xxi oun 2013
DESCRIPTION
xxioun2013TRANSCRIPT
-
ISSN 0356-5526 2013 5, 75
CCG EAC 65 June 2013ISSUE 5 VOL. 75
1 1936
2013
CHEMICA CHRONICA General EditionAssociation of Greek Chemists
l l l l
-
> ... (2013-2015)
: : : : . : . : : :
...
(: . ) 27, 10682 , .: 210 3821524, 210 3829266Fax: 210 3833597, e-mail: [email protected] (: . ) 6, 54623 , . fax: 2310 278077,e-mail: [email protected] (: . )M 211 T N, 26222 ,.: 2610 362460, e-mail: [email protected] (: A. K)E 19, 71110 , T.. 1335,. fax: 2810 220292,e-mail: [email protected] (: . ) 2, 38221 , . fax: 24210 37421,e-mail: [email protected] - - (: . ) 3-206, 2 , - , 45-110, , .: 26510 08716e-mail: [email protected]. - - (: . ) 2, 35100 , e-mail: [email protected] (: . ) 7, 68 100, .. 259. fax: 25510 81002, 6977005626, e-mail: [email protected] (: . ) 1, 81100 , . fax: 22510 28183e-mail: [email protected] (: . ). 1, 85100 , . & fax: 22410 37522,e-mail: [email protected]
...., 27, 106 82 , .: 210 38 21 524 - 210 38 32 151 - Fax: 210 38 33 597 (: M. K)www.eex.gr - e-mail E.E.X.: [email protected] - e-mail X.X.: [email protected]
:
: O ... .
: O
A : X
: N. , E. M,
K. M, . B, N.
.. ... :
( ):
: 3
: - : 74
: 40 , : 15
: $120
- : Adjust Lane
35, 15132 .
.: 210 74 89 487 & 488, email: [email protected]
IHMO OPANO TH ENH HNN HMIKN
2013
1 E
2
3
4 To
. . - . .
E
8
9 . 18 ..23 -
-
// 2013
,
,
. ,
.
-
, -
. , ,
.
,
() . ...
.
, ,
,
.. . 13 10 15
-
>2> // 2013
. . . . . 1804/1988
27, 106 82 .: 38 21 524, 38 29 266,
Fax: 38 33 597 http://www.eex.gr E-mail: [email protected]
ASSOCIATION OF GREEK CHEMISTS 27 Kaningos Str, 106 82 Athens, Greece
Tel. ++30-1-38 21 524; ++30-1-38 29 266, Fax; ++38 33 597
http://www.eex.gr E-mail: [email protected]
14-6-2013
... ...
.
,
.
,
,
.
...
,
, 59 ,
, ,
,
.
,
, .
. . . . . 1804/1988
27, 106 82 .: 38 21 524, 38 29 266,
Fax: 38 33 597 http://www.eex.gr E-mail: [email protected]
ASSOCIATION OF GREEK CHEMISTS 27 Kaningos Str, 106 82 Athens, Greece
Tel. ++30-1-38 21 524; ++30-1-38 29 266, Fax; ++38 33 597
http://www.eex.gr E-mail: [email protected]
14-6-2013
... ...
.
,
.
,
,
.
...
,
, 59 ,
, ,
,
.
,
, .
- > // 2013
-
>4> // 2013
>
2006 . . , - , 210. - , , , 300 , 30 . -. , , . . 50 . . , , . , , 50 . ! - 2009 Barack Obama - , . (Food and Drug Administration ) - . , , , , .
210 - , . 1960 , - . , 1964, Vilma R. Hunt , at the Harvard School of public Health, - ( Pierre Marie Curie 1898) . , , . , . - . Hunt -, , . . Hunt dward P. Radford , - . , Harvard, - . 1965 John B. Little . . , .
. . , . - . . , -
- . . , , , , , .
- // 2013
-
>6> // 2013
- . , - , 2% - , . - .
, , . 1990 - , 46, , , - - . . - . Radford Hunt - 11 1964. - , - , . - , . Philip Morris 1970 1980 . -. , . 1977, Philip Morris - - 222 . - Philip Morris .
Philip Morris - .
