vflseyasf^TtiH^-7C Of»f*l '?C^Ws-^o)

i^0

CQliForniQ RnolyticQl Loborotories, Inc.

California Rnolyticol Laboratories, Inc.2544 Industrial Boulevard • UUest Socromento, Cfl 95691 • (916) 372-1393

September 25, 1984Lab No. T2365-T2388Received: 8/24/84Case 3089/0768-01-6916

Mr. William Langley ' ' l

U.S.EPA 0Region 6 , Laboratory 06608 Hornwood DriveMonterey Park Plaza, Bidg. CHouston, Texas 77074Dear Mr. Langley,Enclosed are data summaries, documentation and QA/QC for samples comprisingcase 3089/07 received August 24, 1984. These samples were logged in under CALLab numbers T2365 through T2388 and analyzed under contract 68-01-6916. Thecross correlation of ID numbers is shown on the data summary.Sample DF003911 (T2375) was analyzed as a native spike. The native spikerecovery was 98%. A partial scan of sample DF003913 (T2377) will be sent withour next data package to you, i . e . , with case number 3089/11. All QA/QC datacomplies with the contract requirements.If you have any questions about the data, please don't hesitate to call.Sincerely,

r CA^-t i/< /i fv[t</i^^f"t'rv{r'1"0 i /]Paul A. Taylor, Ph/D. Michael J' Miille, Ph.D. TeA. J. VergaraPresident \/ Director of GC/MS Services Data Specialist

cc SMOEMSL

TCDD DATA REPORTCalifornia Analytical, Laboratories

25 4 Industrial Blvd.W. Sacramento, CA 95691

Page

Lab: Ca l i fo rn ia Analy t ica l LaboratoriesCase No. 3089/07Batch/Shipment No. 7

Report Date; ________CoLunn: 60 m X 0.32 nrn id

CalLabs

!D

T2365HBT2365T2366T2367T2368T2369T2370T2371T2372FCT2373T2374T2375NST2376T2377T2378T2379T2380T2381T2382T2383T2384T238512386T23860I23B7T2388

Sample(lumber

METHOO BLANKDF003901DF003902DF003903DF003904DF003905DF003906DF003907DF003908DF003909DF003910DF003911NSDF003912DF003913 —DF003914DF003915DF003916DF003917DF003918DF003919DF003920DF003921DF003922DF003922DDF003923DF003924

Al iquotC Uet Ut.U (grams)

N 10 .00H 1 0 . 1 3H 9.98N 9.95N 10.20N 9.99N 10.02N 1 0 . 1 5Y 100.00H 10 .05N 9.95N 9.99M 10.07N 10.50M 10.08N 1 0 . 1 4H 1 0 . 0 1N 10 .45N 10 .07N 9.97N 1 0 . 1 7N 10 .00N 10 .00H 1 0 . 0 1N 10 .50H 10 -07

PPBTCDDMeas

ND0.220 .100.100.37

ND0.390.34

NDNOND

0.980 . 1 07.580 . 1 4

N0NDNDN0NDND

0.610.240.250.31

N0

PP8TCDDDet.Lmt

0.05

0.04

0.010.050.06

0.040.040.030.090.040.06

0.10

InstID Date

5 09/20/15 09/20/!5 09/20/15 09/20/15 09/20/15 09/20/15 09/20/15 09/20/15 09/24/15 09/20/15 09/21/15 09/21/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/15 09/24/1

320/ 332/ Surrg SurrDate Time 322 334 Meas X Ace

09/20/B4 1809/20/84 1909/20/84 1909/20/84 2009/20/84 2009/20/84 2009/20/84 2209/20/S4 2209/24/84 1609/20/84 2309/21/84 2009/21/84 2109/24/84 0909/24/84 0909/24/84 1009/24/84 1009/24/84 1109/24/84 1109/24/84 1109/24/84 1209/24/84 1409/24/84 1409/24/84 1509/24/84 1509/24/84 1509/24/84 16

2203300934551038490537312044053904275818294916385925

00 1.00 0.80 0.91 9100 0.75 0.79 0.97 9700 0.79 0.81 1.04 10400 0.75 0.81 1.00 10000 0.79 0.79 1.00 10000 1 . 1 8 0.81 0.99 9900 0.75 0.81 1.01 10100 0.81 0.72 1 . 1 5 11500 1.00 0.73 0.10 9600 1.00 0.78 1.03 10300 1.00 0.75 1 . 0 1 10000 0.78 0.74 1.02 10200 0.76 0.74 0.89 9000 0.78 0.74 0.89 9300 0.81 0.74 0.94 9400 1.00 0.73 0.95 9700 1.00 0.75 0.94 9400 1,00 0.72 0.89 9300 1.00 0.76 0.95 9600 1.00 0.71 0.94 9300 1.00 0.75 0.92 9300 0.76 0.74 0.94 9400 0.86 0.73 0.94 9400 0.80 0.74 0.93 9300 0.81 0.70 0.91 9600 0.57 0.71 0.96 97

100277283

1279659946

68003438441955

701685704

77900716586

468323326828688

19923180

134429184

1696676342

57604562351748

898967525

1 0 0 2 1 5 020600

612503887236006

24695568

73607064

14668490106388

2598831805

509723244

6°25°213830

406942764023082

1300

2458411 1 2 2 2 418837533205139400033963422201634227163498

2489312243031876562052702438882S56523 0 1 1 8 3261226226466528671370088222730186194318238264814

1458935012

417396229348368824682417781544702703447609559960134077482633463463378503468331518671624127635079578358496164

11543807925754960814050976862855839983042072767

5204342915104574248454039B8032870947 RATIO UNACCEPTABLE5534327773471841646179916176565082636361436969918385018680447661916852871517880112075066016955029893925179267243188 Used H t . Ratios102080 NO 257; BAO BA^i

MB = Method BlankP = Partial Scan/Confirmatory Analysis

MS = Native TCOD Spike0 = Duplicate/Fortified field Blank

R l = Re-injection

FB = field BlankND = Hot DetectedDL = Detection LimitRX = Re-extractionFC = Further Cloon-up EPA Option-D

^Corrected for contribution by native TCDD; 0.9% of m/z 322 subtracted

0 0 5

QUALITY CONTROL SUMMARY

Case No. 3c-^ i Of-

Mean Accuracy , Surrogate Measurements : ____101 /c___ f of Data Po in t s T-Lp'••^.

Accuracy, Fort i f ied/Spike Field Blank: _____(?? h_____ Sample ;? ^F0£:.',,-, /_!___

• "'iR e l . D i f f . ( ' ;) , D u p l i c a t e A n a l y s i s : _______I • I %____Sample » _DFO_ 0 2.Z.

0

C a l i f o r n i a A n a l y t i c a l LaboratoriesD a i l y Ca l i b r a t i on Sunnary

nat ive Injection InjectionCone ID Date Time

PC 5 09/20/84 07 01 00CC1 5 09/20/84 07CC1 5 09/20/84 1 1PC 5 09/20/84 1 2PC 5 09/20/84 16CC1 5 09/20/84 16CC1 5 09/20/84 21PC 5 09/20/84 21CC1 5 09/20/84 23PC 5 09/20/84 23

325318235517433557

000000000000000000

StandardID

DH5840920ST5840920ST5840920ADH5840920ADH5840920BST5840920BST5840920CDH5840920CST5B409200DH58409200

RF RF IsororA320

26727810232078545

153752133974

9 8 1 1 273707

34643271784

208702

A322

34641613185610464620192717559412840499348

45054191206

268588

A323

44520

2833223983

62956

37690

A328

2320047892868312

1618711325578353663528

34341460226

220501

A332

523M7551203439079296782266840534459399359675113397775417247

A334

64BB15685231549747364574326664655095516637825939490583516051

TCDD

Native Surr. Resolut'ns

1.05 .98 5.97.95.93

1.081.04.95.94

1.06.92

1.02

.05

.14

.21 7.40

.10 7.40

.15

.14

.13 11 .80

. 1 1

.17 11 .80

Solution ID Codes:PC = Performance cheCC1 = ConcentrationCC2 = ConcentrationCC3 = ConcentrationCC4 = ConcentrationCC5 = Concentration

ck solua Iibrata Iibratalibrata 1ibratalibrat

ionn soLutn soLutn soli-itn soLutn soLut

on #1 = 0.2 ug/mlon #2 = 1-0 ug/mlon »3 = 5.0 ug/mlon *4 = 20.0 ug/mlon *5 s 40.0 ug/ml

00

California Analytical LaboratoriesDaily Calibration Sunmary

Native Injection Injection StandardCone ID Date Time ID

CC1PCCC1PC

5 09/21/845 09/21/845 09/21/845 09/21/84

19:25:00 ST5840921P19:48:00 DH5840921A21:54:00 ST5840921022:19:00 DH58409218

56908 78328331522 440784 58685115614 149540223504 297637 36903

A328 A33257416 331499

354199 68628098727 640703230406 458530

RFNative

R FSurr.

