019253

/ r!' I ;,.. v i

U.S. c' .• MONMENTAL PROTECTION AGENCY-CLP Samp I o Management Oltlco /•() \ \ \S"'• •;,. 's« 018, Alexandria, VA 22313 - 703/557-2490

ORSANICS ANALYSIS DATA SHEET - Pago I

laboratory Name _H»_n_d CompuChoni ______ Case Number \(g&7 Sfl'-S iALab Sample ID No. ~" It^U QC Report No. /ffi-9 /fl -? x

Multiply Detection limits Dy I Qor loQorQ ____( CnoeK Box lor Appropriate Factor)

ACID COMPOUNDS BASE/NEUTRAL COMPOUNDS

JJPI CA5I ug/l _PPI CA5I ug/l

(2IAI 66-06-2 2,4,6-trlcnloropnanol ______ 20U I42B) 3963B-32-9 bl5-(2-Chlorol50propyl)etnar 40U(22A) 59-50-7 p-cnloro-fli-crosol ________ «W 1436) II— 91-1 Dls-IZ-cnlorootnoxylnieTnane 40U(2«A| 95-57-B 2-«nloropnonol 20U I52B) 87-68-3 nexachloroDutaalene ______ 20U(JIAI I22-6J-2 2|4-nlcnloropnenol_______20U I5MI 77-47-4 hexacniorocyclopontaalone 20U(MA) 105-67-9 2~,4-<lliMTnylpncnol 151? T54BI 76-59-1 I5opnoron_o '20U(57A| ae-75-5 2-nltropnenol 40U I55B) 91-20-3 naphthalene 20U(58AI 100-02-7 4-nltropnenol 200U I56B) 98-95-i nltrooenzene__________20UI59A) 51-86-5 2,4-alnltropnenol_______IOOU 1626) 86-30-6 N-nltrosoolpnenylamlne_____20UloOA) 534-52-1 4,6-alnltro-2-ffl8tnylpnenol 40U 1636) 62I-64-7 N-nltrosoal-n-propylanilne 40UI64A1 B7-J6-5 pentacnioropnenol________40U 16681 II7-B1-7 Dl5l2-«Tnylhe>yl)pnTnalBte 20UI65A) 106-85-2 pnenol______________20U .(67BI '65-68-7 Dutyl Danzyl pntnalate_____20U

(66S) 84-74-2 al-n-butyl pnthalate______20U(Non-Priority Pollutant Hazardous Substances) 16981 117-84-0 ai-n-oetyl pntnalate______20U

1708) S4-66-2 methyl phthalato________20U65-65-0 benzole acla__________20QU 171B) lil-ll-i almetnyl phtnalate_______20U95-46-7 2-metnyI phenol 20U I72B) 56-55-J penzo(a)ontnracene 401'I06-J9-4 4i»9tnyrpnenol 20U I7M) 50-33-8 Mn;o(a|pyrene 40U

____95-95-4 Z,4,5-trlenlorQphenol_____2QOU I74B) 205-99-2 DanKXCItluorantnene______40U' 175BI 207-OB-9 6anzo(K)lluorantnene______40U

BASE-NEUTRAL COMPOUNDS 1766) ilS-OI-9 clirysene_____________20JJ177B) 20B-96-a ncenapnthy I ene_________20U

( IB) 63-32-9 aconaphtnene__________20U 1766) 120-12-7 antnracene____________20U1 58] 92-67-5 Denzlalno SOU (7981 IBI-24-2 Danzolghl iperylene_______40U( 681 120-62-1 1,2,4-trlchloroDenzana_____20U 1606) B6-7J-7 tluorana_____________20U(931 116-74-1 nexBChloroOenzene________20U I a IB) 65-01-6 pnenantnrene__________20U(I2B) 67-72-1 nexacnioroetnane 20U 1623) 52-70-3 Olbenzola,n|antliracehe 40UII8BI 111-44-4 blsl2-<:hloroetnyl)etner____20U IB36) 163-39-5 lngeno(l,2,3-cd)pyrene_____40U(200) 91-58-7 2-cnloronapnthalenB 20U 1646) 129-00-0 pyrene______________20U1256) 95-50-1 1,2-dlcniorolienzane_______20U1268) 541-73-1 l.i-OlchloroODnzene_______20U (Non-Priority Pollutant Hazardous Substances)(278) 106-46-7 1,4-dlcniorobenzane 20U12681 91-94-1 3,ji-<llcMoropen;ldln9_____40U 62-5J-3 aniline_____________20U(.156) I2I-I4-2 2,4-dlnltrotoluene_______40U ____100-51-6 benzyl alconol_________40U1J6B) 006-20-2 2,6-dlnltrotoluene_______40U_ ____106-47-6 4-cnioroanlllh9________IOOU

1,2-dlpnonylhydrazlne ____M2-64-9 dlbenzoturan__________20U137B) 122-66-7 las atooenzene)_________40U ____91-57-6 2-nmtnylnapntlialene______40U1396) 206-44-0 tluorantnane__________20U 86-74-4 2-nltroanlllne_________200U(40B) 7005-72-3 4-chloropnenyl pnehyletner 20U 99-09-2 3-flltroanll Ine_________200U(4IB) 101-55-3 4-oromoptwnyl pnonyl etner 20U IOO-QI-6 4 - n l t r o a h l l l n e 2 0 0 U

30 019253

Uborttory MM MMKJ ConpuCtwmLit) Saipli 10 Ho

ORSANICS WMT5I5 DATA SH6E7 - Plgt 2

CIH NMDW

(Ctmck Bonier Appropriate Factor)

VOLATILES

PPI

( 2Y) 107-02-BI 3V) 107-13-1( 4V) 71-43-2I (V) 96-23-9( 7V) 108-90-7(10V) 107-06-2(11V) 71-99-6(13V) 75-34-3(14V) 79-00-9(19V) 7»-34-9(16V) 79-00-3(19V) 110-75-fl(23V) (7-66-3(29V) 79-39-4(30V) 156-60-5(32V) 7B-67-J(33V) 10061-02-6

10061-01-09(MV) 100-41-4(44V) 79-09-2(49V) 74-17-3(46V) 74-03-9(47V) 75-25-2(4BV) 79-27-4(49V) 79-69-4(90V) 75-71-6(91V) 124-46-1105VI 127-16-4(06V) 109-M-3(67V) 79-01-6(66V) 79-01-4

acrolalnacrylonltrllabanianacarbon ntncnlorldtcnlorobanjatu

I,1,1-Trlct\lofoatl»na1,1-fllcnloroatnana

IOOUIOOU9U9U5U9U909090

1,1,2,2-tatrachlorotthana 90

2-Chloroatt\ylvlnyl aTtwr VIchlocotora \xldlHtlcnioroatnmi

1 wrti90 '

l,2-trani-4lchlorMttMni VI1,2-dlcnloropropina VI

erthylbwizttn VI

cMoroMthanabroMMthanabrovtonii

1 1 uorof r 1 en 1 oro««tMn«

v>VI

• VIVI

3J-*f(dlchlorodltluoTMMfhani NAchlorodlbromMthanatatracnioroarnaratDliwiatrlcnloroatlwn*vinyl ehlorlda

9U9U9U5U90

(Nofi-frlorlty Polluttnt Hmrdoui SubittncM)

67-64-17S-93-379- ISO9l»-7o-6IOo-10-l100-42-910S-05-4JJ-47-6

•crtoo*2-6utinon«cirXfldliultldi2-htx>ncmi4-Mtny 1 -2-pmtinoniiTvrtntvinyl Kttit*o-xylM*

IOOU200U100IOOUIOOU9U100JU

3C

ORSANICS ANALYSIS DATA SHEET - Page 3

Laboratory Nome Mead CompuChom ___________ Case NumberUb Sample ID hti. /</ifo QC Report No. /££•? /£•/•? /

Multiply Detection limits by I(CtiocK Box tor Appropriate Factor)

PESTICIDES

PP» CASI ug/l

(39P) 309-00-2(90P) 60-57-1(9IP) 57-74-9(92P) 50-29-3(93P) 72-55-9194P) 72-54-6(95P) 115-29-7(96P) 115-29-7(97P) 1031-07-6(98P) 78-20-6(99P) 7421-43-4(IOOP) 76-44-6(I01P) 1024-57-3(I02P) 319-64-6(103P) 319-65-7(104P) 319-66-6( 105P) 56-69-9 .(106P) 53469-21-9(107P) 11097-69-7(106P) 1 1104-26-2(I09P) 1II4I-I6-5(HOP) 12672-29-6(HIP) 11096-82-5(1I2P) 12674-11-2(II3P) 6001-35-2

aldrlndleldrlnchlordane4,41-DDT4,41-DDE4,41-OODendosullan 1endosultoh IIandosultan sultateandrlnandrln aldanydaneptacni.orheptacnlor epoxldoBHC-AlpnaBHC-BataBHC-DeltaBHC-GflmniaPCB-1242PCB-1254PCS- 1221PCB-1232PCB-124BPCB-1260.PCB-IOI6toxapnene

0. IU0, IU0. IU0. IU0. IU0, IU0. IUO.IU0, IUO.IU0, IUO.IUO.IUO.IU0, IUO.IUO.IUO.IUO.IUO.IUO.IU0, IUO.IU0.1U0.1U

DIOXINS ug/l

2,3,7i6-tatrachloroo'lbon2o-(1293) 1746-01-6 p-dloxln________0.002U

30

GC SCREEN DATA SHEET

Laboratory Name___Mead CompuChemCase Numbering? SflS fc

SampleID Number

£^/4/

two

FractionVOAB/N/APesticidesD1ox1n

VOAB/N/APesticidesDioxln

VOAB/N/APesticidesOioxin

VOAB/N/APesticidesDloxin

VOAB/N/APesticidesD1ox1n

VOAB/N/APesticidesD1ox1n

VOAB/N/APesticidesDloxin

GCDetectable*

Medium LevelAJDkinDakj,1

Dateof

Screen__^—

Level ofGC/MS

Analysis**• i-L.

Ll_

*Answer Yes or No.**lndkate"M" for medium level GC/MS analysis.

lnd1cate"L" for low level GC/MS analysis.

30 019262

v t

ORGAN1CS ANALYSIS DATA SHEET - Page 4

Lab Name Mead CompuChem______ EPA Caseff //fljj[CompuCheiiuK NT"

•Sample Number

A. SURROGATE SPIKE RESULTS

COMPOUND

dg-Toluene

-1,2-01 chloroethane

Fraction

VOA

VOA

ConcentrationTotal (ugA' )

il. ?0.

3.2^

(Surrogates only)Spike -

Added (ug'Xl

C/

v .

ftRecovery

icZ

' %

COMPOUND

2-Fluorophenol

Pentafluoropheno!

dj-NUrobenzene

2-Fluorob1phenyl

2-Fluoroan1l1ne

Decaf luoroblpnenyl

Fraction

FSCC

FSCC

FSCC

FSCC

FSCC

FSCC

ConcentrationTotal (ugft)

-?7

•?!?

93

//

9. '

rG

[Surrogates only)Spine

Added fig/i')

Oo

/eV

/c-r

/$3

/oo

'oo

"*Recovery

77

3S

93

A-'

^

?i

COMPOUND

1,2,3,4-TCDD

Fraction

TCDD

ConcentrationTotal (ug/.M

5,/

(Surrogates only)SpUe

Added (uq )

25

%Recovery

c20

LIST OF COMMONLY USED FOOTNOTES FOR EPA

II Indistinguishable Isomers.I .Presence Indicated by extracted 1on current profile; definitive spectra not

obtainable due to Interference.Q Quantltated from secondary 1on.CI Concentration estimated; Interferences present with primary quantitatlon

Ions.D Sample analysis using a ____ dilution.SE Sample extract could not be concentrated to 1.0 ml, tnus the detection

limits are higher than normal.

DL Detection limits are adjusted to show change 1n sample quantity processed.The surrogate recoveries are not available.

SR Surrogate recoveries are not available because it was necessary to dilutethe extract, based on GC screening results.

SC Suspected laboratory contaminant.LT Less than the specified detection limit but greater than one half of the

detection limit (present but BDL).

EV Estimated value, Tnis footnote 1s used when estimating a concentrationfor a tentatively identified compound.

H Volatile vial received with headspace.SV Amount corrected for sample volume.

DC Compound calculated from a ____ dilution.CR Compound calculated using total RIC area. All secondary Ions saturated.PC Pesticide or PCB confirmed by GC/MS.

PN Pesticide or PCB cannot be confirmed by GC/MS.U Compound analyzed for but not detected. The number 1s the minimum detection

limit.BDL Below Detection Limit

0192G4ao

DATA REPORTING QUALIFIERS

The attached list of footnotes 1s used by Mead CompuChem to qualify dataresults. This list incorporates and/or supersedes footnotes suggested inEPA contracts. Explicit definitions of the footnotes are also provided.As specified contractually-and alao^ enforced "by {nttrrti peril-mini, notationsor changes to data values are initialled by the CompuChem employee makingand/or approving the change.

To eliminate any confusion between footnotes and initials, the followingprocedure Is employed:

1. Footnotes are indicated to the left of the data value,

2. Initials are Indicated to the right of the data value.

3. Initials are circled.For example:

ug/l ,. (87V) 79-01-6 Tricloroethylene .......... "SU. U

r fFootnote value initial

The reported value of 1000 ug/l trkhloroetnylene has been calculated from asecondary Ion (as Indicated by Footnote Q). This notation has been initialledby a CompuChem employee with initials KH.

20

CRGANICS ANALYSIS bATA SHEET - P»ga 4

Ub NM: MEADJOMPUCHEH

QC REPCBT NO! ____

B. TENTATIVELY IDENTIFIED COMPOUNDS

12

3

4

5

6

7

6

9

10

11

121514

'15

16

17

16

19

20

21

22

23

24

252627

26

29

30

CAS 1 COMPOUND NWE

Oklfc

FRACTIONI MAXIMUM SCORE AHA 1 NEDMASS MATCHING ROUTINES

(SPECIFY)

.

