids.A.L.Smith2:55—301.Predictingservicelifeperformance:Ouranalyticaltoolbox.K.Adamsons3:25—Intermission.3:35—302.ScanningKelvinprobemeasurementsforthedetectionofcorrosionprocessesbeneathappliedpaintcoatingsonaluminumalloyandsteelsubstrates.D.C.Hansen,H.S.Isaacs,G.Adzic,J.GittoIII,F.J.Martin4:05—303.Recentdevelopmentsinthecharacterizationofmelamineresincrosslinkingagentsbymassspectrometryandliquidchromatography.T.T.Chang,M.J.Piquette,P.Li4:35—304.Evaluationoftheprotectivepropertiesofchromate-freeBAMPPV-basedpolymercoatingsusingelectrochemicalimpedancespectroscopy(EIS).E.Kus,N.Anderson,P.Zarras,F.Mansfeld5:05—305.Thermalcharacterizationsofahightemperaturetolerantstereolithographyresin.J.Xu,R.G.Chambers5:25—ConcludingRemarks.


ExcellenceinGraduatePolymerScienceResearchSymposium

CosponsoredwithYCC,andPRESE.H.MartinandT.J.Pacansky,OrganizersH.N.ChengandT.E.Long,Organizers,Presiding2:00—IntroductoryRemarks.C.P.Casey,ACSPresident.2:10—306.Perspectivesonthefutureofpolymerscienceandeducation.E.M.Pearce

2004 Fall meeting

2:40—307.Understandingtheresponsenatureofmetallo-supramolecularpolymergels.J.B.Beck,S.J.Rowan3:00—308.Shapememoryeffectinsmectic-Cliquidcrystallineelastomers.I.A.Rousseau,P.T.Mather3:20—Intermission.3:35—309.Controlleddispersionandassemblyofquantumdotsusingpolymers:Poly(para-phenylene)-quantumdothybrids.H.Skaff,T.Emrick3:55—310.Fullyfunctionalizedphotorefractivepolymerbasedonnovelchromophores.W.You,S.Cao,Z.Hou,L.Yu4:15—311.Bergmancyclizationinthepresenceofmonomer:Asystematicstudyofpolymerizationandcompetingreactions.J.D.Rule,J.S.Moore4:35—Reception.

TUESDAYEVENING



JointPOLY/PMSEPosterSession

J.W.StansburyandJ.M.Antonucci,Organizers6:00-8:00312.Charactristicphoto-andthermo-polymerizationbehaviorandmechanicalpropertiesofUDMA/MAAsystem.J.Tanaka,J.Stansbury,J.Antonucci,K.Suzuki313.Dentalpolymericcompositesactivatedwithcamphorquinoneordiacylphosphineoxidephotoinitiators.N.Richards,S.Dickens,J.M.Antonucci

SectionBPennsylvaniaConventionCenter--HallD



P.Zarras,B.C.Benicewicz,T.G.Wood,andB.Richey,Organizers6:00-8:00314.Combinatorialdevelopmentofpolymercoatingformulationsforchemicalsensorapplications.L.Hassib,R.A.Potyrailo315.Apotentialmanganese-basedcatalystforalkydemulsionpaints.Z.O.Oyman,W.Ming,R.vanderLinde316.Effectofagingonmechanicalpropertiesofahightemperaturetolerantstereolithographyresin.J.Xu,R.G.Chambers,J.Schaefer317.Novelhyperbranchedpolymersforpolyurethanecoatings:Theirpreparationandcrosslinkingwithpolyisocyanates.E.Pavlova,B.I.Voit,M.Dušková-Smrèková,K.Dušek318.Plasmapolymercoatedpigmentsforslowreleaseinorganiccoatings.H.Manian,L.Yang,W.J.vanOoij

2004 Fall meeting

319.PolymercoatingofpharmaceuticalingredientsinsupercriticalCO2.B.Yue,C.Y.Huang320.StudyonscratchprofileofSSO-film/glass-substratemodifiedwithTEOS.P.Chen,L.Hu321.SynthesisandformulationofaremovableconformalcoatingusingDiels-Alderthermally-reversibleadducts.J.H.Aubert,D.R.Tallant,P.S.Sawyer,M.J.Garcia322.Zostericacid:Aneffectiveantifoulantforreducingbacterialattachmentoncoatings.B.M.ZhangNewby,C.Barrios,Q.Xu,T.J.Cutright