TCDDIsomer

ResoLut'ns453311934562853663624287

.86 1.20

.95 1.08 14.70

.89 1 . 0 9

. 9 6 1.05 11.80

Solution ID Codes:PC = Performance check solutionCC1 = Concentration calibrat

calibratcalibratcalibratcalibrat

ion (

ion 'ion sion sion s

ioLutiiolutiiolutiiolutiioluti

CC2 = ConcentrationCC3 = ConcentrationCC4 = ConcentrationCC5 = Concentration

on #1 = 0.2 ug/mlon #2 = 1 . 0 ug/mlon #3 = 5-0 ug/mlon #4 = 20.0 ug/mLon #5 = 40.0 ug/mL

0 0

California Analytical LaboratoriesDaily Calibration Summary

Native InjectionCone ]D Date

PCCC1CC1PCCC1PC

09/24/8409/24/8409/24/8409/24/8409/24/8409/24/84

ectionime

46 004125554509

0000000000

Standard[D

OH5840924ST5840924ST5840924ADH5840924AST5840924BDH5840924B

2378296439473982245093112166146943

A322

29272484233

103818321794145281;193077

TCDDRF RF Isomer

»332 A334 Native Surr. Resolut'ns

37668 2244475519167578

22979092412

143368

4588203719394 5 5 0 1 5497215644448306901

5963115097506 2 1 5 1 4690303881479421295

1 . 0 1.84.83.95.84.93

1.051.031 . 0 3.96

1 . 0 0.97

Solution ID Codes:

PC = Performance check solutionCC1 = Concentration cal

caLcalcalcal

ibraiibraiibra'ibra'ibra

[ion soluti[ion soluti[ion soLutition solutition soLuti

CC2 = ConcentrationCC3 = ConcentrationCC4 = ConcentrationCC5 = Concentration

on <(1 = 0 -2 ug/mon K = 1 - 0 ug/mon (f3 = 5.0 ug/mon «4 = 20.0 ug/mon »5 = 40.0 ug/m

00; '

C a l i f o r n i a A n a l y t i c a l LalxiratoriesI n i t i a l C a l i b r a t i o n Smmiary

Inject ionDate

I n j e c t i o nTime

StandardID

HATIVERRF

SUBROCATEBRF VALLEY

09/21/84

09/21/84 10:13:0009/21/84 13:36:0009/21/84 16:37:00

ST5840921ST5840921EST5840921J

.89

.87

.87

1 . 1 9.87

1-03

09/21/8409/21/8409/21/84

10:56:0014:43:0017:03:00

ST5840921AST5840921FST5B40921K

.92

.90

.91

1.071. 0 11.04

09/21/8409/21/8409/21/84

11:38:0015:04:0017:30:00

ST5840921BST5840921GST5840921L

.93

.92

.95

.933

1.081.05.98

1.037

09/21/8409/21/8409/21/84

12:05:0015:26:0017:54:00

ST5840921CST5840921HST5840921M

.95

.95

.94

. 9 ( 8

09/21/8409/21/8409/21/84

12:49:001 6 : 1 5 : 0 018:15:00

ST5B409210ST58409211ST5B4092W

.95

.95

.94

Over-all Means: .923Std deviations: .0283

1.035.OB53

Solution ID Codes:Performance

Concentrat'ConcentratConcencrat

1 check

i on c a I iion c a l 'ion c a t ;

solution

ibracion solutiibration solutiibration soluti

on #1 = 0 .2 ug/mon «1 = 1 . 0 ug/mlon «3 = 5.0 ug/mion »4 = 20.0 ug/m'on »5 = 40.0 ug/m

SCANS 1175 TO 1475'DATA: DH5840921 S1630CrtLI: F584B921 »10

M I D MASS CHROHATOGRAriS09--21/34 7; 02; 00SAMPLE; 2UL OF CPSC1RANGE: G 1,1800 LABEL: N

121939721.221992.

-4, 2.5 QUANi A 4, 2,0 BASE: U 28/ 3

42.5-, A-""328

121950519.

54.3. 288485-322

12196823.

-, c 36817.< •"~i /i323

121776G90.

82.2n 46e^15-332

—i———r———i———i— ~i———i——1217

93267.100.0n 565,-03-

334

I I - 1 ) ' 1

120011:15

A/W

J I i '/ \ A r

f\ \ { \ r\ 6456G. 1U0-/ V / V I

.iVi-/V.

./ -^^

132116268,

\ 128867.

^ ^\i ' |——i——i——i——i——|——i—h—"T"—

132121855.

\ 169327.

, | , , , , ] , ,

13212845.

\ 19989.

\. ^ . A,

l , , , , l , , , , l , , , ,

1256 133U11:44 12:12

7J3J.^ 37802^9•.

' ' ' ' ' ' 1 ' ' ' '

13689712, 14U4

^\ 5808.' ' ' ' ' ' ' ' ' ' '

13701215.6807.^-

' 1 ' ^ I " ' ' '

0 0 ? . - ; o 4

135S 1400 1450 SCAN12; 49 13:08 13:36 TItlE

39744.320.936

± 0.500

50752.322.036

± 0.500

' '

7136.323.397

± 0.500

"—f^'-

76800.332.099

± 0,500

1

33440.334.100

1 0.500

M I D MASS CHROMATOGRAMS09-'21---S4 7; 02; 08SAMPLE: 2UL OF CPSMRAHGE: G 1,1633 LABEL: N -4- 2.5 QUAN

121930083.166463.

DATA: DH5843921 #1£30CALI: F5340321 »13

SCANS 1198 TO 1263

A 4, 2.0 BASE: U 20,

33288.

257.677± 8.588

39744.

329.096± 0.5013

56752.

322.096± 0.500

713b.

323.097± 9.500

126u SCnH1 1 ; 4 9 TIME

MID MASS CHROMATOGRAMS09/21/84 7:32!00SAMPLE: 2UL OF CPSMRANGE; G L1S00 LABEL:

DATA;CALI;

DH5S40921 #1639F5840321 #13

SCANS 1190 TO 1260

2.0 BASE; U 20-

34432.

328.098± 0.590

76880.

332.999t 9.500

93440.

334.ine± 0.5n£i

119911; 19

120911:15

121011;21

122011;27

123011:32

124011;38

1250l l ! 4 4

1260 SCAN1 1 ; 4 9 TIME

M I D MASS CHRONATOGRAMS09/21./84 7;02;90SAMPLE: 2UL OF CPSI-1RANGE: G 1,1600 LABEL; H -4- 2.5 QUAN:

121939545.

42.5-i 128£ 219359.

320

121959519.

54.3n 1206 288405-322

' 1 ' ] ' 11219

34261.36.8. 2™-328

i | i ' | i I1217

76625.82.2. 464791-332 .

121793179.

ii;,« c. 562309.iy".y-i ., -,•334

1

' 119S 1290 1210 1220H;10 l l ! l5 11;21 ll!27

16628. / \81922. / \^\ y \-^ v ^^^21353. / \186888. / \

/ \, ± 0.500

/ \ 332.039/ \^^ ± 0.508

/ \/ V ± O.SOQ

J ^ ' ^~^-

DATA:CALI;

A

/ ^-f^ Y ± 8.500

- , • ' ' . ' ' 'W ' , • ^

4. 2.0 BASE: LI 20, 3

123023490.131765.

123030883.173787.

1

1239H-S32

DH5840921 S1600F5840921 #10

123826697.152817.

