vol. 4 no. 4 organic building blocks

15
Organic Building Blocks Vol. 4 No. 4 Acid Chlorides Amino Acids and Amino Alcohols Aldehydes Alkynes Aryl Halides Aryl Amines Amides Benzyl Amines and Benzyl Halides Carboxylic Acids Esters Isocyanates and Isocyanides Ketones Nitrostyrenes Nitriles Sulfonyl Chlorides Other Sulfur-containing Building Blocks Miscellaneous Building Blocks sigma-aldrich.com

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OrganicBuilding Blocks

Vol. 4 No. 4

Acid Chlorides

Amino Acids and Amino Alcohols

Aldehydes

Alkynes

Aryl Halides

Aryl Amines

Amides

Benzyl Amines andBenzyl Halides

Carboxylic Acids

Esters

Isocyanates andIsocyanides

Ketones

Nitrostyrenes

Nitriles

Sulfonyl Chlorides

Other Sulfur-containingBuilding Blocks

Miscellaneous Building Blocks

sigma-aldrich.com

TO ORDER: Contact your local Sigma-Aldrich office (see back cover),call 1-800-558-9160 (USA), or visit sigma-aldrich.com.s

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Isoxazole-5-carbonyl chloride, 97%

63,623-1 1gC4H2ClNO2 5g

Cyclopropanecarbonyl chloride, 98%

C11,680-7 5gC4H5ClO 25g

100g

2-Ethylacryloyl chloride, 99%

58,914-4 250mgC5H7ClO

6-Chloronicotinoyl chloride, 97%

52,810-2 25gC6H3Cl2NO

Methyl adipoyl chloride, 97%

63,856-0 5gC7H11ClO3 25g

3,4,5-Trifluorobenzoyl chloride, 97%

55,947-4 1gC7H2ClF3O 5g

3-Chloro-2-fluorobenzoyl chloride, 98%

53,955-4 1gC7H3Cl2FO

6-(Trifluoromethyl)nicotinoylchloride, 97%

64,006-9 1gC7H3ClF3NO 5g

2-Fluoro-6-iodobenzoyl chloride, 97%

55,244-5 1gC7H3ClFIO 5g

Benzotriazole-1-carbonyl chloride, tech., 97%

63,391-7 1gC7H4ClN3O

2,5-Dimethylfuran-3-carbonyl chloride, 97%

53,063-8 1gC7H7O2CI 5g

4-Chlorophenylacetyl chloride, 97%

63,895-1 5gC8H6Cl2O 25g

4-Fluoro-3-methylbenzoyl chloride, 97%

59,500-4 1gC8H6ClFO 5g

2-Chlorocinnamoyl chloride, 97%

53,720-9 5gC9H6Cl2O 25g

2-Ethoxybenzoyl chloride, 97%

63,897-8 5gC9H9ClO2 25g

3,4,5-Trimethoxybenzoyl chloride, 98%

T6,980-9 25gC10H11ClO4 100g

Phthalylglycyl chloride, 96%

63,640-1 1gC10H6ClNO3

3-Methylbenzofuran-2-carbonyl chloride, 97%

54,154-0 1gC10H7ClO3 5g

3,5-Diethoxybenzoyl chloride, 97%

63,491-3 1gC11H13ClO3 5g

2,5-Diethoxybenzoyl chloride, 97%

63,898-6 1gC11H13ClO3 5gCl

O

O

O

O

OCl

O

O

Cl

O

CH3

N

O

OO

Cl

OCH3

H3CO

H3CO

O

Cl

Cl

O

O

Cl

OCl

Cl

O

CH3

F

Cl

Cl

O

O CH3H3C

OCl

NN

N

OCl

Cl

O

F

I

N

Cl

O

F3C

Cl

O

ClF

Cl

O

FF

F

ClOCH3

O

O

N

Cl

O

Cl

O

Cl

O

Cl

NO

Cl

O

Acid Chlorides

New Building Blocks for Organic Synthesis

Aldrich is pleased to offer a growing line of buildingblocks having a wide range of applications in organic

synthesis and medicinal chemistry. This listing contains ournewest building blocks, including many of our latestSmartBlocs™, a compilation of orthogonally reactivebuilding blocks chosen for their ability to undergodistinctly different and potentially non-conflictingreactions. Having two points of reactivity, the

SmartBlocs™ could also serve as a synthetic core forlibrary synthesis. These building blocks have beenarranged by functional group for ease of review. If youdo not see a compound that you need for your research,please call us at 1-800-231-8327 or e-mail the productspecialist at [email protected]. Your new productsuggestions, as always, are welcome and appreciated.

Aci

d C

hlo

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Ready to scale up? For competitive quotes on larger quantities or custom synthesis, contact Sigma-Aldrich Fine Chemicals at 1-800-336-9719 (USA), or visit www.sigma-aldrich.com/safc. O

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Am

ino

Aci

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an

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Ald

eh

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(S)-(+)-2-Amino-4-bromobutyric acidhydrobromide, 97%

