water quality and standards

34
1. Of bacterial Some ,'Importan:t.' ·.,1 , ;_. ,,,:'. ~:;,:,>-:.>~;;,~;. ;~i:t~~ -:':.~" . .:, L Sanitary field survey.of>~the:«i;iource.,'':' whi adjunc t to a complete 'Sanit;~r'y'~An~lysis~.. ' 2. This is .C1 study of the h i s t ory: and .env Ylmlll1'·~",·f'I source that C3n provide' a 'PI1YSl'Qal pic. water cycle in relation' top ·t~ritJal.' " ·c"",.-,:-; ... ,~,,:"'."."-.:· 3. !\ conp Iet e san i t ary analys', '0' e of cell y ovsr.a Ipngp. " .' (b) chemica1·and(mi 4. A cons i der atdonio . vol'led in 'the'!. U ", 1 ~. ,'. Basis of Judging Qual.it'y 'o{a:',groposed Wate~, -'" .~ ..- - .. ' v- "', .: .. ' ~, ;'. I .( , .' ~ '. 'I \ . .... l ;.. ~·' '7-'."""" "'''''i'''''-8Th ...,. ...•. ,,' . !~_~ :\ii' V1r!I}/~ ~" i\~~j''', '.', ,,: \;f.'~f~f;::}~~,~ ~f:~' >. " ..~., . ~. ,~."J~'·CAlt.;;~i",·Ii-',:;'" ..... _ .. ,',., >~;r3\i!t';;~:~f::~~;-:~~ "\., :....'. \.>-t."~ .... '.': . '. '.,_-" . . ....... . -' ~:.;~;;... ":~:.''':;.:J~,L·.~:. : /, ..: .. '. ~ti·:-,;. .;.: . ... :~~\:~'~: .. "":.:"':-:" Def i ni t i cns : ," .: i" ";;, .: :i~~!."::;;j.. .. 1. Potable "Water is one .t'hat do'e~:~p.o.y:;"qontaill~.~pj~ct~o,P~.b"l,p;" ..... . P9,11~ti on.<'con~~llni nati on, mi,!1G:.t,:g}s,:, .,' :~,~~e,~~,~.o.~'<,,:~pg::J'~\~,~,h(3refore . cons i de red 'satIsfad~ory! for domesj umptiL:9IJ.: .. i',;: 2/Contaminat,ed Water .~fs one -t.hattcon .' sea ·bacteriia. '".. ,';-' '_',.'/-,.:.:;\~. . 3. Polluted Waier is .one cOlltaini,ng' s ~_Y.'..•.;,.;,.: ..... ~~'"'!:, .• ,.~.\"!., •.,,., and other>,liqtiids, thus r..e,ndering'it<o .'.~.~.~, ~.,~.'l"':'!~'r.:'~,~~"n~',t.' smel Ij: lienee unsatisfactory f()r culin3;yr <.'J ":,/ ' /\ .""D. / -, c. ::,1'" ., .. ,'. Chapter xv:~ ~ .: ,', . 4. PUre W8t~r ~~neve~ attainab1~ ~n natijre~ tory - usua l Iy 'taken to mean, potab1e,:wa ->, " .... ' ...., \ '.,"X ,84, :;Quali t y of Vlater Sources'; , :' '..... '" \'... ..' :: .".l;< '. \ ',.._ .~.' -,. .' ...~ ..~;J(t' .., ".'-"-. I. Meteoric waters - sati~f{actory<for)lwn.an';:cQqs purification, \ itX . .... '''. :_':~:r!~:' "?i,;'" 2:. Surface waters - usuaU{un$afe ,wit'hout .treatment, be made satisfactory with treat:men't:':" .' 3. Ground waters ~ usually:satis~actory wiih treatment (removal of mi ncra Ls, etc.) , " .:', , '1.>.,.' : .'','.; ;!".~.. ~~" .,... ..' I . ' .. ,." :..

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Contains physical, bacteriological and chemical examination of water

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  • 1. Of bacterial

    Some ,'Importan:t.'