SectionCPennsylvaniaConventionCenter--HallD



C.N.BowmanandA.B.Scranton,Organizers6:00-8:00323.Activatedcamphorquinonesasphotoinitiators.R.Liska,G.Ullrich,D.Herzog,P.Burtscher,N.Moszner324.FluorinatedUV-curedcoatingsforplastics:ImprovementofadhesionbysurfacefunctionalizationassistedbyArplasma.A.DiGianni,R.Bongiovanni,A.Priola,M.SangermanoII,S.Turri,N.Nahal325.Kineticstudiesofnovel(meth)acrylicmonomers.H.Kilambi,E.R.Beckel,J.W.Stansbury,C.N.Bowman326.LaserFlashPhotolysisinvestigationsofpyridineketones.R.Liska,B.Seidl,G.Grabner327.NewphotopolymersforRapidPrototypingofcellularstructures.R.Liska,F.Schwager,C.Vives,J.Stampfl

SectionDPennsylvaniaConventionCenter--HallD



CosponsoredwithYCC,andPRESH.N.Cheng,E.H.Martin,T.E.Long,andT.J.Pacansky,Organizers6:00-8:00328.Synthesis,characterizationandpolymerizationofmonomerstowardsbridgetrifluoromethylatedpoly(p-phenylenevinylene).A.J.Roche,A.D.Loyle,J.P.Pinto329.Vinylsulfoxide:Aversatiletriggerfordendrimerdisassembly.M.L.Szalai,D.McGrath330.Polymerizationofvinylmonomersincyclodextrinchannels:Canconfinedfreeradicalpolymerizationyieldstereoregularpolymers?T.Uyar,M.Rusa,A.E.Tonelli331.Synthesisofperfluorocyclobutyllinkedhexabenzocoronenenetworks.B.K.Spraul,S.Suresh,S.Glaser,D.Perahia,D.W.SmithJr.332.Characterizationofsemiflexiblefibrilnetworksformedviaintramolecularfoldingandself-assemblyofamphiphilicB-hairpinmolecules.B.Ozbas,K.Rajagopal,J.K.Kretsinger,J.P.Schneider,D.J.Pochan333.Carbosilanefilmsformationbythermalcrosslinkingofcyclolinearpolycarbosilanes.Z.Wu,J.Papandrea,A.P.Singh,P.G.Ganesan,T.Apple,R.Ganapathiraman,L.V.Interrante

2004 Fall meeting

334.Hydrosilationcatalysisusingalkene-platinum-silylcomplexes.J.L.Dingman,B.A.Howell,R.B.Taylor335.Super-toughperformanceofmodifiedcarbonnanofiber(MCNF)/UHMWPEnanocompositefilms.X.Chen,K.Yoon,C.Burger,I.Sics,B.Hsiao,B.Chu336.Structureandpropertiesofsingle-walledcarbonnanotubesreinforcednanocompositefibrilsbyco-electrospinning.H.L.Lam,H.Ye,Y.Gogotsi,F.K.Ko337.Tailoringphotopolymerizationmaterialsfornanotechnology.M.D.Dickey,E.Collister,E.K.Kim,C.G.Willson338.Modelingtheflowofcrosslinkedguarguminporousmedia.M.T.Balhoff339.Implicationofhydrogenbondingonrheological/electrospinningrelationships.M.G.McKee,T.E.Long340.Intramolecularelectrostaticinteractionsinpolyelectrolytesolutions:Comparisonofanewempiricalmodeltoexperimentaldata.T.S.Rushing,R.D.Hester

SectionEPennsylvaniaConventionCenter--HallD



R.M.Ottenbrite,OrganizerK.E.Uhrich,K.L.Kiick,andT.Emrick,Presiding6:00-8:00341.Preparationandcharacterizationofpolymericproteo-mimetics.P.D.Hamilton,H.A.Aliyar,N.Ravi342.Towardsthedevelopmentofanartificialhumanvitreous.P.D.Hamilton,H.A.Aliyar,W.Foster,N.Ravi343.Antimicrobialpoly(oxazoline)s.C.J.Waschinski,V.Herdes,J.C.Tiller344.Moleculardesignofbiocompatiblehydrogelbasedonmolecularmobilityofwatersandpolymerchains.T.Morisaku,T.Ikehara,J.Watanabe,M.Takai,K.Ishihara345.Nanostructureofβ-sheetfibrilsconstructedbyunfoldedβ-hairpinpeptideself-assembly.M.S.Lamm,K.Rajagopal,J.P.Schneider,D.J.Pochan346.Remarkablestereocontrolinthepolymerizationofracemiclactideusingaluminuminitiatorssupportedbytetradentateaminophenoxideligands.V.C.Gibson,P.Hormnirun,E.L.Marshall347.Synthesisandsolutionpropertiesofpoly(ethyleneoxide-B-2-ethyl-2-oxazoline)andpoly(ethyleneoxide-B-ethyleneimine).A.Y.Carmichael,B.Caba,P.P.Huffstetler,R.M.Davis,J.S.Riffle348.Acomputationalstudyonthering-openingpolymerizationoflactideinitiatedbyb-diketiminatemetalalkoxides:1.Themechanismofchainpropagation.V.C.Gibson,E.L.Marshall,H.S.Rzepa349.Biodegradablepolymermicelle:Designofwell-definedamphiphilicpolyphosphatewithhydrophilicgraftchainviaATRP.Y.Iwasaki,K.Akiyoshi350.Effectsofβ-hairpinpeptideturnsequencesonhydrogelnanostructureandbulkmaterialpropertiesduetopeptideintramolecularfoldingandconsequentintermolecularself-assembly.T.Yucel,K.Rajagopal,D.J.Pochan,J.P.Schneider351.PLA-PEO-PLAhydrogelsfromtriblockcopolymers.N.Sanabria-DeLong,S.Agrawal,K.Aamer,S.R.Bhatia,G.N.Tew352.Synthesisandiron(II)chelationstudiesofbipyridine-centeredpoly(ethyleneglycol).A.Pfister,T.J.Wedge,C.L.