47,698-6 1gC4H8BrNO2

D-Alloisoleucine, 97%

86,071-9 500mgC6H13NO2 1g

4-Amino-3-nitrobenzoic acid, 97%

24,811-8 5gC7H6N2O4 25g

5-Amino-2-nitrobenzoic acid

56,461-3 1gC7H6N2O4 5g

2-Amino-5-hydroxybenzoic acid, 99%

27,899-8 1gC7H7NO3 5g

5-Amino-2,2-dimethylpentanol

63,626-6 5gC7H17NO 25g

3-Amino-5-(trifluoromethyl)benzoic acid, 97%

57,951-3 1gC8H6F3NO2

2-Amino-3-bromo-5-methylbenzoic acid, 97%

63,153-1 1gC8H8BrNO2 5g

L-2-Chlorophenylglycine, 95%

63,894-3 1gC7H7NO3 5g

2-Amino-5-chloro-3-methylbenzoic acid, 97%

64,351-3 5gC8H8ClNO2 25g

2-Aminophenylacetic acid, 95%

55,283-6 1gC8H9NO2 5g

3-Amino-3-(4-chlorophenyl)propionic acid, 97%

57,335-3 1gC9H10ClNO2 5g

3-Amino-3-(2-chlorophenyl)propionic acid, 97%

57,336-1 1gC9H10ClNO2 5g

3-Amino-3-(4-fluorophenyl)propionicacid, 97%

57,341-8 1gC9H10FNO2

2-Amino-2-phenylbutyric acid, 96%

53,025-5 1gC10H13NO2 5g

3-Amino-3-(4-methylphenyl)propionic acid, 97%

57,334-5 1gC10H13NO2 5g

3-Amino-3-(4-methoxyphenyl)propionic acid, 97%

57,338-8 1gC10H13NO3

N-Boc-1-aminocyclobutanecarboxylic acid, 97%

63,080-2 1gC10H17NO4 5g

3-Amino-3-(3,4-dimethoxyphenyl)propionic acid, 97%

57,342-6 1gC11H15NO4

N-Boc-L-cyclohexylglycinol, 98%

63,754-8 1gC13H25NO3 5g

N-Boc-D-cyclohexylglycinol, 98%

63,755-6 1gC13H25NO3 5g

N-Z-D-Leucinol, 97%

55,429-4 1gC14H21NO3 5g

OHNHO

O

OHNH

O

O

OHNH

O

O

H2N OH

O

H3COOCH3

NH

O OH

OO

H2N OH

O

OCH3

H2N OH

O

CH3

OH

O

NH2

H2N OH

O

F

H2N OH

OCl

H2N OH

O

Cl

OH

O

NH2

CO2HNH2

CH3Cl

Cl

CO2H

NH2

CO2HNH2

BrH3C

CO2H

NH2F3C

HO NH2

CO2HNH2

HO

CO2H

H2N

NO2

CO2H

NH2

NO2

CO2HCH3

NH2

CO2HBr

NH3+

Br_

Amino Acids and Amino Alcohols

5-Iodo-2-furaldehyde, 97%

57,928-9 1gC5H3IO2

2-Bromo-3-pyridinecarboxaldehyde, 96%

63,214-7 1gC6H4BrNO 5g

3-Bromo-4-pyridinecarboxaldehyde, 97%

63,828-5 1gC6H4BrNO 5g

5-Bromo-3-pyridinecarboxaldehyde, 97%

64,410-2 1gC6H4BrNO 5g

2-Chloro-3-pyridinecarboxaldehyde, 97%

63,215-5 1gC6H4ClNO 5g

3-Chloroisonicotinaldehyde, 97%

63,674-6 1gC6H4ClNO 5g

N

Cl

O H

N Cl

H

O

N

BrH

O

N

Br

O H

N Br

H

O

OIH

O

Aldehydes

Ald

eh

yd

es

TO ORDER: Contact your local Sigma-Aldrich office (see back cover),call 1-800-558-9160 (USA), or visit sigma-aldrich.com.s

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2

2-Amino-3-pyridinecarboxaldehyde, 97%63,910-9 1gC6H6N2O 5g

5-Bromo-3-fluorosalicylaldehyde, 97%

59,351-6 1gC7H4BrFO2

3-Chloro-5-fluorosalicylaldehyde, 97%

59,340-0 1gC7H4ClFO2

3-Chloro-5-fluoro-4-hydroxybenzaldehyde, 97%

63,884-6 1gC7H4ClFO2

3,5-Difluorosalicylaldehyde, 97%

47,465-7 1gC7H4F2O2

2-Methoxy-3-pyridinecarboxaldehyde, 96%63,213-9 1gC7H7NO2 5g

3,5-Dimethylpyrrole-2-carboxaldehyde, 95%64,051-4 1gC7H9NO

2,6-Difluoro-4-methoxybenzaldehyde, 97%63,180-9 1gC8H6F2O2 5g

3-Chloro-4-methylbenzaldehyde, 97%

56,323-4 1gC8H7ClO 5g

5-Chloro-2-hydroxy-3-methoxybenzaldehyde, 96%

56,941-0 1gC8H7ClO3 5g

5-Fluoro-3-methylsalicylaldehyde, 97%

59,328-1 1gC8H7FO2

Indole-4-carboxaldehyde, 97%63,242-2 1gC9H7NO 5g

Indole-6-carboxaldehyde, 97%

63,240-6 250mgC9H7NO 1g

Indole-7-carboxaldehyde, 97%

63,241-4 1gC9H7NO 5g

2,6-Dichloro-3,4-dimethoxybenzaldehyde, 97%

56,940-2 1gC9H8Cl2O 5g

2-Acetylbenzaldehyde, 95%

56,291-2 1gC9H8O2

3-Acetylbenzaldehyde, 97%

56,290-4 1gC9H8O2

2,3-Dihydrobenzofuran-5-carboxaldehyde, 97%

63,195-7 1gC9H8O2 5g

4-Ethyl-3-nitrobenzaldehyde, 97%

63,408-5 1gC9H9NO3 5g

3-[(Benzyloxycarbonyl)amino]-1-propanal, 95%

59,295-1 1gC11H13NO3

4-Butoxy-3-nitrobenzaldehyde, 97%

52,319-4 1gC11H13NO4 5g

N-(3-Formyl-2-pyridinyl)-2,2-dimethylproparamide, 97%

63,822-6 1gC11H14N2O2 5g

2,3-Diethoxybenzaldehyde, 97%

56,838-4 1gC11H14O3 5g

4-(N,N-Bis(2-hydroxyethyl)-amino)benzaldehyde, 95%

63,219-8 1gC11H15NO3 5g

N-Boc-cycloleucinal, 97%

63,758-0 1gC11H19NO3 5g

3-(Diethoxymethyl)benzaldehyde, 97%

63,583-9 1gC12H16O3 5g

2-Fluorobiphenyl-4-carboxaldehyde, 97%

54,805-7 1gC13H9FO 5g

4-Fluoro-3-phenoxybenzaldehyde, 97%

64,338-6 5gC13H9FO2 25g

(3R)-(-)-3-(1-Methyl-1H-indol-3-yl)-1-butyraldehyde (>95% ee)

59,188-2 1gC13H15NO

(3S)-(+)-3-(1-Methyl-1H-indol-3-yl)-1-butyraldehyde (>95% ee)

59,134-3 1gC13H15NO

2-(Triisopropylsilyl)oxazole-5-carboxaldehyde, 96%

64,110-3 1gC13H23NO2Si 5g

1-(Phenylsulfonyl)-3-indolecarboxaldehyde, 97%

51,641-4 500mgC15H11NO3S

(3S)-(+)-3-(Methyl-1H-indol-3-yl)-3-phenylpropanaldehyde (>95% ee)

59,101-7 1gC18H17NO

N

HO

CH3

NS O

O

OH

N

O Si[CH(CH3)2]3H

O

N

HO

CH3

H3C

N

HO

CH3

H3C

H

O

OF

H

OF

OO

H

O

NH

H

O

OO

H

O

N

OH

HO

H

O

OO

N

H

O

NH

O

H

O

NO2

O

H

O

HNO

O

H

O

NO2

O

O

H

H

O

CH3O

H

O

CH3

O

H

O

ClOCH3

Cl

H3CO

NH

HO

NH

H

O

NH

O H

H

O

OHCH3

F

H

O

OHOCH3

Cl

H3C

H

O

Cl

F

F

H3CO

H

O

NH

CH3

H3C

O

H

N OCH3

H

O

H

O

OHF

F

H

O

Cl

F

HO

H

O

OHCl

F

H

O

OHF

Br

N NH2

H

O

Aldehydes (continued)

Alk

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Ready to scale up? For competitive quotes on larger quantities or custom synthesis, contact Sigma-Aldrich Fine Chemicals at 1-800-336-9719 (USA), or visit www.sigma-aldrich.com/safc. O