    .,1,

    ;_. ,,,:'. ~:;,:,>-:.>~;;,~;.;~i:t~~-:':.~" . .:,L Sanitary field survey.of>~the:i;iource.,'':' whi

    adjunc t to a complete 'Sanit;~r'y'~An~lysis~..'2. This is .C1 study of the history: and .env Ylmlll1'~",f'I

    source that C3n provide' a 'PI1YSl'Qal pic.water cycle in relation' top t~ritJal.' " c"",.-,:-;...,~,,:"'."."-.:

    3. !\ conp Iet e san it ary analys', '0' e ofcell y ovsr.a Ipngp. " .'(b) chemica1and(mi

    4. A cons ide r atdonio .vol 'led in 'the'!.U

    ", 1 ~. ,'.

    Basis of Judging Qual.it'y 'o{a:',groposed Wate~,

    -'" .~..- - .. '

    v- "',

    .:.. ' ~,;'.I.(

    , .'~'.'I \

    .....

    l;..~''7-'."""" "'''''i'''''-8Th ...,.....,,'. !~_~ :\ii' V1r!I}/~ ~" i\~~j''', '.', ,,:\;f.'~f~f;::}~~,~~f:~'>. " ..~., . ~. ,~."J~'CAlt.;;~i",Ii-',:;'"....._..,',.,>~;r3\i!t';;~:~f::~~;-:~~"\., :... .'. \.>-t."~

    ....'.': . '.'.,_-" .. ....... . -'~:.;~;;...

    ":~:.''':;.:J~,L.~:. : /, ..:

    .. '. ~ti:-,;..;.: .

    ... :~~\:~'~: .. "":.:"':-:"

    Def ini t icns : ," .: i" ";;, . : :i~~!."::;;j.. . .1. Potable "Water is one .t'hat do'e~:~p.o.y:;"qontaill~.~pj~ct~o,P~.b"l,p;"..... .

    P9,11~ti on., " .... ' ...., \'.,"X ,84, :;Quali t y of Vlater Sources';, :' '..... '" \'... ...' :: .".l;eY,e}l~eryti~I?piBg of air in thesand. . -...... n. c. ' . " - '.

    ",; '.::~:~.,\ '

    60 The sand bed is cleaned by temoving appro~imat~ly I inch of sandfrom surface of bede

    Loss of head reaches a maximum.of 4 to 6.ft at whfuh time itis necessary to put the filter out of service and clean the :ped",

    Flow rates are controlled manually by ~and-operated valveu inaccordance with ,flow indication and recordi~g instruments,...

    Since a coating of organic matter (bacterial slime) play~ animpcrt ant part in the straining action of the fil ter mat, it usual-ly requires s~veral days during which the effluent is wasted intothe filter ;:ipe;'sq .

    5. A normal period of operation between c~~anings should be 2 to 3monthr.or longer. .

    1. Preparation of water before filtra;~f;,on usually consists of plainsettling only.

    2. In. an ordinary slow s3nd filter nc provision is made for tho ad-di tion of any chemical s and no' coaqul ant is required.

    3. Operated with Constant depth of 4 feet of'water on tho surfuco ofthe sand. This level is measured and maintained by an autolllaticdevice' which regulates the rate of f l owvto the iilter ,

    4" Rate of flow is maintained ut 1':1 mgad with the most conmon ruto ofabout 1:1 mgad.

    H. Operation an6 Control:

    pumps or gravity conduits.3. Plain settling bas ins ,4~ Filters5. Clearw2ter Stotage basino

    60

    ~.

    : . ,,~..,-.:,I -"~::';.,:,-.,!.'-."_;..!:. -; :~I"'~)'..._....-;...;..-r ,.'I:~.i"'

  • ..........

    ,: .' " ' "0'

    1. Lenqt h to d'i amet er ratio should not exceed 60G~~. Per fo rat ions "- J./4 to' 1/2' inch):round in diamet.ez,3,,, Spacing of per f or at ions is 311" forl-1/4" tro"8"V for 1/2"40 Ratio' of t ot al area of perforations ':in unde rd ra in system to totalt~\

    c ro ss-cscct Ione I area of laterals should not exceed 0.5 for 1.t2't~;C", "and 0..25 fc r 1/ 4~~~ ::;:;;.:::;\"

    ~j~ Ratio of total area .o f- per for at ions to entire filter area is .('O~ J;~!.to ,,003 squate inch/xq, ft of f il ter , .

