· 11231 richmond avenue suite d104 houston, tx 77082 tel (832) 916-3690 october 6, 2017 project...

11231 Richmond Avenue

Suite D104 Houston, TX 77082 Tel (832) 916-3690

�

October 6, 2017 Project No. 4020

Mr. Rodney Bryant VCP-CA Section, MC-221 Remediation Division Texas Commission on Environmental Quality P. O. Box 13087 Austin, Texas 78711-3087 SUBJECT: VOLUNTARY CLEANUP PROGRAM (VCP)

CES GRIGGS ROAD VCP SITE 4900 GRIGGS ROAD, 4904 GRIGGS ROAD, AND 5910 WAYLAND STREET (VCP No. 2751; CN604824904; RN108370644) RESPONSE TO JUNE 16, 2017 COMMENTS ON REVISED APAR: COMMENT 3 GROUNDWATER GRADIENT INFORMATION COMMENT 5 EXPANDED LIST OF ANALYTES IN GROUNDWATER

Dear Mr. Bryant: Pastor, Behling & Wheeler, LLC (PBW), on behalf of the CES Griggs Road PRP Group (the “Group”), is providing the laboratory reports for the September 21, 2017 submittal of responses to TCEQ Comment Nos. 3 and 5 on the revised Affected Property Assessment Report (APAR). The APAR summarized the environmental assessment of the CES Griggs Road VCP Site (the “Site”) pursuant to the requirements of VCP Agreement No. 2751. The VCP Agreement was executed between the Group and the Texas Commission on Environmental Quality (TCEQ) on June 10, 2015. As a clarification, the September 21, 2017 submittal transmitted the following field and laboratory data:

1. groundwater gauging event conducted for monitoring wells located at the Site and the Former Joy Tabernacle VCP No. 2729 site on July 26, 2017;

2. groundwater analytical results from the February 1 to February 2, 2017 sampling event with data for the expanded list of analytes for semivolatile organic compounds (SVOCs) and volatile organic compounds (VOCs);

3. the groundwater analytical results from the May 16, 2017 sampling event with data for chlorinated VOCs (CVOCs) and monitored natural attenuation (MNA) parameters; and

4. the groundwater analytical results from the August 10, 2017 sampling event with data for CVOCs and dibenz(a,h)anthracene (MW-03 only).

The laboratory reports for items 2 through 4 and data usability summary for these three sampling events are attached to this letter.

Mr. Rodney Bryant October 6, 2017 of 2 If you have any questions or comments, please call (832) 916-3691 or email [email protected]. Sincerely, PASTOR, BEHLING & WHEELER, LLC

Brenda P. Basile, Ph.D. Senior Consulting Scientist cc: CES Griggs Road PRP Group Attachment: Revised Laboratory Report HS17020115 Laboratory Report HS17050883 Laboratory Report HS17080601 Data Usability Summary CES APAR DUS

Mr. Rodney Bryant October 4, 2017

Attachments

THIS PAGE BLANK

June 29, 2017

Brenda BasilePastor, Behling & Wheeler, LLC11231 Richmond AvenueSuite D104Houston, TX 77082

This is a REVISED REPORT. Please see the TRRP Laboratory Review Checklist for discussion concerning this revision.

Regards,

ALS Environmental received 10 sample(s) on Feb 02, 2017 for the analysis presented in the following report.

Laboratory Results for: CES Griggs Rd VCP

Dear Brenda,

Work Order: HS17020115

Generated By: Dane.Wacasey

Dane J. Wacasey

1Revision:

10450 Stancliff Rd. Suite 210 Houston, TX 77099 T: +1 281 530 5656 F: +1 281 530 5887

www.alsglobal.comRight Solutions • Right Partner

Page 1 of 99

Client:TRRP Laboratory Data Package Cover PageProject:

WorkOrder:

Pastor, Behling & Wheeler, LLCCES Griggs Rd VCPHS17020115

This data package consists of all or some of the following as applicable:

This signature page, the laboratory review checklist, and the following reportable data:

R1 Field chain-of-custody documentation;

R2 Sample identification cross-reference;

R3 Test reports (analytical data sheets) for each environmental sample that includes:a) Items consistent with NELAC Chapter 5, b) dilution factors, c) preparation methods, d) cleanup methods, and e) if required for the project, tentatively identified compounds (TICs).

R4 Surrogate recovery data including:a) Calculated recovery (%R), and b) The laboratory’s surrogate QC limits.

R5 Test reports/summary forms for blank samples;

R6 Test reports/summary forms for laboratory control samples (LCSs) including:a) LCS spiking amounts, b) Calculated %R for each analyte, and c)The laboratory’s LCS QC limits.

R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified, b) MS/MSD spiking amounts, c) Concentration of each MS/MSD analyte measured in the parent and spiked samples, d) Calculated %Rs and relative percent differences (RPDs), and e) The laboratory’s MS/MSD QC limits.

R8 Laboratory analytical duplicate (if applicable) recovery and precision:a) the amount of analyte measured in the duplicate, b) the calculated RPD, and c) the laboratory’s QC limits for analytical duplicates.

R9 List of method quantitation limits (MQLs) and detectability check sample results for eachanalyte for each method and matrix.

R10 Other problems or anomalies. The Exception Report for each “No” or “Not Reviewed (NR)” item in Laboratory Review Checklist andfor each analyte, matrix, and method for which the laboratory does not hold NELAC accreditation underthe Texas Laboratory Accreditation Program.

ALS Group USA, Corp Date: 29-Jun-17

Page 2 of 99


WorkOrder:


Dane J. Wacasey

Release Statement: I am responsible for the release of this laboratory data package. This laboratory isNELAC accredited under the Texas Laboratory Accreditation Program for all the methods, analytes andmatrices reported in this data package except as noted in the Exception Reports. The data have beenreviewed and are technically compliant with the requirements of the methods used, except where noted bythe laboratory in the attached exception reports. By my signature below, I affirm to the best of myknowledge, all problems/anomalies, observed by the laboratory have been identified by the laboratory inthe Laboratory Review Checklist, and no information affecting the quality of the data has been knowinglywithheld.

Check, if applicable: [NA] This laboratory meets an exception under 30 TAC §25.6 and was last inspectedby [ ] TCEQ or [ ] ______________ on (enter date of last inspection). Any findings affecting the data inthis laboratory data package are noted in the Exception Reports herein. The official signing the cover pageof the report in which these data are used is responsible for releasing this data package and is by signatureaffirming the above release statement is true.


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Laboratory Review Checklist: Reportable Data

Laboratory Name: ALS Laboratory Group LRC Date: 02/09/2017 Project Name: CES Griggs Rd VCP Laboratory Job Number: HS17020115 Reviewer Name: Dane Wacasey Prep Batch Number(s): 112040,112094,112095,112117,R289061 #1 A2 Description Yes No NA3 NR4 ER#5

R1 OI Chain-of-custody (C-O-C)

Did samples meet the laboratory’s standard conditions of sample acceptability upon receipt? X

Were all departures from standard conditions described in an exception report? X R2 OI Sample and quality control (QC) identification Are all field sample ID numbers cross-referenced to the laboratory ID numbers? X Are all laboratory ID numbers cross-referenced to the corresponding QC data? X R3 OI Test reports Were all samples prepared and analyzed within holding times? X

Other than those results < MQL, were all other raw values bracketed by calibration standards? X

Were calculations checked by a peer or supervisor? X Were all analyte identifications checked by a peer or supervisor? X Were sample detection limits reported for all analytes not detected? X Were all results for soil and sediment samples reported on a dry weight basis? X Were % moisture (or solids) reported for all soil and sediment samples? X

Were bulk soils/solids samples for volatile analysis extracted with methanol per SW-846 Method 5035? X

If required for the project, TICs reported? X R4 O Surrogate recovery data Were surrogates added prior to extraction? X

Were surrogate percent recoveries in all samples within the laboratory QC limits? X

R5 OI Test reports/summary forms for blank samples Were appropriate type(s) of blanks analyzed? X Were blanks analyzed at the appropriate frequency? X

Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures? X

Were blank concentrations < MQL? X R6 OI Laboratory control samples (LCS): Were all COCs included in the LCS? X

Was each LCS taken through the entire analytical procedure, including prep and cleanup steps? X

Were LCSs analyzed at the required frequency? X Were LCS (and LCSD, if applicable) %Rs within the laboratory QC limits? X 1

Does the detectability data document the laboratory’s capability to detect the COCs at the MDL used to calculate the SDLs? X

Was the LCSD RPD within QC limits? X R7 OI Matrix spike (MS) and matrix spike duplicate (MSD) data Were the project/method specified analytes included in the MS and MSD? X Were MS/MSD analyzed at the appropriate frequency? X Were MS (and MSD, if applicable) %Rs within the laboratory QC limits? X 2 Were MS/MSD RPDs within laboratory QC limits? X 3 R8 OI Analytical duplicate data Were appropriate analytical duplicates analyzed for each matrix? X Were analytical duplicates analyzed at the appropriate frequency? X Were RPDs or relative standard deviations within the laboratory QC limits? X R9 OI Method quantitation limits (MQLs): Are the MQLs for each method analyte included in the laboratory data package? X

Do the MQLs correspond to the concentration of the lowest non-zero calibration standard? X

Are unadjusted MQLs and DCSs included in the laboratory data package? X R10 OI Other problems/anomalies

Are all known problems/anomalies/special conditions noted in this LRC and ER? X 7

Were all necessary corrective actions performed for the reported data? X

Was applicable and available technology used to lower the SDL and minimize the matrix interference affects on the sample results? X

Is the laboratory NELAC-accredited under the Texas Laboratory Program for the analytes, matrices and methods associated with this laboratory data package? X 4

Items identified by the letter “R” must be included in the laboratory data package submitted in the TRRP-required report(s). Items identified by the letter “S” should be retained and made available upon request for the appropriate retention period. O = Organic Analyses; I = Inorganic Analyses (and general chemistry, when applicable); NA = Not Applicable; NR = Not Reviewed; R# = Exception Report identification number (an Exception Report should be completed for an item if “NR” or “No” is checked).

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Laboratory Review Checklist: Supporting Data Laboratory Name: ALS Laboratory Group LRC Date: 02/09/2017 Project Name: CES Griggs Rd VCP Laboratory Job Number: HS17020115 Reviewer Name: Dane Wacasey Prep Batch Number(s): 112040,112094,112095,112117,R289061 #1 A2 Description Yes No NA3 NR4 ER#5

S1 OI Initial calibration (ICAL)

Were response factors and/or relative response factors for each analyte within QC limits? X

Were percent RSDs or correlation coefficient criteria met? X Was the number of standards recommended in the method used for all analytes? X

Were all points generated between the lowest and highest standard used to calculate the curve? X

Are ICAL data available for all instruments used? X

Has the initial calibration curve been verified using an appropriate second source standard? X

S2 OI Initial and continuing calibration verification (ICCV and CCV) and

continuing calibration blank (CCB) Was the CCV analyzed at the method-required frequency? X Were percent differences for each analyte within the method-required QC limits? X 5 Was the ICAL curve verified for each analyte? X Was the absolute value of the analyte concentration in the inorganic CCB < MDL? X 6 S3 O Mass spectral tuning: Was the appropriate compound for the method used for tuning? X Were ion abundance data within the method-required QC limits? X S4 O Internal standards (IS): Were IS area counts and retention times within the method-required QC limits? X

S5 OI Raw data (NELAC section 1 appendix A glossary, and section 5.12 or ISO/IEC 17025 section

Were the raw data (for example, chromatograms, spectral data) reviewed by an analyst? X

Were data associated with manual integrations flagged on the raw data? X S6 O Dual column confirmation Did dual column confirmation results meet the method-required QC? X S7 O Tentatively identified compounds (TICs):

If TICs were requested, were the mass spectra and TIC data subject to appropriate checks? X

S8 I Interference Check Sample (ICS) results: Were percent recoveries within method QC limits? X S9 I Serial dilutions, post digestion spikes, and method of standard additions

Were percent differences, recoveries, and the linearity within the QC limits specified in the method? X

S10 OI Method detection limit (MDL) studies Was a MDL study performed for each reported analyte? X Is the MDL either adjusted or supported by the analysis of DCSs? X S11 OI Proficiency test reports:

Was the laboratory's performance acceptable on the applicable proficiency tests or evaluation studies? X

S12 OI Standards documentation

Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources? X

S13 OI Compound/analyte identification procedures Are the procedures for compound/analyte identification documented? X S14 OI Demonstration of analyst competency (DOC) Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? X Is documentation of the analyst’s competency up-to-date and on file? X

S15 OI Verification/validation documentation for methods (NELAC Chap 5 or ISO/IEC 17025 Section 5)

Are all the methods used to generate the data documented, verified, and validated, where applicable? X

S16 OI Laboratory standard operating procedures (SOPs): Are laboratory SOPs current and on file for each method performed? X Items identified by the letter “R” must be included in the laboratory data package submitted in the TRRP-required report(s). Items identified by the letter “S” should be retained and made available upon request for the appropriate retention period. O = Organic Analyses; I = Inorganic Analyses (and general chemistry, when applicable); NA = Not Applicable; NR = Not Reviewed; R# = Exception Report identification number (an Exception Report should be completed for an item if “NR” or “No” is checked).

Page 5 of 99

Laboratory Review Checklist: Exception Data

Laboratory Name: ALS Laboratory Group LRC Date: 02/09/2017 Project Name: CES Griggs Rd VCP Laboratory Job Number: HS17020115 Reviewer Name: Dane Wacasey Prep Batch Number(s): 112040,112094,112095,112117,R289061 ER#5 Description

7

This report was revised June 29, 2017 in order to extend the lists of reported analytes for methods SW8260 and SW8270 at the request of the client.

1

Batch R297111, Volatile Organics method SW8260, The LCS was recovered below the lower control limit for Dichlorodifluoromethane. Slight negative bias to results is present for associated samples.

2

Batch 112094, Metals Method SW6020, sample MW-05 170201, MSD recovered below the lower control limit for Barium, however, the result in the parent sample is greater than 4x the spike amount. Batch 112095, Metals Method SW6020, sample HS17020151-03, MS and MSD were performed on unrelated sample. Batch 112040a, Semivolatile Organics Method SW870, sample MW-05 170201, MS failed recovery criteria for 2-Methylnaphthalene due to possible matrix interference.

3

Batch 112040a, Semivolatile Organics Method SW870, sample MW-05 170201, MSD RPD criterion was exceeded for 3,3´-Dichlorobenzidine. This individual recoveries were within criteria.

4

With the exception of 1-Methylnaphthalene Semivolatile Organics Method SW8270 ALS is NELAC-accredited under the Texas Laboratory Program for the analytes, matrices and methods associated with this laboratory data package. Because TCEQ does not offer accreditation for this compound, the results are flagged with n.

5

Batch R297111, Volatile Organics method SW8260, Dichlorodifluoromethane %D (60%) was recovered in the CCV outside of acceptance limits (80-120).

6 See Run Log and CCB Exceptions Report.


Page 6 of 99

ICPMS05_289124Run ID:

FORM 13 - ANALYSIS RUN LOG

SW6020Method: Instrument:

Sample No. D/F Time Analytes

HS17020115CES Griggs Rd VCPPastor, Behling & Wheeler, LLC

WorkOrder:Project:Client:

ICPMS05

Start Date: End Date:07-Feb-2017 07-Feb-2017

FileIDICV 1 07-Feb-2017 10:44 010_ICV.d BA MN VLLICV5 1 07-Feb-2017 10:47 011LICV.d BA MN VLLICV2 1 07-Feb-2017 10:50 012SMPL.d BA MN VICB 1 07-Feb-2017 10:53 013_ICB.d BA MN VICSA 1 07-Feb-2017 10:56 014ICSA.d BA MN VICSAB 1 07-Feb-2017 10:59 015ICSB.d BA MN VCCV 1 1 07-Feb-2017 11:20 022_CCV.d BA MN VCCB 1 1 07-Feb-2017 11:23 023_CCB.d BA MN VCCV 2 1 07-Feb-2017 11:55 034_CCV.d BA MN VCCB 2 1 07-Feb-2017 11:58 035_CCB.d BA MN VMBLK-112094 1 07-Feb-2017 12:13 040SMPL.d BA MN VLCS-112094 1 07-Feb-2017 12:16 041SMPL.d BA MN VMW-05 170201 1 07-Feb-2017 12:22 043SMPL.d BA MN VMW-05 170201SD 5 07-Feb-2017 12:25 044SMPL.d BA MN VCCV 3 1 07-Feb-2017 12:28 045_CCV.d BA MN VCCB 3 1 07-Feb-2017 12:31 046_CCB.d BA MN VMW-05 170201MS 1 07-Feb-2017 12:34 047SMPL.d BA MN VMW-05 170201MSD 1 07-Feb-2017 12:37 048SMPL.d BA MN VMW-05 170201PDS 1 07-Feb-2017 12:40 049SMPL.d BA MN VMW-01 170202 1 07-Feb-2017 12:52 053SMPL.d BA MN VMW-01 Dup 170202 1 07-Feb-2017 12:55 054SMPL.d BA MN VMW-02 170201 1 07-Feb-2017 12:58 055SMPL.d BA MN VMW-03 170201 1 07-Feb-2017 13:01 056SMPL.d BA MN VCCV 4 1 07-Feb-2017 13:04 057_CCV.d BA MN VCCB 4 1 07-Feb-2017 13:07 058_CCB.d BA MN VMW-04 170201 1 07-Feb-2017 13:10 059SMPL.d BA MN VMW-06 170201 1 07-Feb-2017 13:13 060SMPL.d BA MN VMW-07 170202 1 07-Feb-2017 13:16 061SMPL.d BA MN VMW-08 170201 1 07-Feb-2017 13:19 062SMPL.d BA MN VCCV 5 1 07-Feb-2017 13:40 069_CCV.d BA MN VCCB 5 1 07-Feb-2017 13:43 070_CCB.d BA MN VMBLKF-112095 1 07-Feb-2017 13:51 073SMPL.d BA MN VMBLK-112095 1 07-Feb-2017 13:54 074SMPL.d BA MN VLCS-112095 1 07-Feb-2017 13:57 075SMPL.d BA MN VMW-03 170201 1 07-Feb-2017 14:00 076SMPL.d BA MN VMW-06 170201 1 07-Feb-2017 14:03 077SMPL.d BA MN VCCV 6 1 07-Feb-2017 14:15 081_CCV.d BA MN VCCB 6 1 07-Feb-2017 14:18 082_CCB.d BA MN VZZZZZZSD 5 07-Feb-2017 14:21 083SMPL.d BA MN VZZZZZZMS 1 07-Feb-2017 14:24 084SMPL.d BA MN VZZZZZZMSD 1 07-Feb-2017 14:27 085SMPL.d BA MN VZZZZZZPDS 1 07-Feb-2017 14:30 086SMPL.d BA MN VCCV 7 1 07-Feb-2017 14:51 093_CCV.d BA MN VCCB 7 1 07-Feb-2017 14:54 094_CCB.d BA MN VICCV 8 1 07-Feb-2017 15:26 105_ICV.d BA MN VLLCCV5 1 07-Feb-2017 15:29 106LICV.d BA MN VLLCCV2 1 07-Feb-2017 15:32 107SMPL.d BA MN VICCB 8 1 07-Feb-2017 15:35 108_ICB.d BA MN VCCV 9 1 07-Feb-2017 15:53 114_CCV.d BA MN VCCB 9 1 07-Feb-2017 15:56 115_CCB.d BA MN VCCV 10 1 07-Feb-2017 16:29 126_CCV.d BA MN VCCB 10 1 07-Feb-2017 16:32 127_CCB.d BA MN VCCV 11 1 07-Feb-2017 17:04 138_CCV.d BA MN VCCB 11 1 07-Feb-2017 17:07 139_CCB.d BA MN V

29-Jun-17Date: ALS Group USA, Corp

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ICPMS05_289124Run ID:

CCB EXCEPTIONS REPORT




ICPMS05

Seq: 3979139ICB 107-Feb-2017 10:53 D/F:Date:Analyte Result MDL Report Limit

Units: ug/L

-1.256 0.6 5Vanadium

Seq: 3979149CCB 1 107-Feb-2017 11:23 D/F:Date:Analyte Result MDL Report Limit

Units: ug/L



Units: ug/L

1.041 0.6 5Vanadium

Seq: 3979632ICCB 8 107-Feb-2017 15:35 D/F:Date:Analyte Result MDL Report Limit

Units: ug/L



Units: ug/L



Units: ug/L



Page 8 of 99

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Client: Pastor, Behling & Wheeler, LLC

Work Order: HS17020115Project: CES Griggs Rd VCP SAMPLE SUMMARY

Lab Samp ID Client Sample ID Collection DateMatrix TagNo Date Received Hold

HS17020115-01 02-Feb-2017 09:25 02-Feb-2017 14:12MW-01 170202 Groundwater

HS17020115-02 02-Feb-2017 09:25 02-Feb-2017 14:12MW-01 Dup 170202 Groundwater








HS17020115-10 02-Feb-2017 10:00VBLKW-012717-04

02-Feb-2017 14:12TB-01 170202 Water

ALS Group USA, Corp 29-Jun-17Date:

Page 9 of 99

Client:Project:Sample ID:

Pastor, Behling & Wheeler, LLCCES Griggs Rd VCPMW-01 170202

WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-01

02-Feb-2017 09:25 Matrix:Groundwater

ANALYTICAL REPORT

ANALYSES RESULT MQLDILUTION FACTORUNITS

DATE ANALYZEDQUAL SDL

LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: JLJ1mg/L 06-Feb-2017 15:320.000301,1,1,2-Tetrachloroethane 0.0010U

1mg/L 06-Feb-2017 15:320.000201,1,1-Trichloroethane 0.0010U

1mg/L 06-Feb-2017 15:320.000501,1,2,2-Tetrachloroethane 0.0010U

1mg/L 06-Feb-2017 15:320.00101,1,2-Trichlor-1,2,2-trifluoroethane 0.0010U


1mg/L 06-Feb-2017 15:320.000201,1-Dichloroethane 0.00100.012

1mg/L 06-Feb-2017 15:320.000201,1-Dichloroethene 0.00100.0014

1mg/L 06-Feb-2017 15:320.000401,2,3-Trichlorobenzene 0.0010U


1mg/L 06-Feb-2017 15:320.000301,2,4-Trimethylbenzene 0.0010U

1mg/L 06-Feb-2017 15:320.000201,2-Dibromoethane 0.0010U

1mg/L 06-Feb-2017 15:320.000501,2-Dichlorobenzene 0.0010U

1mg/L 06-Feb-2017 15:32J 0.000201,2-Dichloroethane 0.00100.00047

1mg/L 06-Feb-2017 15:320.000501,2-Dichloropropane 0.0010U




1mg/L 06-Feb-2017 15:320.000502-Butanone 0.0020U

1mg/L 06-Feb-2017 15:320.00102-Hexanone 0.0020U

1mg/L 06-Feb-2017 15:320.000304-Isopropyltoluene 0.0010U

1mg/L 06-Feb-2017 15:320.000704-Methyl-2-pentanone 0.0020U

1mg/L 06-Feb-2017 15:320.0020Acetone 0.0020U

1mg/L 06-Feb-2017 15:32J 0.00020Benzene 0.00100.00030

1mg/L 06-Feb-2017 15:320.00020Bromodichloromethane 0.0010U

1mg/L 06-Feb-2017 15:320.00040Bromoform 0.0010U

1mg/L 06-Feb-2017 15:320.00040Bromomethane 0.0010U

1mg/L 06-Feb-2017 15:320.00060Carbon disulfide 0.0020U

1mg/L 06-Feb-2017 15:320.00050Carbon tetrachloride 0.0010U

1mg/L 06-Feb-2017 15:320.00030Chlorobenzene 0.00100.0010

1mg/L 06-Feb-2017 15:320.00030Chloroethane 0.0010U

1mg/L 06-Feb-2017 15:320.00020Chloroform 0.0010U

1mg/L 06-Feb-2017 15:320.00020Chloromethane 0.0010U

1mg/L 06-Feb-2017 15:320.00020cis-1,2-Dichloroethene 0.00100.13

1mg/L 06-Feb-2017 15:320.00010cis-1,3-Dichloropropene 0.0010U

1mg/L 06-Feb-2017 15:32n 0.00030Cyclohexane 0.0010U

1mg/L 06-Feb-2017 15:320.00030Dibromochloromethane 0.0010U

1mg/L 06-Feb-2017 15:320.00030Dichlorodifluoromethane 0.0010U

1mg/L 06-Feb-2017 15:320.00030Ethylbenzene 0.0010U

1mg/L 06-Feb-2017 15:320.00030Isopropylbenzene 0.0010U


Note: See Qualifiers Page for a list of qualifiers and their explanation.

