wastewater discharge monitoring report · pdf file... wastewater discharge monitoring report...

380 Harvey Road Manchester New Hampshire 03103-3347 603-623-3600 FAX 603-624-9463 wwwgzacom

Engineers andIOZA GeoEnvironmental Inc Scientists

VIA EMAIL

February 9 2012 File No 04002930700

Ms Nancy Lesieur Industrial Pretreatment Coordinator Winnipesaukee River Basin Program Wastewater Treatment Plant Water Division New Hampshire Department ofEnvironmental Services 528 River Street Franklin New Hampshire 03235

Re Wastewater Discharge Monitoring Report Treated Wastewater Merrimack Station Public Service ofNew Hampshire Bow New Hampshire

Dear Ms Lesieur

On behalfofPublic Service ofNew Hampshire (PSNH) GZA GeoEnvironmental Inc is pleased to submit the attached Wastewater Discharge Monitoring Report for sampling conducted on January 26 2012 as requested to supplement the initial sampling requirements as outlined in Special Agreement -PSNHand WRBP Wastewater Treatment Plant

The attached Table 1 summarizes the analytical results for all required parameters as outlined in the tenns of the Special Agreement The attached Analytical Data Report however contains a more comprehensive list ofparameters

ANALYTICAL DISCUSSION

Flue Gas Desulfurization (FGD) wastewater requires specialized analytical techniques to overcome matrix interference for certain analysis oftrace metals To assist you in evaluating this issue further we offer an excerpt below from the United States Environmental Protection Agency (EPA) web site and a link to their draft Standard Operating Procedure (SOP) for trace metals analysis ofFGD wastewater that contains further guidance

LABORATORY ANALYSIS OF FGD WASTEWATER

Wastewater from FGD systems can contain constituents known to cause matrix interferences EPA has observed that during inductively coupled plasma - mass spectrometry (ICP-MS) analysis of FGD wastewater certain elements commonly present in the wastewater may cause polyatomic interferences that bias the detection andor quantization of certain elements of interest These potential interferences may become significant when measuring trace elements at concentrations in the low parts-per-billion range

Copyright ~ 2012 GZA Geo Environmental Inc

An Equal Opportunity Employer MFNH

Winnipesaukee River Basin Program Wastewater Treatment Plant File No 04002930700

February 9 2012 Page2

As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses ofFGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater

EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis ofFGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOP For further information see

Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) httpwaterepagovscitechwastetechguideluploadlsteam_draft_soppdf EPAMay20ll

Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FOO wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater

Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744

Very truly yours

GZA GEOENVIRONMENT AL INC

Ronald A Breton P E Principal

RABmm P04Job$0029300s04002930700IWorlcSAMPLING ANO REPORTINGREPORTSFranklinFINAL 040029307 Franklin DATA RPT 020912doa

Attachments Wastewater Discharge Monitoring Report Analytical Data Report

WASTEWATER DISCHARGE MONITORING REPORT

-------------------

WASTEWATER DISCHARGE MONITORING REPORT WINNIPESAUKEE RIVER BASIN PROGRAM

WASTEWATER TREATMENT PLANT

Public Service ofNew Hampshire - Merrimack Station Special Agreement - PSNH and WRBP Wastewater Discharge Request

Dated 9282011

Permitted Flow 25000 gallons per day

FLOW DATA

Daily Flow Rate (gallons) __O_ _(_av_e_rag_e_)---------- shyMonitoring Period Flow (gallons) 0

NOTE Discharge to WRBP Treatment Plant commenced after the 12612 sampling event

PJ)4JobsOOJ9300s04002930700WorkISAMPUN(j AND REPORTThlODATA04002930700 RESULTS 020812xlsxfranklin Reprt Co-middotlaquo

----------------------

---- ------------------

-----------

FAClllTY INFORMATION

Company Name Public Service Company ofNew Hampshire - Merrimack Station Company Owner Public Service Company ofNew Hampshire Facility Address 97 River Road _____________________Facility Contact Harold Keyes

Telephone (603) 224-4081

MONITORING REPORT Submittal Date 292012--------------- - - ------shyMonitoring Point End of treatment process

Reporting Period First Month

SAMPLE ANALYSIS Certified Analytical Laboratory Eastern Analytical Inc (EAi) Certification Number 1012

Authorized Representative Lorraine Olashaw Analytical Subcrontractor Frontier Global Sciences Certification Number E87575

SAMPLE COLLECTION Sampler JeffGagne (EAi)

Sample Type Grab -------- - - shySam p 1 e Date 1262012 Sample Time 1000 AM------------ shypH 76

CATEGORICAL PRETREATMENT STANDARDS 40 CFR 42316 Steam Electric Power Generating Category NOTE There are no numerical pretreatment standards for this source

CERTIFICATION STATEMENT

I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with asystem designed to assure that qualified personnel properly gather and evaluate the information

submitted Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information the information submitted Is to the best of my knowledge and belief true accurate and

complete I am aware that there are significant penalties for submitting false information including the possibility of fine and imprisonment for knowing violationsbull

Harold Keyes StationManager Pinted Name ofAuthorized Representative Title

SUMMARY ANALYTICAL DATA Treated FGD Wastewater

Public Service Company ofNew Hampshire Merrimack Station

Bow New Hampshire

RESULTS

PARAMETER (mgL)

01262012 EAiFrontier

Aluminum lt 0080

Arsenic 000956

Cadmium 0000587 Chloride 9500 Chromium (T) lt 000200 Copper 000261 Cyanide (T) 001

Iron lt 0200

Lead lt 0000800 Manganese 0349

Mercury 00000122

Molybdenum 0373 ~ ickel 000776

Selenium 0104

Silver lt 0000400 Zinc lt 000400

GZA GeoEnvironmental Inc P04Jobs0029300sl04002930700WorlcSAMPUNO AND REPORTTNODATA04002930700 RESULTS 020812xlsxFRANKLIN Ml round 2

ANALYTICAL DATA REPORT

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middotmiddot-_~1-----------~-~-~-~e-(middot-~- _a_n_a_l_y_~i-c-a_l__

Paul Pepler

GZA GeoEnvironmental Inc (NH)

380 Harvey Road

Manchester NH 03103

Subject Laboratory Report

Eastern Analytical Inc ID 107170

Client Identification Wastewater Analysis - Weekly

Date Received 1262012

Dear Mr Pepler

Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QAQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters

The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on adry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery

Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)

The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory

If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date

We appreciate this opportunity to be of service and look forward to your continued patronage

Sincerely

ZmiddotB-12- Date

3S Lorraine Olashaw Lab Director of pages (excluding cover letter)

SAMPLE CONDITIONS PAGE EAi ID 107170

Client GZA GeoEnvironmental Inc (NH)

Client Designation Wastewater Analysis - Weekly

Temperature upon receipt (degC) 45 Received on Ice or cold packs (YesNo) y Acceptable temperature range C) 0-6

Date Date Sample Ory Lab ID Sample ID Received Sampled Matrix Weight ExceptlonslComments (other than thermal preservation)

10717001 Effluent Field Blank 12612 12612 aqueous Adheres to Sample Acceptance Policy

10717002 Treat Tank Effluent 12612 12612 aqueous Adheres to Sample Acceptance Policy

Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint lgnitibility Paint Fiffer Corrosivity Conductivity and Specific Gravity are reported on an as received basis

All resuffs contained in this report relate only to the above fisted samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater fnorganics 19th Edition 1995 Microbiology 2oth Edition 1998 3) Test Methods for Evaluating Solid Waste SW846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992

eastern analytical inc wwweaifabscom Phone (603) 228-0525 1

LABORATORY REPORT EAi ID 107170



Sample ID

Lab Sample ID Matrix

Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor

Chloromethane Vinyl chloride Bromomethane Chloroethane Trichlorofluoromethane Acrolein Acetone 1 1-Dichloroethene Methylene chloride Carbon disulfide Acrylonitrile Methyl-t-butyl ether(MTBE) trans-12-Dichloroethene Vinyl acetate 1 1-Dichloroethane cis-1 2-Dichloroethene 2-Butanone(MEK) Chloroform 1 1 1-Trichloroethane Carbon tetrachloride Benzene 12-Dichloroethane T ricMoroethene 12-Dichloropropane Bromodichloromethane 2-Chloroethylvtnylether 4-Methyl-2-pentanone(MIBK) cis-13-Dichloropropene Toluene trans-13-Dichloropropene 112-Trichloroethane 2-Hexanone Tetrachloroethene Dibromochloromethane Chlorobenzene Ethyl benzene mp-Xylene a-Xylene Styrene Bromoform 1 122-Tetrachloroethane 13-Dichlorobenzene 14-Dichlorobenzene 12-Dichlorobenzene 4-Bromofluorobenzene (surr) 12-Dichlorobenzene-d4 (surr) Toluene-dB (surr)

Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2

lt10 lt2 lt2 lt2 lt 1 lt2 lt2 lt2 lt2 lt2

lt 10 lt2

2 lt2 lt2

lt 10 lt2 lt2 lt2 lt 1 lt 1 lt 1 lt 1 lt2 lt2 lt 1 lt 1 lt 1

93R 106oR

99R

eastern analytical inc wwweailabscom Phone (603) 228-0525 2

QC REPORT EAi ID 107170

Client GZA GeoEnvlronmental Inc (NH)


Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO Method

Chloromethane lt5 22(110R) 22 (108 R) (2 RPO) 1272012 ug1 0- 273 20 624

Vinyl chloride lt2 20 (99 R) 19 (94 R) (5 RPO) 1272012 ug1 0 - 251 20 624

Bromomethane lt2 21 (106 R) 21 (103 R) (3 RPO) 1272012 ug1 0-242 20 624

Chloroethane lt5 26 (129 R) 25 (123 R) (5 RPO) 1272012 ug1 14 - 230 20 624

Trichlorofluoromethane lt5 25 (124 R) 23 (116 R) (7 RPO) 1272012 ug1 17 - 181 20 624

Acrolein lt 50 lt 50 (RNA) lt 50 (RNA) (RPO NIA) 1272012 ug1 624

Acetone lt 50 lt SO (100R) lt 50 (97 ooR) (3 RPO) 1272012 ug1 624

1 1-Dichloroethene lt 1 24 (122 R) 23 (115 R) (6 RPO) 1272012 ug1 0 - 234 20 624

Methylene chloride lt5 26 (129 R) 25 (126 R) (2 RPO) 1272012 ug1 0- 221 20 624

Carbon disulfide ltS 22 ( R) 22 ( R) ( RPO) 1272012 ug1 624

Acrylonltrlle lt 50 lt 50 ( R) lt 50 ( R) ( RPO) 1272012 ug1 624

Methyl-t-butyl ether(MTBE) lt10 20 ( R) 20 ( R) ( RPO) 1272012 ug1 624

trans-12-0ichloroethene lt2 25 (124 R) 24 (121 R) (2 RPO 1272012 ug1 54 - 156 20 624

Vinyl acetate lt 10 30 ( ooR) 30 ( R) ( RPO) 1272012 ug1 624

1 1-0ichloroethane lt2 24 (118 ooR) 23 (113 ooR) (4 RPO 1272012 ug1 59 - 155 20 624

cis-12-Dichloroethene lt2 22 ( R) 21 ( ooR) ( RPO) 1272012 ug1 624

2-Butanone(MEK) lt10 20 ( R) 20 ( R) ( RPO 1272012 ug1 624

Chloroform lt2 22 (109 R) 21 (106 R) (3 RPO) 1272012 ug1 51 - 138 20 624

111-Trichloroethane lt2 23 (115 R) 22 (1 10 R) (4 RPO) 1272012 ug1 52 - 162 20 624

Carbon tetrachloride lt2 26 (132 ooR) 26 (129 R) (2 RPO) 1272012 ug1 70-140 20 624

Benzene lt1 22 (110 R) 21 (107 R) (3 RPO) 1272012 ug1 37 - 151 20 624

12-Dichloroethane lt2 21 (103 ooR) 20 (99 R) (4 RPO) 1272012 ug1 49 - 155 20 624

Trichloroethane lt2 21 (105 R) 20 (101 R) (4 RPO) 1272012 ug1 71 shy 157 20 624

12-Dlchloropropane lt2 21 (105 R) 21 (103 R) (2 RPO) 1272012 ug1 0- 210 20 624

Bromodichloromethane lt2 21 (104R) 20 (101 R) (3 RPO) 1272012 ug1 35- 155 20 624

2-Chloroethylvinylether lt2 lt 2 (RNA) lt 2 (R NA) (RPO NIA) 1272012 ug1 0- 305 20 624

4-Methyl-2-pentanone(MIBK) lt 10 20 ( R) 20 ( R) ( RPO) 1272012 ug1 624 cis-1 3-Dichloropropene lt2 20 (102 R) 20 (102 R) (0 RPO) 1272012 ug1 0 bull 227 20 624

Toluene lt 1 22 (109 R) 21 (106 R) (3 RPO) 1272012 ug1 47 bull 150 20 624

trans-13-0ichloropropene lt2 21 (103 R) 20 (101 R) (2 RPO) 1272012 ug1 17 - 183 20 624 1 12-Trichloroethane lt2 23 (113 R) 22 (109 R) (4 RPO) 1272012 ug1 52 - 150 20 624 2-Hexanone lt 10 20 ( R) 20 ( R) ( RPO) 1272012 ug1 624 Tetrachloroethene lt2 24 (120 R) 23 (116 R) (3 RPO) 1272012 ug1 64 - 148 20 624 Oibromochloromelhane lt2 24 (118 R) 23 (115 R) (3 RPO) 1272012 ug1 53 - 149 20 624 Chlorobenzene lt 2 22 (111 R) 22 (108 ooR) (3 RPO) 1272012 ug1 37 - 160 20 624 Ethylbenzene lt 1 23 (113 R) 22 (110 R) (3 RPO) 1272012 ug1 37 - 162 20 624 mp-Xylene lt 1 47 (117 R) 45 (112 R) (4 RPO) 1272012 ug1 70-130 20 624 o-Xylene lt1 23 (115 R) 22 (109 R) (5 RPO) 1272012 ug1 70-130 20 624 Styrene lt 1 23 ( R) 22 ( ooR) ( RPO) 1272012 ug1 624 Bromofonn lt2 25 (125R) 25 (123 R) (2 RPO) 1272012 ug1 45- 169 20 624 1 122-Tetrachloroethane lt2 20 (101 R) 20 (100 R) (1 RPO) 1272012 ug1 46 - 157 20 624 13-Dichlorobenzene lt 1 22 (110 R) 21 (106 R) (4 RPO) 1272012 ug1 59 - 156 20 624 14-Dichlorobenzene lt1 22 (108 R) 21 (107 R) (1 RPO) 1272012 ug1 18 - 190 20 624 12-0ichlorobenzene lt1 21 (105 R) 21 (104 R) (1 RPO) 1272012 ug1 18 - 190 20 624 4-Bromoiluorobenzene (surr) 93R 99R 102R 1272012 Rec 70 - 130 624

eastern analytical inc 1vwweailabscom Phone (603) 228-0525 3

bull QC REPORT EAi ID 107170



Parameter Name Blank LCS LCSO Analysis Cate Units Limits RPO Method

12-Dichlorobenzene-d4 (surr) 103R 99R 99R 1272012 Rec 70-130 624 Toluene-dB (surr) 99R 101 R 100R 1272012 Rec 70-130 624

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andof laboratory Control Samples met acceptance-criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits Any impact to data is addressed below



Client GZA GeoEnvironrnental Inc (NH) Client Designation Wastewater Analysis - Weekly

Sample ID


Date Sampled Date Received

Units

Date of ExtractionPreparation

Date of Analysis

Analyst

Method

Dilution Factor

Phenol 2-Chlorophenol 24-Dichlorophenol 245-Trichforophenol 246-Trichlorophenol Pentachlorophenol 2-Nitrophenol 4-Nitrophenol 24-Dinitrophenol 2-Methylphenol 34-Methylphenol 24-Dimethylphenol 4-Chloro-3-methylphenol 46-Dinitro-2-methylphenol Benzoic Acid N-Nitrosodimethylamine n-Nitroso-di-n-propylamine n-Nitrosodiphenylamlne bis(2-Chloroethyl)ether bis(2-chforoisopropyl)ether bis(2-Chloroethoxy)methane 13-Dichforobenzene 14-Dichforobenzene 12-Dfchlorobenzene 124-Trichlorobenzene 2-Chloronaphthalene 4-Chlorophenyl-phenylether 4-Bromophenyl-phenylether Hexachloroethane Hexachlorobutadiene Hexachforocycfopentadiene Hexachlorobenzene 4-Chloroaniline 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Benzyl alcohol Nitrobenzene fsophorone 24-0lnitrotoluene 26-0initrotofuene Benzidine (estimated) 33-Dichlorobenzidine Pyridine Azobenzene

Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1

lt 1 lt 1 lt 1 lt 1 lt 1 lt5 lt 1 lt5 lt5 lt 1 lt 1 lt 1 lt 1 lt5

lt 50 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt 1 lt1 lt5 lt 1 lt 1 lt5 lt 1 lt 1 lt5 lt 1 lt 1 lt 1 lt 1 lt5 lt 1 lt5 lt 1

eastern analytical inc wwweaiabscom Phone (603) 228-0525 5

i



Client Designation Wastewater Analysrs - Weekly

Samp11e ID Treat Tank Effluent

Lab Sample ID 10717002

Matrix aqueous

Date Sampled 12612 Date Received 12612

Units ug1

Date of ExtractionPreparation 12712

Date of Analysis 1 3012

Analyst JMR Method 625mod

DIiution Factor 1

Carbazole lt 1 Dimethylphthalate lt1

Di-n-butylphthalate lt5

Phenol-d6 (surr) 29R

Diethylphthalate lt 1

Butylbenzylphthalate lt 1 bis(2-Ethylhexyl)phthalate lt5 Di-n-octylphthalate lt 1 Oibenzofuran lt 1 Naphthalene lt 1 2-Methylnaphthalene lt 1 Acenaphthylene lt 1 Acenaphthene lt 1 Fluorene lt 1 Phenanthrene lt 1 Anthracene lt 1 Fluoranthene lt 1 Pyrene lt 1 Benzo[aJanthracene lt 1 Chrysene lt 1 Benzo[b]fluoranthene lt 1 Benzo[k]fluoranthene lt 1 Benzo[a]pyrene lt 1 lndeno[123-cd]pyrene lt 1 Dibenz[ahjanthracene lt 1 Benzo[ghi]perylene lt 1 2-Fluorophenol (surr) 40R

246--Tribromophenol (surr) 79R Nitrobenzene-D5 (surr) 81 R 2-Fluorobiphenyt (surr) 81 R p-Terphenyl-D14 (surr) 92R

middotbull eastern analytical inc wwweaifabscom Phone (603) 228-0525 6


Client GZA GeoEnvironmental Inc (NH) Batch ID 734529-39483A012712ABN1 Client Designation Wastewater Analysis - Weekly

Parameter Name Blank LCS LCSD Analysis Date Units Limits RPO

20

Method

625mod Phenol lt 1 15 (30 R) 15 (30 R) (0 RPO) 1302012 ug1 15 -130 2-Chlorophenol lt 1 30 (61 R) 31 (61 R) (0 RPO) 1302012 ug1 30 - 130 20 625mod 24-Dichlorophenol lt 1 36 (72 R) 36 (73 R) (1 RPO) 1302012 ug1 30 - 130 20 625mod 245-Trichlorophenol lt 1 21 (85 R) 21 (84 R) (1 RPO) 1302012 ug1 30- 130 20 625mod 246-Trichlorophenol lt 1 38 (76 R) 37 (75 R) (1 RPO) 1302012 ug1 30 - 130 20 625mod Pentachlorophenol lt5 49 (97R) 46 (93 R) (4 RPO) 1302012 ug1 30-130 20 625mod 2-Nitrophenol lt 1 36 (73 R) 36 (72 R) (1 RPO) 1302012 ug1 30 - 130 20 625mod 4-Nitrophenol lt5 16 (33 R) 18 (36 R) (9 RPD) 1302012 ug1 15 - 130 20 625mod 24-Dinltrophenol lt5 38 (76 R) 41 (83 R) (9 RPO) 1302012 ug1 15- 130 20 625mod 2-Methylphenol lt 1 16 (64 R) 16 (65 R) (2 RPO) 1302012 ug1 30 -130 20 625mod 34-Methylphenol lt 1 14 (55 R) 14 (56 R) (2 RPO) 1302012 ug1 30-130 20 625mod 24-Dimethylphenol lt 1 34 (67 R) 33 (67 R) (0 RPO) 1302012 ug1 30- 130 20 625mod 4-Chloro-3-methylphenol lt 1 39 (77 R) 40 (79 R) (3 RPO) 1302012 ug1 30- 130 20 625mod 46-Dinitro-2-methytphenol lt5 44 (89 R) 48 (95 R) (7 RPO) 1302012 ug1 30 - 130 20 625mod Benzoic Acid lt50 lt 50 (33 R) lt 50 (35 ooR) (6 RPO) 1302012 ug1 15 - 140 20 625mod N-Nitrosodimethylamine lt 1 14 (55 R) 13 (51 R) (8 RPO) 1302012 ug1 40- 140 20 625mod n-Nitroso-dl-n-propylamlne lt 1 19 (76 R) 18 (73 R) (4 RPO) 1302012 ug1 40-140 20 625mod n-Nltrosodiphenylamlne lt 1 25 (101 R) 25 (100 R) (1 RPO) 1302012 ug1 40- 140 20 625mod bis(2-Chloroethyl)ether lt 1 17 (67 R) 17 (67 R) (0 RPO) 1302012 ug1 40- 140 20 625mod bis(2-chlorolsopropyl)ether lt 1 17 (70 R) 17 (69 R) (1 RPO) 1302012 ug1 40-140 20 625mod bis(2-Chloroethoxy)methane lt 1 18 (72 R) 17 (70 R) (3 RPO) 1302012 ug1 40- 140 20 625mod 1 3-Dichlorobenzene lt 1 15 (59 R) 14 (54 R) (9 RPO) 1302012 ug1 40-140 20 625mod 1 4-Dichlorobenzene lt 1 15 (59 R) 14 (55 R) (7 RPO) 1302012 ug1 40-140 20 625mod 12-Dlchlorobenzene lt 1 15 (60 ooR) 14 (56 R) (7 RPO) 1302012 ug1 40-140 20 625mod 124-Trichtorobenzene lt 1 16 (65 R) 15 (61 R) (6 RPO) 1302012 ug1 40-140 20 625mod 2-Chloronaphthalene lt 1 18 (73 R) 18 (71 R) (3 RPO) 1302012 ug1 40-140 20 625mod 4-Chlorophenyl-phenylether lt 1 20 (79 R) 20 (80 R) (1 RPO) 1302012 ug1 40 - 140 20 625mod 4-Bromophenyl-phenylether lt 1 21 (84 R) 21 84 ooR) (0 RPO) 1302012 ug1 40-140 20 625mod Hexachloroethane lt 1 13 (54 R) 13 (51 R) (6 RPD) 1302012 ug1 40- 140 20 625mod Hexachlorobutadiene lt 1 15 (61 R) 14 (56 R) (9 RPO) 1302012 ug1 40- 140 20 625mod Hexach lorocyclopentadiene lt5 12 (49 ooR) 11 (45 R) (9 RPO) 1302012 ug1 40-140 20 625mod Hexach lorobenzene lt 1 22 (88 R) 20 (82 R) (7 RPO) 1302012 ug1 40 - 140 20 625mod 4-Chloroaniline lt 1 20 (82 R) 20 (81 R) (1 RPO) 1302012 ug1 15 - 140 20 625mod 2-Nitroaniline lt5 19 77R) 20 (79 R) (3 RPO) 1302012 ug1 40- 140 20 625mod 3-Nitroaniline lt 1 20 (79 R) 20 (82 R) (4 RPO) 1302012 ug1 40 -140 20 625mod 4-Nitroaniine lt 1 19 (74middotR) 22 (88 R) (17 RPO) 1302012 ug1 40-140 20 625mod Benzyl alcohol lt5 17 (70 R) 17 (69 R) (1 RPO) 1302012 ug1 40-140 20 625mod Nitrobenzene lt 1 18 (71 R) 18 (71 R) (0 RPO) 1302012 ug1 40-140 20 625mod lsophorone lt 1 22 (86 R) 21 (84 R) (2 RPO) 1302012 ug1 40-140 20 65mod 24-Dinitrotouene lt 1 22 (88 R) 23 (92 R) (4 RPO) 1302012 ug1 40-140 20 625mod 26-Dinitrotoluene lt 1 21 (82 R) 21 (85 R) (4 RPO) 1302012 ug1 40 140 20 625mod Benzidine (estimated) lt5 19 (76 R) 10 (39 R) (64 RPO) 1302012 ug1 15 - 168 20 625mod 33-Dichlorobenzidine lt 1 22 (87 R) 22 88 R) 1 RPO) 1302012 ug1 40 - 140 20 625mod Pyridine lt5 14 (54 R) 12 (48 R) (12 RPO) 1302012 ug1 40 - 140 20 625mod Azobenzene lt 1 21 (82 R) 20 (82 R) (0 RPO) 1302012 UQ1 40- 140 20 625mod


QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1

Parameter Name Blank LCS LCSO Analysis Date Units Limits RPO Method

CarbazoJe lt 1 22 (87 R) 22 (90 ooR) (3 RPD) 1302012 ug1 40 - 140 20 625mod Dimethylphthalate lt 1 20 (80 R) 20 (82 ooR) (2 RPD) 1302012 ug1 40-140 20 625mod Oiethylphthalate lt 1 21 (82 R) 21 (85 R) (4 RPD) 1302012 ug1 40 - 140 20 625mod Di-n-butylphthalate lt5 22 (87 R) 22 (89 R) (2 RPD 1302012 ug1 40 - 140 20 625mod Butylbenzylphthalate lt 1 21 (85 R) 22 (88 ~) (3 RPD) 1302012 ug1 40-140 20 625mod bls(2-Ethylhexyl)phthalate lt 5 21 (86 R) 22 (89 R) (3 RPO) 1302012 ug1 40 - 140 20 625mod Di-n-octylphthalate lt 1 21 (85 R) 22 (89 R) (5 RPO) 1302012 ug1 40 - 140 20 625mod Dlbenzofuran lt 1 19 (75 R) 19 (74 R) (1 RPD) 1302012 ug1 40 - 140 20 625mod Naphthalene lt 1 19 (77 R) 18 (74 R) (4 RPD) 1302012 ug1 40-140 20 625mod 2-Methyl naphthalene lt 1 18 71 R) 17 (69 ooR) (3 RPO) 1302012 ug1 40 - 140 20 625mod Acenaphthylene lt 1 19 (76 R) 19 (74 R) (3 RPO) 1302012 ug1 40 -140 20 625mod Acenaphthene lt 1 20 (81 R) 20 (80 ooR) (1 RPO) 1302012 ug1 40 - 140 20 625mod Fluorene lt 1 21 (83 R) 21 (83 R (0 RPO) 1302012 ug1 40 - 140 20 625mod Phenanthrene lt 1 22 (86 R) 22 (86 R) (0 RPO) 1302012 ug1 40-140 20 625mod Anthracene lt 1 21 (85 R) 22 (87 R) (2 RPO) 1302012 ug1 40 - 140 20 625mod Fluoranthene lt 1 22 86 R) 22 (88 R) (2 RPD) 1302012 ug1 40 - 140 20 625mod Pyrene lt 1 20 (82 R) 21 (83 R) (1 RPO) 1302012 ug1 40 -140 20 625mod Benzo[a]anthracene lt 1 21 (84 R) 22 (86 R) (2 RPD) 1302012 ug1 40 -140 20 625rnod Chrysene lt1 22 (87 R) 22 (87 R) (0 RPO) 1302012 ug1 40 - 140 20 625mod Benzo(b ]fluoranthene lt 1 20 (81 R) 21 (83 R) (2 RPO) 1302012 ug1 40 - 140 20 625mod Benzo[k]fluoranthene lt 1 22 (90 R) 22 (89 R) (1 RPO) 1302012 ug1 40 - 140 20 625mod Benzo[aJpyrene lt1 21 (83 R) 21 (84 R) (1 RPO) 1302012 ug1 40 - 140 20 625rnod lndeno[123-cd]pyrene lt 1 21 (86 R) 22 (87 R) (1 RPO) 1302012 ug1 40 - 140 20 625mod Dibenz[ah]anthracene lt 1 23 (91 R) 23 (92 R) (1 RPO) 1302012 ug1 40 - 140 20 625mod Benzo[ghi]perylene lt 1 22 (89R) 22 (88 R) (1 RPD) 1302012 ug1 40 - 140 20 625mod 2-Fluorophenol (surr 42 R 41 R 40R 1302012 Rec 21 - 110 20 625mod Phenol-d6 (surr) 29R 30R 30R 1302012 Rec 15 - 94 20 625mod 246-Tribromophenol (surr) 76R 93 R 95R 1302012 Rec 15 - 110 20 625mod Nitrobenzene-05 (surr) 80R 79R 78R 1302012 Rec 35 - 114 20 625mod 2-Fluorobiphenyl (surr) 86R 81 R 77R 1302012 Rec 43 - 116 20 625mod p-Terphenyl-014 (surr) 92 R 97R 95R 1302012 Rec 33 -130 20 625mod

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits sect_iIEe ~rrog~te r~coveries m_~the__bove secttat~d~rite_~ _ The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted Flagged analyte recoveries deviated from the QAQC limits




Client Designation Wastewater Analysis Weekly

Sample ID

Lab Sample ID

Matrix


Units

Date of ExtractionPrep

Date of Analysis

Analyst

Method

Dilution Factor

Oil amp Grease (HEM)

Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5

eastern analytical inc www eaiabs com Phone (603) 228-0525 9


Client GZA GeoEnvironmental Inc (NH) Batch ID 734532-40799A0130120G1661



Oil amp Grease (HEM) lt5 37 (92 R) 36(90R)(2RPD) 1302012 mgL 78-114 18 1664A

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted I Flagged analyte recoveries deviated from the QAQC limits





Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221

PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 TMX (surr) DCB (surr)

Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R

eastern analytical inc wwweailabscom Phone (603) 228-0525

11

QC REPORT EAi ID 10717011AA Client GZA GeoEnvironmental Inc (NH) Batch ID 734529-35119A012712E608P2



PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608

PCB-1221 lt03 lt 03 (R NIA) lt 03 (R NA) (RPD NIA) 12712012 ug1 608

PCB-1232 lt03 lt 03 (R NIA) lt 03 (R NA) (RPO NA) 1272012 ug1 608

PCB-1242 lt 03 lt 03 (R NIA) lt 03 (R NIA) (RPD NIA) 1272012 ug1 608

PCB-1248 lt 03 lt 03 (R NA) lt 03 (R NA) (RPO NIA) 1272012 ug1 608

PCB-1254 lt 03 lt 03 (RNA) lt 03 (RNA) (RPO NA) 1272012 ug1 608

PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)

Samples were extracted and analyzed within holding time limits Instrumentation was calibrated in accordance with the method requirements The method blanks were free ofcontamination at the reporting limits Sample surrogate recoveries met the above stated criteria The associated matrix spikes andor Laboratory Control Samples met acceptance criteria There were no exceptions in the analyses unless noted I Flagged analyte recoveries deviated from the QNQC limits


Ill LABORATORY REPORT EAi ID 107170



-middot---middot--- ~ Sample ID Treat Tank Effluent


Matrix aqueous AnalysisDate Sampled 12612

Units Date Time Mettlod Analyst 12612Date Received

Fluoride 62 mgL 20112 1335 3000 KL Chloride 9500 mgL 13012 1333 4500CIE DLS Nitrate-N 68 mgL 12712 915 3532 DLS Cyanide Total 001 mgL 13112 915 4500CNE KJR Ammonia-N 12 mgl 113012 1515 4500NH3D SEL BOD lt6 mgL 12712 1730 52108 SKC COD 180 mgL 20212 1615 H8000 SKC Total Phenols lt 05 mgL 131112 900 4201 JCC pH 76 SU 12712 1556 4500H+B SEL

Total Phenols The reporting limit has been elevated due to matrix interference

Cyanide Cyanide was re-analyzed on 2820121 per client request The re-analysis confirmed the cyanide hit A matrix spikematrix spike duplicate performed on this sample had acceptable recoveries

eastern analytical inc wwweailabscom Phone (603) 228-0525 1 3

QC REPORT EAi ID 107170ltuul Client GZA GeoEnvlronmental Inc (NH)


Date of

LCSD Units Analysis Limits RPD MethodParameter Name Blank LCS --middot~----middotmiddot-middot---middot--- middotmiddot-middotmiddotmiddot - ------ -middot----middotmiddot-~---middot---- ----middot- -middot--middotmiddotmiddot--- _