    6. Space laterals at 12":o.,c, ',.;'i7. Rate o f washing is ,6-,36:t/minute,'" Trend in us inq CDClI-Sersandwi th "

    hiqhcr rates of washing and fi 1t.e r inq, , Y,'o. Cross-isect ional urea of Later al s gr~ater; than 2 -t imes sum ,of ,areas

    of perf orat Iona , ,'::ft ,,;"}~"" ;i;:':, ;;, ;v< ~~:,', .: : ..~~i'" . . ":: Jl~P:,.:\' '.'" ....',. ~;:'.:':1 " .f: ~

    Ty[)cs 0 f Underdr ai ns : - ,'{,~!,;,A::,':.',': , ~,::.:;,,',I,,J'.':,'\\~,',:.., ",','"." '".,,' "" ~",U;t:A ,,\,,~~,'1. Perforated pipes - ('onsis~~, ~f:c~~,~{ft.~,::,~~i~~if014,'iowhich are Tai~aChe~

    series of latera}, pip~s;' pq~;forclt,ed'':'lt;::~'pw~r:'portion., " '2, Pipe ~nd strainers --:--'"simflar"~9'~n.O~f''?'fAted ,P\~,pes except that(~

    ~t:a 1ne'1'5 with small' op,el1,in:~:,:ar,?:~,~~,er;t)e~ 'lnili" Lateral's ,~t requl arint erval s. 'Y",'" ,

    3, Ridge and valley -- consist'\'ofj)ara1l0t ridges' 'f concrete 8'I",to ' ;',12" o~c*, with l~":~forated brass ,sc,rcen"support d.between ridges

    4~ Perforated pl at.es -- perf orat ed meta Ll Ic, p.Lates 't

  • '..~

    1.

    ,'" '.'~

    .' '. '. . ' , II .! '~'t'" :~.'

    1. Since 'Wash water should not travel more than 3 ft Iat eral Iy, thetroughs are i'!eVer spaced more ,th,an ,6,fee~:, apa~~~ '" ' ,

    2~ They are constructed, of concrete, , steel and' are of var Ious cross-sect icn, The U~shaped bot tomsiwr th vertical sides are cO,nunon',torconcrete troughDo " . . , '

    3. The edge of wash water troughs' shal l be abQut ',~);):.,::~,.!(d) double unit., ; "Ce) doubIe fil t er .i;'

    .,1./.'; .',

    . . ';,'

    prpe and aut.cmat.ical Iy 'mamt at n: (;J}'WJJ;~Q}]ml:i,~,t.~l~I~,~J)~tlj;~);:b~~g',~9~{",>inc rea ses " '" " ;, ~",;;;jf~' '~:,:t ~:i;dtt~t'\:Si,'v :i,.e;lqet:e,J'IIlilfed.'TheYare ' ~ISef ul i~; i~d~c91Ung'}c~ry,e.con.g;i;Vp,~::{~~:,t.S;:~~ri'ic~;~~\U~r":',a,~q\the '.ceas rt.y of WaShll1g." ",' ..~)7,:';Ji";;;~(1;/ ),;, ,': :

    " . " , " ";" , '~~'),~.,~,I"~;,.~,~,';,.,:},,,';':?'";.. . ," , :.

    , ,'C, , ,,,' .. - .. "i';,;' "" ,!,~.~",:.~.,'":,:::,~':,:,,.....' ,,'/ 7, . .~:'. .:~,",'";;l\~,;'!',,., . :}r-

    N.

