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PNNL-14596
Year 6 Post-Remediation Biomonitoring and Phase II Source Investigation at the United Heckathorn Superfund Site, Richmond, California
N. P. Kohn N. R. Evans
Battelle Marine Sciences Laboratory Sequim, Washington
March 2004
Prepared for the U.S. Department of Energy under Contract DE-AC06-76RL01830
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PNNL-14596
Year 6 Post-Remediation Biomonitoring and Phase II Source Investigation at the United Heckathorn Superfund Site, Richmond, California
N. P. Kohn N. R. Evans
Battelle Marine Sciences Laboratory Sequim, Washington
March 2004
Prepared for the U.S. Environmental Protection Agency Region 9 under a Related Services Agreement with the U.S. Department of Energy under Contract DE-AC06-76RL01830
Pacific Northwest National Laboratory Richland, Washington 99352
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Abstract
The Heckathorn Superfund Site in Richmond, California, encompasses the property of the former United Heckathorn pesticide packaging plant and the adjacent waterway, Lauritzen Channel. The site was used from 1945 to 1966 by several operators to produce various agricultural chemicals. The site was placed on the National Priorities List of Superfund sites in 1990, which resulted in the removal of pesticide-contaminated soil from the upland portion of the site and dredging the marine portion of the site. Post-remediation marine monitoring and associated studies conducted through 2002 indicate that the contamination in the channel continues to pose a significant risk to biota and human health. This report documents continued marine monitoring and source investigation studies conducted in 2003.
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Acronyms
cy cubic yards
DDD dichlorodiphenyl dichloroethane
DDE dichlorodiphenyl dichloroethylene
DDT dichlorodiphenyl trichloroethane
EPA U.S. Environmental Protection Agency (EPA)
GIS geographic information system
MDL method detection limit
OBM Older Bay Mud
PCB polychlorinated biphenyl
QC quality control
TOC total organic carbon
TSS total suspended solids
YBM Younger Bay Mud
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Contents
Abstract ...................................................................................................................................................... iii
Acronyms.....................................................................................................................................................v
1.0 Introduction ......................................................................................................................................... 1
1.1 Site Background ........................................................................................................................ 1
1.2 Previous Investigations.............................................................................................................. 1
2.0 Methods............................................................................................................................................... 3
2.1 Year 6 (2003) Monitoring ......................................................................................................... 3
2.1.1 Sample Collection ........................................................................................................ 3
2.1.2 Water Sample Analysis ................................................................................................ 3
2.1.3 Tissue Sample Analysis................................................................................................ 3
2.2 Phase II Source Investigation .................................................................................................... 4
2.2.1 Sample Collection ........................................................................................................ 4
2.2.2 Sediment and Soil Sample Analysis............................................................................. 5
3.0 Results ................................................................................................................................................. 7
3.1 Year 6 (2003) Monitoring ......................................................................................................... 7
3.1.1 Water Samples.............................................................................................................. 7
3.1.2 Tissue Samples ............................................................................................................. 7
3.2 Phase II Source Investigation .................................................................................................... 8
3.2.1 Soil and Sediment Chemistry ....................................................................................... 8
3.2.2 YBM and DDT Distribution......................................................................................... 9
4.0 Discussion ......................................................................................................................................... 11
5.0 References ......................................................................................................................................... 13
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Appendix A – EPA Field Sampling for Mussels and Seawater................................................................A.1
Appendix B – Year 6 (2003) Monitoring Water and Tissue Chemistry ...................................................B.1
Appendix C – Phase II Source Investigation Soil and Sediment Chemistry ............................................C.1
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Figures
1 Location of the United Heckathorn Superfund Site, Richmond, California ..................................... 14
2 Five-Year Biomonitoring Results Summary, United Heckathorn Superfund Site ........................... 15
3 Locations for Year 6 Biomonitoring Sample Collection .................................................................. 16
4 Relationship between Lipid Measurements by Bligh-Dyer and EPA 3450 Methods....................... 17
5 Embankment Soil Sampling Locations, Phase II Source Investigation............................................ 18
6 Diver-Collected Core Sampling Locations for Hotspot Delineation, Phase II SourceInvestigation ..................................................................................................................................... 19
7 Vibracore Sampling Locations in Lauritzen Channel, Phase II Source Investigation...................... 20
8 Embankment Soil Sampling ............................................................................................................. 21
9 Representative Diver-Collected Cores.............................................................................................. 22
10 Vibracore Sampling at Station H03-11, Mouth of Lauritzen Channel ............................................. 23
11 Representative Vibracores Split for Processing, clockwise from upper left..................................... 24
12 Total DDT and Dieldrin in Water (ng/L, total Fraction), Pre-Remediation Through 2003.............. 25
13 Total DDT and Dieldrin in Mussel Tissue, Pre-Remediation Through 2003................................... 25
14 Sediment DDT in Lauritzen Channel Younger Bay Mud, Phase II Source Investigation................ 26
15 Sediment DDT in Hotspot Delineation Area, Phase II Source Investigation ................................... 27
16 Plot of Sediment Thickness using 1999 Sediment Investigation Data, Phase I Under-Pier Survey Data, and Phase II Diver-Collected and Vibracore Data...................................................... 28
17 Sediment DDT Concentrations and YBM Thickness in Lauritzen Channel .................................... 29
18 Sediment DDT Concentrations and YBM Thickness in East Central Lauritzen Channel................ 30
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Tables
1 Sampling Stations for Year 6 Post-remediation Monitoring of the United Heckathorn Site............ 31
2 Embankment Soil Sample Collection Information ........................................................................... 32
3 Diver-Collected Core Sampling Information.................................................................................... 33
4 Vibracore Sampling Information ...................................................................................................... 34
5 Chemistry Subsamples Prepared from Cores ................................................................................... 35
6 Concentrations of DDT, Dieldrin, and Total Suspended Solids in the Total Fraction of Water Samples Collected in February 2003 for Post-remediation Monitoring of the United Heckathorn Superfund Site ................................................................................................... 38
7 Concentrations of DDT and Dieldrin in the Dissolved Fraction of Water Samples Collected in February 2003 for Post-remediation Monitoring of the United Heckathorn Superfund Site ....... 40
8 Comparison of Years 4, 5, and 6 Pesticide Concentrations in Water ............................................... 42
9 Summary of Length and Weight Data from Mussels Collected for Tissue Samples in February 2003 for Year 6 Post-remediation Monitoring of the United Heckathorn Superfund Site 43
10 Summary of Pesticides in Mussel Tissues, Year 6 Post-remediation Monitoring of the United Heckathorn Superfund Site ................................................................................................... 44
11 PCB Aroclors in Mussel Tissues, Year 6 Post-remediation Monitoring of the United Heckathorn Superfund Site............................................................................................................... 46
12 Summary Sediment Chemistry Results for all Soil and Sediment Samples, Phase II Source Investigation ......................................................................................................................... 47
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1.0 Introduction
This report is a brief summary of post-remediation monitoring and associated studies conducted at the United Heckathorn Superfund Site in Richmond, California in 2003. These are follow-on studies to earlier investigations described below. Because the text is so brief, all figures and tables follow the text so as not to interrupt the flow of the document.
1.1 Site Background
The Heckathorn Superfund Site in Richmond, California, encompasses the property of the former United Heckathorn pesticide packaging plant and the adjacent waterway, Lauritzen Channel (Figure 1). The site was used from 1945 to 1966 by several operators to produce various agricultural chemicals, including dichlorodiphenyl trichloroethane (DDT), its breakdown products dichlorodiphenyl dichloroethane (DDD) and dichlorodiphenyl dichloroethylene (DDE), dieldrin, and other pesticides. The site was placed on the National Priorities List of Superfund sites in 1990, which resulted in the removal of pesticide-contaminated soil from the upland portion of the site and dredging the marine portion of the site.
Remediation of the channel by dredging, dewatering, and offsite disposal of contaminated sediment took place between July 1996 and March 1997. Sampling during the dredging operation indicated that the significant mass of contamination was removed. However, subsequent sampling, particularly at the 2-year post-remedial sampling of marine water and biota (1998 to 1999), indicated pesticide contamination significantly above the remediation goals in the Record of Decision and suggested that there was a potential recontamination problem in the channel. The post-remediation marine monitoring and associated studies, described in Section 1.2, indicate that the contamination in the channel continues to pose a significant risk to biota and human health.
1.2 Previous Investigations
Post-remedial monitoring data demonstrated that the pesticide DDT(a) was less bioavailable to marine biota 2 to 3 years after remediation than it was in the first 6 to 10 months after remediation (Figure 3) (Antrim and Kohn 2000a, b; Kohn and Kropp 2001a). However, DDT was detected in the tens of parts-per-million (ppm) range in sediment samples collected from Lauritzen Channel in October and November 1998. Sediment DDT concentrations greater than 0.590 ppm were first measured in October 1998 and reported in Anderson et al. (2000). DDT in sediment was confirmed by additional measurements in November 1998 (Antrim and Kohn 2000b), and was additionally verified in the 1999 Sediment Investigation (Kohn and Gilmore 2001). Furthermore, an increase in bioavailability of DDT to mussels in Lauritzen Channel was observed in 2001, the fourth year of post-remediation monitoring (Kohn and Kropp 2001b); however, this increase was not apparent the following year (Kohn and Kropp 2002) (Figure 2).
(a) Throughout this document, “DDT” is generally intended to mean DDT and its breakdown products, collec-
tively. “Total DDT” is used to indicate concentrations that are the sum of detected DDT, DDD, and DDE compounds.
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Uncertainty about any trend in DDT bioavailability to mussels through 5 years of monitoring prompted the U.S. Environmental Protection Agency (EPA) to continue the biomonitoring program for another year (2003). The results of the 1999 Sediment Investigation and the apparent increase in DDT availability in 2001 triggered EPA to undertake a Phase I Source Investigation study in 2002 (Kohn and Evans 2002). This study identified several potential sources bearing further investigation: a hotspot of sediment contamination beneath the north end of the Levin Pier, embankment soils with elevated concentrations of DDT, and a previously unidentified outfall pipe discharging into the intertidal zone of northeast Lauritzen Channel. Phase II Source Investigation sampling and analysis was undertaken in 2003 to delineate the sediment hotspot, further characterize the depth of contamination in embankment soils, and to verify the outfall discharge. This report summarizes the results of the sixth year of post-remediation biomonitoring and Phase II of the Source Investigation study. All technical reports for previous investigations are available electronically from www.pnl.gov/main/publications, using “Heckathorn” as the search term.
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2.0 Methods
2.1 Year 6 (2003) Monitoring
2.1.1 Sample Collection
Water and mussel samples were collected by EPA Region IX staff in the same manner as all previous years of biomonitoring at the Heckathorn site. EPA’s sample collection summary memo is provided in Appendix A. Triplicate water samples were collected at the four routine monitoring locations, the Seep, and Parr Canal (Figure 3, Table 1). Additional replicates for quality control (QC) were collected from Lauritzen Channel End (303.3) and the Seep, for a total of 20 water samples. Mussel samples were collected at the four routine monitoring locations and four additional locations in Lauritzen Channel. Two of the additional locations are near elevated water or sediment.
2.1.2 Water Sample Analysis
With one exception, triplicate water samples from each of the four routine monitoring locations were analyzed for total DDT (2,4’- and 4,4’- isomers of DDT, DDE, and DDD), dissolved DDT compounds, and total suspended solids (TSS). The exception was Richmond Inner Harbor 303.1, where one of the triplicates was used for QC because the planned QC replicate (from 303.3) was broken during shipping. All water analyses were conducted by Columbia Analytical Services, Kelso, Washington. Upon receipt at the laboratory, each 4-L sample was split as follows: approximately 220 mL was removed for TSS and the remaining volume was split in half for total and dissolved pesticides. The aliquots for total pesticides were assigned suffix –T. The aliquots for dissolved pesticides were assigned suffix –D, transferred to polycarbonate containers, and centrifuged to remove particulate matter. The supernatant was decanted for subsequent analysis of dissolved pesticides.
TSS was analyzed by EPA Method 160.2. The method detection limit (MDL) is typically 1 mg/L TSS, but because the sample volume was limited, the reporting limit for this study was 5 mg/L TSS. The laboratory attempted to achieve lower reporting limits, but values less than 5 mg/L are flagged as estimates (“J”). Organochlorine pesticides were analyzed by EPA Method 8081A; polychlorinated biphenyl (PCB) aroclors were analyzed by EPA Method 8082. The laboratory noted matrix interference in the field samples that prevented reporting to the MDL of 0.05 ng/L to 0.12 ng/L for the target pesticides; reporting limits for field samples ranged from 0.48 ng/L to 0.87 ng/L. In the case of dieldrin, the laboratory MDL was 0.06 ng/L, but the reporting limits for field samples were 0.48 ng/L to 0.50 ng/L.
2.1.3 Tissue Sample Analysis
Eight mussel tissues were analyzed for pesticides and lipid content by Columbia Analytical Services, Kelso, Washington. Chlorinated pesticides were analyzed by EPA Method 8081A; PCB aroclors were analyzed by EPA Method 8082. Lipids were analyzed by the Bligh-Dyer method for consistency and comparison with pre-remediation and other post-remediation data. Lipids were also measured using EPA Method 3450. This method is efficient in that it does not require a separate sample aliquot or extraction: lipids are measured gravimetrically in the same methylene chloride extract that is prepared for pesticide
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analysis. The two methods are fairly comparable, with typically less than 30% difference in results. In this case, the Seep mussel sample was too small to allow a separate Bligh-Dyer lipid extraction, and the EPA 3450 data allowed an estimate of a Bligh-Dyer-equivalent lipid content (Figure 4).
2.2 Phase II Source Investigation
The Phase II Source Investigation was a follow-on study of potential sources of pesticides to Lauritzen Channel identified in the Phase I Source Investigation. The objectives of the Phase II Source Investigation were to 1) further characterize the depth of contamination in embankment soils, 2) delineate the sediment DDT hot spot beneath the north end of the Levin Pier, and 3) survey Younger Bay Mud (YBM) thickness and DDT concentrations throughout Lauritzen Channel.
2.2.1 Sample Collection
Embankment soil and sediment core samples for the Phase II Source Investigation were collected May 20-22, 2003. Embankment soil samples were collected by Battelle and EPA personnel; both diver-collected cores and vibracores were collected by TEG Oceanographic Services of Santa Cruz, California. Locations of Phase II Source Investigation soil and sediment samples are shown in Figures 5 through 7. Sample collection and preparation information is provided in Tables 2 through 5. Sample collection activities are described below.
2.2.1.1 Embankment Samples
Embankment soils from the northeastern edge of Lauritzen Channel were collected during a low tide when the bank was accessible from land. Sampling locations were selected by EPA to represent areas of documented shoreline activities, such as railroad scale use and removal, or prior excavations and bank stabilization. Embankment soil collection information is provided in Table 2. Most samples were collected near the high tide mark, just below the vertical wall or armoring (see descriptions in Table 2 and photos in Figure 8). A hand auger with a stainless steel bit was used to penetrate the sediment surface and collect a sample from the 0- to 0.2-ft (~2.5 in.) interval. The sampler bit was rinsed thoroughly with seawater before augering deeper in the same location to collect a sample from the 0.5- to 1-ft-depth interval. If the location was on a slope, the auger was inserted perpendicular to the slope to determine the true thickness of a contaminated layer. Soil samples were placed directly into labeled sample jars for pesticide, grain size, and total organic carbon (TOC) analysis; sealed sample jars were stored on ice in coolers until transferred or shipped to the appropriate analytical laboratory.
2.2.1.2 Diver-Collected Cores
Cores were collected by TEG divers at 17 stations selected by EPA to delineate the DDT hotspot identified in the Phase I Source Investigation. The hotspot was located at the north end of the Levin Pier, beneath the pier face at Transect +2.5. EPA first placed four stations along the pier face, about 15 ft and 30 ft north of the hotspot (1-N, 2-N), and about 15 ft and 30 ft south of the hotspot (1-S, 2-S). Three stations were placed approximately 25 ft west of the pier face and between the stations on the first line of samples (1-NW, 1-W, and 1-SW). Station 2-W was located another 25 ft out so that it was about 50 ft west of the hotspot. Four more stations were located under the pier about half way between the pier face
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and shore embankment (approximately 12 ft east of pier face): 1-NE, 2-NE, 1-SE, and 2-SE. Although these 13 were the only stations planned, diver time and coring supplies were available to collect four additional samples. The last four stations were located even further east, as close to the embankment as possible in the first four gaps between rows of pilings supporting the Levin Pier (whole transect numbers indicate piling rows, half numbers indicate a gap between piling rows): T(+1.5)E, T(+2.5)E, T(+3.5E), and T(+4.5)E.
Diver-collected cores were obtained by pushing by hand a 2-ft section of 2-in. diameter tubing into the sediment to maximum penetration. The diver would cap the top, dig to the bottom, and cap the bottom before removing the tube from the sediment. Capped, labeled cores were transported to shore, where the stratigraphy was described before sediment was transferred to a disposable aluminum pie plate, homogenized, and split into aliquots for pesticide, grain size, and TOC analysis (Table 5; Figure 9).
2.2.1.3 Vibracores
Vibracore samples were collected at 11 stations in Lauritzen Channel on May 22, 2003. Vibracore sampling stations were located in central and southern Lauritzen Channel to expand the hotspot delineation and fill gaps in the data obtained during the 1999 Sediment Investigation (Figure 7). The goal of the vibracore sample collection was to penetrate through the YBM into the Older Bay Mud (OBM) to determine the present-day thickness of overlying YBM and the concentration of pesticides in the YBM.The vibracore sampler was operated by TEG Oceanographic Services; it was deployed from TEG’s 24-ft pontoon barge, which was anchored at each station prior to sampling (Figure 10).
Vibracore sampling information is provided in Table 4. OBM was retained in all cores except H03-12, where hard clay was reached but not penetrated sufficiently to retain. Throughout the sampling day, capped, labeled vibracores were transported to shore for processing and chemistry subsampling. Vibracores were processed by splitting longitudinally using reciprocating shears and gently prying the halves apart (Figure 11). The stratigraphy and sediment characteristics were described, and YBM was removed and homogenized in a disposable aluminum pie plate. Homogenized sediment was split into aliquots for pesticide, grain size, and TOC analysis (Table 5).
2.2.2 Sediment and Soil Sample Analysis
All sediment and soil samples were analyzed for pesticides by the EPA Region IX Laboratory in Richmond, California. Chlorinated pesticides and PCB aroclors were analyzed by EPA Method 8081A. The EPA Region IX Laboratory also analyzed TOC in sediment samples by EPA Method 9060. Grain size analysis by ASTM D422-63 method was performed by Columbia Analytical Services of Kelso, Washington.
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3.0 Results
3.1 Year 6 (2003) Monitoring
3.1.1 Water Samples
Results for TSS, dieldrin, and DDT compounds in the total fraction samples are provided in Table 6; results for dieldrin and DDT in the dissolved fraction samples are shown in Table 7. Water samples were also analyzed for PCB aroclors but none were detected. All water analysis results received from the laboratory are provided in Appendix B.
It is difficult to evaluate the water chemistry relative to marine water quality criteria because of the elevated reporting limits for dieldrin and some DDT compounds. Dieldrin reporting limits were usually around 0.5 ng/L, 3 to 4 times the 0.14-ng/L remediation goal. The elevated reporting limit is not an issue where dieldrin was clearly detected, as in samples from Lauritzen Channel End 303.3 and the Seep sample. DDT reporting limits, although elevated (0.48 ng/L to 0.87 ng/L compared with MDLs of 0.05 ng/L to 0.12 ng/L), were usually below the 0.59-ng/L remediation goal. It is still clear that there is a gradient of total DDT that decreases with distance from Lauritzen Channel End (303.3). In 2003, the Lauritzen Channel End water samples showed an order-of-magnitude increase in both total and dissolved DDT concentrations from the previous year of monitoring (Table 8, Figure 12). It should be noted that these water samples provide just a snapshot of water-column DDT concentrations and thus provide no information about the temporal variability or vertical stratification of contaminants in the water column. The differences between sampling events do not necessarily verify trends, nor are individual samples necessarily representative of typical conditions.
3.1.2 Tissue Samples
Shell length of individual mussels and mean mussel tissue weight per mussel at each station were measured for Year 6 monitoring (Table 9). The target DDT pesticides were detected in all Year 6 tissue samples (Table 10). Concentrations in mussels from the four routine monitoring locations ranged from 25 µg/kg and 28 µg/kg wet weight at Santa Fe Channel End (303.4) and Richmond Inner Harbor (303.1), respectively, to 214 µg/kg and 431 µg/kg wet weight at Lauritzen Channel Mouth (303.2) and End (303.3), respectively. These follow a pattern of decreasing DDT concentration with distance from Lauritzen Channel similar to previous years (Figure 13), and Year 6 tissue concentrations were generally similar to Year 5. Of the PCB Aroclors, only Aroclor 1254 was detected in any of the mussel tissues (Table 11). This is consistent with previous years of monitoring.
Mussels collected from the four additional locations in 2003 provide valuable additional information about DDT bioavailability in Lauritzen Channel. Despite very small sample size (6 mussels) at the Seep station, pesticide concentrations in tissues from this station were so elevated that multiple dilutions were required to quantify them. The Seep area clearly represents a much higher exposure to bioavailable DDT. Mussels collected from the ladder at Manson Construction, on the west side of the channel across from 303.3, had similar tissue DDT concentrations to 303.3, suggesting that water in central Lauritzen Channel is fairly well-mixed. Mussels from the 8-in. pipe further north on the east bank of Lauritzen Channel had
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higher tissue burdens of DDT, about 2.5 times the burden of 303.3 and Manson Ladder mussels. The north end of the channel would not be flushed or mixed as well as the central and south sections, but it is unclear whether the increased exposure is from Seep water pushed upchannel, from erosion of embankment soils, or (most likely) a combination of sources. Similarly, mussels from the pilings supporting the Levin Pier at Transect +2 had tissue burdens about twice those of 303.3 and Manson Ladder mussels, but the contribution of exposure from the Seep water versus the sediment hotspot cannot be easily distinguished.
3.2 Phase II Source Investigation
3.2.1 Soil and Sediment Chemistry
Results for dieldrin, total DDT, grain size, and TOC in embankment soil and channel sediment are summarized in Table 12. Total DDT concentrations by station are provided on the maps in Figures 14 and 15. Results for individual pesticides are provided in Appendix C.
The purpose of analyzing embankment soils was to determine whether DDT occurred only in the surface few inches (“veneer” of contaminant deposited on surface), or if it could be found at depth (residual contaminated upland soil). Results indicated that this depended on the sampling location. At the north end of the channel near the former train scale (Transect -35), the DDT concentration was about 9 times higher in the 0.5- to 1-ft depth interval (14 ppm) than in the surface 0- to 0.3-ft (1.6 ppm) depth interval (Table 12). In the vicinity of the 8-in. pipe protruding from the retaining wall (Transect -29), the DDT concentrations were similar in the surface and deeper intervals (68 ppm and 75 ppm), and slightly higher than the bank soil concentration from nearby Transect -32.5 (53.4 ppm, Phase I Source Investigation). Further south, around the Seep and areas of upland excavation (T-12.5, T-4.5), soil DDT concentrations did exhibit the “veneer” effect, with surface concentrations of 4 ppm to 13 ppm and <0.05 ppm below. However, under the north end of Levin Pier, embankment soils from T+2.25 were substantially more contaminated at depth (135 ppm), whereas the surface concentration of 3.5 ppm was similar to that at T-4.5 (3.8 ppm).
The diver-collected cores and vibracores near the north end of the Levin Pier were collected primarily to delineate the DDT hotspot identified during the Phase I Source Investigation. Although the highest Phase I concentration of 23,000 ppm (T+2.5 at the pier face) was not confirmed in Phase II, the core collected from that same location in 2003 did have the highest core sediment DDT concentration at 1161 ppm. Sediment total DDT concentrations decreased rapidly to the east under the pier, generally by three to four orders of magnitude within 40 ft, where soft sediment concentrations were similar to surface embankment soils (<6 ppm) (Figure 15). Sediment DDT concentrations also decreased relatively rapidly to the north and south, but remained in the 200-ppm range for 50 ft directly west of the Levin Pier (T+2.5), which is directly downslope from the hotspot.
Vibracores collected throughout the southern two thirds of Lauritzen Channel were intended to provide soft sediment distribution and DDT concentration data, primarily to fill spatial gaps in the 1999 data set, such as along the west edge of Lauritzen Channel. Vibracore data confirmed that a smaller hotspot of 156 ppm DDT appears on the west side of the channel across from the Levin Pier (Figure 14). There are no identified sources on the west side of the channel; it is more likely that contaminated
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sediment is being suspended and redistributed in the channel by a combination of vessel disturbance (propeller wash) and normal tidal currents. Distribution of YBM and associated DDT concentration is discussed further in Section 3.2.2.
3.2.2 YBM and DDT Distribution
All studies conducted to date demonstrate that elevated DDT concentrations in Lauritzen Channel are associated with soft, silty YBM, and that OBM is not contaminated with DDT. The highly compacted, firm OBM acts as a barrier to downward contaminant transport in the sediment column, and thus represents the vertical extent of sediment contamination. Therefore, the distribution of YBM in the channel facilitates the evaluation of contaminant distribution. The thickness of YBM present was measured in all sediment cores collected during the 1999 Sediment Investigation, Phase I Source Investigation, and Phase II Source Investigation. YBM thickness data from all three studies were integrated to estimate the present distribution and volume of YBM in Lauritzen Channel as follows.
First, data from the 1999 study had to be reprojected in ArcView geographic information system (GIS) (v. 3.2, ESRI GIS and Mapping Software) to plot on the same base map and scale as the more recent data. Second, all three data sets were combined in ArcView and then exported to Surfer (v. 8, Golden Software). In Surfer, the kriging method of gridding and contouring the data was used. Kriging is a commonly used algorithm that tends to follow the data patterns more smoothly and creates less of a "bulls-eye" effect around the original data points than do other gridding methods. The grid area was set to include the boundaries of the shoreline file so that sediment thickness could be extrapolated to the shoreline. The resulting contour plot of sediment thickness in 1-cm (0.1-m) intervals is provided in Figure 16. The volume utility in Surfer was used to compute the volume of YBM based on the sediment thickness at each of the data points shown in Figure 16. The resulting total volume of YBM was estimated to be 18,950 cubic yards (cy). Almost half of the volume (9100 cy or 48%) resides in Levin Berths B and C immediately west of the pier. The berths represent only about one third of the area of Lauritzen Channel but they are where sediment is expected to accumulate because it is where the channel is deepest. Approximately 465 cy, or 2.5%, is beneath the Levin Pier.