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Ethyl 2-pentynoate

63,211-2 5gC7H10O2 25g

3-Cyclopentyl-1-propyne, 97%

63,207-4 1gC8H12 5g

3-Cyclohexyl-1-propyne, 97%

63,206-6 1gC9H14 5g

1,3-Diethynylbenzene, 97%

63,210-4 1gC10H6 5g

1,4-Diethynylbenzene, 96%

63,209-0 5gC10H6

4-Phenyl-1-butyne, 97%

63,205-8 5gC10H10

2-Ethynyl-6-methoxynaphthalene, 97%

63,263-5 1gC13H10O 5g

5-Phthalimido-1-pentyne, 97%

64,693-8 5gC13H11NO2 25g

2,5-Dicyclohexyl-1,4-di-(1-propynyl)-benzene

63,646-0 250mgC24H30 1g

N

O

O

H3CO

O

O

Alkynes

1-Bromo-2-(2-Methoxyethoxy)ethane, 95%

63,984-2 10gC5H11BrO2 50g

4-Bromo-5-fluoro-2-iodotoluene, 97%

63,902-8 1gC7H5BrFI 5g

4-Bromo-5-fluoro-2-nitrotoluene, 97%

63,899-4 1gC7H5BrFNO2 5g

3-Fluoro-4-iodotoluene, 97%

63,515-4 1gC7H6FI 5g

4-Fluoro-2-iodotoluene, 97%

64,306-8 5gC7H6FI 25g

4-Fluorophthalic anhydride, 97%

64,137-5 5gC8H3FO3 25g

1-Bromo-4-(1,1,2,2,-tetrafluoroethoxy)benzene, 96%

34,190-8 5gC8H5BrF4O

5-Iodoindole, 98%

56,383-8 5gC8H6IN 25g

2-Bromomethyl-1,4-benzodioxane, 97%

63,264-3 1gC9H9O2Br 5g

1-Bromo-3,4,5-trimethoxybenzene, 97%

63,453-0 10gC9H11BrO3 100g

2-Hydroxy-1-iodonaphthalene, 97%

63,351-8 1gC10H7IO 5g

4-Hydroxy-3-iodobiphenyl, 95%

63,349-6 1gC12H9IO 5g

1-Bromo-2,3-dimethoxynaphthalene

64,714-4 1gC12H11BrO2 10g

1-Bromo-2,4,6-triisopropylbenzene, 98%

63,793-9 1gC15H23Br 5g

Br

BrOCH3

OCH3

I

OH

I

OH

Br

OCH3

OCH3

H3CO

O

OBr

NH

I

O

BrFF

F

FH

OF

O

O

CH3

I

F

I

FH3C

CH3

NO2

FBr

CH3

I

FBr

H3COO

Br

Aryl Halides

Ary

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TO ORDER: Contact your local Sigma-Aldrich office (see back cover),call 1-800-558-9160 (USA), or visit sigma-aldrich.com.s

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N-Methyl-N-methoxytrifluoroacetamide, 99%

64,415-3 5mlC4H6F3NO2 25ml

2-Bromoformanilide, 97%

63,099-3 1gC7H6BrNO 5g

4-Bromoformanilide, 97%

63,101-9 1gC7H6BrNO 5g

5-Bromosalicylamide, 97%

63,120-5 5gC7H6BrNO2 25g

3’-Iodo-5’-nitroacetanilide, 97%

64,435-8 1gC8H7IN2O3 10g

N-(2-Amino-4,5-dichlorophenyl)acetamide, 97%

64,170-7 5gC8H8Cl2N2O 25g

NH

ClCl

NH2

CH3

O

NH

CH3

O

O2N

I

Br

OH

NH2

O

NH

H

OBr

NH

H

O

Br

F3C N

OCH3

OCH3

Amides

2-Amino-5-iodo-3-nitropyridine, 97%

64,016-6 1gC5H4IN3O2 5g

2-Chloro-4,6-difluoroaniline, 97%

64,141-3 1gC6H4ClF2N 5g

3-Iodo-5-nitroaniline, 98%

64,581-8 5gC6H5IN2O2

4-Bromo-o-phenylenediamine, 97%

64,044-1 5gC6H7BrN2 25g

4-Bromo-2-(trifluoromethoxy)aniline, 97%

63,125-6 5gC7H5BrF3O 25g

2-Chloro-4-(trifluoromethyl)aniline, 97%

64,149-9 5gC7H5ClF3N 25g

5-Amino-2-fluorobenzonitrile, 97%

63,987-7 5gC7H5FN2 25g

5-Bromo-4-fluoro-2-methylaniline, 97%

63,903-6 1gC7H7BrFN 5g

2,4-Dichloro-N-methylaniline, 97%

63,095-0 1gC7H7Cl2N 5g

3-Bromo-N-methylaniline, 97%

63,098-5 1gC7H8BrN 5g

2-Bromo-3-methylaniline

64,562-1 5gC7H8BrN

3-Fluoro-N-methylaniline, 97%

63,096-9 1gC7H8FN 5g

3-Iodo-4-methylaniline, 97%

63,126-4 5gC7H8IN 25g

2-Amino-5-bromo-4,6-dimethylpyridine, 97%

63,420-4 1gC7H9BrN2 5g

2-Methoxy-N-methylaniline, 97%

63,092-6 1gC8H11NO 5g

3-Methoxy-N-methylaniline, 97%

63,093-4 1gC8H11NO 5g

2-Amino-4-phenylthiazole, 97%

64,275-4 1gC9H8N2S 5g

4-(1,2,4-Triazolylmethyl)aniline

64,169-3 5gC9H10N4 25g

2,4,6-Trimethyl-N-methylaniline, 97%

63,104-3 1gC10H15N 5g

N-Boc-4-aminophenol, 97%

63,594-4 5gC11H15NO3 25g

N-Boc-3-aminomethylpyridine, 97%

63,444-1 1gC11H16N2O2 5g

4-(2,2-Dicyanovinyl)-N-bis(hydroxyethyl)aniline, 95%

63,227-9 250mgC14H15N3O2 1g

4-Benzyloxy-N-methylaniline, 97%

63,103-5 1gC14H15NO 5g

N,N-Di-Boc-2-iodoaniline, 97%

64,424-2 1gC16H22INO4 10g

4-Bromo-N,N-diphenylaniline, 97%

64,383-1 5gC18H14BrN 25g

Br

N

N

O O

O

O

I

HN

CH3

O

CN

CN

NOHHO

N

NH

O

O

HN

HO

O

O

HN

CH3

CH3H3C

CH3

NN

N

H2N

N

S NH2

HN

CH3H3CO

HN

CH3

OCH3

N NH2

BrCH3

H3C

NH2

H3CI

HN

CH3F

NH2

CH3

Br

HN

CH3Br

HN

CH3

ClCl

NH2

F

Br

CH3

NH2

FCN

NH2

ClF3C

NH2

Br OCF3

NH2

Br NH2

NH2

IO2N

NH2

ClF

F

N NH2

I NO2

Aryl Amines

Am

ides

/ B

en

zyl

Am

ines

an

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Hali

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Ready to scale up? For competitive quotes on larger quantities or custom synthesis, contact Sigma-Aldrich Fine Chemicals at 1-800-336-9719 (USA), or visit www.sigma-aldrich.com/safc. O