    .../~/~ M~ Wash Water Troughs:

    '" ' ,\2. Sand should be free from dirt, hard and resistant and preferablyof quartz or quart~ite: '

    (a) effective size ... 0.35 to 0.5 nm, ~:"(b) uniformity coefficient ",,;,,:1..'35 to'l.'S mm,(c) thickness of sand Layer .':",24" to 9..6"

    (a) hard, '(b) durabl.e'.tc) rounded ' ,(d) weigh about lCO pounds/cubiC f'oot.,(e) free 'from, flat" thin,. or long pf'eces "

  • .Many small size units,0.1 .... OL acres L ".. ,;'

    Few but larger.sizes 'up to I acre

    5. Subdivision'of units

    '100-(125) ..:.150 .mgad4. Rates

    3. Pre l irnfnaryTreatment

    .'English '''.'' .', ;'r.qechanicalor AmericanLondon fiJ.t:~r~/'Je(;.9;,~~,::t::l~9$'exper iments -.:Albani:!fi~;~~:rS)n89~,:.,;:LittletF:all$' filter 19Cis",,~;~,*&i~~~~(~~:~~~ftyi';:;~,:J;:;;:.~11.~~{(~~0~~~~tig~~...",:"

    nonp;:::-spmetimes" '

  • .. ",: .,i

    65

    Disadvantages are: high cost , inef.ficient operat ion, relatively poor"quali ty of result obtained. ,. ," .- . '.," . t', . . . -.

    Pressure :filters are based~on's~,me p'dncipJe':as:"gravity type . ra-pid sand filters but 'the underd~?i~~.~:'i"gl:~V~ra~d SS;~~;~:\~;~'J:'Q,~Q?",th~:~./~l~:~Jsl'',u,nd~r' pres-sure , UnlIke the graVlty-tYRe\;~f;::lt~r~:~r"~lte"(poag:ul?t~d-?.water.1s' usual-ly appl ied di rectly .to fi1tE-}r'wy;~6~t/~'I1l~::x~~(lcJlq.~,9ula:1i:i6n"or: condi ...t ioni nq, They are used almostvexc Ius Ive ly en .swfl1)!J1ing/poo;ls, small

    .later suppl ies, and for ~ndllst'rJa>l,~".,p~,:,::,p>p'se,s,". " i: .... ~ , .

    ...... ';~

    ,'\',

    . redUged17. Iron:-:/~. Press~r~.: Filters:

    few.. ',

    I '~.l".

    more f0ef,l\le~ti;""r0~oved sometimes,. , - , .

    164 Odor and Tastes

    brilliant.. ..... e

    .clear but clogsreadily

    15. Turbidity

    30%14. Color remo~al

    .g,ood,but irregular .'.~~le'sswel l.supervfsed

    Jess than 5 ppm. orsometimes. zero

    13, B~ctcrial r~moval

    straining, sedimentationchemical .

    straining, sodimen-totion, biolog~9allbiochemical' .!.

    12~Theory of Filtration

    0.2%-0.6% of filtered 1-4-6% of filtered waterwater. .

    11_ Amount of wash water

    reverse flow,,,;, every24hrs. 18-24-48inches (wash

    . 10. Cleaning scraping and wash-ing inside C'r~outside filter1-3 months

    4"_6" initial, 9i_12~final

    9. Loss of Head 042 initial, 4-7ft.final.' .

    1.58, Uniformity coefficient 2.0 - 2

  • JisDf!VLlntanos are: hiqh ccs t , inef'f ic ient operation, relatively poorQuality of r~sult obtained

    Pressure filters arc based on same pr inc ipIr, as gravity type ra-pid sand filters but the underdrains, gravel and sJnd arC placed in~:ylj.ndr ic a I tanks and 'Nr! t er is passed t hrcuch tho f iltel'S under pres-aurc , Unlike the gravi ty-r y-c f i 1tel's, the' ccnqu l at od water is usual-ly ,li~llljcd c'Lrcc t l y to filter \\'i:;'I'.lllL 11Iixlll(! [loccuLltio)J orcol1cli-

    -t.icnillO. Th oy :JrL~ us od u Imo s t cxcl us ivo l y C'1l ::;wirrulling pools, smu l lwut cr slll,'lies, nnd for indust rin I P.:PDSCS.,/'

    !'Cn1cvcd someti.mes

    more Ircqueut

    brilliant.