Page 10 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-01


ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: JLJ1mg/L 06-Feb-2017 15:320.00020Methyl tert-butyl ether 0.0010U

1mg/L 06-Feb-2017 15:320.00030Methylcyclohexane 0.0010U

1mg/L 06-Feb-2017 15:320.0010Methylene chloride 0.0020U

1mg/L 06-Feb-2017 15:320.00040n-Butylbenzene 0.0010U

1mg/L 06-Feb-2017 15:320.00030n-Propylbenzene 0.0010U

1mg/L 06-Feb-2017 15:320.00030Naphthalene 0.0010U

1mg/L 06-Feb-2017 15:320.00030sec-Butylbenzene 0.0010U

1mg/L 06-Feb-2017 15:320.00030Styrene 0.0010U

1mg/L 06-Feb-2017 15:320.00030tert-Butylbenzene 0.0010U

1mg/L 06-Feb-2017 15:320.00030Tetrachloroethene 0.00100.0033

1mg/L 06-Feb-2017 15:320.00020Toluene 0.0010U

1mg/L 06-Feb-2017 15:320.00020trans-1,2-Dichloroethene 0.00100.0017

1mg/L 06-Feb-2017 15:320.00020trans-1,3-Dichloropropene 0.0010U

1mg/L 06-Feb-2017 15:320.00020Trichloroethene 0.00100.020

1mg/L 06-Feb-2017 15:320.00030Trichlorofluoromethane 0.0010U

1mg/L 06-Feb-2017 15:320.00020Vinyl chloride 0.00100.0078

1mg/L 06-Feb-2017 15:320.00030Xylenes, Total 0.0010U

Surr: 1,2-Dichloroethane-d4 1%REC 06-Feb-2017 15:3292.7 71-125


Surr: 4-Bromofluorobenzene 1%REC 06-Feb-2017 15:3282.9 70-125


Surr: Dibromofluoromethane 1%REC 06-Feb-2017 15:3290.7 74-125


Surr: Toluene-d8 1%REC 06-Feb-2017 15:3294.5 75-125




Page 11 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-01


ANALYTICAL REPORT



LOW-LEVEL SEMIVOLATILES Method:SW8270 Analyst: ACNPrep:SW3510 / 03-Feb-2017

1mg/L 06-Feb-2017 18:340.0000281,1´-Biphenyl 0.00023U

1mg/L 06-Feb-2017 18:340.0000451,2,4,5-Tetrachlorobenzene 0.00023U

1mg/L 06-Feb-2017 18:34n 0.0000121-Methylnaphthalene 0.00012U

1mg/L 06-Feb-2017 18:340.0000642,3,4,6-Tetrachlorophenol 0.00023U

1mg/L 06-Feb-2017 18:340.0000662,4,5-Trichlorophenol 0.00023U


1mg/L 06-Feb-2017 18:340.0000502,4-Dichlorophenol 0.00023U

1mg/L 06-Feb-2017 18:340.0000472,4-Dimethylphenol 0.00023U

1mg/L 06-Feb-2017 18:340.000122,4-Dinitrophenol 0.0012U

1mg/L 06-Feb-2017 18:340.0000672,4-Dinitrotoluene 0.00023U


1mg/L 06-Feb-2017 18:340.0000242-Chloronaphthalene 0.00023U

1mg/L 06-Feb-2017 18:340.0000422-Chlorophenol 0.00023U

1mg/L 06-Feb-2017 18:340.0000222-Methylnaphthalene 0.00012U

1mg/L 06-Feb-2017 18:340.0000522-Methylphenol 0.00023U

1mg/L 06-Feb-2017 18:340.0000482-Nitroaniline 0.00023U

1mg/L 06-Feb-2017 18:340.0000402-Nitrophenol 0.00023U

1mg/L 06-Feb-2017 18:340.0000423&4-Methylphenol 0.00023U

1mg/L 06-Feb-2017 18:340.0000513,3´-Dichlorobenzidine 0.00023U


1mg/L 06-Feb-2017 18:340.0000234,6-Dinitro-2-methylphenol 0.00023U

1mg/L 06-Feb-2017 18:340.0000594-Bromophenyl phenyl ether 0.00023U

1mg/L 06-Feb-2017 18:340.0000374-Chloro-3-methylphenol 0.00023U

1mg/L 06-Feb-2017 18:340.0000514-Chlorophenyl phenyl ether 0.00023U



1mg/L 06-Feb-2017 18:340.000031Acenaphthene 0.00012U

1mg/L 06-Feb-2017 18:340.000017Acenaphthylene 0.00012U

1mg/L 06-Feb-2017 18:340.000028Acetophenone 0.00023U

1mg/L 06-Feb-2017 18:340.000023Aniline 0.00023U

1mg/L 06-Feb-2017 18:340.000016Anthracene 0.00012U

1mg/L 06-Feb-2017 18:340.000058Benz(a)anthracene 0.00012U

1mg/L 06-Feb-2017 18:34n 0.000035Benzaldehyde 0.00023U

1mg/L 06-Feb-2017 18:340.000023Benzo(a)pyrene 0.00012U

1mg/L 06-Feb-2017 18:340.000027Benzo(b)fluoranthene 0.00012U

1mg/L 06-Feb-2017 18:340.000016Benzo(g,h,i)perylene 0.00012U

1mg/L 06-Feb-2017 18:340.000022Benzo(k)fluoranthene 0.00012U

1mg/L 06-Feb-2017 18:340.000035Bis(2-chloroethoxy)methane 0.00023U

1mg/L 06-Feb-2017 18:340.000030Bis(2-chloroethyl)ether 0.00023U



Page 12 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-01


ANALYTICAL REPORT




1mg/L 06-Feb-2017 18:340.000081Bis(2-chloroisopropyl)ether 0.000230.0013

1mg/L 06-Feb-2017 18:340.000043Bis(2-ethylhexyl)phthalate 0.000230.00028

1mg/L 06-Feb-2017 18:340.000022Butyl benzyl phthalate 0.00023U

1mg/L 06-Feb-2017 18:340.000052Caprolactam 0.00023U

1mg/L 06-Feb-2017 18:340.000029Carbazole 0.00023U

1mg/L 06-Feb-2017 18:340.000024Chrysene 0.00012U

1mg/L 06-Feb-2017 18:34J 0.000023Di-n-butyl phthalate 0.000230.00011

1mg/L 06-Feb-2017 18:340.000023Di-n-octyl phthalate 0.00023U

1mg/L 06-Feb-2017 18:340.000028Dibenz(a,h)anthracene 0.00012U

1mg/L 06-Feb-2017 18:340.000023Dibenzofuran 0.00012U

1mg/L 06-Feb-2017 18:340.000035Diethyl phthalate 0.00023U

1mg/L 06-Feb-2017 18:340.000048Dimethyl phthalate 0.00023U

1mg/L 06-Feb-2017 18:340.000012Fluoranthene 0.00012U

1mg/L 06-Feb-2017 18:340.000035Fluorene 0.00012U

1mg/L 06-Feb-2017 18:340.000051Hexachlorobenzene 0.00023U

1mg/L 06-Feb-2017 18:340.000035Hexachlorobutadiene 0.00023U

1mg/L 06-Feb-2017 18:340.000035Hexachlorocyclopentadiene 0.00023U

1mg/L 06-Feb-2017 18:340.000069Hexachloroethane 0.00023U

1mg/L 06-Feb-2017 18:340.000026Indeno(1,2,3-cd)pyrene 0.00012U

1mg/L 06-Feb-2017 18:340.000029Isophorone 0.00023U

1mg/L 06-Feb-2017 18:340.000037N-Nitrosodi-n-propylamine 0.00023U

1mg/L 06-Feb-2017 18:340.000029N-Nitrosodiphenylamine 0.00023U


1mg/L 06-Feb-2017 18:340.000028Nitrobenzene 0.00023U

1mg/L 06-Feb-2017 18:340.000092Pentachlorophenol 0.00023U

1mg/L 06-Feb-2017 18:340.000024Phenanthrene 0.00012U

1mg/L 06-Feb-2017 18:340.000041Phenol 0.00023U

1mg/L 06-Feb-2017 18:340.000022Pyrene 0.00012U

1mg/L 06-Feb-2017 18:340.000035Pyridine 0.0012U

Surr: 2,4,6-Tribromophenol 1%REC 06-Feb-2017 18:34107 34-129

Surr: 2-Fluorobiphenyl 1%REC 06-Feb-2017 18:3477.9 40-125

Surr: 2-Fluorophenol 1%REC 06-Feb-2017 18:3467.1 20-120

Surr: 4-Terphenyl-d14 1%REC 06-Feb-2017 18:34116 40-135

Surr: Nitrobenzene-d5 1%REC 06-Feb-2017 18:3483.5 41-120

Surr: Phenol-d6 1%REC 06-Feb-2017 18:3478.6 20-120



Page 13 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-01


ANALYTICAL REPORT



LOW-LEVEL TEXAS TPH BY TX1005 Method:TX1005 Analyst: HPPPrep:TX1005PR / 07-Feb-2017

1mg/L 08-Feb-2017 03:550.20nC6 to nC12 0.50U

1mg/L 08-Feb-2017 03:550.20>nC12 to nC28 0.50U

1mg/L 08-Feb-2017 03:550.20>nC28 to nC35 0.50U

1mg/L 08-Feb-2017 03:550.20Total Petroleum Hydrocarbon 0.50U


Surr: Trifluoromethyl benzene 1%REC 08-Feb-2017 03:5590.2 70-130

ICP-MS METALS BY SW6020A Method:SW6020 Analyst: RPMPrep:SW3010A / 06-Feb-2017

1mg/L 07-Feb-2017 12:520.00190Barium 0.005000.101

1mg/L 07-Feb-2017 12:520.000700Manganese 0.005000.0723

1mg/L 07-Feb-2017 12:52J 0.000600Vanadium 0.005000.000737



Page 14 of 99


Pastor, Behling & Wheeler, LLCCES Griggs Rd VCPMW-01 Dup 170202

WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-02


ANALYTICAL REPORT















1mg/L 06-Feb-2017 15:57J 0.000201,2-Dichloroethane 0.00100.00048









1mg/L 06-Feb-2017 15:570.0020Acetone 0.0020U

1mg/L 06-Feb-2017 15:57J 0.00020Benzene 0.00100.00028






1mg/L 06-Feb-2017 15:57J 0.00030Chlorobenzene 0.00100.00094













Page 15 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-02


ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: JLJ1mg/L 06-Feb-2017 15:57J 0.00020Methyl tert-butyl ether 0.00100.00041







1mg/L 06-Feb-2017 15:570.00030Styrene 0.0010U



1mg/L 06-Feb-2017 15:570.00020Toluene 0.0010U

















Page 16 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-02


ANALYTICAL REPORT

































1mg/L 06-Feb-2017 18:530.000023Aniline 0.00023U












Page 17 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-02


ANALYTICAL REPORT




1mg/L 06-Feb-2017 18:530.000081Bis(2-chloroisopropyl)ether 0.000230.00087

1mg/L 06-Feb-2017 18:53J 0.000043Bis(2-ethylhexyl)phthalate 0.000230.00010





1mg/L 06-Feb-2017 18:530.000023Di-n-butyl phthalate 0.00023U




















1mg/L 06-Feb-2017 18:530.000041Phenol 0.00023U

1mg/L 06-Feb-2017 18:530.000022Pyrene 0.00012U


Surr: 2,4,6-Tribromophenol 1%REC 06-Feb-2017 18:5374.7 34-129



Surr: 4-Terphenyl-d14 1%REC 06-Feb-2017 18:5372.6 40-135





Page 18 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-02


ANALYTICAL REPORT




1mg/L 08-Feb-2017 04:270.20nC6 to nC12 0.50U

1mg/L 08-Feb-2017 04:270.20>nC12 to nC28 0.50U

1mg/L 08-Feb-2017 04:270.20>nC28 to nC35 0.50U





1mg/L 07-Feb-2017 12:550.00190Barium 0.005000.102





Page 19 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-03


ANALYTICAL REPORT








1mg/L 06-Feb-2017 16:240.000201,1-Dichloroethane 0.0010U

1mg/L 06-Feb-2017 16:240.000201,1-Dichloroethene 0.0010U















1mg/L 06-Feb-2017 16:240.0020Acetone 0.0020U

1mg/L 06-Feb-2017 16:240.00020Benzene 0.0010U






1mg/L 06-Feb-2017 16:240.00030Chlorobenzene 0.0010U




1mg/L 06-Feb-2017 16:240.00020cis-1,2-Dichloroethene 0.0010U









Page 20 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-03


ANALYTICAL REPORT










1mg/L 06-Feb-2017 16:240.00030Styrene 0.0010U


1mg/L 06-Feb-2017 16:240.00030Tetrachloroethene 0.0010U

1mg/L 06-Feb-2017 16:240.00020Toluene 0.0010U

1mg/L 06-Feb-2017 16:240.00020trans-1,2-Dichloroethene 0.0010U


1mg/L 06-Feb-2017 16:240.00020Trichloroethene 0.0010U


1mg/L 06-Feb-2017 16:240.00020Vinyl chloride 0.0010U












Page 21 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-03


ANALYTICAL REPORT

































1mg/L 06-Feb-2017 19:120.000023Aniline 0.00023U












Page 22 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-03


ANALYTICAL REPORT




1mg/L 06-Feb-2017 19:120.000080Bis(2-chloroisopropyl)ether 0.00023U


























1mg/L 06-Feb-2017 19:120.000040Phenol 0.00023U

1mg/L 06-Feb-2017 19:120.000022Pyrene 0.00011U










Page 23 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-03


ANALYTICAL REPORT




1mg/L 08-Feb-2017 04:580.19nC6 to nC12 0.48U

1mg/L 08-Feb-2017 04:580.19>nC12 to nC28 0.48U

1mg/L 08-Feb-2017 04:580.19>nC28 to nC35 0.48U


Surr: 2-Fluorobiphenyl 1%REC 08-Feb-2017 04:58102 70-130



1mg/L 07-Feb-2017 12:580.00190Barium 0.005000.116


1mg/L 07-Feb-2017 12:580.000600Vanadium 0.00500U



Page 24 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-04


ANALYTICAL REPORT
























1mg/L 06-Feb-2017 16:490.0020Acetone 0.0020U

1mg/L 06-Feb-2017 16:490.00020Benzene 0.0010U



















Page 25 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-04


ANALYTICAL REPORT










1mg/L 06-Feb-2017 16:490.00030Styrene 0.0010U



1mg/L 06-Feb-2017 16:490.00020Toluene 0.0010U

















Page 26 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-04


ANALYTICAL REPORT

































1mg/L 06-Feb-2017 19:310.000024Aniline 0.00024U




1mg/L 06-Feb-2017 19:31J 0.000024Benzo(a)pyrene 0.000120.000065

1mg/L 06-Feb-2017 19:31J 0.000027Benzo(b)fluoranthene 0.000120.000048

1mg/L 06-Feb-2017 19:310.000017Benzo(g,h,i)perylene 0.000120.00023

1mg/L 06-Feb-2017 19:31J 0.000023Benzo(k)fluoranthene 0.000120.000058





Page 27 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-04


ANALYTICAL REPORT







1mg/L 06-Feb-2017 19:310.000054Caprolactam 0.000240.00050


1mg/L 06-Feb-2017 19:31J 0.000025Chrysene 0.000120.000053

1mg/L 06-Feb-2017 19:31J 0.000024Di-n-butyl phthalate 0.000240.000079

1mg/L 06-Feb-2017 19:31J 0.000024Di-n-octyl phthalate 0.000240.00015

1mg/L 06-Feb-2017 19:310.000029Dibenz(a,h)anthracene 0.000120.00027










1mg/L 06-Feb-2017 19:310.000026Indeno(1,2,3-cd)pyrene 0.000120.00025








1mg/L 06-Feb-2017 19:310.000042Phenol 0.00024U

1mg/L 06-Feb-2017 19:310.000023Pyrene 0.00012U










Page 28 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-04


ANALYTICAL REPORT




1mg/L 08-Feb-2017 05:300.20nC6 to nC12 0.50U

1mg/L 08-Feb-2017 05:300.20>nC12 to nC28 0.50U

1mg/L 08-Feb-2017 05:300.20>nC28 to nC35 0.50U





1mg/L 07-Feb-2017 13:010.00190Barium 0.005000.0891



DISSOLVED METALS BY SW6020A Method:SW6020 (dissolved) Analyst: RPMPrep:SW3010A / 06-Feb-2017

1mg/L 07-Feb-2017 14:000.00190Barium 0.005000.0847





Page 29 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-05


ANALYTICAL REPORT
























1mg/L 06-Feb-2017 17:140.0020Acetone 0.0020U

1mg/L 06-Feb-2017 17:140.00020Benzene 0.0010U



















Page 30 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-05


ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: JLJ1mg/L 06-Feb-2017 17:140.00020Methyl tert-butyl ether 0.00100.0020







1mg/L 06-Feb-2017 17:140.00030Styrene 0.0010U



1mg/L 06-Feb-2017 17:140.00020Toluene 0.0010U



1mg/L 06-Feb-2017 17:14J 0.00020Trichloroethene 0.00100.00038














Page 31 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-05


ANALYTICAL REPORT

































1mg/L 06-Feb-2017 19:510.000024Aniline 0.00024U












Page 32 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-05


ANALYTICAL REPORT






























1mg/L 06-Feb-2017 19:510.000041Phenol 0.00024U

1mg/L 06-Feb-2017 19:510.000022Pyrene 0.00012U










Page 33 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-05


ANALYTICAL REPORT




1mg/L 08-Feb-2017 06:010.21nC6 to nC12 0.52U

1mg/L 08-Feb-2017 06:010.21>nC12 to nC28 0.52U

1mg/L 08-Feb-2017 06:010.21>nC28 to nC35 0.52U





1mg/L 07-Feb-2017 13:100.00190Barium 0.005000.0960





Page 34 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-06


ANALYTICAL REPORT
























1mg/L 06-Feb-2017 13:240.0020Acetone 0.0020U

1mg/L 06-Feb-2017 13:24J 0.00020Benzene 0.00100.00023



















Page 35 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-06


ANALYTICAL REPORT










1mg/L 06-Feb-2017 13:240.00030Styrene 0.0010U



1mg/L 06-Feb-2017 13:240.00020Toluene 0.0010U

















Page 36 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-06


ANALYTICAL REPORT

































1mg/L 06-Feb-2017 17:360.000023Aniline 0.00023U












Page 37 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-06


ANALYTICAL REPORT






























1mg/L 06-Feb-2017 17:360.000040Phenol 0.00023U

1mg/L 06-Feb-2017 17:360.000022Pyrene 0.00011U










Page 38 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-06


ANALYTICAL REPORT




1mg/L 07-Feb-2017 22:390.20nC6 to nC12 0.49U

1mg/L 07-Feb-2017 22:390.20>nC12 to nC28 0.49U

1mg/L 07-Feb-2017 22:390.20>nC28 to nC35 0.49U



Surr: Trifluoromethyl benzene 1%REC 07-Feb-2017 22:39100 70-130


1mg/L 07-Feb-2017 12:220.00190Barium 0.005000.442


1mg/L 07-Feb-2017 12:220.000600Vanadium 0.00500U



Page 39 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-07


ANALYTICAL REPORT
























1mg/L 06-Feb-2017 17:400.0020Acetone 0.0020U

1mg/L 06-Feb-2017 17:40J 0.00020Benzene 0.00100.00030






1mg/L 06-Feb-2017 17:400.00030Chlorobenzene 0.00100.0053













Page 40 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-07


ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: JLJ1mg/L 06-Feb-2017 17:40J 0.00020Methyl tert-butyl ether 0.00100.00087







1mg/L 06-Feb-2017 17:400.00030Styrene 0.0010U



1mg/L 06-Feb-2017 17:40J 0.00020Toluene 0.00100.00085

1mg/L 06-Feb-2017 17:40J 0.00020trans-1,2-Dichloroethene 0.00100.00090
















Page 41 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-07


ANALYTICAL REPORT

































1mg/L 06-Feb-2017 20:100.000024Aniline 0.00024U












Page 42 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-07


ANALYTICAL REPORT





1mg/L 06-Feb-2017 20:100.000045Bis(2-ethylhexyl)phthalate 0.00024U

























1mg/L 06-Feb-2017 20:100.000042Phenol 0.00024U

1mg/L 06-Feb-2017 20:100.000023Pyrene 0.00012U










Page 43 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-07


ANALYTICAL REPORT




1mg/L 08-Feb-2017 06:330.20nC6 to nC12 0.49U

1mg/L 08-Feb-2017 06:330.20>nC12 to nC28 0.49U

1mg/L 08-Feb-2017 06:330.20>nC28 to nC35 0.49U





1mg/L 07-Feb-2017 13:130.00190Barium 0.005000.114



DISSOLVED METALS BY SW6020A Method:SW6020 (dissolved) Analyst: RPMPrep:SW3010A / 06-Feb-2017