30

LOW Lim LIQUID

M6E I •! 1

r y*tf NO, ~HINM. NO, PA NO. pc MPOIK HOII44Q- I 4 fo olMtOCIATD MNU Ktti - o CUE MOi

CRIB CC n« (TOED•M CHI_____COMPOUMIS • _________lAHPLt KSULT5 WffLt HE5UIT5 ua/l I KEOYiHT

( TV) IOT-02-t ieroUIn

( 3V) r!07-»-l _ «crylotiltrHi______( 4V) TM3-7 t«nnnt__________( 6V) 86-ti-i cirtxin •tttrieMefldt,

( TV) IOi-90-7novi . ioT-ot-7 _111V) 71-55-t 1.l,1.tTlctilcrorttmn»

(13V) 75-34-3 1,lHll.hlofo-1him(14V) 7VOO-8 _1.1T..tMdiloro.ttiint .(HV1 Tt-34-i l.l.?,2-t-tr».More«thii)i

(16V) r7>-00-3 ctiloro«tMnt________(»V) tlO-7M 2-ch(oroithYl»lnyl rttur

I »V> »7-M-i . cMoretonn____ _1.tp<leliloroiTMiw_____

130V1 Dt-tO-5 l.;.triniH)lcMorortn«ti«

(STY) Tt-e7.i l.frfleMoroorooini _(53 VI 10061.02-t trini-1.V<lcMerMrot>»ni

10061-01-08

r:' f •• i**im "*'~w*ini92o<30

HWCi"gifw«.i~». cwsiwi n. PA NO. A «c KWKT NBI i.;.-; ff ;AS! -"MB) IWW NCUl H C| _ | a, (ME NO I':''I (____II^O i I/H'/ j-' "'-3

"'" /*< *1 S i IHHY

! SMfU WSUITS OKI8. MM1.. KSULTS MLATIVtKg/1________.__M/I OlFFPIEHCE

cm ^4"~ "O__ K firytfp/" ^ — — •2— '—

0

n *• v " •• .,U.*..;;«.019263

BASE-NEUTRAL & ACID MATRIX SPIKE

Low liquid SampleslilL .ML. -i- LabNa^d^puchem"DC 5«*lo No. Original No. EPA No. QC ReportAssociated——— ' \> llWV Case No.

(22A) 59-50-7 p-chloro-m-cresol(24A) 95-57-8 2-chlorophenol(5BA) 100-02-7 4-nitrophenol(64A) 87-36-5 pentachlorophenol

(65A) 10B-95-2 phenol( IB) 83-32-9 acenaphthene( BB) 120-82-1 1,2,4-trichlorobenzene,(27B) 106-46-7 1,4-d1ch1orobenzene(356) 121-14-2 2,4-dinitrotoluene

(63B) 621-64-7(6BB) 84-74-2 d1-n-butyl phthalate(69B) 117-84-0 di-n-octyl phthalate

(768) 318-01-9 chrysene

(84B) 129-00-0 pyrene

r -, ••• r ,-• •»U i, Jt.... >.; i,.'

30

12IjC Sample No. Or1g. No. EPA No, QC Report No.Associated Samples M5j_Il L_ Case No.

PPi Compounds QC Sample Results Original Sample Results Relative IDifference

'/j 0

2-fluorophenol ___

pentafluorophenol __________ _________nil G Adg-nltrobenzene ____I ~____ ___~ U ____ ____

2-fluorobiphenyl ____X <A _ tyty_____ [ J2-fluoroanil1ne ____fl &___ ___2-2_______ _ Indecafluorobiphenyl _____ /(/? ___M )_____ j J

(22A) p-chloro-m-cresol ____!?....*T ____c Q>____ *H '(24A) 2-chlorophenol ____§^ I |Q____ .^ k(5BA) 4-n1trophenol ___(64A) pentachlorophenol ___(65A) phenol -^3 ____ ____L.;_____ ^P( IB) acenaphthene ?^>____ j I L)____ . •v I( BB) 1,2,4-trichlorobenzene 2C____ I 60____ " -(27B) 1,4-dichlorobenzene ^(p____ f 10____ __ J,

/ d OA ° 0(35B) 2,4-d1n1trotoluene ____LO____ &U_____ fr*-.(63B) N-n1trosodi-n-propylam1ne

(6BBl d1-n-buty1 phthalate A fc(69B) d1-n-octyl phthalate Q^ I 0. 0 ____ . ?~\(76B) chrysene 07;(84B)Pyrene 7%

C". v '•," I« A -. .) 'J

Low Level Liquid Xt»i IHMEI*'« corucxp*gciwwr NOT rtiZ-'~

wM.'sw«va*

Low Level Liquid

HIS mas"-1

f/SMlng • »IS"*I »ort">n>ri.1:'.-"-""-"•

r> - < f ' " - '0 ;,' x •/ . u019272

" ^ - .TJl.n mic———""JO

10B-<b-3 ~jTr_-u-.- "——~"—~TF

Lab Name; HeadJompuChem*____ Case No; _Lab Sample l.D. No. vs, -3/. Instrument BlankQC Report No:___________

A. SURROGATE SPIKE RESULTS

COMPOUNDD4 l.2-D1chloroethaneD8-Tol uene

FRACTIONVOAVOA

CONUug/l),3 aa>

(SurrogatesAddelnug/l)

20.020.0

OnlyJRecoveryno10 r

FORM 1 (continued) Data Reporting QualifiersFor reporting results to EPA, the following results qualifiers are used.Additional flags or footnotes explaining results are encouraged. Definition ofsuch flags must be explicit, however.(a) Value - If the result 1s a value greater than or equal to the detection

limit, report the value.(b) U - Indicates compound was analyzed for but not detected. Report the

minimum detection limit value with the U, e.g., 10U. The foot-note should read: U-compound was analyzed but not detected. Thenumber 1s the minimum detection limit.

(c) X - If the mass spectral data indicate the presence of a compoundthat meets the Identification criteria but the quantitativeresults 1s less than the specified detection limit out greaterthan zero, report the detection limit as K, e.g., 10K. The foot-note should read: K-Actual value, within the limitations of thismethod, 1s less than the value given.

(d) J - Indicates as estimated value which 1s used when estimating a con-centration for tentatively Identified compounds, e.g., 120QJ.The footnote should read: J - Estimated value.

(e) Other - Other specific flags and footnotes may be required to properlydefine the results. If used, they must be fully described in apage attached to the data summary report,

(f) " - This flag applies to pesticides parameters where the Iden-tification has been performed using two column confirmation (asspecified 1n Method 608) but the level 1s too low for verlfka- .tion of the compound by mass spectrometry. c oi'; r.ii

sc

Lib Nwe: Case No. 'L-?',Lab Sample l.D. No. fjr£&3Z,• Instrument BlankQC Report No.:__________

6. TENTATIVELY IDENTIFIED COMPOUNDS

f123456789101112131415161718192021222324252627262930

CAS * COMPOUND NAME '

IV&tv

m-BNBNBN 'BNBNBNBNBNBNBNACIDACIDACIDACIDACIDACIDACIDACIDACIDACIDVOAVOAVOAVOAVOAVOAVOAVOAVOAVOA

Pur. Est.cone.

30

QUALITY ASSURANCE NOTICE

. The volatile analysis of blank V.*;y --aWH _ -hows thepresence of the laboratory artifact illoxane it lean /, ;; .This compound Is routinely observed is in Instrument contaminantind nay or may not actually be present 1n this sample. SHoxanehas not been listed as one of the non-priority pollutant compoundsIdentified 1n this sample.

'" ^"^ 7 yTV

Quality Assurance Antftyst

v *"* l*ff'»" '','

Ol-27°

/;;v !

(Non-frlrlTy follirttnt Mnrtoui SuDitincti)

01927V

OR6AN1CS ANALYSIS DATA SHEET - Page 3

tib Harf-_ *"" CanpuChem_

A. SURROGATE SPUE RESULTS

Ptntafluorophenol

D6-Phenol

D5-Nltrobenzene

Decafloroblphenyl

2-Fluorob1phenyl

2-Fluoroan111ne

019272-

30

1 I

QUALITY ASSURANCE NOTICE

This sample has low recovery for pentafluorophenol. The recoveryOf the surrogate pentafluorophenol periodically dips below laboratorycontrol limits. This phenomenon 1i under Investigation. Since theother add surrogate exhibits normal recovery, the sample results havebten reported without any additional analyses.

(.A* <-.'Quality Assurance Analyst

019280

..." ," '•'•.• *\

UboritoTY *"" Jff

PI OX INS

EE5TICIOE5

-• CASI •>"

01928190

v..J

ORSAN1CS AMALtSIS DATA SHEET

Lib u"i

**'• »••• "-isranr- hloe1tttd s Jffffi

A, SURROGATE SPIKE RESULTS

019282

TOO (PU-WCHSU NAZAWOUS MASTC)

WE JZOj »2{

I. life if Ion fnuniltj K/E JM t* J22 Mtchttto -rtttitn IK If Standard Ami/Hi (n»Tsve-TM» nyti PH M

"" "

3. RiUntf en tfH of pf it Nifiu /or•iietljr thit if WE K2 7±>6*A r yti |— Ino

,4. Kpll te MlM OP Cfiwr, 1 . >ri>.iT; X •

I. Pircunt (Ueeinry Cilculitlin

A. Mount 1,1,1,4 TWO (H/ui) found (n tuplo Mtitf on irti ofud irtttrnil iundir< cileuiitfon to .33*. w '»c-aA\yi 5"sT/

I. PfMl iwpll

C. Spfkl 1ml 1,1,1,4-TDO: 11,000

• A I I6

I. UC frttnrttjr of ft«et|mmd of tuplo«I ttHi Plm |~1 MtM wirigi lickmnd if four point eiWritlH •—••" ---

x !

01928

'ROCEDURE; RH DIAGNOSTIC REPORT 5/03/83 8: 52 •"£•ATA FILE: CR001490A12.EFERENCE; IFBS

METHOD: IFBS INITIALIZATION OPTION. 2 PROCESSING OPTION: 3/•-PORT: IFBSS1

t —— STANDARDS ——— :>< —— PLUS UNKNOWNS —— X - LIST NAMES - >PROC USED POSS RMS PROC USED POSS RMS STANDARD/UNKNOWN

2 2 1 0 22 '6 1 63 IFBSS1/IFBSU12 2 1 0 23 7 1 IU IFBSS2/IFBSU2

43 COMPOUNDS PROCESSED, 4.3 FOUND

: COMPOUND X —————————— SEARCH —————————— X SAT X ————— CHRO ————— :NO LIB ENTRY REF PRED SEL DELTA PEAKS FIT PEAKS IVE TOP DELTA PEA> L1 VJ I 164 IB! 181 . i 979 130 1E1 . 12 VM 2 237 233 233 . 1 1000 . 67 233 . 13 VJ 2 31 35 . . . . 504 VJ 3 59 62 . . . . 62S VJ 4 77 79 . . . . 646 V J 5 4 7 5 1 . . . . . 9 4 . .7 VJ 6 130 130 . . . . 56B VJ 7 144 143 . . . 539 VK 1 184 1S2 181 -1 1 9B3 . 130 IB! . 110 VK 2 118 119 119 . i 996 B4 119 111 VK 3 158 157 157 . 1 999 101 157 112 VK 4 173 171 . . . 9613 VK 5 199 196 . . , . 6514 VK 6 213 209 . . . 9615 VK 7 223 221 221 . 1 997 83 221 . I16 VK ' B 240 235 . . . . .621'i ;VK , 9 26S 259 . . . . .97 259 . 1I S V K 1 0 2 7 3 2 6 6 . . . . 1 1 7 . .19 VK 11 283 276 . . . . 12720 VN 2 130 130 . . . . 582 1 V N 3 2 3 9 234. . . . . . 7 2 .2 2 V N 6 1 4 B 1 4 7 . . . . . 7 6 . . .23 VL i 331 324 324 . i 996 84 324 . 134 VM 3 450 449 449 . 1 996 100 449 . i2 S V L 2 3 0 7 2 9 8 . . . . . 6 5 .26 VL 3 313 304 . . . 7527 VL 4 324 316 . . . . 13028 VL 5 333 326 324 -2 1 992 . 7829 VL 6 338 321 . . . 7530 VL 7 338 331 . . . . 9731 VL 8 336 329 . . . . 12732 VL 9 3B6 382 . . . . . 17333 VL 10 429 428 429 1 i 997 . 164 428 -1 i34 VL 11 429 428 . . . 8333 VL 12 453 453 453 . 1 997 92 453 . 13 6 V L 1 3 4 7 6 4 7 8 . . . . . 1 1 2 . .37 VL 14 517 521 . . . . 10638 VL 15 357 351 . . . . 6339 VM 1 331 324 324 . i 996 . 84 324 . 140 VN 1 331 324 324 , 1 996 84 324 . 141 VN 4 394 390 . , . . 5842 VN 5 423 421 . , . . 584r VN 7 276 265 . . . . 4344' VN 8 603 612 . . . . 104 . p.- - . ..45 VN 9 631 642 . . . . . 106 . by'-v. v/J

019283

\. )

3UANTITATION REPORT FILE: CR001490A12

DATA: CR301490A12. TI35/03/B3 8:18.00.AI"- E: 25 ML SAMPLE (11490 * 5 UL B635&B637 ON tt!23U&,,._TTED BY tU2 ANALYST: 633

WOUNT=AREA # REF. AMNT/(REF. AREA)» RESP. FACT)ESP. FAC. FROM LIBRARY ENTRY

NO NAMEi *BROMOCHLOROMETHANE (INTERNAL STANDARD)2 CHLOROMETHANE3 VINYL CHLORIDE4 CHLOROETHANE5• BROMOMETHANE6 ACROLEIN7 ACRYLONITRILEB #BROMOCHLOROMETHANE (INTERNAL STANDARD)9 METHYLENE CHLORIDE10 TRICHLOROFLUOROMETHANE11 i, i-DICHLQROETHYLENE12 1, i-DICHLOROETHANE13 TRANS-1,2-DICHLOROETHYLENE14 CHLOROFORMIS 1, 2-DICHLOROETHANE16 1, 1, 1-TRICHLOROETHANE17 CARBON TETRACHLORIDEIB BROMODICHLOROMETHANE19 *D6 BENZENE (INTERNAL STANDARD)ar 1, 2-DICHLOROPROPANE21 'TRANS-L S-DICHLOROPROPENE25 TRICHLOROETHYLENE23 BENZENE24 CIS-1, 3-DICHLOROPROPENE2S 1, 1« a-TRICHLOROETHANE36 DIBROMOCHLOROMETHANE37 BROMOFORM38 1, 1, 2, a-TETRACHLOROETHYLENE39 1, 1, a, a-TETRACHLOROETHANE30 TOLUENE31 CHLOROBENZENE32 ETHYLBENZENE33 2-CHLOROETHYL VINYL ETHER34 *D6 BENZENE (INTERNAL STANDARD)35 *D4 1,2-DICHLOROETHANE (SURROGATE)36 ttD8 TOLUENE (SURROGATE)37 *D6 BENZENE (INTERNAL STANDARD)3B ACETONE (2-PROPANONE)39 2-BUTANONE40 4-METHYL-a-PENTANOME41 2-HEXANONE42 CARBON DISULFIDE43 VINYL ACETATE44 STYRENE45 0-XYLENE