    Ics s t hau 5 ~)PIl1. orsometimes zero

    ~'()f'd but i rrcnu lurunless well sunorvlsud

    s t r e in inn, sod i111(;II t uti allchemi C~Jl

    rod uced

    few

    cIear but cluqsrCQdily

    Unif crm. ,- good

    straining, s dimon-t:;;t ion I lJ in loU iC ill ,b io ch emicn l

    O.2%-~.6%of filtered 1-(-6% of filturud waterwCltcr

    reverse flow - UVl:ry24 hrs. lO-~~-~Oinch-.;swash

    ~craping and wash-ing Lnsi doou t s idc HI tel'l-~~ mont hs

    tv 2 . it i 1 d '7ft .1"-6" init iaI, ()'_.I~~'" 0" I nIl') , .,- .. . LIfinal f inn l

    PressurE. Filters:../ '1".17. Iron16.. OC:OT anrl Tastes

    is, JurlJid i.Ly

    1.4. ''::;olo~rremoval

    I?. Theory d' '~'iltrill:Inil

    Ll , /,iIlOlwt of wash water

    9. Loss DE Head

    G. Unifo~mity coefficient 2.D - 2,5 - ~.O 1.5.35 - .60 mm,

    12"-18" ura vel2~"..36" sand

    65

    c:.~r:i - C.35 1111','.

    12" 0ravcl (3/t.1~21l)3'-6' sand,

    Slow Sand--~-.~.

    7. Sand, ;;;:.3.

    60 Filtering M~t:rinl

    .. I;\.1i

    i:

    "~

    , i,,

  • (2) IGr.~ICL1-- slow act In. exnens ive , effective in low DB. -3, rxidizing ~0cnts:

    (a) 3ilver -- extremely effective, slow acting, no tastes orodor, but ineffective for waters with organic matter.

    (b) Caustic Lime -- for water with pH of 10 or ever.

    2. foisons w~ich Teact with cdll to form toxic substances and kill byeither chcmica l poison ino or disruptive structural changes wi th inthe cell.

    (0) Eeat -- by be i linq, for hous eho ld use only.(b) Ultraviolet Rays - rays ~re abaorbed by ptotoplasm of

    the cell producing death by oxidation of the entymes.AdvBBt2ges.arc: (0) nc tastes or odors in water (b) nodanger of (verdosage.Di sadvant ar-cs: (a) more costly. than usihg chlorine

    (b) for small private water supr.lies andbottling works only.

    (c) Ultrasonic or nicrowaves -- not commerCially used for water.(d) VibrcJtions ,

    1. Fhysical hctien - ~irect application of force or energy which des-troys orqa nisms :;

    c. mGt~ods of disinfection or destroying organisms;

    / .".) . . f di . f . . ki11 b . , thr nc pr i mn ry arm or wat er n si n oct1011 IS to 1 act erIa ano usprevent waterborne disease.

    B. Furpose:

    4. Germicides -- chemic81 compounds or anything to kill micro-organisms,exclusive: of spores . Ultraviolet radiation and oligodynamicsilver are also germicidal.

    S. Sanitizing -- rendering an article clean of any aesthetically ob-jectionable material plus removal of contamination.

    6. AntiseDtic -- either germicidal or bcictericidal - prevent bacterialmult.i plscat ion,

    1. Eactcricide -- anything that destroys bacteria (uot necessarilyspores)

    2. Disinfectant -- chemical agent that destroys disease germs.3. Sterilization -- destructiun of all living organisms, pathogenic or

    not.

    h. :,-:efinit iorrs:Chapter ZIX. ,lISIf'F'SCTIC N-.-.--.

    67

  • E. S;,hlorine Compounds Used:l~l,cnCiling powder (chlorinated 1Ir,1e,chloride of lime) produced by

    fOCa'ii1g chlorine and Lime into rotating drum. About 6('%-7::'%CaCC2 tho active ingredient. It losses strencth rapi~ly in moistair; losscs l%/month in closcd containers. AI':~licationis bydissolvirig and f8eding i~ the form of n solution of 0.5 25% C12.The solution dernsit~ slud~e of CaC03 and inert m~terials.