- // 2013
-
>8> // 2013
>>
& - -, , 09.03.2013, . , . - 150 . , , . , - . .. ( ) ( ). : / -
59 .
.
/, - . , .
& : .
, ... , .
H , , , - - .
O , , - ...., -.
, , MSc Food Science, - , , - .
, MSc , , .
, , , - .
, - , , .
. /, -
- : : , 23 2013 . , - , . 130 , . T , . , . - - , . . , - : . , ,
.
.. . , , - .
. , Sweet & Balance ..
. , , , - .
:
. , Oenolysis, - .
. . , OLITECN OE, .
. . , Food Allergens Laboratories , .
, 2006, . , Greekpol Co 5 , . , - . - , , , - . .
-
// 2013 >
-
>10> // 2013
. , , , - ,
. -
- -, ,
-.
,
,
, , -
. ( ) - . , - , , , , . , - . -, galena . , , . , , , , , , .
, -, , . Kohl - - , . 16, 17 18 , . - , , - - . (HgCl2) , - . 17 18 , - , . 19 , - . -, , , - . 20 , 19 ( ) . - , 1930 (American Medical Association). 20 , (Cosmetic, Toiletry and Fragrance Association, CTFA) (Scientific Committee on Cosmetic and Non Food Products, SCCNFP) 2004 - (Scientific Committee on Consumer Products, SCCP), ... , , - .
, -
- // 2013
-
>12> // 2013
. , - . , -.
Aluminum ( - Aluminium Allantoinate, Aluminum Carbonate, Aluminium Chloride, luminum Chlorohydrate): , . , . - , / - . - , - - DNA, Alzheimers.
Tallow Animal Fat ( ): .
- , ,
, .
-
. , - -
- .
, -
.Cocamide (Cocamide MEA, Cocamide DEA, Cocamide TEA, DEA Cetyl phosphates, DEA Oleth-3 phosphates, Myristamide DEA, Stearamide MEA, Lauramide DEA, Linoleamide MEA, Oleamide DEA, TEA- Lauryl Sulfate): . O - (U.S. Food and Drug Administration, FDA) 1979. , (International Agency for Research on Cancer, IARC) .Diethanolamine (, DEA), Triethanolamine (-, TEA): - pH. , (Stearate) . , . .Coal Tar Colours ( ): , - (-) . - - (, , ..), - , , , , , , .Formaldehyde (): . - . , . , - (International Agency for Research on Cancer, IARC).Imidazolidinyl urea ( ): - parabens (). -. .Isopropyl Alcohol ( ): - , , -, , , - . () - , , , , , , .Parabens () (methyl, propyl, butyl and ethyl): -
- // 2013
-
>14> // 2013
. - - , , , . , .Sodium Lauryl Sulphate, SLS ( ) Sodium Laureth Sulphate, SLES ( ): - , - . - , . , , -. SLS SLES - . - .Stearalkonium Chloride ( ): , , . -, . - . , - (0.1 5%).Synthetic Perfumes / Fragrance ( ): - -. . , - - . , , . , , -, , , , , . (US Environmental Protection Agency) 100% , . , . -
, , .Benzophenone (): , , . , -, , - . , .
, -. , . - WWF - .
( ) .. ( 76/768/ . 1223/2009), REACH ( . 1907/2006) CLP ( . 1272/2008). -.. -.. - ... - - , - (Scientific Committee for Consumer Products, SCCP). - - European Cosmetic Toiletry and Perfumery Association (COLIPA), . , , 76/768/ , 27 1976. ( 2 93/35/). 76/768/
,
, ,
.
- // 2013
-
>16> // 2013
. -
-
.
-
. -, - - : : -
- .
-
, ,
, ,
, .
: , . / - . .
: - . .
: , . , , , . , .
: , - . , nano.
: -, -
, -:
-
, -
-
,
. -.
: , - - . , - (SCCS), . .
: - : ) , ) - ) .
30 2006 . 1907/2006 (REACH - Registration, Evaluation and Authorisation of Chemicals) , , - , . - - , . , . REACH 1 - 2007, 2018. REACH
- // 2013
-
>18> // 2013
1.
, 19 , 1865, , , . ,
, . , . 1938 W.G.Helis -
. , .