2004 Fall meeting

Fraser353.Afattyacidbiosensorconstructedfromafattyacidbindingproteinimmobilizedinahydrogel.W.Cai,B.J.Pitner354.Anovelapproachforthesynthesisofacrylonitrile-basedcopolymerscontainingphospholipidmoieties.X.J.Huang,Z.K.Xu,J.Q.Wang,L.S.Wan,Q.Yang355.Designandsynthesisofnovelhelicalproteinpolymerswithcontrolledfunctionalgroupplacement.R.S.Farmer,J.D.Sharp,K.L.Kiick356.Self-organizationofpolyphosphazene-polystyreneblockcopolymers.Y.Chang,E.S.Powell,H.R.Allcock,C.Kim357.SynthesisofPLAbydirectcondensationoflacticacidwithmodifiedgneissascatalyst.Z.Wang,H.Ni358.Biocompatibilityofthiol-containingpolyacrylamidepolymerssuitableforophthalmicapplications.P.D.Hamilton,H.A.Aliyar,N.Ravi359.Biocompatiblepolythiophenesandnon-naturalhelicalpoly(3-methyl-4-vinylpyridine)/aminoacidcomplexes:Developingnovelbiofriendlymaterials.I.M.Khan,B.Sannigrahi,P.McGeady,M.Waugaman360.Characterizationofheparin-peptideinteractionsandtheiruseinhydrogelassembly.L.Zhang,N.Yamaguchi,K.L.Kiick361.Influenceofsidechainstructureonpeptideintramolecularfoldingandconsequentself-assembly.Z.Li,L.A.Haines,B.Ozbas,J.P.Schneider,D.J.Pochan362.Oligoethylene-end-cappedpolylactide.N.K.Abayasinghe,S.Glaser,D.W.SmithJr.363.Artificialglycopolypeptidesfortheinhibitionofbacterialtoxins.B.D.Polizzotti,K.L.Kiick364.Effectofmoleculararchitectureonthevesicleformationofamphiphilicdiblockcopolypeptides.K.D.Hales,L.M.Pakstis,E.Bellomo,T.J.Deming,D.Pochan365.Incorporationof5-aminosalicylicacidintopoly(anhydride-esters)bysolutionpolymerization.Y.Kim,K.E.Uhrich366.Synthesisandcharacterizationofphenyleneethynyleneoligomerhavinghydrogenbondingsites.M.Obata,S.Yano,Y.Shinya367.Interactionsofproteinswithlaponite.Q.Hu,K.L.Kiick,D.J.Pochan,S.R.Fahnestock,R.H.Staley368.Morphologyofamphiphilicdiblockpolypeptidesthatcontrollablyself-assembleintohydrogelsandvesicles.L.Pakstis,A.Nowak,E.Holowka,T.J.Deming,D.J.Pochan369.PendantPegylationofaliphaticpolyesterforbiomaterialsapplications.B.Parrish,T.Emrick370.Quantitativestructure-activityrelationshipofacrylateandmethacrylatederivatives.A.Ravi,E.Spitznagel,N.Ravi371.Cosolventeffectsonaqueoussolutionpropertiesofdextran:Staticlightscatteringinvestigation.P.Alexandridis,K.T.Yong372.GradedmodificationofPAMAMdendrimerwithpoly(ethyleneglycol).E.O.Akala,G.Pan373.NMRimagingofwaterdiffusionintoPEM/P(HEMA-CO-THFMA)semi-IPNmatrices.D.J.T.Hill,M.Chowdhury,A.K.Whittaker,M.Braden,M.Patel374.IncorporatingN-vinyl-2-pyrrolidoneintopolyacrylonitrilebywater-phaseprecipitationcopolymerizationtoimproveitsbiocompatibility.L.S.Wan,Z.K.Xu,H.Y.Yu,M.X.Hu,X.J.Huang375.Novelpolymerboundbactericidalsurfaces.J.H.Wynne,A.W.Snow,J.M.Jones-Meehan,W.L.Straube376.Bileacid-basedresinsashydrophobicsponges.S.L.Regen,V.Janout,D.H.McCulloughIII,T.Vrablik,B.Jing

