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Rev.03042017
Well Completion Products & Services
Contact Us Today Office: 1.970.573.4694 Email: [email protected] Visit Us: Sunrisechemcialsllc.com
Rev.03042017
Unit features
Precision Fluid System:
Improve efficiencies and drive cost reduction
Basic Specifications (ADS)
Human Machine Interface (HMI) provides high visibility and easy operation
Panel display greatly enhances user information and control
Rates and totals on one screen Target rates displayed Detailed reporting systems Real-job log
Advanced Monitoring System In-line viscosity meters Temperature/TDS/pH Flowback & pump transducers Quantified plug returns
End of Job Report
Full Job Analysis Total chemical and fluid volumes
Eye wash station Spill containment 15 bbl mix tank 25 bbl sweep tank 10 hp, 0-600gpm pump 4 chemical pumps capable 0-6 gpm
Coil Tubing ADS Unit (Automated Delivery System)
Consistent fluid composition with real time modification capability
Improves slide efficiencies and decreases rig time
Real-time data capture for on-site and future optimization
Reliable, repeatable, and proven RESULTS
Rev.03042017
Proven Results (ADS)
Sunrise Chemicals has been operating for the past four years in the Fayetteville Shale and more recently in the DJ Basin where we continue to maintain an excellent safety and customer service record.
Wellbore Viscosity vs. Return Rate
25 plugs drilled out in less than 24 hours
Recent DJ Basin Results
Average total cost of less than
$240/hr or $1.65/BBL utilizing
2.625” Coil ID
Average FR ~ 0.086 gal/10BBL
Average Gel ~ 3.34 gal/10 BBL
Average POP
< 5,000’ Lateral ~ 11.03 gal >5,000’ Lateral ~ 104.76 gal
Average L Beads
< 5,000’ Lateral ~ 0.00 gal > 5,000’ Lateral ~ 9.03 gal
Chemicals
Specifically designed fluid system for every well
Chemicals – Sourced from the industry leading providers; consistently re- evaluating and testing through our in-house and 3rd party laboratories to maintain optimal chemical performance for the customer
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Rev.03042017
Sunrise Chemicals
Sunrise Chemicals was started with the focus to develop chemicals and chemical delivery systems that would improve horizontal well drill outs and work-overs. In 2015 Sunrise Chemicals developed the Coil Tubing Automated Delivery Systems (ADS). This product line is a fully automated hydration unit which can be operated by one person using a touch screen display/(HMI). The HMI interface allows the operator to adjust all chemical rates on the fly, as well as control volume and viscosity of gel sweeps with a touch of the screen, all valves are air actuated and tanks have fluid level sensors to ensure accurate volume and safety.
Our units have been proven in the Fayetteville Shale and DJ Basin to save the operator significant chemical volumes (upwards of 60% is not uncommon) as well as reduce the time to drill out plugs In current operations chemicals are often dumped via 5 gal buckets directly into the CT tubs and sent downhole. This leaves very little time for mixing and hydration time, as well as giving a very imprecise dosage of the needed chemical for the operation. This is something that has all but been eliminated in fracturing operations, but has seemed to persist in CT operations. Our goal is to both give the proper amount of chemical via liquid add pumps, in-line viscometers, and flowmeters. It also has two on-board mixing tubs to ensure the chemical is fully mixed and hydrated prior to being sent down the coil. These systems combine to give a more precise, economical chemical system at a reduced price for the operator.
Sunrise Chemicals has continued to improve on the existing technology. Our newest hydration unit has all of the above plus a data acquisition system where we are capturing the CT pump rate, pump pressure, pipe light and pipe heavy from the Coil Cat system as well as a pressure transducer on the flow back manifold, and real time data monitoring system that can be viewed anywhere there is internet access. We believe with this expanded data package further optimization of coil tubing drill outs will be made.
Our low overhead and automated system have allowed us to stay extremely competitive with our prices and will gladly share upon request
Rev.03042017
The Team
Stuart Allen
President and Owner of Sunrise Chemical LLC.
Stuart Allen graduated Colorado School of Mines with a degree in Petroleum Engineering.
Contact Info:
Cell: 501-697-8566
Email: [email protected]
Mike Mulligan
Chemical Manager
Mike Mulligan graduated Colorado School of Mines with a degree in Chemical Engineering.
Contact Info:
Cell: 303-229-8485
Email: [email protected] Daniel Bolton Engineer & HSE Coordinator
Daniel Bolton graduated Colorado School of Mines with a degree in Petroleum Engineering.