    2. Co lcium Hypocb Iorite, C.](0c1)2 j-"'j}], Perchloron -- manufacture ismorc complex than bleaching powder, commercial product about 70%- .... ! , - L1,. - L, 1 .......! ,.. ..... ., ......_ , .', ,...,.1 .....(" r- " 1 11+ ; A 11 1 _ ~

    1. Little is known about it - for sometime it was thou~bt thit dis-infection may be dUG to the liberation of ntscent oxygen from thehypoch lorous acid mOCL) but this theory has lost support due tothe feet that chloramines which is also a disinfectant containno oxyqen ,

    2. It is now believed that disinfecting action is probably due toinactivation of cell glucose, metabolizing system by oxidationof enzymes. Thus ch!orine destro~by urtiting with material ofcell (cell-enzyme combination), nttncking it and blocking futureactivity.

    3. Hypochlorous acid and hypochlorites are specifically toxic tobacteria in ways t~at are ~istinct from oxidation. Just what thistoxic rC2cticn is has been the subject of various speculationand theories, Some recent work (:;recnand Stumff) indicate thatthe prim~ry rGsction is one between chlorine and a certain enzymeessential for b3ctcrial reproduction.

    D. Mechanism of chlorine disinfection:

    Ca) centrifuging(b) fi \ t r at ionCc) coacr.l e t ion and sediment at ion,

    ~. Mcchnnical Action - which remove but do not destroy o~gDnisms andpl~cing t~8m ~n less favcrablo environment:

    (c) Bromine - Iodine and other halogens.(d) Hydrogen Peroxide - unstable, no taste and odor residual,

    difficult to maintaic\~(e) Chlorine - cheapest and mo st common.

    (b) Ozone - (03) -_ is an unstable gas that tend to break downinto ndrmal oxygen containing two atoms of oxygen per mo-Lec ule, In the process of breaking down, .it releases nas-c8nt oxygen which is active in oxidizing the organic mat-ter and 1n killing bacteria present in the water.Advantages: no disinfecting chemical remains (n the water,

    odors, taste, and color are removed, inexpensive process.Dis~dvantnge3: cost greater than chlorination, apparltus

    required Is complicated, absence of residual chemicalprovides no safeguard against subseq~ent contamination.

    68

    .....

    ',-.~:-.-:::--~--==,",==--'-"",~""''''''''''''''~-'----------''-----------'-----_._----~.------ --~-,--------- ~----- -:~::_::_:_-~=:::-:-::';:::-:::-':;::;-'~:--:-::--::-:":':":'~:_=:':"~"~:::"":-"-'-~';:'":~=-::-

  • "'...

    1. Crthotolidine -- most widely used, not fco Ipr oof 'since some subs-tances in water like nitri t e; ferric compounds, manqani c COrn-pou~ds, organic iroft::,compound~, F~~qc.equto,se and a~gae tendto mer ease the appar ent :content, :of.;:cllroJ;in~.,.;. .' ". ' .

    2. Icdemet rf c Method _..:.f:cr wi3t.ei;of: residua:!' Cihlp'r~ne gr,~ate( thanI ppmr Colorimetric method, of lodomet,ric' chlorine "det.ermi nat ionis al so ava il ahl e, .. , ;",'",)~~~;;~"::'"',":',',:t:>' :~, ." . - .' . , .

    3. Amperometr I.c Method - only procedure knownit.hat will dd ffe rent Iat.e :between free chlorine and .free -chl cr ine combined with nitroqenouscompounds. The test is known as Laux !'flash" test 'and is a formof colorimetric test having standardized colors. Not applicablein presence of oxidized manqanese, .

    4'1 Drop..Ddl.ut ion test -- rapid field method 'where chlorine cone en- ,tration are gr~ater than 10 ppm~,as . in .water-mam s.ter iHzat.Loni

    G. Four Methods of determining residual chl~rine:

    1. time of contact.2. concentration of organisms.3. concentration of disinfect~nt.4. tempcratureo5. nature of disinfectanto

    F. Factors affecting disinfection efficiency:,

    .',""" . "0

    4. Chlorine Dioxide: - new method - bactericidal propert.Les may be asgret or greater than chlorine, important in water~ o~high alk~-linity, used for waters with phenol troubles, active oxidizing agent2-1/2 more available chlorine than chlorine gaS~

    5, Chlorine-Ammonia: Used where water gives chl om nous taste and odor.