2004 Fall meeting

377.Withdrawn.378.Preparationofmultilayermicrocapsulesusingnon-toxicmaterials.W.H.Jeon,G.H.Kim,I.Kim,C.S.Ha379.Phosphazene-silicatehybridnetworkmembranes:Synthesis,characterization,andapplications.Y.Chang,D.T.Welna,H.R.Allcock380.Anti-microbialpoly(dimethylsiloxane)surfacesobtainedbymicrowaveplasmareactions.W.S.Bae,M.W.Urban

WEDNESDAYMORNING



Thiol-EnePhotopolymerizations

C.N.BowmanandA.B.Scranton,Organizers8:00—381.Kineticsandmechanismofthiol-enephotopolymerizationswithandwithoutphotoinitiators.C.N.Bowman,N.B.Cramer,S.K.Reddy8:30—382.Highlyfunctionalthiolssynthesizedbyanamine-catalyzedthiol-enereaction.T.S.Clark,C.E.Hoyle,S.E.Jönsson9:00—383.Nanocontactmoldingofthiol-enephotopolymers.M.Malkoch,E.C.Hagberg,C.J.Hawker,K.R.Carter9:30—384.Photopolymerizationandcopolymerizationofnovelself-initiatingmonomerswiththiolandvinylether.T.Y.Lee,C.A.Guymon,S.E.Jonsson,C.E.Hoyle10:00—Intermission.10:15—385.Thermalandphotopolymerizationofthiol-enenetworkformingsystems.W.D.Cook,D.Pattison10:50—386.Controllednetworkarchitecturesthroughthiol-eneandthiol-acrylatephotopolymerizations.S.K.Reddy,N.B.Cramer,A.Rydholm,K.S.Anseth,C.N.Bowman11:20—387.Investigationoftheeffectofalkenestructureonthereactionkineticsandmechanismsofphotoinducedthiol-enepolymerizations.T.M.Roper,C.A.Guymon,S.Jonsson,C.E.Hoyle



NewAdvancesinBiorelatedPolymersinHonorofJunzoSunamoto

K.E.Uhrich,OrganizerA.V.Kabanov,PresidingR.M.Ottenbrite,Organizer,Presiding8:30—388.Synthesisoffolicacidmoiety-conjugatedhydrophobizedpullulan(FA-CHP)asacarrierofanticancerdrugs.J.Sunamoto,K.Ushio,D.Lai8:50—389.Polymergenomics:Shiftingthedrugdeliveryparadigms.A.V.Kabanov,E.V.Batrakova,S.Sriadibhatla,Z.

2004 Fall meeting

Yang,D.L.Kelly,V.Y.Alakhov9:10—390.Designoflactide-basedcopolymersforbioabsorbablematerials.T.Ouchi,Y.Ohya9:30—391.Polymericnanohybridsfortargetingtumorangiogenesis.A.Mitra,J.Mulholland,A.Nan,E.McNeill,H.Ghandehari,B.Line9:50—392.ActivecontrolofDNArecognitionbehaviorofalfa-peptideribonucleicacidscontainingbasicaminoacidresiduesbyexternalfactors.T.Wada10:10—Intermission.10:30—393.Surfacemodificationofretinalimplants.C.Scholz,R.Sweitzer,P.Stewart,M.Gingerich,D.Shire,S.Montezuma,J.Rizzo10:50—394.Recentdevelopmentsofathrombogeniccoatingsforartificialkidney,microvascularbloodvesselsandMidlinecathederswithbloodvesselHeparansulfateandrelatedmimetics.H.Baumann11:10—395.Physicalandbiologicalevaluationofsilkfibroingels.C.Migliaresi,A.Motta,P.Torricelli,M.Fini,R.Giardino11:30—396.DesignandsynthesisofbiomolecularmaterialsbasedonSpiderandBombyxmorisilks.D.Y.Sogah,R.Osman,J.Geno



NanocompositesandInorganic-OrganicHybridCoatings

CosponsoredwithFederationofSocietiesforCoatingsTechnology,andPMSEP.Zarras,B.C.Benicewicz,andT.G.Wood,OrganizersA.J.Guenthner,PresidingB.Richey,Organizer,Presiding9:00—IntroductoryRemarks.9:05—397.Carbonnanotubethinfilmarchitecturesandnanocomposites.P.M.Ajayan9:50—398.Anapproachtonovelconductivecoatingsbasedonprocessablelinear-carbon.M.E.Wright,S.Fallis,A.J.Guenthner10:25—Intermission.10:35—399.Synthesisandcharacterizationofemulsionpolymer/claynanocomposites.D.P.Lorah,R.V.Slone,W.C.Finch11:10—400.UV-curable,hybridorganic-inorganiccoatingscontainingmetaloxidenanoparticles.B.J.Chisholm,J.Resue11:45—ConcludingRemarks.