Nt J1/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT .TOT,- . ,,bj».,w.tC

3fl 019S83

NO ,'1/E SCAN TIME REF RRT METH AREMHCHT) AMOUNT '/.TOT:. :TJ 131 9:ia i i. ooo ABB 13698. 4. ooo UG/L 11.17 |2 NOT FOUND }•': ""'MOT FOUND4 NOT FOUND5 NOT FOUND |6 NOT FOUND [1 NOT FOUND8 130 1B1 9:12 8 1.000 A BE 1369B. 4.000 UG/L 11.479 84 <32_pl 6' 03 S 0. 6S7 A BB 9559. 2. 29S UG/Lw*r6. 5B10 101 ( EA 7:59 8 0,867 ABB 66571. 3. 783 UG/L(A«0, B511 NOT Fowe- <l12 NOT FOUND13 NOT FOUND14 83 ( 2011:14 8 1.221 ABB 6743. 0. 474 UC/L y.lT36IS NOT FOURu (J16 97 258 13:07 8 1.425 ABE 5S4. 0. 042 UC/L 0.1217 NOT FOUND18 NOT FOUND19 84 324 16:28 19 1.000 A BB 79963. 4.000 UC/L 11.47 i20 NOT FOUND |21 NOT FOUND i22 NOT FOUND '23 NOT FOUND '•24 NOT FOUND ; .25 NOT FOUND26 NOT FOUND i27 NOT FOUND ' i2B 164 43B 31:45 19 1,331 ABB 748. 0. 069 UG/L 0.20a". 'MU1 FOUND L30 ' 92 453 23:02 19 1.398 ABB 1390. 0. 132 UC/L 0. 3831 NOT FOUND ' i32 NOT FOUND |V33 NOT FOUND j34 84 324 16:28 34 1.000 ABB 79963. 4. 000 UC/L 11.4735 67 233 11:51 34 0.719 ABB 11507. 3. 829 UC/L 10.9836 100 449 32:49 34 i. 386 A BB 60586. 4. 395 UG/L 13. 3237 84 324 16:28 37 1,800 ABB 79963. 4. 000 UC/L 11.4738 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND i44 NOT FOUND L.45 NOT FOUND

NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R.FAC R. FAC(L) RATIO1 9' 21 0. 98 1. 000 1. 00 4. 00 4. 00 1. 000 i. 000 1. 00 ;•R 1 • 35 0, 168 16. 00 1. 368 i3 3: 00 0. 321 16. 00 1. 573 ;4 3: S5 0. 418 16. 00 8. 9335 2; 23 0. 255 16, 00 2. 002 :6 6: 36 0. 707 1S9. 99 0. 035 ;7 7:19 0.783 139.99 8.054S 9: 21 0. 98 1. 000 1. 00 4. 00 4. 00 1. 000 1. 000 1, 00 :S ....-' 6: 00 1. 01 0. 641 1. 03 2. 29 16. 00 0, 174 1. 217 0. 1<T." " f • I

U \Lfn4\i •!.' I019 87"

1

11 8:48 0. 940 16. 00 1. 37912--VO: 07 1. OB2 . 16.00 0.83713 j.0:50 1. 158 16. 00 1. 03814 11:26 0.98 1.223 1,00 0.47 16.00 0.123 4.151 0.0315 12:12 1, 304 16. 00 1. 6B516 13:2B 0. 97 i. 440 0. 99 0. 04 16. 00 0. 010 3. B43 0. 0017 13:50 1,478 16.00 4.691IB 14:23 i. 538 16. 00 0. 26419 16:46 0.98 1.000 1.00 4.00 4.00 -1.000 1.000 1,0020 15:36 0.930 16.00 0.07921 15:55 0.948 16.00 0.37523 16:28 0.982 16.00 0.45223 16:56 1.009 16.00 0.63024 17:11 1.024 16.00 0.16425 17:11 1.024 16.00 0.16126 17:05 1.018 16.00 0.24127 19:37 1. 170 16. 00 0. 12428 21:48 1.00 1.300 1,02 0.07 16.00 0.002 0.542 0.0029 31:48 1.300 16.00 0.12330 33:02 i. 00 1. 373 1. 02 0. 13 16. 00 0. 004 0. 537 0. 0131 34:12 1.442 • 16.00 0.83532 26:17 1.567 16.00 037433 18:09 1.082 16.00 0.06234 16:46 0. 98 1. 000 1, 00 4. 00 4. 00 1. 000 1. 000 1. 0035 12:06 0.93 0.721 1.00 3.83 4.00 0.144 0.150 0.9636 23:53 1. 00 1. 364 1, 02 4. 30 4, 00 0. 758 0. 706 1. 0737 16:46 0. 98 i. 000 1. 00 4. 00 4. 00 1. 000 1. 000 1. 0038 ,6:36 0,394 120.00 0.00339 12:06 0.721 120.00 0.00440 20:02 1.194 120.00 0.03341 21:30 1.382 120.00 0. 01842 7:31 0. 448 . 16. 00 0. 80S43 14:02 0. S36 16.00 0.17444 30:42 1.830 16.00 0.72345 32:08 1,915 16.00 0.488

... A;'

COMPUCHEM NO.______ DATE

IDENTIFIER VQA - LOH LEVEL LIQUID

-\ COMPOUND LIST - NO. ___ (Page One of Two) j-

COMPUCHEM !COMPOUND qUANT.REPORT CORRECTION DETECTION !-

COUNTER t NUMBER, L COMPOUND NAME _____ VALUE x FACTOR « RESULT LIMIT (ug/V :2. 221 CHLOROMETHANE ............. ____ I ___ •&-/3, 231 VINYL CHLORIDE ............ ____ ____ ___ -5-14. 209 CHLOROETHANE .............. ____ ____ ___ -5-15. 220 BROMOMETHANE .............. ____ ____ ___ 5-'6. 201 ACROLEIN .................. ____ ____ ___ W6-2O7. 202 ACRYLON1TRILE ............. ____ , ____ ___ mr^o .,8. 222 METHYLENE CHLORIDE ........ ft •$ _____ __A4 &- I '.9. 230 TRICHLOROFLUOROHETHANE .... .,? ____ 3-fr -5- I i10. 216 1,1-DICHLOROETHYLENE ...... ____ ____ ___ -6- I11. 214 1,1-DICHLOROETHANE ........ ____ ____ ___ *- I j12. 226 TRANS-1, 2-DICHLOROETHYLENE ____ ____ __ * I |.13. 211 CHLOROFORM ................ o.f ____ Tffl -5- ' j-14. 215 1, 2-DICHLOROETHANE ........ ____ ____ ___ *- I j15. 227 1,1,1-TRICHLOROETHANE ..... ____ ____ ___ -5- ' j

1 '16. 206 CARBON TETRACHLORIDE ...... ____ ____ ___ ** '• |17. 212 BROMODI CHLOROMETHANE ...... ____ ____ ___ *• I jIB. 217 1, 2-DICHLOROPROPANE ....... ____ ____ ___ . -5- I )_19. 250 TRANS-1, 3-D1CHLOROPROPENE . ____ ____ ___ -5- I20. 229 TRICHLOROETHYLENE ......... ____ ____ ___ -6" I !21. 203 BENZENE ................... ____ ____ ___ *- I22. 218 C1S-1.3-D1CHLOROPROPENE ... ____ ____ ___ W- 223. 228 1,1,2-TRICHLOROETHANE ..... ____ ____ ___ -6- 1 :24. 208 DIBROMOCHLOROMETHANE ...... ____ ____ ___ -6- I ;25. 205 BROMOFORM ................. ____ ____ ___ -S- I ;26. 224 1,1,2,2-TETRACHLOROETHYLENE ____ ____ ___ -6- I j,27. 223 1,1,2,2-TETRACHLOROETHANE . ____ ____ ___ -6- ' \28. '225 TOLUENE ................... ____ ____ ___ •*•29. 207 CHLOROBENZENE30. 219 ETHYLBENZENE .............31. 210 2-CHLOROETHYL VINYL ETHER34. 252 ACETONE (2-PROPANE) ......

PIEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OP THE COWOUTO'LIST! I

30

ICOMPUCHEM NO.______ DATE

IDENTIFIER VOA - LOW LEVEL LIQUID

COMPOUND LIST - NO. ___ (Page Two of Two)COMPUCHEMCOMPOUND QUANT.REPORT CORRECTION DETECTION

COUNTER NUMBER COMPOUND NAME_____ VALUE x FACTOR - RESULT LIMIT (ug/1)39. 253 2-BUTANONE ................ ____ _ ..!.... 8 4W to40. 256 4-METHYL-2-PENTANONE ...... ____ ____41. 255 2-HEXANONE ................ ____ ____42. 254 CARBON DISULFIDE .......... ____ ____43. 257 VINYL ACETATE ............. ____ ____44. 251 STYRENE ................... ____ ____45. 239 o-XYLENE .................. ____ ___

Correction Factor Calculation:(Use ONLY If factor affects all data, otherwise use correct calculation sheet.)

6-1•s-l

,,. 0192'Ot)•id

3m

•s

£,-

a-

-

! f

3-

8-

Jo 'ill —-ij? u> G« pCH ** C< C«1 . . . . .1 . . . . . . 1 . . , . !

•

HI I...MIIII III, !•

"

•

&nl?!iO i.,;. m10 10f- '.n

I/I .» Id3 " 3t-» r i m

W '/i '"i 5Jg|8|'" m

——— E".8"+ijiF'»>T|i.,;i

| 1

* i§ %2 S'••' H

i1H

n

C(H*4<U'lCiIiK>Mi[•-:;r-'.'

W^

?'lmT———————————————————— .amS"Si\ CO

Ul—

' ' ' ' 1 ' ' ' ' 1 . . . . . . . . , AMiTl <AI

V !

/ i+

r. s if: 'S I:m • • • uiTl . "• O C1, , ! , , , , 1 , , , , 1

£ -'"•'

n~

(Ti -( 1

1 .

a-

-

IAI -

""

_ ___ lt

—._ —

----- "-—-----

——

—

-

w

-

rn u'l2; rt

ni"~* ^ r i,-_. i n

h— 01

tjISCrm

-_ **

S

FCOiTi

'1•I"jO

W

F3

-

gi G'.;'-'-'->i0 wOil r->?!l ?' r\1

S|

lit,i.l I,M •

!::"4ii-mW ' ,'

'" »+ ""Ijl

r

,",a2r.KS

g„0

1

1

oi1 V" m \

wm ^-,1 .. Xy c/\ •

•~ , Li~* 4* fcJi.,1 1 X,

"W iQOQ7"

ss-1

\i

H*tn c« 4* ijjiG' C' ">J •*•

1 , , , , 1 . 1

,_- .,«.-,

• "•

• •••- -1- "-"••"

-

-

—

^

'•

-

mil' •• -.

.

m 1/1iS62S?o

— Hjr

ro 2" m

1

en

ilrj

?1

o

ro

~

iE, gV§Q r™w i'•"!:?!ffsflTT T

&'g.

i

1i

B

a1x>nis

1pM

3*t-*".J

"rft

i;v rnw\ S\

O

1I 15sX). ir\

"--'•-,."1 n -§'G\i^'^'' oilP 019293

I I

Iftliilil

L

30

V I

MEAD COMPUCHEM '1ASS UIST DATA: BFB38503C12 * 172 BASE M/E: 9515/03/83 3:1.1: 00 + 6:45 RIC: 371S0.SAMPLE: 2 UL BFB B676 I«172 - <»30 XI, 00 !''

0. 80 MINIMA MIN INTEN: 0. MAX INTEN: 720B.0 MAXIMA

MASS 55 RA MASS 7. RA869 * 0 MAXIMA '

37 . 7. 82 269 0, 753B 6. 4439 4, 164B 6. 8349 5, 8550 24, 0B51 5, 4B52 1, 0453 0, 7255 0, 3256 0, 4457 5, 3658 0. 2461 4, 4562 6. 0963 3, 1467 1, 2168 11, 0769 6, 2370 i. 6271 1, 23

( 1 13, 60,4 25, 6175 43, 7876 6, 7079 5, 3180 1, 28Bl 7. 1383 0, B387 1, 6088 1, 4091 1, 4092 3, 2393 7, 1494 10, 5795 100, 0096 5. 7697 i. 79

ill 0. 75119 0. 79141 1. 11147 1. 00174 78. 14175 5. 56176 76. 91177 6. 55193 1. 39P<V7 0.17 k'>''~t. i., ()

268 2. 09019293

3

r* IT««28ui en +

«

Lrim

01929'?

k» ••1 Hn 4r HIX "'

""•\

*l A

r*w

.• cH r. i

*«

1 |» J

t •»»> rj! i13

•1M

O

I. » l< h. . .i n i i iCM** •* T*i a •» » r£ .'ir i' ».o c c o? in ii' M ''in IM S !•» -i

u ora u <*• •• ro i r

Ta

-• a a *.•i o c "r ii m IM

5 Mi 1o S -ii* ••• fT

r* 2 3in r.n£nb.HIHS

•1

u

r&um•tX•\p

z

rj i », Ii

1C* 1

U C i v«>l « JO 1* W M Ux n M*j j. i ia r ix n a1 rn Q

M X Ap- 2 -gn •*

("

ff

i" >, ii *•»!•*• * _.», » » * . • • n i* r a • • i"N r- C i I en * 1 Q I 1 i n _ C * O _ C O ' * lHI a w o r o M w ii-ioiji'*'"'™"*11'*''1- ,L -• i • * i n 11 H 1 1 n MI i-. 2 ^» n> r•; * 3 O - 1 i i 2 i a 2 X X u Z M 5 m - i x nc wi r .. .it w r fl bi r* r \. » •* A x r ir»io.n-*no'-:iooTi K o t» c r-i u .*. cj ,u a A, w ** o f* n •-. i.i^kj3 M O X M r O wOOCir M O I M H«- n g c. n (j ii n 1.1 m u r •" o . • » >r'iDain-« «iiBO m «o.- r u c. r u i r j i o «i '«c o y i o m » o * •« i MO • (• i^ T n< omTiHT)J II •? U •< 1 jj A»J - n ? -i P' Mi! -' i S•< rr -n

I I I QU« 1 b Wti • f (•• nr 4 •« r. ri: a ir '"IM n i" «.:i

..:

4-cTSir0JOi:X

J.M

-.

i

». I

gT

?.

i >4 •• •"• 1 >J f

i,j tii 1 1 1 1 1,1. , i ci «'i o o n T .1 o n o ;i c< tj an n n '.• ;•> n a jo o >3 i n 0.3 n laoo

j rs -3 o oo o o ii .) n ci .s n i o o n >*i nn .1 -) o o -T ••• o wj n o n c >'• «n .3 o o -.TMta.t WbWWWlWwAklMk.k.w<JtaW.I

n 'U *. r» M 'i «J m »« N O */i f M •« H •* O O C*' •!.-., ..1 li U • H -*• W * O *•» 1 . .!> ft, . rf

) 9 .> *

— N f ^1 «•» N "* W WWINtrtki .1 * •* 1? *J *< N« •KNNviN.M''_',*>U>ONQO«>l**0'>'«n'

u u j , i f i c. 'i a o a c. o o o c. a in a n o c .*) .•• a c a n a i-j o a o o ui o o 6 o o oo o .'* t. ft c n a u a o .•_ o a o c, o a o o c c o o a o .-? i o o o n a a o o a a o

N-«-«f. f^ •*

Ofv-tMO>rt)«QWwl 4}NWtMiK-*O*»'.>iQ<?t

000000^000000000000000000000000000000000i i i • i * i . i i * * * i * « i * * . * i * « i i i * * i . i i . . i . i • iooautjQoaQoaoaooaoaaaQOQoaooi'aoQaaooaQoooo

i '

!