123734731.202891.

o o : ' ^ y— j ^ - ^

1240ll!38

SCANS 1190 TO 1260'

39744.320,896

50752.322.096

1 ' 1

34432.328.038

' 1

76880,

93449,' 334.100

1 ' 11250 1260 SCANll!44 11:49 T I M E

SCANS 1198 TO l^c.0N10 MASS CHROMATOGRAMS OATA: DH5840921 #168309/21/84 7:02:00 CALI: F5S40921 #10SAMPLE: 2UL OF CPSMRAHGE: G 1,1600 LABEL: 1-1 -4, 2.5 QUAN: ft 4- 2.0 BASE: U 28, 31219

58519.2884Q5.

322.09± 0.590

332.099± 8.508

1260 SCAH11:49 TIME

7S808.

18.7-i257

A

14.6n323

17.3-1322 .

75.4-1332

1Q0. £)-i334

12183918.25537.

^£3^

120921053.133372.

1 ' 11280 12281 1 ; 1 9 1 1 ; 3 1

MID MASS09/21/S4SAMPLE; 2RANGE: G

CHR10;?UL

1

———7

12104796.29589.

/''

OMATOGRAMS13:00OF 0.2NG/UL,1800 LABEL1211

2843.16328.

/ \

120327992.173766.

CALI #1; N -4-

Y

^ > „.

1 i " "r~ • • " — r - - ' - - -• i

0 0 ; ? •..

2.5 QUAN; A

1248 1269ll!42 11:53

DATA; ST584092CALI; F5340921

4, 2.0 BASE: U 20,

1 »1350#203

12621114.7858.

SCANS 1185 TO 128

±

±

±

±

±

128012;S5

3040.257.877

0.508

4136.320.0960.500

5056.322.036

0.500

21344.332.0390.500

28320.334.1000.580

SCHtlTIME

SCANS 1185 TOMID MASS CHROMATOGRANS DATA: ST5840921 #1353CALI; F5840321 #2003/21/84 10:13:00

SAMPLE; 2UL OF 0.2NG4JL CALI #1RANGE; G 1,1350 LABEL; N -4, 2.5 QUAN; A 4, 2.0 BASE; U 20, 31210

3914.25208.14.6-1

320

17.9-1322

14.8-1328

75.4-1332

180.0-,334

/-^- 4136./ \ 328.996

/ v^ ± 0.508

12104796.29560. ,-,,„-

.r-^ 505b.

/ \ -, 322.0-31/ \-^ ^^-J t g.50@

1210. Q. 3559.^ ^ 23168• 3952.' J, / \, 328.933

/ \^ ^ ^ ± 9.589

120921053.131372. ^^ 31344.

/ \ 332.899/ Y^ ± 0.561y ' ^ ^o-""^

120927992.l^£• 28320.

/ \ 334.100/ -Y^ ± 0.500

—————i——^—^——j——'7'~~ i—— o o -! ^ .•' o ———i1196 1208 1218 1220 1230 1246 1250 SCAN11;14 11:19 11:25 11:31 11:36 11:42 11:46 T I M E

MID MASS CHROTOTOGRAnS89/21 84 10;IS;SOSAMPLE; 2UL OF 0.2NG/UL CALI #1RANGE: G 1,1350 LABEL; N -4,

DATA: ST5840921 K1350CALI: F5S40921 #20

2.5 QUftN: A 4, 2.0 BASE; U 20, 3

SCANS 1185 TO 1255

8272.

320.096± 0.500

',. ^

42688.

332.599± 0.509

0 U -? ^ • } 'i

119611:14

126011:19

1211111:25

1220:

ll;3l123011:36

124011:42

125011:48

SCANT I M E

M I D MASS CHROMATOGRAMS09/21/84 13:56!80SAMPLE; 2UL OF 1.0NG.UL CALI #2RANGE: G 1,1880 LABEL! N -4, 2.5

121441323.

52.4. 2524S8-257

121456046.

71.0. 3409S2-328

121472893.

92.2-1- 322

121358788.361063.

332

121278928.

10U.0-^ 48R28-334

i

1290 1223H;19 11:31

y v' 6158.

/ \ ± B.5130Y v^-

444203.A,

/ \ 322.996/ \^ ± 0.598

/ \ ± 0.509

v

/ \

DATA; ST5840921A f»1350CALI; F5S40921 #20

QUAN: A

'

——,———————————

4, 2.0 BASE: U 20- 3

1262987.

i • 1

1 • 1

1 • 1

00 ; ' ..

1240 126011:42 11;53

SCANS

± 0.580

'

; 9

1283 SCAN12:135 TIME

1185 TO 1285'

41472.257.077

1

56123.320.u9b

1

72960.

1

58944332,899

'

79104.334.1UU

± 0.596

DATA; ST5840921A ft 1350 SCANS 1185 TO 1255CALI; F5840921 #28

RANGE: G

71.3-. ^320

92.2. 4^239-322

1

„ , 112665.22.7-1 ,r''"\,328

'

74.5-1332

1BB.6-1334

\ 1190"• 11:14

y v^ ^^\ 1 0 - 5 8 0

1 —————————————.,..;,.,..-

1-1350

i

'

——T

^ ^-—^,1

120011:19

LABEL; N -4, 2.51214

. 55916.

/1214

72849.

121417778.

—'-'"•"•T ' '-•'••1213

58788.361863.

' 1 '1212

78928.486523.

/r\{' 1 '

121011:25

QUAN: A

1

'

'

0 0 ^ \ '.' -'> 334.188-.

1122011:31

4, 2.0

'

'

'

1———

BASE: U 20,

'

'

1

1123011:36

3

56128.326.996

± 0,509

' ' ' , . ' •"'i . • ' • • ' ' ' •

^ , \ / - - ' .. • • " V 72968.r\^\ 322.896

rr-^ ± 8-500

i ' i '

17984.328.03S

± 0.588i—————[—————(—————[—————i

i ) ,0-^ 58944.332.099

79104.

± 8.500i—————]—————i—————[—————i

1240 1258 SCAN11:42 11:48 T I M E

M I D MASS CHROMATOGRAMS OATA: ST5840921A #1350 SCANS 1135 TO I-.JOS-^l-^ 10:56; 00 CftLl! F5840921 lt20SAMPLE; 2UL OF 1 .0NG.UL CALI tt2RANGE; G 1,1350 LABEL: N -4, 2.5 QUAN; A 4- 2.0 BASE; U 20, 3

190.4-1 112256.

329.09r± 8.50b

117S8S.

332.093± 8.590

0 0 :' . • - • '.

11^ 1200 1218 1220 1230 1240 1250 SCnM11 : 1 4 1 1 ; 1 9 11;25 11;31 1 1 : 3 6 11;42 11;48 TIME

SCANS 1185 TO 1285MID MASS CHROMATOGRANS09--'21/84 lli38;S0SAMPLE: 21JL OF 5.0NG/UL CflLI tt3RANGE: G 1 - 1 8 0 0 LABEL: N-4, 2.5

1284

DATA: ST5840921B #1350CALI: F584S921 »20

QUAN; A 4, 2.0 BASE; U 20. 3473041.2762960.57.4-i

257

' 1 ' 1 ' • 1 '1284

635760.77.1. 361)070-320

1294824203.

109.0. 4™0-322

' 1 ' 1 ' 1 • '1203

127794.,,- , 760047.15.5. ^332

. 1 i | i | i1203

168-302.„, c 1B2S830.2U.3~| /~\

334

12UU 1220 124011;19 11:31 11:42

Z.t D^UDU.

/ \

y v^

/ \ t 0.509

/ \ ± 0.500

/ \ 0° :!J -' b 334.109/ \ ± 0.500

"'——

473088.257.877

± 9.508

1 • 1

635304.328.836

1 • 1

824320.322.036

127872.332.839

± 8.508

' 1 ' 1

168968.

1269 1280 SCAN11:53 12:05 T I M E

M I D MASS CHROMATOGRAMS09/21/84 11:33:00SAMPLE: 2UL OF 5.3NG/UL CALI tt3RANGE: G 1-1350 LABEL: N - 4 - 2.5

1284£35769.

-,-, , 3611078.77.1-] /--,328

1204824203.

180.8n 4694318-322

120471834.

8.8. 4^447-328

1—— ] 1 1 1 | -T

1283127703.