1mg/L 07-Feb-2017 14:030.00190Barium 0.005000.111





Page 44 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-08


ANALYTICAL REPORT
























1mg/L 06-Feb-2017 18:050.0020Acetone 0.0020U

1mg/L 06-Feb-2017 18:050.00020Benzene 0.0010U



















Page 45 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-08


ANALYTICAL REPORT










1mg/L 06-Feb-2017 18:050.00030Styrene 0.0010U



1mg/L 06-Feb-2017 18:05J 0.00020Toluene 0.00100.00045

















Page 46 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-08


ANALYTICAL REPORT
































1mg/L 06-Feb-2017 20:29J 0.000028Acetophenone 0.000230.000063

1mg/L 06-Feb-2017 20:290.000023Aniline 0.00023U












Page 47 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-08


ANALYTICAL REPORT





1mg/L 06-Feb-2017 20:290.000043Bis(2-ethylhexyl)phthalate 0.00023U




















1mg/L 06-Feb-2017 20:29J 0.000029N-Nitrosodiphenylamine 0.000230.000072





1mg/L 06-Feb-2017 20:290.000041Phenol 0.00023U

1mg/L 06-Feb-2017 20:290.000022Pyrene 0.00012U










Page 48 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-08


ANALYTICAL REPORT




1mg/L 08-Feb-2017 07:050.20nC6 to nC12 0.50U

1mg/L 08-Feb-2017 07:050.20>nC12 to nC28 0.50U

1mg/L 08-Feb-2017 07:050.20>nC28 to nC35 0.50U





1mg/L 07-Feb-2017 13:160.00190Barium 0.005000.250





Page 49 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-09


ANALYTICAL REPORT
























1mg/L 06-Feb-2017 18:310.0020Acetone 0.0020U

1mg/L 06-Feb-2017 18:310.00020Benzene 0.0010U








1mg/L 06-Feb-2017 18:31J 0.00020Chloroform 0.00100.00049











Page 50 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-09


ANALYTICAL REPORT










1mg/L 06-Feb-2017 18:310.00030Styrene 0.0010U



1mg/L 06-Feb-2017 18:310.00020Toluene 0.0010U

















Page 51 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-09


ANALYTICAL REPORT

































1mg/L 06-Feb-2017 20:480.000024Aniline 0.00024U












Page 52 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-09


ANALYTICAL REPORT






























1mg/L 06-Feb-2017 20:480.000041Phenol 0.00024U

1mg/L 06-Feb-2017 20:480.000022Pyrene 0.00012U

1mg/L 06-Feb-2017 20:48J 0.000035Pyridine 0.00120.000093









Page 53 of 99



WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-09


ANALYTICAL REPORT




1mg/L 08-Feb-2017 07:360.20nC6 to nC12 0.50U

1mg/L 08-Feb-2017 07:360.20>nC12 to nC28 0.50U

1mg/L 08-Feb-2017 07:360.20>nC28 to nC35 0.50U





1mg/L 07-Feb-2017 13:190.00190Barium 0.005000.135





Page 54 of 99


Pastor, Behling & Wheeler, LLCCES Griggs Rd VCPTB-01 170202

WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-10

02-Feb-2017 10:00 Matrix:Water

ANALYTICAL REPORT
























1mg/L 06-Feb-2017 12:580.0020Acetone 0.0020U

1mg/L 06-Feb-2017 12:580.00020Benzene 0.0010U



















1Revision:

Page 55 of 99


Pastor, Behling & Wheeler, LLCCES Griggs Rd VCPTB-01 170202

WorkOrder:Lab ID:

Collection Date:

HS17020115HS17020115-10

02-Feb-2017 10:00 Matrix:Water

ANALYTICAL REPORT










1mg/L 06-Feb-2017 12:580.00030Styrene 0.0010U



1mg/L 06-Feb-2017 12:580.00020Toluene 0.0010U

















1Revision:

Page 56 of 99

WEIGHT LOG



Batch ID: 112040 Method: LOW-LEVEL SEMIVOLATILES 3510_B_LOWPrep:

ContainerSampIDSample Wt/Vol

Final Volume

Prep Factor

HS17020115-06 1 880 1 (mL) 0.001136

Batch ID: 112094 Method: ICP-MS METALS BY SW6020A 3010APrep:


Final Volume

Prep Factor

HS17020115-01 1 50 50 (mL) 1HS17020115-02 1 50 50 (mL) 1HS17020115-03 1 50 50 (mL) 1HS17020115-04 1 50 50 (mL) 1HS17020115-05 1 50 50 (mL) 1HS17020115-06 1 50 50 (mL) 1HS17020115-07 1 50 50 (mL) 1HS17020115-08 1 50 50 (mL) 1HS17020115-09 1 50 50 (mL) 1

Batch ID: 112095 Method: DISSOLVED METALS BY SW6020A 3010A DISSPrep:


Final Volume

Prep Factor

HS17020115-04 1 50 50 (mL) 1HS17020115-07 1 50 50 (mL) 1

Batch ID: 112117 Method: LOW-LEVEL TEXAS TPH BY TX1005 TX 1005_W PRPrep:


Final Volume

Prep Factor

HS17020115-01 1 29.83 3 (mL) 0.1006HS17020115-02 1 30.02 3 (mL) 0.09993HS17020115-03 1 30.93 3 (mL) 0.09699HS17020115-04 1 30.16 3 (mL) 0.09947HS17020115-05 1 28.86 3 (mL) 0.104HS17020115-06 1 30.39 3 (mL) 0.09872HS17020115-07 1 30.33 3 (mL) 0.09891HS17020115-08 1 30.05 3 (mL) 0.09983HS17020115-09 1 30.15 3 (mL) 0.0995


Page 57 of 99

Client:CES Griggs Rd VCPPastor, Behling & Wheeler, LLC

WorkOrder:Project:

HS17020115DATES REPORT

Collection Date Prep Date Analysis DateClient Samp IDSample ID TCLP Date DF

Batch ID 112040a Test Name : LOW-LEVEL SEMIVOLATILES Matrix: Groundwater

03 Feb 2017 11:16 06 Feb 2017 18:34HS17020115-01 02 Feb 2017 09:25 1MW-01 170202

03 Feb 2017 11:16 06 Feb 2017 18:53HS17020115-02 02 Feb 2017 09:25 1MW-01 Dup 170202

03 Feb 2017 11:16 06 Feb 2017 19:12HS17020115-03 01 Feb 2017 16:35 1MW-02 170201

03 Feb 2017 11:16 06 Feb 2017 19:31HS17020115-04 01 Feb 2017 09:17 1MW-03 170201

03 Feb 2017 11:16 06 Feb 2017 19:51HS17020115-05 01 Feb 2017 12:40 1MW-04 170201

03 Feb 2017 11:16 06 Feb 2017 17:36HS17020115-06 01 Feb 2017 14:50 1MW-05 170201

03 Feb 2017 11:16 06 Feb 2017 20:10HS17020115-07 01 Feb 2017 13:40 1MW-06 170201

03 Feb 2017 11:16 06 Feb 2017 20:29HS17020115-08 02 Feb 2017 08:10 1MW-07 170202

03 Feb 2017 11:16 06 Feb 2017 20:48HS17020115-09 01 Feb 2017 10:35 1MW-08 170201

Batch ID 112094 Test Name : ICP-MS METALS BY SW6020A Matrix: Groundwater

06 Feb 2017 10:25 07 Feb 2017 12:52HS17020115-01 02 Feb 2017 09:25 1MW-01 170202


06 Feb 2017 10:25 07 Feb 2017 12:58HS17020115-03 01 Feb 2017 16:35 1MW-02 170201

06 Feb 2017 10:25 07 Feb 2017 13:01HS17020115-04 01 Feb 2017 09:17 1MW-03 170201

06 Feb 2017 10:25 07 Feb 2017 13:10HS17020115-05 01 Feb 2017 12:40 1MW-04 170201

06 Feb 2017 10:25 07 Feb 2017 12:22HS17020115-06 01 Feb 2017 14:50 1MW-05 170201

06 Feb 2017 10:25 07 Feb 2017 13:13HS17020115-07 01 Feb 2017 13:40 1MW-06 170201

06 Feb 2017 10:25 07 Feb 2017 13:16HS17020115-08 02 Feb 2017 08:10 1MW-07 170202

06 Feb 2017 10:25 07 Feb 2017 13:19HS17020115-09 01 Feb 2017 10:35 1MW-08 170201

Batch ID 112095 Test Name : DISSOLVED METALS BY SW6020A Matrix: Groundwater

06 Feb 2017 10:50 07 Feb 2017 14:00HS17020115-04 01 Feb 2017 09:17 1MW-03 170201

06 Feb 2017 10:50 07 Feb 2017 14:03HS17020115-07 01 Feb 2017 13:40 1MW-06 170201

Batch ID 112117 Test Name : LOW-LEVEL TEXAS TPH BY TX1005 Matrix: Groundwater

07 Feb 2017 11:06 08 Feb 2017 03:55HS17020115-01 02 Feb 2017 09:25 1MW-01 170202


07 Feb 2017 11:06 08 Feb 2017 04:58HS17020115-03 01 Feb 2017 16:35 1MW-02 170201

07 Feb 2017 11:06 08 Feb 2017 05:30HS17020115-04 01 Feb 2017 09:17 1MW-03 170201

07 Feb 2017 11:06 08 Feb 2017 06:01HS17020115-05 01 Feb 2017 12:40 1MW-04 170201

07 Feb 2017 11:06 07 Feb 2017 22:39HS17020115-06 01 Feb 2017 14:50 1MW-05 170201

07 Feb 2017 11:06 08 Feb 2017 06:33HS17020115-07 01 Feb 2017 13:40 1MW-06 170201

07 Feb 2017 11:06 08 Feb 2017 07:05HS17020115-08 02 Feb 2017 08:10 1MW-07 170202

07 Feb 2017 11:06 08 Feb 2017 07:36HS17020115-09 01 Feb 2017 10:35 1MW-08 170201

Batch ID R289061 Test Name : LOW LEVEL VOLATILES BY SW8260C Matrix: Water

06 Feb 2017 12:58HS17020115-10 02 Feb 2017 10:00 1TB-01 170202


Page 58 of 99


WorkOrder:Project:



Batch ID R289061 Test Name : LOW LEVEL VOLATILES BY SW8260C Matrix: Groundwater

06 Feb 2017 15:32HS17020115-01 02 Feb 2017 09:25 1MW-01 170202

06 Feb 2017 15:57HS17020115-02 02 Feb 2017 09:25 1MW-01 Dup 170202

06 Feb 2017 16:24HS17020115-03 01 Feb 2017 16:35 1MW-02 170201

06 Feb 2017 16:49HS17020115-04 01 Feb 2017 09:17 1MW-03 170201

06 Feb 2017 17:14HS17020115-05 01 Feb 2017 12:40 1MW-04 170201

06 Feb 2017 13:24HS17020115-06 01 Feb 2017 14:50 1MW-05 170201

06 Feb 2017 17:40HS17020115-07 01 Feb 2017 13:40 1MW-06 170201

06 Feb 2017 18:05HS17020115-08 02 Feb 2017 08:10 1MW-07 170202

06 Feb 2017 18:31HS17020115-09 01 Feb 2017 10:35 1MW-08 170201


06 Feb 2017 12:58HS17020115-10 02 Feb 2017 10:00 1TB-01 170202


06 Feb 2017 15:32HS17020115-01 02 Feb 2017 09:25 1MW-01 170202

06 Feb 2017 15:57HS17020115-02 02 Feb 2017 09:25 1MW-01 Dup 170202

06 Feb 2017 16:24HS17020115-03 01 Feb 2017 16:35 1MW-02 170201

06 Feb 2017 16:49HS17020115-04 01 Feb 2017 09:17 1MW-03 170201

06 Feb 2017 17:14HS17020115-05 01 Feb 2017 12:40 1MW-04 170201

06 Feb 2017 13:24HS17020115-06 01 Feb 2017 14:50 1MW-05 170201

06 Feb 2017 17:40HS17020115-07 01 Feb 2017 13:40 1MW-06 170201

06 Feb 2017 18:05HS17020115-08 02 Feb 2017 08:10 1MW-07 170202

06 Feb 2017 18:31HS17020115-09 01 Feb 2017 10:35 1MW-08 170201


Page 59 of 99


WorkOrder: HS17020115

Test Code: TX1005_W_LowInstrumentID: FID-12

METHOD DETECTION / REPORTING LIMITS

AqueousMatrix:Test Number: TX1005Test Name: Low-level Texas TPH by TX1005

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.64TPH-1005-1 0.20nC6 to nC12 0.500.25

A 0.16TPH-1005-2 0.20>nC12 to nC28 0.500.25

A 0.16TPH-1005-4 0.20>nC28 to nC35 0.500.25

A 0.80TPH 0.20Total Petroleum Hydrocarbon 0.500.50

S 0321-60-8 02-Fluorobiphenyl 00

S 098-08-8 0Trifluoromethyl benzene 00

Page 60 of 99



Test Code: ICP_DISSInstrumentID: ICPMS05


AqueousMatrix:Test Number: SW6020 (dissolved)Test Name: Dissolved Metals by SW6020A

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.001197440-39-3 0.00190Barium 0.005000.00100

A 0.001117439-96-5 0.000700Manganese 0.005000.00100

A 0.0007437440-62-2 0.000600Vanadium 0.005000.00100

Page 61 of 99



Test Code: ICP_TWInstrumentID: ICPMS05


AqueousMatrix:Test Number: SW6020Test Name: ICP-MS Metals by SW6020A

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.001197440-39-3 0.00190Barium 0.005000.00100

A 0.001117439-96-5 0.000700Manganese 0.005000.00100

A 0.0007437440-62-2 0.000600Vanadium 0.005000.00100

Page 62 of 99



Test Code: 8270_LOW_WInstrumentID: SV-7


AqueousMatrix:Test Number: SW8270Test Name: Low-Level Semivolatiles

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.00009192-52-4 0.0000241,1´-Biphenyl 0.000200.00010

A 0.0001195-94-3 0.0000391,2,4,5-Tetrachlorobenzene 0.000200.00010

A 0.00002290-12-0 0.0000101-Methylnaphthalene 0.000100.000050

A 0.00009458-90-2 0.0000552,3,4,6-Tetrachlorophenol 0.000200.00010

A 0.00007095-95-4 0.0000572,4,5-Trichlorophenol 0.000200.00010

A 0.0001388-06-2 0.0000482,4,6-Trichlorophenol 0.000200.00010

A 0.00013120-83-2 0.0000432,4-Dichlorophenol 0.000200.00010

A 0.000079105-67-9 0.0000402,4-Dimethylphenol 0.000200.00010

A 0.0002551-28-5 0.000102,4-Dinitrophenol 0.00100.00010

A 0.000074121-14-2 0.0000582,4-Dinitrotoluene 0.000200.00010

A 0.00011606-20-2 0.0000422,6-Dinitrotoluene 0.000200.00010

A 0.00009391-58-7 0.0000212-Chloronaphthalene 0.000200.00010

A 0.00008795-57-8 0.0000362-Chlorophenol 0.000200.00010

A 0.00001691-57-6 0.0000192-Methylnaphthalene 0.000100.000050

A 0.0001295-48-7 0.0000452-Methylphenol 0.000200.00010

A 0.0001188-74-4 0.0000412-Nitroaniline 0.000200.00010

A 0.0001588-75-5 0.0000342-Nitrophenol 0.000200.00010

A 0.000123/4-CRESOL 0.0000363&4-Methylphenol 0.000200.00010

A 0.0001391-94-1 0.0000443,3´-Dichlorobenzidine 0.000200.00010

A 0.00008599-09-2 0.0000493-Nitroaniline 0.000200.00010

A 0.00019534-52-1 0.0000204,6-Dinitro-2-methylphenol 0.000200.00010

A 0.00014101-55-3 0.0000514-Bromophenyl phenyl ether 0.000200.00010

A 0.00009359-50-7 0.0000324-Chloro-3-methylphenol 0.000200.00010

A 0.000127005-72-3 0.0000444-Chlorophenyl phenyl ether 0.000200.00010

A 0.000085100-01-6 0.0000354-Nitroaniline 0.000200.00010

A 0.000056100-02-7 0.0000474-Nitrophenol 0.00100.00010

A 0.00002983-32-9 0.000027Acenaphthene 0.000100.000050

A 0.000021208-96-8 0.000015Acenaphthylene 0.000100.000050

A 0.0001098-86-2 0.000024Acetophenone 0.000200.00010

A 0.00008362-53-3 0.000020Aniline 0.000200.00010

A 0.000019120-12-7 0.000014Anthracene 0.000100.000050

A 0.00004956-55-3 0.000050Benz(a)anthracene 0.000100.000050

A 0.00012100-52-7 0.000030Benzaldehyde 0.000200.00010

A 0.00003150-32-8 0.000020Benzo(a)pyrene 0.000100.000050

A 0.000040205-99-2 0.000023Benzo(b)fluoranthene 0.000100.000050

A 0.000028191-24-2 0.000014Benzo(g,h,i)perylene 0.000100.000050

A 0.000040207-08-9 0.000019Benzo(k)fluoranthene 0.000100.000050

A 0.00011111-91-1 0.000030Bis(2-chloroethoxy)methane 0.000200.00010

A 0.00011111-44-4 0.000026Bis(2-chloroethyl)ether 0.000200.00010

A 0.00011108-60-1 0.000070Bis(2-chloroisopropyl)ether 0.000200.00010

A 0.00010117-81-7 0.000037Bis(2-ethylhexyl)phthalate 0.000200.00010

Page 63 of 99






Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.0001085-68-7 0.000019Butyl benzyl phthalate 0.000200.00010

A 0.000093105-60-2 0.000045Caprolactam 0.000200.00010

A 0.0001386-74-8 0.000025Carbazole 0.000200.00010

A 0.000042218-01-9 0.000021Chrysene 0.000100.000050

A 0.0001184-74-2 0.000020Di-n-butyl phthalate 0.000200.00010

A 0.00013117-84-0 0.000020Di-n-octyl phthalate 0.000200.00010

A 0.00002853-70-3 0.000024Dibenz(a,h)anthracene 0.000100.000050

A 0.000020132-64-9 0.000020Dibenzofuran 0.000100.000050

A 0.00008684-66-2 0.000030Diethyl phthalate 0.000200.00010

A 0.00013131-11-3 0.000041Dimethyl phthalate 0.000200.00010

A 0.000023206-44-0 0.000010Fluoranthene 0.000100.000050

A 0.00002386-73-7 0.000030Fluorene 0.000100.000050

A 0.00014118-74-1 0.000044Hexachlorobenzene 0.000200.00010

A 0.0001687-68-3 0.000030Hexachlorobutadiene 0.000200.00010

A 0.00008277-47-4 0.000030Hexachlorocyclopentadiene 0.000200.00010

A 0.0001367-72-1 0.000059Hexachloroethane 0.000200.00010

A 0.000044193-39-5 0.000022Indeno(1,2,3-cd)pyrene 0.000100.000050

A 0.0001278-59-1 0.000025Isophorone 0.000200.00010

A 0.00013621-64-7 0.000032N-Nitrosodi-n-propylamine 0.000200.00010

A 0.00008786-30-6 0.000025N-Nitrosodiphenylamine 0.000200.00010

A 0.00001891-20-3 0.000020Naphthalene 0.000100.000050

A 0.0001398-95-3 0.000024Nitrobenzene 0.000200.00010

A 0.0001587-86-5 0.000079Pentachlorophenol 0.000200.00010

A 0.00002585-01-8 0.000021Phenanthrene 0.000100.000050

A 0.000099108-95-2 0.000035Phenol 0.000200.00010

A 0.000037129-00-0 0.000019Pyrene 0.000100.000050

A 0.000092110-86-1 0.000030Pyridine 0.00100.00010

S 0118-79-6 02,4,6-Tribromophenol 0.000200

S 0321-60-8 02-Fluorobiphenyl 0.000200

S 0367-12-4 02-Fluorophenol 0.000200

S 01718-51-0 04-Terphenyl-d14 0.000200

S 04165-60-0 0Nitrobenzene-d5 0.000200

S 013127-88-3 0Phenol-d6 0.000200

Page 64 of 99



Test Code: 8260_LL_WInstrumentID: VOA4


AqueousMatrix:Test Number: SW8260Test Name: Low Level Volatiles by SW8260C

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.00067630-20-6 0.000301,1,1,2-Tetrachloroethane 0.00100.00050

A 0.0005771-55-6 0.000201,1,1-Trichloroethane 0.00100.00050

A 0.0008279-34-5 0.000501,1,2,2-Tetrachloroethane 0.00100.00050

A 0.001176-13-1 0.00101,1,2-Trichlor-1,2,2-trifluoroethane 0.00100.00050

A 0.0006479-00-5 0.000301,1,2-Trichloroethane 0.00100.00050

A 0.0006175-34-3 0.000201,1-Dichloroethane 0.00100.00050

A 0.0006975-35-4 0.000201,1-Dichloroethene 0.00100.00050

A 0.002187-61-6 0.000401,2,3-Trichlorobenzene 0.00100.00050

A 0.0022120-82-1 0.000501,2,4-Trichlorobenzene 0.00100.00050

A 0.0007095-63-6 0.000301,2,4-Trimethylbenzene 0.00100.00050

A 0.00057106-93-4 0.000201,2-Dibromoethane 0.00100.00050

A 0.0007495-50-1 0.000501,2-Dichlorobenzene 0.00100.00050

A 0.00071107-06-2 0.000201,2-Dichloroethane 0.00100.00050

A 0.0006778-87-5 0.000501,2-Dichloropropane 0.00100.00050

A 0.00073108-67-8 0.000301,3,5-Trimethylbenzene 0.00100.00050



A 0.001178-93-3 0.000502-Butanone 0.00200.0010

A 0.0018591-78-6 0.00102-Hexanone 0.00200.0010

A 0.0003399-87-6 0.000304-Isopropyltoluene 0.00100.00050

A 0.00094108-10-1 0.000704-Methyl-2-pentanone 0.00200.0010

A 0.002967-64-1 0.0020Acetone 0.00200.0010

A 0.0006071-43-2 0.00020Benzene 0.00100.00050

A 0.0006175-27-4 0.00020Bromodichloromethane 0.00100.00050

A 0.0005275-25-2 0.00040Bromoform 0.00100.00050

A 0.001174-83-9 0.00040Bromomethane 0.00100.00050

A 0.001475-15-0 0.00060Carbon disulfide 0.00200.0010

A 0.0007656-23-5 0.00050Carbon tetrachloride 0.00100.00050

A 0.00064108-90-7 0.00030Chlorobenzene 0.00100.00050

A 0.0008275-00-3 0.00030Chloroethane 0.00100.00050

A 0.0005767-66-3 0.00020Chloroform 0.00100.00050

A 0.0007774-87-3 0.00020Chloromethane 0.00100.00050

A 0.00057156-59-2 0.00020cis-1,2-Dichloroethene 0.00100.00050

A 0.001410061-01-5 0.00010cis-1,3-Dichloropropene 0.00100.00050

A 0.00081110-82-7 0.00030Cyclohexane 0.00100.00050

A 0.00049124-48-1 0.00030Dibromochloromethane 0.00100.00050

A 0.0006975-71-8 0.00030Dichlorodifluoromethane 0.00100.00050

A 0.00058100-41-4 0.00030Ethylbenzene 0.00100.00050

A 0.0004598-82-8 0.00030Isopropylbenzene 0.00100.00050

A 0.000571634-04-4 0.00020Methyl tert-butyl ether 0.00100.00050

A 0.0014108-87-2 0.00030Methylcyclohexane 0.00100.00050

Page 65 of 99






Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.0007175-09-2 0.0010Methylene chloride 0.00200.00050