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3’-Nitroacetanilide, 97%

64,425-0 5gC8H8N2O3 25g

4’-Nitro-2’-(trifluoromethyl)acetanilide, 97%

63,893-5 5gC9H7F3N2O3 25g

3-(4-Fluorophenyl)-2-propenamide, 97%

63,996-6 5gC9H8FNO 25g

4-Acetamidoacetophenone, 97%

63,136-1 5gC10H11NO2 25g

N-(3-Acetyl-4-hydroxyphenyl)butanamide, 97%

63,687-8 5gC12H15NO3 25g

2-Chloro-5-nitrobenzanilide, 97%

64,235-5 5gC13H9ClN2O3 25g

4-Aminobenzanilide, 95%

63,889-7 5gC13H12N2O 25gN

H

O

H2N

Cl

O2NNH

O

HO

NH

OH3C

O

H3C

O

NH

CH3

O

F

NH2

O

NH

CH3

OO2N

CF3

NH

CH3

O

O2N

Amides (continued)

2,5-Dichlorobenzyl bromide, 97%

54,898-7 5gC7H5BrCl2 25g

2,6-Difluorobenzyl chloride, 97%

55,995-4 5gC7H5ClF2 25g

4-Chlorobenzyl bromide, 97%

55,895-8 25gC7H6BrCl 100g

2-Iodobenzyl bromide, 97%

63,460-3 1gC7H6BrI 5g

4-(Methylthio)benzyl bromide, 97%

63,481-6 1gC8H9BrS 5g

2-Fluoro-4,5-dimethoxybenzyl chloride

52,651-7 1gC9H10ClFO2

3-Phenoxybenzyl chloride, 97%

59,093-2 1gC13H11ClO 5g

3,5-Di-(tert-butyl)-benzyl bromide

57,147-4 1gC15H23Br 5g

2,3-Difluorobenzylamine, 97%

53,861-2 5gC7H7F2N 25g

4-Bromobenzylamine, 96%

47,915-2 500mgC7H8BrN 1g

4-Iodobenzylamine hydrochloride

59,713-9 1gC7H8IN 5g

4-Cyanobenzylamine hydrochloride, 97%

63,139-6 5gC8H8N2 25g

2-Bromo-N-methylbenzylamine, 97%

63,116-7 1gC8H10BrN 5g

3-Bromo-N-methylbenzylamine, 97%

63,115-9 1gC8H10BrN 5g

4-Bromo-N-methylbenzylamine, 97%

63,114-0 1gC8H10BrN 5g

2-Chloro-N-methylbenzylamine, 97%

12,685-3 1gC8H10ClN 5g

3-Chloro-N-methylbenzylamine, 97%

63,111-6 1gC8H10ClN 5g

2-Fluoro-N-methylbenzylamine, 97%

63,109-4 1gC8H10FN 5g

3-Fluoro-N-methylbenzylamine, 97%

63,110-8 1gC8H10FN 5g

4-Fluoro-N-methylbenzylamine, 97%

59,384-2 1gC8H10FN 5g

3-Hydroxy-4-methoxybenzylamine hydrochloride, 97%

63,133-7 5gC8H11NO2

3-Methyl-N-methylbenzylamine, 97%

63,113-2 1gC9H13N 5g

2-Methoxy-N-methylbenzylamine, 97%

59,395-8 1gC9H13NO 5gN

HOCH3

CH3

HN CH3

H3C

H3CO

NH2

• HCl

OH

NHCH3

F

HN CH3

F

HN CH3

F

HN CH3

Cl

NH

Cl

CH3

HN CH3Br

HN CH3

Br

HN CH3

Br

NC

NH2

• HCl

• HCl

NH2

I

Br

NH2

NH2

FF

Br

Cl

O

Cl

F

H3CO

H3CO

H3CS

Br

I

Br

Br

Cl

Cl

FF

Br

Cl

Cl

Benzyl Amines and Benzyl Halides

Ben

zyl

Am

ines

an

d B

en

zyl

Hali

des

/ C

arb

oxyli

c A

cid

s

TO ORDER: Contact your local Sigma-Aldrich office (see back cover),call 1-800-558-9160 (USA), or visit sigma-aldrich.com.s

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6

3-Methoxy-N-methylbenzylamine, 97%

63,112-4 1gC9H13NO 5g

3,4-Dimethoxy-N-methylbenzylamine, 97%

63,108-6 1gC9H13NO2 5g

4-tert-Butylbenzylamine, 97%

63,128-0 5gC11H17N 25g

N-Boc-2-bromobenzylamine, 97%

63,406-9 1gC12H16BrNO2

N-(3,4-Methylenedioxybenzylidene)benzylamine, 97%

63,759-9 1gC15H13NO2 5g

N-Benzylidene-N-(diphenylmethyl)-amine, 97%

64,455-2 1gC20H17N 5g

N

O

O

N

NH

O

OBr

NH2

HN CH3

H3CO

H3CO

HN CH3

H3CO

Benzyl Amines and Benzyl Halides (continued)