,,- , 758108.15.5-1 /-""332

1203168885.

„,-, , 1027769.2U.3-1 /—•^

334

1190 1200 121011:14 11:19 11:25

^/ \^^ ^w.W1 ' \ ' 1

/ ''.y ' ^ ^^^

y ^^»-^ \~, u - >A<-U

DATA:CALI;

QUAN: A 4 / 2 . 0 BASE: U 20, 3

1

1 i

1 i

—————————.—————————^

1220 1230 124911:31 11

ST5840921B W1350F5840321 #20

'

' 1

'

1 ' 1

oo: ' - y

; 36 11; 42

SCANS

'

1

'

t'

1

1185 TO 1255'

635904.320.696

± 0.500

'

824323.322.896

t B.580—i—————i

72320.328.998

± 0.500—1—————i

127872.332.899

I 8.500

'

168960.334.108i 0.500

1259 SCAH11; 48 TIME

M I D MASS CHROMATOGRAMS DATA: ST5840921B ttl35B SCANS 1185 TO 125309/21^84 ll!38!B0 CALI: F584B921 ft20SAMPLE; 2UL OF 5.0NG/UL CALI #3RANGE; G 1 ,1359 LABEL; N -4, 2.5 QUAN: A 4 - 2 . 8 BASE; U 29, 3

208.Q-i 1271800.

320.096± 0.500

255744.

332.899± 0.500

0 0 3 3

——1————————————————————I——————|—————T—————————————I—————————————I——————|————————————————————,

1190 1200 1210 1226 1233 1248 1258 ^CHU11:14 11:19 11:25 11:31 11:36 11:42 11:43 TIME

M I D MASS CHROMATOGRAMS09/21--S4 12; 65:80SAMPLE; 2UL OF 20HG/UL CALI <t4RANGE; G 1,1808 LABEL: N -4, 2.5

12141863678.

.-, -, 10915200.47.7-] /-^257

' 1 ' I1214

2390070.„- - 16150309.76.b-i ^320

12143903480.

100.0-. 2n48400-

322

' ! ' 11212

144237.„ -, 836990.3.7-] , .

332 .

1212194684.

q c, 1117490.5.0-i /-^334

' 1 ' 1 ' 1 ' 1^:! -.1200 122011;19 11;31

/ \ ± 0.500

/ \/ \ t 0.505

/ \ i 0.500

7 V,

DATA: ST5848921C ttl350CALI; F5840921 #29

QUAN: A 4 - 2 . 8 BASE: U 20. 3

l • 1

l • l

) 1

I — — — — — — — — — — — — — I ^———— ————

• .^i;, ' '^

1249 1260 . ; • •11:42 ll!?3

SCANS

. •").!

- i-' • ' , .

^' •?

'• '•' •;

1185 TO

1

1

1, 1280

12:05

1285

1863678.257.077

2990078.320.096

± 0.500

3903480,322,096

144384.332.093

194816.334.100

1 0.500

SCANTIME

MID MASS CHROMATOGRAMS03/21/84 12:05:08SAMPLE: 2UL OF 20NG/UL CALI #4RANGE: G 1,1350 LABEL:

76.6-i329

I ' 1 ' 1 ' 1 ' 1 ' 11214

186.e-i322

1 • 1 1

1.0-1328

3.7-1332

I • 1 •

5.6-1334

1190 1260i 11:14 11;19

/ \ ± 0.590

^

DATA: ST5840321C #1350CALI; F5840921 tt20

N -A, 2.5 QUAN: A 4,1214

2990070.15153300.

3903480.21148493.

' / \

1 • 11214

37797.215352.

/ \

^ --1212

144237.836990.

/\\^

1212194684.

1117490.

/ \/ - -^-^^

1219 : 1226ll!25 . . 11:31

2.0 BASE: U 20, 3

^v' o1 • 1

± 0.50H

1 • 1

^' 1 ' 1

0 0 5 . . '•

\\\^v0 ,,

1236 124011:36 11:42

SCANS

—1———

± 0.500

'

'

332.099± 0.500

•-;>'

-—j—,———.————^125Q SCAN11;48 TItlE

1185 TO 1255

2930079.320.896

— I i

3903480.322.096

1

38144,328.U9y

1

144384.

'

1'34316.334.130

± n.5fl£'

MID MASS CHROMATOGRAMS DATA: ST5840921C #1359 SCANS 1185 TO 1255Q9/21-'84 12; 95; 00 CALI: F5340921 #20SAMPLE! 2UL OF 20HG/UL CALI #4RANGE: G 1,1350 LABEL: N -A, 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

280.0-1 5980159.

12142930079.16150300. 320.696

± 0.509

2S376S.

1212144237.836990. 332.099

± 0.508

00;' '.' 0 U

1198 1290 1216 1228 1230 1240 125n •^111--14 11:19 11:25 11:31 1!;3G H;42 11:48 TIHF

M I D MASS CHROMATOGRAMS03/21-•'34 12; 05; 00SAMPLE; 2UL OF 20HG/UL CALI tt4RAHGE; G 1,1808 LABEL: N -4- 2,5

12141863678.

„-, -, 10915269.47.7-] yv

257

12142990070.

76.6-1328

' 1 ' 11214

3903480.100.0. 211484ee-322

' 1 ' 11212

144237., -, 8369S0.3.7-, ^

'30'?'-f-J^,

1212194684.

, ,, 1117499.5.3-1 /-^334

' 1 ' 112u@ 122011;19 11:31

/ \ 257.977y \16150300.

A :J2u. uab± 0.508

/ \ 322.696./ \^ ± 0.500

/ \ 332.099j \ ± 0.500

/ \/ Y

DATA:CflLI:

QUAN; A 4, 2.0 BASE; U 20- 3

± 0.588

' • 1

2990078.

' 1

' 1 ' [ ' 1

334.180

—i———————[——————1240U;42

ST5840921C ftl350F5840921 #20

'

0 0 ' ^ - i C

± 0.500

126011:53

SCANS 1185 TO 1285

1863678.

' ]

3903488.

144384.

i 194816.

128S SCHH12:05 TINE

M I D MASS09-''21/'S4SAMPLE:RANGE; G

76.6-1320

100.8-]322

1.0-1328

3.7-]332

5.0-334

119S11;14

CHROMATOG12:05:06

2UL OF 20N1-1350

1

1120011:19

RAMS

G/UL CALABEL:

I #4N -4, 2.5 QUA

12142390070.16150300.

/ ' \y \1214

3963480.21148409.^\y ^

121437797.215352.

1 '1212

144237.836990.

1 '1212

194684.1117499.

121011:25

N: A

• ^

38144.

1443S4.

^~T~

122811:31

4,

DATA: SCALI: F

2.0 BASE;

1211

1

•-?•

T5840921C5840321 »2

U 20, 3

0

036

#13530

0 -•• :'

124t311; 42

SCANS

U 2

1185 TO 1: ,

2993370.320.996

± 0.500

3903480.322.896

± 0.500

328.633± 9.588

332.899± B.500

I '

194916.334.180

± 0.500

125U SCAN11:48 TIME

HID MASS CHROMATOGRAMS DATA: ST5840921C #1350 SCANS 1185 TO 125509/21/S4 12;05;00 CrtLI; F5840921 #20SAMPLE; 2UL OF 20NG/UL CALI tt4RANGE: G 1,1350 LABEL; N -4, 2.5 QUAN: A 4, 2.0 BASE; U 20- 3

200.8-1 5980159.

12142990070.161513300. 320.096

± 0.500

288768.

1212144237.836990. 332.099

± 0.590

0 0 ^ .' 0

1196 1200 121E1 1220 1239 1248 !250 5CnN1 1 : 1 4 1 1 : 1 9 11:25 ll!31 11:36 11:42 11;48 TIME

M I D MASS CHROMATOGRAMS09/21/84 12;49;00SAMPLE; 2UL OF 40.0HG/UL CALI 45RANGE: G 1,1890 LABEL: H -4, 2.5

1217301S758.

^ , 18527600.45.1-1 ,-\257

12175136380.

-,,- -, 29338900.76.7-1 /•"i328

12176692860.

inn Q 38212200.10U.0-] /•".

322

——————,—————————————.——————————————,—————————————.———————————

1215124632.

1.9^ 765743- 124S03.332

1215165177.