Contact Info:
Cell: 303-594-0102
Email: [email protected] John Boozy
DJ Basin Operations Supervisor
Contact Info:
Cell: 501-581-9272
Email: [email protected] Hunter Stokes
Rocky Mountain Regional Manager
Snubbing and Well control, extensive workover and production experience
Contact Info:
Cell: 970-373-8526
Email: [email protected]
Rev.03042017
Fluid System Additives
FR-100 (Friction Reducer)
Rev.03042017
Physical Properties
Flash Point: >200 oF (>93.3 oC)
Specific Gravity: 1.06 Solubility: Water, Brine Chemical Family: Synthetic Polymer Charge: Anionic Appearance: Light Green Liquid Odor: Petroleum Distillates
Description FR-100 is the next generation, REACH registered friction reducer that is an ultra-high molecular weight, salt tolerant polymer engineered to provide premium friction reduction. This anionic, friction reducer can be used in freshwater, KCl waters, and water treated with KCl Substitutes. FR-100 yields rapidly and will reduce friction by as much as 70% or more, depending on the pipe dimensions, pressures and flow rates. This unique hydrogenated polymer is more effective pound for pound than competitive products, providing better or equivalent drag reduction.
FR-100 is available in 5 gallon pails, 55 gallon drums and 330-gallon tote tanks.
Advantages Is more effective pound for pound than competitive products Reduces friction as much as 70% or more Salt tolerant friction reducer Compatible with fresh water, KCl waters, and water treated with KCl substitutes
Mixing/Treatment Prior to use, stir the container to ensure best results. Over time the product may settle out in the container. This is normal and does not affect product quality. Simply mechanically agitate to re-disperse. Do not air-stir as the moisture in the air will hydrate the polymer prematurely and a very viscous or semi-solid mass will result.
FR-100 may be used in higher concentration or other types of brines as well; however, compatibility and performance should be confirmed. May be batch mixed or added directly on the fly. Normal use rate to increase aqueous drilling fluid viscosity is 0.5 to 2.5 gpt (0.21 gal/10bbl - 1.05 gal/10bbl). For friction reduction use rate is 0.25-0.5 gpt (0.105 gal/10bbl – 1.21 gal/10bbl).
Handling/ Storage Store away from heat sparks and open flame. Keep container tightly sealed to prevent evaporation, contamination, and explosion hazards. Use only with adequate ventilation. Promptly remove any spilled material as it is extremely slippery, especially when wet. Rinse spill with copious amounts of water. It can cause eye, skin and respiratory tract irritation by contact. Do not breathe vapors, especially in a confined area. Recommend use of chemical splash goggles and rubber gloves during handling.
Refer to Safety Data Sheet (SDS) for handling and hazard data.
FR-100 (Friction Reducer)
Rev.03042017
Technical Data
Friction Flow Loop MaximumFriction Reduction
0.25 gpt Loading, 1/2" OD, 5 gpm
80.0
70.0
60.0
50.0
40.0
30.0
20.0
10.0
0.0
2% KCl 7% KCl
FR‐100 Competitor B1 Competitor C1 Competitor D1 Competitor E1 Competitor F1
Friction Reduction (%)
OptiGel 1000 (Viscosifier)
Rev.03042017
Physical Properties
pH: 5.0 – 8.0 Specific Gravity: 1.0 - 1.1 Density: 8.33 – 9.16 lb/gal Appearance: Off White Opaque Liquid
Description OptiGel 1000 provides desired viscosities in high TDS brines containing high levels of chlorides and divalent ions (Ca2+, Mg2+, etc.). Extremely effective when utilized with coiled tubing to circulate fluids to pick up and remove solids and debris from wellbore. This product does not settle or experience oil separations allowing for efficient quick mixes and sweeps without the need for elaborate and expensive mixing equipment and more accurate metering of active products resulting in improved fluid performance. Packaging consists 5 gallon pails (36 per pallet) and IBC (totes) 330 gallons.
Advantages Pound for Pound Better than Competitor Products Extremely stable suspension Highly effective viscosifier Works well in light to saturated brines Increases carrying capacity of fluid Easy to handle and mixes well in low shear rate environments No “fisheyes” Compatible with anionic and nonionic additives
Mixing/Treatment Low-shear mixing equipment is sufficient to provide through dispersion and homogeneous mixtures. Sunrise recommends to use 3-5 gallons per 1-15bbl pill in
Handling/ Storage Do not breathe vapors/ dust. Avoid exposure, obtain special instructions before use. Avoid contact with skin and eyes. Provide sufficient air exchange and/ or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. Product very Slippery when wet.
Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Store away from Acids, Oxidizers.
See SDS for more information
OptiGel 1000 (Viscosifier)
Rev.03042017
Technical Data
Gel Sweep HB (Viscosifier)
Rev.03042017
Physical Properties
Pour Point: < -22 °F Specific Gravity: 1.05 -1.08 Density: 8.75 - 8.9 lbs/gal Appearance: Off White Opaque Liquid
Description Gel sweep provides desired viscosities in high TDS brines containing high levels of chlorides and divalent ions (Ca2+, Mg2+, etc.). Extremely effective when utilized with coiled tubing to circulate fluids to pick up and remove solids and debris from wellbore. This product does not settle or experience oil separations allowing for efficient quick mixes and sweeps without the need for elaborate and expensive mixing equipment and more accurate metering of active products resulting in improved fluid performance. Packaging consists 5 gallon pails (36 per pallet) and IBC (totes) 275 gallons.
Advantages Extremely stable suspension Highly effective viscosifier Works well in light to saturated brines Increases carrying capacity of fluid Easy to handle and mixes well in low shear rate environments Compatible with anionic and nonionic additives
Mixing/Treatment Low-shear mixing equipment is sufficient to provide through dispersion and homogeneous mixtures. Gel Sweep HB is utilized for medium to high brines and is recommended in a more complex brine application where the TDS can range from 50-150K mg/L. Sunrise recommends to use 5-10 gallons per 1—15bbl pill in order obtain sufficient sweep viscosities (concentration will vary according to job requirement).
Note: Use Gel Sweep (no HB) in freshwater to light brines (< 20K mg/L TDS). It works well in monovalent brine waters.
Handling/ Storage Do not breathe vapors/ dust. Avoid exposure,obtain special instructions before use. Avoid contact with skin and eyes. Provide sufficient air exchange and/ or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. Product very Slippery when wet.
Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. Store away from Acids, Oxidizers.
See SDS for more information
OptiGlide CT (Pipe on Pipe Lubricant)
Rev.03042017
Physical Properties
Flash Point 200 °F Specific Gravity: 0.87 – 0.92 pH: 7.0 – 9.0 Appearance: Cloudy-Amber Liquid Odor: Hydrocarbon-like
Description OptiGlide CT, a vegetable-based lubricant, is designed to be more environmentally responsible than conventional, oil- based “pipe on pipe” lubricants. Consisting of a proprietary blend of lubricants, OptiGlide CT is formulated to perform even in high temperature, up to 350 °F, and high solids environments. OptiGlide CT can be used in most drilling and coil tubing water-based fluids to provide non-foaminglubrication.
Advantages Superior lubricity Environmentally friendly Compatible with most fluid systems Thermally stable up to 350 °F
Mixing/Treatment Recommended application rates will vary by job depending on local conditions. Suggested application rates for drilling fluid are 1% to 2% by volume depending on the mud type and friction reduction required. For coil tubing and sweeps, add 3% to 5% by volume to the existing fluid. Adjust rates as needed to reduce drag.
A compatibility test is advised before use.
OptiGlide CT is available in 5 gallon pails, 55 gallon drums, or one-way totes. Other packaging may be available upon request.
Handling/ Storage Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation. Do not breathe vapors or spray mist. Keep away from open flames, hot surfaces and sources of ignition. Avoid contact with skin, eyes or clothing. Wear personal protective equipment/face protection. When using do not eat, drink or smoke.
Refer to Safety Data Sheet (SDS) for more information.
NanoLube CT (Pipe on Pipe Lubricant)
Rev.03042017
Physical Properties
Flash Point >200 °F Specific Gravity: 0.851 – 0.952 pH: 7.0 – 9.0 Appearance: Dark gray to black Liquid Odor: Mild
Description NanoLube CT is a superior emulsion based green extreme pressure, high temperature (over 400 °F), metal on metal lubricant for drilling and coil tubing with unique nanoparticles. It is designed to reduce torque, drag, and wear while dramatically increasing Rate of Penetration (ROP) in all water-base drilling fluids. The unique platelet shaped nanoparticles position themselves between contacting surfaces aiding in movement of the two surfaces. NanoLube CT quickly lubricates metal surfaces reducing friction and preventing corrosion significantly better than a variety of competitors. It does not grease-out ("cheese out") in the presence of lime and calcium and does not adversely affect rheology or gel strength.