1,3-Thiazole-4-carboxylic acid, 97%

63,365-8 1gC4H3NO2S 5g

2-Bromo-3-thiophenecarboxylic acid, 97%

63,812-9 1gC5H3BrO2S 5g

3-Bromothiophene-2-carboxylic acid, 97%

63,301-1 5gC5H3BrO2S 25g

5-Chlorothiophene-2-carboxylic acid, 97%

63,300-3 5gC5H3ClO2 25g

4-Methyl-1,3-thiazole-5-carboxylic acid, 97%

63,366-6 1gC5H5NO2S 10g

5-Methylisoxazole-4-carboxylic acid, 97%

63,377-1 1gC5H5NO3 10g

2-Bromonicotinic acid, 97%

63,246-5 1gC6H4BrNO2 5g

3-Chloroisonicotinic acid, 97%

63,341-0 1gC6H4ClNO2 5g

3-Fluoroisonicotinic acid, 97%

63,875-7 1gC6H4FNO2 10g

Ethyl 2-bromothiazole-5-carboxylate, 97%

64,249-5 1gC6H6BrNO2S 5g

4-Methylthiophene-2-carboxylic acid, 97%

63,355-0 5gC6H6O2 25g

3-Chloro-2,4,5-trifluorobenzoic acid, 97%

64,330-0 5gC7H2ClF3O2

2-Bromo-4,5-difluorobenzoic acid, 97%

63,890-0 5gC7H3BrF2O2 25g

5-Bromo-2-fluorobenzoic acid, 97%

63,645-2 1gC7H4BrFO2 5g

2-Chloro-5-iodobenzoic acid, 97%

63,173-6 5gC7H4ClIO2 25g

2-Methoxynicotinic acid, 97%

63,276-7 1gC7H7NO3 5g

4-Cyclopropyl-4-oxobutyric acid

51,460-8 500mgC7H10O3 1g

4-Chloro-2-methylbenzoic acid, 97%

63,403-4 1gC8H7ClO2 5g

2-Methyl-4-nitrobenzoic acid, 97%

63,831-5 5gC8H7NO4

2-Methyl-5-nitrobenzoic acid, 97%

63,830-7 1gC8H7NO4 5g

4-Methyl-2-nitrobenzoic acid, 97%

63,829-3 1gC8H7NO4 5g

3-4-Ethylenedioxypyrrole-2,5-dicarboxylic acid, 95%

63,720-3 500mgC8H7NO6

3-(2-Bromophenyl)propionic acid, 97%

64,391-2 5gC9H9BrO2 25g

3-(4-Bromophenyl)-1H-pyrazole-5-carboxylic acid, 97%

63,370-4 1gC10H7BrN2O 5g

NH

NHO

O

Br

Br

OH

O

NH

OO

HO

O

OH

O

NO2

O OH

CH3

CH3

O OH

O2N

CH3

O OH

NO2

CH3

Cl

O OH

OH

O

O

N

OH

O

OCH3

I

Cl

O OH

O

OH

F

Br

O OH

FF

Br

F F

OH

O

Cl

F

S

H3C

OH

O

N

SO

OBr

H3C

N

F

O OH

N

Cl

O OH

N

OH

O

Br

ON

H3C

HOO

N

S

H3C

HO

O

SClOH

O

SOH

O

Br

S Br

OH

N

S

OHO

Carboxylic Acids

Carb

oxyli

c A

cid

s /

Est

ers

Ready to scale up? For competitive quotes on larger quantities or custom synthesis, contact Sigma-Aldrich Fine Chemicals at 1-800-336-9719 (USA), or visit www.sigma-aldrich.com/safc. O

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US$ 7

3-Phenyl-5-isoxazolecarboxylic acid, 97%

63,369-0 1gC10H7NO3 5g

5-Phenyl-4-isoxazolecarboxylic acid, 97%

63,368-2 1gC10H7NO3 5g

3-Phenyl-1H-pyrazole-5-carboxylic acid, 97%

63,373-9 1gC10H8N2O2 5g

3-Chloro-4-methoxycinnamic acid, 97%

63,876-5 1gC10H9ClO3 5g

5-Amino-1-phenyl-1H-pyrazole-4-carboxylic acid, 97%

63,981-8 1gC10H9N3O2 5g

3-(3-Chloro-4-methoxyphenyl)-propionic acid, 97%

63,877-3 1gC10H11ClO3 5g

10-Bromodecanoic acid, 95%

54,139-7 5gC10H19BrO2 25g

1-Phenyl-5-(trifluoromethyl)-1H-pyrazole-4-carboxylic acid, 97%

63,976-1 1gC11H7F3N2O2 5g

6-Phenyl-4-pyrimidinecarboxylic acid, 97%

63,367-4 1gC11H8N2O2 5g

5-Amino-1-(4-methoxyphenyl)-1H-pyrazole-4-carboxylic acid, 97%

63,978-8 1gC11H11N3O3 5g

1-(4-Methoxyphenyl)-5-(trifluoro-methyl)-1H-pyrazole-4-carboxylic acid, 97%

63,982-6 1gC12H9F3N2O3 5g

1,4,5,8-Naphthalenetetracarboxylic acid, 97%

64,150-2 5gC14H8O8 25g

4’,6’-Dimethoxy-2’-hydroxy-2-phenylacetophenone, 96%

63,062-4 1gC16H16O4 5g

16-Bromohexadecanoic acid, 99+%

56,870-8 5gC16H31BrO2

OH

OBr

OOH

OOH3C

CH3

OHO

OOH

HO O

HO O

NN

F3C

HOO

OH3C

NN

H2N

HOO

OCH3

N

NHO

O

NN

F3C

HOO

OH

OBr

OH

O

OCl

H3C

NN

H2N

HOO

OH

O

OCl

H3C

NH

NHO

O

ON

OHO

ONHO

O

Carboxylic Acids (continued)

Methyl 3-nitropropionate, 97%

31,687-3 1gC4H7NO4 5g

Methyl 6-chloronicotinate, 98%

63,117-5 1gC7H6ClNO2 5g

25g

Methyl 5-chloro-2-nitrobenzoate, 97%

57,982-3 5gC8H6ClNO4 25g

Methyl 4-hydroxy-3-iodobenzoate, 97%

63,194-9 1gC8H7IO3 5g

Methyl 5-aminosalicylate, 97%

63,643-6 1gC8H9NO3 5g

Methyl 3-amino-4-methylbenzoate, 97%

64,060-3 5gC9H11NO2 25g

Methyl 4-fluorocinnamate, 97%, predominantly trans

59,244-7 5gC10H9FO2 25g

Ethyl 2-bromo-(4-bromophenyl)acetate, 97%

63,857-9 5gC10H10Br2O2 25g

Methyl 4-vinylbenzoate, 97%

63,740-8 1gC10H10O2 5g

Methyl 3-((Z)-2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate, 97%

54,977-0 25gC10H12ClF3O2

N,N-Dibenzyl-o-serine methyl ester, 97%

54,531-7 1gC18H21NO3 5g

OCH3

O

HON

OCH3

OClF3C

OCH3

O

Br

Br

O

O

OCH3

O

F

O

OCH3

NH2

H3C

OH

OCH3

OH2N

O

HO

IOCH3

OCH3

O

NO2

Cl

NCl

OCH3

O

OCH3

O

O2N

Esters

Iso

cyan

ate

s an

dIs

ocy

an

ides

/ K

eto

nes

TO ORDER: Contact your local Sigma-Aldrich office (see back cover),call 1-800-558-9160 (USA), or visit sigma-aldrich.com.s

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Benzhydryl isothiocyanate, 97%