Prior studies and the Phase II Source Investigation also demonstrated that the total DDT concentrations in nearly all YBM in Lauritzen Channel soft sediment exceeds the remediation goal of 0.59 ppm, and that several hotspots have concentrations five to six orders of magnitude higher. Sediment and embankment soil DDT concentrations for all studies are shown superimposed on the sediment thickness plots for all of Lauritzen Channel (Figure 17) and the hotspot area in east central Lauritzen Channel (Figure 18). The hotspots represent only 0.1% of the surface area, but nearly half of the area (48%) has YBM DDT concentrations between 10 and 100 ppm and another 43% of the area has YBM DDT concentrations between 1 and 10 ppm. Because both east and west sides of the channel are active facilities, vessel traffic is common, although at irregular intervals and with varying degree of activity. The vessels are often tugboats with powerful engines, maneuvering barges or larger vessels in the channel, which can resuspend and mix unconsolidated soft sediment. Resuspended sediment can be transported and deposited elsewhere in the channel or even out of the channel if resuspension occurs during a strong ebb current.
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4.0 Discussion
Both water and mussel tissue chemistry results for 2003 show that DDT is still present above the remediation goal, and it is bioavailable and accumulated by resident biota. The Phase I and Phase II Source Investigations served to identify a broken concrete outfall, called the “Seep” in Year 6, below the riprap on the eastern shore about 180 ft north of the Levin Pier (Figure 8). The Phase II Source Investigation also confirmed and delineated the sediment hotspot beneath the north end of Levin Pier. The sediment hotspot, along with the Seep, is probably contributing to high tissue burdens of DDT in mussels collected from Transect +2 pilings. The highest concentrations of DDT were measured in water, sediment, and mussels sampled from the Seep pipe; high DDT in water samples taken approximately a year apart suggests that this Seep represents a persistent, if not continuous, source of DDT to the channel. Soon after draft 2003 data were provided to EPA, EPA took action to have the Seep pipe plugged and sealed when it was exposed at low tide (July 18, 2003). We recommend that the effectiveness of this action to reduce bioavailable DDT be monitored using mussels collected at the eight Year 6 monitoring locations. Once the potentially continuous source of dissolved DDT from the Seep is eliminated, the source of bioavailable DDT should be limited to sediment and embankment soils. The Phase II Source Investigation confirmed prior study results showing that DDT concentrations exceed the remediation goal of 0.59 ppm in nearly all the YBM in Lauritzen Channel. Continued monitoring would allow evaluation of the magnitude of the sediment/soil contribution until it is removed or otherwise remediated.
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5.0 References
Anderson BS, JW Hunt, BM Phillips, M Stoelting, J Becker, R Fairey, HM Puckett, M Stephenson, RS Tjeerdema, and M Martin. 2000. “Ecotoxicologic Change at a Remediated Superfund Site in San Francisco, California, USA.” Environmental Toxicology and Chemistry 19(4):879-887.
Antrim LD and NP Kohn. 2000a. Post-remediation Biomonitoring of Pesticides in Marine Waters Near the United Heckathorn Site, Richmond, California. PNNL-11911, Rev. 1. Prepared for the U.S. Environmental Protection Agency by Battelle Marine Sciences Laboratory, Sequim Washington; published by Pacific Northwest National Laboratory, Richland, Washington.
Antrim LD and NP Kohn. 2000b. Post-remediation Biomonitoring of Pesticides and Other Contaminants in Marine Waters and Sediment Near the United Heckathorn Site, Richmond, California.PNNL-13059, Rev 1. Prepared for the U.S. Environmental Protection Agency by Battelle Marine Sciences Laboratory, Sequim Washington; published by Pacific Northwest National Laboratory, Richland, Washington.
Kohn NP and TJ Gilmore. 2001. Field Investigation to Determine the Extent of Sediment Recontamination at the United Heckathorn Superfund Site, Richmond, California. PNNL-13730. Prepared for the U.S. Environmental Protection Agency by Battelle Marine Sciences Laboratory, Sequim Washington; published by Pacific Northwest National Laboratory, Richland, Washington.
Kohn NP and RK Kropp. 2001a. Year 3 Post-Remediation Monitoring of Pesticides and Other Contaminants in Marine Waters Near the United Heckathorn Superfund Site, Richmond, California.PNNL-13286. Prepared for the U.S. Environmental Protection Agency by Battelle Marine Sciences Laboratory, Sequim Washington; published by Pacific Northwest National Laboratory, Richland, Washington.
Kohn NP and RK Kropp. 2001b. Year 4 Post-Remediation Monitoring of Pesticides and Other Contaminants in Marine Waters Near the United Heckathorn Superfund Site, Richmond, California.PNNL-13632. Prepared for the U.S. Environmental Protection Agency by Battelle Marine Sciences Laboratory, Sequim Washington; published by Pacific Northwest National Laboratory, Richland, Washington.
Kohn NP and NR Evans. 2002. Phase I Source Investigation, Heckathorn Superfund Site, Richmond, California. PNNL-14088. Prepared for the U.S. Environmental Protection Agency by Battelle Marine Sciences Laboratory, Sequim Washington; published by Pacific Northwest National Laboratory, Richland, Washington.
Kohn NP and RK Kropp. 2002. Year 5 Post-Remediation Biomonitoring of Pesticides and Other Contaminants in Marine Waters Near the United Heckathorn Superfund Site, Richmond, California. PNNL-13990. Prepared for the U.S. Environmental Protection Agency by Battelle Marine Sciences Laboratory, Sequim, Washington; published by Pacific Northwest National Laboratory, Richland, Washington.
14
Figure 1. Location of the United Heckathorn Superfund Site, Richmond, California
15
Ñ
Ñ
Ñ
Ñ
#0
#0
#0
#0
Point Potrero
GravingDocks
LC-2
LC-3
LC-4
LC-1
Station Total DDT(ppm dry wt)
Dieldrin(ppb dry wt)
LC-1 130.0 3270.0
LC-2 13.9 382.0
LC-3 10.3 171.0LC-4 2.7 51.5
November 1998 Sediment Results
Total DDT Dieldrin
40.0 4.0Yr 1 (1997-98) 127.0 5.4Yr 2 (1998-99) 30.0 1.9Yr 3 (1999-2000) 52.0 5.4Yr 4 (2000-01) 25.0 0.7Yr 5 (2001-02) 9.3 0.7
Pre Remediation
(ppm wet wt)
303.1 Resident Mussel Tissue Results
1000 0 1000 Feet
N
EW
S
Ñ November 1998 Surface Sediment Station#0 Biomonitoring (mussels, water) Station
Total DDT Dieldrin
350.0 19.0Yr 1 (1997-98) 256.0 8.2Yr 2 (1998-99) 76.0 2.8Yr 3 (1999-2000) 75.0 6.4Yr 4 (2000-01) 150.0 3.3Yr 5 (2001-02) 24.0 0.6
Pre Remediation
(ppm wet wt)
303.4 Resident Mussel Tissue Results
Total DDT Dieldrin
No Data No DataYr 5 (2001-02) 39.7 1.16Pre Yr 5
(ppm wet wt)
Parr Canal - Year 5 only
Total DDT Dieldrin
629.0 87.0Yr 1 (1997-98) 1222.0 40.0Yr 2 (1998-99) 176.0 6.5Yr 3 (1999-2000) 310.0 28.0Yr 4 (2000-01) 340.0 6.3Yr 5 (2001-02) 139.0 2.9
Pre Remediation
(ppm wet wt)
303.2 Resident Mussel Tissue Results
Total DDT Dieldrin
2900.0 97.0Yr 1 (1997-98) 4504.0 184.0Yr 2 (1998-99) 606.0 28.0Yr 3 (1999-2000) 522.0 43.0Yr 4 (2000-01) 1136.0 32.0Yr 5 (2001-02) 310.0 17.0
Pre Remediation
(ppm wet wt)
303.3 Resident Mussel Tissue Results
Santa Fe Channel
LauritzenChannel
Par
r C
anal
Richm
ondI nner
Har bor
Channel
Figure 2. Five-Year Biomonitoring Results Summary, United Heckathorn Superfund Site
16
Figure 3. Locations for Year 6 (2003) Biomonitoring Sample Collection
17
Percent Lipids
Using All Data, y = 0.5035x + 0.3538R2 = 0.5597
Excluding 303.3, y = 0.6191x + 0.1954R2 = 0.8899
0.00
0.20
0.40
0.60
0.80
1.00
1.20
1.40
1.60
1.80
2.00
0.00 0.20 0.40 0.60 0.80 1.00 1.20 1.40 1.60 1.80 2.00
EPA 3450 Lipid %
Blig
h-D
yer
Lip
id %
Year 6 Data Seep (estimated) Year 6 excl 303.3
Seep, est regr excl 303.3 Linear (Year 6 Data) Linear (Year 6 excl 303.3)
303.3LC-End
303.1RIHC
303.4 SFC-End
303.2LC-Mouth
MansonLadder
T +2.08" Pipe, LC
Y6-06 Seep (1.16% B-D)(est by regression using all data)
Y6-06 Seep (1.18 % B-D, est by regression excluding 303.3)
Figure 4. Relationship between Lipid Measurements by Bligh-Dyer and EPA 3450 Methods
18
#S#S
#S
#S
#S
#S
#S
T35 OLDSCALEP2.7
T29 36FTN OF 8IN PIPE
T-12.5BANKT-11.5 1FT N SEEP
T-4.5BANK
T2.25BANKN
EW
S
70 0 70 FeetFormer BuildingsExcavation PitLauritzen ShorelineUnderwater Survey Transect Lines
#S Phase II Bank
Figure 5. Embankment Soil Sampling Locations, Phase II Source Investigation
19
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
T(+1.5)E
2-NE
1-NE
T(+2.5)E
1-SE
T(+3.5)E
2-SE
2-S
T(+4.5)E
2-W
1-SW
1-S
1-W
1-C (hotspot)
1-N
1-NW
2-N
N
EW
S
10 0 10 FeetFormer BuildingsExcavation PitLauritzen ShorelineUnderwater Survey Transect LinesPier face from 2003 GPS
Phase II Dive Cores#S Estimated#S GPS
Figure 6. Diver-Collected Core Sampling Locations for Hotspot Delineation, Phase II Source Investigation
20
#S
#S
#S
#S#S#S
#S
#S
#S
#S
#S
#S
H03-01H03-02
H03-03
H03-04H03-04 H03-05
H03-06
H03-07
H03-08
H03-10
H03-11
H03-12
N
EW
S
100 0 100 FeetFormer BuildingsExcavation PitLauritzen ShorelineUnderwater Survey Transect Lines
#S Phase II Cores
Figure 7. Vibracore Sampling Locations in Lauritzen Channel, Phase II Source Investigation
21
Fig
ure
8.
Em
bank
men
t Soi
l Sam
plin
g (c
lock
wis
e fr
om le
ft:
sam
ple
colle
ctor
with
soi
l aug
er a
t T(-
35),
sam
ple
colle
ctio
n at
T(-
12.5
), th
eSe
ep p
ipe
at lo
w ti
de 1
230
on M
ay 2
0, 2
003)
22
Fig
ure
9.
Rep
rese
ntat
ive
Div
er-C
olle
cted
Cor
es:
left
, H03
-1-W
with
sam
ple
prep
arat
ion
uten
sils
and
sam
ple
cont
aine
rs; c
ente
r, H
otsp
ot
H03
-1-C
; rig
ht, H
03-2
-NE
with
Old
er B
ay M
ud v
isib
le a
t bot
tom
23
Figure 10. Vibracore Sampling at Station H03-11, Mouth of Lauritzen Channel
24
Fig
ure
11.
Rep
rese
ntat
ive
Vib
raco
res
Split
for
Pro
cess
ing,
clo
ckw
ise
from
upp
er le
ft:
H03
-05
with
gra
yish
gre
en c
lay
OB
M, H
03-0
7 “c
lass
ic”
prof
ile o
f da
rk g
ray
silty
YB
M o
ver
high
ly c
onso
lidat
ed b
row
n cl
ay O
BM
, H03
-04
entir
e co
re, H
03-0
4 cl
ose
up o
f sa
nd la
yer
betw
een
18.5
and
23
inch
es d
own
core
25
0110100
1000
1000
0
ER
A19
9819
9920
0020
0120
0220
03
Total DDT Concentration (ng/L)
Ric
hmon
d In
ner
Har
bor
Cha
nnel
Laur
itzen
Cha
nnel
/Mou
thS
anta
Fe
Cha
nnel
/End
Laur
itzen
Cha
nnel
/End
Rem
edia
tion
Goa
lP
arr
Can
al
Rem
edia
tion
Goa
l 0.5
9 ng
/L
01
10
100
ER
A19
98
19
99
20
00
20
01
20
02
200
3
Dieldrin Concentration (ng/L)
La
uri
tze
n C
ha
nn
el/
En
dL
au
ritz
en
Ch
an
ne
l/M
ou
thS
an
ta F
e C
ha
nn
el/
En
dR
ich
mo
nd
In
ner
Ha
rbo
r C
han
ne
lR
em
ed
iati
on
Go
al
Parr
Can
al
Re
media
tion G
oa
l 0.1
4 n
g/L
Fig
ure
12.
Tot
al (
a) D
DT
and
(b)
Die
ldri
n in
Wat
er (
ng/L
, tot
al F
ract
ion)
, Pre
-Rem
edia
tion
Thr
ough
200
3
110100
1000
1000
0
E R
A19
9819
9920
0020
0120
0220
03
Total DDT Concentration (ng/g wet weight)
Ric
hm
on
d In
ner
Har
bo
r C
han
nel
Lau
ritz
en C
han
nel
/Mo
uth
Lau
ritz
en C
han
nel
/En
dS
anta
Fe
Ch
ann
el/E
nd
Par
r C
anal
0.1
1.0
10.0
100.
0
1000
.0
E R
A19
9819
9920
0020
0120
0220
03
Dieldrin Concentration (ng/g wet weight)
Ric
hm
on
d In
ner
Har
bo
r C
han
nel
Lau
ritz
en C
han
nel
/Mo
uth
Lau
ritz
en C
han
nel
/En
dS
anta
Fe
Ch
ann
el/E
nd
Par
r C
anal
Fig
ure
13.
Tot
al (
a) D
DT
and
(b)
Die
ldri
n in
Mus
sel T
issu
e (n
g/g
wet
wei
ght)
, Pre
-Rem
edia
tion
Thr
ough
200
3
See
p, 2
003:
135
,700
ng/
g w
et w
eigh
tS
eep,
200
3: 4
000
ng/g
wet
w
eigh
t
26
#S#S#S#S#S#S#S#S #S
#S#S#S
#S#S#S
#S#S
#S#S
#S
#S#S #S
#S
#S
#S
#S
#S
#S
T(+1. 5)E
2- NE
1- NE
T(+2. 5)E
1- SE
T(+3. 5)E
2- SE
2- S
T(+4. 5)E
2- W
1- SW
1- S
1- W1- C (hot spot)
1- N
1- NW
2- N
#156
#26.3
#7.1027.2
#
12.5
#
53.6
#0.09
#
0.09
#
0.88
#
2.12
N
EW
S
100 0 100 Feet
See expandedfigure
Former BuildingsExcavation PitLauritzen ShorelineUnderwater Survey Transect Lines
>1000#S
100 - 1000#S
10 - 100#S
1 - 10#S
<1#S
Sed Core/Bank - DDT (ppm)
Figure 14. Sediment DDT in Lauritzen Channel Younger Bay Mud, Phase II Source Investigation (2003)
27
#S#S
#S#S
#S#S
#S
#S #S
#S
#S
#S
#S #S
#S
#S
#S
#S
#S
#S
#S
2.50
16.0
#
27.2
#
28.7
#195 #
190
#
1161#26.8
#
0.85
# 1.20
# 51.6
# 5.87#43.0
#0.92#
25.6
# 6.50
#
22.1
#
53.6
156
26.3 #
26.4
N
EW
S
50 0 50 FeetFormer BuildingsExcavation PitLauritzen ShorelineUnderwater Survey Transect Lines>1000#S100 - 1000#S10 - 100#S1 - 10#S<1#S
Sed Core/Bank - DDT (ppm)
Figure 15. Sediment DDT in Hotspot Delineation Area, Phase II Source Investigation (2003)
28
Figure 16. Plot of Sediment Thickness using 1999 Sediment Investigation Data, Phase I Under-Pier Survey Data, and Phase II Diver-Collected and Vibracore Data
29
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S#S#S
#S#S
#S#S
#S#S
#S#S
#S#S#S#S#S#S#S
#S#S
#S
#S
#S#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S#S#S#S#S#S#S#S #S
#S#S#S
#S#S#S
#S#S
#S#S
#S
#S#S #S
#S
#S
#S
#S
#S
#S
1.26
2.69
1.77
8.91
1.79
53.4
T(+1. 5)E
2- NE
1- NE
T(+2. 5)E
1- SE
T(+3. 5)E
2- SE
2- S
T(+4. 5)E
2- W
1- SW
1- S
1- W1- C (hot spot)
1- N
1- NW
2- N
#156
#26.3
#7.1027.2
#
12.5
#
53.6
#0.09
#
0.09
#
0.88
#
2.12
#
85.0#
85.0#
37.9
# 24.2
# 24.2
#45.2
#0.24
#2.11
#0.05#
3.26#0.05
#104
#5.67
#43.4 #42.4
#6.77
#20.6
#3.45
#2.25
#3.45
# 42.4
#
2.82
N
EW
S
100 0 100 Feet
See expandedfigure
1999 2002 2003
Former BuildingsExcavation PitLauritzen ShorelineUnderwater Survey Transect Lines
>1000#S
100 - 1000#S
10 - 100#S
1 - 10#S
<1#S
Sed Core/Bank - DDT (ppm)
YBM Thickness (meters)
Figure 17. Sediment DDT Concentrations (1999, 2002, 2003) and YBM Thickness in Lauritzen Channel
30
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S
#S#S#S
#S#S
#S#S
#S#S
#S#S
#S#S
#S
#S#S#S #S
#S#S
#S
#S
#S
#S
#S
#S
#S
#S#S
#S#S
#S#S
#S
#S #S
#S
#S
#S
#S #S
#S
#S
#S
#S
#S
#S
#S
16.9
10.7
10.4
5.92
32.3
317
46.2
0.62
144
3.6014.9
3.50
33.8
0.8339.0
39.0
0.026
8.76
30.1
117
42.4
2.50
16.0
#
27.2
#
28.7
#195 #
190
#
1161#26.8
#
0.85
# 1.20
# 51.6
# 5.87#43.0
#0.92#
25.6
# 6.50
#
22.1
#
53.6
156
26.3
104
#
23190
#
370
#
214
#
26.4
#
0.80
#
3.00
#
0.05
#
34.4
#
13.4#
25.0
#
1591
# 13.7
#
163
#
8.30
#
0.48
N
EW
S
50 0 50 Feet
1999 2002 2003
Former BuildingsExcavation PitLauritzen ShorelineUnderwater Survey Transect Lines>1000#S100 - 1000#S10 - 100#S1 - 10#S<1#S
Sed Core/Bank - DDT (ppm)
YBM Thickness (meters)
Figure 18. Sediment DDT Concentrations (1999, 2002, 2003) and YBM Thickness in East Central Lauritzen Channel
31
Table 1. Sampling Stations for Year 6 (2003) Post-remediation Monitoring of the United Heckathorn Site
Station Number Station Name
Sample Types Collected Location Remarks
303.1 Richmond Inner Harbor Channel
Seawater,mussels
37º54' 32.869" N 122º21' 33.523" W
On western most wooden dolphin, near abandoned Ford automotive plant, southeast of public fishing pier.
303.2 Lauritzen Channel/ Mouth (South)
Seawater,mussels
37º55' 12.236" N 122º22' 01.298" W
On east side of canal, on pilings beneath the Levin Dock near the northern end of a large fender structure.
303.3 Lauritzen Channel/ End (North)
Seawater,mussels
37º55' 22.415" N 122º21 59.980" W
On east side of canal, southern end of small wooden pier that extends out into the channel.
303.4 Santa Fe Channel/End Seawater, mussels
37º55' 21.081" N 122º22' 17.694" W
At northwest corner of floating boat shed, east of small boat fuel dock
303.6 Parr Canal Seawater(a) 37º55' 11.817" N 122º21' 45.996" W
8” Pipe, Northeast Lauritzen Channel
Mussels 37º 55' 25.349" N 122º 21' 59.383" W
Mussels collected from nearby pilings
Manson Ladder Mussels 37º 55' 23.332" N 122º 22' 01.646" W
Seep Seawater, mussels
37º 55' 22.99" N 122º 21' 59.66" W
Transect +2.5 Mussels 37º 55' 21.156" N 122º 22' 00.241" W
Mussels collected from pilings under north end of Levin Pier
(a) Mussels were not collected in Parr Canal. As noted in Appendix A, mussels were not plentiful, possibly due to poor substrate or lower salinity.
32
Tab
le 2
. E
mba
nkm
ent S
oil S
ampl
e C
olle
ctio
n In
form
atio
n
Stat
ion
ID
Dat
e T
ime
Stat
ion
Des
crip
tion
Stat
ion
Posi
tion
(Lat
itude
Lon
gitu
de)
Dep
thIn
terv
al(f
t)Se
dim
ent D
escr
iptio
n C
hem
istr
y Sa
mpl
e ID
T
(-35
)ol
d sc
ale
05/2
0/03
10
:48
base
of
vert
ical
wal
l 37
° 55
' 26.
6910
8" N
12
2° 2
1' 5
9.05
878"
W
0-0.
3da
rk g
ray
(bro
wn
at s
urfa
ce),
mos
tly
sand
, silt
y sa
nd, s
ome
shel
l deb
ris
Hec
k03-
001
T(-
35)
old
scal
e 05
/20/
03
10:4
8 ba
se o
f ve
rtic
al w
all
37°
55' 2
6.69
108"
N
122°
21'
59.
0587
8" W
0.
5-1
med
-coa
rse
sand
, mix
ed w
/gra
vel &
m
ud, b
row
n-da
rk g
ray
Hec
k03-
002
T(-
29)
36 f
t N
of
8" p
ipe
05/2
0/03
11
:08
inte
rsec
tion
of p
iling
row
&
vert
ical
wal
l, ba
se o
f ve
rtic
al
wal
l
37°
55' 2
5.81
612"
N
122°
21'
59.
1947
2" W
0-
0.5
very
gra
vely
at s
urfa
ce
Hec
k03-
004
T(-
29)
36 f
t N
of
8" p
ipe
05/2
0/03
11
:08
inte
rsec
tion
of p
iling
row
&
vert
ical
wal
l, ba
se o
f ve
rtic
al
wal
l
37°
55' 2
5.81
612"
N
122°
21'
59.
1947
2" W
0.
5-1
grav
ely
mud
dy s
and
w/o
rgan
ic o
dor,
br
own
@ s
urfa
ce, g
reen
ish
gray
at
dept
hH
eck0
3-00
3
T(-
12.5
) B
ank
05/2
0/03
11
:40
slip
pery
ban
k at
bas
e of
ver
tical
w
all,
arm
ored
abo
ve ti
de m
ark,
cl
ayey
bel
ow
37°
55' 2
3.02
334"
N
122°
21'
59.
5302
3" W
0-
0.2
stic
ky c
lay/
silt
w/g
rave
l and
org
anic
de
bris
, hig
h pa
stic
ity c
lay
Hec
k03-
006
T(-
12.5
) B
ank
05/2
0/03
11
:40
slip
pery
bank
at b
ase
of v
ertic
al
wal
l, ar
mor
ed a
bove
tide
mar
k,
clay
ey b
elow
37°
55' 2
3.02
334"
N
122°
21'
59.
5302
3" W
0.
5-1
very
fir
m, s
ticky
cla
y, d
ark
gray
, H2S
od
orH
eck0
3-00
5
T(-
11.5
) Se
ep 1
-ft N
05
/20/
03
12:0
0 1
ft n
orth
of
seep
(cl
ay p
ipe
outf
all)
37°
55' 2
2.90
342"
N
122°
21'
58.
5304
7" W
0-
0.2
stic
ky g
ray
clay
w/o
rgan
ic m
atte
r H
eck0
3-00
7
T(-
11.5
) Se
ep 1
-ft N
05
/20/
03
12:0
0 1
ft n
orth
of
seep
(cl
ay p
ipe
outf
all)
37°
55' 2
2.90
342"
N
122°
21'
58.
5304
7" W
0.
5-1
silty
cla
y m
atri
x, lo
ts o
f br
own
orga
nic
mat
ter,
H2S
odo
r H
eck0
3-00
8
T(-
11.5
) Se
ep 1
-ft N
05
/20/
03
12:0
0 1
ft n
orth
of
seep
(cl
ay p
ipe
outf
all)
37°
55' 2
2.90
342"
N
122°
21'
58.
5304
7" W
N
Aso
upy
brow
n sa
ndy
silt/
clay
col
lect
ed
from
abo
ut 1
ft u
p se
ep p
ipe
Hec
k03-
009
T(-
4.5)
Ban
k 05
/20/
03
12:4
0 ba
se o
f la
rge
cobb
les
& r
ipra
p be
low
gra
vel v
enee
r 37
° 55
' 21.
8319
5" N
12
2° 2
1' 5
9.71
644"
W
0-0.
2gr
ay s
andy
silt
-cla
y br
own
orga
nic
mat
ter
thro
ugho
ut, n
o od
or
Hec
k03-
011
T(-
4.5)
Ban
k 05
/20/
03
12:4
0 ba
se o
f la
rge
cobb
les
& r
ipra
p be
low
gra
vel v
enee
r 37
° 55
' 21.
8319
5" N
12
2° 2
1' 5
9.71
644"
W
0.5-
1da
rk g
ray
sand
y si
lty c
lay
Hec
k03-
010
T(+
2.25
) B
ank
05/2
0/03
13
:13
on s
lope
just
bel
ow g
eote
xtile
, ab
out 8
ft h
oriz
onta
l dis
tanc
e fr
om v
ertic
al w
all
37°
55' 2
1.19
563"
N
122°
21'
59.
8267
5" W
0-
0.2
dark
gra
y cl
ay
Hec
k03-
012
T(+
2.25
) B
ank
05/2
0/03
13
:13
on s
lope
just
bel
ow g
eote
xtile
, ab
out 8
ft h
oriz
onta
l dis
tanc
e fr
om v
ertic
al w
all
37°
55' 2
1.19
563"
N
122°
21'
59.
8267
5" W
0.