- c 1620560.^. 5-i /--^

334

' 1 ' 11200 122011:19 11:31

/ \/ \ t 0.500

/ \ '~>^^ OQ^f \ •-'^.^-. yJb

/ \ ± 0.50M

/ \\ " - 334.100\ ± 0.500

^ -^

DATA:CALI:

QUAH; A 4/ 2.0 BASE: U 20. 3

± 0.500

'6692860.

± 0.503

'

' 1

1124011:42

ST5840921D »1350F5840921 #20

' 1

1

'

'

n o 3 >

' i126811; 53

SCANS 1185 TO 1285

3818750.257.077

1

5136380.320.u9b

'

i 1

332.099

1

, ^ ^ 165376.

123S SCrtt-112:05 T I M E

M I D MASS CHROMATOGRAMS09-'21/84 12; 49; 80SAMPLE; 2UL OF 40.0NG/ULRANGE: G 1.1359 LABEL:

,, -, 29338308.76.7-] /"\^323

1 ' 1 '

100.0-1

322

' ' ' '

1.0-1

328

1 ' [ '

1.9-1332 .

1

2.5-1334 .

1198 129B11:14 11:19

/ \ ± 0.500

/ \ 322,U9b^/ ^ ^SSn'vQ

/ \ 0c\sy v^ ^-

/ \ 334.100

^ ^^ n^^^'i

DATA: ST58409210 ttl350CALI: F5S40921 tt20

CALI »5N -4- 2.5 QUAN: A 4-

12175136380.

1217G692860.38212200.

1 ' 11216

64044.373000.

1215124632.765743.

1215165177.

1B20500.

1218 122811:25 11:31

2.0 BASE: U 20- 3

' 1 ' 1

' 1 ' 1

± 0.500

1 • 1

1 • 1

0 0 :•• . 0

1230 124011:36 11;42

SCANS 1185 TO

1

'

' 1

± 0.500

——'—————1———

3

± 0.533——j—————.———

125611:48

1255

5136380.320.096

'

6692860.

+ fl SRR

—i

64192.328.698

124800.332.099

'

1G5376.

SCANTINE

MID MASS CHROMATOGRAMS DATA: ST5848921D ttl358 SCANS 1185 TO 125509/21 84 12;49;60 CALI: F5840921 »20SAMPLE: 2UL OF 4B.0NG/UL CALI ft5RANGE; G 1,1350 LABEL; H -4, 2.5 QUAN; A 4, 2.0 BASE: U 20, 3

280.8-1 10272798.

12175136380.29338900. 320.096

± 0.500

249608.

332.099± 8.500

1193 1260 1218 1228 1230 1249 125S SCHH1 1 : 1 4 1 1 : 1 9 11:25 11:31 l l ; 3 b 11:42 11;48 TIME

M I D MASS CHROMATOGRAMS89-'21/84 13:36:00SAMPLE; 2UL OF 9.2NG/UL CALI ttlRANGE: G 1,1800 LABEL: N -4, 2.5

121217 7 219S-^•l 13777-257

12123346.

15.9-, 19^4-328

12124399.

20.0-, 2e856-

322

121117224.

-,.- -, 113956.75.7-] ,-332

121022795.

180.0-. ^•334

' 1 ' 11299 122U11:19 11:31

/X/-^ /- —-^ ^- -^. I -^//\^-^—--—^->-

/ \. 328.896/ ^\ i 8.5B0

/ \/ \

•

/ \ 334.1?0/ \ ± 9.58U

''-—-„

DATA;CALI:

QUAN: A 4, 2.0 BASE: U 20, 3

^^^f-^V^^-^/ Vf^^^.^ -^——\/'

i I

'

± 0.500

± 0.500

'

124011; 42

ST5840921E #1358F5840921 #20

12632585.15200.

^ ^ ^ ^ ^ - ^ • r ^ — — — — —

1

00 ; ' ; •

. ^y • ff

1260;.;ll!53'. :'

SCANS 1185 TO 1285

2904., 257.977'\ ± 0.508

'

3640.

' 1

4600.322.096

17376.332.099

IJ 7 223-14.

-; -,'•-• • •

1280 SC.AH! 12;05 T I M E

M I D MASS CHROMATOGRAMS09/21/84 13:36:00SAMPLE: 2UL OF 0.2NG/'UL CALI ttlRANGE; G 1.1358 LABEL: N -4, 2.5

12123346.

15.9. 19564:320

' ' ' 1212 ' ' '4309.

20. 0n 2^322

12122516.

p ,, 14086.

323

121117224.

-„- -, 113955.f 3 . t~\ ^--^

332

' 1 ' • I '1210

22795.luu.Ei. W33K-334

1 ' ' 1 '1196 1268 121011:14 11:19 11;25

^- ^r~— , . ^ i

/ \/ \^^ ^ t 0.506

/ \/ K

DATA: ST5840921E #1350CftLI; F5840921 tt20

QUAN: A 4,

-s. ^.

'"•, -^

\

•——^———122011; 31

2.0 BASE: U 20, 3

. //^— -^ y "-' '"^-'.• -f | i

„ •y

n G^

0>^c'

1 1 "•'•' "-

123U11; 36

t 9.536

o^^^o

± 0.500

——

/

""

s^

^^~-

-

•^- ^~

1

1

0 3 .' 0(,.

1124011:42

SCANS

t 0.500

•"1——'——

-^\—I——

/.)

1 - 1 1

1258 SCAN11:48 T I N E

1185 TO 1255

3640.320.396

4680.322.096

2800.328.098

———^-~x——,————•»———j

17376.332.099

22944.334.100

± u.500

MID MASS CHROMATOGRAMS DATA: ST5840921E #1350 SCANS 1185 TO 125503/21/84 13;36;09 CALI; F5340921 )»20SAMPLE; 2UL OF 0.2NG/-UL CALI »1RANGE: G 1,1350 LABEL: M -4- 2.5 QUAN; A 4- 2.0 BASE; U 20, 3

200.0-1 3-1752.

332.033± 0.500

0 0 ;• ' 0 ?

1198 1266 1210 1220 1239 1240 1258 SCAN1 1 : 1 4 1 1 ; 1 9 11:25 11:31 1 1 ; 3 6 11:42 1 1 : 4 6 TIME

M I D MASS CHROMATOGRAMSW.'2l-'S^ 14:43; OSSAMPLE; 2UL OF 1.0NG/UL CALI tt2RANGE: G 1,1803 LABEL: H - 4 , 2.5

121646543.

,„ c 291037.52.6-i .'•~\257

121663145.

-,, , 389849.71. l-i ,- .328

121682589.50^543.

322

' 1 ' 11215

65952.-,. „ 426535.74.3-1 r~\332

121489305.

1&8.0. 5£238£-334

1208 122311:19 11:31

/ ^ ± 9.530

/ \\^ ± 8.598

/ \ ± 9.500

/ \ ± 0.588y ^^->^

DATA:CALl!

QUAN: A 4, 2.0 BASE: IJ 20, 3

1 . i " . . " . . . . . . .

1

I

—i———————^——————

1124011:42

ST5840921F ttl358F5340921 tt20

'

'

' 1

0 0 ^ -.'

- . • i126011:53

SCANS 1185 TO 12a5

46848.257.877

± 0.500

'

63360.320.8-36

'

82688.322,096

' 1

66176.332.099

'

89383.' u 334.100

——i———————i———1280 SCAN12;@5 TIME

M I D MASS CHROMATOGRAMS09/21/84 14;43;00SAMPLE: 2UL OF 1.0NG/UL CftLI #2RANGE: G 1,1350 LABEL: N - 4 , 2.5 QUAN: A 4,

1216£3145.

-., , 389849.71. l-i /---s329

1 ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 '1216

82589.503543.

322

121520953.

22.8n P4e96-323

1 ' 1 ' 1 ' 11215

65935.., .. 425349.( 4 . J~l .'—', . -

332

121489005.