. , - , , . , - W.G. Helis, , , . 1960 , , - , . , - , , . , , B.P.EXPORATION LTD 3950, , . - , (24 ). .
-
.
,
, -
.
.., . , - /
- // 2013
-
>20> // 2013
. , . , .. - , .
3. , , - , . , , , . , , . , -, . , , . , . :. . 50150 -
, .. . , ,
, , .. K .
.V. . , .V. , . -
, .
4. , , . , - , . , , 1973, , , , , - . ,
. ,
, .
, ,
. :1) East 250 380 . .2) 80 . .3) .. , 320 . .
4) 120 . .5) , , 1 .
6) , , 150 . .7) 100 . 60 . .
1999, 172 , 12
- // 2013
-
>22> // 2013
. , : ) -
, ) , ) , ) , ) , )
Olimpi ) ., -
6 . - 1,7 . -, , , , TGSNOPEC, CGG VERITAS SPECTRUM GEOSERVICES, 2002 2009, . .
,
. - .
:1) ,
.2) , ,
, , .3) , , -
, , . , . - , , , . . - , 2020, , . , , - . . . . , - . . , Mobil Chevron . Chevron, 2011 , Mobil 2008 . , , ., , , , , . Center for European Policy Studies , . 175 . , 2011 , - Chevron, 3000 m3 1 m3. ., . ,, . (shale gas). , , , . n
- // 2013
-
>24> // 2013
10Pa 20oC. VOCs
13.3 Pa 25oC.2
3.
THMs (VOCs), -
( Disinfection By-Products- DBPs). Rook 1974
, , -
. THMs CHX3, X .
1. 1
UV
( )
4 mg/L 4 mg/L 0.8 mg/L - -
,
( )
2. 3,10
EU TTHMs (g/L) WHO (g/L) IARC category
s (g/L) EPA
CHCl3 300 Group 2B ,
CHCl2Br 80 100 60 Group 2B ,
CHClBr2 100 Group 3 ,
,
CHBr3 100 Group 3 ,
-
// 2013 > -
> .
-
,
. -
( IARC),
, -
, 3. THMs
EPA WHO, 2.
,
.
, ,
, , .
. > > -
> , .
, -
.
. ,
, 90%
. -
, , 2,3.
4.
(ECD) (MS).
ng/L g/L, ,
3. VOCs,
ng/L-g/L2,3. -
, , , ,
3. ,
.
1
-
>26> // 2013
,
, , headspace.
VOCs
2:
( : SPME , : Purge and Trap)
(Direct aqueous injection):
. -
. .
- ( Liquid-Liquid Extraction) : .
LLE, (5-100mL), s
0.5-2mL. LLE , -
. , .
( Headspace): Ms
. (Purge and Trap). ,
, ,
. , . ,
. headspace,
. , .
on-line , -
, .
, .
(HS-SPME): THMs
, , .
, , , -
THMs CF BF BDCM DBCM
7 1-40.8g/L 1.8-24.7g/L 3.1-55.3g/L 2-66.5g/L
8 44.9ng/L
12.8ng/L - 0-249ng/L 0-57ng/L
9 1900ng/L
11 34.58g/L 21.23g/L
, 12 6-32ng/L 147-762ng/L 16-97ng/L 92-39ng/L
202-771ng/L - 99-283ng/L 32-220ng/L
13 0.12-0.73g/L 0.01-0.24g/L 0.07-6.25g/L 0.59-0.64g/L
14 1.9-20.5g/L 0.4-2.7g/L 1.1-18.6g/L 0.4-14g/L
56.1-290.9g/L 0.3-3.1g/L 5.4-51.5g/L 0.8-24.6g/L
15 14.1-155.9g/L - 1.21-10.8g/L 0.21-3.34g/L
* ( ) 0.52-1.681g/L 0.38-8.4g/L 0.5-2.6g/L 0.5-6.34g/L
CF , BF , BDCM: , DBCM .
*H 2012
- // 2013
-
>28> // 2013
157 01
. 210 7274502Fax. 210 7274158
, 12/6/2013
. , . 4 . 20/9/2013. : 2107274502 . . http://dbmb.biol.uoa.gr/CBMD/
...
. . .
-
// 2013 // 2013
-
>30> // 2013