5-1
dark
gra
y cl
ay
Hec
k03-
013
33
Tab
le 3
. D
iver
-Col
lect
ed C
ore
Sam
plin
g In
form
atio
n
Stat
ion
ID
Dat
e T
ime
Unc
orre
cted
W
ater
Dep
th
(ft)
Sam
pler
Cor
eD
iam
eter
(i
n)Pe
netr
atio
nD
epth
(cm
) D
escr
iptio
n an
d C
omm
ents
H
03-1
N
05/2
1/03
10
:45
23.2
Pu
sh C
ore
2 12
H03
-2N
E
05/2
1/03
10
:50
17.2
Pu
sh C
ore
2 15
St
eep
clay
, gra
velly
H
03-2
N
05/2
1/03
11
:00
23.7
Pu
sh C
ore
2 27
R
ocky
, ste
ep
H03
-1N
W
05/2
1/03
11
:20
29.5
Pu
sh C
ore
2 52
So
ft b
otto
m, f
ull p
enet
ratio
n, c
an f
eel d
ebri
s ar
ound
on
botto
m,
hard
spo
t at b
otto
m o
f tu
be tr
ying
to r
etai
n H
03-1
C (
Hot
spot
) 05
/21/
03
11:2
4 23
.0
Push
Cor
e 3.
5 30
St
eep
soft
cob
bly,
pen
etra
ted
fully
but
onl
y ~1
/2 r
etai
ned
H03
-1N
E
05/2
1/03
11
:27
11.2
Pu
sh C
ore
2 23
U
nder
pie
r, v
ery
stee
p an
d gr
avel
ly
H03
-1W
05
/21/
03
12:3
9 32
.3
Push
Cor
e 2
45
12-f
t bar
ge w
idth
fro
m p
ier
face
; ful
l pen
etra
tion
but r
etri
eved
~30
cm
, fla
t bot
tom
, sof
t, no
roc
ks, n
o sh
ells
H
03-2
W
05/2
1/03
12
:43
34.9
Pu
sh C
ore
2 45
15
ft o
ut (
W)
of H
03-1
W.
Ver
y so
ft, v
ery
flat
, no
rock
s, to
tal
pene
trat
ion,
har
d sp
ot a
t ~ 1
4", z
ero
visi
bilit
y H
03-1
S 05
/21/
03
12:4
7 23
.3
Push
Cor
e 2
15
Face
of
pier
bet
wee
n T
+3
& T
+4.
Slop
ing,
roc
ky, l
ooki
ng f
or s
oft
spot
bet
wee
n ro
cks,
mov
ed o
ut ~
3 ft
dee
per
to g
et s
oft s
pot,
pene
trat
ion
~6"
H03
-1SE
05
/21/
03
12:5
2 11
.0
Push
Cor
e 2
~10
Slop
ing,
roc
ky, v
ery
unev
en, l
ooks
like
ligh
t bro
wn
clay
plu
g co
llect
ed
H03
-1SW
05
/21/
03
13:0
0 32
.1
Push
Cor
e 2
45
App
rox.
12
ft o
ff p
ier
face
bet
wee
n T
+4
and
T+
5. C
ore
reta
ined
, ro
cky,
une
ven,
no
visi
bilit
y, b
ut s
oft s
pots
bet
wee
n ro
cks,
gra
velly
, pe
netr
atin
g th
roug
h ro
cks
~16"
, but
sof
t thr
ough
out
H03
-2S
05/2
1/03
13
:04
23.1
Pu
sh C
ore
2 12
st
eep,
ver
y ro
cky,
big
roc
ks, l
ooki
ng f
or s
oft s
pot,
forc
ing
core
th
roug
h ro
cks,
sof
t to
~14"
, ~30
% s
lope
H
03-2
SE
05/2
1/03
13
:10
11.3
Pu
sh C
ore
2 23
R
ight
aga
inst
T+4
, hal
fway
bet
wee
n pi
er f
ace
and
back
slo
pe.
Ver
y un
even
, big
roc
ks, s
teep
slo
pe, v
ery
rock
y, tr
ying
to f
ind
soft
sp
ot, p
enet
ratin
g be
twee
n ro
cks
H03
-T(+
4.5)
E
05/2
1/03
14
:08
6.3
Push
Cor
e 2
27
Em
bank
men
t jus
t bel
ow r
ipra
p; v
ery
stee
p sl
opin
g, c
lay
like
at to
p,
hard
cla
y, m
ovin
g do
wn
slop
e to
dee
per,
~1
ft p
enet
ratio
n,
estim
ated
5 f
t wat
er
H03
-T(+
3.5)
E
05/2
1/03
14
:16
4.9
Push
Cor
e 2
15
Cla
y em
bank
men
t bel
ow lo
w ti
de; r
ocky
ste
ep, h
ard
clay
H
03-T
(+2.
5)E
05
/21/
03
14:2
0 6.
6 Pu
sh C
ore
2 21
E
mba
nkm
ent,
sub
tidal
, bet
wee
n T
+2
& T
+3;
ste
ep c
lay
bank
, un
ifor
m s
lope
, slig
htly
roc
ky, s
hells
, som
e ro
cks
H03
-T(+
1.5)
E
05/2
1/03
14
:26
6.3
Push
Cor
e 2
30
hard
cla
y su
rfac
e se
mi r
ocky
, cla
y w
all a
t 5 f
t, st
eep,
mov
ing
slig
htly
dee
per
to f
ind
soft
spo
t, so
ft s
pot b
etw
een
very
har
d cl
ay
34
Tab
le 4
. V
ibra
core
Sam
plin
g In
form
atio
n
Stat
ion
ID
Dat
e T
ime
Lat
itude
(d
d m
m.m
mm
) L
ongi
tude
(d
d m
m.m
mm
)
Unc
orre
cted
W
ater
Dep
th (
ft)
Cor
e R
ecov
ered
(f
t)
Com
men
ts
H03
-01
05/2
2/03
14
:57
37º 5
5.36
61
122º
22.
0340
22
.6
3.2
~4m
S o
f ta
rget
, sam
ple
time
1504
, gra
y Y
BM
and
br
own
OB
M o
n ou
tsid
e of
bar
rel,
~2 f
t YB
M o
n ~1
ft O
BM
H
03-0
2 05
/22/
03
14:2
2 37
º 55.
3693
12
2º 2
2.01
80
30.5
~0
.3
Too
k 2
atte
mpt
s. S
ampl
e tim
e 14
26, s
mal
l bit
of
soft
sed
imen
t 1-1
.5"
on p
lug
of s
tiff
gray
cla
y O
BM
H
03-0
3 05
/22/
03
15:4
7 37
º 55.
3500
12
2º 2
2.03
30
25.6
2.
8 sa
mpl
e tim
e 15
51, g
ray
YB
M &
bro
wn
OB
M o
n ou
tsid
e of
bar
rel,
2.8'
ret
aine
d H
03-0
4 05
/22/
03
16:1
7 37
º 55.
3313
12
2º 2
2.04
93
21.0
3.
6 sa
mpl
e tim
e 16
23
H03
-05
05/2
2/03
13
:44
37º 5
5.33
29
122º
22.
0148
37
.8
3.9
sam
ple
colle
cted
at 1
352,
47"
(3.
9')
tota
l col
lect
ed,
all Y
BM
exc
ept 1
-2"
gray
cla
y pl
ug
H03
-06
05/2
2/03
10
:05
37º 5
5.30
14
122º
22.
0540
13
.0
3.8
firm
OB
M p
lug
in c
atch
er (
brow
n), s
ampl
e co
llect
ed 1
010,
gra
y sa
ndy
clay
, pic
ked
up b
y A
L
& N
B a
t 104
3 H
03-0
7 05
/22/
03
16:4
0 37
º 55.
3143
12
2º 2
2.04
18
27.5
3.
2 sa
mpl
e tim
e 16
45
H03
-08
05/2
2/03
10
:44
37º 5
5.27
30
122º
22.
0588
15
.9
2.0
sam
ple
colle
cted
at 1
050,
stic
ky b
row
n cl
ay o
n ba
rrel
, ste
ep s
lope
, une
ven
feel
ing,
gra
velly
top,
~1
ft g
ray
sand
on
brow
n st
iff
OB
M c
lay
H03
-10
05/2
2/03
12
:29
37º 5
5.28
93
122º
22.
0213
37
.3
4.0
hit h
ard
clay
~4.
5 ft
, har
d gr
ay p
lug
at b
otto
m
H03
-11
05/2
2/03
11
:26
37º 5
5.24
61
122º
22.
0638
19
.0
2.1
diff
icul
t anc
hori
ng, w
ind
& h
ard
botto
m, s
ampl
e tim
e 11
31
H03
-12
05/2
2/03
11
:57
37º 5
5.25
51
122º
22.
0234
37
.3
4.0
sam
ple
time
1203
, pen
etra
ted
3.5
ft to
har
d cl
ay,
no p
lug,
but
OB
M w
ould
be
at b
otto
m o
f co
re
35
Tab
le 5
. C
hem
istr
y Su
bsam
ples
Pre
pare
d fr
om C
ores
Stat
ion
ID
Tot
al C
ore
Len
gth
(ft)
D
epth
Inte
rval
(ft
) Se
dim
ent D
escr
iptio
n C
hem
istr
y Sa
mpl
e ID
A
liquo
ts
Com
men
ts
Div
er-C
olle
cted
Cor
es
0-0.
2 m
uddy
san
d, o
live
gree
n, lo
ose
(YB
M)
H03
-T(+
1.5)
-E
1.0
0.2-
1sa
ndy
mud
, bro
wn,
stif
f, c
ompa
ct (
OB
M),
m
ostly
cla
y (p
last
ic)
Hec
k03-
037
Pest
, GS/
TO
C
stee
p cl
ay b
ank,
sam
pled
fro
m s
oft
spot
in c
lay,
pho
to in
line
r, c
ompo
site
d in
pie
pla
te
0-0.
2 ol
ive
brow
n, lo
ose,
mud
dy s
and
(YB
M)
H03
-T(+
2.5)
-E
0.7
0.2-
0.7
sand
mud
, oliv
e gr
ay, c
ompa
ct (
OB
M)
Hec
k03-
036
Pest
, GS/
TO
C
hard
cla
y fr
om u
nifo
rm s
lope
, som
e ro
ck/g
rave
l, sh
ell h
ash
cove
r, p
hoto
in
liner
, com
posi
ted
in p
ie p
late
0-
0.25
da
rk g
ray,
mud
dy s
and
(YB
M)
H03
-T(+
3.5)
-E
0.5
0.25
-0.5
gr
ay s
andy
mud
, com
pact
, stif
f (O
BM
) H
eck0
3-03
5 Pe
st, G
S/T
OC
st
eep
clay
ban
k, c
ompo
site
d in
pie
pl
ate,
pho
to in
line
r 0-
0.1
mud
dy s
and,
dar
k gr
ay (
YB
M)
H03
-T(+
4.5)
-E
0.9
0.1-
0.9
sand
y m
ud, b
row
n, c
ompa
ct (
OB
M)
Hec
k03-
034
Pest
, GS/
TO
C
from
ste
ep c
lay
bank
, all
com
posi
ted
toge
ther
in p
ie p
late
, pho
to in
line
r
H03
-2-S
E
0.75
0-
0.75
mud
dy s
and,
fin
er a
t top
, poo
rly
sort
ed,
fine
to c
oars
e sa
nd, a
few
peb
bles
, pile
w
orm
s, d
ark
gray
(Y
BM
), a
few
gra
y bl
obs
poss
ibly
fro
m O
BM
bel
ow
Hec
k03-
033
Pest
, GS/
TO
C
com
posi
ted
in p
ie p
late
, pho
to in
line
r
0-0.
25
mud
dy s
and,
dar
k gr
ay, l
oose
(Y
BM
) H
03-1
-SE
0.
5 0.
25-0
.5m
uddy
san
d, b
row
n, c
ompa
ct, m
ottle
d (O
BM
)H
eck0
3-03
0 Pe
st, G
S/T
OC
sl
opin
g ro
cky,
une
ven
botto
m, l
ittle
pe
netr
atio
n, a
ll co
mpo
site
d to
geth
er in
pi
e pl
ate,
pho
to in
line
r
H03
-2-S
0.
4 0-
0.4
mud
dy s
and,
peb
bly,
lous
e, d
ark
gray
(Y
BM
)H
eck0
3-03
2 Pe
st, G
S/T
OC
co
mpo
site
d in
pie
pla
te, p
hoto
in li
ner
H03
-1-S
W
1.5
0-1.
5 m
uddy
san
d, d
ark
gray
, loo
se, p
oorl
y so
rted
(Y
BM
) H
eck0
3-03
1 Pe
st, G
S/T
OC
ro
cky,
une
ven
botto
m, s
ampl
ed s
oft
sedi
men
t bet
wee
n ro
cks,
com
posi
ted
in
pie
plat
e, p
hoto
in li
ner
H03
-2-W
1.
5 0-
1.5
mud
dy s
and,
dar
k gr
ay, l
oose
, poo
rly
sort
ed (
YB
M)
Hec
k03-
028
Pest
, GS/
TO
C
sam
ple
all c
ompo
site
d in
pie
pla
te,
phot
o in
line
r
H03
-1-S
0.
6 0-
0.6
pebb
ly m
uddy
san
d, lo
ose,
dar
k gr
ay
(YB
M)
Hec
k03-
029
Pest
, GS/
TO
C
slop
ing,
roc
ky, s
ampl
ed f
rom
sof
t spo
t be
twee
n ro
cks
2-3
ft f
rom
pie
r, n
o ph
oto,
ext
rude
d to
o so
on, c
ompo
site
d in
pie
pla
te
H03
-1-W
1.
5 0-
1.5
mud
dy s
and,
dar
k gr
ay, l
oose
(Y
BM
),
shel
l fra
gmen
ts, p
oorl
y so
rted
, som
ewha
t st
icky
H
eck0
3-02
7 Pe
st, G
S/T
OC
so
ft a
ll th
e w
ay, f
lat b
otto
m, n
o ro
cks
or d
ebri
s, c
ompo
site
d in
pie
pla
te,
phot
o in
line
r 0-
0.1
dark
gra
y, m
uddy
san
d, lo
ose
(YB
M)
H03
-1-N
0.
4 0.
1-0.
4 br
own
mud
dy f
ine
sand
, com
pact
(O
BM
) H
eck0
3-01
7 Pe
st, G
S/T
OC
en
tire
inte
rval
(co
re?)
com
posi
ted
in
pie
plat
e an
d th
en c
olle
cted
into
sa
mpl
e ja
rs, p
hoto
take
n in
line
r
36
Tab
le 5
. (c
ontd
)
Stat
ion
ID
Tot
al C
ore
Len
gth
(ft)
D
epth
Inte
rval
(ft
) Se
dim
ent D
escr
iptio
n C
hem
istr
y Sa
mpl
e ID
A
liquo
ts
Com
men
ts
Div
er-C
olle
cted
Cor
es (
cont
d)
0-0.
25m
uddy
san
d, d
ark
gray
(Y
BM
), lo
ose,
po
orly
sor
ted
Hec
k03-
022
Pest
, GS/
TO
C
H03
-2-N
E
0.5
0.25
-0.5
mud
dy f
ine
sand
, bro
wn,
com
pact
, wel
l so
rted
(O
BM
) N
A
NA
sam
ple
com
posi
ted
from
upp
er d
ark
gray
inte
rval
onl
y -
brow
n m
ater
ial
excl
uded
, pho
to ta
ken
in li
ner
H03
-2-N
0.
9 0-
0.9
pebb
ly m
uddy
san
d, d
ark
gray
, loo
se,
wor
ms,
she
ll fr
agm
ents
(O
BM
) H
eck0
3-02
3 Pe
st, G
S/T
OC
en
tire
inte
rval
com
posi
ted
in p
ie p
late
be
fore
aliq
uot d
istr
ibut
ion,
pho
to ta
ken
in li
ner
H03
-1-N
W
1.7
0-1.
7 m
uddy
san
d, d
ark
gray
, loo
se, b
row
nish
at
top
(YB
M)
Hec
k03-
024
Pest
, GS/
TO
C
liner
ful
l 2 f
t 4 in
, cak
e ba
tter
cons
iste
ncy,
com
posi
ted
in p
ie p
late
H03
-1-C
1.
0 0-
1.0
mud
dy s
and,
dar
k gr
ay, l
oose
, peb
bles
(Y
BM
), p
oorl
y so
rted
H
eck0
3-02
5 Pe
st, G
S/T
OC
al
l sam
ple
com
posi
ted
in p
ie p
late
, ph
oto
take
n in
line
r
H03
-1-N
E
0.75
0-
0.75
pe
bbly
, mud
dy f
ine
to c
oars
e sa
nd, p
oorl
y so
rted
, loo
se, d
ark
gray
(YB
M)
Hec
k03-
026
Pest
, GS/
TO
C
all c
ompo
site
d in
pie
pla
te, p
hoto
in
liner
Vib
raco
res
0-0.
3 sa
nd, g
rave
l H
eck0
3-01
4 Pe
st, G
S/T
OC
0.3-
1.4
dark
gra
y Y
BM
, oily
laye
r in
YB
M 8
-10
inch
es
Hec
k03-
014
Pest
, GS/
TO
C
1.4-
1.7
coar
se s
and
NA
N
A
H03
-06
3.7
1.7-
3.7
OB
M, t
an, s
tiff,
fir
m c
lay
NA
N
A
Hec
k03-
014
com
posi
te o
f to
p 17
in
(1.4
2 ft
), p
hoto
may
sho
w d
uct t
ape
indi
catin
g H
03-1
1, b
ut s
ampl
e st
atio
n 11
is a
ctua
lly H
03-0
6
0-0.
7 gr
avel
, gra
y cl
ay, s
and
light
gra
y an
d ta
n H
eck0
3-01
5 Pe
st, G
S/T
OC
H03
-08
2.2
0.7-
2.2
light
tan,
san
dy O
BM
N
A
NA
0-0.
7Y
BM
, gra
y/ol
ive
gray
with
san
d/gr
avel
at
top
Hec
k03-
016
Pest
, GS/
TO
C
0.7-
1.0
cons
olid
ated
tan
clay
N
A
NA
1.0-
1.3
soft
er, s
and
(tan
) cl
ay la
yer
NA
N
A
H
03-0
11
2.4
1.3-
2.4
light
bro
wn
OB
M, s
andy
cla
y N
A
NA
H03
-012
3.
8 0-
3.8
all b
lack
silt
y cl
ay Y
BM
H
eck0
3-03
8 Pe
st, G
S/T
OC
co
mpo
site
acr
oss
entir
e co
re, f
ield
pe
rson
nel n
oted
sta
nd o
f O
BM
at e
nd
of c
ore
but w
ere
not a
ble
to k
eep
0-2.
3 bl
ack
YB
M
2.6-
2.6
fine
san
d an
d bl
ack
2.6-
3.4
blac
k Y
BM
H
eck0
3-03
9 Pe
st, G
S/T
OC
co
mpo
site
0-4
1 in
(3.
42 f
t)
H03
-010
4.
3
3.4-
4.2
blac
k O
BM
cla
y, d
ry, c
rum
bly
NA
N
A
37
Tab
le 5
. (c
ontd
)
Stat
ion
ID
Tot
al C
ore
Len
gth
(ft)
D
epth
Inte
rval
(ft
) Se
dim
ent D
escr
iptio
n C
hem
istr
y Sa
mpl
e ID
A
liquo
ts
Com
men
ts
Vib
raco
res
(con
td)
0-2.
0 bl
ack
YB
M c
lay,
sof
t 2-
2.3
oliv
e gr
een
sand
2.
3-2.
8 Y
BM
bla
ck
Hec
k03-
043
Pest
, GS/
TO
C
com
posi
te 0
-34
in (
2.83
ft)
H
03-0
5 4.
0
2.8-
4.0
OB
M g
ray
clay
, dry
cru
mbl
y N
A
NA
0-0.
1 Y
BM
, bla
ck, g
rave
l H
eck0
3-04
0 Pe
st, G
S/T
OC
H03
-02
0.3
0.1-
0.3
OB
M, d
ark
gray
, pla
stic
N
A
NA
0-1.
0bl
ack
YB
M, f
ine
silt
clay
sm
ooth
, som
e w
orm
sH
eck0
3-04
4 Pe
st, G
S/T
OC
1.0-
2.2
tan
OB
M w
ith s
and,
stif
f cl
ay w
ith r
ust
colo
red
sand
N
A
NA
H03
-01
3.3
2.2-
3.33
ta
n O
BM
mor
e cl
ay, s
tiffe
r, d
ense
r N
A
NA
0-0.
8Y
BM
, gra
vel a
t top
, silt
y cl
ay, s
moo
th,
blac
k st
icky
0.8-
1.3
YB
M, b
lack
silt
y cl
ay w
ith s
ome
sand
y te
xtur
e
Hec
k03-
045
Pest
, GS/
TO
C
1.3-
1.7
OB
M g
ray
clay
N
A
NA
1.7-
2.0
OB
M b
row
n N
A
NA
2.0-
2.5
sand
mix
ed w
ith c
lay
redd
ish
brow
n N
A
NA
2.5-
2.8
OB
M b
row
n st
iff
smoo
th c
lay
NA
N
A
H03
-03
3.0
2.8-
3.0
sand
y cl
ay b
row
n N
A
NA
0-0.
8 pe
bble
s, s
and
blac
k Y
BM
0.8-
1.5
few
er p
ebbl
es, o
rgan
ic m
atte
r, s
andy
cla
y,
blac
kH
eck0
3-04
6 Pe
st, T
OC
1.5-
1.9
blac
k-gr
ay o
live
sand
and
few
er p
ebbl
es
1.9-
2.1
blac
k sh
iny
laye
r, c
lay,
org
anic
mat
ter
2.1-
3.1
gray
OB
M, c
lay
smoo
th, s
lick
Hec
k03-
047
Pest
, TO
C
Hec
k03-
046
0-18
.5 in
(0-
1.54
ft)
Hec
k03-
047
23-3
7.5
in (
1.92
-3.1
3 ft
) in
clud
ing
orga
nic
mat
ter
in s
hiny
laye
r at
top
of (
dist
urbe
d) O
BM
H03
-04
3.7
3.1-
3.7
OB
M ta
n cl
ay, m
ore
grea
sy te
xtur
e N
A
NA
0-1.
3Y
BM
bla
ck c
lay
smoo
th, w
orm
H
eck0
3-04
8 Pe
st, G
S/T
OC
H
eck0
3-04
8 Y
BM
onl
y 0-
16 in
(1.
33
ft),
cla
ssic
pro
file
: YB
M o
n sa
nd o
n O
BM
sur
face
1.
3-2.
3 sa
nd g
ray
to ta
n br
own
to r
eddi
sh b
row
n N
A
NA
H03
-07
2.9
2.3-
2.9
OB
M ta
n cl
ay s
moo
th
NA
N
A
38
Tab
le 6
. C
once
ntra
tions
of
DD
T, D
ield
rin,
and
Tot
al S
uspe
nded
Sol
ids
(TSS
) in
the
Tot
al F
ract
ion
of W
ater
Sam
ples
Col
lect
ed in
Fe
brua
ry 2
003
for
Post
-rem
edia
tion
Mon
itori
ng o
f th
e U
nite
d H
ecka
thor
n Su
perf
und
Site
Con
cent
ratio
n (n
g/L
)
Stat
ion
Loc
atio
n T
SS
(mg/
L)
Die
ldri
n 2,
4'-D
DE
4,
4'-D
DE
2,
4'-D
DD
4,
4'-D
DD
2,
4'-D
DT
4,
4'-D
DT
T
otal
DD
T
Aro
clor
125
4
303.
1A
8
0.50
UI(a
)0.
76U
I 0.
50
U
0.50
UI
0.50
UI
0.50
UI
0.50
UI
ND
5.
0 U
30
3.1B
Ric
hmon
d In
ner
Har
bor
Cha
nnel
6
0.
21 J
0.
50U
0.
50
U
0.50
U
0.50
UI
0.50
UI
0.52
P 0.
52 P
5.
0 U
M
ean(b
) 7
0.
21 J
N
A
NA
N
A
NA
N
A
0.52
P N
A
NA
st
anda
rd d
evia
tion
1.4
NA
N
A
NA
N
A
NA
N
A
NA
N
A
NA
303.
2A
5
0.16
J 0.
52U
I 0.
5U
I 0.
5U
0.
5 U
I 0.
5U
0.
85
0.85
5.
0 U
303.
2B
10
0.24
JP
0.87
UI
0.5
U
0.5
UI
0.67
UI
0.5
UI
0.61
0.
61
5.0
U
303.
2C
Lau
ritz
en
Cha
nnel
/Mou
th6
0.
27J
0.85
UI
0.5
U
0.5
UI
0.5
UI
0.5
U
0.49
J 0.
49 J
5.
0 U
M
ean(b
) 7
0.
22J
NA
N
A
NA
N
A
NA
0.
65
0.65
N
A
st
anda
rd d
evia
tion
2.6
0.
06
NA
N
A
NA
N
A
NA
0.
18
0.18
N
A
303.
3A
6
25D
1 0.
99P
11
18
53 D
I 12
0D
1 58
0D
2 78
3 5.
0 U
30
3.3B
4
J 7.
9
0.31
JP
3.2
6.
6
12
38D
1,P
190
D1
250
5.0
U
303.
3C
Lau
ritz
en C
hann
el/
End
6
12
0.5
UI
3.5
11
P 16
15
D1,
P 11
0D
1 15
6 5.
0 U
M
ean(b
) 5.
3
15
0.65
5.
9
12
27
58
293
39
6 N
A
st
anda
rd d
evia
tion
1.2
8.
9
0.48
4.
4
5.7
23
55
25
1
338
NA
303.
4A
6
0.19
J 0.
78U
I 0.
50U
0.
50U
0.
50 U
I 0.
50U
I 0.
57P
0.6
P 5.
0 U
303.
4B
5
0.14
J 0.
80U
I 0.
50U
0.
50U
0.
77 P
0.
50U
I 0.
33JP
1.
1 P
5.0
U
303.
4C
Sant
a Fe
Cha
nnel
/ E
nd(e
)
6
0.17
JP
0.69
UI
0.50
U
0.50
UI
0.50
UI
0.50
UI
0.29
JP
0.3
JP
5.0
U
M
ean(b
) 7
0.
17J
NA
N
A
NA
0.
77 P
N
A
0.31
0.
67
NA
st
anda
rd d
evia
tion
2.6
0.
03
NA
N
A
NA
N
A
NA
0.
03
0.40
N
A
303.
6A
6
0.86
0.
50U
I 0.
50U
0.
50U
I 0.
62 U
I 0.
38JP
1.
7
2.1
5.0
U
303.
6B
5 U
1.
0
0.50
UI
0.50
U
0.50
UI
0.54
UI
0.50
U
1.6
1.