180.0-, 562^-

334

1 ' 1 ' 1 • ' 11190 1200 1216 122011:14 11:19 11:25 11;31

/ ^^ t 0.580

/ \^ ± 0.593

/ Y ± 0.500

/ ^/ \^

y '^-^ c^^q^-s-1 ' 1 ' 1 ' ' " ^^ ""—" ' 1 ' I '

/ \ 334.100

DATA: ST5840921F ft 1350CALI: F5840921 tt20

2.0 BASE; U 20, 3

^ ^}\^WZ,1

?^

0 0 : ^

1230 124011:36 11;

ow

' 1

42

SCANS

1

—1—————|—————i1250 SCAN11:48 T I M E

1135 TO 1255

63363.320.096

82688.322.036

'

20352.328.038

1

66176.332.099

± 0.530

89088.

t 0.500

HID MASS CHROMATOGRAMS DATA; ST5840921F #1350 SCANS 1185 TO 1255G'3/2^84 14:43!00 CALI; F5340921 tt20SAMPLE; 2UL OF l .QNG/UL CALI tt2RANGE: G 1,1350 LABEL; N -4- 2.5 QUAN; A 4, 2.0 BASE: U 20. 3

191.5-1 126720.

320.996± 0.506

08.8-1 132352.

332.899± 9.509

0 0 ^ : • i ^

1190 1200 1216 1228 1230 1246 1256 SCflH1 1 : 1 4 1 1 ; 1 9 11;25 11:31 ll!36 11;42 11:48 TIME

M I D MASS CHROMATOGRAMS09/21/84 15;04;09SAMPLE; 2UL OF 5.9NG/UL CALI »3RANGE: G 1-1800 LABEL: N -4, 2.5

1295353239.

59.3. 2WWQ-257

1296451995.

76.5n 27™-329

1205590797.

100.0-. 354^28-322

' 1 ' 11204

97753.... ,- 584593.16. bn ^332

1204127000.

21.5-i334

———————T————————— -1———————— ————I———————————————I————————————

1280 122011:19 11;31

/ \J ^

/ \ ± 0.500

/ \y \ ± 0.508

// ' -v-

/ \ ± 0.500

783991.

/ V 334.100

J ^-^-.

DATA; ST584092CftLI: F5340921

QUAN: A 4, 2.0 BASE; U 20,

353269.12512512.17495.

' 1 '

1

598848.

' 1 '

' 1 '

00 ? ' '

124011:42

1G #1350#23

3

257,377± 0.500

1

1

± 8.500

126011:53

SCANS 1185 TO 12S5

' 1

452096.320.036

'

322.096

' 1

97920.3:32.099

' 1

;) 127232.

' 11289 SCAH12:05 TIME

M I D MASS CHROMATOGRAMS03/21--S4 15; 04; 90SAMPLE: 2UL OF 5.0NG/UL CALI #3RANGE: G 1,1350 LABEL: N - 4 , 2.5

1206451395.

.,c ,- 2725700.76.5-i /—\329

\— i | i —T-1205

590737.100.0. 35441M-322

120552452.

8.9. 3W56-323 .

1 ' ' I '1264

97753..c c 584583.1E.6. ^332

1204127800.

• c 733991.21. 5-1 --"

334

I i I ' I '119U 1200 121S11:14 11:19 11:25

y ' ^^i0|——————————^. ,- ....^,, . , -—-.,

/ \ 326.093

// --- -

/ \ il.-

^/ ^-—^ \^3^\[ i ] ' | T

/ \ U U -• •- '1 ^

y ---- .

DATA: ST5840921G ttl350CALI; F5S40921 #28

QUAN: A 4,

1

± e.580-„ ,

1

± 0.500

1122811:31

2.0 BASE: U 28, 3

1

' 1 ' 1

' i ' i

1233 124U11:36 11; 42

SCANS 1185 TO

± 0.580

'

* 8,500I

L\Z, •I -

± 9.586i I

' i125011:48

1255

452096.320.996

i

590848.322.896

——1

5273G.

'

97920.332.093

1

127232.334.100

SCANTIME

MID MASS CHROMATOGRAMS DATA; ST584B921G S1350 SCANS 1185 TO 125509/21/84 15:04:00 ML I; F5340921 #20SAMPLE: 2UL OF 5.0NG/UL CALI #3RANGE: G 1,1350 LABEL: H -4, 2.5 QUAN; A 4. 2.0 BASE: U 29- 3

203,0-) 904192.

1206451995.2725760. 320.096

± 0.500

- T p

195840.

332.099± 0.50Q

0 0 ;- :• •} ^

1190 1209 1210 1226 12-w 1240 1250 SCAH1 1 : 1 4 1 1 : 1 9 . . 11:25 11:31 1 1 : 3 6 11;42 ; • 11:48 TIME

M I D MASS CHROMATOGRAMS09/21/84 15;26;80SAMPLE: 2UL OF 20.0NG/UL TCDD CALI#4RANGE: G 1,1800 LABEL; H - 4 , 2.5 QUAN; A

12131517498.

50.0-, 92^80-257

12132301333.

75.8-i323

12133035130.

100.0-, 17™-322

1211113420.

„ -, 676980.3.7n ^332

1211153684.

, , 910191.0 .1—1 y^-

334

1280 122611:19 11:31

7 V^13691200,A

/ \ ± 0.500

/ \ 322.096/ \ ± 0.500

/ \/ \ ± 0.500

/ \ 334.188

/ \'*---

DATA; ST5840921H #1350CALI: F5840321 »20

4, 2.0 BASE: U 20- 3

12602478.15297.

1 ' 1

1 ' 1

00--/ 1 5

l ' ' i1249 126011:42 11:53

SCANS

± 3.500

± 8.560

' 11236 '5CRN12:95 T I M E

1185 TO 1285

1517560.257.977

'

2301950.326.696

3035130.

'

11353G.332.093

1

153856.

M I D MASS CHRONATOGRAtISOS-^l-^ 15; 26:00SAMPLE; 2UL OF 20.0NG/UL TCDD CALItt4RANGE: G 1,1350 LABEL: N -4, 2.5 QUAN; A 4,

12132381930.

-„- Q 13091280.f J . O ~ - l ^^

328

1 ' 1 ' 1 ' 11213

3035139.108.0. 17W100-322

121230285.

, ,-, 186289.1.0-1 ^-\

323

"T ' " ' •" ' 1 ' "" 11211

113426.„ -, 676980.3.7-i //-'V

332

1211153684.

„ . 910191.J. 1-1 /" ,

334

[- 1 i i | i |1198 120S 1210 122U11:14 11:19 11:25 11:31

/ '\ ± 0.588

/ \, ± 0.509^/ v-^ 2,C>\'1•^•^,Q^

1 | ' i ' 1 ' 1

/ \ 1229

y ' ' ^ 25793.

/ \ ^o.^^/ ^- i<>- i ia (

— — — — — — — — — — — — . — — — — — — — — — — — — ^ — — — — — — — — — — — — ^ — — — — — — — — — — — • y r f ~ j — — — — — — — — — — — — , " " T

/ \ 334.100

^ ---

DATA: ST5840921H #1350CALI; F5843921 »20

2.0 BASE: U 20- 3

' 1 ' 1

3035130.

' 1 ' 1

30464.

2355.

1 • 1

———,———————————^——————————,———————————j—————————

0 0 3 .,' 1 7

± 0.580

1230 124011;36 11:42

SCANS

T

T

~T——————

1253 SCHU

1185 TO 1255

2301950.320.096

322,896

1

328.033+ R.50FI

'

113536.332.899

± 0.538————j——————————,

15385G.

11:48 TIt'l.E

MIO MASS CHROMATOGRAMS DATA: ST5840921H #1350 SCANS 1185 TO 1255W/2\.'W 15;26!00 CALI; F5840921 #20SAMPLE: 2UL OF 20.0NG/UL TCDD CALI#4RANGE; G 1,1359 LABEL; N -4- 2.5 QUAN: A 4- 2.0 BASE: U 20, 3

280.0-1 4693900.

12132391930.13091200. 320.09S

± 0.509

227072.

1211113420.676980. 332.099

± 0.500

0 0

1'——————————T—————I——————————|—————1———-T——————————————————————————,119" 12S0 1210 1220 1239 1240 125H TnH";H 11:13 11:25 11:31 11:36 11:42 11:4S T I M E

M I D MASS CHROMATOGRANS09/21/84 16;15;00SAMPLE: 2UL OF 40NG./LIL TCDD 5TO< CALI ft5RANGE: G 1,1806 LABEL: N - 4 , 2.5 QUAHs

12163436530.22405600.

