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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY
1.1 Identification of the substance EC# 202-307-7
CAS# 94-13-3
NIOSH, Registry of Toxic Effects (RTECS) Identification Number
DH280000
Substance Name Propyl Praben (Propyl 4-hydroxybenzoate)
Synonym: Benzoic acid, 4-hydroxy-, propyl esterPropyl p-hydroxybenzoate
Chemical Formula C10H12O3
1.2 Use of the substance/mixture Cosmetics Hair care Preservative The recommended use level is 0.10.6% by weight of product as supplied. It is easy to handle, very stable and cost-effective. It is stable over a wide range of pH and temperature conditions It does not discolor product when combined with additives or by changes in pH.
1.3 Company/undertaking identification
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Safety Data Sheet Saligin PP
SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
The person responsible for placing the substance on the market within Community
Full address SALICYLATES & CHEMICALS PVT. LTDA-25, ROAD NO.18, IDA NACHARAM,HYDERABAD – 500 076ANDHRA PRADESH INDIA
Telephone No. +91- 40-27171550, 27174691
1.4 Emergency telephone Emergency
telephone number of the company
+91- 40-27171550, 27174691
Specification if this phone number is available only during office hours
2. HAZARDS IDENTIFICATION
Classification according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
Hazard Class and Category Code(s)
Skin Irr. 2Eye Irr.2 Resp. Sens. 1
Hazard statement Code(s)
H315H319H334
Most important adverse physicochemical, human health and environmental effects and symptoms relating to the uses and possible misuses of the mixture that can reasonably be forseen
May be harmful in case of inhalation.
CARCINOGENIC EFFECTS: None found
Slightly harmful in the aquatic environment or are otherwise designed for biocidal action
Causes irreversible eye damage
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
Substance Name CAS# EC# Percentage
by weightRisk
phrases
Hazard Class and Category Code(s)
Hazard statement Code(s)
Pictogram, Signal Word
Code(s)
Propyl 4-hydroxybenzoate
94-13-3 202-307-7 100% R 37 Resp. Sens. 1
H334
WngR 36/38 Skin Irr. 2
Eye Irr. 2H315, H319
Wng3 COMPOSITION / INFORMATION ON INGREDIENTS.
Propyl 4-hydroxybenzoate 94-13-3 100%
4. FIRST AID MEASURES
Subdivision of information according to route of exposure Eye contact Check for and remove any contact lenses.
Do not use an eye ointmentSeek medical attention
Skin Contact After contact with skin, wash immediately with plenty of water.Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap.Be particularly careful to clean folds, crevices, creases and groin.Cover the irritated skin with an emollient.If irritation persists, seek medical attention.Wash contaminated clothing before reusing.
Serious Skin Contact
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial creamSeek medical attention.
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
Inhalation Allow the victim to rest in a well ventilated area.Seek medical attention.
Serious Inhalation
Evacuate the victim to a safe area as soon as possible.Loosen tight clothing such as a collar, tie, belt or waistband.If breathing is difficult, administer oxygen.If the victim is not breathing, perform mouth-to-mouth resuscitation.Seek medical attention.
Ingestion Do not induce vomiting.Loosen tight clothing such as a collar, tie, belt or waistband.If the victim is not breathing, perform mouth-to-mouth resuscitation.Seek medical attention.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media SMALL FIRE Use DRY chemical powder or carbon dioxide. LARGE FIRE Use water spray or fog.
Cool containing vessels with water jet in order to prevent pressurebuild-up, autoignition or explosion.During a fire,highly toxic and irritating gases carbon oxides (CO, CO2) may be generated
Other information Flammability of
the ProductNon Flammable
Products of Combustion
Products of combustion are toxic. At high temperatures, this will release CO and Co2
6. ACCIDENTAL RELEASE MEASURES
Methods for cleaning up: Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal
container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirement
Large Spill Wear appropriate protective equipment and NIOSH/MSHA approved respirator where mists or vapors of unknown concentrations may be generated (self-contained breathing apparatus preferred)Dike and contain spill with inert material (sand, earth, etc.) and transfer the powder to containers for recovery or disposal
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
Keep spill out of sewers and open bodies of water
7. HANDLING AND STORAGE
7.1 Handling Keep locked up Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation. Wear suitable respiratory equipment if ingested, seek medical advice immediately and show the
container or the label. Avoid contact with skin and eyes
7.2 Storage
Keep away from heat. Keep away from sources of ignition. Keep container tightly closed Keep in a cool, well-ventilated place Ground all equipment containing material. Keep container dry. Keep in a cool place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Exposure limit valuesNo Limits have been found from OSHAConsult local authorities for acceptable exposure limits.
Source Type ValueOEL TWA No Limits have been found
OEL No Limits have been foundLLV No Limits have been found
8.2 Exposure controls
8.2.1 Occupational Exposure controls Engineering
ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits.
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
(a) Respiratory protection
Dust respirator Be sure to use an approved/certified respirator A self contained breathing apparatus should be used to avoid inhalation of the product.
(b) Eye protection Splash goggles
(c) Skin protection Lab coat Be sure to use approved/certified or equivalent Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 General Information Physical state Solid Color White
9.2 Important health, safety and environmental information
pH at 250C Not Available Molecular Weight 180.2 g/mol Melting Point 96°C (204.8°F
Solubility Soluble in methanol, diethyl ether, acetone. Very slightly soluble in cold water, hot water
Density Not Known Boiling point 68 deg C Specific Gravity 1.063 (Water = 1
10. STABILITY AND REACTIVITY Stability: The product is stable.
10.1 . Materials to avoid:
Oxidising agents Mineral acids
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
.Note
Corrosivity: Non-corrosive in presence of glass, steel, stainless steel(304), stainless steel(316). Polymerization: No.