6 5.
0 U
303.
6C
Parr
Can
al
2 J
0.79
0.
50U
I 0.
50U
I 0.
50U
I 0.
67 U
I 0.
50U
1.
7
1.7
5.0
U
M
ean(b
) 4
0.
88
NA
N
A
NA
N
A
0.38
JP
1.7
1.
8 N
A
st
anda
rd d
evia
tion
2.8
0.
11
NA
N
A
NA
N
A
NA
0.
06
0.26
N
A
39
Tab
le 6
. (c
ontd
)
Con
cent
ratio
n (n
g/L
)
Stat
ion
Loc
atio
n T
SS
(mg/
L)
Die
ldri
n 2,
4'-D
DE
4,
4'-D
DE
2,
4'-D
DD
4,
4'-D
DD
2,
4'-D
DT
4,
4'-D
DT
T
otal
DD
T
Aro
clor
125
4
Seep
A
5 U
31
00D
3 27
0D
2,P
370
D2
1900
D2
1300
D2
3100
D3,
P19
00D
3 88
40
14,0
00
UI
Seep
B
5
2900
D3
320
D2,
P 34
0D
218
00D
2 15
00 D
2,P
3200
D3,
P20
00D
3 91
60
14,0
00
UI
Seep
C Se
ep (
inte
rtid
al
outf
all ~
180
ft N
of
Lev
in P
ier)
3
J 30
00D
3 29
0D
2 39
0D
218
00D
2 13
00 D
2 32
00D
3,P
2000
D3
8980
17
,000
U
I
M
ean(b
) 4
30
00
290
370
1830
1370
31
7019
70
8990
N
A
st
anda
rd d
evia
tion
1.4
10
025
2558
115
5858
160
NA
(a)
Qua
lifie
rs a
re d
efin
ed a
s fo
llow
s:
U
Und
etec
ted
abov
e gi
ven
conc
entr
atio
n.
I
Ele
vate
d de
tect
ion
limit
due
to c
hrom
atog
raph
ic in
terf
eren
ce
J
Est
imat
ed v
alue
bel
ow r
epor
ting
limit
but a
bove
det
ectio
n lim
it.
P
>40
% R
PD b
etw
een
prim
ary
and
conf
irm
atio
n co
lum
ns.
N
D N
one
dete
cted
.
D1
Ext
ract
req
uire
d 1:
10 d
ilutio
n fo
r qu
antit
atio
n
D2
Ext
ract
req
uire
d 1:
100
dilu
tion
for
quan
titat
ion
D
3 E
xtra
ct r
equi
red
1:10
00 d
ilutio
n fo
r qu
antit
atio
n (b
) M
ean
of d
etec
ted
anal
yte
conc
entr
atio
ns
40
Tab
le 7
. C
once
ntra
tions
of
DD
T a
nd D
ield
rin
in th
e D
isso
lved
Fra
ctio
n of
Wat
er S
ampl
es C
olle
cted
in F
ebru
ary
2003
for
Pos
t-re
med
iatio
n M
onito
ring
of
the
Uni
ted
Hec
kath
orn
Supe
rfun
d Si
te
Con
cent
ratio
n (n
g/L
)
Stat
ion
Loc
atio
n D
ield
rin
2,4'
-DD
E
4,4'
-DD
E
2,4'
-DD
D
4,4'
-DD
D
2,4'
-DD
T
4,4'
-DD
T
Tot
al D
DT
A
rocl
or 1
254
303.
1A
0.12
J 0.
80U
I 0.
52
UI
0.48
UI
0.48
UI
0.48
UI
0.48
UI
ND
4.
8U
30
3.1B
Ric
hmon
d In
ner
Har
bor
Cha
nnel
0.
48U
0.
74U
I 0.
48
U
0.48
UI
0.48
UI
0.48
UI
0.48
UI
ND
4.
8U
M
ean(b
) 0.
12J
NA
N
A
NA
N
A
NA
N
A
NA
N
A
st
anda
rd d
evia
tion
NA
N
A
NA
N
A
NA
N
A
NA
N
A
NA
303.
2A
0.14
JP
0.49
UI
0.49
U
0.18
J 0.
49U
I 0.
49U
0.
49U
I 0.
18 J
4.
9U
303.
2B
0.49
U
0.49
U
0.49
U
0.49
UI
0.49
UI
0.49
UI
0.64
P 0.
64 P
4.
9U
303.
2C
Lau
ritz
en
Cha
nnel
/Mou
th0.
12JP
0.
49U
I 0.
49U
0.
49U
I 0.
49U
I 0.
49U
0.
48J
0.48
J
4.9
U
M
ean(b
) 0.
13JP
N
A
NA
0.
18J
NA
N
A
0.56
0.
43
NA
st
anda
rd d
evia
tion
0.01
N
A
NA
N
A
NA
N
A
0.11
0.
23
NA
303.
3A
13
0.49
UI
2.0
9.
2P
8.1
4.
8P
12
36.0
4.
9U
30
3.3B
7.
2
0.49
UI
1.2
6.
5P
5.8
2.
3U
I 5.
2
18.7
4.
9U
303.
3C
Lau
ritz
en C
hann
el/
End
7.6
0.
38J,
P 1.
0
2.8
UI
7.1
1.
9U
I 4.
4
12.5
4.
9U
M
ean(b
) 9.
3
0.38
J,P
1.4
7.
9P
7.0
4.
8P
7.2
22
.4
NA
st
anda
rd d
evia
tion
3.2
NA
0.5
1.9
1.2
NA
4.2
12.2
N
A
303.
4A
0.07
6J
0.49
UI
0.49
U
0.49
UI
0.49
UI
0.49
UI
0.49
UI
ND
4.
9U
303.
4B
0.16
JP
0.70
UI
0.49
U
0.49
UI
0.49
UI
0.49
UI
0.49
UI
ND
4.9
U
303.
4C
Sant
a Fe
Cha
nnel
/ E
nd(e
)
0.49
U
0.49
UI
0.49
UI
0.49
UI
0.49
UI
0.49
UI
0.49
UI
ND
4.9
U
M
ean(b
) 0.
12
NA
N
A
NA
N
A
NA
N
A
NA
N
A
st
anda
rd d
evia
tion
0.06
N
A
NA
N
A
NA
N
A
NA
N
A
NA
303.
6A
0.45
J 0.
49U
I 0.
88U
I 0.
49U
I 0.
49U
I 0.
49U
I 0.
49U
I N
D
4.9
U
303.
6B
0.56
0.
49U
I 2.
0U
I 0.
49U
I 0.
49U
I 0.
49U
1.
3P
1.3
P 4.
9U
303.
6C
Parr
Can
al
0.51
0.
49U
I 0.
82U
I 0.
49U
I 0.
49U
I 0.
49U
1.
1P
1.1
P 4.
9U
M
ean(b
) 0.
51
NA
N
A
NA
N
A
NA
1.
2P
1.2
P N
A
st
anda
rd d
evia
tion
0.06
N
A
NA
N
A
NA
N
A
0.1
0.
1 N
A
41
Tab
le 7
. (c
ontd
)
Con
cent
ratio
n (n
g/L
)
Stat
ion
Loc
atio
n D
ield
rin
2,4'
-DD
E
4,4'
-DD
E
2,4'
-DD
D
4,4'
-DD
D
2,4'
-DD
T
4,4'
-DD
T
Tot
al D
DT
A
rocl
or 1
254
Seep
A
2400
D3
190
D2,
P16
0D
2 10
00D
2 64
0D
2 44
0U
I 92
0D
2 29
10
1400
UI
Seep
B
2600
D3
62U
I 13
0D
2,P
850
D2
480
D2
320
UI
740
D2
2200
83
00U
I
Seep
C Se
ep (
inte
rtid
al
outf
all ~
180
ft N
of
Lev
in P
ier)
26
00D
3 49
UI
170
D2
1000
D2
1000
D2,
P 62
0U
I 95
0D
2 31
20
8600
UI
M
ean(b
) 25
3010
015
095
071
046
087
027
40
NA
st
anda
rd d
evia
tion
115
7821
8726
615
111
448
2 N
A
(a)
Qua
lifie
rs a
re d
efin
ed a
s fo
llow
s:
U
Und
etec
ted
abov
e gi
ven
conc
entr
atio
n.
I
Ele
vate
d de
tect
ion
limit
due
to c
hrom
atog
raph
ic in
terf
eren
ce
J
Est
imat
ed v
alue
bel
ow r
epor
ting
limit
but a
bove
det
ectio
n lim
it.
P
>40
% R
PD b
etw
een
prim
ary
and
conf
irm
atio
n co
lum
ns.
N
D N
one
dete
cted
.
D2
Ext
ract
req
uire
d 1:
100
dilu
tion
for
quan
titat
ion
D
3 E
xtra
ct r
equi
red
1:10
00 d
ilutio
n fo
r qu
antit
atio
n (b
) M
ean
of d
etec
ted
anal
yte
conc
entr
atio
ns.
42
Table 8. Comparison of Years 4, 5, and 6 Pesticide Concentrations in Water
Average Total DDT (ng/L) Average Dieldrin (ng/L)
Station Location Year 4 (2001)
Year 5 (2002)
Year 6 (2003)
Year 4 (2001)
Year 5 (2002)
Year 6 (2003)
Remediation Goal 0.59 0.59 0.59 0.14 0.14 0.14 Total Fraction 303.1-T Richmond Inner Harbor Channel 0.06 U 0.66 0.52 P 0.08 U 0.16 0.21 J 303.2-T Lauritzen Channel/ Mouth 2.88 1.7 0.65 0.46 0.43 0.22 J 303.3-T Lauritzen Channel/ End 142 18 396 8.49 2.1 15 303.4-T Santa Fe Channel/ End 2.51 0.60 0.67 P 0.46 0.20 0.17 J 303.6-T Parr Canal NS 2.57 1.8 NS 0.98 0.88
Seep-T Seep NS 4455 8990 NS 2520 C 3000 Dissolved Fraction 303.1-D Richmond Inner Harbor Channel 0.33 0.10 B 0.5 U 0.34 0.15 0.12 J 303.2-D Lauritzen Channel/ Mouth 2.57 1.00 0.43 JP 0.46 0.34 0.13 JP 303.3-D Lauritzen Channel/ End 10.4 4.51 22.4 4.23 1.81 9.3 303.4-D Santa Fe Channel/ End 2.21 0.44 0.5 U 0.47 0.22 0.12 JP 303.6-D Parr Canal NS 1.49 1.2 P NS 0.90 0.51
Seep-D Seep NS NM 2740 NS NM 2470
B Total DDT concentration is flagged B when a constituent is 4,4’-DDE was detected in associated blank at <5X amount in the blank.
U All DDT compounds undetected; value is average reporting limit. J Estimated value between reporting limit and method detection limit. P Estimated value: >40% RPD between primary and confirmation columns. NS Not sampled. NM Dissolved fraction not analyzed in 2002 Seep sample. C Associated surrogate recovery was outside of QC limits because extract required 10:1 dilution.
43
Tab
le 9
. Su
mm
ary
of L
engt
h an
d W
eigh
t Dat
a fr
om M
usse
ls C
olle
cted
for
Tis
sue
Sam
ples
in F
ebru
ary
2003
for
Yea
r 6
Post
-re
med
iatio
n M
onito
ring
of
the
Uni
ted
Hec
kath
orn
Supe
rfun
d Si
te St
atio
n30
3.1
303.
2 30
3.3
303.
4
Ric
hmon
d In
ner
Har
bor
Cha
nnel
L
auri
tzen
C
hann
el/M
outh
Lau
ritz
en
Cha
nnel
/End
Sant
a Fe
C
hann
el/E
ndM
anso
nL
adde
r8-
in. p
ipe,
NE
L
auri
tzen
Se
ep
Tra
nsec
t +2.
0
Shel
l Len
gth
n 41
43
37
42
49
48
6
46
Min
leng
th (
cm)
4.23
3.
27
3.93
4.
25
2.57
3.
84
3.07
4.
37
Max
leng
th (
cm)
7.31
6.
16
6.64
7.
08
6.24
6.
76
5.55
6.
49
Mea
n le
ngth
(cm
) 5.
68
5.13
5.
35
5.40
4.
94
5.10
4.
29
5.45
st
anda
rd d
evia
tion
0.79
0.
69
0.62
0.
78
0.67
0.
66
0.98
0.
48
n ou
tsid
e ra
nge(a
)8
larg
e 2
smal
l 1
larg
e, 1
sm
all
3 la
rge
1 sm
all
3 sm
all,
1 la
rge
2 sm
all
0
gran
d m
ean
leng
th(b
)
5.1
7 cm
(5.
29 c
m w
ithou
t See
p sa
mpl
e)
st
anda
rd d
evia
tion
0
.42
(0.2
5 w
ithou
t See
p sa
mpl
e)
Tis
sue
Wet
Wei
ght
sam
ple
wei
ght (
g)
294.
75
221.
79
295.
13
333.
86
223.
23
200.
22
20.1
0 33
8.91
m
ean
wt (
g)/m
usse
l 7.
19
5.16
7.
98
8.35
(c)
4.56
4.
17
3.35
7.
37
gr
and
mea
n w
eigh
t 6.
01 g
(6.
20 g
with
out S
eep
sam
ple)
stan
dard
dev
iatio
n 1.
92 (
1.72
with
out S
eep
sam
ple)
L
ipid
Con
tent
(%
)
B
ligh-
Dye
r M
etho
d 1.
2 0.
84
1.0
0.55
0.
78
0.75
1.
2(d)
0.68
E
PA M
etho
d 35
40
1.5
1.2
0.74
0.
56
0.81
1.
0 1.
6 0.
79
gran
d m
ean
0.87
% B
ligh-
Dye
r (1
.0%
EPA
354
0)
st
anda
rd d
evia
tion
0.23
0 B
ligh-
Dye
r (0
.375
EPA
354
0)
(a
)In
divi
dual
s ou
tsid
e pr
efer
red
size
ran
ge o
f 4.
0-6.
5 cm
. (b
)M
ean
of a
ll st
atio
ns c
ombi
ned.
(c
)B
ased
on
40 in
divi
dual
s; tw
o of
the
mea
sure
d sh
ells
con
tain
ed n
o tis
sue.
(d
)B
ligh-
Dye
r lip
id c
onte
nt e
stim
ated
by
linea
r re
gres
sion
rel
atio
nshi
p be
twee
n E
PA 3
540
and
Blig
h-D
yer
resu
lts f
or a
ll ot
her
sam
ples
.
44
Tab
le 1
0.
Sum
mar
y of
Pes
ticid
es in
Mus
sel T
issu
es, Y
ear
6 (2
003)
Pos
t-re
med
iatio
n M
onito
ring
of
the
Uni
ted
Hec
kath
orn
Supe
rfun
d Si
te
Sam
ple
Loc
atio
n
303.
1R
ichm
ond
Inne
r H
arbo
r C
hann
el30
3.2
Lau
ritz
en
Cha
nnel
Mou
th
303.
3 L
auri
tzen
C
hann
el E
nd
303.
4 S
anta
Fe
Cha
nnel
E
nd8"
pip
e, N
. L
auri
tzen
M
anso
n L
adde
r Se
ep (
App
rox.
T
rans
ect -
12)
Tra
nsec
t +2.
0 (N
orth
end
of
Lev
in P
ier)
Bat
telle
Sam
ple
ID
Y6-
04
Y6-
03
Y6-
07
Y6-
05
Y6-
02
Y6-
01
Y6-
06
Y6-
08
Pest
icid
es (
g/K
g w
et w
eigh
t)
Die
ldri
n 2.
9
6.2
J, P
, D1,
#
18P,
D1,
# 1.
3
49D
1, #
20
P, D
1, #
40
00D
2, #
26
D1,
#
4,4’
-DD
E
17
41
D1,
#
64D
1, #
9.
4
110
D1,
#
68D
1, #
15
000
D3,
#
86D
1, #
4,4’
-DD
D
11
56
D1,
#
110
D1,
#
9.3
U, I
39
0D
1, #
13
0D
1, #
21
000
D3,
#
130
D1,
#
4,4’
-DD
T
9.7
U, I
57
D1,
#
120
D1,
#
8.6
18
0D
1, #
92
D1,
#
3100
0D
3, #
20
0D
1, #
2,4’
-DD
E
3.8
U, I
29
D1,
#
61D
1, #
6.
8
150
D1,
#
68D
1, #
32
000
D3,
#
78D
1, #
2,4’
-DD
D
0.26
U
2.
6U
2.
6U
0.
26U
10
U, I
2.
6U
17
00D
2, #
10
U, I
2,4’
-DD
T
5.7
U, I
31
D1,
#
76D
1, #
4.
7U
, I
99D
1, #
59
D1,
#
3500
0D
3, #
12
0D
1, #
Tot
al D
etec
ted
DD
T
28
214
431
24.8
92
9 41
7 13
5700
61
4 Pe
rcen
t Lip
ids
EPA
3540
1.
50
1.
20
0.74
0.
56
1.00
0.
81
1.6
0.
79
Perc
ent L
ipid
s B
ligh
& D
yer
1.20
0.84
1.
0
0.55
0.
75
0.78
1.
16E
0.
68
Lip
id N
orm
aliz
ed T
otal
D
DT
(pp
b lip
id)
2,33
3
25,4
76
43,1
00
4,50
9
123,
867
53
,462
11
,698
,276
90
,294
Perc
ent D
ry W
eigh
t 14
.0
12.7
10.1
8.2
12
.312
.011
.2E
9.
4
Tot
al D
DT
, g/
kg d
ry w
eigh
t 20
0
1685
42
67
304
75
53
3475
12
1160
7
6525
Die
ldri
n,
g/kg
dry
wei
ght
21
49
17
8
16
398
16
7
3571
4
276
Surr
ogat
e R
ecov
erie
s (p
estic
ides
)
Tet
rach
loro
-m-x
ylen
e 99
0D
1, #
0
D1,
#
88
0D
1, #
0
D1,
#
0D
2, #
0D
1, #
Dec
achl
orob
iphe
nyl
90
0
D1,
#
0D
1, #
85
0
D1,
#
0D
1, #
0
D2,
#0
D1,
#
45
Tab
le 1
0. (
cont
d)
P >
40%
RPD
bet
wee
n pr
imar
y an
d co
nfir
mat
ion
colu
mns
. #
Surr
ogat
e re
cove
ry c
ontr
ol li
mits
not
app
licab
le b
ecau
se o
f di
lutio
n fa
ctor
. J
Est
imat
ed b
elow
rep
ortin
g lim
it, b
ut a
bove
met
hod
dete
ctio
n lim
it.
U
Und
etec
ted
abov
e gi
ven
conc
entr
atio
n.
D1
Ext
ract
req
uire
d 1:
10 d
ilutio
n fo
r qu
antit
atio
n.
D2
Ext
ract
req
uire
d 1:
100
dilu
tion
for
quan
titat
ion.
D
3 E
xtra
ct r
equi
red
1:10
00 d
ilutio
n fo
r qu
antit
atio
n.
I E
leva
ted
dete
ctio
n lim
it du
e to
chr
omat
ogra
phic
inte
rfer
ence
. E
Se
ep s
ampl
e B
ligh-
Dye
r lip
id e
quiv
alen
t est
imat
ed f
rom
EPA
3540
lipi
d re
sult
by li
near
reg
ress
ion
of a
ll ot
her
data
; per
cent
dry
wei
ght e
stim
ated
as
mea
n of
oth
er
sam
ples
.
46
Tab
le 1
1.
PCB
Aro
clor
s in
Mus
sel T
issu
es, Y
ear
6 (2
003)
Pos
t-re
med
iatio
n M
onito
ring
of
the
Uni
ted
Hec
kath
orn
Supe
rfun
d Si
te
Sam
ple
Loc
atio
n
303.
1R
ichm
ond
Inne
r H
arbo
r C
hann
el30
3.2
Lau
ritz
en
Cha
nnel
Mou
th
303.
3 L
auri
tzen
C
hann
el E
nd
303.
4 S
anta
Fe
Cha
nnel
End
8"
pip
e, N
. L
auri
tzen
M
anso
nL
adde
rSe
ep (
App
rox.
T
rans
ect -
12)
Tra
nsec
t +2.
0 (N
orth
end
of
Lev
in P
ier)
Bat
telle
Sam
ple
ID
Y6-
04
Y6-
03
Y6-
07
Y6-
05
Y6-
02
Y6-
01
Y6-
06
Y6-
08
Aro
clor
101
6 0.
65
U
0.65
U
0.65
U
0.65
U
0.65
U
0.65
U
140
U
0.65
U
Aro
clor
122
1 0.
65
U
0.65
U
0.65
U
0.65
U
0.65
U
0.65
U
140
U
0.65
U
Aro
clor
123
2 0.
65
U
0.65
U
0.65
U
0.65
U
0.65
U
0.65
U
140
U
0.65
U
Aro
clor
124
2 0.
65
U
0.65
U
0.65
U
0.65
U
0.65
U
0.65
U
140
U
0.65
U
Aro
clor
124
8 0.
65
U
0.65
U
0.65
U
0.65
U
0.65
U
0.65
U
140
U
0.65
U
Aro
clor
125
4 93
96P
90P
45
270
P 14
0P
3100
U, I
11
0P
Aro
clor
126
0 0.
65
U
0.65
U
0.65
U
0.65
U
0.65
U
0.65
U
140
U
0.65
U
Tot
al D
etec
ted
PC
B
93
96P
90
P
4527
0P
14
0P
N
DI
110
P
Surr
ogat
e R
ecov
ery
Dec
achl
orob
iphe
nyl
95
97
92
94
92
99
0
D2,
#95
U
Und
etec
ted
abov
e gi
ven
conc
entr
atio
n.
P >
40%
RPD
bet
wee
n pr
imar
y an
d co
nfir
mat
ion
colu
mns
. N
D
Non
e de
tect
ed.
I E
leva
ted
dete
ctio
n lim
it du
e to
chr
omat
ogra
phic
inte
rfer
ence
. D
2 E
xtra
ct r
equi
red
1:10
0 di
lutio
n fo
r qu
antit
atio
n.
# Su
rrog
ate
reco
very
con
trol
lim
its n
ot a
pplic
able
bec
ause
of
dilu
tion
fact
or.
47
Tab
le 1
2.
Sum
mar
y Se
dim
ent C
hem
istr
y R
esul
ts f
or a
ll So
il an
d Se
dim
ent S
ampl
es, P
hase
II
Sour
ce I
nves
tigat
ion
Gra
in S
ize,
TO
C (
% D
ry W
eigh
t)
Pe
stic
ides
(µ
g/kg
dry
wei
ght)
Che
mis
try
Sam
ple
ID
Sam
ple
Typ
e St
atio
n ID
V
ertic
al
Inte
rval
(ft
) G
rave
l Sa
nd
Silt
+ C
lay
TO
C
T
otal
D
DT
(a)
Die
ldri
n
Hec
k03-
001
Ban
k So
il T
(-35
) ol
d sc
ale
0-0.
3 5.
5 87
.17.
40.
54
1620
95
U
Hec
k03-
002
Ban
k So
il T
(-35
) ol
d sc
ale
0.5-
1 43
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34.1
22.5
1.4
14
100
11
00U
Hec
k03-
004
Ban
k So
il T
(-29
) 36
ft N
of
8" p
ipe
0-0.
5 76
.0
20.5
3.5
1.2
68
100
59
00
Hec
k03-
003
Ban
k So
il T
(-29
) 36
ft N
of
8" p
ipe
0.5-
1 55
.4
23.2
21.4
1.3
75
000
32
00
Hec
k03-
006
Ban
k So
il T
(-12
.5)
Ban
k 0-
0.2
4.2
15.9
79.9
2.1
12
900
18
00U
Hec
k03-
005
Ban
k So
il T
(-12
.5)
Ban
k 0.
5-1
0.0
12.9
87.1
8.1
N
D
46U
Hec
k03-
009
Ban
k So
il T
(-11
.5)
Seep
1-f
t N
NA
(fr
om p
ipe)
44.4
33
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.22.
5
3634
100
22
000
J, Q
7
Hec
k03-
007
Ban
k So
il T
(-11
.5)
Seep
1-f
t N
0-0.
2 0.
8 10
.788
.54.
1
4180
43
0U
Hec
k03-
008
Ban
k So
il T
(-11
.5)
Seep
1-f
t N
0.5-
1 0.
0 11
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5
28
49U
Hec
k03-
011
Ban
k So
il T
(-4.
5) B
ank
0-0.
2 5.
2 22
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4
3810
41
0U
Hec
k03-
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Ban
k So
il T
(-4.
5) B
ank
0.5-
1 0.
0 11
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N
D
45U
Hec
k03-
012
Ban
k So
il T
(+2.
25)
Ban
k 0-
0.2
0.0
14.3
85.7
3.5
35
20
530
U, J
, Q7
Hec
k03-
013
Ban
k So
il T
(+2.
25)
Ban
k 0.
5-1
4.6
14.5
80.9
2.3
13
5200
46
00J,
C1
Hec
k03-
025
YB
M
H03
-1-C
0-
1.0
8.6
24.9
66.5
1.3
11
6050
0
1300
0J,
Q7
Hec
k03-
017
0.1
ft Y
BM
on
0.3
ft O
BM
H
03-1
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0-0.
4 9.
6 27
.163
.30.
67
920
23
0U
Hec
k03-
026
YB
M
H03
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E
0-0.
75
60.2
27
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.60.
3
4300
0
1000
U
Hec
k03-
024
YB
M
H03
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W
0-1.
7 6.
0 30
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4
2870
0
1600
U
Hec
k03-
029
YB
M
H03
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0-
0.6
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27
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.11.
1
5360
0
2300
U
Hec
k03-
030
0.25
ft Y
BM
on
0.25
ft O
BM
H
03-1
-SE
0-
0.5
24.1
26
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42
5160
0
2700
U
Hec
k03-
031
YB
M
H03
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W
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5 13
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24.7
61.6
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800
17
00U
Hec
k03-
027
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M
H03
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1.5
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29.9
68.8
1.8
19
0000
16
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Hec
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023
OB
M
H03
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0-
0.9
15.9
24
.659
.51.
4
2720
0
2700
U
Hec
k03-
022
YB
M
H03
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E
0-0.
25
27.2
21
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44
2560
0
2400
U
Hec
k03-
032
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M
H03
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0-
0.4
45.4
19
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9
2210
0
1400
U
Hec
k03-
033
YB
M w
/few
blo
bs O
BM
H
03-2
-SE
0-
0.75
47
.9
25.2
26.9
0.72
26
400
13
00U
Hec
k03-
028
YB
M
H03
-2-W
0-
1.5
0.2
23.7
76.1
2.4
19
4500
35
00U
Hec
k03-
037
0.5
ft Y
BM
on
0.5
ft O
BM
H
03-T
(+1.