A 0.00045104-51-8 0.00040n-Butylbenzene 0.00100.00050

A 0.00074103-65-1 0.00030n-Propylbenzene 0.00100.00050

A 0.002591-20-3 0.00030Naphthalene 0.00100.00050

A 0.00076135-98-8 0.00030sec-Butylbenzene 0.00100.00050

A 0.00068100-42-5 0.00030Styrene 0.00100.00050

A 0.0005298-06-6 0.00030tert-Butylbenzene 0.00100.00050

A 0.00066127-18-4 0.00030Tetrachloroethene 0.00100.00050

A 0.00067108-88-3 0.00020Toluene 0.00100.00050

A 0.00067156-60-5 0.00020trans-1,2-Dichloroethene 0.00100.00050

A 0.002410061-02-6 0.00020trans-1,3-Dichloropropene 0.00100.00050

A 0.0006479-01-6 0.00020Trichloroethene 0.00100.00050

A 0.001175-69-4 0.00030Trichlorofluoromethane 0.00100.00050

A 0.0006475-01-4 0.00020Vinyl chloride 0.00100.00050

A 0.00191330-20-7 0.00030Xylenes, Total 0.00100.0015

S 017060-07-0 01,2-Dichloroethane-d4 0.00100

S 0460-00-4 04-Bromofluorobenzene 0.00100

S 01868-53-7 0Dibromofluoromethane 0.00100

S 02037-26-5 0Toluene-d8 0.00100

Page 66 of 99

Client:Project:

Pastor, Behling & Wheeler, LLCCES Griggs Rd VCP


QC BATCH REPORT

Batch ID: 112117 Instrument: FID-12 Method: TX1005

Sample ID: MBLK-112117 Units: mg/L Analysis Date: 07-Feb-2017 21:02

Run ID: FID-12_289212 SeqNo: 3980858 PrepDate: 07-Feb-2017 DF: 1

Analyte SPK ValMQLResultSPK Ref

Value %RECControl

LimitRPD Ref

Value %RPDRPD Limit Qual

MBLK

Client ID:

nC6 to nC12 U 0.50

>nC12 to nC28 U 0.50

>nC28 to nC35 U 0.50

Total Petroleum Hydrocarbon U 0.50

2.284 2.5 0 91.4 70 - 1300Surr: 2-Fluorobiphenyl

2.169 2.5 0 86.8 70 - 1300Surr: Trifluoromethyl benzene

Sample ID: LCS-112117 Units: mg/L Analysis Date: 07-Feb-2017 21:35



Value %RECControl

LimitRPD Ref


LCS

Client ID:

nC6 to nC12 22.52 25 0 90.1 75 - 1250.50

>nC12 to nC28 23.05 25 0 92.2 75 - 1250.50

2.353 2.5 0 94.1 70 - 1300Surr: 2-Fluorobiphenyl


Sample ID: LCSD-112117 Units: mg/L Analysis Date: 07-Feb-2017 22:07



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

nC6 to nC12 23.76 25 0 95.0 75 - 125 22.52 5.36 200.50

>nC12 to nC28 22.9 25 0 91.6 75 - 125 23.05 0.621 200.50

2.473 2.5 0 98.9 70 - 130 2.353 4.95 200Surr: 2-Fluorobiphenyl

2.079 2.5 0 83.2 70 - 130 2.014 3.2 200Surr: Trifluoromethyl benzene

Sample ID: HS17020115-06MS Units: mg/L Analysis Date: 07-Feb-2017 23:11



Value %RECControl

LimitRPD Ref


MS

Client ID: MW-05 170201

nC6 to nC12 24.74 24.56 0 101 75 - 1250.49

>nC12 to nC28 24.16 24.56 0 98.4 75 - 1250.49

2.779 2.456 0 113 70 - 1300Surr: 2-Fluorobiphenyl




Page 67 of 99

Client:Project:



QC BATCH REPORT

Batch ID: 112117 Instrument: FID-12 Method: TX1005

Sample ID: HS17020115-06MSD Units: mg/L Analysis Date: 07-Feb-2017 23:42



Value %RECControl

LimitRPD Ref


MSD


nC6 to nC12 25.32 24.93 0 102 75 - 125 24.74 2.31 200.50

>nC12 to nC28 25.17 24.93 0 101 75 - 125 24.16 4.09 200.50

2.897 2.493 0 116 70 - 130 2.779 4.17 200Surr: 2-Fluorobiphenyl

2.44 2.493 0 97.9 70 - 130 2.368 3.01 200Surr: Trifluoromethyl benzene

The following samples were analyzed in this batch: HS17020115-01 HS17020115-02 HS17020115-03 HS17020115-04 HS17020115-05 HS17020115-06 HS17020115-07 HS17020115-08 HS17020115-09



Page 68 of 99

Client:Project:



QC BATCH REPORT

Batch ID: 112094 Instrument: ICPMS05 Method: SW6020


Run ID: ICPMS05_289124 SeqNo: 3979321 PrepDate: 06-Feb-2017 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Barium U 0.00500

Manganese U 0.00500

Vanadium U 0.00500




Value %RECControl

LimitRPD Ref


LCS

Client ID:

Barium 0.04348 0.05 0 87.0 80 - 1200.00500

Manganese 0.04377 0.05 0 87.5 80 - 1200.00500

Vanadium 0.04341 0.05 0 86.8 80 - 1200.00500




Value %RECControl

LimitRPD Ref


MS


Barium 0.4935 0.05 0.4419 103 80 - 120 O 0.00500

Manganese 0.1367 0.05 0.09192 89.6 80 - 1200.00500

Vanadium 0.04545 0.05 -0.000681 92.3 80 - 1200.00500




Value %RECControl

LimitRPD Ref


MSD


Barium 0.4776 0.05 0.4419 71.3 80 - 120 0.4935 3.27 20 SO 0.00500

Manganese 0.1343 0.05 0.09192 84.7 80 - 120 0.1367 1.81 200.00500

Vanadium 0.04454 0.05 -0.000681 90.4 80 - 120 0.04545 2.02 200.00500



Page 69 of 99

Client:Project:



QC BATCH REPORT

Batch ID: 112094 Instrument: ICPMS05 Method: SW6020

Sample ID: HS17020115-06PDS Units: mg/L Analysis Date: 07-Feb-2017 12:40



Value %RECControl

LimitRPD Ref


PDS


Barium 0.537 0.1 0.4419 95.1 75 - 125 O 0.00500

Manganese 0.1858 0.1 0.09192 93.9 75 - 1250.00500

Vanadium 0.09176 0.1 -0.000681 92.4 75 - 1250.00500

Sample ID: HS17020115-06SD Units: mg/L Analysis Date: 07-Feb-2017 12:25



Value %RECControl

LimitRPD Ref

Value %D%D Limit Qual

SD


Barium 0.4239 0.4419 4.09 100.0250

Manganese 0.09302 0.09192 1.2 100.0250

Vanadium U -0.000681 0 100.0250




Page 70 of 99

Client:Project:



QC BATCH REPORT

Batch ID: 112095 Instrument: ICPMS05 Method: SW6020 (dissolved) (DISSOLVED)

Sample ID: MBLKF-112095 Units: mg/L Analysis Date: 07-Feb-2017 13:51



Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Barium U 0.00500

Manganese U 0.00500

Vanadium U 0.00500




Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Barium U 0.00500

Manganese U 0.00500

Vanadium U 0.00500




Value %RECControl

LimitRPD Ref


LCS

Client ID:

Barium 0.0449 0.05 0 89.8 80 - 1200.00500

Manganese 0.04355 0.05 0 87.1 80 - 1200.00500

Vanadium 0.0448 0.05 0 89.6 80 - 1200.00500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Barium 0.0948 0.05 0.05279 84.0 75 - 1250.00500

Manganese 0.2863 0.05 0.2536 65.6 75 - 125 SO 0.00500

Vanadium 0.04128 0.05 -0.000427 83.4 75 - 1250.00500



Page 71 of 99

Client:Project:



QC BATCH REPORT

Batch ID: 112095 Instrument: ICPMS05 Method: SW6020 (dissolved) (DISSOLVED)




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Barium 0.09996 0.05 0.05279 94.3 75 - 125 0.0948 5.3 200.00500

Manganese 0.3007 0.05 0.2536 94.2 75 - 125 0.2863 4.88 20 O 0.00500

Vanadium 0.04296 0.05 -0.000427 86.8 75 - 125 0.04128 3.98 200.00500

Sample ID: HS17020151-03PDS Units: mg/L Analysis Date: 07-Feb-2017 14:30



Value %RECControl

LimitRPD Ref


PDS

Client ID:

Barium 0.1368 0.1 0.05279 84.0 75 - 1250.00500

Manganese 0.3318 0.1 0.2536 78.2 75 - 1250.00500

Vanadium 0.07877 0.1 -0.000427 79.2 75 - 1250.00500

Sample ID: HS17020151-03SD Units: mg/L Analysis Date: 07-Feb-2017 14:21



Value %RECControl

LimitRPD Ref

Value %D%D Limit Qual

SD

Client ID:

Barium 0.05256 0.05279 0.439 100.0250

Manganese 0.2461 0.2536 2.95 100.0250

Vanadium U -0.000427 0 100.0250

The following samples were analyzed in this batch: HS17020115-04 HS17020115-07



Page 72 of 99

Client:Project:



QC BATCH REPORT

Batch ID: 112040a Instrument: SV-7 Method: SW8270

Sample ID: MBLK-112040 Units: ug/L Analysis Date: 06-Feb-2017 15:00

Run ID: SV-7_289114 SeqNo: 4136606 PrepDate: 03-Feb-2017 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

1,1´-Biphenyl U 0.20

1,2,4,5-Tetrachlorobenzene U 0.20

1-Methylnaphthalene U 0.10

2,3,4,6-Tetrachlorophenol U 0.20

2,4,5-Trichlorophenol U 0.20

2,4,6-Trichlorophenol U 0.20

2,4-Dichlorophenol U 0.20

2,4-Dimethylphenol U 0.20

2,4-Dinitrophenol U 1.0

2,4-Dinitrotoluene U 0.20

2,6-Dinitrotoluene U 0.20

2-Chloronaphthalene U 0.20

2-Chlorophenol U 0.20

2-Methylnaphthalene U 0.10

2-Methylphenol U 0.20

2-Nitroaniline U 0.20

2-Nitrophenol U 0.20

3&4-Methylphenol U 0.20

3,3´-Dichlorobenzidine U 0.20


4,6-Dinitro-2-methylphenol U 0.20

4-Bromophenyl phenyl ether U 0.20

4-Chloro-3-methylphenol U 0.20

4-Chlorophenyl phenyl ether U 0.20


4-Nitrophenol U 1.0

Acenaphthene U 0.10

Acenaphthylene U 0.10

Acetophenone U 0.20

Aniline U 0.20

Anthracene U 0.10

Benz(a)anthracene U 0.10

Benzaldehyde U 0.20

Benzo(a)pyrene U 0.10



Page 73 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Benzo(b)fluoranthene U 0.10

Benzo(g,h,i)perylene U 0.10

Benzo(k)fluoranthene U 0.10

Bis(2-chloroethoxy)methane U 0.20

Bis(2-chloroethyl)ether U 0.20

Bis(2-chloroisopropyl)ether U 0.20

Bis(2-ethylhexyl)phthalate U 0.20

Butyl benzyl phthalate U 0.20

Caprolactam U 0.20

Carbazole U 0.20

Chrysene U 0.10

Dibenz(a,h)anthracene U 0.10

Dibenzofuran U 0.10

Diethyl phthalate U 0.20

Dimethyl phthalate U 0.20

Di-n-butyl phthalate U 0.20

Di-n-octyl phthalate U 0.20

Fluoranthene U 0.10

Fluorene U 0.10

Hexachlorobenzene U 0.20

Hexachlorobutadiene U 0.20

Hexachlorocyclopentadiene U 0.20

Hexachloroethane U 0.20

Indeno(1,2,3-cd)pyrene U 0.10

Isophorone U 0.20

Naphthalene U 0.10

Nitrobenzene U 0.20

N-Nitrosodi-n-propylamine U 0.20

N-Nitrosodiphenylamine U 0.20

Pentachlorophenol U 0.20

Phenanthrene U 0.10

Phenol U 0.20

Pyrene U 0.10

Pyridine U 1.0



Page 74 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:

4.628 5 0 92.6 34 - 1290.20Surr: 2,4,6-Tribromophenol

4.067 5 0 81.3 40 - 1250.20Surr: 2-Fluorobiphenyl

3.9 5 0 78.0 20 - 1200.20Surr: 2-Fluorophenol

4.235 5 0 84.7 40 - 1350.20Surr: 4-Terphenyl-d14

4.489 5 0 89.8 41 - 1200.20Surr: Nitrobenzene-d5

4.241 5 0 84.8 20 - 1200.20Surr: Phenol-d6



Page 75 of 99

Client:Project:



QC BATCH REPORT


Sample ID: LCS-112040 Units: ug/L Analysis Date: 06-Feb-2017 15:20



Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,1´-Biphenyl 4.182 5 0 83.6 45 - 1250.20

1,2,4,5-Tetrachlorobenzene 4.512 5 0 90.2 40 - 1400.20

1-Methylnaphthalene 3.705 5 0 74.1 45 - 1200.10

2,3,4,6-Tetrachlorophenol 4.224 5 0 84.5 30 - 1400.20

2,4,5-Trichlorophenol 4.423 5 0 88.5 46 - 1200.20

2,4,6-Trichlorophenol 4.338 5 0 86.8 42 - 1200.20

2,4-Dichlorophenol 4.042 5 0 80.8 49 - 1200.20

2,4-Dimethylphenol 3.534 5 0 70.7 35 - 1200.20

2,4-Dinitrophenol 4.303 5 0 86.1 15 - 1201.0

2,4-Dinitrotoluene 5.004 5 0 100 50 - 1220.20

2,6-Dinitrotoluene 4.887 5 0 97.7 50 - 1200.20

2-Chloronaphthalene 5.138 5 0 103 50 - 1200.20

2-Chlorophenol 3.87 5 0 77.4 40 - 1200.20

2-Methylnaphthalene 3.637 5 0 72.7 50 - 1200.10

2-Methylphenol 3.815 5 0 76.3 45 - 1200.20

2-Nitroaniline 4.473 5 0 89.5 28 - 1390.20

2-Nitrophenol 4.002 5 0 80.0 40 - 1200.20

3&4-Methylphenol 3.775 5 0 75.5 35 - 1200.20

3,3´-Dichlorobenzidine 4.498 5 0 90.0 15 - 1200.20

3-Nitroaniline 4.544 5 0 90.9 30 - 1200.20

4,6-Dinitro-2-methylphenol 4.141 5 0 82.8 25 - 1210.20

4-Bromophenyl phenyl ether 4.204 5 0 84.1 45 - 1200.20

4-Chloro-3-methylphenol 4.28 5 0 85.6 47 - 1200.20

4-Chlorophenyl phenyl ether 4.228 5 0 84.6 50 - 1200.20

4-Nitroaniline 5.121 5 0 102 30 - 1330.20

4-Nitrophenol 5.681 5 0 114 30 - 1301.0

Acenaphthene 3.944 5 0 78.9 45 - 1200.10

Acenaphthylene 4.258 5 0 85.2 47 - 1200.10

Acetophenone 4.105 5 0 82.1 40 - 1200.20

Aniline 3.996 5 0 79.9 10 - 1200.20

Anthracene 3.888 5 0 77.8 45 - 1200.10

Benz(a)anthracene 4.421 5 0 88.4 40 - 1200.10

Benzaldehyde 1.031 5 0 20.6 15 - 1200.20

Benzo(a)pyrene 4.115 5 0 82.3 45 - 1200.10



Page 76 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Benzo(b)fluoranthene 5.483 5 0 110 50 - 1200.10

Benzo(g,h,i)perylene 4.397 5 0 87.9 42 - 1270.10

Benzo(k)fluoranthene 3.098 5 0 62.0 45 - 1270.10

Bis(2-chloroethoxy)methane 4.225 5 0 84.5 45 - 1200.20

Bis(2-chloroethyl)ether 3.615 5 0 72.3 37 - 1210.20

Bis(2-chloroisopropyl)ether 3.729 5 0 74.6 40 - 1200.20

Bis(2-ethylhexyl)phthalate 4.7 5 0 94.0 40 - 1390.20

Butyl benzyl phthalate 4.6 5 0 92.0 47 - 1230.20

Caprolactam 4.046 5 0 80.9 35 - 1340.20

Carbazole 4.383 5 0 87.7 42 - 1280.20

Chrysene 4.031 5 0 80.6 43 - 1200.10

Dibenz(a,h)anthracene 4.809 5 0 96.2 45 - 1250.10

Dibenzofuran 4.262 5 0 85.2 50 - 1200.10

Diethyl phthalate 4.381 5 0 87.6 41 - 1200.20

Dimethyl phthalate 4.299 5 0 86.0 40 - 1220.20

Di-n-butyl phthalate 4.354 5 0 87.1 45 - 1230.20

Di-n-octyl phthalate 5.224 5 0 104 45 - 1290.20

Fluoranthene 3.991 5 0 79.8 45 - 1250.10

Fluorene 4.375 5 0 87.5 49 - 1200.10

Hexachlorobenzene 3.982 5 0 79.6 48 - 1200.20

Hexachlorobutadiene 4.202 5 0 84.0 40 - 1200.20

Hexachlorocyclopentadiene 4.08 5 0 81.6 34 - 1360.20

Hexachloroethane 3.521 5 0 70.4 40 - 1200.20

Indeno(1,2,3-cd)pyrene 5.38 5 0 108 41 - 1280.10

Isophorone 4.291 5 0 85.8 40 - 1210.20

Naphthalene 3.918 5 0 78.4 45 - 1200.10

Nitrobenzene 4.255 5 0 85.1 44 - 1200.20

N-Nitrosodi-n-propylamine 4.043 5 0 80.9 40 - 1200.20

N-Nitrosodiphenylamine 3.78 5 0 75.6 40 - 1250.20

Pentachlorophenol 3.514 5 0 70.3 19 - 1210.20

Phenanthrene 3.653 5 0 73.1 45 - 1210.10

Phenol 4.079 5 0 81.6 20 - 1240.20

Pyrene 3.626 5 0 72.5 40 - 1300.10

Pyridine 4.116 5 0 82.3 15 - 1201.0



Page 77 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

4.732 5 0 94.6 34 - 1290.20Surr: 2,4,6-Tribromophenol


4.01 5 0 80.2 20 - 1200.20Surr: 2-Fluorophenol

4.147 5 0 82.9 40 - 1350.20Surr: 4-Terphenyl-d14


4.435 5 0 88.7 20 - 1200.20Surr: Phenol-d6



Page 78 of 99

Client:Project:



QC BATCH REPORT


Sample ID: HS17020115-06MS Units: ug/L Analysis Date: 06-Feb-2017 17:55



Value %RECControl

LimitRPD Ref


MS


1,1´-Biphenyl 2.998 5.814 0 51.6 45 - 1250.23

1,2,4,5-Tetrachlorobenzene 3.166 5.814 0 54.4 40 - 1400.23

1-Methylnaphthalene 2.811 5.814 0 48.4 45 - 1200.12

2,3,4,6-Tetrachlorophenol 4.27 5.814 0 73.5 30 - 1400.23

2,4,5-Trichlorophenol 3.634 5.814 0 62.5 46 - 1200.23

2,4,6-Trichlorophenol 3.156 5.814 0 54.3 42 - 1200.23

2,4-Dichlorophenol 2.889 5.814 0 49.7 49 - 1200.23

2,4-Dimethylphenol 2.595 5.814 0 44.6 35 - 1200.23

2,4-Dinitrophenol 4.279 5.814 0 73.6 15 - 1201.2

2,4-Dinitrotoluene 4.642 5.814 0 79.9 50 - 1220.23

2,6-Dinitrotoluene 3.76 5.814 0 64.7 50 - 1200.23

2-Chloronaphthalene 3.008 5.814 0 51.7 50 - 1200.23

2-Chlorophenol 2.602 5.814 0 44.8 40 - 1200.23

2-Methylnaphthalene 2.844 5.814 0 48.9 50 - 120 S 0.12

2-Methylphenol 2.72 5.814 0 46.8 45 - 1200.23

2-Nitroaniline 3.694 5.814 0 63.5 28 - 1390.23

2-Nitrophenol 2.959 5.814 0 50.9 40 - 1200.23

3&4-Methylphenol 2.805 5.814 0 48.2 35 - 1200.23

3,3´-Dichlorobenzidine 2.94 5.814 0 50.6 15 - 1200.23

3-Nitroaniline 3.849 5.814 0 66.2 30 - 1200.23

4,6-Dinitro-2-methylphenol 5.038 5.814 0 86.6 25 - 1210.23

4-Bromophenyl phenyl ether 3.724 5.814 0 64.0 45 - 1200.23

4-Chloro-3-methylphenol 3.555 5.814 0 61.1 47 - 1200.23

4-Chlorophenyl phenyl ether 3.09 5.814 0 53.2 50 - 1200.23

4-Nitroaniline 5.472 5.814 0 94.1 30 - 1330.23

4-Nitrophenol 6.295 5.814 0 108 30 - 1301.2

Acenaphthene 2.859 5.814 0 49.2 45 - 1200.12

Acenaphthylene 3.138 5.814 0 54.0 47 - 1200.12

Acetophenone 2.891 5.814 0 49.7 40 - 1200.23

Aniline 2.512 5.814 0 43.2 10 - 1200.23

Anthracene 4.183 5.814 0 71.9 45 - 1200.12

Benz(a)anthracene 4.813 5.814 0 82.8 40 - 1200.12

Benzaldehyde 0.9905 5.814 0 17.0 15 - 1200.23

Benzo(a)pyrene 4.91 5.814 0 84.5 45 - 1200.12



Page 79 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS


Benzo(b)fluoranthene 5.362 5.814 0 92.2 50 - 1200.12

Benzo(g,h,i)perylene 5.151 5.814 0 88.6 42 - 1270.12

Benzo(k)fluoranthene 4.537 5.814 0 78.0 45 - 1270.12

Bis(2-chloroethoxy)methane 3.031 5.814 0 52.1 45 - 1200.23

Bis(2-chloroethyl)ether 2.833 5.814 0 48.7 37 - 1210.23

Bis(2-chloroisopropyl)ether 2.815 5.814 0 48.4 40 - 1200.23

Bis(2-ethylhexyl)phthalate 5.919 5.814 0.1692 98.9 40 - 1390.23

Butyl benzyl phthalate 5.745 5.814 0 98.8 47 - 1230.23

Caprolactam 4.211 5.814 0 72.4 35 - 1340.23

Carbazole 5.682 5.814 0 97.7 42 - 1280.23

Chrysene 4.838 5.814 0 83.2 43 - 1200.12

Dibenz(a,h)anthracene 5.829 5.814 0 100 45 - 1250.12

Dibenzofuran 3.106 5.814 0 53.4 50 - 1200.12

Diethyl phthalate 4.343 5.814 0 74.7 41 - 1200.23

Dimethyl phthalate 3.577 5.814 0 61.5 40 - 1220.23

Di-n-butyl phthalate 5.609 5.814 0 96.5 45 - 1230.23

Di-n-octyl phthalate 5.984 5.814 0 103 45 - 1290.23

Fluoranthene 4.925 5.814 0 84.7 45 - 1250.12

Fluorene 3.354 5.814 0 57.7 49 - 1200.12

Hexachlorobenzene 3.73 5.814 0 64.2 48 - 1200.23

Hexachlorobutadiene 2.97 5.814 0 51.1 40 - 1200.23

Hexachlorocyclopentadiene 2.798 5.814 0 48.1 34 - 1360.23

Hexachloroethane 2.657 5.814 0 45.7 40 - 1200.23

Indeno(1,2,3-cd)pyrene 6.013 5.814 0 103 41 - 1280.12

Isophorone 3.061 5.814 0 52.6 40 - 1210.23

Naphthalene 2.816 5.814 0 48.4 45 - 1200.12

Nitrobenzene 3.044 5.814 0 52.4 44 - 1200.23

N-Nitrosodi-n-propylamine 2.952 5.814 0 50.8 40 - 1200.23

N-Nitrosodiphenylamine 3.968 5.814 0 68.2 40 - 1250.23

Pentachlorophenol 4.41 5.814 0 75.8 19 - 1210.23

Phenanthrene 3.784 5.814 0 65.1 45 - 1210.12

Phenol 3.284 5.814 0 56.5 20 - 1240.23

Pyrene 4.524 5.814 0 77.8 40 - 1300.12

Pyridine 2.891 5.814 0 49.7 15 - 1201.2



Page 80 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS


4.657 5.814 0 80.1 34 - 1290.23Surr: 2,4,6-Tribromophenol

2.979 5.814 0 51.2 40 - 1250.23Surr: 2-Fluorobiphenyl

2.741 5.814 0 47.1 20 - 1200.23Surr: 2-Fluorophenol

4.902 5.814 0 84.3 40 - 1350.23Surr: 4-Terphenyl-d14

3.143 5.814 0 54.1 41 - 1200.23Surr: Nitrobenzene-d5

3.096 5.814 0 53.2 20 - 1200.23Surr: Phenol-d6



Page 81 of 99

Client:Project:



QC BATCH REPORT


Sample ID: HS17020115-06MSD Units: ug/L Analysis Date: 06-Feb-2017 18:14



Value %RECControl

LimitRPD Ref


MSD


1,1´-Biphenyl 3.241 5.952 0 54.5 45 - 125 2.998 7.8 200.24

1,2,4,5-Tetrachlorobenzene 3.462 5.952 0 58.2 40 - 140 3.166 8.94 200.24

1-Methylnaphthalene 3.024 5.952 0 50.8 45 - 120 2.811 7.29 200.12

2,3,4,6-Tetrachlorophenol 4.384 5.952 0 73.7 30 - 140 4.27 2.64 200.24

2,4,5-Trichlorophenol 3.866 5.952 0 65.0 46 - 120 3.634 6.19 200.24

2,4,6-Trichlorophenol 3.368 5.952 0 56.6 42 - 120 3.156 6.49 200.24

2,4-Dichlorophenol 3.149 5.952 0 52.9 49 - 120 2.889 8.6 200.24

2,4-Dimethylphenol 2.839 5.952 0 47.7 35 - 120 2.595 8.98 200.24

2,4-Dinitrophenol 4.067 5.952 0 68.3 15 - 120 4.279 5.09 501.2

2,4-Dinitrotoluene 4.643 5.952 0 78.0 50 - 122 4.642 0.00674 200.24

2,6-Dinitrotoluene 3.953 5.952 0 66.4 50 - 120 3.76 5.01 200.24

2-Chloronaphthalene 3.649 5.952 0 61.3 50 - 120 3.008 19.3 200.24

2-Chlorophenol 2.892 5.952 0 48.6 40 - 120 2.602 10.6 200.24

2-Methylnaphthalene 3.039 5.952 0 51.0 50 - 120 2.844 6.6 200.12

2-Methylphenol 2.903 5.952 0 48.8 45 - 120 2.72 6.54 200.24

2-Nitroaniline 3.815 5.952 0 64.1 28 - 139 3.694 3.2 200.24

2-Nitrophenol 3.464 5.952 0 58.2 40 - 120 2.959 15.7 200.24

3&4-Methylphenol 2.849 5.952 0 47.9 35 - 120 2.805 1.58 200.24

3,3´-Dichlorobenzidine 3.731 5.952 0 62.7 15 - 120 2.94 23.7 20 R 0.24

3-Nitroaniline 3.624 5.952 0 60.9 30 - 120 3.849 6.02 200.24

4,6-Dinitro-2-methylphenol 4.392 5.952 0 73.8 25 - 121 5.038 13.7 300.24

4-Bromophenyl phenyl ether 3.628 5.952 0 60.9 45 - 120 3.724 2.61 200.24

4-Chloro-3-methylphenol 3.622 5.952 0 60.9 47 - 120 3.555 1.87 200.24

4-Chlorophenyl phenyl ether 3.421 5.952 0 57.5 50 - 120 3.09 10.1 200.24

4-Nitroaniline 5.641 5.952 0 94.8 30 - 133 5.472 3.06 200.24

4-Nitrophenol 6.02 5.952 0 101 30 - 130 6.295 4.46 201.2

Acenaphthene 3.093 5.952 0 52.0 45 - 120 2.859 7.84 200.12

Acenaphthylene 3.409 5.952 0 57.3 47 - 120 3.138 8.29 200.12

Acetophenone 3.244 5.952 0 54.5 40 - 120 2.891 11.5 200.24

Aniline 2.633 5.952 0 44.2 10 - 120 2.512 4.71 500.24

Anthracene 3.927 5.952 0 66.0 45 - 120 4.183 6.3 200.12

Benz(a)anthracene 5.011 5.952 0 84.2 40 - 120 4.813 4.04 200.12

Benzaldehyde 1.04 5.952 0 17.5 15 - 120 0.9905 4.9 300.24

Benzo(a)pyrene 4.736 5.952 0 79.6 45 - 120 4.91 3.6 200.12



Page 82 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD


Benzo(b)fluoranthene 5.457 5.952 0 91.7 50 - 120 5.362 1.76 200.12

Benzo(g,h,i)perylene 5.087 5.952 0 85.5 42 - 127 5.151 1.25 200.12

Benzo(k)fluoranthene 4.189 5.952 0 70.4 45 - 127 4.537 7.97 200.12

Bis(2-chloroethoxy)methane 3.343 5.952 0 56.2 45 - 120 3.031 9.8 200.24

Bis(2-chloroethyl)ether 2.933 5.952 0 49.3 37 - 121 2.833 3.44 200.24

Bis(2-chloroisopropyl)ether 2.813 5.952 0 47.3 40 - 120 2.815 0.0797 200.24

Bis(2-ethylhexyl)phthalate 5.817 5.952 0.1692 94.9 40 - 139 5.919 1.74 200.24

Butyl benzyl phthalate 5.488 5.952 0 92.2 47 - 123 5.745 4.57 200.24

Caprolactam 3.766 5.952 0 63.3 35 - 134 4.211 11.2 200.24

Carbazole 5.377 5.952 0 90.3 42 - 128 5.682 5.51 200.24

Chrysene 4.849 5.952 0 81.5 43 - 120 4.838 0.23 200.12

Dibenz(a,h)anthracene 5.443 5.952 0 91.4 45 - 125 5.829 6.86 200.12

Dibenzofuran 3.372 5.952 0 56.7 50 - 120 3.106 8.23 200.12

Diethyl phthalate 4.041 5.952 0 67.9 41 - 120 4.343 7.21 200.24

Dimethyl phthalate 3.644 5.952 0 61.2 40 - 122 3.577 1.84 200.24

Di-n-butyl phthalate 5.206 5.952 0 87.5 45 - 123 5.609 7.44 200.24

Di-n-octyl phthalate 5.991 5.952 0 101 45 - 129 5.984 0.106 200.24

Fluoranthene 4.594 5.952 0 77.2 45 - 125 4.925 6.95 200.12

Fluorene 3.624 5.952 0 60.9 49 - 120 3.354 7.73 200.12

Hexachlorobenzene 3.54 5.952 0 59.5 48 - 120 3.73 5.24 200.24

Hexachlorobutadiene 3.162 5.952 0 53.1 40 - 120 2.97 6.28 200.24

Hexachlorocyclopentadiene 3.252 5.952 0 54.6 34 - 136 2.798 15 200.24

Hexachloroethane 2.728 5.952 0 45.8 40 - 120 2.657 2.62 200.24

Indeno(1,2,3-cd)pyrene 5.96 5.952 0 100 41 - 128 6.013 0.887 200.12

Isophorone 3.415 5.952 0 57.4 40 - 121 3.061 10.9 200.24

Naphthalene 3.137 5.952 0 52.7 45 - 120 2.816 10.8 200.12

Nitrobenzene 3.499 5.952 0 58.8 44 - 120 3.044 13.9 200.24

N-Nitrosodi-n-propylamine 2.955 5.952 0 49.6 40 - 120 2.952 0.0974 200.24

N-Nitrosodiphenylamine 3.583 5.952 0 60.2 40 - 125 3.968 10.2 200.24

Pentachlorophenol 3.978 5.952 0 66.8 19 - 121 4.41 10.3 200.24

Phenanthrene 3.617 5.952 0 60.8 45 - 121 3.784 4.51 200.12

Phenol 3.383 5.952 0 56.8 20 - 124 3.284 2.97 200.24

Pyrene 4.261 5.952 0 71.6 40 - 130 4.524 5.99 200.12

Pyridine 2.76 5.952 0 46.4 15 - 120 2.891 4.65 201.2



Page 83 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD


4.66 5.952 0 78.3 34 - 129 4.657 0.0649 200.24Surr: 2,4,6-Tribromophenol

3.257 5.952 0 54.7 40 - 125 2.979 8.94 200.24Surr: 2-Fluorobiphenyl

2.68 5.952 0 45.0 20 - 120 2.741 2.25 200.24Surr: 2-Fluorophenol

4.624 5.952 0 77.7 40 - 135 4.902 5.83 200.24Surr: 4-Terphenyl-d14

3.516 5.952 0 59.1 41 - 120 3.143 11.2 200.24Surr: Nitrobenzene-d5

3.161 5.952 0 53.1 20 - 120 3.096 2.08 200.24Surr: Phenol-d6




Page 84 of 99

Client:Project:



QC BATCH REPORT

Batch ID: R289061 Instrument: VOA4 Method: SW8260

Sample ID: VBLKW-170206 Units: ug/L Analysis Date: 06-Feb-2017 11:13

Run ID: VOA4_289061 SeqNo: 3977990 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

cis-1,2-Dichloroethene U 1.0

Tetrachloroethene U 1.0

trans-1,2-Dichloroethene U 1.0

Trichloroethene U 1.0

Vinyl chloride U 1.0

45.86 50 0 91.7 71 - 1251.0Surr: 1,2-Dichloroethane-d4

42.56 50 0 85.1 70 - 1251.0Surr: 4-Bromofluorobenzene

46.52 50 0 93.0 74 - 1251.0Surr: Dibromofluoromethane

47.98 50 0 96.0 75 - 1251.0Surr: Toluene-d8

Sample ID: VLCSW-170206 Units: ug/L Analysis Date: 06-Feb-2017 09:56



Value %RECControl

LimitRPD Ref


LCS

Client ID:

cis-1,2-Dichloroethene 52.16 50 0 104 75 - 1251.0

Tetrachloroethene 45.12 50 0 90.2 75 - 1301.0

trans-1,2-Dichloroethene 52.47 50 0 105 75 - 1251.0

Trichloroethene 50.46 50 0 101 71 - 1251.0

Vinyl chloride 47.31 50 0 94.6 70 - 1351.0




46.58 50 0 93.2 75 - 1251.0Surr: Toluene-d8



Page 85 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS


cis-1,2-Dichloroethene 133.3 50 79.55 107 75 - 1251.0


trans-1,2-Dichloroethene 56.69 50 3.407 107 75 - 1251.0

Trichloroethene 54.9 50 3.558 103 71 - 1251.0

Vinyl chloride 67.55 50 11.86 111 70 - 1351.0




46.14 50 0 92.3 75 - 1251.0Surr: Toluene-d8




Value %RECControl

LimitRPD Ref


MSD


cis-1,2-Dichloroethene 135.4 50 79.55 112 75 - 125 133.3 1.55 201.0

Tetrachloroethene 47.62 50 0 95.2 75 - 130 46.69 1.98 201.0

trans-1,2-Dichloroethene 58.44 50 3.407 110 75 - 125 56.69 3.04 201.0

Trichloroethene 54.79 50 3.558 102 71 - 125 54.9 0.215 201.0

Vinyl chloride 69.26 50 11.86 115 70 - 135 67.55 2.51 201.0

44.89 50 0 89.8 71 - 125 45.95 2.32 201.0Surr: 1,2-Dichloroethane-d4

46.99 50 0 94.0 70 - 125 46.09 1.93 201.0Surr: 4-Bromofluorobenzene

45.44 50 0 90.9 74 - 125 45.62 0.406 201.0Surr: Dibromofluoromethane

46.41 50 0 92.8 75 - 125 46.14 0.587 201.0Surr: Toluene-d8

The following samples were analyzed in this batch: HS17020115-01 HS17020115-02 HS17020115-03 HS17020115-04 HS17020115-05 HS17020115-06 HS17020115-07 HS17020115-08 HS17020115-09 HS17020115-10



Page 86 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:

1,1,1,2-Tetrachloroethane U 1.0

1,1,1-Trichloroethane U 1.0

1,1,2,2-Tetrachloroethane U 1.0

1,1,2-Trichlor-1,2,2-trifluoroethane U 1.0

1,1,2-Trichloroethane U 1.0

1,1-Dichloroethane U 1.0

1,1-Dichloroethene U 1.0

1,2,3-Trichlorobenzene U 1.0

1,2,4-Trichlorobenzene U 1.0

1,2,4-Trimethylbenzene U 1.0

1,2-Dibromoethane U 1.0

1,2-Dichlorobenzene U 1.0

1,2-Dichloroethane U 1.0

1,2-Dichloropropane U 1.0

1,3,5-Trimethylbenzene U 1.0



2-Butanone U 2.0

2-Hexanone U 2.0

4-Isopropyltoluene U 1.0

4-Methyl-2-pentanone U 2.0

Acetone U 2.0

Benzene U 1.0

Bromodichloromethane U 1.0

Bromoform U 1.0

Bromomethane U 1.0

Carbon disulfide U 2.0

Carbon tetrachloride U 1.0

Chlorobenzene U 1.0

Chloroethane U 1.0

Chloroform U 1.0

Chloromethane U 1.0


cis-1,3-Dichloropropene U 1.0



Page 87 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Cyclohexane U 1.0

Dibromochloromethane U 1.0

Dichlorodifluoromethane U 1.0

Ethylbenzene U 1.0

Isopropylbenzene U 1.0

Methyl tert-butyl ether U 1.0

Methylcyclohexane U 1.0

Methylene chloride U 2.0

Naphthalene U 1.0

n-Butylbenzene U 1.0

n-Propylbenzene U 1.0

sec-Butylbenzene U 1.0

Styrene U 1.0

tert-Butylbenzene U 1.0


Toluene U 1.0


trans-1,3-Dichloropropene U 1.0


Trichlorofluoromethane U 1.0


Xylenes, Total U 1.0




47.98 50 0 96.0 81 - 1191.0Surr: Toluene-d8



Page 88 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

1,1,1,2-Tetrachloroethane 48.59 50 0 97.2 77 - 1181.0

1,1,1-Trichloroethane 52.45 50 0 105 70 - 1301.0

1,1,2,2-Tetrachloroethane 54.8 50 0 110 70 - 1201.0

1,1,2-Trichlor-1,2,2-trifluoroethane 49.01 50 0 98.0 70 - 1301.0

1,1,2-Trichloroethane 46.27 50 0 92.5 77 - 1131.0

1,1-Dichloroethane 50.46 50 0 101 71 - 1221.0

1,1-Dichloroethene 47.85 50 0 95.7 70 - 1301.0

1,2,3-Trichlorobenzene 53.38 50 0 107 72 - 1301.0

1,2,4-Trichlorobenzene 50.67 50 0 101 77 - 1261.0

1,2,4-Trimethylbenzene 46.25 50 0 92.5 73 - 1211.0

1,2-Dibromoethane 56.23 50 0 112 76 - 1231.0

1,2-Dichlorobenzene 44.69 50 0 89.4 77 - 1131.0

1,2-Dichloroethane 50.52 50 0 101 70 - 1241.0

1,2-Dichloropropane 50.25 50 0 101 72 - 1191.0

1,3,5-Trimethylbenzene 43 50 0 86.0 75 - 1181.0



2-Butanone 119.2 100 0 119 70 - 1302.0

2-Hexanone 110.9 100 0 111 70 - 1302.0

4-Isopropyltoluene 47.89 50 0 95.8 74 - 1261.0

4-Methyl-2-pentanone 122 100 0 122 70 - 1302.0

Acetone 114.2 100 0 114 70 - 1302.0

Benzene 50.42 50 0 101 74 - 1201.0

Bromodichloromethane 53.32 50 0 107 74 - 1221.0

Bromoform 58.59 50 0 117 73 - 1281.0

Bromomethane 51.46 50 0 103 70 - 1301.0

Carbon disulfide 104.2 100 0 104 70 - 1302.0

Carbon tetrachloride 46.73 50 0 93.5 71 - 1251.0

Chlorobenzene 47.21 50 0 94.4 76 - 1131.0

Chloroethane 46.57 50 0 93.1 70 - 1301.0

Chloroform 49.67 50 0 99.3 71 - 1211.0

Chloromethane 42.83 50 0 85.7 70 - 1291.0

cis-1,2-Dichloroethene 52.16 50 0 104 75 - 1221.0

cis-1,3-Dichloropropene 52 50 0 104 73 - 1271.0



Page 89 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


LCS

Client ID:

Cyclohexane 51.88 50 0 104 70 - 1301.0

Dibromochloromethane 52.92 50 0 106 77 - 1221.0

Dichlorodifluoromethane 29.49 50 0 59.0 70 - 130 S 1.0

Ethylbenzene 47.51 50 0 95.0 77 - 1171.0

Isopropylbenzene 51.04 50 0 102 73 - 1271.0

Methyl tert-butyl ether 56.73 50 0 113 70 - 1301.0

Methylcyclohexane 50.56 50 0 101 61 - 1571.0

Methylene chloride 46.71 50 0 93.4 70 - 1272.0

Naphthalene 54.75 50 0 109 70 - 1301.0

n-Butylbenzene 51.55 50 0 103 72 - 1301.0

n-Propylbenzene 44.87 50 0 89.7 73 - 1241.0

sec-Butylbenzene 44.55 50 0 89.1 73 - 1281.0

Styrene 54.95 50 0 110 72 - 1261.0

tert-Butylbenzene 50.12 50 0 100 75 - 1241.0


Toluene 49.53 50 0 99.1 77 - 1181.0

trans-1,2-Dichloroethene 52.47 50 0 105 72 - 1271.0

trans-1,3-Dichloropropene 50.65 50 0 101 77 - 1191.0


Trichlorofluoromethane 48.92 50 0 97.8 70 - 1301.0

Vinyl chloride 47.31 50 0 94.6 70 - 1301.0

Xylenes, Total 147.7 150 0 98.5 75 - 1221.0




46.58 50 0 93.2 81 - 1191.0Surr: Toluene-d8



Page 90 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS


1,1,1,2-Tetrachloroethane 45.67 50 0 91.3 70 - 1201.0

1,1,1-Trichloroethane 54.58 50 0 109 70 - 1301.0

1,1,2,2-Tetrachloroethane 51.06 50 0 102 70 - 1231.0

1,1,2-Trichlor-1,2,2-trifluoroethane 55.13 50 0 110 70 - 1301.0

1,1,2-Trichloroethane 44.55 50 0 89.1 70 - 1171.0

1,1-Dichloroethane 57.52 50 6.741 102 70 - 1271.0

1,1-Dichloroethene 53.85 50 2.31 103 70 - 1301.0

1,2,3-Trichlorobenzene 45.53 50 0 91.1 70 - 1301.0

1,2,4-Trichlorobenzene 44.9 50 0 89.8 70 - 1251.0


1,2-Dibromoethane 52.49 50 0 105 70 - 1241.0


1,2-Dichloroethane 47.48 50 0 95.0 70 - 1271.0

1,2-Dichloropropane 48.48 50 0 97.0 70 - 1221.0




2-Butanone 110.1 100 0 110 70 - 1302.0

2-Hexanone 101.4 100 0 101 70 - 1302.0

4-Isopropyltoluene 47.92 50 0 95.8 70 - 1301.0

4-Methyl-2-pentanone 111.5 100 0 111 70 - 1302.0

Acetone 103.4 100 0 103 70 - 1302.0

Benzene 50.6 50 0.2283 101 70 - 1271.0

Bromodichloromethane 51.31 50 0 103 70 - 1241.0

Bromoform 52.76 50 0 106 70 - 1291.0

Bromomethane 51.9 50 0 104 70 - 1301.0

Carbon disulfide 111.5 100 0 111 70 - 1302.0

Carbon tetrachloride 47.87 50 0 95.7 70 - 1301.0

Chlorobenzene 46.11 50 0.2904 91.6 70 - 1141.0

Chloroethane 51.42 50 0 103 70 - 1301.0

Chloroform 49.15 50 0 98.3 70 - 1251.0

Chloromethane 48.22 50 0 96.4 70 - 1301.0

cis-1,2-Dichloroethene 133.3 50 79.55 107 70 - 1281.0

cis-1,3-Dichloropropene 48.64 50 0 97.3 70 - 1251.0



Page 91 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MS


Cyclohexane 56.67 50 0 113 70 - 1301.0

Dibromochloromethane 49.75 50 0 99.5 70 - 1241.0

Dichlorodifluoromethane 51.21 50 0 102 70 - 1301.0

Ethylbenzene 47.49 50 0 95.0 70 - 1241.0

Isopropylbenzene 51.01 50 0 102 70 - 1301.0

Methyl tert-butyl ether 52.94 50 0 106 70 - 1301.0

Methylcyclohexane 54.38 50 0 109 61 - 1581.0

Methylene chloride 46.09 50 0 92.2 70 - 1282.0

Naphthalene 44.23 50 0 88.5 70 - 1301.0

n-Butylbenzene 51.18 50 0 102 70 - 1301.0

n-Propylbenzene 45.35 50 0 90.7 70 - 1301.0

sec-Butylbenzene 45.07 50 0 90.1 70 - 1301.0

Styrene 52.22 50 0 104 70 - 1301.0

tert-Butylbenzene 51.34 50 0 103 70 - 1301.0


Toluene 48.06 50 0 96.1 70 - 1231.0

trans-1,2-Dichloroethene 56.69 50 3.407 107 70 - 1301.0

trans-1,3-Dichloropropene 45.22 50 0 90.4 70 - 1211.0

Trichloroethene 54.9 50 3.558 103 70 - 1291.0

Trichlorofluoromethane 57.08 50 0 114 70 - 1301.0

Vinyl chloride 67.55 50 11.86 111 70 - 1301.0

Xylenes, Total 145.9 150 0 97.2 70 - 1301.0




46.14 50 0 92.3 87 - 1171.0Surr: Toluene-d8



Page 92 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD


1,1,1,2-Tetrachloroethane 48.6 50 0 97.2 70 - 120 45.67 6.21 201.0

1,1,1-Trichloroethane 56.23 50 0 112 70 - 130 54.58 2.97 201.0

1,1,2,2-Tetrachloroethane 51.86 50 0 104 70 - 123 51.06 1.57 201.0

1,1,2-Trichlor-1,2,2-trifluoroethane 56.93 50 0 114 70 - 130 55.13 3.21 201.0

1,1,2-Trichloroethane 45.96 50 0 91.9 70 - 117 44.55 3.1 201.0

1,1-Dichloroethane 59.15 50 6.741 105 70 - 127 57.52 2.79 201.0

1,1-Dichloroethene 55.21 50 2.31 106 70 - 130 53.85 2.48 201.0

1,2,3-Trichlorobenzene 52.1 50 0 104 70 - 130 45.53 13.5 201.0

1,2,4-Trichlorobenzene 50.96 50 0 102 70 - 125 44.9 12.7 201.0

1,2,4-Trimethylbenzene 48.48 50 0 97.0 70 - 125 45.35 6.66 201.0

1,2-Dibromoethane 53.62 50 0 107 70 - 124 52.49 2.14 201.0

1,2-Dichlorobenzene 45.51 50 0 91.0 70 - 115 42.94 5.8 201.0

1,2-Dichloroethane 47.98 50 0 96.0 70 - 127 47.48 1.06 201.0

1,2-Dichloropropane 48.21 50 0 96.4 70 - 122 48.48 0.562 201.0

1,3,5-Trimethylbenzene 45.13 50 0 90.3 70 - 126 42.68 5.58 201.0



2-Butanone 115.3 100 0 115 70 - 130 110.1 4.58 202.0

2-Hexanone 103.7 100 0 104 70 - 130 101.4 2.33 202.0

4-Isopropyltoluene 51.09 50 0 102 70 - 130 47.92 6.41 201.0

4-Methyl-2-pentanone 114.1 100 0 114 70 - 130 111.5 2.34 202.0

Acetone 108.5 100 0 108 70 - 130 103.4 4.79 202.0

Benzene 50.14 50 0.2283 99.8 70 - 127 50.6 0.919 201.0

Bromodichloromethane 50.8 50 0 102 70 - 124 51.31 1.01 201.0

Bromoform 53.76 50 0 108 70 - 129 52.76 1.87 201.0

Bromomethane 55.8 50 0 112 70 - 130 51.9 7.25 201.0

Carbon disulfide 114.2 100 0 114 70 - 130 111.5 2.43 202.0

Carbon tetrachloride 47.47 50 0 94.9 70 - 130 47.87 0.847 201.0

Chlorobenzene 48.04 50 0.2904 95.5 70 - 114 46.11 4.1 201.0

Chloroethane 52.56 50 0 105 70 - 130 51.42 2.19 201.0

Chloroform 49.83 50 0 99.7 70 - 125 49.15 1.37 201.0

Chloromethane 50.07 50 0 100 70 - 130 48.22 3.77 201.0

cis-1,2-Dichloroethene 135.4 50 79.55 112 70 - 128 133.3 1.55 201.0

cis-1,3-Dichloropropene 49.81 50 0 99.6 70 - 125 48.64 2.38 201.0



Page 93 of 99

Client:Project:



QC BATCH REPORT





Value %RECControl

LimitRPD Ref


MSD


Cyclohexane 58.9 50 0 118 70 - 130 56.67 3.86 201.0

Dibromochloromethane 50.76 50 0 102 70 - 124 49.75 2 201.0

Dichlorodifluoromethane 50.46 50 0 101 70 - 130 51.21 1.47 201.0

Ethylbenzene 48.95 50 0 97.9 70 - 124 47.49 3.03 201.0

Isopropylbenzene 53.57 50 0 107 70 - 130 51.01 4.88 201.0

Methyl tert-butyl ether 54.63 50 0 109 70 - 130 52.94 3.14 201.0

Methylcyclohexane 54.69 50 0 109 61 - 158 54.38 0.561 201.0

Methylene chloride 47.86 50 0 95.7 70 - 128 46.09 3.77 202.0

Naphthalene 50.33 50 0 101 70 - 130 44.23 12.9 201.0

n-Butylbenzene 55.19 50 0 110 70 - 130 51.18 7.53 201.0

n-Propylbenzene 47.96 50 0 95.9 70 - 130 45.35 5.59 201.0

sec-Butylbenzene 48.79 50 0 97.6 70 - 130 45.07 7.93 201.0

Styrene 54.29 50 0 109 70 - 130 52.22 3.89 201.0

tert-Butylbenzene 54.99 50 0 110 70 - 130 51.34 6.86 201.0


Toluene 51.08 50 0 102 70 - 123 48.06 6.08 201.0

trans-1,2-Dichloroethene 58.44 50 3.407 110 70 - 130 56.69 3.04 201.0

trans-1,3-Dichloropropene 47.07 50 0 94.1 70 - 121 45.22 4.01 201.0

Trichloroethene 54.79 50 3.558 102 70 - 129 54.9 0.215 201.0

Trichlorofluoromethane 58.36 50 0 117 70 - 130 57.08 2.22 201.0

Vinyl chloride 69.26 50 11.86 115 70 - 130 67.55 2.51 201.0

Xylenes, Total 150.9 150 0 101 70 - 130 145.9 3.4 201.0

44.89 50 0 89.8 70 - 126 45.95 2.32 201.0Surr: 1,2-Dichloroethane-d4

46.99 50 0 94.0 81 - 113 46.09 1.93 201.0Surr: 4-Bromofluorobenzene


46.41 50 0 92.8 87 - 117 46.14 0.587 201.0Surr: Toluene-d8




Page 94 of 99

QUALIFIERS, ACRONYMS, UNITS

Client:Project:WorkOrder:


Qualifier Description* Value exceeds Regulatory Limit

a Not accredited

B Analyte detected in the associated Method Blank above the Reporting Limit

E Value above quantitation range

H Analyzed outside of Holding Time

J Analyte detected below quantitation limit

M Manually integrated, see raw data for justification

n Not offered for accreditation

ND Not Detected at the Reporting Limit

O Sample amount is > 4 times amount spiked

P Dual Column results percent difference > 40%

R RPD above laboratory control limit

S Spike Recovery outside laboratory control limits

U Analyzed but not detected above the MDL/SDL

Acronym DescriptionDCS Detectability Check Study

DUP Method Duplicate

LCS Laboratory Control Sample

LCSD Laboratory Control Sample Duplicate

MBLK Method Blank

MDL Method Detection Limit

MQL Method Quantitation Limit

MS Matrix Spike

MSD Matrix Spike Duplicate

PDS Post Digestion Spike

PQL Practical Quantitaion Limit

SD Serial Dilution

SDL Sample Detection Limit

TRRP Texas Risk Reduction Program

Unit Reported Descriptionmg/L Milligrams per Liter


Page 95 of 99

CERTIFICATIONS,ACCREDITATIONS & LICENSES

Agency Number Expire Date

Arkansas 17-027-0 27-Mar-2018

California 2919 2016-2018 31-Jul-2018

Illinois 004112 09-May-2018

Kansas E-10352 2016-2017 31-Jul-2017

Kentucky 123043 30-Apr-2018

Louisiana 03087 2016-2017 30-Jun-2017

North Carolina 624-2017 31-Dec-2017

Oklahoma 2016-122 31-Aug-2017

Texas T104704231-17-18 30-Apr-2018


Page 96 of 99


Work Order: HS17020115Project: CES Griggs Rd VCP SAMPLE TRACKING

Lab Samp ID Client Sample ID Action Date Person New Location

HS17020115-10 TB-01 170202 Login 2/2/2017 5:59:16 PM CL VW-3

HS17020115-04 MW-03 170201 Out 2/3/2017 5:31:03 PM PVL METPREP


HS17020115-04 MW-03 170201 Return 2/3/2017 5:31:20 PM PVL 10C



HS17020115-02 MW-01 Dup 170202 Out 2/6/2017 4:04:12 PM PVL METPREP









HS17020115-02 MW-01 Dup 170202 Return 2/6/2017 4:04:34 PM PVL 10C













Page 97 of 99

KRM

02-Feb-2017 14:12Date/Time Received:

HS17020115

PBW - Houston

Work Order:

Client Name:

Sample Receipt Checklist

Received by:

Shipping container/cooler in good condition?

Custody seals intact on shipping container/cooler?

Custody seals intact on sample bottles?

Chain of custody present?

Chain of custody signed when relinquished and received?

Chain of custody agrees with sample labels?

Samples in proper container/bottle?

Sample containers intact?

Sufficient sample volume for indicated test?

All samples received within holding time?

Container/Temp Blank temperature in compliance?

Temperature(s)/Thermometer(s):

Cooler(s)/Kit(s):

Date/Time sample(s) sent to storage:

Water - VOA vials have zero headspace?

Water - pH acceptable upon receipt?

pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

1.0c/1.6c - 1.2c/1.8c - 1.8c/2.4c - 2.0c/2.6c uc/c IR#1525234/42644/42789/427872/2/2017 7:00pm

Yes No No VOA vials submitted

Yes No N/A

Yes No N/A

Checklist completed by: Cesar A. LiraDateeSignatureDateeSignature

7-Feb-20172-Feb-2017

ALS.HSWater Carrier name:Matrices:

Reviewed by: Corey Grandits

Client Contacted: Date Contacted: Person Contacted:

Contacted By: Regarding:

Comments:

Corrective Action:

Yes

NoYesTX1005 solids received in hermetically sealed vials? N/A


Page 98 of 99

THIS PAGE BLANK

May 26, 2017


The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Results are expressed as "as received" unless otherwise noted.

QC sample results for this data met EPA or laboratory specifications except as noted in the Case Narrative or as noted with qualifiers in the QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained by ALS Environmental. Samples will be disposed in 30 days unless storage arrangements are made.

If you have any questions regarding this report, please feel free to call me.

Sincerely,

ALS Environmental received 11 sample(s) on May 16, 2017 for the analysis presented in the following report.

Laboratory Results for: CES Griggs Rd VCP

Dear Brenda,


Generated By: Jumoke.Lawal

Dane J. Wacasey



Page 1 of 46

August 16, 2017


The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested. Results are expressed as "as received" unless otherwise noted.

QC sample results for this data met EPA or laboratory specifications except as noted in the Case Narrative or as noted with qualifiers in the QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in full unless written approval has been obtained by ALS Environmental. Samples will be disposed in 30 days unless storage arrangements are made.

If you have any questions regarding this report, please feel free to call me.

Sincerely,

ALS Environmental received 10 sample(s) on Aug 10, 2017 for the analysis presented in the following report.

Laboratory Results for: CES Griggs Rd Quarterly GW

Dear Brenda,


Generated By: Jumoke.Lawal

Dane J. Wacasey



Page 1 of 30


WorkOrder:

Pastor, Behling & Wheeler, LLCCES Griggs Rd Quarterly GWHS17080601













ALS Group USA, Corp Date: 16-Aug-17

Page 2 of 30


WorkOrder:


Dane J. Wacasey




Page 3 of 30


Laboratory Name: ALS Laboratory Group LRC Date: 08/16/2017 Project Name: CES Griggs Rd Quarterly GW Laboratory Job Number: HS17080601 Reviewer Name: Dane Wacasey Prep Batch Number(s): 119158,R299978 #1 A2 Description Yes No NA3 NR4 ER#5













Were LCSs analyzed at the required frequency? X Were LCS (and LCSD, if applicable) %Rs within the laboratory QC limits? X


Was the LCSD RPD within QC limits? X R7 OI Matrix spike (MS) and matrix spike duplicate (MSD) data Were the project/method specified analytes included in the MS and MSD? X Were MS/MSD analyzed at the appropriate frequency? X 1 Were MS (and MSD, if applicable) %Rs within the laboratory QC limits? X Were MS/MSD RPDs within laboratory QC limits? X R8 OI Analytical duplicate data Were appropriate analytical duplicates analyzed for each matrix? X Were analytical duplicates analyzed at the appropriate frequency? X Were RPDs or relative standard deviations within the laboratory QC limits? X R9 OI Method quantitation limits (MQLs): Are the MQLs for each method analyte included in the laboratory data package? X



Are all known problems/anomalies/special conditions noted in this LRC and ER? X



Is the laboratory NELAC-accredited under the Texas Laboratory Program for the analytes, matrices and methods associated with this laboratory data package? X


Page 4 of 30

Laboratory Review Checklist: Supporting Data Laboratory Name: ALS Laboratory Group LRC Date: 08/16/2017 Project Name: CES Griggs Rd Quarterly GW Laboratory Job Number: HS17080601 Reviewer Name: Dane Wacasey Prep Batch Number(s): 119158,R299978 #1 A2 Description Yes No NA3 NR4 ER#5








continuing calibration blank (CCB) Was the CCV analyzed at the method-required frequency? X Were percent differences for each analyte within the method-required QC limits? X Was the ICAL curve verified for each analyte? X Was the absolute value of the analyte concentration in the inorganic CCB < MDL? X S3 O Mass spectral tuning: Was the appropriate compound for the method used for tuning? X Were ion abundance data within the method-required QC limits? X S4 O Internal standards (IS): Were IS area counts and retention times within the method-required QC limits? X















Page 5 of 30


Laboratory Name: ALS Laboratory Group LRC Date: 08/16/2017 Project Name: CES Griggs Rd Quarterly GW Laboratory Job Number: HS17080601 Reviewer Name: Dane Wacasey Prep Batch Number(s): 119158,R299978 ER#5 Description

1

Batch 119158, Semivolatile Organics Method SW8270, LCS/LCSD were analyzed and reported in lieu of an MS/MSD for this batch. The batch quality control criteria were met.


Page 6 of 30


Work Order: HS17080601Project: CES Griggs Rd Quarterly GW SAMPLE SUMMARY


HS17080601-01 10-Aug-2017 16:10 10-Aug-2017 17:15MW-01 170810 Groundwater






HS17080601-07 10-Aug-2017 14:28 10-Aug-2017 17:15MW-06 DUP 170810 Groundwater



HS17080601-10 10-Aug-2017 16:20 10-Aug-2017 17:15TB 170810 Water

ALS Group USA, Corp 16-Aug-17Date:

Page 7 of 30


Pastor, Behling & Wheeler, LLCCES Griggs Rd Quarterly GWMW-01 170810

WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-01

10-Aug-2017 16:10 Matrix:Groundwater

ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1mg/L 11-Aug-2017 13:580.00020cis-1,2-Dichloroethene 0.00100.089

1mg/L 11-Aug-2017 13:580.00030Tetrachloroethene 0.00100.0012

1mg/L 11-Aug-2017 13:580.00020trans-1,2-Dichloroethene 0.00100.0014

1mg/L 11-Aug-2017 13:580.00020Trichloroethene 0.00100.013

1mg/L 11-Aug-2017 13:580.00020Vinyl chloride 0.00100.0052

Surr: 1,2-Dichloroethane-d4 1%REC 11-Aug-2017 13:5899.1 70-126

Surr: 4-Bromofluorobenzene 1%REC 11-Aug-2017 13:5898.6 81-113

Surr: Dibromofluoromethane 1%REC 11-Aug-2017 13:58100 77-123

Surr: Toluene-d8 1%REC 11-Aug-2017 13:58103 82-127

16-Aug-17Date: ALS Group USA, Corp


Page 8 of 30



WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-02


ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1mg/L 11-Aug-2017 14:230.00020cis-1,2-Dichloroethene 0.0010U

1mg/L 11-Aug-2017 14:230.00030Tetrachloroethene 0.0010U

1mg/L 11-Aug-2017 14:230.00020trans-1,2-Dichloroethene 0.0010U

1mg/L 11-Aug-2017 14:230.00020Trichloroethene 0.0010U

1mg/L 11-Aug-2017 14:230.00020Vinyl chloride 0.0010U



Surr: Dibromofluoromethane 1%REC 11-Aug-2017 14:2399.8 77-123




Page 9 of 30



WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-03


ANALYTICAL REPORT












LOW-LEVEL SEMIVOLATILES Method:SW8270 Analyst: GEYPrep:SW3510 / 11-Aug-2017

1mg/L 15-Aug-2017 16:420.000024Dibenz(a,h)anthracene 0.00010U

Surr: 2-Fluorobiphenyl 1%REC 15-Aug-2017 16:4247.3 40-125

Surr: 4-Terphenyl-d14 1%REC 15-Aug-2017 16:4269.4 40-135

Surr: Nitrobenzene-d5 1%REC 15-Aug-2017 16:4246.8 41-120



Page 10 of 30



WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-04


ANALYTICAL REPORT








Surr: 1,2-Dichloroethane-d4 1%REC 11-Aug-2017 20:10101 70-126






Page 11 of 30



WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-05


ANALYTICAL REPORT





1mg/L 11-Aug-2017 15:370.00020trans-1,2-Dichloroethene 0.00100.0026









Page 12 of 30



WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-06


ANALYTICAL REPORT








Surr: 1,2-Dichloroethane-d4 1%REC 11-Aug-2017 16:01100 70-126






Page 13 of 30


Pastor, Behling & Wheeler, LLCCES Griggs Rd Quarterly GWMW-06 DUP 170810

WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-07


ANALYTICAL REPORT














Page 14 of 30



WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-08


ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1mg/L 11-Aug-2017 16:52J 0.00020cis-1,2-Dichloroethene 0.00100.00093






Surr: 4-Bromofluorobenzene 1%REC 11-Aug-2017 16:52100 81-113





Page 15 of 30



WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-09


ANALYTICAL REPORT














Page 16 of 30


Pastor, Behling & Wheeler, LLCCES Griggs Rd Quarterly GWTB 170810

WorkOrder:Lab ID:

Collection Date:

HS17080601HS17080601-10

10-Aug-2017 16:20 Matrix:Water

ANALYTICAL REPORT














Page 17 of 30

WEIGHT LOG

HS17080601CES Griggs Rd Quarterly GWPastor, Behling & Wheeler, LLC


Batch ID: 119158 Method: LOW-LEVEL SEMIVOLATILES 3510_B_LOWPrep:


Final Volume

Prep Factor

HS17080601-03 1 980 1 (mL) 0.00102


Page 18 of 30

Client:CES Griggs Rd Quarterly GWPastor, Behling & Wheeler, LLC

WorkOrder:Project:



Batch ID 119158 Test Name : LOW-LEVEL SEMIVOLATILES Matrix: Groundwater

11 Aug 2017 07:53 15 Aug 2017 16:42HS17080601-03 10 Aug 2017 08:40 1MW-03 170810


11 Aug 2017 17:42HS17080601-10 10 Aug 2017 16:20 1TB 170810


11 Aug 2017 13:58HS17080601-01 10 Aug 2017 16:10 1MW-01 170810

11 Aug 2017 14:23HS17080601-02 10 Aug 2017 10:40 1MW-02 170810

11 Aug 2017 15:12HS17080601-03 10 Aug 2017 08:40 1MW-03 170810

11 Aug 2017 20:10HS17080601-04 10 Aug 2017 13:22 1MW-04 170810

11 Aug 2017 15:37HS17080601-05 10 Aug 2017 15:18 1MW-05 170810

11 Aug 2017 16:01HS17080601-06 10 Aug 2017 14:25 1MW-06 170810

11 Aug 2017 16:26HS17080601-07 10 Aug 2017 14:28 1MW-06 DUP 170810

11 Aug 2017 16:52HS17080601-08 10 Aug 2017 09:53 1MW-07 170810

11 Aug 2017 17:17HS17080601-09 10 Aug 2017 12:35 1MW-08 170810


Page 19 of 30






Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.00002053-70-3 0.000024Dibenz(a,h)anthracene 0.000100.000050