59,169-6 1gC4H11NS 5g

2,4,5-Trichlorophenyl isothiocyanate, 97%

63,000-4 1gC7H2Cl3NS 5g

2-Chlorophenyl isocyanide, 97%

59,411-3 1gC7H4ClN

4-Chlorophenyl isocyanide, 97%

59,422-9 1gC7H4ClN

2-Chloro-6-methylphenyl isocyanide, 97%

59,434-2 1gC8H6ClN

2-Tolylisocyanide, 95%

59,390-7 1gC8H7N

4-Methoxyphenyl isocyanide, 97%

59,445-8 1gC8H7NO

2-4(Chlorophenethyl)isothiocyanate, 97%

59,137-8 1gC9H8ClNS 5g

2,5-Dimethylphenyl isocyanide, 95%

59,368-0 1gC9H9N

2,6-Dimethylphenyl isocyanide, 96%

59,488-1 1gC9H9N 5g

3-Ethoxyphenyl isocyanate, 97%

55,701-3 1gC9H9NO2 5g

2-Naphthyl isocyanide, 97%

59,478-4 1gC11H7N

2,5-Dimethoxyphenethyl isocyanate, 97%

57,167-9 1gC11H13NO3 5g

4-Diethylaminophenyl isocyanide, 97%

59,455-5 1gC11H14N2

Trityl isothiocyanate, 95%

59,190-4 1gC20H15NS 10g

NCS

NC

N

NCO

OCH3

H3CO

NC

NCOO

NC

CH3

CH3

N

CH3

H3CC

Cl

NCS

NC

H3CO

N

CH3

C

NC

CH3

Cl

NC

Cl

N

Cl

C

NCS

Cl

Cl

Cl

NCS

Isocyanates and Isocyanides

3’-Bromo-4’-fluoroacetophenone, 96%

33,967-9 5gC8H6BrFO 25g

2-Bromo-2’-hydroxyacetophenone, 97%

59,493-8 1gC8H7BrO2 5g

2-Bromo-3’-hydroxyacetophenone

59,470-9 1gC8H7BrO2 5g

3’-Iodo-4’-methoxyacetophenone, 97%

63,151-5 5gC9H9IO2 25g

1-(5-Bromo-2-hydroxyphenyl)-1,3-butanedione

54,636-4 1gC10H9BrO3 5g

6’-Ethoxy-2’-hydroxyacetophenone, 98%

57,920-3 1gC10H12O3 5g

2’-Hydroxy-4’-methoxypropiophenone, 97%

59,225-0 5gC10H12O3

4’,6’-Dimethoxy-2’-hydroxyacetophenone, 97%

63,058-6 5gC10H12O4

3-Allyl-4-hydroxyacetophenone, 97%

63,275-9 1gC11H12O2 5g

4’-Ethoxy-2’-hydroxy-3’-methylacetophenone, 97%

63,490-5 1gC11H14O3 5g

4-Bromoacetophenone diethyl acetal, 95%

56,859-7 1mlC12H17O2Br 5ml

2-Amino-4-bromobenzophenone, 95%

56,143-6 1gC13H10BrNO 5g

ONH2

Br

OCH3

Br

O

CH3

O

OHCH3

O

HO

CH3

O

CH3

O

OCH3

OH

H3CO

OOH

H3CO

O

CH3

OH

O

O

Br

CH3

OOH

CH3

O

IH3CO

OH

OBr

OBr

OH

O

F

CH3

Br

Ketones

Nit

rost

yre

nes

/ N

itri

les

Ready to scale up? For competitive quotes on larger quantities or custom synthesis, contact Sigma-Aldrich Fine Chemicals at 1-800-336-9719 (USA), or visit www.sigma-aldrich.com/safc. O

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US$ 9

trans-2,4-Dichloro-β-nitrostyrene, 97%

64,216-9 1gC8H5Cl2NO2 5g

trans-2,6-Dichloro-β-nitrostyrene, 97%

64,214-2 1gC8H5Cl2NO2 5g

trans-3,4-Dichloro-β-nitrostyrene, 97%

64,215-0 1gC8H5Cl2NO2 5g

trans-2-Bromo-β-nitrostyrene, 95%

64,221-5 5gC8H6BrNO2

trans-3-Bromo-β-nitrostyrene, 97%

64,220-7 5gC8H6BrNO2

trans-2-Chloro-β-nitrostyrene, 97%

64,218-5 5gC8H6ClNO2

trans-3-Chloro-β-nitrostyrene

64,219-3 5gC8H6ClNO2

trans-4-Chloro-β-nitrostyrene, 97%

64,217-7 5gC8H6ClNO2

trans-2-Hydroxy-β-nitrostyrene, 97%

63,968-0 1gC8H7NO3 5g

trans-3-Hydroxy-β-nitrostyrene, 96%

63,967-2 1gC8H7NO3 5g

trans-4-Hydroxy-β-nitrostyrene, 97%

63,972-9 1gC8H7NO3 5g

trans-2-Chloro-3-hydroxy-4-methoxy-β-nitrostyrene, 97%

64,154-5 1gC9H8ClNO4 5g

trans-2-Methoxy-β-nitrostyrene, 97%

63,971-0 1gC9H9NO3 5g

trans-2-Chloro-3,4-dimethoxy-β-nitrostyrene, 97%

63,839-0 1gC10H10ClNO4

trans-3-Chloro-4,5-dimethoxy-β-nitrostyrene, 97%

64,155-3 1gC10H10ClNO4

trans-2,3-Dimethoxy-β-nitrostyrene, 97%

63,970-2 1gC10H11NO4 5g

trans-2,5-Dimethoxy-β-nitrostyrene, 97%

63,969-9 1gC10H11NO4 5g

trans-2-Benzyloxy-β-nitrostyrene, 97%

63,823-4 1gC15H13NO3 5g

trans-3-Benzyloxy-β-nitrostyrene, 97%

63,825-0 1gC15H13NO3 5g

trans-4-Benzyloxy-β-nitrostyrene, 97%

63,824-2 1gC15H13NO3 5g

trans-2-Chloro-3-benzyloxy-4-methoxy-β-nitrostyrene, 97%

64,153-7 1gC16H14ClNO4 5g

trans-3-Chloro-4-benzyloxy-5-methoxy-β-nitrostyrene, 97%

64,152-9 1gC16H14ClNO4 5g

trans-3,4-Dibenzyloxy-β-nitrostyrene, 97%

63,826-9 1gC22H19NO4 5g

trans-3,5-Dibenzyloxy-β-nitrostyrene, 97%

63,827-7 1gC22H19NO4

H NO2

H

O

O

H NO2

H

O O

OCl

H3CO NO2

H

H

H3COO

NO2

H

H

Cl

HNO2

HO

H NO2

H

O

H NO2

HO

NO2

H

H

O

OH3C

CH3

NO2

H

H

OCH3O

H3C

H3COCl

NO2

H

HH3CO

H NO2

H

OCH3H3CO

Cl

NO2

H

H

OCH3

H3COOH

NO2

H

H

Cl

NO2

H

H

HO

NO2

H

H

OH

NO2H

OHH

NO2

H

H

Cl

NO2

H

H

Cl

NO2

H

H

Cl

NO2

H

H

Br

NO2

H

H

Br

NO2

H

H

ClCl

NO2

H

H

Cl

Cl

NO2

H

H

ClCl

Nitrostyrenes

6-(Trifluoromethyl)nicotinonitrile, 97%

64,009-3 1gC7H3F3N2 5g

2,6-Dichloro-4-methylnicotinonitrile, 97%

64,352-1 5gC7H4Cl2N2 25g

2-Methoxy-5-pyridinecarbonitrile, 97%

64,225-8 1gC7H6N2O 5g

NH3CO

N

N ClCl

CH3 NNF3C

N

Nitriles

Nit

rile

s /

Su

lfo

nyl

Ch

lori

des

TO ORDER: Contact your local Sigma-Aldrich office (see back cover),call 1-800-558-9160 (USA), or visit sigma-aldrich.com.s