257

12156119410.

— , 36316500.76.1-j /~^\320

'— 1 ' 1 • 1 ' 11215

8036350.180.0-. 47™3-322

1214142385.

1.8. M2851-332

1 ' I • 1 ' 11214

191319.„ , 1261160.2.4-i ^/—\

334

1199 126.3 1210 122011;14 11:19 11;25 11:31

/ \ 320.096

/ \^/ Y

/ \. ± 0.500

DATA; ST5840921I #1260CALI: F5840921 »20

A

± 0.500

± 0.500

0 0 ;' .' 1 9

4- 2.0 BASE; U 20, 3

1 ' 1 '

I 1 I

-T | , 1 ,

-1 | I | 1

1230 124011:36 11:42

SCANS

1

± 0,500

'

± 0.500

'

125011:48

1185 TO 1260

3436540.257.077

' 1

6119420.

' 1

8036350.322.096

1

143104.332.099

191483.334.100

' I1266 SCHtl11:53 T I H E

SCANS 1185 TO 1255MID MASS CHROMATOGRAMS DATA; ST5840921I #1268CALI: F5840921 #20

4, 2.0 BASE; U 20. 309/21/84 16;15:30SAMPLE: 2UL OF 40NG/UL TCDD STD, CALI »5RANGE! G 1,1260 LABEL: N - 4 , 2.5 QUAN: A1215

£119419.36316509.76.1-1

320

12158036350.

100.0. 474?3000-322

121577120.

, „ 457346.1.0-1 /'"^

328

1214142985.

1.8. 932851-332

1214131319.1261160.2.4-] /^x

334

1198 12S0 1219 122011:14 11:19 11:25 11:31

ODOiQUtW,

/ \

// '\ ± 0.500

/ \ 322.096/ \ - , . , - ± 0 . 5 0 0^/ V^ ^^W

1 ' " ' \ ' 1 ' ''

/ \ .^ 332.699/ \ ^ y b - ± 0.500

/ \ 334.100

"

6119420.320.096

1 ' 1 ' 1 -]

8036350.

1 ' 1 ' 1 '

77312.328.098

± 0.500

1 ' 1 ' 1 '

143104.

1 ' 1 ' 1 '

0 0 . : . - 2 03^\oU ± s-500

1230 1240 1250 SCHH11:36 11:42 11;4S T I M E

MID MASS CHROt'WTOGRAMS DATA: ST5840921I #1260 SCANS 1185 TO 125589/-21--S4 16:15:00 CALI; F5840921 #20SAMPLE; 2UL OF 40NG/UL TCDD STD, CALI #5RANGE: G 1,1268 LABEL; N -4, 2.5 QUAN: A 4. 2.0 BASE; U 20, 3

230.0-1 12238868.

12156119410.36316503.

—^——————————^_

4.7-1

328.096± 0.50Q

-1—————i

2S6208.

1214142985.932851. 332.B33

± 0.500

0 0 3 '; 2

1190 1206 1210 1228 1230 124Q 1250 SCAH1 1 ; 1 4 1 1 ; 1 9 11:25 11:31 11:36 11:42 11;48 TIME

M I D MASS CHROMATOGRAMS09/21/84 IS:37;QQSAMPLE; 2UL OF 0.2NG/UL TCDD STD, CALI #1RANGE: G 1,1809 LABEL! N -4, 2.5 QUAN: A

12099885.

11.0-. 64146;

257

120912495.

13.8. 865^-323

120916576,

,o o 105110.1 o. •S~~i /"•

322

120870287.

76.7. 4S9431-332 .

1 ' 1 ' ' 11208

91785.100.0-, 60^51-

334

1190 1206 1210 1220l l ! l 4 11;19 11:25 11:31

y \^^ ± 0.500

/ \^ ± 0.500

/ \/ Y i 0.500

DATA; ST5840921J #1260CALIs F5840921 #20

4, 2.0 BASE; U 20, 3

i i i | i

I , , ,

0 0 :••• •

1236 124011:36 11;42

SCANS

± 0.500

'

2 2t 0.500

1125011; 49

1185 TO 1260

10112.257.077

12704.320.836

'

16800.322.096

7052S.332.893

31904.334.100

11268 SC:HH11:53 T I M E

0

T\

-^ \\ 0 '(.0 -\

t-iJ r.J

LO

CO -

C*.

>--

.

- W

,(J1

•-fc

C&

'CT

CO

-en

®•3?

'-o

i5 c

om

Ei

'Sl

l-L'

GJ

0"i

M I D MASS CHROMATOGRAMS DATA: ST5840921J #1269 SCANS 1185 TO 125599/21./.94 16; 37.-90 CALI; F5840921 tt20SAMPLE; 2UL OF 0,2NG/UL TCDD STD, CALI tilRANGE; G 1,1260 LABEL; N -4, 2.5 QUAN; A 4, 2.0 BASE; U 20, 3

36.0-i 25498.

320.896± 0.506

1190 1209 1210 1220 1230 1240 12501 1 : 1 4 1 1 ; 1 9 11:25 11 ; 3 1 1 1 : 3 6 ll!42 11:48

SCAMTIME

M I D MASS CHROhATOGRAMS89/-21/S4 17; 03:00SAMPLE! 2UL OF l -BHG/UL TCDD STD, CALI #2RANGE: G 1,1809 LABEL; N -A,

121173898.

,-. „ 448215.54.2-1 /-\257

121087811.

„ , 559011.67.1 -i /—\320

1210115856.

88.5-1322

120996833.

,. ,, 608735.74.8-1 ^-^332

I ' 1 ' 1 ' 11209

139959.„,-, „ 811835.16U. U-i ,,-..334 J / \ 334.100

) / ''--,. ± 8.580

1 ' 1 ' ,11190 1200 121011;14 11;19 11:25.

/ \^^ ± 0.500

/ \ 32u.u9b/ N. ± 0.500

72^- 115968./ \^

/ \ ± 0.500y

/ -^ ± 0.500

^// , . . . • • "

DATA: ST5840921K #1CALI: F5340921 )t20

2.5 QUAN; A

' [

1

^ ^ ^ . . ^ .'^ 1 — —

1220.11:31

4, 2.0 BASE: U 20, 3

1 • 1

1 ' 1

1 • i

0 0 :•••

• " 1'' 1

1230 124011:36 11:42

'

'

'

'

,; 2 -:>

SCANS

1

1

1

'

125011:48

1185 TO 1266

71049.257.077

' "1

87936.

i 1

322.U96

' 1

37024.332,099

' 1

131072.

1260 SCAN11:53 TINE

SCANS 1185 TO 1255MID MASS CHROMATOGRflMS09/21--84 17:03; 60

DATA; ST5848921K #1CCiL I; F5840921 #20

SAMPLE: 2UL OF 1.8NG/'UL TCDD STD, CALI #2RANGE: G 1 ,1260 LABEL: N -4, 2.5 QUAN: A 4, 2.0 BASE: U 20,

121387811.559011.67.1-i

320

1 1 ' 1 ' 1 ' 1 '1219

115356.88.5. 72^33-322

1 ' 1 i 1 ' I '1210

30367.23.4. 184298-328

' 1 ' "1 ' ] ' •1209

96833.74.0. 608735-332

' 1 ' 1 ' 1 '1209

130959.100.0. s^885-

334

1198 1200 1210 122011:14 11:19 11:25 11:31

JJ3011•

^\^/ '\^

,f '"- ^^

/ \ -,^\ 332.099/ \ ^ ± 8-580

/ \ 334.100

---/ ^~'-~—

87936.320.896

± 0.500

I ' 1 ' " 1 '

115968.322.896

., -,,.,1 ± 0.500^'L^-i'-n1 • 1 • 1 •

38688.328.098

± 0.500

"•I- ' 1 -•••••'- | • • i

97024.

0 0 21 • 2 6 13W2.

, ± 0.500l^.Ci^.^0

1230 1246 1250 SCAN11:36 11:42 11:48 T I M E

M I D MASS CHROMATOGRAMS DATA; 5T5840921K #1 SCANS 1185 TO 125509--21./84 17:03;00 CALI; F5340921 #20SAMPLE; 2UL OF 1.0NG/UL TCDD STD- CALI ft2RAHGE; G 1,1268 LABEL; N -4, 2.5 QUAN! A 4, 2.0 BASE; U 20, 3

181.3-1 175872.