5)-E
0-
1.0
0.0
13.8
86.2
0.12
65
00
1300
U
Hec
k03-
036
0.2
ft Y
BM
on
0.5
ft O
BM
H
03-T
(+2.
5)-E
0-
0.7
1.5
21.3
77.2
0.16
58
70
1100
U
Hec
k03-
035
0.25
ft Y
BM
on
0.25
ft O
BM
H
03-T
(+3.
5)-E
0-
0.5
0.2
24.5
75.3
0.15
12
00
130
U
48
Tab
le 1
2. (
cont
d)
Gra
in S
ize,
TO
C (
% D
ry W
eigh
t)
Pe
stic
ides
(µ
g/kg
dry
wei
ght)
Che
mis
try
Sam
ple
ID
Sam
ple
Typ
e St
atio
n ID
V
ertic
al
Inte
rval
(ft
) G
rave
l Sa
nd
Silt
+ C
lay
TO
C
T
otal
D
DT
(a)
Die
ldri
n
Hec
k03-
034
0.1
ft Y
BM
on
0.8
ft O
BM
H
03-T
(+4.
5)-E
0-
0.9
2.7
14.4
82.9
0.16
85
0
53U
Hec
k03-
044
YB
M
H03
-01
0-1.
0 0.
0 10
.589
.52.
0
1564
00
2300
J, C
1
Hec
k03-
040
0.1
ft Y
BM
on
0.2
ft O
BM
H
03-0
2 0-
0.3
23.8
25
.850
.41.
1
2500
15
0U
Hec
k03-
045
YB
M
H03
-03
0-1.
3 3.
3 52
.244
.51.
0
2630
0
1400
U
Hec
k03-
046
YB
M
H03
-04
0-1.
5 9.
9 67
.922
.20.
54
7100
26
0U
, J, Q
7
Hec
k03-
047
OB
M-d
istu
rbed
H
03-0
4 1.
9-3.
1 6.
4 48
.545
.10.
51
2716
0
1300
U
Hec
k03-
043
YB
M
H03
-05
0-2.
8 0.
0 16
.283
.81.
5
1600
0
750
U, J
, Q7
Hec
k03-
014
YB
M
H03
-06
0-1.
4 22
.2
27.7
50.1
0.72
92
27
U
Hec
k03-
048
YB
M
H03
-07
0-1.
3 0.
6 22
.776
.71.
0
5360
0
2900
U
Hec
k03-
015
YB
M
H03
-08
0-0.
7 32
.9
18.3
48.8
0.65
88
0
110
U
Hec
k03-
039
YB
M
H03
-10
0-3.
4 0.
0 15
.284
.81.
5
1250
0
410
U
Hec
k03-
016
YB
M
H03
-11
0-0.
7 30
.5
39.6
29.9
0.33
85
21
U
Hec
k03-
038
YB
M
H03
-12
0-3.
8 0.
0 15
.085
.02.
2
2117
85
U
(a)
Sum
of
dete
cted
2,4
'-DD
D, 2
,4'-D
DE
, 2,4
'-DD
T, 4
,4'-D
DD
, 4,4
'-DD
E, a
nd 4
,4'-D
DT
con
cent
ratio
ns.
U
Und
etec
ted
abov
e gi
ven
conc
entr
atio
n.
J
The
rep
orte
d re
sult
for
this
ana
lyte
sho
uld
be c
onsi
dere
d an
est
imat
ed v
alue
.
Q7
Sur
roga
te s
pike
rec
over
ies
for
this
sam
ple
wer
e ou
tsid
e co
ntro
l lim
its
C
1 T
he r
epor
ted
conc
entr
atio
n fo
r th
is a
naly
te is
bel
ow th
e qu
antit
atio
n lim
it.
Appendix A
EPA Field Sampling for Mussels and Seawater
A-1
Field Sampling Summary for Mussels and Seawaterat the United Heckathorn Site in
Richmond, California, conducted 2/25/2003.
Andrew LincoffEPA Region 9 Laboratory
PMD-2March 25, 2003
INTRODUCTION
This sampling event involved the collection of bay mussels and seawater at the United Heckathorn Superfund Site in Richmond, California. Sampling was performed on February 25, 2003 by Andrew Lincoff and Peter Husby of the EPA Region 9 Laboratory, and Carmen White, United Heckathorn RPM. Sampling was performed in accordance with Battelle’s “United Heckathorn Post-Remediation Field Monitoring Plan” (FSP), dated February 5, 1997, and “Sampling and Analysis Plan for the Investigation of Contaminant Source and Contaminant Movement in the Lauritzen Channel, United Heckathorn Site, Richmond, California” (SAP), drafted January 11, 2002.
OBJECTIVE
EPA conducted this field sampling as part of the oversight of a final Remedial Action under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or Superfund) at the United Heckathorn Site in Richmond, California. The sampling effort involved collecting physical environmental samples to analyze for the presence of hazardous substances.
The United Heckathorn Site was used to formulate pesticides from approximately 1947 to 1966. Soils at the Site and sediments in Richmond Harbor were contaminated with various chlorinated pesticides, primarily DDT, as a result of these pesticide formulation activities. The final remedy contained in EPA's October, 1994 Record of Decision addressed remaining hazardous substances, primarily in the marine environment. The major marine components of the selected remedy included:
- Dredging of all soft bay mud from the Lauritzen Channel and Parr Canal, with offsite disposal of dredged material.
- Marine monitoring to verify the effectiveness of the remedy.
Long-term monitoring is addressed by Battelle’s February 5, 1997 FSP. The purpose of the long-term monitoring is to demonstrate the effectiveness of the remedy. Prior to the remediation,mussels in the Lauritzen Channel contained the highest levels of DDT and dieldrin in the State, and surface water exceeded EPA’s Ambient Water Quality Criteria for DDT by a factor of 50. Lower but
A-2
still elevated levels were found in mussels and surface water in the Santa Fe Channel. It was concluded in EPA’s Remedial Investigation that these elevated levels were the result of continuous flux from contaminated sediments. Approximately 98% of the mass of DDT in sediments in Richmond Harbor was removed by the remedial dredging. The long-term monitoring will demonstrate whether this action has succeeded in reducing the levels of DDT in mussels and surface waters.
Battelle’s FSP included monitoring using both transplanted California mussels and resident Bay mussels. The first round of the long-term sampling occurred in January, 1998. This is the sixth annual round of sampling. The seasonal timing was chosen to match the protocol used by the California State Mussel Watch Program, in order to permit comparison with the State’s results over the past 15 years.In the first two rounds, both transplanted and resident mussels are analyzed to determine any difference. Based on the results of the first two rounds and discussions with California State Mussel Watch Program personnel, only resident mussels were collected in subsequent rounds. Mussels collected on February 25, 2003 were shipped to Battelle for processing prior to analysis by Columbia Analytical.Seawater samples collected on February 25, 2003 were shipped directly to Columbia Analytical.
FIELD NOTES AND OBSERVATIONS
1. 1. Seawater and mussel samples were collected at the routine Mussel Watch station numbers 303.1 to 303.4 used in the previous annual collections and at the Parr Canal station which last year was given the number 303.6. Three gallons of seawater were collected from approximately one foot below the surface at each location. An extra gallon was collected at station 303.3 for lab QC. In addition, three gallons of seawater were collected from a pipe which emerges from the shoreline near station 303.3 called the “seep” (Photo 1). Water can be seen flowing from this pipe when the tide drops. An extra gallon was collected from the “seep” and labeled “blind duplicate.”No time was recorded on the label of the blind duplicate to prevent its identification, but it was collected at the same time as the other “seep” samples.
2. Bay mussels were collected at each of the water stations above except for station 303.6 in the Parr Canal. Mussels are not plentiful in the Parr Canal, possibly due to poor substrate or lower salinity. Bay mussels were also collected at three additional locations: the “seep,” a ladder off the Manson dock, and from piles near an 8” pipe near the northern end of the canal which emerges from Levin’s sheet pile wall (Photo 2). The mussels were all collected near the surface, which at the collection time was approximately at 1 ft above Mean Lower Low Water (MLLW), except for station 303.4 where the mussels were collected near the surface from a floating dock, and the “seep” where the mussels were collected from in and around the mouth of the pipe.
3. The samples were promptly delivered to the Region 9 Lab and the seawater samples were placed in a 4 ºC cold room. The mussels were cleaned of gross debris in the laboratory’s clean filtered seawater, wrapped in ashed foil, placed in zip-loc bags, and stored in a -20 ºC freezer. The
A-3
seawater and mussels were packaged and shipped on March 26, 2003 by Fed Ex. The seawater was shipped chilled to Columbia Analytical and the mussels were shipped frozen to Battelle.
4. GPS coordinates for the sample locations are listed in Table 1. No location was taken at station 303.1 on the day of sampling. The location listed is from the April 10, 2002 sampling report. All locations were differentially corrected with the exception of the “seep.” It was not possible to differentially correct the readings from this location. The cause is unknown. The location listed is the mean of five position recordings.
5. Salinity was measured using a refractometer in seawater from the "seep" and nearby station 303.3.The salinity of the "seep" was 21 parts per thousand (ppt) and the salinity at station 303.3 was 23 ppt.
Table 1Sample Locations
Sample GPS Location Remarks
303.3 37º 55' 22.415" N, 122º 21' 59.980" W seawater, mussels
303.2 37º 55' 12.236" N, 122º 22' 01.298" W seawater, mussels
303.4 37º 55' 21.081" N, 122º 22' 17.694" W seawater, mussels
303.1 37º 54' 32.869" N, 122º 21' 33.523" W* seawater, mussels
303.6 37º 55' 12.140" N, 122º 21' 45.915" W seawater
Seep 37º 55' 22.99" N, 122º 22' 59.66" W** seawater, mussels
Transect 2.5 37º 55' 21.156" N, 122º 22' 00.241" W mussels
Near 8” pipe 37º 55' 25.349" N, 122º 21' 59.383" W mussels collected from nearbypiles
Manson Ladder 37º 55' 23.332" N, 122º 22' 01.646" W mussels
* Location from April 10, 2002 field report.** Mean of five uncorrected positions.
A-4
Photo 1. Water flowing from "seep."
Photo 2: Mussel collection from piles near 8" pipe in background.
Appendix B
Year 6 (2003) Monitoring Water and Tissue Chemistry
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
D30
3.1A
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
25=
303.
1B- T
SM
PL
NO
NE
SM
252
0Bg/
Kg
Sal
init
y1
225
=30
3.1C
-T-Q
CS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
25=
303.
6A- T
SM
PL
NO
NE
SM
252
0Bg/
Kg
Sal
init
y1
213
=30
3.6B
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
12=
303.
6C- T
SM
PL
NO
NE
SM
252
0Bg/
Kg
Sal
init
y1
215
=30
3.4A
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
25=
303.
4B- T
SM
PL
NO
NE
SM
252
0Bg/
Kg
Sal
init
y1
225
=30
3.4C
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
25=
303.
2A- T
SM
PL
NO
NE
SM
252
0Bg/
Kg
Sal
init
y1
225
=30
3.2B
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
25=
303.
2C- T
SM
PL
NO
NE
SM
252
0Bg/
Kg
Sal
init
y1
225
=30
3.3A
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
24=
303.
3B- T
SM
PL
NO
NE
SM
252
0Bg/
Kg
Sal
init
y1
224
=30
3.3C
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
24=
Bli
nd D
up.-
TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
23=
See
p A
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
23=
See
p B
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
23=
See
p C
- TS
MP
LN
ON
ES
M 2
520B
g/K
gS
alin
ity
12
22=
Met
hod
Bla
nkM
B1
NO
NE
SM
252
0Bg/
Kg
Sal
init
y1
2N
DN
D30
3.1A
- TD
UP
1N
ON
ES
M 2
520B
g/K
gS
alin
ity
12
225
=25
< 1
303.
1A- T
SM
PL
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
58
=30
3.1B
- TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
6=
303.
1C-T
-QC
SM
PL
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
57
=30
3.6A
- TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
6=
303.
6B- T
SM
PL
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
5N
DN
D30
3.6C
- TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
2=,
J30
3.4A
-TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
6=
303.
4B- T
SM
PL
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
55
=30
3.4C
- TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
6=
303.
2A- T
SM
PL
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
55
=30
3.2B
- TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
10=
303.
2C- T
SM
PL
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
56
=30
3.3A
- TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
6=
303.
3B- T
SM
PL
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
54
=, J
303.
3C-T
SM
PL
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
56
=B
lind
Dup
.-T
SM
PL
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
54
=, J
See
p A
-TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
ND
ND
See
p B
- TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
5=
See
p C
- TS
MP
LN
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
3=,
JM
etho
d B
lank
MB
1N
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
ND
ND
Met
hod
Bla
nkM
B1
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
51.
5=
Met
hod
Bla
nkM
B1
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
5-1
.5=
Met
hod
Bla
nkM
B1
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
5-1
=M
etho
d B
lank
MB
1N
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
-1.5
=M
etho
d B
lank
MB
1N
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
ND
ND
Met
hod
Bla
nkM
B1
NO
NE
160.
2m
g/L
Sol
ids,
Tot
al S
uspe
nded
(T
SS
)1
50
=M
etho
d B
lank
MB
1N
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
0.5
=M
etho
d B
lank
MB
1N
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
-2=
Lab
Con
trol
Sam
ple
LC
S1N
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
25.
4=
5.7
94.7
3684
211
85-1
15
B.1
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
DD
upli
cate
Lab
Con
tro
DL
CS
1N
ON
E16
0.2
mg/
LS
olid
s, T
otal
Sus
pend
ed (
TS
S)
15
26.
4=
5.7
112
85-1
1516
303.
1A- T
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
75S
UR
7510
-157
303.
1A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
500.
0024
ND
ND
303.
1A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
500.
0024
ND
ND
303.
1A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
500.
0024
ND
ND
303.
1A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
ND
ND
303.
1A-D
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
87S
UR
8710
-157
303.
1A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
480.
0024
ND
ND
303.
1A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
480.
0024
ND
ND
303.
1A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
480.
0024
ND
ND
303.
1A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
480.
0024
ND
ND
303.
1B- T
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
61S
UR
6110
-157
303.
1B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
500.
0024
ND
ND
303.
1B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
500.
0024
ND
ND
303.
1B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
500.
0024
ND
ND
303.
1B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
ND
ND
303.
1B-D
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
77S
UR
7710
-157
303.
1B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
480.
0024
ND
ND
303.
1B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
480.
0024
ND
ND
303.
1B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
480.
0024
ND
ND
303.
1B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
480.
0024
ND
ND
303.
6A- T
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
62S
UR
6210
-157
303.
6A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
500.
0024
ND
ND
303.
6A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
500.
0024
ND
ND
303.
6A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
500.
0024
ND
ND
303.
6A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
ND
ND
303.
6A-D
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
65S
UR
6510
-157
303.
6A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
490.
0024
ND
ND
303.
6A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
490.
0024
ND
ND
303.
6A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
490.
0024
ND
ND
303.
6A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
490.
0024
ND
ND
303.
6B- T
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
55S
UR
5510
-157
303.
6B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
500.
0024
ND
ND
303.
6B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
500.
0024
ND
ND
303.
6B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
500.
0024
ND
ND
303.
6B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
ND
ND
303.
6B-D
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
72S
UR
7210
-157
303.
6B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
490.
0024
ND
ND
303.
6B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
490.
0024
ND
ND
303.
6B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
490.
0024
ND
ND
303.
6B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
490.
0024
ND
ND
303.
6C- T
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
67S
UR
6710
-157
303.
6C- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
500.
0024
ND
ND
303.
6C- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
500.
0024
ND
ND
303.
6C- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
500.
0024
ND
ND
303.
6C- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
ND
ND
303.
6C-D
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
70S
UR
7010
-157
303.
6C-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
490.
0024
ND
ND
303.
6C-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
490.
0024
ND
ND
303.
6C-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
490.
0024
ND
ND
B.2
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
D30
3.6C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
D30
3.4A
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
154
SU
R54
10-1
5730
3.4A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0050
0.00
24N
DN
D30
3.4A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0050
0.00
24N
DN
D30
3.4A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0050
0.00
24N
DN
D30
3.4A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
24N
DN
D30
3.4A
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
161
SU
R61
10-1
5730
3.4A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0049
0.00
24N
DN
D30
3.4A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0049
0.00
24N
DN
D30
3.4A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0049
0.00
24N
DN
D30
3.4A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
D30
3.4B
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
159
SU
R59
10-1
5730
3.4B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0050
0.00
24N
DN
D30
3.4B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0050
0.00
24N
DN
D30
3.4B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0050
0.00
24N
DN
D30
3.4B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
24N
DN
D30
3.4B
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
166
SU
R66
10-1
5730
3.4B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0049
0.00
24N
DN
D30
3.4B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0049
0.00
24N
DN
D30
3.4B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0049
0.00
24N
DN
D30
3.4B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
D30
3.4C
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
161
SU
R61
10-1
5730
3.4C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0050
0.00
24N
DN
D30
3.4C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0050
0.00
24N
DN
D30
3.4C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0050
0.00
24N
DN
D30
3.4C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
24N
DN
D30
3.4C
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
176
SU
R76
10-1
5730
3.4C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0049
0.00
24N
DN
D30
3.4C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0049
0.00
24N
DN
D30
3.4C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0049
0.00
24N
DN
D30
3.4C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
D30
3.2A
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
151
SU
R51
10-1
5730
3.2A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0050
0.00
24N
DN
D30
3.2A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0050
0.00
24N
DN
D30
3.2A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0050
0.00
24N
DN
D30
3.2A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
24N
DN
D30
3.2A
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
169
SU
R69
10-1
5730
3.2A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0049
0.00
24N
DN
D30
3.2A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0049
0.00
24N
DN
D30
3.2A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0049
0.00
24N
DN
D30
3.2A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
D30
3.2B
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
155
SU
R55
10-1
5730
3.2B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0050
0.00
24N
DN
D30
3.2B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0050
0.00
24N
DN
D30
3.2B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0050
0.00
24N
DN
D30
3.2B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
24N
DN
D30
3.2B
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
173
SU
R73
10-1
5730
3.2B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0049
0.00
24N
DN
D30
3.2B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0049
0.00
24N
DN
D30
3.2B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0049
0.00
24N
DN
D
B.3
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
D30
3.2B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
D30
3.2C
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
167
SU
R67
10-1
5730
3.2C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0050
0.00
24N
DN
D30
3.2C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0050
0.00
24N
DN
D30
3.2C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0050
0.00
24N
DN
D30
3.2C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
24N
DN
D30
3.2C
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
173
SU
R73
10-1
5730
3.2C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0049
0.00
24N
DN
D30
3.2C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0049
0.00
24N
DN
D30
3.2C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0049
0.00
24N
DN
D30
3.2C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
D30
3.3A
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
156
SU
R56
10-1
5730
3.3A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0050
0.00
24N
DN
D30
3.3A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0050
0.00
24N
DN
D30
3.3A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0050
0.00
24N
DN
D30
3.3A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
24N
DN
D30
3.3A
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
171
SU
R71
10-1
5730
3.3A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0049
0.00
24N
DN
D30
3.3A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0049
0.00
24N
DN
D30
3.3A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0049
0.00
24N
DN
D30
3.3A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
D30
3.3B
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
144
SU
R44
10-1
5730
3.3B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0050
0.00
24N
DN
D30
3.3B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0050
0.00
24N
DN
D30
3.3B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0050
0.00
24N
DN
D30
3.3B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
24N
DN
D30
3.3B
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
173
SU
R73
10-1
5730
3.3B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0049
0.00
24N
DN
D30
3.3B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0049
0.00
24N
DN
D30
3.3B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0049
0.00
24N
DN
D30
3.3B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
D30
3.3C
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
155
SU
R55
10-1
5730
3.3C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0050
0.00
24N
DN
D30
3.3C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0050
0.00
24N
DN
D30
3.3C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0050
0.00
24N
DN
D30
3.3C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
24N
DN
D30
3.3C
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
163
SU
R63
10-1
5730
3.3C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
10.
0049
0.00
24N
DN
D30
3.3C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
10.
0049
0.00
24N
DN
D30
3.3C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
10.
0049
0.00
24N
DN
D30
3.3C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0049
0.00
24N
DN
DB
lind
Dup
.-T
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l10
010
0SU
R, D
,#10
010
-157
Bli
nd D
up.-
TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
100
0.50
0.24
ND
ND
Bli
nd D
up.-
TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
100
1.6
1.6
ND
ND
, iB
lind
Dup
.-T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
410
014
14N
DN
D, i
Bli
nd D
up.-
TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
260
100
1.6
1.6
ND
ND
, iB
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l10
012
9SU
R, D
,#12
910
-157
Bli
nd D
up.-
DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
242
100
0.49
0.24
ND
ND
Bli
nd D
up.-
DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
248
100
2.1
2.1
ND
ND
, iB
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
410
09.
79.
7N
DN
D, i
B.4
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
DB
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
010
01.
91.
9N
DN
D, i
See
p A
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
100
48SU
R, D
,#48
10-1
57S
eep
A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
210
00.
480.
24N
DN
DS
eep
A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
810
01.
61.
6N
DN
D, i
See
p A
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
100
1414
ND
ND
, iS
eep
A- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
010
01.
51.
5N
DN
D, i
See
p A
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
100
118
SUR
, D,#
118
10-1
57S
eep
A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
210
00.
490.
24N
DN
DS
eep
A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
810
01.
41.
4N
DN
D, i
See
p A
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
100
8.6
8.6
ND
ND
, iS
eep
A-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
010
01.
81.
8N
DN
D, i
See
p B
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
100
112
SUR
, D,#
112
10-1
57S
eep
B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
210
00.
490.
24N
DN
DS
eep
B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
810
01.
51.
5N
DN
D, i
See
p B
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
100
1414
ND
ND
, iS
eep
B- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
010
01.
41.
4N
DN
D, i
See
p B
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
100
125
SUR
, D,#
125
10-1
57S
eep
B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
210
00.
490.
24N
DN
DS
eep
B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
810
01.
91.
9N
DN
D, i
See
p B
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
100
8.3
8.3
ND
ND
, iS
eep
B-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
010
01.
81.
8N
DN
D, i
See
p C
- TS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
100
125
SUR
, D,#
125
10-1
57S
eep
C- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
210
00.
490.
24N
DN
DS
eep
C- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
810
02.
82.
8N
DN
D, i
See
p C
- TS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
100
1717
ND
ND
, iS
eep
C- T
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
010
01.
91.
9N
DN
D, i
See
p C
-DS
MP
LE
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
100
125
SUR
, D,#
125
10-1
57S
eep
C-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
210
00.
490.
24N
DN
DS
eep
C-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
810
01.
21.
2N
DN
D, i
See
p C
-DS
MP
LE
PA
35
20
C80
82ug
/LA
rocl
or 1
254
100
8.6
8.6
ND
ND
, iS
eep
C-D
SM
PL
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
010
01.
61.
6N
DN
D, i
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
100
SU
R10
010
-157
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
500.
0024
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
500.
0024
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
500.
0024
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
85S
UR
8510
-157
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
21
0.00
500.
0024
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
ug/L
Aro
clor
124
81
0.00
500.
0024
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
ug/L
Aro
clor
125
41
0.00
500.
0024
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
ND
ND
303.
1B-D
MS1
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
90S
UR
9010
-157
303.
1B-D
MS1
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.01
90.
0089
0.38
9=
0.37
010
524
-150
303.
1B-D
DM
S1E
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
187
SU
R87
10-1
5730
3.1B
-DD
MS1
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.02
30.
011
0.43
8=
0.45
596
24-1
5012
303.
1B- T
MS1
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
92S
UR
9210
-157
303.
1B- T
MS1
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
0.10
9=
0.10
010
924
-150
303.
1B- T
DM
S1E
PA
35
20
C80
82P
ER
CE
NT
Dec
achl
orob
iphe
nyl
184
SU
R84
10-1
5730
3.1B
- TD
MS1
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
0.10
7=
0.10
010
724
-150
2L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
87S
UR
8710
-157
B.5
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
DL
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8082
ug/L
Aro
clor
126
01
0.00
500.
0024
0.09
71=
0.10
097
61-1
35L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8082
PE
RC
EN
TD
ecac
hlor
obip
heny
l1
87S
UR
8710
-157
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
82ug
/LA
rocl
or 1
260
10.
0050
0.00
240.
100
=0.
100
100
61-1
3530
3.1A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
53S
UR
5328
-105
303.
1A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
83S
UR
8310
-134
303.
1A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
50N
DN
D, i
303.
1A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
12N
DN
D30
3.1A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.50
0.50
ND
ND
, i30
3.1A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.50
0.50
ND
ND
, i30
3.1A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.76
0.76
ND
ND
, i30
3.1A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.16
ND
ND
, i30
3.1A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.50
0.50
ND
ND
, i30
3.1A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
59S
UR
5928
-105
303.
1A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
86S
UR
8610
-134
303.
1A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
480.
056
0.12
=, J
303.
1A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
520.
52N
DN
D, i
303.
1A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
480.
48N
DN
D, i
303.
1A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
480.
48N
DN
D, i
303.
1A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
800.
80N
DN
D, i
303.
1A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
480.
14N
DN
D, i
303.
1A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
480.
23N
DN
D, i
303.
1B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
162
SU
R62
28-1
0530
3.1B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
165
SU
R65
10-1
3430
3.1B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
61S
UR
6128
-105
303.
1B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
74S
UR
7410
-134
303.
6A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
156
SU
R56
28-1
0530
3.6A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
159
SU
R59
10-1
3430
3.6A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.50
0.05
60.
86=
303.
6A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
12N
DN
D30
3.6A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.62
0.62
ND
ND
, i30
3.6A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.50
0.04
71.
7=
303.
6A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
500.
50N
DN
D, i
303.
6A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
500.
27N
DN
D, i
303.
6A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
500.
120.
38=,
JP
303.
6A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
160
SU
R60
28-1
0530
3.6A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
155
SU
R55
10-1
3430
3.6A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.49
0.05
60.
45=,
J30
3.6A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.88
0.88
ND
ND
, i30
3.6A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.49
ND
ND
, i30
3.6A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.49
0.49
ND
ND
, i30
3.6A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.49
0.49
ND
ND
, i30
3.6A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.49
0.22
ND
ND
, i30
3.6A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.49
0.34
ND
ND
, i30
3.6B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
54S
UR
5428
-105
303.
6B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
51S
UR
5110
-134
303.
6B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
1.0
=30
3.6B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.50
0.12
ND
ND
303.
6B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
540.
54N
DN
D, i
303.
6B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
500.