1 1 i 1 [. 1 1 1 1 1 ( 1 1 1 *«-•)(! 1 •« 1 1 1 | 1• • t t t • . i . . « . i t i . * « . . f

*>QL<>* «j«<*4oga«-iaQ^i<-io->iNwiMi

1 1 i^ 1*« « • « • • > « . . . . . . . I * ! *

3 3 .-1 f .' ' *) Co .*i - 1 ,r • -, .1

C w U « u

nii

C • • i • .' N NH N N 'S !•• >A

nj P. n. f> l»

n o n h rt '.hJ M W »J »-*

QT)

o a o i* *»

O fw (\J -w rw (N<o o a oa an o o oa o

Q O W a O

Tl

Wl W) Ul N Njq .ci wi in tst inn n is in 11 M-1 U U U f O* o * <j <i

ona o '• nit •*" r* ,,n • i pJS j ^S3 'M I

1a.n.-

• ri > M i03 ii io -.1 r

r-• c

j« r»• r •

T -3 H

0 *"

n u

b «

/*n u.0a •*n a

T

T O

» *•»

W

_ _ .01« .. u a i na r i w O C i ^ o w M M r nmra m r p n P i o> Hi u •* n AI —111 *i »• n n c* »2 ** rti n •£•.*•; j. i i •l r n M jg r *i*tO-i»IOZlt o A (w n a c w r t- MI w r- i« i» r rr** n n M i i i n n n n o c i o«j Lin iuyiujQi'1 o^i . __..n f irx xMoa^ro wooc r MITIM* - " • • • •

</« * i ' t r« HI M 'f t,. •* w ~* v f* O <» A r •*• ** Tj A M« J w1 ^ w *»f O N N i»i N *^ •* I

. O n a N M *4 M b

-«•« 0 .4*4 i _«^ ^ ni -> i t -« I I - * -»"

i n>* tit r? c? i n « ^

V 1

n 1B fP

JO

3

.

C

i r. i•_ n cC *ii U t

") PI•i « (

O1*£

l l > l 1 - J C » m A, « »• fi XI * * i »i ft « * 1 » » * q i' «,w tf t' a r r-rf-iu —t,'*M*,Kcr*j«**i-p"«^«-iM-»ij-« x t o e < n x ». i "• n a- i i m * t o i i i rt z -3n r it o i*> ii z1 * n*n i * a r* i •«• "< ci -C i N - c H M M r - p pr i •: .. • . * i'i r. I k.j -< i • *• -3 •• »'• •! * -i n *. o n «LI n jC n P« ft £ in i r* c n i AI « 2 t < o i A T r< r, 2 7 "i s pi 1 M |f» II f « »I M U * Mb O • 1 P 1 1 «' il' M P r fc' P P Q M t.SP?*Hivrii rn U ip>» >niO£)C*inQXIOC''1 b•>. i (ii i .• i -i u L P H w '• ' *j jy -C " .-< _* ,». H P i,p •» '^ r ^3in • r i T »* c X H P O M o o c t i

tj p ii |*H i_i P •< f i 0 OPOm i i irt rn u f" <M < PX no r i -g a i w H T H H n r, iw n = >4 ' < w * > itPU t. POX r 1 1 u .) im x p p1 H «.i o no1! i o m » o M H x >• n

i;t

"

t ( < • \a o C c o i ocou.ir. Guooc. noooonrk i c* v.1 n o i» n o rj on P u _•; o o o o o o c £ o o o c

. & o c o -3 c ; ci rs c: ft u c- r u o c. c Ci ii o c o c. »•» <'i o a c c o c c .1 ra n o o t o

^* i n wi r

;--pV2'*iSJ!«.tl.'CC.;t32u-N2 1

I uI CI lU

Q19300C- •,. ~ j

vi»|.'o(..'Ji

V. i

. t, Z ». i * i n V t T i I o » .7 a i » «i. n u •. « P * * I * * »< AM- n n » I -"•*•«£/. * j; c. mu p _.PP — *»UP «•*!.: •• * i» ••• » —i. i* r- -.-««.• u « •• r »: •*^H^(Tinpe-4 -- I 5 O C » S JE C 1 I t" P = I S Bl » IOI I I P l H O X O l X• , n P L i i « « * i O n * r r i i j i n i > . » » u * h « H t r j w n p r D « * u u * < e u i « * p p - » ^ r - »n«ff . fiiPZnp-oo-nx* p-no i* rp 1*^02 i n o n r * w p p n m p Q r• ( u j n •! iii r i '* 11 « i i in i u u i ^i i< w •* n w •* fi ii i< i* ri u >> c m lit nr» pfippo e (i n S m I P J D M S I o-auHwioz7:snat'-tZ[iiHTP•. •-. .• i J *iii w c- t-» £ -» o - '* »- a o t. P n .11 MP j).« P P t, .<• i u t r ji... r Pin PJ r P H i«t N p - n n o M n - i O A j H P o t i a o - n w OKOP•v j • c, i i i i t .* f i u i- i n i u « vi *y i ~ o c n r n M > c £ j i t ii -»p u •» p ^ m K nm XPJ z M a X f r* o «oacir «mh.n, n i ft ur ''i MI u o P •« 11 -a LI n u <n rt in m u P ••) o i* *-• • 2 o « «; n i a w o p T u T E « i i -i H » o m >i> u

M 1 9 -J r- XX h O » HiPOi'PhJJ (~ t J. £ # ii. l> k i-nx P P H m Q xoa-iOnto o N •< i -i

«* -' it. M *.' i> Co n o> N N

M .4 *4 Q, C

w

MP

h

-i w r i i i f i i i t> i•% u A -c j: u i» - w. jifl *i IB ft* ni c H *•i ' i P U M > H < H C W i ^ U2* 2 fc X M £ III O f*mr M £ *4jj «.< £ P I fi•-IUCJPO l*« C O P*'1 •-' if 1 i 0 Ml HI f-1 IIIH «n m pjn. i , 2 z p, s.• C 1 I IP i- 4 in« p T» D ri *n Hi ij CiM ar o nw -1 .J OHI »• M m

>C £ 1no xA »• **"i -n x

*• pi

A P<• £" l" *J

iD fj

Pi UP Ni; nn S

X

P Mr. *r »'

1*1Q

P

P

a igaiHI

C. P •• *•1C* 1O U rj ->•"0 1 •a u -« hiw M n i2 r. M oA) rt «ixr i

HPI 0X -4 Vi» x nP S T>t *P

•C w P p.M n z in x 1^0ZP I MHID -I'-n > tc w*r

PI 1 O£ MQ

£ n qni IJ UUKB .11qOT)

w n M •<x cr »t-r e-'•' O X 1i: * iP> O 1 «IP U ll>MS n •» nSUP

H a m* n iM«X2 O t*IT m rni

f . r i •1 O 1^ AJ •*S?2SO 7P iii ba x io .«

M aM nin u-ii

rrsr^ •* M "1i i n it- a x iM M r rP p »i nX X » Kr r on.o o noaci

(• -< 1 Ma r f om in -t ni* x" Sin

« r.k At

5?P OA tJ in qh. M2 P

If*

•n

P i* X • .« «r i.o xoiP •* A« Pn r OM |,| P2 UJ H I

AJ IPO W QA Z 0M m M

a P1 bp aop. oX Cp ai- ««u m

•'i

i - ('. »•, c c ucaticouaooonaci»5uobbciti"uuu&c.cir, o c J c r! n c. c o c i. .- • • • • - • • - - - - - • - - - - - . . ...... i • i .. i i i i i i i « * « i i i ini o •«i a t*

i i « i i i i i i i i i i * i < i i i i * * i i i i * i i • i • • • •" .. ., r i_i .* N *i u rf**c.ijvift«*ii*k*i>*iM*_i-iH-i% %*;i^.»it«l»Mi'<»*.j •* it - . vi -) * t. 4 n •-. PJ o.» N w MI o o N ->ft P. a ID * M a M N ** ci M *" -' *•_, fe -.1 w -t W Wtl. .1 M «Vt-l .1 H V. W» V «l »' *. f l» *f\. •"» J .1 h »•*(•»•*. W' •• rf U. -

< « • • • * • • • • • ' • ' • L'-LL '_'..'.I. *-..'_

i cr v>' T P:*?

a (W1 Ia i

i 01930?30 ! ! ____

( i

CO C OO CO

• i i< r« *• r ••« t, f * 9 Q tili* (C £ opXn

i "i i i i t i1. M U M t' M

II 1 1 1 1 1

A Ci 01 rt f> •* •*

)

a o a a o n nao Q naci o

' iji

i1

7.'.!.- • .>. . • . i.-. : .

a 01 c o o o a a P o pxvaao oacoci fc <n a n- .0

Q a bi wi vi w vi w 1. 1 '* o ON. M i* < 4 N o o o a '. f*. rjn n n P P a tn m a iii CD IA a i» t« n »• P i* i* u '». TI -y

^ * -tt

• M i i~ii i "t i 'i i i i i i i i i i i i i i i i i i i i itiff**-** M»«|H..ti »i^»*»I> **»l*fV*|i >- I* Q D 0

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

lrtMM>Slw< "l.«MMf« MINJ.l vlfl ISMMPir.Pt fy N IN, -,

SSSSS S5S33 gX4« ii- SSSsS

no o no aaann aaaoa aoauo o oa o aoo o oa oa o oo oaoaa aaaoo o o a u o

: ; : i

1 11

'• , 30" ; V t . —— . - t • • » . ! • i'i • i ' < i . '- • • T- v ;":"• • T T

ISI_•

•HC3

0r*

M3«M

Mlf*

Q .>/1 3 I «

»]

»J '* I f

M iV • ill• 4*« M

0 «

P O *U 1 J

VI 3 O1 rf» it It

S HPi J

P* ii(l 1

i» i m csi ^H U

/J M

r* (-"* ft

r* f*-D II3

3 *••* <• *

in i H1 •> 13

VI 13 I r*n i n *3 I v•. \ *1 i i ai i *i t» i * in1 t -3• i a": §A m• Ar* H• H3 r*i* H«t* «a •

K 0! • ,3 * U* 1• I

T y ni w if» U 1 " i **0 1 C (• ' •*3 •* * 0 1

3 M hr»"S -f— i >•W «

* fc

tSl»•1rfkl

w A) .'t•* r:M n1 'C

"* 's!x 'eM••ii'u

«*-»

i

19303|'i

•' '..,.7

^

v i

IMT STD.RESP.VERIFICATION CONTROL CHART **&j.1 t , . wi I u 'teW--.'-! ffim.QBOMETHANE/'Qa-flENZBE

:'!.B'-

«»

.1-

PATE

ANALYIT

COM HE NTS

MTJVLflE-SfIJtlfE

- *.**«.

Isr&•nf

i

tf

ri

?

*cflSL

«)tv

> *®

^IfIt

rIil<\n

(HIr

ri

_....-

j . — — _j- __ ———

——— ^

•— — — ~

- •t-> - A -j--'-'-1'A> j- j- - 'Ajiy'j-'.|'-' ' ' ' 'iKHMT «•)» pumta ii S-if/W IMBI nu nmccvi

0

ffft

n\icRl

r

n(t

y•f

5•f\&ITN

r

]

<Ni;1*1oJo*

IN

cri(V

^Up

^

\

i

2«ie»^tsX

\1(Nv",

fl

(»iH

CI

r K

r<V,jF

5?

c

C

«.