Fluoride lt 01 20 (101 R) 20 (101 R) (0 RPD)middot mgL 13112 90 - 110 20 3000

Chloride lt 1 26 (102 R) 25 (101 R) (1 RPO) mgL 13012 90 - 110 20 4500ClE

Nitrate-N lt 05 51 (103 R) 52 (103 R) (0 RPD) mgL 12712 90 -110 20 3532

Cyanide Total lt 001 022 (89 R) mgL 13112 85 - 115 20 4500CNE

Ammonia-N lt 005 21 (104 R) 22 (109 R) (5 RPO) mgL 13012 90 - 110 20 4500NH3DN

~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000

Total Phenols lt 005 024 (94 R) 027 (106 R) (12 RPO) mgL 13112 85 - 115 20 4201

799 797 SU 112712 795- 807 10 4500H+BpH

Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page bull11 Flagged analyte recoveries deviated from the QAQC limits


I

C LOB AL SC IE N CE S

414 Pontius Ave North Seattle WA 98 I 09 Ph 206-622-6960 Fx 206-622-6870

03 February 2012

Jeff Gagne

Eastern Analytical Inc

25 Chenell Drive

Concord NH 03301

RE Merrimack Station

Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception ofthose listed in the case narrative section ofthis report

Ifyou have any questions concerning this report please feel free to contact me

Sincerely

Liz Siska

i Project Manager

15

414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES

ANALYTICAL REPORT FOR SAMPLES

Laboratory Frontier Global Sciences Inc SDG

Client Eastern Analytical Inc Project Merrimack Station

Sample ID Lab ID Matrix Date Sampled Date Received

C-3024 Effluent Field Blank 1201361-01 Water 26-Jan-12 0915 27-Jan-12 0942

Treat Tank Effluent 1201361-02 Water 26-Jan-12 0920 27-Jan-12 0942

The results In this report only apply to the samples analyzed in accordance with thechain of custody document This analytical report must be reprodJJcedin its emirety

Frontier Global Sciences Inc

Liz Siska Project Manager

Page I o19 1201361 Final Report

020312012

16

414 Pontius Ave North~l0 Seattle WA 98109 Ph 206-622-6960

~~NT~ Fx 206-622-6870 G l O 6 A L SC I E NC ES

CASE NARRATIVE

SAMPLE RECEIPT

Samples were received at Frontier Global Sciences (FGS) on January 27th 2012 The samples were received intact on-ice with temperatures measured at 29 degrees Celsius

SAMPLE PREP ARATION AND ANALYSIS

Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638

Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE

ANALYTICAL ISSUES

The Effluent Field Blank was greater than the PQL however the because the associated sample was a non-detect re-analysis was not required

All analytes pass according to the QC parameters ofEPA Method 200amp

Liquid spmiddotikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits

As an additional measure of the accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report

A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitioos section ofthe following report

Frontier Global Sciences Inc The results in this report oily apply to the samples analyzed in accordance with the chain ofcustody document This aniJlytica report must be reproduced In its entirety


Page 2ofl9 1201361 Final Report

02032012

17

414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870

GLOBAL SCIENCES

CHAIN OF CUSTODY FORMS

rll Po11trus Me ff Cllttlc WA 8109 Pho~ 206-622 6960

F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1

hltp lmntierGScumiddot

The results in this report only apply to the samples analyzed in accordance wirh thechain ofcustody documenl This analytical report must be reproduced in its entirety Frontier Global Sciences Inc


Page3of19 120I 3 6 I Final Report

020312012

18



The results in this report only apply to the sampchain ofcustody document This analytical rep

les analyzed in accordance with the ort must be reproduced in tts entirety

414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206622-6870 ~ G l0 BAL SClljNCES

ANALYTICAL RESULTS

C-3024 Effluent Field Blank

Matrix Water Laboratory ID 1201361-01

Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Aluminwn ND 04 40 microgL F201252 2B02001 020112 FGS-054 u Antimony ND 0005 0020 microgL 1 F201252 2B02001 020112 FGS-054 u Arsenjc ND 005 015 microgL 1 F201252 2B0200l 020112 FGS-054 u Barium ND 003 020 microgL 1 F20I252 2B02001 020112 FGS-054 u Beryllium ND 0023 0060 microgL l F201252 2B02001 020112 FGS-054 u Cadmium ND 0004 0020 microgL F201252 2B02001 020112 FGS-054 u Chromium ND 0009 010 microgL F201252 2B0200I 020112 FGS-054 u Copper ND OQl 010 microgL 1 F20I252 2B02001 020112 FGS-054 u Iron ND 13 100 microgL l F201252 2B02001 020112 FGS-054 u Lead ND 0004 0040 microgL l F201252 2B02001 020112 FGS-054 u Manganese ND 0007 010 microgL I F201252 2B02001 020112 FGS-054 u Mercury ND 008 050 ngL 1 F202015 2B0300l 020212 EPA 1631E u Molybdenum ND 0006 006 microgL 1 F201252 2B02001 020112 FGS-054 u Nickel ND 0008 010 microgL 1 F201252 2B02001 020112 FGS-054 u Selenium ND 019 060 microgL 1 F201252 21302001 020112 FGS-054 u Silver ND 0006 0020 microgL 1 F201252 2B02001 020112 FGS-054 u Thallium ND 0001 0005 microgL 1 F201252 2B02001 020112 FGS-054 QB-02 U Zinc 025 002 020 microgL 1 F201252 2B02001 020112 FGS-054

Page4oI9 1201361 Final ampport

021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent



Aluminum ND 89 800 microgL 20 F201252 2B02001 020112 FGS-054 u Antimony 0758 0092 0400 microgL 20 F201252 2B02001 020112 FGS-054 Arsenic 956 102 300 microgL 20 F201252 2B02001 020112 FGS-054

Barium 208 054 400 microgL 20 F201252 2B02001 020112 FGS-054

Beryllium ND 0454 120 microgL 20 F201252 2B02001 020112 FGS-054 u Cadmium 0587 0083 0400 microgL 20 F201252 2B02001 020112 FGS-054 Chromium ND 018 200 microgL 20 F201252 2B02001 020112 FGS-054 u Copper 261 020 200 microgL 20 F201252 2B02001 020112 FGS-054

Iron ND 260 200 microgL 20 F20I252 2B02001 020112 FGS-054 u Lead ND 0078 0800 microgL 20 F201252 2B02001 020112 FGS-054 u Manganese 349 015 200 microgL 20 F201252 2B02001 020112 FGS-054

Mercury 122 034 202 ngL 4 F20201S 2803001 020212 EPA 1631E Molybdenum 373 012 120 microgL 20 F201252 2B02001 020112 FGS-054

Nickel 776 016 2 00 microgL 20 F20I252 2B02001 020112 FGS-054

Selenium 104 388 120 microgL 20 F201252 2B02001 020112 FGS-054 Silver ND 0120 0400 microgL 20 F201252 2B02001 020112 FGS-054 u Thallium S65 0022 0100 microgL 20 F201252 2B02001 020112 FGS-054 QB-01

Zinc ND 033 4 00 microgL 20 F201252 2B02001 020112 FGS-054 QB-02 U

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page5 of19 1201361 Final Report

02032012

Liz Siska Project Manager 20


C LOBAL_SCIENCES

MATRIX DUPLICATESTRIPLICATES

SOURCE 1201316-03

Batch F202015

Preparation BrCl Oxidation

Sequence 2B03001

Lab Number F202015-DUPI

Sample Duplicate Concentration Concentration RPD

Analyte ngL ngL MRL RPD Limit Method Notes Mercury 699 598 100 156 24 EPA 163 IE

Frontier Global Sciences Inc 1ne results in this report only apply to the sampl~ analyzed in accordance with 1he chain ofcustody document This analytical report must be reproduced in its entirety

bull

Page6of19 1201361 Final Report

02032012

21 Liz Siska Project Manager

414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960

FRONTIER Fx 206-622-6870 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201361-02

Batch F201252 Sequence 2B02001

Preparation Closed Vessel Nitric Oven Digestion Lab Number F201252-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes

Beryllium ND 20200 2214 110 FGS-054 Alwninum 662 15150 2137 974 80 - 115 FGS-054 Chromium 057 70700 792 104 85 - 115 FGS-054 Manganese 3487 60600 3539 86l 80 - 120 FGS-054 Iron ND 50500 4947 980 75 - 125 FGS-054 Nickel 116 40400 1166 967 68- 134 FGS-054 Copper 261 40400 622 894 51 bull 145 FGS-054 Zinc ND 10100 996 986 46 - 146 FGS-054 Arsenic 956 15150 2420 966 85 - 115 FGS-054 Selenium 1044 30300 I278 771 59 - I49 FGS-054 Molybdenum 3735 20200 3759 119 80 - 115 FGS-054 QM-02 Silver ND 15150 1289 85 l 74 - 119 FGS-054 Cadmium 0587 080800 1229 795 84 bull 113 FGS-054 QM-07 Antimony 0758 080800 l539 967 79- 122 FGS-054 Barium 2084 10100 2145 603 80 - 120 FGS-054 QM-02 Thallium 5650 040400 5907 636 64 - 137 FGS-054 QB-OJ

QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery

Limits RPD Limit Method Notes

Beryllium 20200 2256 112 188 75 - 125 20 FGS-054 Aluminum 15150 2136 973 00484 80 - 115 20 FGS-054 Chromium 70700 758 991 445 85 - Il5 20 FGS-054 Manganese 60600 3558 118 0544 80 -120 20 FGS-054 Iron 50500 4895 969 106 75 - 125 20 FGS-054 Nickel 40400 1139 899 239 68 - 134 20 FGS-054 Copper 40400 623 895 0117 51 bull 145 20 FGS-054 Zinc 10100 923 914 753 46 bull 146 20 FGS-054 Arsenic 15150 2581 107 644 85 - 115 20 FGS-054 Selenium 30300 1308 869 228 59- 149 20 FGS-054 Molybdenum 20200 3777 210 0491 80 - 115 20 FGS-054 QM-02


Page 7of19120361 Final Report

02032012

~ ltl middot -- --(-1-~shy


414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201361-02


Preparation Closed Vessel Nitric Oven Qjgestion Lab Number F2012~2-MSMSD1

Spike Added

MSD Concentration

MSD Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Silver 15150 1273 840 128 74 middot 119 20 FGS-054 Cadmium 080800 l102 638 108 84 - 113 20 FGS-054 QM-07 Antimony 080800 1618 107 502 79 - 122 20 FGS-054 Barium 101 00 2196 110 232 80 bull 120 20 FGS-054 Thallium 040400 6127 118 366 64 bull 137 20 FGS-054 QB-01 Lead 15150 1502 991 0946 72 - 143 20 FGS-054

The results In this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced In Its enrirety

Page8o19 J201361 Fino Report

02032011




GLOBIll SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201361-02

Batch f201252 Sequence 2B02001

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20I252-MSMSD3

Sample Spike MS MS

Analyte Concentration

microgL) Added (microgL)

Concentration (microgL) Recovery

Recovery Limits Method Notes

Beryllium ND 20200 1823 902 75 - 125 FGS-054 AS Aluminum 662 40400 3986 970 80- 115 FGS-054 AS Chromium 057 40400 4113 102 85 shy ll5 FGS-054 AS Manganese 3487 40400 7557 101 80 - 120 FGS-054 AS Iron ND 20200 2012 996 75 - 125 FGS-054 AS Nickel 776 50500 4887 952 68 - 134 FGS-054 AS Copper 261 50500 4599 906 51 - 145 FGS-054 AS Zinc ND 10100 870l 86l 46 - 146 FGS-054 AS Arsenic 956 40400 4082 987 85 - llS FGS-054 AS Selenium 1044 40400 4803 930 59- 149 FGS-054 AS Molybdenum 3735 20200 5749 997 80 - 115 FGS-054 AS Silver ND 20200 1743 863 74 - 119 FGS-054 AS Cadmium 0587 40400 3752 914 middot 84 - 113 FGS-054 AS Antimony 0758 20200 2006 955 79 - 122 FGS-054 AS Barium 2084 80800 987l 964 80 -120 FGS-054 AS Thallium 5650 20200 2586 100 64- 137 FGS-054 AS QB-01 Lead ND 10100 9763 967 72 - 143 FGS-054 AS

Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Beryllium 20200 1826 904 0151 75 - 125 20 FGS-054 AS Alwninum 40400 3956 963 0751 80 - 115 20 FGS-054 AS Chromium 40400 408l 101 0780 85 - 115 20 FGS-054 AS Manganese 40400 7520 998 0487 80 - 120 20 FGS-054 AS Iron 20200 1989 985 113 75 - 125 20 FGS-054 AS Nickel 50500 4854 946 0681 68 - 134 20 FGS-054 AS Copper 50500 4592 904 0161 51- 145 20 FGS-054 AS Zinc 10100 8705 862 00542 46 - 146 20 FGS-054 AS Arsenic 40400 4120 996 0916 85 - 115 20 FGS-054 AS Seleni1UO 40400 4701 905 215 59 - 149 20 FGS-054 AS Molybdenwn 20200 5745 995 00697 80 - 115 20 FGS-054 AS Silver 20200 1750 866 0385 74 - 119 20 FGS-054 AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analyticalreport must be reproduced in its entirety


02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02


Preparation Closed Vessel Nitric Oven Qigestion Lab Number F20 222-MSMSDJ

Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Cadmium 40400 3859 941 281 84-113 20 FGS-054 AS Antimony 20200 2014 959 0386 79- 122 20 FGS-054 AS Barium 80800 9944 973 0729 80 bull 120 20 FGS-054 AS Thallium 20200 2585 100 00375 64 - 137 20 FGS-054 AS QB-01 Lead 10100 9756 966 00774 72 -143 20 FGS-054 AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody docwnent This analytical report must N reprodulaquod In itsentirety

Page IOof9 1201361 Final Report

02032012


FRONTIER~


GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201316-03

Batch F202015 Sequence 2803001

Preparation BrCl Oxidation Lab Number F202015-MSMSD1

middot Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ogL) Recovery Method Notes Limits

Mercury 699 20200 2210 748 71 - 125 EPA 163IE

Spike MSD MSD Recovery RPD Added Concentration

RPD Limits Limit Method Notes (ngL) (ngL) Recovery Analyte

Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05

Frontier Global Sciences Inc The results in this report only apply to the samples anared in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

1 of19 1201361 Final Report

02032012



GLOBAL SCIENCES


SOURCE 1201361-02



Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte (ngL) (ugL) (ngL) Recovery Method Limits Notes

Mercury 1220 40800 5232 983 71 - 125 EPA l631E

Spike MSD MSD Added Concentration Recovery RPD (ngL) RPD Limits Limit Method Notes Analyte (ngL) Recovery

Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analyttcal report must be reproduced in its entirety

Page 12of19 1201361 Final Report

02032012


414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960bull ~ Fx 206-622-6870

GLOBAL SCIENCES


SOURCE 1201359-01


Preparation BrCI Oxidation Lab Number F202015-MSMSD4

Sample Spike MS MS Concentration middotmiddot Added Concentration Recovery

Aoalyte (ngL) (ogL) (ngL) Recovery Method NotesLimits

Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD

Analyte (ogL) (ngL) Recovery RPD Limits Limit Method Notes

Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E



The results in this report only apply to 1he samples analy-ed in accordance with the chain ofcustody document This analytical reporl must be reproduced in its entirety


02032012

28

GLO~AL SCIENCES


LABO RA TORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD


Preparation Closed Vessel Nitric Oven Digestion Lab Number F20l252-BSBSD1

LCS Source Blank S12ike

Spike LCS LCS Added Concentration Recovery

Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~

Spike LCSD LCSD Added Concentration Recovery RPD


Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054

Aluminum 15000 1459 972 00872 85 bull 115 20 FGS-054

Chromium 70000 646 922 0275 85 bull 115 20 FGS-054

Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054

Copper 40000 416 104 00881 51 - 145 20 FGS-054 Zinc 10000 1039 104 0846 46 bull 146 20 FGS-054

Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054

Frontier Global Sciences Inc TM results in this report only apply to the samples a110yred in accordance with the chain qfcustody documenL This 0111Jlytfcal report must be reprodu1in its entirety

Page Uo19~ __ltl~ 1201361 Fl110l Report 020312012


I


GLOBAL SC I ENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO


Preparation Closed Vessel Nitric Oven Digestion Lab Number F201252-BSBSD1

LCS Source Blank Spike Dup

Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054

Frontier Global Sciences fnc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 15 of19 1201361 Final Report