047
1.6
=30
3.6B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.50
0.50
ND
ND
, i
B.6
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
D30
3.6B
-TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.26
ND
ND
, i30
3.6B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.50
0.12
ND
ND
303.
6B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
155
SU
R55
28-1
0530
3.6B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
165
SU
R65
10-1
3430
3.6B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.49
0.05
60.
56=
303.
6B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
12.
02.
0N
DN
D, i
303.
6B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
490.
49N
DN
D, i
303.
6B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
490.
047
1.3
=, P
303.
6B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
490.
49N
DN
D, i
303.
6B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
490.
49N
DN
D, i
303.
6B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
490.
12N
DN
D30
3.6C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
54S
UR
5428
-105
303.
6C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
63S
UR
6310
-134
303.
6C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
0.79
=30
3.6C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.50
0.50
ND
ND
, i30
3.6C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.67
0.67
ND
ND
, i30
3.6C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.50
0.04
71.
7=
303.
6C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
500.
50N
DN
D, i
303.
6C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
500.
26N
DN
D, i
303.
6C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
500.
12N
DN
D30
3.6C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
53S
UR
5328
-105
303.
6C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
59S
UR
5910
-134
303.
6C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
490.
056
0.51
=30
3.6C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.82
0.82
ND
ND
, i30
3.6C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.49
ND
ND
, i30
3.6C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.49
0.04
71.
1=,
P30
3.6C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.49
0.49
ND
ND
, i30
3.6C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.49
0.20
ND
ND
, i30
3.6C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.49
0.12
ND
ND
303.
4A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
155
SU
R55
28-1
0530
3.4A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
157
SU
R57
10-1
3430
3.4A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.50
0.05
60.
19=,
J30
3.4A
-TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.50
0.12
ND
ND
303.
4A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
500.
50N
DN
D, i
303.
4A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
500.
047
0.57
=, P
303.
4A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
780.
78N
DN
D, i
303.
4A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
500.
060
ND
ND
303.
4A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
500.
50N
DN
D, i
303.
4A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
161
SU
R61
28-1
0530
3.4A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
167
SU
R67
10-1
3430
3.4A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.49
0.05
60.
076
=, J
303.
4A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
490.
12N
DN
D30
3.4A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.49
ND
ND
, i30
3.4A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.49
0.49
ND
ND
, i30
3.4A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.49
0.40
ND
ND
, i30
3.4A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.49
0.06
8N
DN
D, i
303.
4A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
490.
18N
DN
D, i
303.
4B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
157
SU
R57
28-1
0530
3.4B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
162
SU
R62
10-1
3430
3.4B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.50
0.05
60.
14=,
J
B.7
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
D30
3.4B
-TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.50
0.12
ND
ND
303.
4B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
500.
047
0.77
=, P
303.
4B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
500.
047
0.33
=, J
P30
3.4B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.80
0.80
ND
ND
, i30
3.4B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.06
0N
DN
D30
3.4B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.50
0.50
ND
ND
, i30
3.4B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
60S
UR
6028
-105
303.
4B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
63S
UR
6310
-134
303.
4B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
490.
056
0.16
=, J
P30
3.4B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.49
0.12
ND
ND
303.
4B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
490.
49N
DN
D, i
303.
4B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
490.
49N
DN
D, i
303.
4B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
700.
70N
DN
D, i
303.
4B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
490.
27N
DN
D, i
303.
4B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
490.
19N
DN
D, i
303.
4C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
158
SU
R58
28-1
0530
3.4C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
166
SU
R66
10-1
3430
3.4C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.50
0.05
60.
17=,
JP
303.
4C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
12N
DN
D30
3.4C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.50
0.50
ND
ND
, i30
3.4C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.50
0.04
70.
29=,
JP
303.
4C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
690.
69N
DN
D, i
303.
4C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
500.
15N
DN
D, i
303.
4C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
500.
13N
DN
D, i
303.
4C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
160
SU
R60
28-1
0530
3.4C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
171
SU
R71
10-1
3430
3.4C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.49
0.05
6N
DN
D30
3.4C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.49
0.49
ND
ND
, i30
3.4C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.49
ND
ND
, i30
3.4C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.49
0.49
ND
ND
, i30
3.4C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.49
0.23
ND
ND
, i30
3.4C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.49
0.31
ND
ND
, i30
3.4C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.49
0.17
ND
ND
, i30
3.2A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
51S
UR
5128
-105
303.
2A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
54S
UR
5410
-134
303.
2A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
0.16
=, J
303.
2A-T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
50N
DN
D, i
303.
2A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
500.
50N
DN
D, i
303.
2A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
500.
047
0.85
=30
3.2A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.52
0.52
ND
ND
, i30
3.2A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.06
0N
DN
D30
3.2A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.50
0.12
ND
ND
303.
2A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
152
SU
R52
28-1
0530
3.2A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
156
SU
R56
10-1
3430
3.2A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.49
0.05
60.
14=,
JP
303.
2A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
490.
12N
DN
D30
3.2A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.49
ND
ND
, i30
3.2A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.49
0.49
ND
ND
, i30
3.2A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.49
0.49
ND
ND
, i30
3.2A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.49
0.06
00.
18=,
J
B.8
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
D30
3.2A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.49
0.12
ND
ND
303.
2B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
150
SU
R50
28-1
0530
3.2B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
158
SU
R58
10-1
3430
3.2B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.50
0.05
60.
24=,
JP
303.
2B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
12N
DN
D30
3.2B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.67
0.67
ND
ND
, i30
3.2B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.50
0.04
70.
61=
303.
2B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
870.
87N
DN
D, i
303.
2B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
500.
077
ND
ND
, i30
3.2B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.50
0.50
ND
ND
, i30
3.2B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
56S
UR
5628
-105
303.
2B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
63S
UR
6310
-134
303.
2B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
490.
056
ND
ND
303.
2B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
490.
12N
DN
D30
3.2B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.49
ND
ND
, i30
3.2B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.49
0.04
70.
64=,
P30
3.2B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.49
0.04
7N
DN
D30
3.2B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.49
0.14
ND
ND
, i30
3.2B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.49
0.14
ND
ND
, i30
3.2C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
53S
UR
5328
-105
303.
2C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
69S
UR
6910
-134
303.
2C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
0.27
=, J
303.
2C-T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
12N
DN
D30
3.2C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.50
0.50
ND
ND
, i30
3.2C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.50
0.04
70.
49=,
J30
3.2C
-TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.85
0.85
ND
ND
, i30
3.2C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.50
ND
ND
, i30
3.2C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.50
0.12
ND
ND
303.
2C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
154
SU
R54
28-1
0530
3.2C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
162
SU
R62
10-1
3430
3.2C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.49
0.05
60.
12=,
JP
303.
2C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
490.
12N
DN
D30
3.2C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.49
ND
ND
, i30
3.2C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.49
0.04
70.
48=,
J30
3.2C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.49
0.49
ND
ND
, i30
3.2C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.49
0.34
ND
ND
, i30
3.2C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.49
0.12
ND
ND
303.
3A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
146
SU
R46
28-1
0530
3.3A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
154
SU
R54
10-1
3430
3.3A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n10
5.0
0.56
25=,
D30
3.3A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.50
0.12
11=
303.
3A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
105.
00.
4753
=, D
303.
3A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
100
504.
758
0=,
D30
3.3A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.50
0.04
70.
99=,
P30
3.3A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.06
018
=30
3.3A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T10
5.0
1.2
120
=, D
303.
3A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
151
SU
R51
28-1
0530
3.3A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
158
SU
R58
10-1
3430
3.3A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.49
0.05
613
=30
3.3A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.49
0.12
2.0
=
B.9
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
D30
3.3A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.04
78.
1=
303.
3A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
490.
047
12=
303.
3A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
490.
46N
DN
D, i
303.
3A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
490.
060
9.2
=, P
303.
3A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
490.
124.
8=,
P30
3.3B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
38S
UR
3828
-105
303.
3B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
42S
UR
4210
-134
303.
3B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
7.9
=30
3.3B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.50
0.12
3.2
=30
3.3B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.50
0.04
712
=30
3.3B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T10
5.0
0.47
190
=, D
303.
3B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
500.
047
0.31
=, J
P30
3.3B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.06
06.
6=
303.
3B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
105.
01.
238
=, P
D30
3.3B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
51S
UR
5128
-105
303.
3B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
63S
UR
6310
-134
303.
3B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
490.
056
7.2
=30
3.3B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.49
0.12
1.2
=30
3.3B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.04
75.
8=
303.
3B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
490.
047
5.2
=30
3.3B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.49
0.49
ND
ND
, i30
3.3B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.49
0.06
06.
5=,
P30
3.3B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
2.3
2.3
ND
ND
, i30
3.3C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
49S
UR
4928
-105
303.
3C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
51S
UR
5110
-134
303.
3C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
12=
303.
3C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
123.
5=
303.
3C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
500.
047
16=
303.
3C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
105.
00.
4711
0=,
D30
3.3C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.50
0.41
ND
ND
, i30
3.3C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.06
011
=, P
303.
3C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
105.
01.
215
=, P
D30
3.3C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
53S
UR
5328
-105
303.
3C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
58S
UR
5810
-134
303.
3C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
490.
056
7.6
=30
3.3C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.49
0.12
1.0
=30
3.3C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.49
0.04
77.
1=
303.
3C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
490.
047
4.4
=30
3.3C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.49
0.04
70.
38=,
JP
303.
3C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
12.
82.
8N
DN
D, i
303.
3C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
11.
91.
9N
DN
D, i
Bli
nd D
up.-
TS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e10
00
SUR
, D,#
028
-105
Bli
nd D
up.-
TS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
100
0SU
R, E
D,#
010
-134
Bli
nd D
up.-
TS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n10
0050
056
2700
=, D
Bli
nd D
up.-
TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E10
050
1236
0=,
DB
lind
Dup
.-T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
100
504.
792
0=,
DB
lind
Dup
.-T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
100
504.
720
00=,
DB
lind
Dup
.-T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
100
5050
ND
ND
, iB
lind
Dup
.-T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
100
506.
017
00=,
DB
lind
Dup
.-T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
1000
500
120
2800
=, P
D
B.1
0
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
DB
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
100
0SU
R, D
,#0
28-1
05B
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l10
00
SUR
, D,#
010
-134
Bli
nd D
up.-
DS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n10
0049
056
2600
=, D
Bli
nd D
up.-
DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E10
049
1216
0=,
DB
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
100
494.
783
0=,
DB
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
100
494.
791
0=,
DB
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
100
9393
ND
ND
, iB
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
100
496.
010
00=,
DB
lind
Dup
.-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
100
560
560
ND
ND
, iS
eep
A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
100
0SU
R, D
,#0
28-1
05S
eep
A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l10
00
SUR
, D,#
010
-134
See
p A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n10
0048
056
3100
=, D
See
p A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E10
048
1237
0=,
DS
eep
A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
100
484.
713
00=,
DS
eep
A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
1000
480
4719
00=,
DS
eep
A- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
100
484.
727
0=
, PD
See
p A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D10
048
6.0
1900
=, D
See
p A
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T10
0048
012
031
00=
, PD
See
p A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e10
00
SUR
, D,#
028
-105
See
p A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
100
0SU
R, D
,#0
10-1
34S
eep
A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
1000
490
5624
00=,
DS
eep
A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
100
4912
160
=, D
See
p A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D10
049
4.7
640
=, D
See
p A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T10
049
4.7
920
=, D
See
p A
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E10
049
4.7
190
=, P
DS
eep
A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
100
496.
010
00=,
DS
eep
A-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
100
440
440
ND
ND
, iS
eep
B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
100
0SU
R, D
,#0
28-1
05S
eep
B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l10
00
SUR
, ED
,#0
10-1
34S
eep
B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
1000
490
5629
00=,
DS
eep
B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
100
4912
340
=, D
See
p B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D10
049
4.7
1500
=, P
DS
eep
B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
1000
490
4720
00=,
DS
eep
B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
100
494.
732
0=
, PD
See
p B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D10
049
6.0
1800
=, D
See
p B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T10
0049
012
032
00=
, PD
See
p B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e10
00
SUR
, D,#
028
-105
See
p B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
100
0SU
R, D
,#0
10-1
34S
eep
B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
1000
490
5626
00=,
DS
eep
B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
100
4912
130
=, P
DS
eep
B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
100
494.
748
0=,
DS
eep
B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
100
494.
774
0=,
DS
eep
B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
100
6262
ND
ND
, iS
eep
B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
100
496.
085
0=,
DS
eep
B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
100
320
320
ND
ND
, iS
eep
C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
100
0SU
R, D
,#0
28-1
05S
eep
C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l10
00
SUR
, ED
,#0
10-1
34S
eep
C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
1000
490
5630
00=,
DS
eep
C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
100
4912
390
=, D
See
p C
- TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D10
049
4.7
1300
=, D
B.1
1
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
DS
eep
C-T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
1000
490
4720
00=,
DS
eep
C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
100
494.
729
0=,
DS
eep
C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
100
496.
018
00=,
DS
eep
C- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
1000
490
120
3200
=, P
DS
eep
C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
100
0SU
R, D
,#0
28-1
05S
eep
C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l10
00
SUR
, ED
,#0
10-1
34S
eep
C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
1000
490
5624
00=,
DS
eep
C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
100
4912
170
=, D
See
p C
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D10
049
4.7
1000
=, P
DS
eep
C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
100
494.
795
0=,
DS
eep
C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
100
4948
ND
ND
, iS
eep
C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
100
496.
010
00=,
DS
eep
C-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
100
620
620
ND
ND
, i30
3.1B
-DM
S1E
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
58S
UR
5828
-105
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
66S
UR
6628
-105
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
110
5S
UR
105
10-1
34L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/Lal
pha-
BH
C1
0.50
0.25
3.54
=4.
0089
62-1
14L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/Lal
pha-
BH
C1
0.50
0.25
4.03
=4.
0010
162
-114
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
beta
-BH
C1
0.50
0.50
4.65
=4.
0011
657
-126
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
gam
ma-
BH
C (
Lin
dane
)1
0.50
0.20
3.49
=4.
0087
65-1
18L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/Lga
mm
a-B
HC
(L
inda
ne)
10.
500.
204.
04=
4.00
101
65-1
18L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/Lde
lta-
BH
C1
0.50
0.06
24.
56=
4.00
114
10-1
44L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LH
epta
chlo
r1
0.50
0.07
33.
40=
4.00
8550
-119
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Hep
tach
lor
10.
500.
073
3.86
=4.
0096
50-1
19L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LA
ldri
n1
0.50
0.14
3.34
=4.
0083
58-1
17L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LH
epta
chlo
r E
poxi
de1
0.50
0.21
3.57
=4.
0089
62-1
18L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LH
epta
chlo
r E
poxi
de1
0.50
0.21
3.76
=4.
0094
62-1
18L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/Lga
mm
a-C
hlor
dane
10.
500.
065
3.93
=4.
0098
61-1
21L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LE
ndos
ulfa
n I
10.
500.
103.
25=
4.00
8150
-128
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
alph
a-C
hlor
dane
10.
500.
044
3.82
=4.
0096
63-1
18L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
3.89
=4.
0097
65-1
29L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
3.94
=4.
0098
65-1
29L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
124.
22=
4.00
105
69-1
27L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LE
ndri
n1
0.50
0.05
43.
81=
4.00
9566
-125
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
End
rin
10.
500.
054
4.04
=4.
0010
166
-125
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
End
osul
fan
II1
0.50
0.06
33.
73=
4.00
9363
-123
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.50
0.04
74.
32=
4.00
108
66-1
32L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
500.
047
5.54
=, *
4.00
139
66-1
32L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LE
ndri
n A
ldeh
yde
10.
500.
038
4.09
=4.
0010
264
-113
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
End
osul
fan
Sul
fate
10.
500.
134.
43=
4.00
111
66-1
15L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
500.
047
4.83
=4.
0012
169
-130
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.50
0.04
75.
03=
4.00
126
69-1
30L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LE
ndri
n K
eton
e1
0.50
0.03
04.
25=
4.00
106
69-1
26L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LM
etho
xych
lor
10.
500.
174.
61=,
P4.
0011
559
-136
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
60S
UR
6028
-105
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
189
SU
R89
10-1
34L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
500.
060
4.13
=5.
0083
70-1
30L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
500.
047
4.00
=5.
0080
70-1
30L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
500.
124.
66=
5.00
9370
-130
Dup
lica
te L
ab C
ontr
oD
LC
S1
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
155
SU
R55
28-1
05
B.1
2
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
DD
upli
cate
Lab
Con
tro
DL
CS
1E
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
169
SU
R69
10-1
34D
upli
cate
Lab
Con
tro
DL
CS
1E
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.06
04.
43=
5.00
8970
-130
7D
upli
cate
Lab
Con
tro
DL
CS
1E
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.50
0.04
73.
89=
5.00
7870
-130
3D
upli
cate
Lab
Con
tro
DL
CS
1E
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.50
0.12
3.76
=5.
0075
70-1
3021
303.
1B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
480.
056
ND
ND
303.
1B-D
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
480.
12N
DN
D30
3.1B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.48
0.48
ND
ND
, i30
3.1B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.48
0.48
ND
ND
, i30
3.1B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.74
0.74
ND
ND
, i30
3.1B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.48
0.17
ND
ND
, i30
3.1B
-DS
MP
LE
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.48
0.20
ND
ND
, i30
3.1B
-DM
S1E
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
193
SU
R93
10-1
3430
3.1B
-DM
S1E
PA
35
20
C80
81A
ng/L
Die
ldri
n1
1.9
0.21
13.1
=14
.889
35-1
3730
3.1B
-DM
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
1.9
0.45
16.1
=14
.810
822
-148
303.
1B-D
MS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
11.
90.
1823
.2=,
*14
.815
732
-148
303.
1B-D
MS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
11.
90.
1817
.8=
14.8
120
37-1
4330
3.1B
-DD
MS1
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
154
SU
R54
28-1
0530
3.1B
-DD
MS1
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
87S
UR
8710
-134
303.
1B-D
DM
S1E
PA
35
20
C80
81A
ng/L
Die
ldri
n1
2.3
0.26
15.4
=18
.285
35-1
3716
303.
1B-D
DM
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
2.3
0.55
16.9
=18
.293
22-1
485
303.
1B-D
DM
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
2.3
0.22
25.4
=18
.214
032
-148
930
3.1B
-DD
MS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
12.
30.
2220
.7=
18.2
114
37-1
4315
303.
1B- T
MS1
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
172
SU
R72
28-1
0530
3.1B
- TM
S1E
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
197
SU
R97
10-1
3430
3.1B
- TM
S1E
PA
35
20
C80
81A
ng/L
Die
ldri
n1
2.0
0.23
15.7
=16
.097
35-1
3730
3.1B
- TM
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
2.0
0.48
16.6
=16
.010
422
-148
303.
1B- T
MS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
12.
00.
1924
.2=,
*16
.015
132
-148
303.
1B- T
MS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
12.
00.
1920
.7=
16.0
126
37-1
4330
3.1B
- TD
MS1
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
172
SU
R72
28-1
0530
3.1B
- TD
MS1
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
94S
UR
9410
-134
303.
1B- T
DM
S1E
PA
35
20
C80
81A
ng/L
Die
ldri
n1
2.0
0.23
15.3
=16
.094
35-1
373
303.
1B- T
DM
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
2.0
0.48
16.3
=16
.010
222
-148
230
3.1B
- TD
MS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
12.
00.
1922
.0=
16.0
137
32-1
489
303.
1B- T
DM
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
2.0
0.19
22.5
=16
.013
737
-143
8L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
166
SU
R66
28-1
05L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
105
SU
R10
510
-134
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
alph
a-B
HC
10.
500.
254.
03=
4.00
101
62-1
14L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/Lbe
ta-B
HC
10.
500.
504.
65=
4.00
116
57-1
26L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/Lga
mm
a-B
HC
(L
inda
ne)
10.
500.
204.
04=
4.00
101
65-1
18L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/Lde
lta-
BH
C1
0.50
0.06
24.
10=
4.00
103
10-1
44L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/Lde
lta-
BH
C1
0.50
0.06
24.
56=
4.00
114
10-1
44L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LH
epta
chlo
r1
0.50
0.07
33.
86=
4.00
9650
-119
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Ald
rin
10.
500.
143.
34=
4.00
8358
-117
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Hep
tach
lor
Epo
xide
10.
500.
213.
76=
4.00
9462
-118
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
gam
ma-
Chl
orda
ne1
0.50
0.06
53.
93=
4.00
9861
-121
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
End
osul
fan
I1
0.50
0.10
2.93
=4.
0073
50-1
28L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LE
ndos
ulfa
n I
10.
500.
103.
25=
4.00
8150
-128
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
alph
a-C
hlor
dane
10.
500.
044
3.82
=4.
0096
63-1
18L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
3.94
=4.
0098
65-1
29L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
124.
22=
4.00
105
69-1
27
B.1
3
Tab
le B
-1.
2003
Wat
er C
hem
istr
y
Sam
ple
Sam
ple
Typ
e
Ext
ract
ion
Met
hod
Met
hod
Uni
tsC
ompo
nent
Dil
utio
n
Fac
tor
Rep
orti
ng
Lim
it
Det
ecti
on
Lim
itR
esul
t
Res
ult
Not
es
Spi
ke
Con
cent
rati
on
Per
cent
Rec
over
y
Acc
epta
nce
Lim
its
Ave
rage
RP
DL
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LE
ndri
n1
0.50
0.05
44.
04=
4.00
101
66-1
25L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LE
ndos
ulfa
n II
10.
500.
063
3.73
=4.
0093
63-1
23L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
500.
047
5.54
=, *
4.00
139
66-1
32L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LE
ndri
n A
ldeh
yde
10.
500.
038
3.89
=4.
0097
64-1
13L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LE
ndri
n A
ldeh
yde
10.
500.
038
4.09
=4.
0010
264
-113
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
End
osul
fan
Sul
fate
10.
500.
134.
43=
4.00
111
66-1
15L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
500.
047
5.03
=4.
0012
669
-130
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
End
rin
Ket
one
10.
500.
030
4.16
=4.
0010
469
-126
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
End
rin
Ket
one
10.
500.
030
4.25
=4.
0010
669
-126
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Met
hoxy
chlo
r1
0.50
0.17
4.61
=, P
4.00
115
59-1
3630
3.1B
- TS
MP
LE
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.50
0.05
60.
21=,
J30
3.1B
-TS
MP
LE
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.50
0.12
ND
ND
303.
1B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
500.
50N
DN
D, i
303.
1B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
500.
047
0.52
=, P
303.
1B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
500.
047
ND
ND
303.
1B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
500.
060
ND
ND
303.
1B- T
SM
PL
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
500.
50N
DN
D, i
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8081
Ang
/LT
etra
chlo
ro-m
-xyl
ene
147
SU
R47
28-1
05M
etho
d B
lank
MB
1E
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
196
SU
R96
10-1
34M
etho
d B
lank
MB
1E
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.50
0.05
6N
DN
DM
etho
d B
lank
MB
1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.50
0.12
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DD
10.
500.
047
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
500.
047
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DE
10.
500.
047
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DD
10.
500.
060
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8081
Ang
/L2,
4'-D
DT
10.
500.
12N
DN
DM
etho
d B
lank
MB
1E
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
50S
UR
5028
-105
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
97S
UR
9710
-134
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
12N
DN
DM
etho
d B
lank
MB
1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.50
0.04
7N
DN
DM
etho
d B
lank
MB
1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.50
0.04
7N
DN
DM
etho
d B
lank
MB
1E
PA
35
20
C80
81A
ng/L
2,4'
-DD
E1
0.50
0.04
7N
DN
DM
etho
d B
lank
MB
1E
PA
35
20
C80
81A
ng/L
2,4'
-DD
D1
0.50
0.06
0N
DN
DM
etho
d B
lank
MB
1E
PA
35
20
C80
81A
ng/L
2,4'
-DD
T1
0.50
0.12
0.22
=, J
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
45S
UR
4528
-105
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
189
SU
R89
10-1
34L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LD
ield
rin
10.
500.
056
3.52
=4.
0088
65-1
29L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DE
10.
500.
123.
92=
4.00
9869
-127
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.50
0.04
74.
86=
4.00
121
66-1
32L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/L4,
4'-D
DT
10.
500.
047
4.82
=4.
0012
169
-130
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Tet
rach
loro
-m-x
ylen
e1
66S
UR
6628
-105
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Dec
achl
orob
iphe
nyl
110
2S
UR
102
10-1
34L
ab C
ontr
ol S
ampl
eL
CS1
EP
A 3
52
0C
8081
Ang
/LD
ecac
hlor
obip
heny
l1
105
SU
R10
510
-134
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
Die
ldri
n1
0.50
0.05
63.
94=
4.00
9865
-129
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
E1
0.50
0.12
4.22
=4.
0010
569
-127
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
D1
0.50
0.04
75.
54=,
*4.
0013
966
-132
Lab
Con
trol
Sam
ple
LC
S1E
PA
35
20
C80
81A
ng/L
4,4'
-DD
T1
0.50
0.04
75.
03=
4.00
126
69-1
30
B.1
4
Tab
le B
-2.
2003
Tis
sue
Che
mis
try
Sam
ple
Sam
ple
Typ
eE
xtra
ctio
n M
etho
dM
etho
dB
asis
Uni
tsC
ompo
nent
Dilu
tion
Fac
tor
Rep
ortin
gL
imit
Det
ecti
onL
imit
Res
ult
Res
ult N
otes
Spik
eC
once
ntra
tio
nP
erce
ntR
ecov
ery
Acc
epta
nce
Lim
itsA
vera
geR
PD
2021
2-Y
6-01
SM
PL
BL
IGH
& D
YE
RP
SE
PA
s R
ecei
ved
PER
CE
NT
Lip
ids,
Tot
al1
0.17
0.78
=
2021
2-Y
6-02
SM
PL
BL
IGH
& D
YE
RP
SE
PA
s R
ecei
ved
PER
CE
NT
Lip
ids,
Tot
al1
0.16
0.75
=
2021
2-Y
6-03
SM
PL
BL
IGH
& D
YE
RP
SE
PA
s R
ecei
ved
PER
CE
NT
Lip
ids,
Tot
al1
0.16
0.84
=
2021
2-Y
6-04
SM
PL
BL
IGH
& D
YE
RP
SE
PA
s R
ecei
ved
PER
CE
NT
Lip
ids,
Tot
al1
0.17
1.2
=
2021
2-Y
6-05
SM
PL
BL
IGH
& D
YE
RP
SE
PA
s R
ecei
ved
PER
CE
NT
Lip
ids,
Tot
al1
0.17
0.55
=
2021
2-Y
6-07
SM
PL
BL
IGH
& D
YE
RP
SE
PA
s R
ecei
ved
PER
CE
NT
Lip
ids,
Tot
al1
0.16
1=
2021
2-Y
6-08
SM
PL
BL
IGH
& D
YE
RP
SE
PA
s R
ecei
ved
PER
CE
NT
Lip
ids,
Tot
al1
0.16
0.68
=
2021
2-Y
6-04
DU
P1
BL
IGH
& D
YE
RP
SE
PA
s R
ecei
ved
PER
CE
NT
Lip
ids,
Tot
al1
0.17
1.2
=1.