Advantages Superior lubricity Environmentally friendly Compatible with all known fluid systems Dramatically decreases drag and wear Thermally stable up to 400 °F
Mixing/Treatment Recommended application rates will vary by job depending on local conditions. Suggested application rates for coil tubing fluid system are 0.1 to 0.6 gal/10BBL by volume depending on the water quality and friction reduction required. Adjust rates as needed to reduce drag.
NanoLube CT is available in 5 gallon pails or one-way totes. Other packaging may be available upon request.
Handling/ Storage Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation. Do not breathe vapors or spray mist. Keep away from open flames, hot surfaces and sources of ignition. Avoid contact with skin, eyes or clothing. Wear personal protective equipment/face protection. When using do not eat, drink or smoke.
Refer to Safety Data Sheet (SDS) for more information.
Technical Data
Percent Reduction in Coefficient of Friction
Conc. % 0.50% 1.00% 1.50% 2.0% Tap Water 66.5% 71.5% 73.8% 72.6%
DI Water 73.2% 73.5% 73.8% 74.1%
2% KCl 63.5% 71.5% 72.6% 72.6%
Liqui-Beads (Co-Polymer Beads)
Rev.03042017
Physical Properties
Pour Point: < -20 °F (< -28 °C)
Specific Gravity: 0.877
pH: 6.0-7.0
Thermal Stability: 400°F (204 °C)
Boiling Point: 450 °F
Appearance: Light Brown Liquid
Odor: Mild Odor
Description Liqui-Beads® provides the combination of a liquid lubricant and the premium performance of Lubra-Glide “CE” Co- Polymer Beads® in a single product. This combination gives you the tools to solve drag, friction and torque issues immediately in a single-drum applicationpackage.
The use of Liqui-Beads® to resolve stuck coil tubing issues has been outstanding. The combination of synthetic lubricity combined with the mechanical action of Lubra-Glide “CE” Co-Polymer Beads® developes a fulcrum effect downhole that gives you an excellent opportunity to free stuck tubing.
Liqui-Beads® is available in 5-gallon pails, 55-gallon drums, 550-gallon bulk containers, & Disposable tote tanks.
Advantages Reduces torque and drag associated with drilling, logging, workover, completion and coiled tubing
applications Suspended fine Lubra-Glide “CE” Co-Polymer Beads® offer excellent mechanical lubrication Fine grade beads average 247 microns or 65 mesh The premium liquid lubricant component has a high affinity for metal and bonds with thesesurfaces,
reducing the coefficient of friction between the work string and wellbore Non-aromatic components will not harm mud motors, MWD or LWD tools LC50 >750,000 at 2% concentration Bio-degradability index ~60%
Mixing/Treatment Liqui-Beads® can be mixed directly into most fluid systems via injection pump, pill form or gravity feeding, directly over the fluid pump suction. Mix slowly through metered additions while circulating. Mix up to 1% LiquiBeads™ evenly throughout the circulating volume to reduce torque and drag.
Pills, approximately 2% Liqui-Beads® with sufficient volume to cover the BHA or problem area and/or build sections. After spotting a pill, stop circulation, rotate and reciprocate the drill string for 3-5 minutes, allowing the product to saturate the zone before continuing operations.
Liqui-Beads (Co-Polymer Beads)
Rev.03042017
Technical Data Liqui-Beads® tested with an OFI EP Metal-toMetal Lubricity Tester (Model# 11-00). Distilled water was used to run a calibration test, and a torque reading of 32 was recorded. This calibration reading was used to determine a coefficient of friction correction factor, to give an accurate coefficient of friction.
During testing API standards were used and the solution was heated to approximately 120 oF. The tests was run with a 10 ppg NaCL Brine Base. The NaCl and 2% Liqui-Beads® were tested and then the metal components (Object A) were unsubmurged overnight with residual fluid remaining on the components. The next day the metal cup (Object B) was washed out and refilled with NaCL Brine 10 ppg to see if the Liqui-beads® would contribute to lubricity in a fresh fluid sample.
Test Results can be seen in the Table Below.