2004 Fall meeting

CosponsoredwithYCC,andPRESH.N.ChengandT.E.Long,OrganizersE.H.MartinandT.J.Pacansky,Organizers,Presiding8:15—IntroductoryRemarks.8:20—401.Rationaldesignofthecatalystforatomtransferradicalpolymerizationinaqueousmedia.N.V.Tsarevsky,K.Matyjaszewski8:40—402.Mainchainperfluorocyclobutyl(PFCB)liquidcrystallinepolymerswitholigo-p-phenylenevertebrae.J.Jin,S.Glaser,J.Ballato,D.W.SmithJr.9:00—403.Branchedpolyethylenefromethylenemonomer:AreneutralNi(II)iminophosphonamidecomplexesinvolvedinpolymerizationcatalysis?R.A.Stapleton,A.Nuamthanom,P.L.Rinaldi,N.J.Taylor,S.Collins9:20—404.Lipase-catalyzedroutetohyperbranchedpolymerswithdendriticglycerolunits.A.Kulshrestha,W.Gao,D.Kudasheva,R.A.Gross9:40—405.Exploringthearchitecturalandhydrogenbondingmediatedlong-rangeconnectivityofthehardsegmentphaseinmodeloligomericpolyurethanes.J.P.Sheth,A.R.Fornof,T.E.Long,I.Yilgor,G.L.Wilkes10:00—Intermission.10:15—406.Antigen-decoratedshellcrosslinkednanoparticles.M.J.Joralemon,K.L.Wooley10:35—407.Biomaterialswithtightlycontrolledporesizethatpromotevascularin-growth.A.J.Marshall,C.A.Irvin,T.Barker,E.H.Sage,K.D.Hauch,B.D.Ratner10:55—408.Controlofbioresponsetopolymers.L.H.Wilson11:15—409.Theimpactofoxygenonphotopolymerizationkineticsandpolymerstructure.A.K.O'Brien,C.N.Bowman11:35—410.Functionalperfluoropolyethersasnovelmaterialsformicrofluidicsandsoftlithography.J.Rolland,R.M.vanDam,E.C.Hagberg,K.R.Carter,S.R.Quake,J.DeSimone

WEDNESDAYAFTERNOON



CationicPhotopolymerizations

C.N.BowmanandA.B.Scranton,Organizers1:30—411.Synthesisofmicrospheresbycationicsuspensionphotopolymerization.J.V.Crivello,B.Falk2:05—412.Characterizationofkineticrateconstantsofcationicphotopolymerizationsofepoxides.V.Sipani,A.Kirsch,A.B.Scranton2:40—413.Hyperbranchedpolymerincationicphotopolymerizationofepoxysystems.M.SangermanoII,R.Bongiovanni,A.Priola,G.Malucelli,A.Harden,B.Voit,R.R.Thomas3:15—Intermission.3:35—414.Synthesisandcationicphotopolymerizationofnewsilicon-containingoxetanemonomers.M.SangermanoII,R.Bongiovanni,G.Malucelli,A.Priola,A.Harden,N.Rehnberg4:10—415.DarkandlightreactionsinEBcationicpolymerizationofepoxies.J.Lee,G.R.Palmese