2<
1
2021
2-Y
6-04
TP
LB
LIG
H &
DY
ER
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
171.
2=
1.2
<1
2021
2-Y
6-01
SM
PL
EP
A 3
540
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
025
0.81
=
2021
2-Y
6-02
SM
PL
EP
A 3
540
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
025
1=
2021
2-Y
6-03
SM
PL
EP
A 3
540
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
025
1.2
=
2021
2-Y
6-04
SM
PL
EP
A 3
540
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
025
1.5
=
2021
2-Y
6-05
SM
PL
EP
A 3
540
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
025
0.56
=
2021
2-Y
6-06
SM
PL
EP
A 3
540
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
025
1.6
=
2021
2-Y
6-07
SM
PL
EP
A 3
540
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
025
0.74
=
2021
2-Y
6-08
SM
PL
EP
A 3
540
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
025
0.79
=
2021
2-Y
6-07
DU
P1
EP
A 3
540
PS
EP
As
Rec
eive
dPE
RC
EN
TL
ipid
s, T
otal
10.
025
0.83
=0.
785
8
2021
2-Y
6-04
TP
LE
PA
354
0P
SE
PA
s R
ecei
ved
PER
CE
NT
Lip
ids,
Tot
al1
0.02
51.
5=
1.5
<1
2021
2-Y
6-01
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e10
92SU
R, D
100
9238
-109
2021
2-Y
6-01
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
1011
8SU
R, D
100
118
51-1
20
2021
2-Y
6-01
SMPL
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
1010
0.63
20=
, PD
2021
2-Y
6-01
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
1010
1.1
68=
, D
2021
2-Y
6-01
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
1010
1.5
130
=, D
2021
2-Y
6-01
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
1010
1.6
92=
, D
2021
2-Y
6-01
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
1010
1.3
68=
, D
2021
2-Y
6-01
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
1010
2.6
ND
ND
2021
2-Y
6-01
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
1010
1.4
59=
, D
2021
2-Y
6-02
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e10
98SU
R, D
100
9838
-109
2021
2-Y
6-02
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
1011
3SU
R, D
100
113
51-1
20
2021
2-Y
6-02
SMPL
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
1010
0.63
49=
, D
2021
2-Y
6-02
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
1010
1.1
110
=, D
2021
2-Y
6-02
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
1010
1.5
390
=, D
2021
2-Y
6-02
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
1010
1.6
180
=, D
2021
2-Y
6-02
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
1010
1.3
150
=, D
2021
2-Y
6-02
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
1010
10N
DN
D, i
2021
2-Y
6-02
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
1010
1.4
99=
, D
2021
2-Y
6-03
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e10
97SU
R, D
100
9738
-109
2021
2-Y
6-03
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
1011
6SU
R, D
100
116
51-1
20
2021
2-Y
6-03
SMPL
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
1010
0.63
6.2
=, J
PD
2021
2-Y
6-03
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
1010
1.1
41=
, D
2021
2-Y
6-03
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
1010
1.5
56=
, D
2021
2-Y
6-03
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
1010
1.6
57=
, D
2021
2-Y
6-03
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
1010
1.3
29=
, D
B.1
5
Tab
le B
-2.
2003
Tis
sue
Che
mis
try
Sam
ple
Sam
ple
Typ
eE
xtra
ctio
n M
etho
dM
etho
dB
asis
Uni
tsC
ompo
nent
Dilu
tion
Fac
tor
Rep
ortin
gL
imit
Det
ecti
onL
imit
Res
ult
Res
ult N
otes
Spik
eC
once
ntra
tio
nP
erce
ntR
ecov
ery
Acc
epta
nce
Lim
itsA
vera
geR
PD
2021
2-Y
6-03
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
1010
2.6
ND
ND
2021
2-Y
6-03
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
1010
1.4
31=
, D
2021
2-Y
6-04
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e1
99S
UR
100
9938
-109
2021
2-Y
6-04
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
190
SU
R10
090
51-1
20
2021
2-Y
6-04
SMPL
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
11
0.06
32.
9=
2021
2-Y
6-04
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
11
0.11
17=
2021
2-Y
6-04
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
11
0.15
11=
2021
2-Y
6-04
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
19.
79.
7N
DN
D, i
2021
2-Y
6-04
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
13.
83.
8N
DN
D, i
2021
2-Y
6-04
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
11
0.26
ND
ND
2021
2-Y
6-04
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
15.
75.
7N
DN
D, i
2021
2-Y
6-05
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e1
88S
UR
100
8838
-109
2021
2-Y
6-05
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
185
SU
R10
085
51-1
20
2021
2-Y
6-05
SMPL
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
11
0.06
31.
3=
2021
2-Y
6-05
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
11
0.11
9.4
=
2021
2-Y
6-05
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
19.
39.
3N
DN
D, i
2021
2-Y
6-05
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
11
0.16
8.6
=
2021
2-Y
6-05
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
11
0.13
6.8
=
2021
2-Y
6-05
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
11
0.26
ND
ND
2021
2-Y
6-05
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
14.
74.
7N
DN
D, i
2021
2-Y
6-06
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e10
013
6SU
R, D
,#10
013
638
-109
2021
2-Y
6-06
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
100
0SU
R, D
,#10
00
51-1
20
2021
2-Y
6-06
SMPL
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
100
110
6.6
4000
=, D
2021
2-Y
6-06
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
1000
1100
120
1500
0=
, D
2021
2-Y
6-06
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
1000
1100
160
2100
0=
, D
2021
2-Y
6-06
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
1000
1100
170
3100
0=
, D
2021
2-Y
6-06
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
1000
1100
140
3200
0=
, D
2021
2-Y
6-06
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
100
110
2717
00=
, D
2021
2-Y
6-06
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
1000
1100
150
3500
0=
, D
2021
2-Y
6-07
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e10
97SU
R, D
100
9738
-109
2021
2-Y
6-07
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
1010
9SU
R, D
100
109
51-1
20
2021
2-Y
6-07
SMPL
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
1010
0.63
18=
, PD
2021
2-Y
6-07
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
1010
1.1
64=
, D
2021
2-Y
6-07
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
1010
1.5
110
=, D
2021
2-Y
6-07
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
1010
1.6
120
=, D
2021
2-Y
6-07
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
1010
1.3
61=
, D
2021
2-Y
6-07
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
1010
2.6
ND
ND
2021
2-Y
6-07
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
1010
1.4
76=
, D
2021
2-Y
6-08
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e10
93SU
R, D
100
9338
-109
2021
2-Y
6-08
SMPL
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
1011
1SU
R, D
100
111
51-1
20
2021
2-Y
6-08
SMPL
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
1010
0.63
26=
, D
2021
2-Y
6-08
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
1010
1.1
86=
, D
2021
2-Y
6-08
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
1010
1.5
130
=, D
2021
2-Y
6-08
SMPL
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
1010
1.6
200
=, D
B.1
6
Tab
le B
-2.
2003
Tis
sue
Che
mis
try
Sam
ple
Sam
ple
Typ
eE
xtra
ctio
n M
etho
dM
etho
dB
asis
Uni
tsC
ompo
nent
Dilu
tion
Fac
tor
Rep
ortin
gL
imit
Det
ecti
onL
imit
Res
ult
Res
ult N
otes
Spik
eC
once
ntra
tio
nP
erce
ntR
ecov
ery
Acc
epta
nce
Lim
itsA
vera
geR
PD
2021
2-Y
6-08
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
1010
1.3
78=
, D
2021
2-Y
6-08
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
1010
10N
DN
D, i
2021
2-Y
6-08
SMPL
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
1010
1.4
120
=, D
2021
2-Y
6-05
DU
P1
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e1
94S
UR
100
9438
-109
2021
2-Y
6-05
DU
P1
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
182
SU
R10
082
51-1
20
2021
2-Y
6-05
DU
P1
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
11
0.06
31.
3=
1.3
1
2021
2-Y
6-05
DU
P1
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
11
0.11
8.4
=8.
911
2021
2-Y
6-05
DU
P1
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
17.
97.
9N
DN
D, i
ND
2021
2-Y
6-05
DU
P1
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
11
0.16
7.4
=8.
015
2021
2-Y
6-05
DU
P1
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
11
0.13
6.1
=6.
512
2021
2-Y
6-05
DU
P1
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
11
0.26
ND
ND
ND
2021
2-Y
6-05
DU
P1
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
14.
14.
1N
DN
D, i
ND
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e1
88S
UR
100
8838
-109
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
110
3S
UR
100
103
51-1
20
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
11
0.06
3N
DN
D
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
11
0.11
1.5
=, P
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
11
0.15
1.5
=, P
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
11
0.16
8.4
=
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
11
0.13
0.5
=, J
P
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
11
0.26
ND
ND
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
11
0.14
4.9
=
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
PER
CE
NT
Tet
rach
loro
-m-x
ylen
e1
82S
UR
100
8238
-109
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
186
SU
R10
086
51-1
20
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
gD
ield
rin
11
0.06
3N
DN
D
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
11
0.11
ND
ND
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
11
0.15
ND
ND
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
11
0.16
ND
ND
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
11
0.13
ND
ND
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
11
0.26
ND
ND
Met
hod
Bla
nkM
B1
EPA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
11
0.14
ND
ND
2021
2-Y
6-05
MS1
EP
A 3
540C
8081
AW
etP
ER
CE
NT
Tet
rach
loro
-m-x
ylen
e1
87S
UR
100
8738
-109
2021
2-Y
6-05
MS1
EP
A 3
540C
8081
AW
etP
ER
CE
NT
Dec
achl
orob
iphe
nyl
185
SU
R10
085
51-1
20
2021
2-Y
6-05
MS1
EP
A 3
540C
8081
AW
etug
/Kg
Die
ldri
n1
10.
063
19.9
=20
9327
-175
2021
2-Y
6-05
MS1
EP
A 3
540C
8081
AW
etug
/Kg
4,4'
-DD
E1
10.
1127
.4=
2090
38-1
37
2021
2-Y
6-05
MS1
EP
A 3
540C
8081
AW
etug
/Kg
4,4'
-DD
D1
10.
1527
=, #
2013
541
-145
2021
2-Y
6-05
MS1
EP
A 3
540C
8081
AW
etug
/Kg
4,4'
-DD
T1
10.
1625
.5=
2084
34-1
54
2021
2-Y
6-05
MS1
EP
A 3
540C
8081
AW
etug
/Kg
2,4'
-DD
D1
10.
1324
.9=
2090
70-1
30
2021
2-Y
6-05
MS1
EP
A 3
540C
8081
AW
etug
/Kg
2,4'
-DD
E1
10.
2619
=20
9570
-130
2021
2-Y
6-05
MS1
EP
A 3
540C
8081
AW
etug
/Kg
2,4'
-DD
T1
10.
1423
.5=
, #20
117
70-1
30
2021
2-Y
6-05
DM
S1E
PA 3
540C
8081
AW
etPE
RC
EN
TT
etra
chlo
ro-m
-xyl
ene
193
SU
R10
093
38-1
09
2021
2-Y
6-05
DM
S1E
PA 3
540C
8081
AW
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
84S
UR
100
8451
-120
2021
2-Y
6-05
DM
S1E
PA 3
540C
8081
AW
etug
/Kg
Die
ldri
n1
10.
063
22=
2010
427
-175
10
2021
2-Y
6-05
DM
S1E
PA 3
540C
8081
AW
etug
/Kg
4,4'
-DD
E1
10.
1131
.5=
2011
038
-137
14
2021
2-Y
6-05
DM
S1E
PA 3
540C
8081
AW
etug
/Kg
4,4'
-DD
D1
10.
1530
.8=
, #20
154
41-1
4513
B.1
7
Tab
le B
-2.
2003
Tis
sue
Che
mis
try
Sam
ple
Sam
ple
Typ
eE
xtra
ctio
n M
etho
dM
etho
dB
asis
Uni
tsC
ompo
nent
Dilu
tion
Fac
tor
Rep
ortin
gL
imit
Det
ecti
onL
imit
Res
ult
Res
ult N
otes
Spik
eC
once
ntra
tio
nP
erce
ntR
ecov
ery
Acc
epta
nce
Lim
itsA
vera
geR
PD
2021
2-Y
6-05
DM
S1E
PA 3
540C
8081
AW
etug
/Kg
4,4'
-DD
T1
10.
1629
.2=
2010
334
-154
14
2021
2-Y
6-05
DM
S1E
PA 3
540C
8081
AW
etug
/Kg
2,4'
-DD
D1
10.
1325
.8=
2095
70-1
304
2021
2-Y
6-05
DM
S1E
PA 3
540C
8081
AW
etug
/Kg
2,4'
-DD
E1
10.
2619
.5=
2098
70-1
303
2021
2-Y
6-05
DM
S1E
PA 3
540C
8081
AW
etug
/Kg
2,4'
-DD
T1
10.
1424
.4=
, #20
122
70-1
304
Lab
Con
trol
Sam
ple
LC
S1E
PA 3
540C
8081
AW
etPE
RC
EN
TT
etra
chlo
ro-m
-xyl
ene
196
SU
R10
096
38-1
09
Lab
Con
trol
Sam
ple
LC
S1E
PA 3
540C
8081
AW
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
99S
UR
100
9951
-120
Lab
Con
trol
Sam
ple
LC
S1E
PA 3
540C
8081
AW
etug
/Kg
Die
ldri
n1
10.
063
21.9
=20
110
44-1
51
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
11
0.11
29.3
=, B
2014
738
-158
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
11
0.15
37.1
=, *
2018
537
-154
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
11
0.16
35.7
=, B
,*20
179
48-1
56
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
11
0.13
20.2
=20
101
70-1
30
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
11
0.26
19.8
=20
9970
-130
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
11
0.14
21.7
=, B
2010
970
-130
Lab
Con
trol
Sam
ple
LC
S1E
PA 3
540C
8081
AW
etPE
RC
EN
TT
etra
chlo
ro-m
-xyl
ene
179
SU
R10
079
38-1
09
Lab
Con
trol
Sam
ple
LC
S1E
PA 3
540C
8081
AW
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
83S
UR
100
8351
-120
Lab
Con
trol
Sam
ple
LC
S1E
PA 3
540C
8081
AW
etug
/Kg
Die
ldri
n1
10.
063
20.2
=20
101
44-1
51
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DE
11
0.11
20.6
=20
103
38-1
58
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DD
11
0.15
20.6
=20
103
37-1
54
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g4,
4'-D
DT
11
0.16
20.4
=20
102
48-1
56
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DD
11
0.13
19.9
=20
9970
-130
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DE
11
0.26
19.8
=20
9970
-130
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
81A
Wet
ug/K
g2,
4'-D
DT
11
0.14
19.9
=20
9970
-130
2021
2-Y
6-01
SMPL
EPA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
99S
UR
100
9940
-141
2021
2-Y
6-01
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
101
61
100.
65N
DN
D
2021
2-Y
6-01
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
122
11
200.
65N
DN
D
2021
2-Y
6-01
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
123
21
100.
65N
DN
D
2021
2-Y
6-01
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
21
100.
65N
DN
D
2021
2-Y
6-01
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
81
100.
65N
DN
D
2021
2-Y
6-01
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
125
41
100.
6514
0=
, P
2021
2-Y
6-01
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
126
01
100.
65N
DN
D
2021
2-Y
6-02
SMPL
EPA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
92S
UR
100
9240
-141
2021
2-Y
6-02
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
101
61
100.
65N
DN
D
2021
2-Y
6-02
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
122
11
200.
65N
DN
D
2021
2-Y
6-02
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
123
21
100.
65N
DN
D
2021
2-Y
6-02
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
21
100.
65N
DN
D
2021
2-Y
6-02
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
81
100.
65N
DN
D
2021
2-Y
6-02
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
125
41
100.
6527
0=
, P
2021
2-Y
6-02
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
126
01
100.
65N
DN
D
2021
2-Y
6-03
SMPL
EPA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
97S
UR
100
9740
-141
2021
2-Y
6-03
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
101
61
100.
65N
DN
D
2021
2-Y
6-03
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
122
11
200.
65N
DN
D
2021
2-Y
6-03
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
123
21
100.
65N
DN
D
2021
2-Y
6-03
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
21
100.
65N
DN
D
2021
2-Y
6-03
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
81
100.
65N
DN
D
B.1
8
Tab
le B
-2.
2003
Tis
sue
Che
mis
try
Sam
ple
Sam
ple
Typ
eE
xtra
ctio
n M
etho
dM
etho
dB
asis
Uni
tsC
ompo
nent
Dilu
tion
Fac
tor
Rep
ortin
gL
imit
Det
ecti
onL
imit
Res
ult
Res
ult N
otes
Spik
eC
once
ntra
tio
nP
erce
ntR
ecov
ery
Acc
epta
nce
Lim
itsA
vera
geR
PD
2021
2-Y
6-03
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
125
41
100.
6596
=, P
2021
2-Y
6-03
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
126
01
100.
65N
DN
D
2021
2-Y
6-04
SMPL
EPA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
95S
UR
100
9540
-141
2021
2-Y
6-04
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
101
61
100.
65N
DN
D
2021
2-Y
6-04
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
122
11
200.
65N
DN
D
2021
2-Y
6-04
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
123
21
100.
65N
DN
D
2021
2-Y
6-04
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
21
100.
65N
DN
D
2021
2-Y
6-04
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
81
100.
65N
DN
D
2021
2-Y
6-04
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
125
41
100.
6593
=
2021
2-Y
6-04
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
126
01
100.
65N
DN
D
2021
2-Y
6-05
SMPL
EPA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
94S
UR
100
9440
-141
2021
2-Y
6-05
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
101
61
100.
65N
DN
D
2021
2-Y
6-05
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
122
11
200.
65N
DN
D
2021
2-Y
6-05
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
123
21
100.
65N
DN
D
2021
2-Y
6-05
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
21
100.
65N
DN
D
2021
2-Y
6-05
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
81
100.
65N
DN
D
2021
2-Y
6-05
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
125
41
100.
6545
=
2021
2-Y
6-05
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
126
01
100.
65N
DN
D
2021
2-Y
6-06
SMPL
EPA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l20
011
2SU
R, D
,#10
011
240
-141
2021
2-Y
6-06
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
101
620
021
0014
0N
DN
D
2021
2-Y
6-06
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
122
120
042
0014
0N
DN
D
2021
2-Y
6-06
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
123
220
021
0014
0N
DN
D
2021
2-Y
6-06
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
220
021
0014
0N
DN
D
2021
2-Y
6-06
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
820
021
0014
0N
DN
D
2021
2-Y
6-06
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
125
420
031
0031
00N
DN
D, i
2021
2-Y
6-06
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
126
020
021
0014
0N
DN
D
2021
2-Y
6-07
SMPL
EPA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
92S
UR
100
9240
-141
2021
2-Y
6-07
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
101
61
100.
65N
DN
D
2021
2-Y
6-07
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
122
11
200.
65N
DN
D
2021
2-Y
6-07
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
123
21
100.
65N
DN
D
2021
2-Y
6-07
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
21
100.
65N
DN
D
2021
2-Y
6-07
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
81
100.
65N
DN
D
2021
2-Y
6-07
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
125
41
100.
6590
=, P
2021
2-Y
6-07
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
126
01
100.
65N
DN
D
2021
2-Y
6-08
SMPL
EPA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
95S
UR
100
9540
-141
2021
2-Y
6-08
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
101
61
100.
65N
DN
D
2021
2-Y
6-08
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
122
11
200.
65N
DN
D
2021
2-Y
6-08
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
123
21
100.
65N
DN
D
2021
2-Y
6-08
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
21
100.
65N
DN
D
2021
2-Y
6-08
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
124
81
100.
65N
DN
D
2021
2-Y
6-08
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
125
41
100.
6511
0=
, P
2021
2-Y
6-08
SMPL
EPA
354
0C80
82W
etug
/Kg
Aro
clor
126
01
100.
65N
DN
D
2021
2-Y
6-07
DU
P1
EP
A 3
540C
8082
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
196
SU
R10
096
40-1
41
2021
2-Y
6-07
DU
P1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
016
110
0.65
ND
ND
ND
B.1
9
Tab
le B
-2.
2003
Tis
sue
Che
mis
try
Sam
ple
Sam
ple
Typ
eE
xtra
ctio
n M
etho
dM
etho
dB
asis
Uni
tsC
ompo
nent
Dilu
tion
Fac
tor
Rep
ortin
gL
imit
Det
ecti
onL
imit
Res
ult
Res
ult N
otes
Spik
eC
once
ntra
tio
nP
erce
ntR
ecov
ery
Acc
epta
nce
Lim
itsA
vera
geR
PD
2021
2-Y
6-07
DU
P1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
221
120
0.65
ND
ND
ND
2021
2-Y
6-07
DU
P1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
232
110
0.65
ND
ND
ND
2021
2-Y
6-07
DU
P1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
242
110
0.65
ND
ND
ND
2021
2-Y
6-07
DU
P1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
248
110
0.65
ND
ND
ND
2021
2-Y
6-07
DU
P1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
254
110
0.65
130
=, P
110
39
2021
2-Y
6-07
DU
P1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
260
110
0.65
ND
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
540C
8082
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
188
SU
R10
088
40-1
41
Met
hod
Bla
nkM
B1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
016
110
0.65
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
221
120
0.65
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
232
110
0.65
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
242
110
0.65
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
248
110
0.65
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
254
110
0.65
ND
ND
Met
hod
Bla
nkM
B1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
260
110
0.65
ND
ND
2021
2-Y
6-04
MS1
EP
A 3
540C
8082
Wet
PER
CE
NT
Dec
achl
orob
iphe
nyl
199
SU
R10
099
40-1
41
2021
2-Y
6-04
MS1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
016
110
0.65
208
=20
010
470
-130
2021
2-Y
6-04
MS1
EP
A 3
540C
8082
Wet
ug/K
gA
rocl
or 1
260
110
0.65
230
=20
011
570
-130
2021
2-Y
6-04
DM
S1E
PA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
95S
UR
100
9540
-141
2021
2-Y
6-04
DM
S1E
PA
354
0C80
82W
etug
/Kg
Aro
clor
101
61
100.
6518
2=
200
9170
-130
13
2021
2-Y
6-04
DM
S1E
PA
354
0C80
82W
etug
/Kg
Aro
clor
126
01
100.
6521
5=
200
108
70-1
307
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
82W
etPE
RC
EN
TD
ecac
hlor
obip
heny
l1
99S
UR
100
9940
-141
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
82W
etug
/Kg
Aro
clor
101
61
100.
6518
8=
200
9457
-134
Lab
Con
trol
Sam
ple
LC
S1E
PA
354
0C80
82W
etug
/Kg
Aro
clor
126
01
100.
6518
9=
200
9564
-136
B.2
0
Appendix C
Phase II Source Investigation Soil and Sediment Chemistry
Tab
le C
-1.
Chl
orin
ated
Pes
tici
des
and
PC
Bs
in E
mba
nkm
ent
Soils
, Pha
se I
I So
urce
Inv
esti
gati
on
T(-
35)
Old
Sca
leT
(-3
5) O
ld S
cale
T(-
29)
36ft
N o
f 8"
pip
eT
(-29
) 36
ft N
of
8" p
ipe
T(-
12.5
) B
ank
T(-
12.5
) B
ank
Ana
lyte
0-0.
3 ft
0.5-
1 ft
0-0
.5 f
t0.
5-1
ft0-
0.2
ft0.
5-1
ft
0-D
ield
rin
95U
1100
U59
0032
0018
00U
46U
2,4´
-DD
E95
U11
00U
1000
U21
00U
1800
U46
U2,
4´-D
DT
160
1100
U55
0019
00C
1, J
1900
46U
2,4'
-DD
D18
021
0027
0093
0018
00U
46U
4,4'
-DD
D68
077
0086
0045
000
Q7,
J22
0046
U4,
4'-D
DE
170
1800
5300
3800
1800
U46
U4,
4'-D
DT
430
2500
4600
0Q
7, J
1500
088
0046
U
Ald
rin
49U
570
U48
0015
0094
0U
24U
alph
a-B
HC
49U
570
U52
0U
1100
U94
0U
24U
alph
a-C
hlor
dane
49U
570
U52
0U
1100
U94
0U
24U
beta
-BH
C49
U57
0U
520
U11
00U
940
U24
Ude
lta-B
HC
49U
570
U52
0U
1100
U94
0U
24U
End
osul
fan
I49
U57
0U
520
U11
00U
940
U24
UE
ndos
ulfa
n II
95U
1100
U55
0C
1, G
1, N
, J21
00U
1800
U46
UE
ndos
ulfa
n su
lfat
e95
U11
00U
1000
U21
00U
1800
U46
UE
ndri
n95
U11
00U
5900
1300
C1,
J18
00U
46U
End
rin
alde
hyde
95U
1100
U10
00U
2100
U18
00U
46U
End
rin
keto
ne95
U11
00U
2300
N, G
121
00U
1800
U46
Uga
mm
a-B
HC
(L
inda
ne)
49U
570
U52
0U
1100
U94
0U
24U
gam
ma-
Chl
orda
ne49
U57
0U
520
U70
0C
1, J
940
U24
UH
epta
chlo
r49
U57
0U
520
U11
00U
940
U24
UH
epta
chlo
r ep
oxid
e49
U57
0U
520
U11
00U
940
U24
UM
etho
xych
lor
490
U57
00U
5200
U11
000
U94
00U
240
UT
oxap
hene
4900
U57
000
U52
000
U11
0000
U94
000
U24
00U
Aro
clor
101
695
0U
1100
0U
1000
0U
2100
0U
1800
0U
460
UA
rocl
or 1
221
1900
U22
000
U20
000
U43
000
U36
000
U93
0U
Aro
clor
123
295
0U
1100
0U
1000
0U
2100
0U
1800
0U
460
UA
rocl
or 1
242
950
U11
000
U10
000
U21
000
U18
000
U46
0U
Aro
clor
124
895
0U
1100
0U
1000
0U
2100
0U
1800
0U
460
UA
rocl
or 1
254
300
1100
0U
1000
0U
2100
0U
1800
0U
460
UA
rocl
or 1
260
950
U11
000
U10
000
U21
000
U18
000
U46
0U
Surr
ogat
e R
ecov
ery
2,4,
5,6-
Tet
rach
loro
-m-x
ylen
e70
%80
%
82%
85%
73 %
75
%2,
2',3
,3',4
,4',5
,5',6
,6'-D
ecac
hlor
obip
heny
l86
%12
5 %
11
5%10
0%88
%
70%
Con
cent
rati
on µ
g/kg
dry
C.1
Tab
le C
-1.