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10

3-Bromo-4-methylbenzonitrile

64,239-8 5gC8H6BrN 25g

3-Chloroveratronitrile, 97%

63,993-1 5gC9H8ClNO2 25g

Benzofuran-3-acetonitrile, 95%

63,842-0 250mgC10H7NO 1g

3,5-Dimethyl-4-methoxybenzonitrile, 97%

63,881-1 1gC10H11NO 5g

5-(3,4-Dichlorophenyl)-2-furonitrile

63,122-1 1gC11H5Cl2NO 5g

5-(2-Nitrophenyl)-2-furonitrile, 97%

63,991-5 1gC11H6N2O3 5g

3-(4-Aminophenyl)-benzonitrile, 97%

64,402-1 1gC13H10N2 5g

4-(4-Aminophenyl)-benzonitrile, 95%

64,404-8 1gC13H10N2 5g

4-(3-Aminophenyl)-benzonitrile

64,405-6 1gC13H10N2 5g

(E)-α-(2,4-Dichlorophenyl)-4-fluorocinnamonitrile, 97%

59,602-7 1gC15H8Cl2FN 5g

(E)-α-(4-Fluorophenyl)-2,4-dichlorocinnamonitrile, 97%

59,657-4 1gC15H8Cl2FN 5g

(E)-α-(4-Chlorophenyl)-4-fluorocinnamonitrile, 97%

59,613-2 1gC15H9ClFN 5g

(E)-α-(4-Fluorophenyl)-4-chlorocinnamonitrile, 97%

59,646-9 1gC15H9ClFN 5g

F

NCl

Cl

NF

F

NCl

Cl

Cl Cl

NF

N

H2N

N

H2N

H2N

N

O

NO2

N

O

Cl

Cl

N

H3CO

H3C

CH3

N

O

N

ClH3CO

H3CON

BrH3C

N

Nitriles (continued)

5-Bromothiophene-2-sulfonyl chloride

63,622-3 5gC4H2BrClO2S2 25g

4-Bromo-2,6-dichlorobenzenesulfonyl chloride, 97%

55,874-5 1gC6H2BrCl3O2S 5g

4-Bromo-2,5-difluorobenzenesulfonyl chloride

63,285-6 1gC6H2BrClF2O2S 5g

2-Chloro-4-fluorobenzenesulfonyl chloride, 95%

63,891-9 1gC6H3Cl2FO2S 5g

5-Chloro-2-fluorobenzenesulfonyl chloride, 97%

55,868-0 1gC6H3Cl2FO2S

2,3-Dichlorobenzenesulfonyl chloride, 97%

54,691-7 5gC6H3Cl3O2S 25g

2-Chloro-4-(trifluoromethyl)-benzenesulfonyl chloride, 97%

63,836-6 1gC7H3Cl2F3O2S 5g

4-(trifluoromethyl)benzenesulfonyl chloride, 97%

56,584-9 1gC7H4ClF3O2S 5g

2-(Trifluoromethoxy)benzenesulfonyl chloride, 97%

57,994-7 1gC7H4ClF3O3S

3-(Trifluoromethoxy)benzenesulfonyl chloride, 97%

57,950-5 1gC7H4ClF3O3S

3-Cyanobenzenesulfonyl chloride, 97%

63,835-8 1gC7H4ClNO2S 5g

4-Cyanobenzenesulfonyl chloride, 97%

63,833-1 1gC7H4ClNO2S 5g

2-Fluoro-5-methylbenzenesulfonyl chloride, 97%

63,888-9 1gC7H6ClFO2S 5g

4-Methyl-3-nitrobenzenesulfonyl chloride, 97%

63,286-4 5gC7H6ClNO4S

m-Toluenesulfonyl chloride

56,635-7 5gC7H7ClO2S 25g

4-n-Propylbenzenesulfonyl chloride

53,938-4 5gC9H11ClO2S 25g

100gS

ClO

O

S

CH3

ClO

O

S ClO

O

H3CNO2

S ClO

O

F

H3C

S ClO

O

N

S ClO

O

N

SCl

O

O

OCF3

S

OCF3

Cl

O

O

SClO

O

F3C

SClO

O

F3C Cl

SClO

O

ClCl

SClO

O

F

Cl

S ClO

O

ClF

S ClO

O

Br

F

F

SClO

O

Br

Cl

Cl

SBr SO

O Cl

Sulfonyl Chlorides

Su

lfo

nyl

Ch

lori

des

/ O

ther

Su

lfu

r-co

nta

inin

g

Bu

ild

ing

Blo

cks

Ready to scale up? For competitive quotes on larger quantities or custom synthesis, contact Sigma-Aldrich Fine Chemicals at 1-800-336-9719 (USA), or visit www.sigma-aldrich.com/safc. O

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US$ 11

3-(4-Methoxyphenoxy)propane sulfonyl chloride, 98%

57,551-8 1gC10H13ClO4S 5g

Pentamethylbenzenesulfonyl chloride, 97%

56,536-9 5gC11H15ClO2S 25g

Biphenyl-4-sulfonyl chloride

53,693-8 5gC12H9ClO2S 25gS

ClO

OSCl

O O

CH3

H3C

H3C CH3

CH3

O

H3CO

SClO

O

Sulfonyl Chlorides (continued)