NaCl Brine Base (10 ppg)
2% Liqui-Beads Liqui-Beads Residual
Torque 28 7.8 5.2
Friction Reduction N/A 72.1% 81.4%
CoF 0.301 0.0804 0.056
Concentration (vol.) 100% 2% residual
Calibration 31.6 Correction Factor 1.076
AF-300 (Foamer)
Rev.03042017
Physical Properties
Flash Point: 202 °F (94 °C)
Specific Gravity: 1.04 Charge: N/A Appearance: Amber Liquid Odor: Odorless
Description AF-300 is designed to be a foamer as well as a wetting agent. It has excellent foaming qualities in fresh water, brine waters, and acids. This foamer has excellent carrying capabilities of cuttings and particles created during the acidizing process as well as reducing hydrostatic head created by large volumes offluid.
AF-300 also reduces surface tension, and is ideal when used in conjunction with CO2 or Nitrogen. It makes an excellent foam for sweeps & diversion. It is compatible with most make-up waters, and creates a soft foam which degrades rapidly when exposed to atmospheric conditions.
AF-300 available in 5 gallon pails or 55 gallondrums.
Advantages Compatible with most make-up waters Reduces fluid surface tension Has excellent carrying capabilities Reduces hydrostatic head Degrades rapidly at atmospheric conditions
Mixing/Treatment AF-300 recommended concentration is 1-3 gpt (0.42 gal/10bbl-1.26 gal/10bbl) for acidizing and 3-5 gpt (1.26 gal/10bbl- 2.1 gal/10bbl) for sweeps & diverter applications. Concentrations may vary depending on job requirements.
Handling/ Storage AF-300 should avoid contact with strong oxidizers, high temperatures, flames/sparks, and temperatures above flash point. It may react with excessive heat, ignition source, strong oxidizing agents, and alkaline materials. May decompose into carbon dioxide or carbon monoxide if reacted.
AF-300 is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. No decomposition if stored and applied as directed.
See SDS for more information.
CI-310 (Acid Corrosion Inhibitor)
Rev.03042017
Physical Properties
Specific Gravity: 0.87 Density: 7.25 lbs/gal Charge: Cationic pH: 4.0-5.0 Color: Dark Amber Liquid
Description CI-310 is an acid inhibitor for use in hydrochloric acid solutions. This chemical was developed specifically for acidizing oiland gas. It is highly dispersible in the most common concentrations of hydrochloric acid blends.
Advantages Highly Dispersible in common Hydrochloric Acid Blends Mitigates Equipment and Wellbore corrosion Optimizes Acid Treatment
Mixing/Treatment The recommended concentration for CI-310 ranges from 1 to 20 gallons per thousand gallons (gpt). Acid strength, temperature, contact time, and type of steel should all be taken into consideration when determining CI-310’s set point. Chemical compatibility with other additives should be considered to prevent undesired reactions from occurring. For coiling tubing jobs contact Sunrise Chemicals LLC for best concentration to be utilized.
Technical Data
Temperature Concentrations
Degrees F GPT % Formic
150 2 NA
175 3 NA
200 5 NA
225 6 NA
250 8 25-30gpt/Formic Acid
275 8 25-30 gpt/Formic Acid
300 10 30-35gpt/Formic Acid
325 12 35-40 gpt/Formic Acid
350 15 40-50 gpt/Formic Acid
Note: The recommendations above are only recommendations from lab testing. Please contact Sunrise Chemicals LLC for optimal concentrationrecommendations
Rev.03042017
Please Contact Sunrise Chemicals for a full product list
Phone: 1-970-573-4694
Visit us on the Web:
www.sunrisechemicalsllc.com
DISCLAIMER: While the information and data contained herein are presented in good faith and believed to be reliable, nothing herein shall be deemed to constitute a warranty, express or implied, that the information or data is reliable, accurate, or complete or that the products described hereinare merchantable or fit for a particular purpose or that said information, data, or products can be used without infringing the intellectual property rights of third parties. Individuals who receive the products or the information or data relating to the products described herein, must use their own judgment in determining fitness for a particular purpose. Unless otherwise stated, the information or data contained herein relates to the products when not used in conjunction with any other products or materials. Sunrise Chemicals, LLC and its affiliates disclaim all express and implied warranties of merchantability, fitness for a particular purpose, and non-infringement. Sunrise Chemicals, LLC shall not be liable for any loss or damage that may occur from the use of the products described herein, including the use of the products in conjunction with other products or materials, or reliance on the data or information described herein.