    3. Sodf umHypochl.or ite CNaCCl)., manufactured by electrolysis of brines.Pr oduce s an aIkalLne sodium hypochlorite solution containing either3-5% or 10 - 16%by weight of available'chlorine. 'Practical,y1old-1 Ib , chlorine from 8 pounds ,NaC12'using up, to 400,,:,500 ampere - hr s,70-90% effective. Maybe purchased from'manufacturet'or made.direct-ly at pl ants, latter method seldom used now. .Available only forlarge plants which prefer'liquid chlorine. GQO~ '1cii isolated regionwith cheap elettric power. Application of dilutlon is by solutionfeeders~ Advaptages are: simple'dosing equipmentl no sludge, 'hfgh inert per cent aqe but it cannot be,' shipped far economicallyand loses strength when storede

    also yiel~s sludgenot so hygroscopic as bleaching powder~dry feed difficult ~ltho~gh practicable.costs more but allows storage and higher strength per pound'and al so stabl.e, . .f

    (a)(b)(c)Cd)

    69

    .... -'

    ......~ ...........-~...-~~.-."'"" ...-.._'--

  • Chlorine Man:J} - Chlorine InstituteChlorine EGndbook - Diamond Alkali Co.

    Re rer enccs :

    (c) s~ronger bacterial effect.(d) longer periods of persistence of the bactericidal

    effect~(e) reduction of chlorine requirements.(f)' a reducing action which r ender s its effects in-

    dependent of the pre5ence of organic matter~(g) less irritation of the eyes and nose, resulting

    in its use in sWimr,lingpool s,(h) cperators, no lcnger fearing to overdose with

    chlorine, will feed an a~equate dose.(i) fre~dom fro~ dan]er of overdosage.

    71

    ..,!-.~~.~~~,. '-),:,""~~~-;:r.l:_!.~"~

    ", M_._ _.., __ ~ ,~ ~._. _ _ n.__. ~_~_.". __ -... _._- ~_ -._

  • Diffusion

    , '1. Temperature of the water.2. Saturation deficit or surplus of gas in water.3. {-irea of contact surface per unit volume of water.

    . .F, Factors .det ermi nt nq effecti veness or Aerators.::'

    . ,- .c .' _.,,- ,-.:-;"':

    Aeration is usually asso(}Aat~q ..\~.itt:PllrJfjic~t.ion. Somet.Imes aera-t?rs are placed only for psYc~H)~o9~CaL',ef~~c:t~.:::At"time,s ::it is jU5-t if l ed also for, no ct,her r eason+t.han to .enhance the attractivenessof the water treatment pl ant , .. ' .. .' ,.: .... ".,' \

    1. Oegree of under-saturaticn of water with respect to the gas, orsaturation deficit.

    2, Temperature.3. Extent of intermingling of water and g,a5j L, e., the extent to which

    int imat e contact ~is ach ieved and to which' immobile film~ are pre-vented at the ga,-watcr inter~aceQ .

    110 Total amount of solution depends on time .of cont.act ;

    E. Aesthetic Consideration:

    The concentration of gases in a liqUid will come to equilibriumwith the atmosphere w_ith which the liquid is in contact in a.ccordancewith Henry+s Law. : So that if a water containing gases is placed incont(lct with an atmosphere other than that with which it is in equi:-Libr ium, B"11 exch~:1ge of gases b~twce~ the wat er and the atmosphere nn..m:"':"i~tely starts and will ccnt inue unt il Eiquflibrium rs reached. '.l:'hesol ut ion may absorb or give up gases depending on whether it is super-saturat ed or under sat urut edo- SOLUBILITY THEOOY.

    D: Solution of G'a'B&s~i'" . .The rate at which a ga~ will be 'absorbed in water depends on the

    following factors:

    c. Theory of Aeration:

    (a) Inka(b) Simplex Brush

    \

    5. Others

    (a) Aero-mix(b) C::1'Irit ator(c) Diffusair(d) Others

    4. Proprietary Devices

    (a) Perforated pipes .(b) Diffusers(c) Air lift pumps.

    3. Injection Aerators - air blown into water} as bubbles.

    '!