S 0321-60-8 02-Fluorobiphenyl 0.000200

S 01718-51-0 04-Terphenyl-d14 0.000200

S 04165-60-0 0Nitrobenzene-d5 0.000200

Page 20 of 30






Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.00056156-59-2 0.00020cis-1,2-Dichloroethene 0.00100.00050




A 0.0004575-01-4 0.00020Vinyl chloride 0.00100.00050




S 02037-26-5 0Toluene-d8 0.00100

Page 21 of 30

Client:Project:

Pastor, Behling & Wheeler, LLCCES Griggs Rd Quarterly GW


QC BATCH REPORT

Batch ID: 119158 Instrument: SV-7 Method: SW8270

Sample ID: MBLK-119158 Units: ug/L Analysis Date: 16-Aug-2017 14:26

Run ID: SV-7_300150 SeqNo: 4201331 PrepDate: 11-Aug-2017 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Dibenz(a,h)anthracene U 0.10


4.969 5 0 99.4 40 - 1350.20Surr: 4-Terphenyl-d14


Sample ID: LCS-119158 Units: ug/L Analysis Date: 16-Aug-2017 14:46



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Dibenz(a,h)anthracene 4.072 5 0 81.4 45 - 1250.10


4.294 5 0 85.9 40 - 1350.20Surr: 4-Terphenyl-d14


Sample ID: LCSD-119158 Units: ug/L Analysis Date: 16-Aug-2017 15:05



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Dibenz(a,h)anthracene 4.109 5 0 82.2 45 - 125 4.072 0.886 200.10

3.951 5 0 79.0 40 - 125 3.882 1.75 200.20Surr: 2-Fluorobiphenyl

4.19 5 0 83.8 40 - 135 4.294 2.45 200.20Surr: 4-Terphenyl-d14

3.572 5 0 71.4 41 - 120 3.733 4.42 200.20Surr: Nitrobenzene-d5

The following samples were analyzed in this batch: HS17080601-03



Page 22 of 30

Client:Project:



QC BATCH REPORT


Sample ID: VBLKW-170811 Units: ug/L Analysis Date: 11-Aug-2017 11:27



Value %RECControl

LimitRPD Ref


MBLK

Client ID:








50.83 50 0 102 73 - 1261.0Surr: Dibromofluoromethane

51.15 50 0 102 81 - 1201.0Surr: Toluene-d8

Sample ID: VLCSW-170811 Units: ug/L Analysis Date: 11-Aug-2017 10:13



Value %RECControl

LimitRPD Ref


LCS

Client ID:

cis-1,2-Dichloroethene 47.76 50 0 95.5 75 - 1221.0


trans-1,2-Dichloroethene 49.95 50 0 99.9 72 - 1271.0

Trichloroethene 48.82 50 0 97.6 77 - 1211.0

Vinyl chloride 48.43 50 0 96.9 70 - 1301.0

50.74 50 0 101 70 - 1301.0Surr: 1,2-Dichloroethane-d4

50.63 50 0 101 82 - 1151.0Surr: 4-Bromofluorobenzene


49.48 50 0 99.0 81 - 1201.0Surr: Toluene-d8



Page 23 of 30

Client:Project:



QC BATCH REPORT


Sample ID: VLCSDW-170811 Units: ug/L Analysis Date: 11-Aug-2017 10:38



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

cis-1,2-Dichloroethene 47.29 50 0 94.6 75 - 122 47.76 0.987 201.0


trans-1,2-Dichloroethene 47.52 50 0 95.0 72 - 127 49.95 5 201.0

Trichloroethene 48.93 50 0 97.9 77 - 121 48.82 0.207 201.0

Vinyl chloride 45.64 50 0 91.3 70 - 130 48.43 5.93 201.0

50.6 50 0 101 70 - 130 50.74 0.285 201.0Surr: 1,2-Dichloroethane-d4

50.25 50 0 101 82 - 115 50.63 0.741 201.0Surr: 4-Bromofluorobenzene


49.31 50 0 98.6 81 - 120 49.48 0.342 201.0Surr: Toluene-d8

Sample ID: HS17080529-05MS Units: ug/L Analysis Date: 11-Aug-2017 12:43



Value %RECControl

LimitRPD Ref


MS

Client ID:


Tetrachloroethene 50.62 50 0 101 70 - 1301.0



Vinyl chloride 35.44 50 0 70.9 70 - 1301.0

51.3 50 0 103 70 - 1261.0Surr: 1,2-Dichloroethane-d4

50.44 50 0 101 81 - 1131.0Surr: 4-Bromofluorobenzene


49.4 50 0 98.8 82 - 1271.0Surr: Toluene-d8



Page 24 of 30

Client:Project:



QC BATCH REPORT


Sample ID: HS17080529-05MSD Units: ug/L Analysis Date: 11-Aug-2017 13:08



Value %RECControl

LimitRPD Ref


MSD

Client ID:

cis-1,2-Dichloroethene 46.21 50 0 92.4 70 - 128 47.02 1.76 201.0


trans-1,2-Dichloroethene 43.66 50 0 87.3 70 - 130 47.27 7.93 201.0

Trichloroethene 47.92 50 0 95.8 70 - 129 51.17 6.56 201.0

Vinyl chloride 35.05 50 0 70.1 70 - 130 35.44 1.1 201.0

51 50 0 102 70 - 126 51.3 0.573 201.0Surr: 1,2-Dichloroethane-d4

50.46 50 0 101 81 - 113 50.44 0.0241 201.0Surr: 4-Bromofluorobenzene


49.2 50 0 98.4 82 - 127 49.4 0.403 201.0Surr: Toluene-d8




Page 25 of 30





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution



Unit Reported Descriptionmg/L Milligrams per Liter


Page 26 of 30



Arkansas 17-027-0 27-Mar-2018

California 2919 2016-2018 31-Jul-2018


Kentucky 123043 30-Apr-2018

Louisiana 03087 2017-2017 30-Jun-2018


North Dakota R193 2017-2017 30-Apr-2018

Oklahoma 2016-122 31-Aug-2017

Texas T104704231-17-19 30-Apr-2018


Page 27 of 30


Work Order: HS17080601Project: CES Griggs Rd Quarterly GW SAMPLE TRACKING


HS17080601-01 MW-01 170810 Login 8/10/2017 6:24:02 PM TL VOA014


HS17080601-03 MW-03 170810 Login 8/10/2017 6:32:53 PM TL EXT133



HS17080601-04 MW-04 170810 Login 8/10/2017 6:32:53 PM TL TPH076



HS17080601-07 MW-06 DUP 170810 Login 8/10/2017 6:32:53 PM TL VOA014



HS17080601-09 MW-08 170810 Login 8/10/2017 6:32:53 PM TL TPH076

HS17080601-10 TB 170810 Login 8/10/2017 6:32:53 PM TL VOA014


Page 28 of 30

JRM

10-Aug-2017 17:15Date/Time Received:

HS17080601

PBW - Houston

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.9c/3.5c UC/C IR112440808/10/2017 18:40


Yes No N/A

Yes No N/A

Checklist completed by: Jared R. MakanDateeSignatureDateeSignature

11-Aug-201710-Aug-2017

ClientWater Carrier name:Matrices:

Reviewed by: Dane J. Wacasey

Client Contacted: PBW Date Contacted: 08/11/2017 Person Contacted: Dane Wacasey

Contacted By: Brenda Basile Regarding: TPH analysis

Comments:

Corrective Action:

Yes



08/11/2017: Please hold TPH until further advised.

08/11/2017: Placed TPH analysis on hold.

Page 29 of 30


WorkOrder:














ALS Group USA, Corp Date: 26-May-17

Page 2 of 46


WorkOrder:


Dane J. Wacasey




Page 3 of 46


Laboratory Name: ALS Laboratory Group LRC Date: 05/26/2017 Project Name: CES Griggs Rd VCP Laboratory Job Number: HS17050883

Reviewer Name: Dane Wacasey

Prep Batch Number(s): 116496,R294902,R294967,R295010,R295083,R295128,R295180,R295234

#1 A2 Description Yes No NA3 NR4 ER#5













Were LCSs analyzed at the required frequency? X Were LCS (and LCSD, if applicable) %Rs within the laboratory QC limits? X


Was the LCSD RPD within QC limits? X R7 OI Matrix spike (MS) and matrix spike duplicate (MSD) data Were the project/method specified analytes included in the MS and MSD? X Were MS/MSD analyzed at the appropriate frequency? X Were MS (and MSD, if applicable) %Rs within the laboratory QC limits? X Were MS/MSD RPDs within laboratory QC limits? X R8 OI Analytical duplicate data Were appropriate analytical duplicates analyzed for each matrix? X Were analytical duplicates analyzed at the appropriate frequency? X Were RPDs or relative standard deviations within the laboratory QC limits? X R9 OI Method quantitation limits (MQLs): Are the MQLs for each method analyte included in the laboratory data package? X



Are all known problems/anomalies/special conditions noted in this LRC and ER? X



Is the laboratory NELAC-accredited under the Texas Laboratory Program for the analytes, matrices and methods associated with this laboratory data package? X 1


Page 4 of 46

Laboratory Review Checklist: Supporting Data Laboratory Name: ALS Laboratory Group LRC Date: 05/26/2017 Project Name: CES Griggs Rd VCP Laboratory Job Number: HS17050883



#1 A2 Description Yes No NA3 NR4 ER#5








continuing calibration blank (CCB) Was the CCV analyzed at the method-required frequency? X Were percent differences for each analyte within the method-required QC limits? X Was the ICAL curve verified for each analyte? X Was the absolute value of the analyte concentration in the inorganic CCB < MDL? X 2 S3 O Mass spectral tuning: Was the appropriate compound for the method used for tuning? X Were ion abundance data within the method-required QC limits? X S4 O Internal standards (IS): Were IS area counts and retention times within the method-required QC limits? X















Page 5 of 46


Laboratory Name: ALS Laboratory Group LRC Date: 05/26/2017 Project Name: CES Griggs Rd VCP Laboratory Job Number: HS17050883



ER#5 Description

1 Ferrous Iron by SM3500; TCEQ does not offer accreditation for Ferrous Iron, the results are flagged with n.

2 See Run Log and CCB Exceptions Report.


Page 6 of 46

ICS2100_295010Run ID:

FORM 13 - ANALYSIS RUN LOG


Sample No. D/F Time Analytes



ICS2100

Start Date: End Date:16-May-2017 17-May-2017

FileIDCCV 1 1 16-May-2017 07:38 CL NO3N SO4CCB 1 1 16-May-2017 07:52 CL NO3N SO4WBLKW1-051617 1 16-May-2017 08:07 CL NO3N SO4WLCSW1-051617 1 16-May-2017 08:21 CL NO3N SO4WLCSDW1-051617 1 16-May-2017 08:36 CL NO3N SO4CCV 2 1 16-May-2017 12:54 CL NO3N SO4CCB 2 1 16-May-2017 13:09 CL NO3N SO4ZZZZZZMS 50 16-May-2017 22:18 CL NO3N SO4ZZZZZZMSD 50 16-May-2017 22:33 CL NO3N SO4CCV 3 1 17-May-2017 00:00 CL NO3N SO4CCB 3 1 17-May-2017 00:14 CL NO3N SO4MW-01 170516 1 17-May-2017 02:25 CL NO3N SO4CCV 4 1 17-May-2017 02:54 CL NO3N SO4CCB 4 1 17-May-2017 03:09 CL NO3N SO4MW-02 170516 1 17-May-2017 03:23 CL NO3N SO4MW-03 170516 1 17-May-2017 03:53 NO3NMW-03 170516 20 17-May-2017 04:07 CL SO4MW-04 170516 1 17-May-2017 04:22 NO3NMW-04 170516 20 17-May-2017 04:36 CL SO4MW-05 170516 1 17-May-2017 04:51 CL NO3N SO4MW-06 170516 1 17-May-2017 05:20 CL NO3NMW-06 170516 20 17-May-2017 05:34 SO4CCV 5 1 17-May-2017 05:49 CL NO3N SO4CCB 5 1 17-May-2017 06:03 CL NO3N SO4MW-07 170516 1 17-May-2017 06:18 CL NO3N SO4MW-08 170516 1 17-May-2017 06:47 NO3NMW-08 170516 20 17-May-2017 07:02 CL SO4CCV 6 1 17-May-2017 08:00 CL NO3N SO4CCB 6 1 17-May-2017 08:14 CL NO3N SO4CCV 7 1 17-May-2017 09:56 CL NO3N SO4CCB 7 1 17-May-2017 10:11 CL NO3N SO4CCV 8 1 17-May-2017 12:27 CL NO3N SO4CCB 8 1 17-May-2017 12:42 CL NO3N SO4

26-May-17Date: ALS Group USA, Corp

Page 7 of 46

Dane.Wacasey

Highlight

Dane.Wacasey

Highlight

Dane.Wacasey

Highlight

Dane.Wacasey

Highlight

Dane.Wacasey

Highlight

Dane.Wacasey

Highlight

Dane.Wacasey

Highlight

Dane.Wacasey

Highlight

ICS2100_295010Run ID:

CCB EXCEPTIONS REPORT




ICS2100

Seq: 4095418CCB 4 117-May-2017 03:09 D/F:Date:Analyte Result MDL Report Limit

Units: ug/L

237 200 500Chloride


Page 8 of 46


Work Order: HS17050883Project: CES Griggs Rd VCP SAMPLE SUMMARY


HS17050883-01 16-May-2017 16:33 16-May-2017 18:00MW-01 170516 Groundwater






HS17050883-07 16-May-2017 14:25 16-May-2017 18:00MW-06 170516 Dup Groundwater



HS17050883-10 16-May-2017 16:45 16-May-2017 18:00TB 170516 Water

HS17050883-11 16-May-2017 00:00 16-May-2017 18:00Trip Blank Water

ALS Group USA, Corp 26-May-17Date:

Page 9 of 46



WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-01

16-May-2017 16:33 Matrix:Groundwater

ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1mg/L 18-May-2017 07:050.00020cis-1,2-Dichloroethene 0.00100.12

1mg/L 18-May-2017 07:050.00030Tetrachloroethene 0.00100.0022

1mg/L 18-May-2017 07:050.00020trans-1,2-Dichloroethene 0.00100.0015

1mg/L 18-May-2017 07:050.00020Trichloroethene 0.00100.016

1mg/L 18-May-2017 07:050.00020Vinyl chloride 0.00100.0060

Surr: 1,2-Dichloroethane-d4 1%REC 18-May-2017 07:0596.8 71-125

Surr: 4-Bromofluorobenzene 1%REC 18-May-2017 07:0598.3 70-125

Surr: Dibromofluoromethane 1%REC 18-May-2017 07:05103 74-125

Surr: Toluene-d8 1%REC 18-May-2017 07:05102 75-125

DISSOLVED GASES BY RSK-175 Method:RSK-175 Analyst: AAP10ug/L 24-May-2017 12:441.07Methane 5.00205

1ug/L 22-May-2017 14:070.144Ethane 1.002.24

1ug/L 22-May-2017 14:070.234Ethene 1.00U

ALKALINITY BY SM2320B Method:SM2320B Analyst: KMU1mg/L 23-May-2017 14:365.00Alkalinity, Bicarbonate (As

CaCO3)5.00513

1mg/L 23-May-2017 14:365.00Alkalinity, Carbonate (As CaCO3) 5.00U

1mg/L 23-May-2017 14:365.00Alkalinity, Hydroxide (As CaCO3) 5.00U

1mg/L 23-May-2017 14:365.00Alkalinity, Total (As CaCO3) 5.00513

FERROUS IRON BY SM3500 FE D Method:SM3500FED Analyst: JHD1mg/L 17-May-2017 08:12Jn 0.0200Ferrous Iron 0.05000.0420

SULFIDE METHYLENE BLUE BY SM4500 S2- D

Method:SM4500 S2-D Analyst: JHDPrep:SM4500 S2-D / 23-May-2017

1mg/L 23-May-2017 17:130.0110Sulfide 0.0500U

TOTAL ORGANIC CARBON - SM5310B Method:SM5310B Analyst: KMU1mg/L 22-May-2017 16:590.500Organic Carbon, Total 1.001.79

ANIONS BY SW9056A Method:SW9056 Analyst: JBA1mg/L 17-May-2017 02:250.200Chloride 0.50047.7

1mg/L 17-May-2017 02:250.0300Nitrogen, Nitrate (As N) 0.100U

1mg/L 17-May-2017 02:250.200Sulfate 0.50059.8



Page 10 of 46



WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-02


ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1mg/L 18-May-2017 07:290.00020cis-1,2-Dichloroethene 0.0010U

1mg/L 18-May-2017 07:290.00030Tetrachloroethene 0.0010U

1mg/L 18-May-2017 07:290.00020trans-1,2-Dichloroethene 0.0010U

1mg/L 18-May-2017 07:290.00020Trichloroethene 0.0010U

1mg/L 18-May-2017 07:290.00020Vinyl chloride 0.0010U





DISSOLVED GASES BY RSK-175 Method:RSK-175 Analyst: AAP2ug/L 24-May-2017 12:520.214Methane 1.0063.0

1ug/L 22-May-2017 14:170.144Ethane 1.00U

1ug/L 22-May-2017 14:170.234Ethene 1.00U


CaCO3)5.00422




FERROUS IRON BY SM3500 FE D Method:SM3500FED Analyst: JHD5mg/L 17-May-2017 08:22n 0.100Ferrous Iron 0.2502.30



1mg/L 23-May-2017 17:130.0110Sulfide 0.0500U



1mg/L 17-May-2017 03:23J 0.0300Nitrogen, Nitrate (As N) 0.1000.0440

1mg/L 17-May-2017 03:230.200Sulfate 0.50032.7



Page 11 of 46



WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-03


ANALYTICAL REPORT













1ug/L 22-May-2017 14:270.144Ethane 1.00U

1ug/L 22-May-2017 14:270.234Ethene 1.00U


CaCO3)5.00772







1mg/L 23-May-2017 17:130.0110Sulfide 0.0500U


ANIONS BY SW9056A Method:SW9056 Analyst: JBA20mg/L 17-May-2017 04:074.00Chloride 10.0197

1mg/L 17-May-2017 03:530.0300Nitrogen, Nitrate (As N) 0.1000.422

20mg/L 17-May-2017 04:074.00Sulfate 10.0149



Page 12 of 46



WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-04


ANALYTICAL REPORT













1ug/L 22-May-2017 14:390.144Ethane 1.00U

1ug/L 22-May-2017 14:39J 0.234Ethene 1.000.304


CaCO3)5.00842







1mg/L 23-May-2017 17:130.0110Sulfide 0.0500U



1mg/L 17-May-2017 04:220.0300Nitrogen, Nitrate (As N) 0.1000.896

20mg/L 17-May-2017 04:364.00Sulfate 10.0272



Page 13 of 46



WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-05


ANALYTICAL REPORT













1ug/L 22-May-2017 14:480.144Ethane 1.003.22

1ug/L 22-May-2017 14:480.234Ethene 1.001.10


CaCO3)5.00688







1mg/L 23-May-2017 17:130.0110Sulfide 0.0500U




1mg/L 17-May-2017 04:510.200Sulfate 0.50052.6



Page 14 of 46



WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-06


ANALYTICAL REPORT













1ug/L 22-May-2017 14:580.144Ethane 1.005.10

1ug/L 22-May-2017 14:58J 0.234Ethene 1.000.442


CaCO3)5.00685







1mg/L 23-May-2017 17:130.0110Sulfide 0.0500U




20mg/L 17-May-2017 05:344.00Sulfate 10.0158



Page 15 of 46


Pastor, Behling & Wheeler, LLCCES Griggs Rd VCPMW-06 170516 Dup

WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-07


ANALYTICAL REPORT














Page 16 of 46



WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-08


ANALYTICAL REPORT



LOW LEVEL VOLATILES BY SW8260C Method:SW8260 Analyst: AKP1mg/L 18-May-2017 09:54J 0.00020cis-1,2-Dichloroethene 0.00100.00068










1ug/L 22-May-2017 15:13J 0.144Ethane 1.000.204

1ug/L 22-May-2017 15:130.234Ethene 1.00U


CaCO3)5.00543







1mg/L 23-May-2017 17:130.0110Sulfide 0.0500U




1mg/L 17-May-2017 06:180.200Sulfate 0.50049.9



Page 17 of 46



WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-09


ANALYTICAL REPORT













1ug/L 22-May-2017 15:250.144Ethane 1.00U

1ug/L 22-May-2017 15:250.234Ethene 1.00U


CaCO3)5.00891







1mg/L 23-May-2017 17:130.0110Sulfide 0.0500U




20mg/L 17-May-2017 07:024.00Sulfate 10.0403



Page 18 of 46


Pastor, Behling & Wheeler, LLCCES Griggs Rd VCPTB 170516

WorkOrder:Lab ID:

Collection Date:

HS17050883HS17050883-10

16-May-2017 16:45 Matrix:Water

ANALYTICAL REPORT














Page 19 of 46

WEIGHT LOG



Batch ID: 116496 Method: SULFIDE METHYLENE BLUE BY SM4500 S2- D

SULFIDE_W_METHYLENE PREP

Prep:


Final Volume

Prep Factor

HS17050883-01 1 50 50 (mL) 1HS17050883-02 1 50 50 (mL) 1HS17050883-03 1 50 50 (mL) 1HS17050883-04 1 50 50 (mL) 1HS17050883-05 1 50 50 (mL) 1HS17050883-06 1 50 50 (mL) 1HS17050883-08 1 50 50 (mL) 1HS17050883-09 1 50 50 (mL) 1


Page 20 of 46


WorkOrder:Project:



Batch ID 116496 Test Name : SULFIDE METHYLENE BLUE BY SM4500 S2- D Matrix: Groundwater