02032012



G~OBAL SCIENCES


RECOVERY AND RPD


Preparation BrCI Oxidation Lab Number F20201 5-BSBSD1

LCS Source Nist 164Id

Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes



The results in this report only apply to the samples analyzedin accordance with the chain ofcustody document This analytical report must be reproduced in its elllirety

Page I6of19 1201361 FinaReport

0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

u F201252-BLK1 Beryllium -00003 0060 microgL F201252 FGS-054

F20I252-BLK1 Aluminum 001 40 microgL F201252 middot FGS-054 u F20] 252-BLKl Chromium -004 010 microgL F201252 FGS-054 u F201252-BLKI Manganese -00007 010 microgL F201252 FGS-054 u F201252-BLK1 Iron -04 100 microgL F201252 FGS-054 u F201252-BLKI Nickel 0004 010 microgL F201252 FGS-054 u F201252-BLK I Copper 002 010 microgL F201252 FGS-054 u F201252-BLK1 Zinc 032 020 microgL F201252 FGS-054 QB-10

F201252-BLK1 Arsenic -015 015 microgL F201252 FGS-054 u F201252-BLKI Selenium 014 060 microgL F201252 FGS-054 u F20I252-BLK1 Molybdenwn 0004 006 microgL F201252 FGS-054 u F201252-BLKJ Silver -0001 0020 microgL F201252 FGS-054 u F201252-BLK1 Cadmium -0010 0020 microgL F201252 FGS-054 u F201252-BLK1 Antimony -00003 0020 microgL F201252 FGS-054 u F201252-BLKI Barium 007 020 microgL F201252 FGS-054 u F201252-BLKI Thallium 0002 0005 microgL F201252 FGS-054 QB-02 U

F201252-BLKl Lead 00003 0040 microgL F20I252 FGS-054 u

Frontier Global Sciences Inc The results fn 1hfs report only apply to the samples analyzed fn accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page Jlof19 1201361 Final Repon

02032012



GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2B0300



F202015-BLK1 Mercury 006 050 ngL F202015 EPA 1631E u F202015-BLIlt2 Mercury 003 050 ngL F202015 EPA 1631E u F202015-BLK3 Mercury 005 050 ngL F202015 EPA 1631E u F202015-BLK4 Mercury 006 050 ngL F202015 EPA 163IE QB-04 U

Frontier Global Sciences Inc The results in this report only apply to the samples anolyzed in accordance with the chain ofcustody document This analytical report must bt reprodulaquod In itsenlirety

Page Bo19 1201361 Final Rtport

02031012



GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QM-05 The spike recovery was outside acceptance limits for the MSMSD and or ASASD due to matrix interference The LCS andor LCSD were within acceptance limits showing that the laboratory is in control and the data is acceptable

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-IO The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL Only report sample results greater than IO times the contamination value (QB-01) or samples less than the MRL (QB-02)

QB-04 The blank was preserved to 2 BrCl rather than I The control limit for blanks preserved to greater than 1 BrCI is the preservation percentage multiplied by the MRL

QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL

QB-01 The method blank andor initialcontinuing calibration blank contains ana]yte at a concentration above the MRL However the blank concentration(s) are less than I0 ofthe sample result

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimwn Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation



The resJtJ in this report onlyapply to rhe samples analyzed b1 accordi111ce with the chain ofcustody document 111is analytical report must be reproduced in its entirety


02032012

middot 34

JJiihl CHAIN-OF-CUSTODY RECORD eastern analytical Inc 107170 C) professional laboratory services

DateTime Composites need start and stop dateslimes Sample IDs Matrix Parameters and Sample Notes of containers

Effluent Field Blank AqTotSWLLMetalsSub 2 r 1 2 t ---~ueous [[9 ~ gt middot~r~rComp

bullbull bull I

Biampler confirms ID and parameters are accurate Circle preservatives HCL HNO H so NaOH MEOH Na so Dissolved Sample Field Filtered L 1 1

Treat Tank Effluent I z 6 12 AqTotSWLLMetalsSubNH3BODCICODCyanTFN030G1664N624NE625E608PCBTPhenols J -7 aqueous I (J1 1 02Gorcomp1 2- 0 deg AT Cv-hgttw-rJ ~1---

Gsampler confirms ID and parameters are accurate Circle preservativelq)No ~EOH NaSO ~ Dissolved Sample Field Filtered L

Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary

EAi Project ID 3902

Project Name Wastewater Analysis - Weekly

State NH

Client (Pro Mgr) Paul Pepler

Customer GZA GeoEnvlronmental Inc (NH)

Address 380 Harvey Road

City Manchester NH 03103

Phone 623-3600 Fax 624-9463 (37)

EmallAddress paulpeplergzacom

fi -_q R rtmiddot o tiResults Needed by Preferred date O epo mg P ons

Notes about project (ie Special Limits Billing info if different )

Subcontract ALL metals to Frontier Global Sciences Metals include Total AlSbAsBaBeCdCrCuFePbMnHgMoNiSeAgTI Zn Metals analyses require project-specific MSMSD

6 2 - R S 6 (J g NJ II- n edeJ

-2 i~ z I I Iao - middotamp

QC deliverables

~A DA+ P(s DB+ DC OPC

181 HC PONumber 02259252 181 EDD PDF

Quote No181 EDD email 4- s- oc181 PDF prellm NO FAX Temperature D e-mail login Confirmation

Ice present Yes q6 No CJONO FAX

DateTime

Relinquished by DatefTimemiddot Received by

Eastern Analytical Inc 25 CheneI Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228-4591

bull R obullbull~ - -Tlt

Winnipesaukee River Basin Program Wastewater Treatment Plant File No 04002930700

February 9 2012 Page2

As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses ofFGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater

EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis ofFGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOP For further information see

Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) httpwaterepagovscitechwastetechguideluploadlsteam_draft_soppdf EPAMay20ll

Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FOO wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater

Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744

Very truly yours

GZA GEOENVIRONMENT AL INC

Ronald A Breton P E Principal

RABmm P04Job$0029300s04002930700IWorlcSAMPLING ANO REPORTINGREPORTSFranklinFINAL 040029307 Franklin DATA RPT 020912doa

Attachments Wastewater Discharge Monitoring Report Analytical Data Report


-------------------




Dated 9282011


FLOW DATA




----------------------

---- ------------------

-----------



Telephone (603) 224-4081















Bow New Hampshire

RESULTS

PARAMETER (mgL)


Aluminum lt 0080

Arsenic 000956


Iron lt 0200


Mercury 00000122


Selenium 0104






Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

ZmiddotB-12- Date















Sample ID


Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2


lt 10 lt2

2 lt2 lt2


93R 106oR

99R













































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES








ofl9 1201361 Final Report

02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





-------------------




Dated 9282011


FLOW DATA




----------------------

---- ------------------

-----------



Telephone (603) 224-4081















Bow New Hampshire

RESULTS

PARAMETER (mgL)


Aluminum lt 0080

Arsenic 000956


Iron lt 0200


Mercury 00000122


Selenium 0104






Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

ZmiddotB-12- Date















Sample ID


Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2


lt 10 lt2

2 lt2 lt2


93R 106oR

99R













































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E




ofl9 1201361 Final Report

02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




-------------------




Dated 9282011


FLOW DATA




----------------------

---- ------------------

-----------



Telephone (603) 224-4081















Bow New Hampshire

RESULTS

PARAMETER (mgL)


Aluminum lt 0080

Arsenic 000956


Iron lt 0200


Mercury 00000122


Selenium 0104






Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

ZmiddotB-12- Date















Sample ID


Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2


lt 10 lt2

2 lt2 lt2


93R 106oR

99R













































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




----------------------

---- ------------------

-----------



Telephone (603) 224-4081















Bow New Hampshire

RESULTS

PARAMETER (mgL)


Aluminum lt 0080

Arsenic 000956


Iron lt 0200


Mercury 00000122


Selenium 0104






Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

ZmiddotB-12- Date















Sample ID


Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2


lt 10 lt2

2 lt2 lt2


93R 106oR

99R













































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime






Bow New Hampshire

RESULTS

PARAMETER (mgL)