2004 Fall meeting



BiorelatedNanostructuresandAssemblies

R.M.OttenbriteandK.Uhrich,OrganizersJ.S.RiffleandH.Baumann,Presiding1:30—416.GelandmicelletypeintermediatesolutionstructuresofPEG-b-polylactideforhydrophilicandhydrophobicdrugdelivery.I.M.Khan,J.K.Krangle,K.P.Pemawansa1:50—417.Novelblockionomermicelleswithcross-linkedioniccores.T.K.Bronich,A.V.Kabanov2:10—418.Core/shellnanoparticleswithlipidcoreforadrugdeliverysystem.S.H.Yuk,K.S.Oh,S.H.Cho2:30—419.Enhancedanticanceractivityofcore-surface-crosslinkednanoparticles.P.Xu,E.A.VanKirk,S.Li,J.Ren,W.J.Murdoch,M.Radosz,Y.Shen2:50—420.Selectiveandeffectivecytotoxicityoffolicacid-conjugatedCHPhydrogelnanoparticlescomplexedwithanticancerdrugsininvitrostudies.M.Hidaka,M.Yamamoto,K.Ichinose,T.Kanematsu,N.Ishii,K.Ushio,J.Sunamoto3:10—Intermission.3:30—421.Effectofpluronicblockcopolymersongeneexpression.A.V.Kabanov,S.Sriadibhatla,Z.Yang,V.Y.Alakhov3:50—422.Blockionomercomplexesfromcombinationsofsurfactants:Particlemorphologyandsurfactantmixing.S.V.Solomatin,T.K.Bronich,V.A.Kabanov,A.Eisenberg,A.V.Kabanov4:10—423.Magneticpoly(L-lactide)-cobaltcomplexesandmicrospheres.M.Vadala,M.S.Thompson,M.Zalich,T.G.St.Pierre,J.S.Riffle



NanocompositesandInorganic-OrganicHybridCoatings

CosponsoredwithFederationofSocietiesforCoatingsTechnology,andPMSET.G.WoodandB.Richey,OrganizersP.ZarrasandB.C.Benicewicz,Organizers,Presiding1:30—IntroductoryRemarks.1:35—424.Nanostructuredinorganicconversioncoatings.J.L.Liang,W.E.Fristad,K.Meagher,T.Bryden2:10—425.Nanosystemsforfilmformation.A.Üveges,J.F.Hartmann,J.Borbely2:35—426.Nanocompositecoatingmaterialsfromhybridlatexes.V.Castelvetro,C.DeVita,M.Geppi,S.Giaiacopi,G.Giannini,M.Martinelli3:00—Intermission.3:10—427.Polyurethane/polysiloxaneceramercoatings.H.Ni,W.J.SimonsickJr.,M.D.Soucek3:45—428.SynthesisandphotopolymerizationofUVcurablepolyhedraloligomericsilsesquioxane(POSS).B.Pan,C.E.

2004 Fall meeting

Hoyle,J.Lichtenhan4:10—ConcludingRemarks.


GeneralPapers

PolymerSynthesis-B

D.Garcia,OrganizerR.Ranade,Presiding1:00—429.Peroxidecrosslinkingofanunsaturatedthermotropicpolyester.H.Qin,P.T.Mather1:20—430.Towardsthermallycross-linkeddiblockcopolymertemplatesusingpoly[(styrene-r-benzocyclobutene)-b-D,L-lacticacid].J.Leiston-Belanger,E.Drockenmuller,C.Hawker,T.P.Russell1:40—431.Synthesisandpropertiesofamaskedmaleimide-containingpoly(phenyleneethynylene).T.M.Swager,G.C.Bailey2:00—432.Newsyntheticrouteforconjugatedthiophenes.W.G.Skene,T.Trefz2:20—433.Synthesisofstarchmaleatehalf-estersundermicrowaveirradiation.A.Biswas,R.L.Shogren,J.L.Willett2:40—434.Polymerizationofhigheralpha-olefinswithmetallocenecatalysts.M.R.Mosia,R.Duchateau,G.J.G.J.M.Gruter3:00—435.Synthesisofnarrowdistributionpolycyclopenteneusingaruthenium-basedringopeningmetathesisinitiator.S.B.Myers,R.A.Register3:20—436.Triisobutylaluminumaspowerfulcatalystfortheanionicpolymerizationofpropyleneoxideinitiatedbyalkalimetalderivativesortetralkylammoniumsalts.A.Deffieux,C.Billouard,S.Carlotti,P.Desbois3:40—437.Novelmethodologyforstarpolymersynthesisusingthereactionoflivingpolymerswithalkoxysilyl-functionalizedpolymers.M.D.Foster,R.P.Quirk,C.Wesdemiotis,K.M.Wollyung,J.S.Lee4:00—438.Influenceofsurfactantsonpropertiesofchemicallysynthesizedpolypyrrole.M.Omastová,M.Trchová,J.Stejskal4:20—439.Photolyticandfreeradicalpolymerizationofepoxidizedplantoiltriglycerides.H.Esen,S.H.Kusefoglu,R.P.Wool4:40—440.Enhancedepoxidationofsoybeanoilthroughmicroemulsiontechnique.D.Rethwisch,A.B.Scranton,K.Jain,P.G.Rasmussen