' 4

1

1

IT

f-

*

ri

.»••%,ts

5»?if|5KIT

$i»si

019304: <:

«"L _.CO

G'

t.n to•» Ci —0°

• • Gi'1X1 OCS

iri o1=1 .n

1

sIc.

iiCOS

I

oiwof! -

M<5_•• ei-

urs;»Ei

Wwo

F.'enS

m(d

30

PROCEDURE:: RK DIAGNOSTIC REPORT s/06/83 i:45-iiDATA PILE: GM«iea49GCl5RErEhENCE: FSCC6

METHOD: FSCC6 INITIALIZATION OPTION: 2 PROCESSING OPTION- 3"'SPORT: FSCC6S

< —— STANDARDS ——— X —— PLUS UNKNOWNS —— >< - LIST NAMES - >PROC USED POSS RUB PROC USED POSS RMS STANDARD/UNKNOWN

4 4 1 121 79 9 1 16* FSCC6S/FSCC6U

1 Pi 1 -619 613 61S , 1 956 97 6152 F2 1 -860 B57 357 , i 996 136 3573 F3 1 -1416 1415 1416 i 1 995 . IBS 14164 F4 1 -1333 1BB3 1882 -1 1 994 . 240 1882S F i 2 -366 3 0 0 . . . . . 7 4 . .6 F i 3 -619 6 1 4 . . . . . 9 4 . .7 F i 4 -617 6 1 2 . . . . . 9 3 . .8 F i 5 -629 6 2 4 . . . . . 9 3 . .9 FI 6 -632 627 . . . . 128

10 Fi 7 -65S 647 . . . . 14611 Fi 9 -660 6S5 . . . 14612 FI 9 -637 6B3 . . . . 1461 3 F i 1 0 -636 6 E 2 . . . . . 1 0 81 4 F I 1 1 -712 7 0 8 . . . . . 1 2 1 . .15 FI 12 -70S 704 . . . . 1081 6 F i 1 3 -734 7 3 0 . . . . . 1 1 7 . .J , FI 14 -732 728 . . . . 108L Fi 13 -436 4B1 473 -3 i 9B5 . 112 47B19 FI i6 -621 616 ... . , 1B420 Fi 17 -749 745 745 . i 991 B2 74521 Fi 13 -735 731 782 1 1 996 . 334 7SS22 FI 19 -593 5B3 587 -1 i 993 , 111 58723 FI 20 -1049 1046 1043 2 i 995 . 172 104S24 F2 2 -734 730 . . , 13025 F2 3 -752 743 , . . , , 1232 6 F 2 4 -790 7 8 6 , . . . . 8 2 . .27 F2 5 -303 799 , , . . 13923 F2 6 -315 Bli , . . . 12229 F2 7 -332 823 . . . 93 . '30 F2 3 -341 837 , , . , 16231 F2 9 -354 BSO . . . , 18032 F2 10 -373 B74 , , . . 12733 F2 11 -852 848 . , . , . 105 . ,34 F2 13 -395 891 . . . . 2253 5 F 2 1 3 -965 9 6 2 . . . . . 1 0 7 , .36 F2 14 -979 976 , . . . 11537 F2 IS -1019 1016 23738 F2 16 -1041 1033 1963 9 F 2 1 7 -1062 1059 . . . . . 1 6 2 . .4 0 F 2 1 3 -1134- 1132 . . . . . 1 5 2 . .41 F2 19 -1131 1129 . . . . 163 ,4 2 F 2 2 0 -363 8 5 9 . . . . . 1 2 3 . .0 , 1 F 2 2 1 -1141 1139 . . . . . 1 6 5 p .;:••• r-,;A / F 2 S 2 -120B 1206 . . . . . 1 6 5 u.*"-v>0.145 F2 23 -1169 1167 . . , , . 1 3 8 nl> n*4 6 F 2 2 4 -1091 10B8 . . . . . 1 3 8 .01931!'47 F2 23 -1195 1193 1684 3 F 2 2 6 -1279 1277 . . . . . 1 3 3 . .49 F2 27 -1041 1033 . . . . 196 30 .

5 1 F 3 3 -1131 1179 . . . . . 1 B 4 . . .5 2 F 3 4 -1195 1193 . . . . . 1 3 9 . . .5 3 F 3 5 -12S4 1252 . . . . . 1 6 6 . .5 4 F 3 6 -1253 1256 . . . . . 2 0 4 . . .5 3 r 3 7 -12S5 1253 . . . . . 1 4 9 1255 . iSr F3 3 -1273 1276 . . . . 198S ' ^ F 3 9 -1232 1230 . . . . . 1 6 9 . . .5 8 F 3 1 0 -1342 1340 . . . . . 2 4 8 . . .5 9 F 3 1 1 -1364 1363 . . . . . 2 3 4 . . .6 0 F 3 1 2 -1420 1419 . . . . . 1 7 8 . . .6 1 F 3 1 3 -1423 1427 . . . . . 1 7 3 . . .6 2 F 3 1 4 -16S9 1629 . . . . . 2 0 2 . . .6 3 F 3 1 5 -1668 1668 . . . . . 2 0 2 . . .6 4 F 3 1 6 -1236 12B4 . . . . . 7 7 . . .6 5 F 3 1 7 -1S39 1538 . , . . . 1 4 9 1540 . i6 6 F 3 1 3 -1398. 1397 . . . . . 2 6 6 . . .6 7 F 4 2 -1830 1831 . . . . . 2 2 8 . . .6 8 F 4 3 -1337 18B3 . . . . . . 2 2 3 .6 9 F 4 4 -1334 1BB5 . . . . . 2 S 2 . .7 0 F 4 5 -1800 1B01 . . . . . 1 4 9 . . .7 1 F 4 6 -1906 1907 . . . . . 1 4 9 1906 . i7 2 F 4 7 -2003 2010 . . . . . 1 4 9 . . .73 F4 3 -1357 1853 1B47 4 F 4 9 -2127 2129 . . . . . 2 3 2 . . .7 5 F 4 1 0 -2414 2417 . . . . . 2 7 6 . . .7 6 F 4 1 1 -S422 2425 . . . . . 2 7 3 . . .7 7 F 4 1 2 -2496 2S00 , . . . . 2 7 6 . . .7 8 F 4 1 3 -2068 2073 . . . . . 2 3 2 . . .7 9 F 4 1 4 -206B 2070 . . . . . 2 5 2 . . .

019303.Uo^'./Jk

I »C1UANTITATION REPORT FILE: CH00149flC15

DATA: CH001490C15. Tl05 6/83 1:01:00SA X.E: 1UL #1490 +(3699 IS) ON (USSUBMITTED BY: #15 ANALYST: 6S9

AMQUNT=AREA * REF. AMNT/(REF. AREA)* PJiSP, FACT)RESP. FAC. FROM LINEAR FIT TO WHOLE . RL

NO NAME1 »D3-PHENQL (INTERNAL STANDARD) (624)2 N-NXTROSODIMETHYLAMINE (441)3 PHENOL (610) .4 ANILINE (473)5 BIS(2-CHLOROETHYL)ETHER (411)6 2-CHLOROPHENOL (601)7 1,3-DICHLOROBENZENE (421)8 1, 4-DXCHLCiROBENZENE (422)9 1, 2-DICHLOROBENZENE (420)

10 BENZYL ALCOHOL (474)11 BIS (2-CHL':iRCiISOPROPYL) ETHER (412)12 2-METHYLPHENOL (620)13 HEXACHLORQETHANE (436)14 4-METHYLPHENOL (622)15 2-FLUOROPHENOL (SURROGATE) (619)16 PENTAFLUOROPHENOL (SURROGATE) (623)17 DS-NITROBENZENE (SURROGATE) (447)13 DECAFLUORO&IPHENYL (SURROGATE) (470)1" i2~FLUORO ANILINE (SURROGATE) (472). > 2-FLUOROBIPHENYL (SURROGATE) (448)21 #D8-NAPHTHALENE (INTERNAL STANDARD) (460)S2 N-NITROSO-DI-N-PROPYLAMINE (442)23 NITROBENZENE (440)24 ISOPHORONE (43B)25 2-NITROPHENOL (606)26 2, 4-DJMETHYLPHENQL (603)27 BIS(2«CHLOROETHOXY)METHANE (410)2B 2, 4-D1CHLOROPHENOL (602)29 i, 2, 4-TRICHLOROBENZENE (446)30 4-CHLOROANILINE (475)31 BENZOIC ACID (623)32 .HEXACHLOROBUTADIENE (434)33 P-CHLQRO-M-CRESQL (608)34 2-METHYLNAPHTHALENE (477)33 HEXACHLOROCYCLOPENTADIENE (435)36 2, 4, 6-TRICHLOROPHENOL (611)37 2-CHLORONAPHTHALENE (416)38 ACENAPHTHYLENE (402)39 DIMETHYLPHTHALATE (425)40 NAPHTHALENE (439)41 2, 6-DINITROTOLUENE (428)42 2, 4-DINITROTOLUENE (427)43 3-NITROANILINE<479) -...nnnr.44 2-NITROANILINE(478) 01° >>»<•'45 DIBENZOFURAN (476)f 4-NITROANILINE(430) p '• -,- ~..-,

30nn

V )

C1UANTITATION REPORT FILE: GH001490C15

DATA: GH001490C15. Tl0S/36/B3 1:01:00SA' IE: iUL #1490 +(8699 IS) ON 015SUBMITTED BY: #15 ANALYST: 6S9

AMOUNT^AREA * REF, AMNT/(REF. AREA)* RESP. PACT)RESP. FAC. FROM LINEAR FIT TO WHOLE . RL

NO NAME1 *D3-PHENOL (INTERNAL STANDARD) (624)2 N-NXTROSOOIMETHYLAMINE (441)3 PHENOL (610) .4 ANILINE (473)5 BIS(2-CHLOROETHYL)ETHER (411)a 2-CHLORCiPHENOL (601)7 1, 3-DXCHLOROBENZENE (421)8 1, 4-DXCHLOROBENZENE (422)9 1, 2-DICHLOROBENZENE (420)

10 BENZYL ALCOHOL (474)ii BIS(2-CHLOROISOPROPYL)ETHER (413)12 a-METHYLPHENOL (620)13 HEXACHLOROETHANE (436)14 4-METHYLPHENOL (622)15 a-FLUQROPHENOL (SURROGATE) (619)16 PENTAFLUOROPHENOL (SURROGATE) (623)17 DS-NITROBENZENE (SURROGATE) (447>18 DECAFLUOROBIPHENYL (SURROGATE) (470)I* a-FLUOROANILINE (SURROGATE) (472). ) a-FLUOROBIPHENYL (SURROGATE) (448)SI *D8-NAPHTHALENE (INTERNAL STANDARD) (460)22 N-NXTROSC-DI-N-PROPYLAMINE (442)23 NITROBENZENE (440)24 ISOPHORONE (438)25 3-NXTROPHENOL (606)26 3, 4-DIMETHYLPHENOL (603)27 6XS(2-CHLQROETHOXY)METHANE (410)28 3, 4-DICHLOROPHENOL (602)29 i, 2, 4-TRICHLOROBENZENE (446)30 4-CHLOROANILXNE (475)31 BENZOIC ACID (623)32 .HEXACHLOROBUTADXENE (434)33 P-CHLQRO-M-CRESOL (608)34 a-METHYLNAPHTHALENE (477)35 HEXACHLCiROCYCLQPENTADXENE (433)36 a, 4, 6-TRICHLOROPHENOL (611)37 3-CHLORONAPHTHALENE (416)38 ACENAPHTHYLENE (402)39 DIMETHYLPHTHALATE (425)40 NAPHTHALENE (439)41 2, 6-DXNITRQTOLUENE (428)42 2, 4-DINITROTOLUENE (427)43 3-NXTRQANILXNE<479)44 a-NXTROANILINE(478) Q193RJ45 DIBENZOFURAN (476)f 4-NXTROANILINE(480) p •• - ,- « .,

30on

NO NAMEa.' i, 4, 5-TRICHLQROPMENOL (626)4.3 *D10-PHENANTHRENE (INTERNAL STANDARD) (467)•''"''' ACENAPHTHENE (401)Stf 2,4-DINITROPHENOL (605)51 4-NXTROPHENOL (607)52 FLUORENE (432)S3 4-CHLOROPHENYL PHENYL ETHER (417)34 DIETHYLPHTHALATE (424)35 4,6-DINITRO-O-CRESOL (604)36 DXPHENYLAMINE (N-NITROSO) (443)37 4-BROMOPHENYL PHENYL ETHER (414)38 HEXACHLOROBENZENE (433)39 PHENANTHRENE (444)60 ANTHRACENE (403)61 FLUORANTHENE (431)62 PYRENE (445)63 i, 2-DIPHENYLHYDRAZINE (AZOBENZENE) (43S)64 DX-N-BUTYLPHTHALATE 1426)65 PENTACHLOROPHENOL (609)66 *012-CHRYSENE (INTERNAL STANDARD) (459)67 BENZO(A)ANTHRACENE (405)68 CHRYSEME (413)69 3, 3'-DICHLOROBENZIDINE (423)70 BUTYLBENZYLPHTHALATE (415)71 BIS(2-ETHYLHEXYDPHTHALATE (413)72 DX-N-OCTYLPHTHALATE (429)73 BENZXDINE (404)'•'a POTOIAWRENE (406)1 ) INDENO(1. 2, 3-C, D)PYRENE (#437)'ia DXBENZO(A, H)ANTHRACENE (419)77 BENZOIC; H/DPERYLENE (408)78 BENZO(B)FLUORANTHENE (407)79 BENZO(K)FLUORANTHEME (409)

NO M/E SCAN TIME REF RRT METH AREA(HGHT) AMOUNT '/.TOT

NO M/E SCAN TIME REF RRT METH AREA(HCHT) AMOUNT V.TOT1 97 613 7:41 1 1.000 A BV 14040. 20. 000 NO 6.09'.'., NOT FOUND

^ NOT FOUND4 NOT FOUND5 NOT FOUND6 NOT FOUND7 NOT FOUND8 NOT FOUND9 NOT FOUND

10 NOT FOUND11 NOT FOUND12 NOT FOUND13 NOT FOUND14 NOT FOUND15 112 473 5:53 1 0.777 A BB ittfy tSfiSfr $?>t* •99rS3±-NC 10.2216 NOT FOUND 2( 3- / 3.?_»3-17 82 745 9:19 1 1.211 ABB 29666. 46. 764 NG 14.2518 334 732 9:46 1 1.272 ABB 1B974. 42. 807 NC 13.0419 111 537 7:20 1 0.954 A BV 38976. 49. 161 NC 14.9820 172 1043 13:06 1 1.784 A BV 59SS2. 55. 1B7 NC 16. Si21 136 857 10:43 21 1,000 A BV 44433. 20. 000 NC i. 0922 NOT FOUND23 NOT FOUND24 NOT FOUND25 NOT FOUND26 NOT FOUND27 NOT FOUND2* NOT FOUND;' 1 NOT FOUND30 NOT FOUND31 NOT FOUND32 NOT FOUND33 NOT FOUND34 NOT FOUND35 NOT FOUND36 NOT FOUND37 NOT FOUND38 NOT FOUND39 NOT FOUND40 NOT FOUND41 NOT FOUND42 NOT FOUND43 NOT FOUND44 NOT FOUND45 NOT FOUND46 NOT FOUND47 NOT FOUND48 138 i416 17:42 48 1.000 A BV 40312, 20, 000 NG 6,0949 NOT FOUND30 NOT FOUND51 NOT FOUND32 NOT FOUND53 NOT FOUND54 149 1253 15:41 43 0.836 ABB 564. 0, 302 NC 0.09r NOT FOUNDL...--NOT FOUND