Chl
orin
ated
Pes
tici
des
and
PC
Bs
in E
mba
nkm
ent
Soils
, Pha
se I
I So
urce
Inv
esti
gati
on
Ana
lyte
0-D
ield
rin
2,4´
-DD
E2,
4´-D
DT
2,4'
-DD
D4,
4'-D
DD
4,4'
-DD
E4,
4'-D
DT
Ald
rin
alph
a-B
HC
alph
a-C
hlor
dane
beta
-BH
Cde
lta-B
HC
End
osul
fan
IE
ndos
ulfa
n II
End
osul
fan
sulf
ate
End
rin
End
rin
alde
hyde
End
rin
keto
nega
mm
a-B
HC
(L
inda
ne)
gam
ma-
Chl
orda
neH
epta
chlo
rH
epta
chlo
r ep
oxid
eM
etho
xych
lor
Tox
aphe
ne
Aro
clor
101
6A
rocl
or 1
221
Aro
clor
123
2A
rocl
or 1
242
Aro
clor
124
8A
rocl
or 1
254
Aro
clor
126
0
Surr
ogat
e R
ecov
ery
2,4,
5,6-
Tet
rach
loro
-m-x
ylen
e2,
2',3
,3',4
,4',5
,5',6
,6'-D
ecac
hlor
obip
heny
l
T(-
11.5
) Se
ep 1
-ft
NT
(-11
.5)S
eep
1-ft
NT
(-11
.5)
Seep
1-f
t N
T(-
4.5)
Ban
kT
(-4.
5) B
ank
NA
(P
ipe
Sed)
0-0.
2ft
0.5-
1ft
0-0.
2ft
0.5-
1ft
2200
0Q
7, J
430
U49
U41
0U
45U
5100
G1,
N, J
, Q7
430
U49
U41
0U
45U
1200
00Q
7, J
780
49U
340
C1,
J45
U37
0000
Q7,
J43
0U
49U
330
C1,
J45
U15
0000
0Q
7, J
430
U49
U83
045
U39
000
Q7,
J43
0U
49U
410
45U
1600
000
Q7,
J34
0028
C1,
J19
0045
U
1600
U22
0U
25U
210
U23
U16
00U
220
U25
U21
0U
23U
1700
Q7,
J22
0U
25U
210
U23
U16
00U
220
U25
U21
0U
23U
1600
U22
0U
25U
210
U23
U16
00U
220
U25
U21
0U
23U
3200
U43
0U
49U
410
U45
U32
00U
430
U49
U41
0U
45U
3000
C1,
G1,
N, Q
7,
430
U49
U41
0U
45U
3200
U43
0U
49U
410
U45
U32
00U
430
U49
U41
0U
45U
1600
U22
0U
25U
210
U23
U31
00G
1, N
, Q7,
J22
0U
25U
210
U23
U16
00U
220
U25
U21
0U
23U
1600
U22
0U
25U
210
U23
U16
000
U22
00U
250
U21
00U
230
U16
0000
U22
000
U25
00U
2100
0U
2300
U
3200
0U
4300
U49
0U
4100
U45
0U
6400
0U
8600
U97
0U
8200
U90
0U
3200
0U
4300
U49
0U
4100
U45
0U
3200
0U
4300
U49
0U
4100
U45
0U
3200
0U
4300
U49
0U
4100
U45
0U
3200
0U
4300
U49
0U
4100
U45
0U
3200
0U
4300
U49
0U
4100
U45
0U
105
%
74 %
73
%
77 %
13
5 %
15
9 %
89
%
69 %
10
0 %
13
6 %
Con
cent
rati
on µ
g/kg
dry
C.2
Tab
le C
-1.
Chl
orin
ated
Pes
tici
des
and
PC
Bs
in E
mba
nkm
ent
Soils
, Pha
se I
I So
urce
Inv
esti
gati
on
Ana
lyte
0-D
ield
rin
2,4´
-DD
E2,
4´-D
DT
2,4'
-DD
D4,
4'-D
DD
4,4'
-DD
E4,
4'-D
DT
Ald
rin
alph
a-B
HC
alph
a-C
hlor
dane
beta
-BH
Cde
lta-B
HC
End
osul
fan
IE
ndos
ulfa
n II
End
osul
fan
sulf
ate
End
rin
End
rin
alde
hyde
End
rin
keto
nega
mm
a-B
HC
(L
inda
ne)
gam
ma-
Chl
orda
neH
epta
chlo
rH
epta
chlo
r ep
oxid
eM
etho
xych
lor
Tox
aphe
ne
Aro
clor
101
6A
rocl
or 1
221
Aro
clor
123
2A
rocl
or 1
242
Aro
clor
124
8A
rocl
or 1
254
Aro
clor
126
0
Surr
ogat
e R
ecov
ery
2,4,
5,6-
Tet
rach
loro
-m-x
ylen
e2,
2',3
,3',4
,4',5
,5',6
,6'-D
ecac
hlor
obip
heny
l
T(+
2.25
) B
ank
T(+
2.25
) B
ank
0-0.
2 ft
0.5-
1ft
530
Q7,
J, U
4600
C1,
J53
0Q
7, J
, U51
00U
520
C1,
Q7,
J11
000
530
Q7,
J, U
5100
U53
0Q
7, J
, U42
00C
1, J
530
Q7,
J, U
5100
U30
00Q
7, J
1200
00
270
Q7,
J, U
2600
U27
0Q
7, J
, U26
00U
270
Q7,
J, U
2600
U27
0Q
7, J
, U26
00U
270
Q7,
J, U
2600
U27
0Q
7, J
, U26
00U
530
Q7,
J, U
5100
U53
0Q
7, J
, U51
00U
530
Q7,
J, U
5100
U53
0Q
7, J
, U51
00U
530
Q7,
J, U
5100
U27
0Q
7, J
, U26
00U
270
Q7,
J, U
2600
U27
0Q
7, J
, U26
00U
270
Q7,
J, U
2600
U27
00Q
7, J
, U26
000
U27
000
Q7,
J, U
2600
00U
5300
Q7,
J, U
5100
0U
1100
0Q
7, J
, U10
0000
U53
00Q
7, J
, U51
000
U53
00Q
7, J
, U51
000
U53
00Q
7, J
, U51
000
U53
00Q
7, J
, U51
000
U53
00Q
7, J
, U51
000
U
49 %
80
%
82 %
11
0 %
C.3
Tab
le C
-2.
Chl
orin
ated
Pes
tici
des
and
PC
Bs
in D
iver
-Col
lect
ed C
ores
, Pha
se I
I So
urce
Inv
esti
gati
on
H03
-1-N
H03
-1-N
EH
03-1
-NW
H03
-1-S
H03
-1-S
EA
naly
te0-
1.0
ft0-
0.4
ft0-
0.75
ft
0-1.
7 ft
0-0.
6 ft
0-0.
5 ft
0-D
ield
rin
1300
0Q
7, J
230
U10
00U
1600
U23
00U
2700
U2,
4´-D
DE
5500
U23
0U
1000
U16
00U
2300
U27
00U
2,4´
-DD
T11
0000
J, Q
723
0U
4200
1500
C1,
J52
0036
002,
4'-D
DD
2000
0J,
Q7
230
U12
0017
0043
0024
00C
1, J
4,4'
-DD
D54
000
J, Q
723
0U
3600
4500
8700
5600
4,4'
-DD
E65
00Q
7, J
230
U10
00U
1600
U14
00C
1, J
2700
U4,
4'-D
DT
9700
00Q
7, J
920
3400
021
000
3400
040
000
Ald
rin
2800
U12
0U
540
U80
0U
1200
U14
00U
alph
a-B
HC
2800
U12
0U
540
U80
0U
1200
U14
00U
alph
a-C
hlor
dane
2800
U12
0U
540
U80
0U
1200
U14
00U
beta
-BH
C28
00U
120
U54
0U
800
U12
00U
1400
Ude
lta-B
HC
2800
U12
0U
540
U80
0U
1200
U14
00U
End
osul
fan
I28
00U
120
U54
0U
800
U12
00U
1400
UE
ndos
ulfa
n II
5500
U23
0U
1000
U16
00U
2300
U27
00U
End
osul
fan
sulf
ate
5500
U23
0U
1000
U16
00U
2300
U27
00U
End
rin
5500
U23
0U
1000
U16
00U
2300
U27
00U
End
rin
alde
hyde
5500
U23
0U
1000
U16
00U
2300
U27
00U
End
rin
keto
ne55
00U
230
U10
00U
1600
U23
00U
2700
Uga
mm
a-B
HC
(L
inda
ne)
2800
U12
0U
540
U80
0U
1200
U14
00U
gam
ma-
Chl
orda
ne28
00U
120
U54
0U
800
U12
00U
1400
UH
epta
chlo
r28
00U
120
U54
0U
800
U12
00U
1400
UH
epta
chlo
r ep
oxid
e28
00U
120
U54
0U
800
U12
00U
1400
UM
etho
xych
lor
2800
0U
1200
U54
00U
8000
U12
000
U14
000
UT
oxap
hene
2800
00U
1200
0U
5400
0U
8000
0U
1200
00U
1400
00U
Aro
clor
101
655
000
U23
00U
1000
0U
1600
0U
2300
0U
2700
0U
Aro
clor
122
111
0000
U46
00U
2100
0U
3100
0U
4600
0U
5400
0U
Aro
clor
123
255
000
U23
00U
1000
0U
1600
0U
2300
0U
2700
0U
Aro
clor
124
255
000
U23
00U
1000
0U
1600
0U
2300
0U
2700
0U
Aro
clor
124
855
000
U23
00U
1000
0U
1600
0U
2300
0U
2700
0U
Aro
clor
125
455
000
U23
00U
1000
0U
1600
0U
2300
0U
2700
0U
Aro
clor
126
055
000
U23
00U
1000
0U
1600
0U
2300
0U
2700
0U
Surr
ogat
e R
ecov
ery
2,4,
5,6-
Tet
rach
loro
-m-x
ylen
e97
%
70 %
77
%
78 %
80
%
65 %
2,
2',3
,3',4
,4',5
,5',6
,6'-D
ecac
hlor
obip
heny
l15
7 %
90
%
124
%
86 %
11
0 %
85
%
H03
-1-C
Con
cent
rati
onµ
g/kg
dry
C.4
Tab
le C
-2.
Chl
orin
ated
Pes
tici
des
and
PC
Bs
in D
iver
-Col
lect
ed C
ores
, Pha
se I
I So
urce
Inv
esti
gati
on
Ana
lyte
0-D
ield
rin
2,4´
-DD
E2,
4´-D
DT
2,4'
-DD
D4,
4'-D
DD
4,4'
-DD
E4,
4'-D
DT
Ald
rin
alph
a-B
HC
alph
a-C
hlor
dane
beta
-BH
Cde
lta-B
HC
End
osul
fan
IE
ndos
ulfa
n II
End
osul
fan
sulf
ate
End
rin
End
rin
alde
hyde
End
rin
keto
nega
mm
a-B
HC
(L
inda
ne)
gam
ma-
Chl
orda
neH
epta
chlo
rH
epta
chlo
r ep
oxid
eM
etho
xych
lor
Tox
aphe
ne
Aro
clor
101
6A
rocl
or 1
221
Aro
clor
123
2A
rocl
or 1
242
Aro
clor
124
8A
rocl
or 1
254
Aro
clor
126
0
Surr
ogat
e R
ecov
ery
2,4,
5,6-
Tet
rach
loro
-m-x
ylen
e2,
2',3
,3',4
,4',5
,5',6
,6'-D
ecac
hlor
obip
heny
l
H03
-1-S
WH
03-1
-WH
03-2
-NH
03-2
-NE
H03
-2-S
H03
-2-S
EH
03-2
-W0-
1.5
ft0-
1.5
ft0-
0.9
ft0-
0.25
ft
0-0.
4 ft
0-0.
75 f
t0-
1.5
ft
1700
U16
00U
2700
U24
00U
1400
U13
00U
3500
U17
00U
1600
U27
00U
2400
U14
00U
1300
U35
00U
2300
1700
038
00J,
Q7
1000
013
00C
1, J
2400
3600
015
00C
1, J
2800
2700
U25
0014
0021
0028
00C
1, J
4000
9100
1400
C1,
Q7,
J31
0024
0039
0057
0017
00U
1100
C1,
J27
00U
2400
U14
00U
1300
U35
00U
1900
016
0000
Q7,
J22
000
Q7,
J10
000
1700
018
000
1500
00
870
U82
0U
1400
U12
00U
700
U66
0U
1800
U87
0U
820
U14
00U
6900
0Q
7, J
700
U66
0U
1800
U87
0U
820
U14
00U
1200
U70
0U
660
U18
00U
870
U82
0U
1400
U32
0070
0U
660
U18
00U
870
U82
0U
1400
U12
00U
700
U66
0U
1800
U87
0U
820
U14
00U
1200
U70
0U
660
U18
00U
, C1
1700
U16
00U
2700
U24
00U
1400
U13
00U
3500
U17
00U
1600
U27
00U
2400
U14
00U
1300
U35
00U
1700
U16
00U
2700
U24
00U
1400
U13
00U
3500
U17
00U
1600
U27
00U
2400
U14
00U
1300
U35
00U
1700
U16
00U
2700
U24
00U
1400
U13
00U
3500
U87
0U
820
U14
00U
1200
U70
0U
660
U18
00U
870
U82
0U
1400
U12
00U
700
U66
0U
1800
U87
0U
820
U14
00U
1200
U70
0U
660
U18
00U
870
U82
0U
1400
U12
00U
700
U66
0U
8900
U87
00U
8200
U14
000
U12
000
U70
00U
6600
U18
000
U87
000
U82
000
U14
0000
U12
0000
U70
000
U66
000
U18
0000
U
1700
0U
1600
0U
2700
0U
2400
0U
1400
0U
1300
0U
3500
0U
3400
0U
3200
0U
5400
0U
4700
0U
2700
0U
2600
0U
6900
0U
1700
0U
1600
0U
2700
0U
2400
0U
1400
0U
1300
0U
3500
0U
1700
0U
1600
0U
2700
0U
2400
0U
1400
0U
1300
0U
3500
0U
1700
0U
1600
0U
2700
0U
2400
0U
1400
0U
1300
0U
3500
0U
1700
0U
1600
0U
2700
0U
2400
0U
1400
0U
1300
0U
3500
0U
1700
0U
1600
0U
2700
0U
2400
0U
1400
0U
1300
0U
3500
0U
67 %
77
%
75 %
80
%
70 %
72
%
75 %
98 %
10
8 %
17
0 %
12
0 %
10
3 %
11
2 %
10
0 %
Con
cent
rati
onµ
g/kg
dry
C.5
Tab
le C
-2.
Chl
orin
ated
Pes
tici
des
and
PC
Bs
in D
iver
-Col
lect
ed C
ores
, Pha
se I
I So
urce
Inv
esti
gati
on
Ana
lyte
0-D
ield
rin
2,4´
-DD
E2,
4´-D
DT
2,4'
-DD
D4,
4'-D
DD
4,4'
-DD
E4,
4'-D
DT
Ald
rin
alph
a-B
HC
alph
a-C
hlor
dane
beta
-BH
Cde
lta-B
HC
End
osul
fan
IE
ndos
ulfa
n II
End
osul
fan
sulf
ate
End
rin
End
rin
alde
hyde
End
rin
keto
nega
mm
a-B
HC
(L
inda
ne)
gam
ma-
Chl
orda
neH
epta
chlo
rH
epta
chlo
r ep
oxid
eM
etho
xych
lor
Tox
aphe
ne
Aro
clor
101
6A
rocl
or 1
221
Aro
clor
123
2A
rocl
or 1
242
Aro
clor
124
8A
rocl
or 1
254
Aro
clor
126
0
Surr
ogat
e R
ecov
ery
2,4,
5,6-
Tet
rach
loro
-m-x
ylen
e2,
2',3
,3',4
,4',5
,5',6
,6'-D
ecac
hlor
obip
heny
l
H03
-T(+
1.5)
-EH
03-T
(+2.
5)-E
H03
-T(+
3.5)
-EH
03-T
(+4.
5)-E
0-1.
0 ft
0-0.
7 ft
0-0.
5 ft
0-0.
9 ft
1300
U11
00U
130
U53
U13
00U
1100
U13
0U
53U
1000
C1,
J67
0C
1, J
68C
1, J
100
1300
U11
00U
82C
1, J
49C
1, J
1300
U11
00U
120
C1,
J12
013
00U
1100
U13
0U
51C
1, J
5500
5200
930
530
670
U58
0U
66U
27U
670
U58
0U
66U
27U
670
U58
0U
66U
27U
670
U58
0U
66U
27U
670
U58
0U
66U
27U
670
U58
0U
66U
27U
1300
U11
00U
130
U53
U13
00U
1100
U13
0U
53U
1300
U11
00U
130
U53
U13
00U
1100
U13
0U
53U
1300
U11
00U
130
U53
U67
0U
580
U66
U27
U67
0U
580
U66
U27
U67
0U
580
U66
U27
U67
0U
580
U66
U27
U67
00U
5800
U66
0U
270
U67
000
U58
000
U66
00U
2700
U
1300
0U
1100
0U
1300
U53
0U
2600
0U
2300
0U
2500
U11
00U
1300
0U
1100
0U
1300
U53
0U
1300
0U
1100
0U
1300
U53
0U
1300
0U
1100
0U
1300
U53
0U
1300
0U
1100
0U
1300
U53
0U
1300
0U
1100
0U
1300
U53
0U
50 %
67
%
64 %
64
%
65 %
90
%
78 %
65
%
Con
cent
rati
onµ
g/kg
dry
C.6
Tab
le C
-3.
Chl
orin
ated
Pes
tici
des
and
PC
Bs
in V
ibra
core
s, P
hase
II
Sour
ce I
nves
tiga
tion
Ana
lyte
0-D
ield
rin
2300
C1,
J15
0U
1400
U26
0J,
Q7,
U13
00U
750
J, Q
7, U
2,4´
-DD
E37
00U
150
U14
00U
260
J, Q
7, U
2000
U75
0J,
Q7,
U2,
4´-D
DT
3200
C1,
J12
0C
1, J
1400
U19
0J,
C1,
Q7
1300
U70
0J,
Q7,
C1
2,4'
-DD
D16
000
190
3500
650
J, Q
723
0016
00J,
Q7
4,4'
-DD
D66
000
890
8800
3100
J, Q
712
000
B1,
J67
00J,
Q7
4,4'
-DD
E22
00C
1, J
150
U14
00U
160
J, C
1, Q
786
0C
1, J
750
J, Q
7, U
4,4'
-DD
T69
000
1300
1400
030
00J,
Q7
1200
0J,
B1
7000
J, Q
7
Ald
rin
1900
U75
U70
0U
140
J, Q
7, U
680
U38
0J,
Q7,
Ual
pha-
BH
C19
00U
75U
700
U14
0J,
Q7,
U68
0U
380
J, Q
7, U
alph
a-C
hlor
dane
1900
U75
U70
0U
140
J, Q
7, U
680
U38
0J,
Q7,
Ube
ta-B
HC
1900
U75
U70
0U
140
J, Q
7, U
680
U38
0J,
Q7,
Ude
lta-B
HC
1900
U75
U70
0U
140
J, Q
7, U
680
U38
0J,
Q7,
UE
ndos
ulfa
n I
1900
U75
U70
0U
140
J, Q
7, U
680
U38
0J,
Q7,
UE
ndos
ulfa
n II
3700
U15
0U
1400
U26
0J,
Q7,
U13
00U
750
J, Q
7, U
End
osul
fan
sulf
ate
3700
U15
0U
1400
U26
0J,
Q7,
U13
00U
750
J, Q
7, U
End
rin
3700
U15
0U
1400
U26
0J,
Q7,
U13
00U
750
J, Q
7, U
End
rin
alde
hyde
3700
U15
0U
1400
U26
0J,
Q7,
U13
00U
750
J, Q
7, U
End
rin
keto
ne37
00U
150
U14
00U
260
J, Q
7, U
1300
U75
0J,
Q7,
Uga
mm
a-B
HC
(L
inda
ne)
1900
U75
U70
0U
140
J, Q
7, U
680
U38
0J,
Q7,
Uga
mm
a-C
hlor
dane
1900
U75
U70
0U
140
J, Q
7, U
680
U38
0J,
Q7,
UH
epta
chlo
r19
00U
75U
700
U14
0J,
Q7,
U68
0U
380
J, Q
7, U
Hep
tach
lor
epox
ide
1900
U75
U70
0U
140
J, Q
7, U
680
U38
0J,
Q7,
UM
etho
xych
lor
1900
0U
750
U70
00U
1400
J, Q
7, U
6800
U38
00J,
Q7,
UT
oxap
hene
1900
00U
7500
U70
000
U14
000
J, Q
7, U
6800
0U
3800
0J,
Q7,
U
Aro
clor
101
637
000
U15
00U
1400
0U
2600
J, Q
7, U
1300
0U
7500
J, Q
7, U
Aro
clor
122
173
000
U29
00U
2700
0U
5200
J, Q
7, U
2600
0U
1500
0J,
Q7,
UA
rocl
or 1
232
3700
0U
1500
U14
000
U26
00J,
Q7,
U13
000
U75
00J,
Q7,
UA
rocl
or 1
242
3700
0U
1500
U14
000
U26
00J,
Q7,
U13
000
U75
00J,
Q7,
UA
rocl
or 1
248
3700
0U
1500
U14
000
U26
00J,
Q7,
U13
000
U75
00J,
Q7,
UA
rocl
or 1
254
3700
0U
1500
U14
000
U26
00J,
Q7,
U13
000
U75
00J,
Q7,
UA
rocl
or 1
260
3700
0U
1500
U14
000
U26
00J,
Q7,
U13
000
U75
00J,
Q7,
U
Surr
ogat
e R
ecov
ery
2,4,
5,6-
Tet
rach
loro
-m-x
ylen
e80
%
50 %
68
%
48 %
63
%
44 %
2,
2',3
,3',4
,4',5
,5',6
,6'-D
ecac
hlor
obip
heny
l80
%
65 %
10
5 %
62
%
80 %
57
%
0-1.
0 ft
Con
cent
rati
onµ
g/kg
dry
1.9-
3.1
ft0-
1.5
ft0-
1.3
0-0.
3 ft
0-2.
8 ft
H03
-04
H03
-03
H03
-02
H03
-04
H03
-05
H03
-01
C.7
Tab
le C
-3.
Chl
orin
ated
Pes
tici
des
and
PC
Bs
in V
ibra
core
s, P
hase
II
Sour
ce I
nves
tiga
tion
Ana
lyte
0-D
ield
rin
2,4´
-DD
E2,
4´-D
DT
2,4'
-DD
D4,
4'-D
DD
4,4'
-DD
E4,
4'-D
DT
Ald
rin
alph
a-B
HC
alph
a-C
hlor
dane
beta
-BH
Cde
lta-B
HC
End
osul
fan
IE
ndos
ulfa
n II
End
osul
fan
sulf
ate
End
rin
End
rin
alde
hyde
End
rin
keto
nega
mm
a-B
HC
(L
inda
ne)
gam
ma-
Chl
orda
neH
epta
chlo
rH
epta
chlo
r ep
oxid
eM
etho
xych
lor
Tox
aphe
ne
Aro
clor
101
6A
rocl
or 1
221
Aro
clor
123
2A
rocl
or 1
242
Aro
clor
124
8A
rocl
or 1
254
Aro
clor
126
0
Surr
ogat
e R
ecov
ery
2,4,
5,6-
Tet
rach
loro
-m-x
ylen
e2,
2',3
,3',4
,4',5
,5',6
,6'-D
ecac
hlor
obip
heny
l
27U
2900
U11
0U
410
U21
U85
U15
C1,
J44
00U
110
U41
0U
21U
85U
27U
2900
U11
0U
410
U21
U85
U27
U36
0014
014
0013
C1,
J25
052
2000
0J,
B1
600
6300
5811
0027
U29
00U
110
U30
0J
21U
8725
C1,
J30
000
140
4500
14C
1, J
680
14U
1500
U57
U21
0U
11U
44U
14U
1500
U57
U21
0U
11U
44U
14U
1500
U57
U21
0U
11U
44U
14U
1500
U57
U21
0U
11U
44U
14U
1500
U57
U21
0U
11U
44U
14U
1500
U57
U21
0U
11U
44U
27U
2900
U11
0U
410
U21
U85
U27
U29
00U
110
U41
0U
21U
85U
27U
2900
U11
0U
410
U21
U85
U27
U29
00U
110
U41
0U
21U
85U
27U
2900
U11
0U
410
U21
U85
U14
U15
00U
57U
210
U11
U44
U14
U15
00U
57U
210
U11
U44
U14
U15
00U
57U
210
U11
U44
U14
U15
00U
57U
210
U11
U44
U14
0U
1500
0U
570
U21
00U
110
U44
0U
1400
U15
0000
U57
00U
2100
0U
1100
U44
00U
270
U29
000
U11
00U
4100
U21
0U
850
U54
0U
5800
0U
2200
U81
00U
420
U17
00U
270
U29
000
U11
00U
4100
U21
0U
850
U27
0U
2900
0U
1100
U41
00U
210
U85
0U
270
U29
000
U11
00U
4100
U21
0U
850
U27
0U
2900
0U
1100
U41
00U
210
U85
0U
270
U29
000
U11
00U
4100
U21
0U
850
U
52 %
65
%
60 %
58
%
50 %
52
%
53 %
95
%
67 %
75
%
54 %
66
%
Con
cent
rati
onµ
g/kg
dry
0-0.
7 ft
0-1.
3 ft
0-1.
4 ft
H03
-12
0-3.
8 ft
0-0.
7 ft
0-3.
4 ft
H03
-07
H03
-08
H03
-10
H03
-11
H03
-06
C.8
PNNL-14596
Distr.1
Distribution
No. of Copies
OFFSITE
7 C. White, SFD-8-1 U. S. Environmental Protection Agency Region IX 75 Hawthorne Street San Francisco, CA 94105
A. Lincoff U. S. Environmental Protection Agency Region IX Laboratory 1337 S. 46th Street, Building 201 Richmond, CA 94804
No. of Copies
ONSITE
N. P. Kohn (5) SEQUI N. R. Evans SEQUI Information Release Office K1-06