23 May 2017 15:01 23 May 2017 17:13HS17050883-01 16 May 2017 16:33 1MW-01 170516

23 May 2017 15:01 23 May 2017 17:13HS17050883-02 16 May 2017 10:28 1MW-02 170516

23 May 2017 15:01 23 May 2017 17:13HS17050883-03 16 May 2017 08:40 1MW-03 170516

23 May 2017 15:01 23 May 2017 17:13HS17050883-04 16 May 2017 13:07 1MW-04 170516

23 May 2017 15:01 23 May 2017 17:13HS17050883-05 16 May 2017 15:18 1MW-05 170516

23 May 2017 15:01 23 May 2017 17:13HS17050883-06 16 May 2017 14:25 1MW-06 170516

23 May 2017 15:01 23 May 2017 17:13HS17050883-08 16 May 2017 09:38 1MW-07 170516

23 May 2017 15:01 23 May 2017 17:13HS17050883-09 16 May 2017 11:17 1MW-08 170516


18 May 2017 05:04HS17050883-10 16 May 2017 16:45 1TB 170516


18 May 2017 07:05HS17050883-01 16 May 2017 16:33 1MW-01 170516

18 May 2017 07:29HS17050883-02 16 May 2017 10:28 1MW-02 170516

18 May 2017 07:53HS17050883-03 16 May 2017 08:40 1MW-03 170516

18 May 2017 08:17HS17050883-04 16 May 2017 13:07 1MW-04 170516

18 May 2017 08:42HS17050883-05 16 May 2017 15:18 1MW-05 170516

18 May 2017 09:06HS17050883-06 16 May 2017 14:25 1MW-06 170516

18 May 2017 09:30HS17050883-07 16 May 2017 14:25 1MW-06 170516 Dup

18 May 2017 09:54HS17050883-08 16 May 2017 09:38 1MW-07 170516

18 May 2017 10:19HS17050883-09 16 May 2017 11:17 1MW-08 170516

Batch ID R294967 Test Name : FERROUS IRON BY SM3500 FE D Matrix: Groundwater

17 May 2017 08:12HS17050883-01 16 May 2017 16:33 1MW-01 170516

17 May 2017 08:22HS17050883-02 16 May 2017 10:28 5MW-02 170516

17 May 2017 08:23HS17050883-03 16 May 2017 08:40 1MW-03 170516

17 May 2017 08:24HS17050883-04 16 May 2017 13:07 1MW-04 170516

17 May 2017 08:26HS17050883-05 16 May 2017 15:18 1MW-05 170516

17 May 2017 08:27HS17050883-06 16 May 2017 14:25 1MW-06 170516

17 May 2017 08:28HS17050883-08 16 May 2017 09:38 5MW-07 170516

17 May 2017 08:28HS17050883-09 16 May 2017 11:17 1MW-08 170516


Page 21 of 46


WorkOrder:Project:



Batch ID R295010 Test Name : ANIONS BY SW9056A Matrix: Groundwater

17 May 2017 02:25HS17050883-01 16 May 2017 16:33 1MW-01 170516

17 May 2017 03:23HS17050883-02 16 May 2017 10:28 1MW-02 170516

17 May 2017 04:07HS17050883-03 16 May 2017 08:40 20MW-03 170516

17 May 2017 03:53HS17050883-03 16 May 2017 08:40 1MW-03 170516

17 May 2017 04:36HS17050883-04 16 May 2017 13:07 20MW-04 170516

17 May 2017 04:22HS17050883-04 16 May 2017 13:07 1MW-04 170516

17 May 2017 04:51HS17050883-05 16 May 2017 15:18 1MW-05 170516

17 May 2017 05:34HS17050883-06 16 May 2017 14:25 20MW-06 170516

17 May 2017 05:20HS17050883-06 16 May 2017 14:25 1MW-06 170516

17 May 2017 06:18HS17050883-08 16 May 2017 09:38 1MW-07 170516

17 May 2017 07:02HS17050883-09 16 May 2017 11:17 20MW-08 170516

17 May 2017 06:47HS17050883-09 16 May 2017 11:17 1MW-08 170516

Batch ID R295083 Test Name : TOTAL ORGANIC CARBON - SM5310B Matrix: Groundwater

22 May 2017 16:59HS17050883-01 16 May 2017 16:33 1MW-01 170516

22 May 2017 17:12HS17050883-02 16 May 2017 10:28 1MW-02 170516

22 May 2017 17:26HS17050883-03 16 May 2017 08:40 1MW-03 170516

22 May 2017 17:46HS17050883-04 16 May 2017 13:07 1MW-04 170516

22 May 2017 18:02HS17050883-05 16 May 2017 15:18 1MW-05 170516

22 May 2017 18:17HS17050883-06 16 May 2017 14:25 1MW-06 170516

22 May 2017 18:32HS17050883-08 16 May 2017 09:38 1MW-07 170516

22 May 2017 18:47HS17050883-09 16 May 2017 11:17 1MW-08 170516

Batch ID R295128 Test Name : DISSOLVED GASES BY RSK-175 Matrix: Groundwater

22 May 2017 14:07HS17050883-01 16 May 2017 16:33 1MW-01 170516

22 May 2017 14:17HS17050883-02 16 May 2017 10:28 1MW-02 170516

22 May 2017 14:27HS17050883-03 16 May 2017 08:40 1MW-03 170516

22 May 2017 14:39HS17050883-04 16 May 2017 13:07 1MW-04 170516

22 May 2017 14:48HS17050883-05 16 May 2017 15:18 1MW-05 170516

22 May 2017 14:58HS17050883-06 16 May 2017 14:25 1MW-06 170516

22 May 2017 15:13HS17050883-08 16 May 2017 09:38 1MW-07 170516

22 May 2017 15:25HS17050883-09 16 May 2017 11:17 1MW-08 170516

Batch ID R295180 Test Name : ALKALINITY BY SM2320B Matrix: Groundwater

23 May 2017 14:36HS17050883-01 16 May 2017 16:33 1MW-01 170516

23 May 2017 14:43HS17050883-02 16 May 2017 10:28 1MW-02 170516

23 May 2017 14:51HS17050883-03 16 May 2017 08:40 1MW-03 170516

23 May 2017 14:59HS17050883-04 16 May 2017 13:07 1MW-04 170516

23 May 2017 15:07HS17050883-05 16 May 2017 15:18 1MW-05 170516

23 May 2017 15:14HS17050883-06 16 May 2017 14:25 1MW-06 170516

23 May 2017 15:22HS17050883-08 16 May 2017 09:38 1MW-07 170516

23 May 2017 15:30HS17050883-09 16 May 2017 11:17 1MW-08 170516


Page 22 of 46


WorkOrder:Project:



Batch ID R295234 Test Name : DISSOLVED GASES BY RSK-175 Matrix: Groundwater

24 May 2017 12:44HS17050883-01 16 May 2017 16:33 10MW-01 170516

24 May 2017 12:52HS17050883-02 16 May 2017 10:28 2MW-02 170516

24 May 2017 13:00HS17050883-05 16 May 2017 15:18 5MW-05 170516

24 May 2017 13:12HS17050883-06 16 May 2017 14:25 2MW-06 170516

24 May 2017 13:21HS17050883-08 16 May 2017 09:38 2MW-07 170516

24 May 2017 13:32HS17050883-09 16 May 2017 11:17 2MW-08 170516


Page 23 of 46



Test Code: RSK175InstrumentID: FID-4


AqueousMatrix:Test Number: RSK-175Test Name: Dissolved Gases by RSK-175

Units: ug/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.24374-82-8 0.107Methane 0.5000.193

A 0.33674-84-0 0.144Ethane 1.000.361

A 0.29574-85-1 0.234Ethene 1.000.337

Page 24 of 46






Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.00056156-59-2 0.00020cis-1,2-Dichloroethene 0.00100.00050




A 0.0004575-01-4 0.00020Vinyl chloride 0.00100.00050




S 02037-26-5 0Toluene-d8 0.00100

Page 25 of 46



Test Code: 9056_anions_WInstrumentID: ICS2100


AqueousMatrix:Test Number: SW9056Test Name: Anions by SW9056A

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.17716887-00-6 0.200Chloride 0.5000.250

A 0.032014797-55-8 0.0300Nitrogen, Nitrate (As N) 0.1000.0500

A 0.24214808-79-8 0.200Sulfate 0.5000.250

Page 26 of 46



Test Code: ALK_W 2320BInstrumentID: ManTech01


AqueousMatrix:Test Number: SM2320BTest Name: Alkalinity by SM2320B

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 6.35ALK-Bicarb 5.00Alkalinity, Bicarbonate (As CaCO3) 5.005.00

A 5.00ALK-Carb 5.00Alkalinity, Carbonate (As CaCO3) 5.005.00

A 5.00ALK-Hyd 5.00Alkalinity, Hydroxide (As CaCO3) 5.005.00

A 6.35ALK 5.00Alkalinity, Total (As CaCO3) 5.005.00

Page 27 of 46



Test Code: FERROUS IRON_WInstrumentID: UV-2450


AqueousMatrix:Test Number: SM3500FEDTest Name: Ferrous Iron by SM3500 Fe D

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.0260FEFERROUS 0.0200Ferrous Iron 0.05000.0250

Page 28 of 46



Test Code: SULF_W_MethyleneBlueInstrumentID: UV-2450


WaterMatrix:Test Number: SM4500 S2-DTest Name: Sulfide Methylene Blue by SM4500

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.018018496-25-8 0.0110Sulfide 0.05000.0250

Page 29 of 46



Test Code: TOC_W 5310BInstrumentID: TOC_02


AqueousMatrix:Test Number: SM5310BTest Name: Total Organic Carbon - SM5310B

Units: mg/L

Type Analyte DCSCAS MDL PQLDCS SpikeA 0.7357440-44-0 0.500Organic Carbon, Total 1.000.500

Page 30 of 46

Client:Project:



QC BATCH REPORT

Batch ID: R295128 Instrument: FID-4 Method: RSK-175

Sample ID: MBLK-170522 Units: ug/L Analysis Date: 22-May-2017 13:37

Run ID: FID-4_295128 SeqNo: 4097280 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Ethane U 1.00

Ethene U 1.00

Methane U 0.500

Sample ID: LCS-170522 Units: ug/L Analysis Date: 22-May-2017 12:54



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Ethane 18.79 18.04 0 104 75 - 1251.00

Ethene 18.1 16.8 0 108 75 - 1251.00

Methane 9.171 9.647 0 95.1 75 - 1250.500

Sample ID: LCSD-170522 Units: ug/L Analysis Date: 22-May-2017 13:05



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Ethane 19.47 18.04 0 108 75 - 125 18.79 3.55 301.00

Ethene 18.93 16.8 0 113 75 - 125 18.1 4.51 301.00

Methane 9.62 9.647 0 99.7 75 - 125 9.171 4.77 300.500

Sample ID: HS17050606-01DUP Units: ug/L Analysis Date: 22-May-2017 15:47



Value %RECControl

LimitRPD Ref


DUP

Client ID:

Ethane U 0 0 301.00

Ethene U 0 0 301.00

Methane 0.4605 0.2123 0 30 J 0.500

The following samples were analyzed in this batch: HS17050883-01 HS17050883-02 HS17050883-03 HS17050883-04 HS17050883-05 HS17050883-06 HS17050883-08 HS17050883-09



Page 31 of 46

Client:Project:



QC BATCH REPORT

Batch ID: R295234 Instrument: FID-4 Method: RSK-175

Sample ID: MBLK-170524 Units: ug/L Analysis Date: 24-May-2017 11:10



Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Methane 0.4544 J 0.500

Sample ID: LCS-170524 Units: ug/L Analysis Date: 24-May-2017 10:45



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Methane 9.827 9.647 0 102 75 - 1250.500

Sample ID: LCSD-170524 Units: ug/L Analysis Date: 24-May-2017 10:58



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Methane 8.242 9.647 0 85.4 75 - 125 9.827 17.5 300.500

Sample ID: HS17050883-09DUP Units: ug/L Analysis Date: 24-May-2017 13:46



Value %RECControl

LimitRPD Ref


DUP


Methane 51.94 51.9 0.0711 301.00

The following samples were analyzed in this batch: HS17050883-01 HS17050883-02 HS17050883-05 HS17050883-06 HS17050883-08 HS17050883-09



Page 32 of 46

Client:Project:



QC BATCH REPORT


Sample ID: VBLKW-170517 Units: ug/L Analysis Date: 18-May-2017 04:40



Value %RECControl

LimitRPD Ref


MBLK

Client ID:








52.48 50 0 105 74 - 1251.0Surr: Dibromofluoromethane

51.44 50 0 103 75 - 1251.0Surr: Toluene-d8

Sample ID: VLCSW-170517 Units: ug/L Analysis Date: 18-May-2017 03:51



Value %RECControl

LimitRPD Ref


LCS

Client ID:




Trichloroethene 44.51 50 0 89.0 71 - 1251.0

Vinyl chloride 47.06 50 0 94.1 70 - 1351.0




49.1 50 0 98.2 75 - 1251.0Surr: Toluene-d8



Page 33 of 46

Client:Project:



QC BATCH REPORT


Sample ID: HS17050674-17MS Units: ug/L Analysis Date: 18-May-2017 05:52



Value %RECControl

LimitRPD Ref


MS

Client ID:

cis-1,2-Dichloroethene 444.9 500 0 89.0 75 - 12510

Tetrachloroethene 486.7 500 0 97.3 75 - 13010

trans-1,2-Dichloroethene 441.9 500 0 88.4 75 - 12510

Trichloroethene 422.2 500 0 84.4 71 - 12510

Vinyl chloride 389 500 0 77.8 70 - 13510

481.2 500 0 96.2 71 - 12510Surr: 1,2-Dichloroethane-d4

497.3 500 0 99.5 70 - 12510Surr: 4-Bromofluorobenzene

481.3 500 0 96.3 74 - 12510Surr: Dibromofluoromethane

495.2 500 0 99.0 75 - 12510Surr: Toluene-d8

Sample ID: HS17050674-17MSD Units: ug/L Analysis Date: 18-May-2017 06:16



Value %RECControl

LimitRPD Ref


MSD

Client ID:

cis-1,2-Dichloroethene 436.4 500 0 87.3 75 - 125 444.9 1.93 2010

Tetrachloroethene 493.6 500 0 98.7 75 - 130 486.7 1.41 2010

trans-1,2-Dichloroethene 447.2 500 0 89.4 75 - 125 441.9 1.2 2010

Trichloroethene 424.4 500 0 84.9 71 - 125 422.2 0.525 2010

Vinyl chloride 386.2 500 0 77.2 70 - 135 389 0.74 2010

474 500 0 94.8 71 - 125 481.2 1.53 2010Surr: 1,2-Dichloroethane-d4

492.7 500 0 98.5 70 - 125 497.3 0.929 2010Surr: 4-Bromofluorobenzene

484.1 500 0 96.8 74 - 125 481.3 0.575 2010Surr: Dibromofluoromethane

490.6 500 0 98.1 75 - 125 495.2 0.922 2010Surr: Toluene-d8




Page 34 of 46

Client:Project:



QC BATCH REPORT

Batch ID: 116496 Instrument: UV-2450 Method: SM4500 S2-D

Sample ID: MBLK-116496 Units: mg/L Analysis Date: 23-May-2017 17:13

Run ID: UV-2450_295186 SeqNo: 4099522 PrepDate: 23-May-2017 DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Sulfide U 0.0500

Sample ID: LCS-116496 Units: mg/L Analysis Date: 23-May-2017 17:13



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Sulfide 0.181 0.2 0 90.5 77 - 1240.0500

Sample ID: HS17050901-10MS Units: mg/L Analysis Date: 23-May-2017 17:13



Value %RECControl

LimitRPD Ref


MS

Client ID:

Sulfide 0.168 0.2 -0.001 84.5 77 - 1240.0500

Sample ID: HS17050901-10MSD Units: mg/L Analysis Date: 23-May-2017 17:13



Value %RECControl

LimitRPD Ref


MSD

Client ID:

Sulfide 0.18 0.2 -0.001 90.5 77 - 124 0.168 6.9 200.0500




Page 35 of 46

Client:Project:



QC BATCH REPORT

Batch ID: R294967 Instrument: UV-2450 Method: SM3500FED

Sample ID: MBLK-294967 Units: mg/L Analysis Date: 17-May-2017 08:29

Run ID: UV-2450_294967 SeqNo: 4094675 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Ferrous Iron U 80 - 1200.0500

Sample ID: LCS-294967 Units: mg/L Analysis Date: 17-May-2017 08:12



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Ferrous Iron 0.292 0.25 0 117 80 - 1200.0500




Value %RECControl

LimitRPD Ref


MS


Ferrous Iron 0.287 0.25 0.033 102 75 - 1250.0500




Value %RECControl

LimitRPD Ref


MSD


Ferrous Iron 0.29 0.25 0.033 103 75 - 125 0.287 1.04 200.0500




Page 36 of 46

Client:Project:



QC BATCH REPORT

Batch ID: R295010 Instrument: ICS2100 Method: SW9056

Sample ID: WBLKW1-051617 Units: mg/L Analysis Date: 16-May-2017 08:07

Run ID: ICS2100_295010 SeqNo: 4095399 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Chloride U 0.500

Nitrogen, Nitrate (As N) U 0.100

Sulfate U 0.500

Sample ID: WLCSW1-051617 Units: mg/L Analysis Date: 16-May-2017 08:21



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Chloride 19.46 20 0 97.3 80 - 1200.500

Nitrogen, Nitrate (As N) 3.824 4 0 95.6 80 - 1200.100

Sulfate 19.35 20 0 96.8 80 - 1200.500

Sample ID: WLCSDW1-051617 Units: mg/L Analysis Date: 16-May-2017 08:36



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Chloride 19.52 20 0 97.6 80 - 120 19.46 0.313 200.500

Nitrogen, Nitrate (As N) 3.825 4 0 95.6 80 - 120 3.824 0.0261 200.100

Sulfate 19.49 20 0 97.4 80 - 120 19.35 0.7 200.500




Value %RECControl

LimitRPD Ref


MS

Client ID:

Chloride 1432 500 954.4 95.5 80 - 12025.0

Nitrogen, Nitrate (As N) 98.57 100 0 98.6 80 - 1205.00

Sulfate 750.8 500 244.1 101 80 - 12025.0



Page 37 of 46

Client:Project:



QC BATCH REPORT

Batch ID: R295010 Instrument: ICS2100 Method: SW9056




Value %RECControl

LimitRPD Ref


MSD

Client ID:

Chloride 1432 500 954.4 95.5 80 - 120 1432 0.00524 2025.0

Nitrogen, Nitrate (As N) 98.3 100 0 98.3 80 - 120 98.57 0.274 205.00

Sulfate 748.6 500 244.1 101 80 - 120 750.8 0.294 2025.0




Page 38 of 46

Client:Project:



QC BATCH REPORT

Batch ID: R295083 Instrument: TOC_02 Method: SM5310B


Run ID: TOC_02_295083 SeqNo: 4096619 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Organic Carbon, Total U 1.00

Sample ID: WLCSW1-052217 Units: mg/L Analysis Date: 22-May-2017 10:46



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Organic Carbon, Total 9.169 10 0 91.7 80 - 1201.00

Sample ID: WLCSDW1-052217 Units: mg/L Analysis Date: 22-May-2017 10:59



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Organic Carbon, Total 9.149 10 0 91.5 80 - 120 9.169 0.218 201.00




Value %RECControl

LimitRPD Ref


MS

Client ID:

Organic Carbon, Total 13.92 10 4.183 97.4 80 - 1201.00




Page 39 of 46

Client:Project:



QC BATCH REPORT

Batch ID: R295180 Instrument: ManTech01 Method: SM2320B


Run ID: ManTech01_295180 SeqNo: 4098406 PrepDate: DF: 1


Value %RECControl

LimitRPD Ref


MBLK

Client ID:

Alkalinity, Bicarbonate (As CaCO3) U 5.00

Alkalinity, Carbonate (As CaCO3) U 5.00

Alkalinity, Hydroxide (As CaCO3) U 5.00

Alkalinity, Total (As CaCO3) U 5.00

Sample ID: LCS-ALK1-170523 Units: mg/L Analysis Date: 23-May-2017 13:15



Value %RECControl

LimitRPD Ref


LCS

Client ID:

Alkalinity, Carbonate (As CaCO3) 1062 1000 0 106 80 - 1205.00

Alkalinity, Total (As CaCO3) 1099 1000 0 110 80 - 1205.00

Sample ID: LCSD-ALK1-170523 Units: mg/L Analysis Date: 23-May-2017 13:24



Value %RECControl

LimitRPD Ref


LCSD

Client ID:

Alkalinity, Carbonate (As CaCO3) 1057 1000 0 106 80 - 120 1062 0.451 205.00

Alkalinity, Total (As CaCO3) 1095 1000 0 109 80 - 120 1099 0.393 205.00

Sample ID: HS17050876-09DUP Units: mg/L Analysis Date: 23-May-2017 13:58



Value %RECControl

LimitRPD Ref


DUP

Client ID:

Alkalinity, Bicarbonate (As CaCO3) 117.1 116.4 0.574 205.00

Alkalinity, Carbonate (As CaCO3) U 0 0 205.00

Alkalinity, Hydroxide (As CaCO3) U 0 0 205.00

Alkalinity, Total (As CaCO3) 117.1 116.4 0.574 205.00




Page 40 of 46





a Not accredited

















MBLK Method Blank



MS Matrix Spike




SD Serial Dilution



Unit Reported DescriptionDate

mg/L Milligrams per Liter


Page 41 of 46



Arkansas 17-027-0 27-Mar-2018

California 2919 2016-2018 31-Jul-2018


Kansas E-10352 2016-2017 31-Jul-2017

Louisiana 03087 2016-2017 30-Jun-2017


Oklahoma 2016-122 31-Aug-2017

Texas T104704231-17-18 30-Apr-2018


Page 42 of 46




HS17050883-01 MW-01 170516 Login 5/16/2017 6:47:25 PM PMG WET017



HS17050883-01 MW-01 170516 Login 5/16/2017 6:47:25 PM PMG RSK014


HS17050883-01 MW-01 170516 Login 5/16/2017 6:47:25 PM PMG VOA040































HS17050883-07 MW-06 170516 Dup Login 5/16/2017 6:56:23 PM PMG VOA040





Page 43 of 46












HS17050883-10 TB 170516 Login 5/16/2017 7:01:15 PM PMG VOA040


Page 44 of 46

JRM

16-May-2017 18:00Date/Time Received:

HS17050883

PBW - Houston

Work Order:

Client Name:


Received by:













Cooler(s)/Kit(s):




pH adjusted?

pH adjusted by:

Login Notes:

No Not Present

Yes No Not Present

Yes No Not Present

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

Yes No

2.8c/3.4c, 3.2c/3.8c U/C IR20Green, 245285/16/17 19:40


Yes No N/A

Yes No N/A

2 sets of Trip Blanks received in Green cooler ( All VOC vials in this cooler.) Logged in only 1 with analysis. 2nd Trip Blank logged on hold.

Checklist completed by: Paresh M. Giga Dane J. WacaseyDateeSignatureDateeSignature

16-May-2017

ClientGroundwater/Water Carrier name:Matrices:

Reviewed by:

Client Contacted: Date Contacted: Person Contacted:

Contacted By: Regarding:

Comments:

Corrective Action:

Yes



18-May-2017

Page 45 of 46

· 11231 richmond avenue suite d104 houston, tx 77082 tel (832) 916-3690 october 6, 2017 project...

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