019311

! l

NO M/S SCAN TIME REP RRT METH AREA(HCHT) AMOUNT '/.TOT57 NOT FOUND5P. NOT FOUND'. ' NOT FOUND60 NOT FOUND6i NOT FOUND62 NOT FOUND63 NOT FOUND64 149 1540 19:15 43 1,088 ABB 2738. 0. 993 NC 0.3065 NOT FOUND66 240 1832 23:31 66 1.000 ABB 45131. 40. 000 NG 12.1967 NOT FOUND68 NOT FOUND69 NOT FOUND70 NOT FOUND71 149 1906 23:49 66 1.0i3 ABB 431. 0. 151 NC 0.0572 NOT FOUND73 NOT FOUND74 NOT FOUND75 NOT FOUND76 NOT FOUND77 NOT FOUND7B NOT FOUND79 NOT FOUND

i 7:442 3:49T 7:44 1.000 50.00 1.175

1 7:43 0. 997 ' SO. 00 0. 967.H 7:32 1,016 50,00 1,0716 7:54 1,021 50,00 ' 0,8277 3:09 i. 053 50.00 0.9238 B: 15 1. 066 50, 00 0, 9459 3: 35 i, 110 50. 00 0, 91410 B: 34 i. 108 50. 00 0. 48011 8:54 1,150 50,00 0,22512 B: Si i. 144 50, 00 0, 77413 9: 10 1. 186 50, 00 0. 38714 9:09 i. 183 50,00 0.59515 6: 04 0. 93 0. 785 0. 99 33. 53 50, 00 0. 434 0. 647 0. 6716 7: 46 1. 003 50. 00 0. 27417 9: 22 0. 99 i. 210 1. 00 46. 76 50. 00 0. 845 0. 904 0. 9418 9: 49 i. 00 i. 263 i. 00 42. Si 50. 00 0. S41 0, 631 0, B619 7: 23 0. 99 0. 958 i. 00 49. 16 50. 00 1. 110 1. 129 0, 9820 13: 07 i. 00 1. 695 1. 01 55, 19 50, 00 1. 697 i, 537 1, 1021 10: 45 i. 00 1. 000 i. 00 20, 00 20. 00 i, 000 1. 000 i. 0022 9: 10 0, 853 50. 00 0. 03323 9:24 8,874 50,00 0,18024 9: 52 0, 919 50, 00 0, 73125 10: 02 0, 934 50. 00 0. 18026 10: 11 0, 948 50, 00 0, 34327 10:24 0/967 50.00 0.39728 10: 31 0, 978 50. 00 0. 29129 10:40 0.993 50,00 0.314r 10: 53 i. 021 250. 00 0, 229«•_.-• 10:39 0.991 250.00 0.180

s

/' /V

32 11: 11 1. 041 50. 00 0. 17331 12: 04 1. 122 50. 00 0. 362

^ 12:14 i. 138 50. 00 0. 2293S 12: 44 1. 135 50. 00 0. 10636 13:01 1. S10 50. 00 0. 39637 13:16 1.235 . 50.00 0.62438 14:10 1. 319 50. 00 0. 92139 14: 0B i, 315 50. 00 0. 70640 16: 47 i. 003 50. 00 1. 09341 14: 16 1. 327 50, 00 0. 14942 15:06 1. 405 50. 00 0. 21343 14: 37 i. 359 250. 00 0. 00544 13:38 i. 269 250. 00 0. 21243 14: 56 1. 390 50. 00 0. 87946 15:59 1. 437 250. 00 0. 02947 13: 01 1. 310 250. 00 0. 17943 17:42 1.00 i. 000 100 20.00 20.00 1,000 1.000 1.0049 14:35 0. B24 50. 00 0. 68750 14: 46 0. B34 250. 00 0. 05851 14; 56 0. 844 125. 00 0. 27052 15:40 0. 836 50. 00 0. 76553 15:43 0. BS8 50. 00 0. 31654 15: 41 i, 00 0. 886 1. 00 0. 30 50, 00 0. 006 0, 916 0. 0155 15:58 0. 903 250. 00 0. 09256 16:01 0. 905 50. 00 0. 44357 16: 46 0. 94B 50. 00 • • 0. 18458 17:03 0. 963 50. 00 0, 22659 17: 45 1, 003 . 50. 00 i. 090: : 17: 51 1. 00B 50. 00 0. 99561 20:22 1. 150 50, 00 i, 062

' 62 20: 51 JL'JJB 50, 00 1. 04163 16: 04 0, 908 50. 00 i. 20764 19:14 i, 00 1.037 L 00 0. 99 50. 00 0. 027 i. 352 0. 0265 17:28 0. 937 50. 00 0, 07466 23:32 1, 00 1. 000 1, 00 40, 00 40. 00 1, 000 1, 000 1, 0067 23:30 0. 998 50. 00 i. 36968 23: 35 1. 002 50. 00 1. 07769 23: 33 1. 001 50. 00 0. 09470 22: 30 0. 956 50, 00 0, 87171 23: 49 1. 00 i. 012 1, 00 0, 15 50, 00 0, 008 2. 534 0. 0072 25: 06 1. 066 50. 00 S. 18173 23: 13 0. B90 4iO, 99 0, 00274 26: 35 1. 130 50. 00 0. S7375 38:10 1.232 50.00 0.56276 30: 16 i. 236 50. 00 0. 53777 31: 12 • 1. 326 50. 00 - 0. 55273 25:51 1. 09B 50. 00 i. 94579 25:51 i, 09B 50. 00 1. 939

019313-

——————— IDENTIFIER SEMl-VOLATILES - LOH LEVEL LIQUID

• COMPOUND QUANT.REPORT CORRECTION DETECTIONCOUNTER NUMBER COMPOUNDS_______ _ VALUE x FACTOR • RESULT LIMIT (ug/1)

2 441 N-NITROSODIMETHYLAMINE ..... ____ 3- ..', .. A 20~3 610 PHENOL .....................4 473 ANILINE ....................5 411 BIS(2-CHLOROETHYL)ETHER ....6 601 . 2-CHLOROPHENOL .............7 421 1,3-DICHLOROBENZENE ........8 422 1,4-DlCHLOROBENZENE ........9 420 1,2-DICHLOROBENZENE ........10 474 BENZYL ALCOHOL .............11 412 BIS(2-CHLOROISOPROPYL)ETHER.12 620 2-METHYLPHENOL .............13 436 HEXACHLOROETHANE ...........14 622 4-METHYLPHENOL .............22 442 N-NITROSO-DI-N-PROPYLAMINE .23 440 NITROBENZENE ...............24 438 ISOPHORONE .................25 606 2-NITROPHENOL ..............26 603 2,4-DIMETHYLPHENOL .........

, 1 410 BIS(2-CHLOROETHOXY)METHANE..28 602 2,4-DICHLOROPHENOL .........29 446 1,2,4-TRICHLOROBENZENE .....30 475 4-CHLOROANIL1NE ............31 625 BENZOIC ACID ...............32 434 HEXACHLOROBUTADIENE ........33 608 P-CHLORO-M-CRESOL ..........34 477 2-METHYLNAPTHALENE .........35 435 HEXACHLOROCYCLOPENTADIENE ..36 611 2,4,6-TRICHLOROPHENOL.......37 416 2-CHLORONAPHTHALENE ........38 402 ACENAPHTHYLENE .............39 428 DIMETHYLPHTHALATE ..........40 439 NAPHTHALENE ................41 428 2,6-DINITROTOLUENE .........42 427 2,4-DINITROTOLUENE .........43 478 2-NITROANILINE .............44 480N 3-N1TROANILINE .............

476 DIBENZOFURAN ...............

PLEASE COMPLETE CORRECTION FACTOR CALCULATIONS ON SECOND SHEET OF THE

ao

COHPUCHEM NO. _____ DATE ______ I OT ICOMPOUND 'LIST NO. ____ —————

1 ———— IDENTIFIER r5EH1-VOLAT1LES LOH LEVEL LUjUIDCOMPOUND QUANT.REPORT CORREaiON DETECTION

JCOjrp. KUHB COMPOUNDS_____ ._ VALUE X FACTOR, • RESULT LIMIT (ug/ll'-« 479 4-NITROANILINE47 626 2,4,5-TRICHLOROPHENOL49 401 MENAPHTHENE50 605 2,4-DINlTROPHENOL51 607 4-N1TROPHENOL52 432 FLUORENE53 417 4-CHLOROPHENYL PHENYL ETHER.......54 424 DIETHYLPHTHALATE55 604 4,6-DINITRO-O-CRESOL56 443 DIPHENYLAMINE (N-N1TROSO)57 414 4-BROHDPHENYL PHENYL ETHER58 433 KEXACHLOROBENZENE59 444 PHENANTHRENE60 403 ANTHRACENE61 431 FLUORANTHENE62 445 PYRENE63 430 1,2-DlPHENYLHYDRAZINE (AZOBENZENE)' ' 426 DI-N-BUTYLPHTHALATE65 609 PENTACHLOROPHENOL67 405 BENZO(A)ANTHRACENE68 418 CHRYSENE69 423 3,3'-DICHLOROBENZlDINE70 415 BUTYLBENZYLPHTHALATE71 413 B1S(2-ETHYLHEXYL)PHTHALATE72 429 DI-N-OCTYLPHTHALATE73 404 BENZIDINE74 406 BENZO(A)PYRENE75 437 1NDENO(1,2,3-C,D)PYRENE76 419 DIBENZO(A,H)ANTHRACEKE77 408 BENZO(6,H,I)PERYLENE ..78 407 . KNZO(B)FLUORANTHENE ..79 409 BENZO(K)FLUORANTHENE ..

Instrument Code 239 • Correction Fictor frlculitlonFinal enaction volume (ni) 1000______ Dilution Conversion 'n,6ml for Ac, l.Onil Tor B/N * Volume of Simple Used (ml) x Fictor K 2 • Fictor

' / K), looo / . . „ CL. 019315or. 1.0 (il)*0.5

(clrcltone)

30

019318

;*:Ci

£'!.-!

Mb1

-»G

!I?

c _>

019317

30

FORM 1AGC/MS PERFORMANCE STANDARD - DecifluorotrlphenylphosphlnePate frS-hi. Run Mo.om.v<M..r Anilyst

•ftm68,

70

127

197

198

199

275

365

441

442

443

Ion Abundance Criteria

30-601 of MSS 198

less than 21 of MSS 69

less than 21 of MSS 69

40-601 of MSS 198

less than 1% of MSS 198

base peak, 1001 relative abundance

5-n of MSS 198

10-301 of MSS 198

It of MSS 19B

less than MSS 443

greater than 401 of MSS 198

17-231 of MSS 442

Sped

S3%

*\%

1,5%

Kl%

<l%

\oo%

b.1??*

\b%

I.Mfc

s%HI 7,

\1l

Spedt

Spec f

Contents:20 Area 266

Ptntachlorophenol Response Factor • Area lBB " so s . Q&»en.1d1ne Detectable I 50ng Level P yes |~1 no_______•Area (counts) 20ng (00 anthracene •_____^ STg ] 9-____________ColMn description_______________________________________Tenperiture_________ Iiothenwl^________ Projrim______

Exnple B7

30

Q_.,"03/B3 IB'-S • _'-JSftMPLE- 1UL DFTFP SbTt4-~V| TO «.» 9UMMSD

MTN INTEN 5- MftX INTEN: *;,<= 0 60 MINIMA MIN INTEN

*

..r o.»i^ -;• V-°,

A: f- ;• %: j i .-c-i c TVS •-""• '» j-?. Ji1- S

o at_ 7-

'•- ; ..... « *.•• aw » =••••"' ; '" •;. o 34 Ef ° BtS" >- "••• •; " " _. ;._,, u «,-•-si •• • •;:'' •: 7. ..-,', o f va-. • Ji« •'•l ' v 7H , -..-i- - • , r.. , JT ;.•...•• 1. >v^« i -f -.u-, I So B» 30 !.a* c •'; :;-': t o. 5^ *7has .; •••• ;•'. ;•:;•; ,-.•., o. 3;:s-' i '' 7':. I': *;w i 7SB" ^ '•' 7';. ;, 77 "-65 0. 33

S t£ S S;3 iSS -' ?' JS K IS3 |» ;i .» S iS" o "fl J," i' X.. T.u.d 3. sr.^ !S:' i;? 073 ^ 022^ 11:' -i s .3 3EJ i-rtc:1C4 -i ;« ;» s o"

-t -VU . tSs i« w _«

?3 IS » . p S !5 S i?S fS • iS "? 5i J5 SS «"50 11 B? «•• ^ :£ , c. TO 443 7.

w . n/, ;. -jr.C'"J •' "'

V )

'———T— T —'"

m

I '•'• ' L. JI *T*. •

*l 1 " •"1 4i-—.',-•i . ..r «>

,'J ' r'*

t:'-• J'.1

30

r> m -••• 1/1m •• .» TQ i.'.' m• S - -il/l 1= M T-- o"- s

"

I

.I..1 I-

'•''' W'

A320

ootaonnaaaoooooaooooooooQooaoooQoaooooiaooooooo i oooQOQonoQQOQoaoaaaciooaoGor.auoaaoQoaracsaoae3ciooa i n

ii^ •* •* -« -« •• •* i

i

MVMigLVual.MMMVp.La-a-'*1^^ j »

iiis* rw f\* rg " fs< pj 1o) 'oooooQQOOooQoaQOoaoooaooooaoaoaooQQQaaaooo i aooaoaaQooaoaoaoaooaoQaaoaaaaaooaaaaaQaooaaaaain

** iiNO** * MN ii

i

oooaQOQooaQOQOQaQQaQoaoaoaaaoaooQOQOQoooooaoQ ! aooaaQaaoaaaoaoaaooaaaQoaaQaaaaaaaaoaaaaaoaaoainOQQuouoooaaaa oooaQaoaaaooooooooaQooooaooaoooa i

iil 1 1 l l ( 1 I t l t l • l < l * l * l l l l « l t l l l * l | l l l * t » « l t * l l * |M

M M W« W4 ><l M (

.-.-rrr.-r.-r.-r.-.-.-.-r. r. ....... r. rrr. rr.-.-.-v,-.-.-.-, .-. L

i n nis;i •* ii •»«i >•**

no on i QDO OQ i n ao

i1 Z1 r«o1 1^0

1 O

•.— It.!9>AO>n 1

ii »i rl ^ tiaaaa i oao oa i n o aoo a a i <• >*

i »gS

1 nut

r- o * •* i n **

1t S •

aaaa i aao oa i n a aao a Q i « «

1 X1 N X

l n ai xm1 » rt P

M -• M - 1 • X*

>'"'

•o cu nn 3-i *

>,oaa«a«o«aioaoQ<«a««4-oo<ao«aa«a4aaa«oaaaaaaaQairta- - ( V

019321

9'0

1

N I t*» m fn ft N 3C H i H r < H Z I m O X i C I * X } M l i ^ Z O ^ I < >O P O C Z Q M I n f ™ I M Q V> I O J C H » l « O G « l Q i n j Q " l U * <m r>*o DON o ni nQ»r»fn»»*;cia»rt««ai^ioii'«" X nO r»wO|i»nZ«XCO *O»irJO*r»-l->-5-.