THURSDAYMORNING

SectionAMarriott--SalonA


MaterialsDevelopment

2004 Fall meeting

C.N.BowmanandA.B.Scranton,Organizers8:00—445.Synthesisofcompositematerialsbyphotopolymerization.C.Decker,L.Keller,S.Benfarhi,K.Zahouily,C.Bianchi8:35—442.Nanocontactmoldingoffunctionalphotopolymerresinsfordirectfabricationoforganicelectronics.E.C.Hagberg,K.R.Carter9:00—443.Kineticstudiesofsurface-confined,photoinifertermediatedphotopolymerization.S.B.Rahane,S.M.KilbeyII,A.T.Metters9:25—444.Effectofpolymer-brushmodifiedfilleronphotopolymerization.X.Ding,J.W.Stansbury,S.Newman9:50—Intermission.10:10—441.Photopolymerizationofsynthetichydrogelnichesfor3Dcellcultureandtissueregeneration.M.A.Rice,P.Martens,S.J.Bryant,M.J.Mahoney,C.N.Bowman,K.S.Anseth10:45—446.Synthesisandphotopolymerizationofnovelmultifunctionalvinylesterdendrimers.T.Y.Lee,C.A.Guymon,S.E.Jonsson,C.E.Hoyle11:10—447.Reverse-selectivepolymericmembranesforhydrogenpurification.H.Lin,B.D.Freeman,L.Toy,V.Bondar,R.Gupta,S.Pas,A.Hill11:35—448.ThermalUVdualcureofoxetaneacrylates.M.Sangermano,M.Manea

SectionBMarriott--SalonI&J


BiosensorsandAssays

R.M.OttenbriteandK.Uhrich,OrganizersA.Guiseppi-ElieandC.Scholz,Presiding8:30—449.Multi-modeconjugationofenzymesonpolymernanoparticlescoveredwithphosphorylcholinegroupsforhigh-sensitivediagnosis.K.Ishihara,T.Konno,J.Watanabe8:50—450.Mimickingtheimmunologicalsynapsewithmulticomponentprotein-patternedsurfaces.D.J.Irvine,J.Doh9:10—451.Cationicfaciallyamphiphilicphenyleneethynylenesashostdefensepeptidemimics.G.N.Tew,L.Arnt9:30—452.Synthesisandcharacterizationofbioconjugatesofnaturalpolymersandpeptidesforthedetectionofbacterialspores.N.K.Sharma,K.Levon9:50—453.Theself-assemblyofhydrogelsensorsintoafunctionalarray.S.M.Grayson,M.J.Schmid,J.E.Meiring,V.Desai,D.U,K.Manthiram,A.D.Ellington,C.G.Willson10:10—Intermission.10:30—454.Solid-phaseimmunoassayonpolymer-basedmicroanalyticaldevices.S.Wei,S.A.Soper,R.L.McCarley10:50—455.TransductionandmolecularrecognitionofClostridiumbotulinumusingpolyanilinenanowiremodifiedantibodyattachedtoquartzcrystalmicrobalance.J.Lou,H.Yin11:10—456.Structureanalysisofthebeta1-28fragmentoftheamyloidpeptidebypolarizedRaman,IRandelectronicCDspectroscopy.R.Schweitzer-Stenner,F.Eker,K.Griebenow

2004 Fall meeting

SectionCMarriott--SalonB


SpecialtyandAdvancedCoatings

CosponsoredwithFederationofSocietiesforCoatingsTechnology,andPMSEP.Zarras,B.C.Benicewicz,andB.Richey,OrganizersS.Feng,PresidingT.G.Wood,Organizer,Presiding8:00—IntroductoryRemarks.8:05—457.Effectofprocessingparametersontheanisotropyofsolvent-casterigidpolymerfilms.A.J.Guenthner,K.R.Davis,L.Steinmetz,J.M.Pentony8:35—458.Combinatorialandhigh-throughputdevelopmentofpolymersensormaterialsforopticalandresonantsensors.R.A.Potyrailo9:05—459.Spraycoatableelectroactivedioxythiophenepolymers.B.D.Reeves,C.R.G.Grenier,J.R.Reynolds9:35—460.Newfunctionalfluorinatedacrylatecoating:PTFEAwithtwohydroxylgroupsatsamechainend.H.Hong,T.C.Chung9:55—Intermission.10:05—461.Responsivecoatingsforthesequestrationandremovaloftoxicheavymetalsfromsurfaces.H.N.Gray,B.S.Jorgensen10:35—462.Novelautodepositingcoatingcompositionproducedbymini-emulsionsyntheticapproach.B.D.Bammel,J.D.McGee11:05—463.OligomersofH12-MDIanddiethylmalonateasprecursorsforlowtemperaturepowdercoatingscrosslinkers.T.P.Fäcke,S.Feng11:35—ConcludingRemarks.

