water quality

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Water Quality Dr. Partha Chattopadhyay Senior Principal Scientist CSIR-Institute of Minerals And Materials Technology Bhubaneswar 751 013

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Page 1: Water quality

Water Quality

Dr. Partha ChattopadhyaySenior Principal Scientist

CSIR-Institute of Minerals And Materials TechnologyBhubaneswar 751 013

Page 2: Water quality

Ppo

• Potable water is the water whose consumption would not affect health adversely

• Man’s requirement of water for drinking purposes is more important than any other of its use

• The mean daily intake of water by an individual is ~ 3.1% of the body wt.

• Availability of water free of bacteriological and chemical contamination is becoming challenging in major parts of India, particularly in rural are

What is water Quality

Page 3: Water quality

Water Quality Index

A water quality index provides a single number (like a grade) that expresses overall water quality at a certain location and time based on several water quality parameters

Objective

To turn complex water quality data into information that is understandable and useable by the public

Page 4: Water quality
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Drinking Water Quality Index (DWQI)

all parameters regardless of WHO designation

Source Water Quality Index (SWQI) health and microbial criteria only arsenic, boron, cadmium, chromium, copper, fluoride, lead, manganese, mercury, nitrate, nitrite, faecal coliforms

Acceptability Water Quality Index (AWQI) acceptability criteria only ammonia, chloride, iron, pH, sodium, sulphate, zinc

4X4 Rule: Each parameter that contributes to the index must be measured at least 4 times per year at stations that have measured a minimum of 4 parameters per year.Calculation of Global Water

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Analytical Report along with Drinking Water Specification, Bureau of Indian Standard (BIS) BIS 10500 : 1991

Sl.No. Characteristics Desirable Limit

Permissible Limit

1. Cloour (Hazen Unit) 5 5

2 Odour Unobjectionale Unobjectionale

3 Taste Agreeable

4. Turbidity, NTU 5 105. pH 6.5 – 8.5 6.5 –8.56. Total Hardness 300 6007. Iron 0.3 1.08. Chlorides 250 10009. Residual Free Chlorine 0.2 -10. Dissolved Solids 500 200011. Calcium 75 20012. Mn 0.05 1.513. Sulfate 0.10 0.314. Nitrate 200 40015. Fluoride 45 100

16. Mercury 1.0 1.5

17. Cadmium 0.001 No relaxation

18. Selenium 0.01 do

Page 10: Water quality

Analytical Report along with Drinking Water Specification, Bureau of Indian Standard (BIS) BIS 10500 : 1991

Unit mg/L or ppm*UK Drinking Water Regulation Act 1989

Sl.No. Characteristics Desirable Limit Permissible Limit

19. Arsenic 0.05No relaxation

20. Cyanide 0.05do

21. Lead 0.05do

22. Zinc 515

23. Chromium (VI) 0.05No relaxation

24. Alkalinity200 600

25. Aluminium 0.03

26. Boron 1.05

27. *Sodium

150.00--

28. *Potassium

12.029. Mineral Oil 0.01 0.03

Page 11: Water quality

Parameters Test sample, mg/L Max. permissible conc.(mg/L)

Calcium 2.0 (0.1 mEq/L)

Magnesium 4.0 (0.3 mEq/L)

Cu 0.1

Al 0.1

Zn 5.0

Sulphate 100

Nitrate 2.0

Fluoride 0.2

Potassium 8.0 (0.2 mEq/L)

Sodium 70.0 (3.0 mEq/L)

Hemodialysis Water (AAMI Standards)

Page 12: Water quality

Sl No. Parameters Test Results Max. Permissible Limit, mg/L

1. Organic 200

2. Inorganic(Total dissolved solids)

3000

3. Chloride 2000

4. Sulphate 400

5. pH 5.5 – 8.5

Water quality for construction BIS 3025

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TARGET

Page 14: Water quality

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Summary of targets for water quality parameters included in water quality index

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MONITORING

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Many factors affecting water quality

• Sedimentation

• Run off

• Erosion

• Dissolved Oxygen

• pH

• Temperature

• Decayed Organic Materials

• Pesticides

• Toxic and Hazardous Substances

• Oil, grease and chemicals

• Detergents

• Litter and rubbish

Page 19: Water quality

GUIDELINE

Page 20: Water quality

Some recommended alkalinity values

Industry and ProcessRecommended Maximum Total Alkalinity (in mg/L CaCO3)

Carbonated beverages 85

Food products (canning) 300

Fruit juice 100

Washing diapers 60

Pulp and paper making(ground-wood process) 150

Rayon manufacture 50

Tanning hides 135

Textile mill products 50-200

Petroleum refining 500

Page 21: Water quality

Water Quality Guidelines:

• Guidelines for Drinking–Water Quality:

The primary purpose of the Guidelines for Drinking–Water Quality is the

protection of the public health

• Adequate, safe and accessible supply must be available to all

• Access to safe drinking water is essential to health, a basic human right

and a component of effective policy for health protection

• Safe drinking water, as defined by the Guidelines, does not represent any

significant risk to health over a lifetime of consumption,

including different sensitivities that may occur between life stages

• UN General Assembly declared the period from 2005-2015

as the International Decade for Action, “water for life”

Page 22: Water quality

CSIR

Page 24: Water quality

Water Purification Technology Inventions by CSIR

Problem Solution by CSIR Tech

High arsenic •Ceramic membrane based As removal by CGCRI

•Adsorbent based As removal by NML

•As test kit (NEERI)High F •RO based CSCMRI

•Electrolytic defluoridation

High Fe •Ceramic based iron removal (CGCRI)•Hand pump attachable iron removal (NEERI)•Terafil (IMMT)•NEERI-Zar Potable water filter (NEERI)(