    ',fiti!....-._._.'._-'_'---" ..~-..--...- .'._.,.,._-----_. __ .__ .._--_ ..__._...... _...,_ ....'....;;-;.............. :._,.

  • 74

    Reference:Taste & Cdor Control - Industrial themical Corporation_

    '.

  • (b) slow ao it at ion for 30 to cC minutes to a l Lowcomnl et ion .;

    I!

    '.~ ,.r, ' ... )

    (a) addition of softening and. coagulating -chemi cal s and followed :4.~!~by thorough mixing 'of the. chemicafs wi th water' .,'. , ... '.. '." .. ' ,. . ...

    It :.!

    i ~.

    ,;, ,

    1. Lime-Soda Pr oi.es s -- this precess ;CP,l}sj,Sts.;of the fo11owiI19,,,steps: " " ::i'~, '.\ .' .'.'"

    1. conservation of. spap.,2. reduction cf work~i~t~e laundry.3. prevention of' t.he Jor,mation' ot scales in steam bof l ers,4. p repar at ion of w'at,~r:\for domestic and industrial ~uses ~5. increases efficiencY; of:fi1iraiion~'" " '\ ;;., .' .":6. aids in the removal: of':C!;:: .8. improves the cook inq of foods and is, des ir ab l e for other, domestic

    Purposes ',', i-""';:i"":', .. : .: ...,,, . " . ' (:'1,9. increases the efficiency of'\i'~~i9!,,~,!.j}~tr,~Al\9tion When filtr.ation

    follows soft en inq, ... ',::,;-:'i,.;:/::>.';>-:. ," -. .' '".,\C, Two General methods Of

  • (h)

    (b)(c)(d)(e)(f)(g)

    high opcratInq. '..' .of the reo.u{r,~,d/eglifreedom -.from,tag ..,'~,"',""':,'r c.." ':r.';:;".:;,,,7.;,,.;.;, '.""freedom fromi,'.;j , ....'.J:""" ..,.'."low salt reqlii .avat Lab i l l t y.und ... ' , .dur ab i l ity ,to res is '.... , .. ' 're;wash~ng#freedom from the efJ~'9:t~" of! ...' , ' .

    (b) temporary storage to perrni t' discl~arg~'":i:-:t 0, the stream duringhigh-water period , , '. ?, i",'~:'!',; ~ ,the filling of depressions or "excavat ions , as old quarries.the eli scharge into the city sewer s ," throuqh 'the sewage treat-

    ment .pl ant , ' .' , .dr y i 111 the sludge and using it for liming, the so,il~reburning for, the production of Lime, i,use as a filler for paintsg

    . '3. Disposal of sludge 'accumulated in>the 'lime-soda> process:

    2. Types of Pl ant Oper at iom.

    (a) continuous type plant -~ continuous appligation of chemigalsduring. the hour the. plant is in operation>. ,The constructioncost is less than other type -- most municipal plants are .of this type,

    (b) Intermittent type - consists 'in ba tch or fill-and,..drawoperation in wooden, steel, :,'01' conc re t e tagl.cs';'pf any con ...venient shape, from wh Lch sludg~ ~s,'w~th~~:~wn eithe r; by.grc)Vity'in a conical (Irpyrami~.Fl~~~~.ap~d,:bottom or-bymechanicalsl,;;.capers from flat';';bottom;;ttqnks~:; " .

    (c) Conventional type' plant -,;. when;'ch~m!ca~'lyttrcated water .is.mixed andvs et t l ed in separate tanks;;:'P

  • G. ::':::::::: :: :::e:;:::5::g\;;!~;~~~~~~~;;'~::,(::,~;~ti:,. , .'1. sui table for t.urbfd;: C~li3Jype,a,te':) , , ;:'9I,;ior'W,a:t~r'where zeo If te cannot

    be used. " ,:,j;;,:;:;{"f;". 1;,,', ~i,W:Pi;;~;Jff)'i+':":~;?;,", "2. the effluent ccnt a Insi.I'o: er,i~i0 "s,o,lid.s/than" that from zeolite

    softening. '" ';>~>: ' "",">':i);;!::;1;:i;;~}!(\:1~;, > ,:'{,:'Y:;r

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