Aluminum lt 0080

Arsenic 000956


Iron lt 0200


Mercury 00000122


Selenium 0104






Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

ZmiddotB-12- Date















Sample ID


Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2


lt 10 lt2

2 lt2 lt2


93R 106oR

99R













































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime







Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

ZmiddotB-12- Date















Sample ID


Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2


lt 10 lt2

2 lt2 lt2


93R 106oR

99R













































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery




of19120361 Final Report

02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime






Paul Pepler


380 Harvey Road

Manchester NH 03103





Dear Mr Pepler







Sincerely

ZmiddotB-12- Date















Sample ID


Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2


lt 10 lt2

2 lt2 lt2


93R 106oR

99R













































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime

















Sample ID


Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2


lt 10 lt2

2 lt2 lt2


93R 106oR

99R













































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery




of191201361 Final Report

02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime







Sample ID


Date Sampled

Date Received Units

Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

12612 112612

ug1

127112

KJP

624

lt5 lt2 lt2 lt5 lt5

lt 50 lt 50

lt 1 lt5 lt5

lt 50 lt10 lt2

lt10 lt2 lt2


lt 10 lt2

2 lt2 lt2


93R 106oR

99R













































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime















































Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05


of19 1201361 Final Report

02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime













Sample ID



Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002

aqueous

1 2612

12612

ug1 1 2712

13012

JMR

625mod

1




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




i






Matrix aqueous


Units ug1




DIiution Factor 1











20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime







20

Method



QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




QC REPORT



EAi ID 107170

Batch ID 734529-39483A012712ABN1








Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime







Sample ID

Lab Sample ID

Matrix


Units


Date of Analysis

Analyst

Method

Dilution Factor


Treat Tank Effluent

10717002 aqueous

112612 12612

mgl

13012

13012

LAS

1664A

lt5












Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime














Sample ID

Lab Sample ID

Matrix


Units


Date of Analysls

Analyst

Method

Dilution Factor

PCB-1016 PCB-1221


Treat Tank Effluent

10717002

aqueous

12612 12612

ug1

12712

12712

JW

608

lt 03 lt 03

lt 03 lt 03 lt 03

lt 03 lt 03

87R 86R


11




PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime







PCB-1016 lt 03 20 (101 R) 20 (99 R) (2 RPO) 1272012 ug1 50 - 114 20 608






PCB-1260 lt 03 19 (95 R) 19 (93 R) (2 RPO) 12712012 ug1 8 -127 20 608

TMX (surr) 93R 92R 89R 1272012 Rec 30 - 150 608

104R 103 R 96R 1272012 Rec 30-150 608DCB (surr)
















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime

















Date of







~ BOD lt6 330 (84 R) 360 (89 R) (6 RPO) mgL 12712 84 - 115 20 5210B

COD lt 10 100 (102 R) 100 (100 R) (2 RPD) mgL 2212 85 -115 20 H8000


799 797 SU 112712 795- 807 10 4500H+BpH



I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




I



03 February 2012

Jeff Gagne


25 Chenell Drive

Concord NH 03301




Sincerely

Liz Siska

i Project Manager

15


GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





GLOBAL SCIENCES











020312012

16



CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime






CASE NARRATIVE

SAMPLE RECEIPT





ANALYTICAL ISSUES









02032012

17


GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





GLOBAL SCIENCES



F- OG-(gt~Z-6870 1r~(9Jltier~~~~-1





020312012

18






ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime









ANALYTICAL RESULTS






021032012

19


I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





I l CLOBAL SCIENCES

ANALYTICAL RESULTS

Treat Tank Effluent













02032012



C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





C LOBAL_SCIENCES


SOURCE 1201316-03

Batch F202015


Sequence 2B03001





bull


02032012





SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime







SOURCE 1201361-02



Analyte


(microgL)


MS Concentration

(microgL)

MS

Recovery Recovery

Limits

75 - 125

Method Notes


QM-02 Lead ND l5150 l488 982 72 - 143 FGS-054

Analyte


MSD Concentration

(microgL)

MSD 0o

Recovery

Oo

RPD Recovery





02032012




GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





GLOBAL SCIENCES


SOURCE 1201361-02



Spike Added

MSD Concentration

MSD Oo Recovery RPD





02032011




GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





GLOBIll SCIENCES


SOURCE 1201361-02



Sample Spike MS MS






Aoalyte


MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery





02032012 ~ A-~



GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





GLOBAL SCIENCES


SOURCE 1201361-02



Aoalyte


MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits





02032012


FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




FRONTIER~


GLOBAL SCIENCES


SOURCE 1201316-03





Mercury 699 20200 2210 748 71 - 125 EPA 163IE



Mercury 20200 2097 692 522 71 - 125 24 EPA I631E QM-05



02032012



GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





GLOBAL SCIENCES


SOURCE 1201361-02




Mercury 1220 40800 5232 983 71 - 125 EPA l631E


Mercury 40800 5212 978 0379 71 - 125 24 EPA 163lE



02032012



GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





GLOBAL SCIENCES


SOURCE 1201359-01





Mercury 1171 15300 2618 946 71- 125 EPA 1631E

Spike Added

MSD Concentration

MSD Oo Recovery RPD


Mercury 15300 2594 93l 0888 71 - 125 24 EPA I631E





02032012

28

GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




GLO~AL SCIENCES



RECOVERY AND RPD





Analyte

Beryllium

(pgL)

20000

(microgL)

1962

Recovery

98l

Limits

75 -125

Method

FGS-054

Notes

Aluminwn 15000 1460 973 85 -115 FGS-054

Chromium 70000 647 925 85 - 115 FGS-054

Manganese 60000 583 97l 8S - 115 FGS-054

Iron 50000 4594 919 80 -120 FGS-054

Nickel 40000 392 980 68 bull 134 FGS-054

Copper 40000 417 104 51 - 145 FGS-054

Zinc 10000 1048 105 46 - 146 FGS-054

Arsenic 15000 1427 95 l 85 - 115 FGS-054

Selenium 30000 2804 935 59 - 149 FGS-054

Molybdenum 20000 188 938 85 - 115 FGS-054

Silver 15000 1490 993 74 - 119 FGS-054

Cadmium 080000 0825 103 84 - 113 FGS-054

Antimony 080000 0780 975 79 - 122 FGS-054

Barium 10000 978 978 85 - 115 FGS-054

Thallium 040000 0417 104 64 - 134 FGS-054 QB-01

Lead 15000 1517 101 72- 143 FGS-054

~



Beryllium 20000 1944 972 0928 75 - 125 20 FGS-054



Manganese 60000 574 956 155 85 - 115 20 FGS-054

Iron 50000 4582 916 0251 80-120 20 FGS-054

Nickel 40000 396 990 101 68 - 134 20 FGS-054


Arsenic 15000 1417 944 0731 85 bull 115 20 FGS-054




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




I


GLOBAL SC I ENCES


RECOVERY AND RPO




Analyte


LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery


Selenium 30000 2798 933 0184 59 - 149 20 FGS-054

Molybdenum 20000 186 928 111 85 -115 20 FGS-054

Silver l5000 l501 100 0752 74 - 119 20 FGS-054

Cadmium 080000 0757 947 856 84 - 113 20 FGS-054

Antimony 080000 0797 996 218 79 - 122 20 FGS-054

Barium 10000 976 976 0247 85 shy 115 20 FGS-054

Thallium 040000 0410 103 151 64 - 134 20 FGS-054 QB-01

Lead 15000 1524 102 0433 72 - 143 20 FGS-054



02032012



G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





G~OBAL SCIENCES


RECOVERY AND RPD




Analyte

Mercuxy

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1511

LCS

Recovery

964

Recovery Limits

80 - 120

Method

EPA 1631E

Notes

Analyte

Mercury

Spike Added (ngL)

15679

LCSD Concentration

(ngL)

1479

LCSD

Recovery

943

RPD

216

Recovery Limits

80- 120

RPD Limit

24

Method

EPA 163IE

Notes





0210312012

31

~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




~


GLOBA_L SCIENCES

Instrument ICPMS-6

PREPARATION BLANKS

Sequence 2B0200I









02032012



GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





GLOBAL SCIENCES

PREPARATION BLANKS







02031012



GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime





GLOBAL SCIENCES























02032012

middot 34




bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime







bullbull bull I





EAi Project ID 3902


State NH





Phone 623-3600 Fax 624-9463 (37)







QC deliverables





DateTime




wastewater discharge monitoring report · pdf file... wastewater discharge monitoring report...

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