3-(Methylthio)propylamine, 97%

63,909-5 1gC4H11NS 5g

2-(2-Methoxyethoxy)ethanethiol, 97%

63,229-5 1gC5H12O2S

1H-Benzotriazole-4-sulfonic acid, 97%

63,280-5 1gC6H5N3O3S 5g

2-Bromobenzenesulfonamide, 97%

64,460-9 1gC6H6BrNO2S 5g

N-Boc-thiourea, 97%

59,276-5 1gC6H12N2O2S 5g

4-Fluorophenylthiourea, 97%

63,294-5 1gC7H7FN2S 5g

5-Fluoro-2-mercaptobenzyl alcohol, 97%

63,924-9 1gC7H7FOS

1-Cyclohexen-1-yl trifluoromethanesulfonate, 97%

48,058-4 5gC7H9F3O3S 25g

4-Bromophenyl thioacetate, 97%

63,465-4 1gC8H7BrOS 5g

3-(Trifluoromethyl)phenylthiourea, 97%

63,293-7 1gC8H7F3N2S 5g

2,6-Dimethoxyphenyl trifluoromethanesulfonate, 97%

63,787-4 5gC9H9F3O5S 25g

Ethyl 5-fluoro-2-mercaptobenzoate, 97%

63,926-5 1gC9H9FO2S

Thiobenzylacetimidate hydrochloride, 96%

63,711-4 1gC9H11NS 5g

6-Quinolyltrifluoromethanesulfonate, 97%

63,344-5 1gC10H6F3NO3S 5g

Naphthalene-2-sulfonamide, 97%

63,407-7 1gC10H9NO2S 10g

3-(4-Methoxyphenoxy)propyl methanesulfonate, 98%

57,543-7 1gC11H16O5S 5g

9H-Carbazol-2-yl trifluoromethanesulfonate, 97%

63,920-6 1gC13H8F3NO3S 5g

4-(2-(4-Bromophenylsulfanyl)ethyl)-pyridene, 97%

64,223-1 1gC13H12BrNS 5g

2-(Phenylsulfonyl)-1,3-cycloheptadiene, 97%

55,892-3 1gC13H14O2S

Bis-(4-methoxyphenyl)disulfide, 97%

64,136-7 1gC14H14O2S2 5g

N-Boc-2-napthalenesulfonamide, 97%

63,921-4 1gC10H10Br2O2 5g

3,5-Di-tert-butylphenyl trifluoromethanesulfonate, 97%

59,322-2 1gC15H21F3O3S 10g

1,1’-Bi-2-naphthyl dimethanesulfonate, 97%

63,170-1 1gC22H18O6S2

OS

OS

CH3

O

O

O

O

CH3

OS

CF3O

O

SNH

O

OO

O

CH3

CH3

CH3

SS

OH3C

OCH3

SO

O

N

S

Br

NH

OS

CF3O

O

O

H3CO

OS

CH3

O

O

SNH2

O

O

N

OS

F3C

O

O

SCH3

NH

• HCl

SH

F

OO CH3

OS

CF3

O

O

OCH3

OH3C

NH

NH2

S

F3C

Br

S CH3

O

OS

CF3O

O

SH

F

OH

NH

NH2

SF

O NH

NH2

SO

SO

ONH2

Br

NH

NN

SO

OOH

H3CO

OSH

H3CS NH2

Other Sulfur-containing Building Blocks

Mis

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Bu

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Blo

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TO ORDER: Contact your local Sigma-Aldrich office (see back cover),call 1-800-558-9160 (USA), or visit sigma-aldrich.com.s

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12

2-Methoxyethyl chloroformate

59,229-3 5mlC4H7ClO3 25ml

250ml

1-(Dimethylamino)-2-nitroethylene, 97%

63,290-2 1gC4H8N2O2 5g

(R)-(-)-4-Penten-2-ol, 96%

55,803-6 1gC5H10O 5g

1,1-Bis(hydroxymethylcyclopropane), 95%

54,656-9 1gC5H10O2 5g

1-Dimethylamino-2-propylamine, 98%

58,818-0 10gC5H14N2 50g

2-Bromo-4,6-difluorophenol, 97%

57,946-7 1gC6H3BrF2O 5g

3,5-Dibromophenol, 97%

64,610-5 1gC6H4BrO 10g

2-Amino-4-chloro-6-nitrophenol, 97%

53,038-7 5gC6H5ClN2O3 25g

(S)-(+)-5-Hexen-2-ol, 97%

55,804-4 1gC6H12O 5g

N-Cyclohexylhydroxylamine

63,593-6 1gC6H13NO

11-Chloro-1-undecene, 97%

59,311-7 5mlC11H21Cl 25ml

2,7-Di(tert-butyl)-9-fluorenylmethyl chloroformate, 97%

55,100-7 1gC23H27ClO2

rac-trans-N,N’-Dimethylcyclohexane-1,2-diamine, 97%

63,308-9 5mlC8H18N2

HN

CH3

NH

CH3

O

ClO

Cl

HN

OH

OH

OH

NH2

NO2

Cl

OH

BrBr

OH

Br

F

F

NCH3

CH3NH2

OH

OH

OH

NO2N CH3

CH3

Cl OO

CH3

O

Miscellaneous Building Blocks

We manufacture over 40,000 products and can provide you with:NEW Rapid Pre-Clinical Custom Synthesis • Clinical cGMP Custom Manufacturing • Commercial cGMP Custom Manufacturing

We look forward to discussing your manufacturing needs!To discuss how our expertise can benefit your next scale-up project or to obtain a quote,

please call us at 800-336-9719 (USA) or visit us at www.sigma-aldrich.com/safc

France: tel. 0800 211 408 - fax 0800 031 052 • Germany: tel. 0800-51 55 000 - fax 0800-649 00 00 • Italy: tel. 02 33417310 - fax 02 38010737 • Japan: tel. 03 5796 7300 - fax 03 5796 7315 • Switzerland: tel. +41 81 755 2828 - fax +41 81 755 2815

U.K.: tel. 01747 833000 - fax 01747 833313 • USA: tel. 800 325 3010 or 314 771 5765 - fax 314 771 5757 • Email: [email protected]

Ready to scale up? For competitive quotes on larger quantities or custom synthesis, contact Sigma-Aldrich Fine Chemicals at 1-800-336-9719 (USA), or visit www.sigma-aldrich.com/safc. O

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L30,017-9

C8H9F2N 1gMW 157.16

L30,018-7

C8H9F2N 1gMW 157.16

L30,022-5

C9H10F3N 1g MW 189.18

L30,023-3

C8H9F2N 1gMW 157.16

L30,024-1

C8H9F2N 1gMW 157.16

L30,027-6

C8H9F2N 1gMW 157.16

L30,029-2

C8H9Cl2N 250mgMW 190.07

L48,018-5

C14H10O3 500mgMW 226.23

L30,036-5

C11H7FN2O2 500mgMW 218.19

L30,037-3

C12H10N2O3 500mgMW 230.23

L48,020-7

C14H13NO2 500mgMW 227.27

L30,065-9

C11H7NS 500mgMW 185.25

L30,082-9

C12H10ClN 250mg MW 203.67

L30,013-6

C13H11NO2 1gMW 213.24

L30,084-5

C12H10ClNO 250mgMW 219.67

L30,034-9

C20H26N2O3S 500mgMW 374.51

L30,038-1

C22H28N2O3 500gMW 368.48

L48,023-1

C22H27BrN2O3 500mgMW 447.38

L48,026-6

C15H22N2O4S 500mgMW 326.42

L48,027-4

C15H21BrN2O4S 500mgMW 405.31

L48,028-2

C17H23BrN2O4 500mgMW 399.29

New Building Blocks Aldrich is proud to bring you the following new building blocks. Each month, we will provide a new set of building blocks

that are suitable for your medicinal and synthetic chemistry needs. If you require a building block, but do not see it on thelist, please contact [email protected]. To place an order for any of the items below, please call 800-558-9160 (USA) or contactyour local Sigma-Aldrich office.