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  • Workshop Biorefineries 2010 Recent Advances and New Challenges

    Biorefineries: Factors for technology selection

    NOV/2010

  •  BRASKEM

     BIOREFINERIES: ACTORS, CONCEPTS AND SYNERGIES

     COMPETING TECHNOLOGIES

     FACTORS

     CONCLUSIONS

    Agenda

  •  BRASKEM

     BIOREFINERIES: ACTORS, CONCEPTS AND SYNERGIES

     COMPETING TECHNOLOGIES

     FACTORS

     CONCLUSIONS

    Agenda

  • EXTRACTION Raw Materials

    1st GENERATION Basic

    Petrochemicals

    2nd GENERATION Thermoplastic

    Resins

    3rd GENERATION Plastic Converters

    NAPHTHA CONDENSED

    GAS

    ADDED VALUE COMPETITIVENESS

    COMPETITIVE INTEGRATION

    Market Leadership

    Biggest Producer of Resin in the Americas

    Cost Competitiveness

    Integration with Scale

    Technological Autonomy

    Know-How

    Brazilian Petrochemical Industry

  • GROSS REVENUES

    EBITDA

    NET INCOME

    EXPORTS

    Economic and Financial Performance 2009*

    R$ 28.2 billion

    R$ 3.1 billion

    R$ 21.8 billion

    USD 2.5 billion

    Source: Braskem *Includes Quattor and Sunoco

  • Launching of US$ 144 MM in RANPV* for innovation projects

    More than US$ 330 million in assets

    220 researchers

    More than 260 patents deposited

    7 pilot plants

    Global technology agreement with BASELL

    12% of revenues from the sale of resins in 2009 was obtained from products launched in the past 3 years

    Innovation and Technology

    *Net Present Value Adjusted to Risk

  • BRASKEM - IDEOM: Sustainable Developments Solution

    Ser a líder mundial da química sustentável, inovando para melhor servir às pessoas.

    ECOEFICIENCE

    GREEN PE

    NEW SUSTAINABLE PLATFORM

  •  BRASKEM

     BIOREFINERIES: ACTORS, CONCEPTS AND SYNERGIES

     COMPETING TECHNOLOGIES

     FACTORS

     CONCLUSIONS

    Agenda

  • Renewables Chemicals: symbiosis with Biofuels

     Biorefineries are the main driver for

    renewable chemical products

     Biofues: US$ 50 billions (2012)

     Today: bioethanol e biodiesel

     Brazil has competitive position in this

    area (sugar cane)

     High and diversify investments around

    the world

  • Diversified actors

    Large Companies Small Business VC Funds

    Universities and R&D

    Centers

    ... and others...

    PS: Usually, with participation of large companies and funds

    CHEMISTRY

    AGROCOMPANIES

    ENERGY

    OTHERS

    http://cleantech.com/index.cfm http://www.krict.re.kr/english/index.php http://www.emerald-ventures.com/ http://www.ngenpartners.com/ http://www.mmtfund.com/ http://www.google.com.br/imgres?imgurl=http://www.hawaiibioenergy.com/Portals/0/images/logo_khosla.gif&imgrefurl=http://www.hawaiibioenergy.com/Partners/tabid/55/Default.aspx&usg=__2is9oaRyuE0CzyylKxi-eJqmvQE=&h=52&w=209&sz=6&hl=pt-BR&start=2&zoom=1&tbnid=Rn4DZF44MYkrqM:&tbnh=26&tbnw=106&prev=/images?q=Khosla+Ventures&um=1&hl=pt-BR&sa=N&tbs=isch:1&um=1&itbs=1

  • Biorefinery Concept

    “A processing and conversion facility that (1) efficiently

    separates its biomass raw material into individual components

    and (2) converts these components into marketplace

    products, including biofuels, biopower, and conventional and

    new bioproducts.” The Biomass Research and Development, Technical Advisory Committee (2002), U.S. Departments of Energy and

    Agriculture

    very open, not clear enough ...

    Diferent visions (regions / available feedstocks)...

    Diferent approaches (Biochemical / Thermochemical /

    Hybrid)...

  • ENZIMATIC HID.