THURSDAYAFTERNOON

SectionAMarriott--SalonA


PhotopolymerizationKinetics

C.N.BowmanandA.B.Scranton,Organizers1:00—464.Kineticmodelingofphotoinitiatedacrylatepolymerization.J.F.G.A.Jansen,T.J.G.Zwartkruis1:30—465.Compositiondependenceofthephotopolymerizationkineticsinholographicpolymerdispersedliquidcrystals(HPDLCs).T.J.White,C.A.Guymon1:55—466.Insitumonitoringofconversionextentandviscoelasticpropertiesduringthephotocrosslinkingofanacrylateformulation.J.Dupuy,A.Botella,A.A.Roche,H.Sautereau,V.Verney2:20—467.Thermalandphotochemicalcuringofacrylicresins.K.Studer,C.Decker,E.Beck,R.Schwalm

2004 Fall meeting

2:50—468.Effectofthemoleculardynamicsonthephotopolymerizationprocess.E.Andrzejewska,P.Ziobrowski,A.Maciejewska,E.Socha,M.Drozdowski,M.Andrzejewski3:20—Intermission.3:35—469.Influenceofhydrogenbondingonthephotopolymerizationratesofmono-andmultifunctional(meth)acrylates.T.Y.Lee,C.A.Guymon,T.M.Roper,S.E.Jonsson,C.E.Hoyle4:05—470.Studyoflaser-initiatedpolymerizationsbyopticalpyrometry.M.Jang,J.V.Crivello,B.Falk,P.Lin4:30—471.Photoinitiatedfrontalpolymerizationkineticsofmeth(acrylates).C.Nason,C.E.Hoyle,J.Pojman

SectionBMarriott--SalonI&J


Protein,DNAandPolysaccharides

R.M.OttenbriteandK.Uhrich,OrganizersD.Y.SogahandH.Ghandehari,Presiding1:30—472.SynthesisofDNA-polymerhybridsusingaqueoussolution-basedatomtransferradicalpolymerization(ATRP).X.Lou,L.He1:50—473.AnovelpolysaccharideDNA-carriertodeliverCpGmotifstoendosome.K.Sakurai,S.Shinkai2:10—474.Osmoticandsmall-angleneutronscatteringpropertiesofDNAgels.F.Horkay,P.J.Basser,A.M.Hecht,E.Geissler2:30—475.Structure-baseddesignandsynthesisofartificialproteinpolymersfortoxininhibition.R.S.Farmer,B.D.Polizzotti,J.D.Sharp,K.L.Kiick2:50—476.Dynamicsandinteractionsofcomplexesformedbycarrageenan/furcelleranandbovineserumalbuminhybrids.Q.Huang,J.Lee,C.Ruengruglikit3:10—Intermission.3:30—477.Microencapsulationandcontrolled-releaseoffoodenzymeusingprotein-polysaccharidecoacervates.Y.Jiang,Q.Huang3:50—478.Enzyme-polymercompositeswithhighactivityandstability.J.Kim,T.J.KostoII,J.C.Manimala,E.B.Nauman,J.S.Dordick4:10—479.Enzymaticmodificationofpolysaccharidebiopolymers:Rheology,kineticsandsynergisticeffectsofmultipleglycosidaseenzymes.S.Mahammad,S.A.Khan

SectionCMarriott--SalonB


SpecialtyandAdvancedCoatings

CosponsoredwithFederationofSocietiesforCoatingsTechnology,andPMSEP.Zarras,B.C.Benicewicz,andT.G.Wood,Organizers

2004 Fall meeting

D.B.Pourreau,PresidingB.Richey,Organizer,Presiding1:00—IntroductoryRemarks.1:05—480.Modifiedureabasedliquidrheologyadditivesforcoatings.J.Hajas1:30—481.Weatheringandglosslossinthermoplasticpaints:CaseofPVDFarchitecturalpaints.K.A.Wood2:00—482.Newlow-viscosityacrylic-urethaneprepolymersandtheiracrylatedoligomersformoisture-andUV-curablecoatingsandadhesives.D.B.Pourreau,S.E.Smyth2:30—Intermission.2:40—483.HighperformanceUV-curedacryliccoatings.C.Decker3:10—484.DevelopmentofaUV-curingpolyurethanedispersionforsoftfeelapplication.P.D.Schmitt,L.K.Gindin,A.Lockhart,P.D.Lunney3:40—485.Surface-fluorinatedpolyurethanecoatings.W.Ming4:05—486.Thiopheneoligomerasa″redoxmediator″forthebiocatalyticsynthesisofPoly(3,4-Ethylenedioxythiophene)[PEDOT].R.Nagarajan,F.F.Bruno,L.A.Samuelson,J.Kumar4:35—ConcludingRemarks.

2004 fall natl acs meeting - polyacs.org

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