•n HI i« H rxriroi nrx m m m o m o n i s; mjgr>TI r* *• » fy TI H •« Q m i* Q •» 2 •! en x M o H ri £ o £COWMA xx o H H x i i a r x o »o»m i m Hm*Q0ioxnt-i<i r«* m i r« >• jg t» n < S H x m n u x a m fl E n nl» S •« Z O m »-<HZn»OI»» Z X rt P -1.c i r i M praiNNnrr*!* m m r m mXmzwii H rg z -»^« ^xu5mmoH x^ezs m ^Sc

^ X X I X - 1£ 25 a•i mmm z K10 m

oooooooaoooooooooooaoooQcociooo

i t i i t i i i i i « i ( * i t i « i t i i * i t * i i i *

OOwrwN"*OOOOOOOOOO»«<->OQ4 OO^QBCQtDvQJlA

ao-jooQQOoooaooaQaooQQQOoaoowioaooaooaoaooooaQOfaoQooQOOooooooa

s*i;n.*Ofva«*-*^viff|rgM<A,u<j>k«ttswt»ia«)i-i'* <4^rui

N haaaaaooaoQaoaoaoooaaaoaaoaaaaoaoaaaaaooaaooQaooQoaacaaaooaaoaaOQaaaaaaaoQaQaoaoaooQaoaaoaaa

(h^fVrt<Wllfla^MM««nO>M«'Mf*fMWf«U>Nf> •*» <1 fw N rg »^ VI<4wmni« rsoworgo^NO»O"*o*»**w»4i*»oiasworyrJN

i -vfl) 13

<*XU><:Xft»:il3l"in'tHX(lHZnrur.nrZl3-iJETltit £ m £ A i i X f n Z X * » m : c * n x » i i « -o » M r rwi-is H-iooii»r»n-irnor^or»oHioiCC| H^H»MM31TJQ I Z X O X M O ll-mjtxflQOIJOOQuciaoiCZi»'«XJ|'*ir"'»Jorn»-fn i a o « i> o » *itflSSSSrrSoaoroo onxnm-oos.ooar c s z H H m x z M M z i M t » i n r - i r x H X Z r s a u »eifl»<cir»X'D-<^no » x o n ?! r o r x m m ro a « zr**f*r"ooniarii]inTi i a >-» "»i n o z x ri TI n^sLnS-iSfTisrH-incarro^ro m i x ra ^Z'jo xzionx»H wto-oo-or zmwfn m i" r »mxjgr»fn» z n x m x izz'\ ec f* »oorwo inof-*m Tj«<mmm *> rv'omoit uizxz »r

w x o o z nx o o u bti - -* M r m mX -rt Z 2mo N N

*•. -. ............. m a o Q a rm m m J B m z n t z _ _ . _ _ _ _niZH in w -^ H o m m nt **

jizunnn^zrwrMn^nnjc ^H>(,UWII b*)a..i *r a * t9 r ^ i i i x rzm r ^ o i i i n n u n r *incmnni^^ouM'naMXviiwr'Mm^rworai nnjgCororn^ixa o TI H I r f* rw n x o rno ain a m m o u ig a in Q M

n Ti * a i i N Q I Ci s U m i g o 3 H .t»n>3;.cio 3 M H -1 Z H O I C Hu> n I r i a

ooonooQOGOOooooooooooaoooaoooooooooooQoocionoo i a a a Q a t o• i i i i i i i i i i i i i « i « i i i i i i i i i i « * * i i i i i i * i * t i i < i i i a 1 * 1 1 i 3 — monQOQoooaQ i n a a o a i n oo

M o «'^ J u M 5 Irt n* M a ii r ft* ? A » a'OrwNO'S^"*^'*^ «^OOOO<ini^iw wi Wl •« oo ( fc vWl^-*--Nl«t*l*ir--*B<Ml-—*iON I 1 M^^M I

b, sQoooaooooooooooaoQaoQQooooooooaaaoQoooooao i o aa QQ i o<< 'i i t i l l l i « t l i « l • t i -i i t t l . l . t t • i i l l i i * t i • t i i « |3 1 1 * 1 ) 3 M nQuiJQoaaaoaaQoooaaoQQooQocjQooaaoaooooooQaaaoQO i n aaoo i n oa

^M r rv I * a w

QoaQoaoaoaaaooaaQQooQaoQaoQaoaQQoaooaQOQODoo o o a a oi t * i i « t i ( « i t ( t t i i i t ( i ( « i i i i * i t i * i i ( * i i i * i i i i * )3 * ! • * I 3 n Maaoaaoooaaaaaaaaaaaaaaoaaaaaooaaaaaoaaaaaaaaain ooooi n aaauaQoaaaaaaaaaaaaaaaaaoaaaaoQauaaaaaoaaaaaaaa aaaa ••»

I • I I I I ( I t ( • ( • • • I l l l l t

* « t t < i i i t * i t * ( * i i * i i t i i i * t t i i i * i * ( * t i i i

019323

r* l N m m N M z H « •< r< i z i m Qo o o a z Q « i r . r i - f l O » I U Z Nm NO oar* o m n a r* m »••» Z « O nmOl-lpiXnaCD Z

O » m i m itn-owojniH^

z-ir«i»» rrxwi-nrnii

zm n « x -i a z s m

XZftflti I-4TOM 12flpociuar o-ict*NZXlJDM'HOmjQn'Qn-iroozr>»<:ta«:i

a r i o »• •* r if. m i rr .nni TJ 2 O » Zm m r m n x rZ » w m

rsr ?

aoaanaaoooooaaouaaoaooaaaaoooaCj&OUOQCta*fc*CUCC*'Ot*UCiai-.t.Uwwk-*_.W.WtCJt.. wl

«Gwirf|«(BOw*waftirt.aw«f\.C)aaC)rs***wiQWi*Ni3C;o'

addoaoodooaoaaoaaoaodoQaadoooaoaoQooaQQOQOoooooaaoooQQQOoooaaaataaaaaaaoQaaaooauoaauaaaoaaa

x o -i c c -n * cmnn. o o r *•> « on.« x x t>o i x ----- „.._..--

z n TJ BI m. ncar wr ~oa ixnan- - mn z mx.t ni i i . „nr zmoi r n i o am r p i f i x m z

l * l l l ( * * l » l l « ( l l t l l l * ( l l l t « l l ( * l * l l l l * * t * * t > *-*CjorwCjrvMi*N<i(>rwQn.M*^fvw«ru*'iM*u-*4Q*<'i*9t'6r\iNi*Mn4%*'iA<M*-vCi<i;'«t'i(Bfifo>4rvrtiwii«f''<)0iv44W4NN4firw4r-ifvQ> ONwio^rwM^ t* <j\ t* p* ** Q ryNCBQiMf>»*^

— Out(^i-Srv^QN*jihkM--i(N<w«"*p4)\*^fgw4^-*N'*Ow)«*(>OfwN*fli^Nrvr*i1**'OM*O<i'*(>>«« •NVI.«M»^«.«V M»Ma«r«-,Me^arfM«»oi.^«^i.u,dfM..N-N<.M - U « O N J » - J ;

C<*> n '^i,4<)019323

O O 0 Z Z O n Im MO O C.

n 2 <->O «M O

,rx mrnco _ .. _ _ = o .

CO Tl -• b* Ao A m I rn» »• a * n z»_ iC H z om f

r u z ii M

* * * * *

01932

s}i U

r.-,L*r

-I.WS-

J-tO-P

!CtH4P

.10m QX T)III Xm§

z zzoo izions/g-im m m r r* limxAPfcmi*mm fc rvumortxz i mxmzrmmm ffl z m z m x

m x i mo >•rornzm

nO 1 M ru no M x n m

X M X m x(B Z X Xm a o az r H rm *•zm nm

vtx

TJ O Z in X O am m in o X w Z2 Z M » •» w

1 X Z Z

O<Bxr»xzm

0 WCOa P> n xn m a m

X fn m r

H r

r o r no rm uX 0* M

SSS2?» x x x o nno a o x rO ft M 0 O On ffl m m p m

rn m rnZ X Zai in m

•4rmHxmn

zor-

n

0

A

'•Us

rw N ••«

aaoaaoooaaaaaaraaoaoooaoaaaaaaooooaoaooaoaaooaacaaaat-C&^OOOwpaatjDOOOOQOOOQOOOOOOCQt-OOO&ti&OO&OOUCQOOt-OOO

* * * i * • * • • • * * * * • * * • * • • * • * *' *' *' •' *' *' i * *' * * * *' • i • • * * * *' *' * i' * *' *aaaoaaoaaaaoaaaaooaaaaaaaaoaaooaaaadaaaaaaaaaooaooa

1Cm n1 3m *

•': (I j /',019327

X f X ut o X r. l *i -i w. W Z •*

GHII ?E*l

CQFLUJW**

O FLUQOJ

-i rrn jf

X

»

-RACEME

% •«Y mnz*»PTUEXE

-ix

Eir r

PHTK4L

ITEQ

D 0)x mXNrot Zfn m

D

ft

tBHlttV

•<EHTLHTOBFTI_

FHTHJLaRQPHENC

ZTSEME

ftl 4«TMffl

n r r t»

s "^

s s

ooX

4d 1ZN?H_

m

•4Tm

1 Ia

i

n .

!n

obooooaocaao OQ o o a o o ooaociouaoaa

^•grg^jyjNQJ «i tfl

1 1 1 1 1 1

aaoaaaaaoQi

oooooaocooooooooo oaaooooaooaocooaouaaoouaQtioeocc.coout-iO

ooSo«2oH3oo5J?aQ3.i:-i

i l l i i i looaoaaooaoooooQaoo

0193 23

1 J. i 4 I fl *'• 1 6. k. | itD O O O O O *-» 00 O IBccOtJO M MW.MCI o.4 ,4.*.*.- OOOOO f-

i IV -« O U Ht -•

a oouo*a aaaua

a aaaoa aaaaaa aaaoa aaoaaa aaaaa aaoaaa aaaaa aaaaa

01932:

0o

•4n

l»•41OB

tf

4)•4N

NWlrv»»

M

n

*•*

*aaaa

o*aN

a a -t a xooo ooc. ci G no

•* o a o Nn nn a nWl <J\ W WIWI

i i i i iX X X tX

1 1 1 1 1a MM m»

*\ y.rfiryf.

££2Ss

*M * *< N *»

-««*«

N W1W).**

aaaaaa ao a aa aaaao a a -iO)i-*

•o «a ««rn a M ui •>

r 2 2 x xO 0) * M O

•* a ao Nn 0 ft » n

ii'iiii i i i t« n a 01 ot

N r^ n vu N

f\« N *1 ** Wl

2Sa_2

W4MMOW4

o 3 iw M •** * • » *

aaaaa iaaaaa ia a aa a iaacjuo

-» !ONNN« i* ei -»r\t>* i

i *1 B0

Snc

0a*¥•

(•go>•c/»

l/>tt3

T

» N• •rt r-

3 f*r*- <Q *

H•3

A A

i* *•• fta i«/t f*r* «0 •3

* •

0 1

M 1T)X

M Z

Q I

w mXm

i n n

i ii it n1 Xi M1 * mam

i

3r»

VIr*a*»

n3rt

i/lr*A

(R

It-4t a •' 3

C-. .. - .. ]wcv/J'i! -

0193

INI.blU.HtbH.VtHihlUAIlON CONTROL CHARTSEHIVQUTILE: D3-PHENOL/DB-NAPHTHALENE

•LIMP. NHM UO. 10.

1

.1

.1

.4

.1

RESTIVE RESPONSE

X

•

*-*NV*-*-*v*L.

'Tm*

'|0 1 • 4" ' 1 "I" » « KmftoTS11 » « « »am men ruma Sfs aflS UNBI CM mm

SEMIVQUTILE: OB-NAPHTHALENE/DM-PHENANTHRENEHB..ROP. «*M UCU

|4 RELATIVE. RESPONSE1.81

IIII14131I14t

s o

9I.II.I1.4i.ai

.1

.4

.1

*

[ iHr"tdhi£*s!.,( trtM»

'•"a 4 "i- r u -« ' 'KN.LiSSIS'« » « * »nwr /wn MTTBI« d7Wa UK» FU nmoau

- SEMIVOUTILE: DIOH'HENANTHflENE/Dia-CWIYSENEIC..IOP. ««H UB.

ftLATIVE RESPONSE '

«.fl£~- 1

• DATE

ANALYIT

COMMENTS

M

I

13

r*

\

irj<§

s

1<5

M

§

r

^

|v

5

"S

s

H

^

!|^

«~4

9 D

• K

SB

•i

1

1^

-\

i.tnANf

cw hr>-ia—\

ii *_aIT ('• •«"•

US,

-*-~ -• «

10.