    ACID HID./ OTHERS

    FERMENTATION

    GENETICS

    PIROLYSIS

    TORREFACTION

    Milling / ↑ density - Pellet - briquetting

    Drying

    PRE TREATMENT CONVERSION PRODUCTS

    ENERGY

    BIO-OIL

    ALCOHOLS

    FATTY ACIDS

    BIFUNCTIONALS HCs – gas, diesel, naphtha, etc

    ESTERS

    H2 OTHERS

    BIOPOLYMERS

    FCC ETHYLENE

    PROPYLENE

    AROMATICs

    BUTENES

    HCs – gas, diesel, naphtha, etc

    REN. RAW MATERIALS -Sugar cane - elephant grass -Corn - algies -Residues …

    GASEIFICATION

    CHEMICAL PROCESSES

    Biorefinery: Technology Production Chain Complexity

    GENETICS

    FERMENTATION

    BIOMASS

    CHEMICAL PROCESSES

    http://www.google.com.br/imgres?imgurl=http://www.gartic.com.br/imgs/mural/tc/tchon/1228385949.png&imgrefurl=http://www.gartic.com.br/Tchon/gallery/140750&usg=___mTk-cryDLldpb4TqgJtVNnHaTU=&h=304&w=321&sz=36&hl=pt-BR&start=1&sig2=65xNgnlrV_Hh4fx3TA8Odw&zoom=1&tbnid=Z4j2A7N0k5awaM:&tbnh=112&tbnw=118&ei=6g2ZTJKMMMP_lgfHtPXqDw&prev=/images?q=cana+de+a%C3%A7ucar+desenho&um=1&hl=pt-BR&tbs=isch:1&um=1&itbs=1 http://www.google.com.br/imgres?imgurl=http://colorirdesenhos.com/files/desenhos/fabrica.gif&imgrefurl=http://colorirdesenhos.com/desenhos/190-fabrica&usg=__sYaeI9zqUBcbaXw0uz0TeG_D4Fs=&h=601&w=643&sz=14&hl=pt-BR&start=1&sig2=RjMD7UEXmsWfAotX-IpJ2A&zoom=1&tbnid=B7RGaE3n25bWrM:&tbnh=128&tbnw=137&ei=oA2ZTMbGOoH6lwfrkJnWDw&prev=/images?q=f%C3%A1brica&um=1&hl=pt-BR&tbs=isch:1&um=1&itbs=1 http://www.google.com.br/imgres?imgurl=http://3.bp.blogspot.com/_y8jJJQ2orpY/SjgPDJB8r5I/AAAAAAAAAMQ/tyi9gYlpsWY/s400/quimica.jpg&imgrefurl=http://superinteressante-pt.blogspot.com/2009/06/exame-de-fisica-e-quimica.html&usg=__QVGc9ZZBoA4Oo_h56jMWLgEOxK0=&h=254&w=270&sz=11&hl=pt-BR&start=2&sig2=lZGvahExdj7PlrcfwE45Bw&zoom=1&tbnid=Ln_OmS_d63olQM:&tbnh=106&tbnw=113&ei=xwmZTKf7IIWBlAfbxpztDw&prev=/images?q=quimica&um=1&hl=pt-BR&tbs=isch:1&um=1&itbs=1 http://www.google.com.br/imgres?imgurl=http://quiprona.files.wordpress.com/2009/07/saccharomyces-cereviseae.jpg&imgrefurl=http://quiprona.wordpress.com/2009/07/12/saccharomyces-cereviseae-turbinadas/&usg=__Ijz68r6b_rehC65RcuKatqeoUiE=&h=1447&w=1285&sz=486&hl=pt-BR&start=2&sig2=4xxS2HDEAJHzS_e-UkHFNA&zoom=1&tbnid=GFeMf96yQ_kIYM:&tbnh=150&tbnw=133&ei=Pg-ZTL2MJoGclgfdj6HuDw&prev=/images?q=saccharomyces&um=1&hl=pt-BR&sa=X&tbs=isch:1&um=1&itbs=1

  • Biorefinery: Different actors / Different visions

    Complexity (so many actors)...

    Only 3 products? What kind of products?

  • BRASKEM

    BIOREFINERIES: ACTORS, CONCEPTS AND SYNERGIES

    COMPETING TECHNOLOGIES

    FACTORS

    CONCLUSIONS

    Agenda

  • Competing technologies

     technologies: termochemical/chemical, biochemical

    http://3.bp.blogspot.com/_ZC2nsH64aOo/S8SeCYZr08I/AAAAAAAAGv8/4vhKRBNgahw/s1600/Wacker+ACEO+Process.bmp

  • Timeline / distribution

  • Raw materials approaches

     raw materials: switch gras, miscantus, corn, wood, sorghum, sugar cane,

    algies, waste (hemi cellulose), etc..

     raw material could define the technolgy to be used

  • BIOCHEMICAL GENETIC / ENZIM./FERMENTATION

    CHEMICAL TERMO / CATALYTIC

    B IO

    M A

    SS T

    R EA

    TM EN

    T

    BIOPRODUCT PRODUCTION

    C H

    EM IC

    A L

    TE R

    M O

    / C

    A TA

    LY TI

    C

    B IO

    C H

    EM IC

    A L

    G EN

    ET IC

    / E

    N ZI

    M ./

    FE R

    M EN

    TA TI

    O N

    BIO-OIL

    ETHANOL

    ACRYLIC

    ACIDETHANOL SUCCINIC

    ACID

    BIO-OIL

    SUGAR, HMF,

    FDCA, PEF

    GLICOSE,

    FRUTOSE, HMF

    ACIDO

    ACETICO ETHYLENE

    ISOPRENE

    EPYCHLORIDRIN

    SYNTHESIS GAS

    PLA

    ETHANOL

    ETHANOL

    PROPANODIOL BIO-OIL

    Both competences will be necessary in the future

    http://www.cbi.com/ http://images.google.com/imgres?imgurl=http://www.ibsresearch.nl/nederlands/images/Logo_DSM.jpg&imgrefurl=http://www.ibsresearch.nl/nederlands/nl_clientsuccesses.html&start=14&h=218&w=640&sz=14&tbnid=JVzjBWToLU2O_M:&tbnh=47&tbnw=137&hl=en&prev=/images?q=dsm+logo&gbv=1&svnum=10&hl=en http://images.google.com/imgres?imgurl=http://www.ibsresearch.nl/nederlands/images/Logo_DSM.jpg&imgrefurl=http://www.ibsresearch.nl/nederlands/nl_clientsuccesses.html&start=14&h=218&w=640&sz=14&tbnid=JVzjBWToLU2O_M:&tbnh=47&tbnw=137&hl=en&prev=/images?q=dsm+logo&gbv=1&svnum=10&hl=en http://www.topsoe.com/ http://www.wacker.com/cms/en/home/index.jsp

  •  BRASKEM

     BIOREFINERIES: ACTORS, CONCEPTS AND SYNERGIES

     COMPETING TECHNOLOGIES

     FACTORS

     CONCLUSIONS

    Agenda

  • Economic Aspects

    Different approahes, different numbers... Do

    not consider chemical products...

  • OIL

    RENEWABLES

    REFINERY

    PROCESS

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