High saline(brine water in coastal area) Thin film composite (TFe)RO membrane based Tech (CMCRI)

Pathogen like bacteria and viruses Ultrafiltration membrane Tech (NCL)Hollow Fibre membrane Technology

Page 25: Water quality

NEERI-

Implementation status of key water Purification Technologies

Laboratory Technology produced and implemented

CSMCRI •Installed dozens of RO plants across the country•Installed 6 RO plants in Afganistan•Installed demonstration Solar powered /Animal power plants•Installed several plants in earth quake, cyclone and tsunami affected are

CSMCRI 20 arsenic and fluoride removal units set up using ion specific resin in West Bengal, Gujrat and Tamil Nadu

NCL Developed and transferred ultra filtration membrane based technology for water purification

IMMT •About 1 lakh Terafil filters installed under Bharat Nirman and Jalmani schemes•Installed hundreds of filters during floods in different parts of the country•Technology transferred to >100 entrepreneurs

NEERI •Developed NEERI-ZAR another type of instant water filter suitable for flooded areas•Developed hundreds of unit during different floods in the country•240 hand pump attachable iron removal plants installed in North Eastern states

NGRI •Technology on rain water harvesting and artificial recharge implemented in 3 villages in Chittoor district of AP•Technology on artificial recharge & recovery of surplus storm runoff in desert areas for use as drinking water source,Churu district of Rjasthan•Technology on drinking water self sufficiency for industry through rain water harvesting •Technology on interaction of lake water and ground water (5 lakes in Hyderabad)

CGCRI •28 COMMUNITY MODEL PLANTS set up in WB and North East states BASED ON CERAMIC MEMBRANE FOR As and Fe removal•Technology transferred to 7 private entrepreneurs

Page 26: Water quality

TETERATERAFIL FILTER CANDLE BY IMMT (RRL BHUBANESWAR)

Page 27: Water quality

Samples collected on …….

Odd nos. are raw water, Even are terafil filter productTH = Total hardness, measure of sum of concentration of calcium and magnesium expressed as

carbonate in mg/L (ppm)TDS = Total dissolved solids in mg/L (ppm)

BIS = Bureau of Indian Standard for drinking water (BIS 10500:1991)

Sl. No.

1 2 3 4 5 6 7 8 9 10 BIS LimitDesirable/Permissible

Ter. 7 nil 6 nil 8 nil 7 nil 8 5 /10 NTU

pH 5.55 6.63 5.53 6.84 5.63 6.97 5.63 6.68 5.64 6.71 6.5 to 8.5

TH 20 50 30 40 30 50 30 40 30 40 300 /600 mg/L

Fe 4.5 0.2 1.3 0.1 1.1 0.2 3.9 0.1 2.3 0.1 0.3 /1.0 mg/L

TDS 65 90 64 86 62 88 64 83 62 91 250 /2000 mg/L

Page 28: Water quality

Samples collected on ……….

Odd nos. are raw water, Even are terafil filter productTH = Total hardness, measure of sum of concentration of Ca and Mg expressed as carbonate in mg/L (ppm)TDS = Total dissolved solids in mg/L (ppm)BIS = Bureau of Indian Standard for drinking water

Sl. No.

1 2 3 4 5 6 7 8 9 10 BIS LimitDesirable/Permissible

Ter. 7 nil 6 nil 8 nil 7 nil 8 5 /10 NTU

pH 5.42 6.7 5.3 6.5 5.3 6.7 5.4 6.3 5.4 6.4 6.5 to 8.5

TH 20 50 30 40 30 50 30 40 30 40 300 /600 mg/L

Fe 4.5 0.2 1.3 0.1 1.1 0.2 3.9 0.1 2.3 0.1 0.3 /1.0 mg/L

TDS 65 90 64 86 62 88 64 83 62 91 250 /2000 mg/L

Page 29: Water quality

Samples collected on ……….

Odd nos. are raw water, Even are terafil filter productTH = Total hardness, measure of sum of concentration of calcium and magnesium expressed as carbonate in mg/L (ppm)TDS = Total dissolved solids in mg/L (ppm)BIS = Bureau of Indian Standard for drinking water

Sl. No.

1 2 3 4 5 6 7 8 9 10 BIS LimitDesirable/Permissible

Ter. 6 nil 6 nil 8 nil 7 nil 7 nil 5 /10 NTU

pH 5.59 6.91 5.61 6.78 5.58 6.66 5.64 6.93 5.68 6.87 6.5 to 8.5

TH 12.5 26.5 10.0 30.0 15.0 30.0 12.5 37.5 17.5 32.5 300 /600 mg/L

Fe 1.2 <0.1 1.1 <0.1 1.3 <0.1 0.79 <0.1 1.3 <0.1 0.3 /1.0 mg/L

TDS 78.3 122 78.1 118 78 113 81 136 78 118 250 /2000 mg/L

Page 30: Water quality

pH change of raw water

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Effect of total hardness (mg/L) from raw water by passing through terafil

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Removal of iron (mg/L) from raw water by passing through terafil

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B (5.9.07)

D (29.11.07)

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Conclusion:

• Raw water is acidic, high iron and low calcium – magnesium concentration

• Terafil filter water improves the water quality by decreasing acidity

• Total hardness increases significantly with the rise in concentration of

both Ca and Mg

• Raw water tested so far contain well above the permissible limit for iron

• Terafil product brings down to much below the desired limit

Page 34: Water quality