11. TOXICOLOGICAL INFORMATION
Acute effects (acute toxicity, irritation and corrosivity)
The substance (as fume or dust) is mildly irritating to the respiratory tract.
Sensitisation
May cause allergic skin reaction.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction) Carcinogenic
EffectsNone Found
Other Toxic Effects on Humans: Lungs The substance is toxic to lungs
ORAL LD50(RAT) : LD50 = 6332 mg/kg. DERMAL(RABBIT): MILD IRRITANT EYES(RABBIT) : MILD IRRITANT INHALATION LD50(RAT ): No information found
12. ECOLOGICAL INFORMATION
12.1. EcotoxicityNo information has been found
12.2. Bioaccumulative potential Not bioaccumulative
12.3. Products of Biodegradation
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
Using a Zahn-Wellens test(2), which requires a 0.2 - 1.0 g/L dry inolculum and 50-400 dissolved organic carbon/L test concentration(1), analogous methylparaben degraded 100% after 6 days with a 2 day acclimation period in a sludge inoculum(2), suggesting that propylparaben may be subject to biodegradation(SRC).
12.4. Toxicity of the Products of Biodegradation The products of degradation are as harmful as the original product.
13. DISPOSAL CONSIDERATIONS
Substance Disposal Material in the elemental state should be recovered for reuse or recycling. Contact a licensed
professional waste disposal service to dispose of this material. Observe all federal, state, and local environmental regulations.
14. TRANSPORT INFORMATION
DOT(Department of Transportation) Classification
Not classified
Identification Shipping name: Propyl Paraben RID(Regulations
Concerning the International Transport of Dangerous Goods by Rail) /ADR(Agreement on Dangerous Goods by Road)
Non-hazardous for road transport
IMDG( International Maritime Dangerous Goods)
Non-hazardous for sea transport
IATA(International Air Transport Association)
Non-hazardous for air transport
UN number
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
15. REGULATORY INFORMATION
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
Classification and Labelling according to REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
Respiratory and Skin sensitisationLabel elements Respiratory sensitisation Skin sensitisation
GHS Pictogram
Signal Word Warning WarningHazard Statement H334: May cause allergy or asthma
symptoms or breathing difficulties if inhaled
H315: Causes skin irritationH319: Causes serious eye irritation
Precautionary Statement prevention
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray
P285: In case of inadequate ventilation wear respiratory protection.
P272: Contaminated work clothing should not be allowed out of the workplace.P280: Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary Statement Response P304 + P341: IF INHALED: If
breathing is difficult, remove victim tofresh air and keep at rest in a position comfortable for breathing.
P302 + P352: IF ON SKIN: Wash withplenty of soap and water.
P342+ P311: symptoms: Call a POISON CENTER or doctor/physician.
P333 + P313: If skin irritation or rashoccurs: Get medical advice/attention.
P321: Specific treatment as per first aid measure.P363: Wash contaminated clothingbefore reuse.
Precautionary Statement StoragePrecautionary Statement Disposal
P501: Dispose of contents/container in accordance with local/regional/national/international regulation
P501: Dispose of contents/container in accordance with local/regional/national/international regulation
May be harmful to the aquatic environment
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
Other regulatory information HMIS (Hazardous Materials Identification System) Classification
2 = Moderate Hazard = Temporary or minor injury may occur
1= Minimal Hazard = Materials that must be preheated before ignition will occur.
0 = Minimal Hazard = Materials that are normally stable under fire conditions and will not react to water, polymerise, decompose, condense or self reactE =
NFPA (National Fire Protection Association)
2= Health Hazard = Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given.1= Flammability = Must be preheated before ignition can occur.0 = Instability = Normally stable, even under fire exposure conditions, and are not reactive with water.
Federal and State RegulationsNo information found
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
OSHANo information found
16. OTHER INFORMATION
Technical Advice Use data given in this Safety Data Sheet and make an inventory list of all chemicals used in the
factory Create a Register for Workplace Chemicals; Set priorities concerning the safety in the organization Create emergency plans for the assessed hazards; Organize occupational health care and regular surveys as necessary; Organize contacts with authorities/laboratories to create a monitoring system for chemical hazards,
and to reliably measure and/or estimate occupational exposures to chemicals when needed; Start collecting case studies of accidents and sickness records in the enterprise to create a basis
for priority measures in the control of hazards; Involve workers in safety organizations, such as the system of Safety Representatives and
Committees. Do regular inspection using checklists made for the particular chemicals and chemical processes in
use; Mark and label all chemicals; Keep at hand an inventory list of all chemicals handled in the place of work together with a
collection of Chemical Safety Data Sheets for these chemicals; Train workers to read and understand the Chemical Safety Information, including the health
hazards and routes of exposure; train them to handle dangerous chemicals and processes with respect;
Plan, develop and choose the safe working procedures; Reduce the number of people coming into contact with dangerous chemicals; Reduce the length of time and/or frequency of exposure of workers to dangerous chemicals; Train workers to know and understand the emergency procedures; Equip and train workers to use personal protective equipment properly after everything possible
has been done to eliminate hazards by means of other methods;
List of relevant R phrases R37 Irritating to respiratory system R36/38 Irritating to eyes and skin
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SALICYLATES & CHEMICALS PVT. LTD.,A-25, Road No.18, I.D.A. Nacharam,
Hyderabad - 500 076 – India.Tel # 91 40 27171550, 27174691
Fax # +91 40 27171249Email : [email protected]
Visit us : www.preservativesindia.com
Created By:ELC GROUP Contact Person momaja s.r.o. Jastin SardharaKrakovska 9, Prague 1, 110 00Czech Republic Tel. +420 22 491 0000 Fax. +420 22 491 0671
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Salicylates and Chemical Pvt. Ltd. be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages.
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