-**-•*— I

GG

rC531

» s

•A><JI_

JUlIS"

/• ® IT

. _

SJ5s"S*° $?CD p I J)Q •• Q

iM i

5

8

OT

88? 88? 88? 83? 0193330

2 a§i nlQ^32 ;

2 ?*o , to

J8-I

IJO An 03"

m

1

oZ

COCO(B

"019333

'RQCEDURE: RK DIAGNOSTIC REPORT 3/U/B3 19:54:.7>ATA FILE! TC001490B03iEFERENCE: TC

BSTHOD: TC INITIALIZATION OPTION: 2 PROCESSING OPTION: 3»ORT: TCS

; —— STANDARDS ——— X —— PLUS UNKNOWNS —— >< - LIST NAMES - >PROC USED POSB RMS PROC USED POSS RMS STANDARD/UNKNOWN

2 1 20 7 7 4 355 TCS/TCU

7 COMPOUNDS PROCESSED, 6 FOUND

C COMPOUND X ———————— SEARCH ———————— X SAT X ———— CHRO ————— >NO LIB ENTRY REF .PRED SEL DELTA PEAKS FIT PEAKS WE TOP DELTA PEAKS1 TC 1 -566 565 . . . . . 332 566 . Xa TC 3 -551 550 550 , 8 9B3 380 550 , i3 TC 3 -551 549 550 1 S 983 . 382 550 . 14 TC 4 -551 549 550 1 8 9B3 . 257 550 . 15 TC 5 -567 565 563 -2 1 972 3206 TC 6 -567 565 563 -2 1 978 3227 TC 7 -567 565 566 1 1 962 . 257

i )

019334ao

MEAD COMPUCHEMaUANTITATION REPORT FILE: TC001490B03

DATA: TC001490B03. Tl050783 19:32:00SAMrLE: 2UL TCDD SAMPLE tU490(5/5/B3> ON #4SUBMITTED BY; 94 ANALYST: 586

AMOUNT=AREA(HCHT) * REF. AMNT/tREF. AREA(HCHT)* RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAME1 tl3C12-2, 3, 7, B-TCDD(INTERNAL STANDARD)2 1, 2, 3, 4-TCDD3 1, 2, 3, 4-TCDD4 1, 2, 3, 4-TCDD5 2, 3, 7, 8-TCDD6 2, 3, 1, 8-TCDD7 2, 3, 7, 8-TCDD

NO M/E SCAN TIME REF RRT METH AREAfHCHT) AMOUNT '/.TOT1 332 566 12:44 1 1. 000 A BB 7B3495, 200. 000 PG/UL 57, 162 320 550 12:23 1 0. 972 A BB 112376. 51. 052 PC/UL 14, 593 322 550 12:23 1 0. 972 A BB 130304, 44. 430 PC/UL 12, 704 257 550 12:23 1 0. 972 A BB 54438, 54. 414 PG/UL 15, 555 NOT FOUND6 NOT FOUND7 NOT FOUND

NO RET(L) RATIO RRT(L) RATIO AMNT AMNT(L) R. FAC R. FAC(L) RATIOI ,12; 44 1,00 1,000 1.00 200.00 200.09 1.000 1.000 1,00fa 12:24 1,00 0,973 1.00 51.05 200.00 0.143 0.562 0.263 12:24 i, 00' 0,973 1.00 44.43 200.00 0,166 0,749 0.824 12:84 1,00 0.973 1.00 54.41 200.00 0,069 0,255 0.875 18:46 1,002 800.00 0.5476 12:46 1.008 200.00 0,7157 18:46 1.008 800,00 0.876

01933so

• CO• •jj- «H ~n SB: i ™ .?o

s)U]_

0 U]• /!!-• iuj 7\ ui i ^vi'^^n )2r : ui /m ".« v*. ja

WU!_..00

CJCT1« 03 -

/

sg

pP H

'SSS'S&?!ds

royif*>*$"£&r +

jo;

1

W

51

.0 01033C'

HPIPLITUDE x.2S uV-seconds (Enlarged x 16.27)

7)

'OB

5-8CrtIt

wh"

. 0

(n5•3rn (f\Tl

3*Ou)

CD .n wn Q

NJSUm

IK

NH ®

NWNWS

T l-> .

n"aTl•M3HO

* bi

00u

M

N(B

W

in o ui oO , Q3 133 d

IS 09 (9 O

w —— ifi2 —— -J ———— : ———— s ———— ! -M

MS.-- -.59

1 > 4.71

7« 5.85

" 1

) 9.74

,

•

13.19

•

•

i . i . i -ro ——————————————————————————C9

Column A Column B

1.5J 2250/1.95J 2401 Supelco Capillary Column DB-B 30MCond.: 190, Isothermal > 50 for 1 then 210 at 20Ar/CHa, 25 cc/m1n. hold 1 then 250 at 3 hold 20

Ar/CH4, 50 cm/sec

Peaks. 0250 Standard Peaks. _02SO Standard

1A Alpha-BHC- IB Alpha-BHC2A Beta-BHC 2B Beta-BHC3A Gamma-BHC 3B Gaima-BHC4A Heptachlor Epoxlde 48 Heptachlor Epoxlde5A Alpha-Chlordane SB Alpha-Chlordane6A p,p'-DDE 6B p,p'-DDE7A p.p'-DDD 7B p.p'-DOD8A p,p'-DDT BB Endosulfan Sulfate9A Endosulfan Sulfate 9B p.p'-DDTPeaks, 0266 Standard Peaks. 0266 Standard

IDA Delta-BHC 10B Delta-BHC11A Heptacnlor 11B Heptachlor12A AldMn 12B Aldpln13A Delta-Chlordane 13B Delta-Chlordane14A Endosulfan 1 14B Endosulfan I15A D1eldr1n 15B D1eldr1n16A Endrln 16B Endrln and Endosulfan 1117A Endosulfan II 17B Endrln AldehydeISA Endrln Aldehyde

6'-•£{', G<2019333

flHPLITUDE x.25 uV-seconds (Enlarged x 2.39)

( I

v i

RUPUTUDE x.2S uV-seconds (Enlarged x 2. SI I

p •• - r ;• i"wt. v;lK(

0130

RMPLITUDE x.2S uV-seconds (Enlarged x .81)

•n 01 ® W '2 o o s> £ i -•H S o o o I. '••••'» e <» * S -;''3 S * O O

Q)

.PfnVI

w»-O

SD^rn (j,

aS '"'M, T,

9.30

1IRH

X

IHJECTE

:hod t B

SCKB7

Rmi

r"H 0

?J?,?,"J in,!o °TI~NSDBOH!W ,-

CO0)« cr.

•0COu

tx)M

•vl09

N*.

^ A0S= ^ i 27cr-rrsTT ' -f rn•Ij&ll- 2 08^ Wf6?JP >"

x? 3 . 7 "wj} 4.11 > .

\ B.se ^> 6'17 ^3> 6.8S Vc, ^> 7.71

"_> 8.73 C\C N^'> 9.93 NT} 10*62 -^ .

S V)/ ^(.1 Q '\ 12.9?

^>1S.S1 \j '

/^ |l>^

^\

./21.81

. ——— L

. 1

1

1

'-'

019341 :^

g j7 ;• ; ,., f, ,.

fc 90

• r ' >"*•!••» (>x'* ;

X,'J-•--.••--• -----I---.-.--, • ^~-'^^ ''': '

RFIPLITUDE x.zs uV-seconds teniargea x le.n * oo w a>~1 (D CO O (SO Q (B QHI CO O © ©3(8 0 CO O 09

CO

§T)

m

ae12.S3.33

======—————-16.84em „ | J*=>-16.83

70

-20.33

019342

".v<

fltlP-ITUDE x.25 uV-seconds (Enlarged x .58)

r ii ,i •

019343

v. J

flPIPLITUDE x.2S uV-seconds (Enlarged x .52)_ -. w u * <n2 m co o o o"" 5, O 0 S 0.

Q C . i Q G . C E i" 19 IS O O OJ CD . .

?b

^m

rfj.7 i/.'0 (h

oaT wCO ffi

mwoss.." O -,j

(Jir-WW

T)V02

Vo

I

019344C«'«3w{'J.i

RUPLITUDE x.25 uV-seconds (Enlarged x .6?)

t I

flMPLITUDE x.2S uV-seeonds (Enlarged x

019343

DETECTION LIMIT SUttlARY FORVOR OF HAZARDOUS SUilSTANCE LIST COMPOUNDS

Compound l.D.Bromocnlorometnane (IS)Cnlo.'oetnaneVinyl CnlorldeCnloroetnaneBromometnaneAcroleinAcrylohitrileMettiy ene CnloriaeTrkn orofluorometnanel.l-D1cnloroetnylene1. 1-1)1 cnioroetnane1.2-Trans-Dicnloroetnylenecnioroforml.2-U1cnloroetnaneI.l,l-Tr1 cnioroetnaneCarbon tetracnloriaeBrnmodlcnloronietnane/ kDicnloroDutane (IS)l,_-DicnloropropaneTrans-l,3-DicnloropropyleneTricnloroetnylenebenzeneCi5-l,3-01cii]oropropeneI.l.2-Tr1cnloroetnane1, 2-DlDromocniorometnaneBromoform1,1,2,2-Tetracnloroetnylene1,1,2,2-TetracnioroetnaneToluenecniorooenzeneEtnyloenzene2-Cnloroetnyl vinyl etner"4-1,2 Oi cnloroetnane (Surr.)dlu- Benzene (Int.Std.)db - Toluene (Sum.)Acetone.-tJutanone4-Metnyl-i-Pentanone^-HexanoneCaroon disulfideVinyl acetateStyreneQ-Xylene

Mead CompuChem*Low Level MaterDetection Limits

(ug/D*

655b

1001UO5bbbbbbbbb

bbbb

10bbbbbsbbb

10U2001001001010bb

Low Level SolidDetection Limits

(ug/kg)*

2.52.52.52.5

bObO2.52.52.52.52.52.52.52.52.52.5

2.52.52.52.5b.O2.52.52.52.52.52.52.52.52.5

bO100bO50bb2.52.5

Medium LevelDetection Limits

(ug/g)*

555b

100100

bbbb555b55

b5bb10b555555bb

100200100100101055

j x StandardDeviation

ng on-column

1248362123434223

4r242

1132111111

Ii)830132522

•tlmated MDL•Sigma DL

3fl 019347

DETECTION LIMIT SUMMARY FORSEMIVOLATILE HAZARDIODS SOBSTANCE LIST COMPOUNDS

Compound l.D.

-Ja-PHENOL (IS)N-NITROSODlMETHYLAMlNEPHENOLANILINEB1S(2-CHLOROETHYL)ETHEK2-CHLOROPHENOL1.3-D CHLOROBENZENE1.4-D CHLOKQBENZENE1.2-D;CHLOROBENZENEBENZYL ALCOHOLB1S( 2-CHLOROISOPROPYL (ETHER2-METHYLPHENOLHEXACHLOROETHANE4-METHYLPHENOL

, VFLUOROPHENOL (Surr.),'ENTAFLOOROPHENOL (Surr.)"b-PHENUL (Surr)ab-NITROBENZENE Surr.)DECAFLOOROBIPHENYL (Surr.)2-FLUQROANIL1NE (Surr)2-FLUORQBIPHENYL (Surr)d8- NAPHTHALENE (IS)N-N1TROSO-DI-N-PROPYLAM1NENITROBENZENEISOPHQRONE2-N1TROPHENOL2,4-DIMETHYLPHENOLBlS(2-CHLOROETHOXY)METHANE2,4-UlCHLOROPHENOL1.2,4'TKlCHLORObENZENE4-CHLORUANILlNEBENZOIC ACIDHEXACHLOROBUTADIENEP-CHLORO-M-CRESOL2-METHYLNAPTHALENEHEXACHLOKOCYCLUPENTADIENE

" 2.4,i>-TKICHLOROMNOL1 .-CHLORUNAPHTHALENEACENAPHTHYLENEDIMETHYLPHTHALATENAPHTHALENE..(.t-DlNITROTOLUENE

Mead CompuChem*Low Level WaterDetection Limit

(ug/l)*

2020202020202020204040202020

40202040204020201UO20020404020202020202040

Low Level SolidDetection Limit

(ug/Kg)*

400400400400400400400400400800800400400400

BOO4004008004008004004002UUU4000400800800400400400400400400600

Medium LevelDetection Limits

(ug/g)«

1010101010101010102020101010

201002010201010bU10010202010101010101020

3 x StandardDeviation**

ng on-column

34106454448343

8432265b27101043710436-54

'Estimated MDL**3-S1gma DL

30

DETECTION LIMIT SOMMARY FORSEMIVOLAT1LE HAZARDIOUS SUBSTANCE LIST COMPOUNDS

Compound l.D.2.4.DIN1TROTOLOENE2-NITROAN1L1NE3-NITROANILINED1BENZOFURAN4-NITROAN1L1NE2,4,5-TRlCHLOROPHENOLd!0-PHENANTHRENE (IS)ACENAPHTHENE2,4-DlNITROPHENOL4-N1TROPHENOLFLUORENE4-CHLOKUPHENYL PHENYL ETHERUIETHYLPHTHALATE4,6-DINITRO-O-CRESOLDIPHENYLAM1NE (N-NITROSO)4f '(OMOPHENYL PHENYL ETHERH.«rtCHLOROBENZENE

1 PHENANTHRENEANTHRACENEFLUURANTHENEPYRENE1.2-D1PHENYLHYDRAZINE (AZOBENZENE;D1-N-BUTYLPH1HALATEPENTACHLUROPHENOL012-CHRYSENE (IS)BENZOIAIANTHRACENECHRYSENE3,3'-DlCHLOKOBENZlDlNEBUTYLBENZYLPHTHALATEB1S(2-ETHYLHEXYL)PHTHALATEDl-N-OCTYLPHTHALATEBENZIDINEB!NZO(A PYRENEUDENOi: .2~,3-C.D)PYRi;NED1BENZO(A,H ANTHRACENEBEMO(G,H.l PERYLENEBENZO(B)FLOORANTHENEBENZO(K)FLUORANTHENE

Mead CompuChem*Low Level MaterDetection Limits

(ug/l)*4020020020200200

201001002020204020202020202020402040

2020402020208040404040

Low Level SolidDetection Limits

(ug/kg)*8004000400040040004000

40020004000400400400800400400400400400400400800400800

4004008004004004001600800800800800

Medium LevelDetection Limits

(ug/g)*20100100100000

10501001010

. 102010101010101010201020

101020 '1010104020202020

3 x Standard.Deviation**

ng on-column

81993bb

47

11454214695b9631310

108204166

>20910887

>20Estl mated MDL

**3-S1gma CL 019349", " rJ /-'I/l «,»

30

DETECTION LIMIT SUMMARY FORPESTICIDES HAZARDOUS SUBSTANCE LIST COMPOUNDS

Mead CompuCnem*

Compound l.D.ALPHA BHCBETA BHC

DELTA BHC

HEPTACHLOR EPOXIDE

CHLORODANE

DUE

DDD

DOT

ENDOSULFAN SULFATE

BAMMA BHC

HEPTACHLOR

GAMMA CHLORDANE

ENDUSULFAN 1

ENDOSULFAN 11

ALURIN

D1ELDR1N

ENDR1N

TCDD

Low Level HaterDetection Limit

(ug/l)*0.10.10.1

0.10.10.10.10.1

0.10.10.1

0.1

0.1

0.1

0.1

0.1

0.1

0.002

Low Level SolidDetection Limit

(ug/kg)*4.04.04.0

4.04.0

4.0

4.0

4.0

4.0

4.0

4.0

4.0

4.0

4.0

4.0

4.0

4.0

0.08

Medium LevelDetection Limit

(ug/g)*0.010.010.01

0.010.010.010.01

0.01

0.01

0.01

0.01

0.01

0.01

0.01

0.01

0.01

0.01

0.002

3 x StandardDeviation**

ng on-column0.00190.0030

0.0008

0.0013

0.0008

0.0007

0.0062

0.0136

0.0091

0.0023

0.0027

0.0025

0.0039

0.0126

0.0032

0.0043

0.0082

•Estimated MDL**3-S1gma DL «< qn,r'