328.096± 0.588

194048.

332.B99± 0.568

0 0 ^ -\ 2 7

1190 1206 1210 1220 1230 1240 1250 SCAN1 1 : 1 4 1 1 ; 1 9 11:2S 11:31 l l ; 3 6 11:42 11:48 TIME

M I D MASS CHROMATOGRAMS8^•/21-'•.34 17; 30:00SAMPLE; 2UL OF 5.0NG/UL TCDD CALI STD #3RANGE; G 1,1808 LABEL: N -4, 2.5 QUAN: A

120526489.

53.5. 206573-257

120433261.

-,, , 267667.i'4.5-) - ,320

128444629.

100.0n 350263-322

' ' 1 '12037380.

l£.8n 551^-332

12039501.

„, -, 74S6S.21.7-i ^-^334

1206 122011:19 11:31

/ \^

/ ^ 322.036

y v^

/ v, ± a.500

/ \ 334.100y v^^

DflTA: ST5840921L ttl359CALI; F5840921 #20

4, 2.0 BASE; U 20, 3

26ess.12601820.

13484.1 • 1

,..,„..-,,... , ^

44864.

± 0.56Q

1 • 1

0 0 ^± Q.509

1240 1260n;42 11;53

SCANS

257.n77± 0.500

'

2 3

12S8 SCAH12:85 TIME

1185 TO 1235

'

33408.320.0'db

± 0.500

'

I

7552.332.099

9744.

MID MASS CHROMATOGRAMS@9/-21--'84 17; 39; 09SAMPLE: 2UL OF 5.0NG/UL TCDO CALI STD #3RANGE: G 1 ,1358 LABEL: N -4, 2.5 QUAN; A

123433261.267G67.

DATA; ST5S43921L #1359CALI; F5S40921 #20

4- 2.0 BASE: U 20- 3

SCANS 1185 TO 1255

MID MASS CHROMATOGRANS DATA; ST5846921L #1350 SCANS 1185 TO 125509/21/34 17:30:00 CALI; F5840321 #20SAMPLE: 2UL OF 5.0NG/'UL TCDD CALI STD #3RANGE; G 1,1350 LABEL: N -4, 2.5 QUflN; A 4, 2.0 BASE: U 20- 3

283.0-1 66S16.

320.096± 0.500

15194.

332.093± 0.506

1138 1260 1210 1228 1239 1248 125Fi SCAN1 1 ; 1 4 1 1 : 1 9 11:25 11:31 11:36 11:42 11:48 TIME

SCANS 1185 TO 1285MID MASS CHROMATOGRAMSS3/21/84 17;54:80

DATA: ST5B40921M ?1350CALI: F5S40921 #20

4, 2.0 BASE: U 28, 3SAMPLE; 2UL OF 20NG/UL TCDD CALI STD #4RANGE; G 1,1800 LABEL: N -4- 2.5 QUAN: A1211

1189830.7312640.52.6-i

257

' ] ' 1 ' 11211

1736659.7c Q 9996450.i b . 9 — i -^

328

' I ' 1 ' 11211

2269970.100.0n 129,31900-

322

. i | i |1209

S6£24.„ o 524757.o. on y^,

332

1209115968.

5.1-i334 .

i I • ' 1 ' 11200 1220 1240

i H s l l 11:31 11:42

f 01 .0*10.

/ \ 257.677/ \ ± 0.590

/ \/ '\ ± 0.500

/ \ 322.096/ \ i 9.580

/ \/ \ ± 0.500

697795.

A\"--

1189888.

1 • 1

1736700.328.u9b

1 • 1

2269990.

' 1 ' 1

86784.332.099

1 • 1

00.:' .' 3 1 •...•r,,^ • n6036;• • • . • • • - • . .1 , ' . ""-'''f ' • '•, 334.'100

' ' • ^ . . . . ^ ' ' ± 0.500

' 1 ' 11260 1280 SCANll!53 12:05 TIME

SCANS 1185 TO 1255MID MASS CHROMATOGRAMS DATA; ST5840921M ttl350CALI: F5840921 #20

4. 2.0 BASE: U 28, 3

as-^i.^ 17:54; ssSAMPLE: 2UL OF 20HG/UL TCDD CALI STD #4RANGE: G 1,1358 LABEL; N -4, 2.5 QUAN: A1211

1736650.9996450.75.8-1

328

1 i 1 -r ' 1 ' 1 - ' 1 '1211

2268970.I Q Q n 12931900.100.6-1 /•^\322

1 i ] . ] i ] i i 1 i1211

23904., , 141920.l.l-i ,^-\

328

120986635.

3.8-1332

1209115968.

5 , . . . . . . . — . „ - - .. , ., , . , . ,63l t 30 ••-., ..-. , -,,.•,,..-.-^••t.-^*t. , - - . - • • . - . < • >1 • 1 -^ , . • , -; .--^Ir. 'U- -^^^^^^^•'y^^.^^i.-.-^^W'^ 0 0 - ' . ; ^ ^334

1190 1200 1210 1220 ' - 1230. 124611:14 11:19 11:25 11:31. : ; . 11:36 11:42

^.J-JO-tUO.

/ \

/ \ ± 6.508

y Y^ ^.z-yso

/ \ 1244/ \ 868.

^ ~^-^ 2403.

525406.r\ ^/ \ ft //0

/ V V4'^ "-- \>^01

' f - ' "^ T ; ' ' ' ^ • ; " ' • ;';•?'/::>"' • \ - i ? ' ' • • . • ? W " B r ' ;

1736783,328.096

1 '

2260390.322.y'3b

± 0.500

] '

24169.328.098

± 0.500

'

86784.332.939

± 3.5.10

'

116696.334.100

± 0.50n

1259 SCAN11; 46 T I M E

MID MASS CHROMATOGRAMS DATA; ST5840921M #1350 SCANS 11S5 TO 125599/21/84 17.-54;00 CALI: F5S40921 #20SAMPLE; 2UL OF 20NG/UL TCOO CALI STO ft4RANGE; G 1-1350 LABEL; N - 4 , 2.5 QUAH: A 4. 2.0 BASE; U 20, 3

290.8-1 3473400.

12111736650.9996450. 320.096

± 0.500

173563.

332.699± 0.500

0 0 - ^ - ':' 3

1130 1208 1218 1220 1233 1240 l^Q vw^••^ 11:19 11;25 11;31 11:36 11;42 11..48 HME

SCANS 1185 TO 1285MID MASS CHROMATOGRAMSSS-^l/^ 13:15:30

DATA; ST5840921N ftl350CALI i F5840321 #20

4, 2.0 BASE; I) 20, 3SAMPLE: 2UL OF 40NG/UL TCDD CALI STDttSRANGE; G 1,1800 LABEL; N - 4 , 2.5 QUAN; A

12163268600.20637000.45.5-1

257

76.7-1328

108.0-1

322

1.9-1332

2.5-334

/ \ 12G1 257.877/ \ 3053. ± 3.500

^/ '-^- 17548.1216

5513210.32416200./ \ 320.836/ \ ± 0.500

. \ ' \ •12167184380.42576303.r\/Y1214133704.849894.y\1214

179276.1143620.

12B0 122S1 1 ; 1 9 1 1 ; 3 1

3268600.

5513218.

1 ' 1 ' 1

71843SQ.322,396± 0.509

• 1 ' 1 ' 1

133S8S.332.093± 0,508

1 ' 1 ' 1

^ , . . - . - 179456.0 0 -•- -. ') 4334.108± 0.500

1240 1260 1289 SCAN11:42 11:53 12:95 TIME

M I D MASS CHROtlATOGRAMS09/21/84 13;15:00SAMPLE; 2UL OF 40NG4JL TCDD CALI STD15RANGE; G 1,1350 LABEL; N -4, 2.5 QUAN: A 4,

12165513210.

.,- , 32416200.76.7~i ,—^320

1 ' 1 ' • 1 ' 11216

7184389.100.0. 4257K3a0-322

121571521.

, ,, 417606.1 .U-i y~^\

328

1 ' 1 ' 1 ' 11214

133704., a 849894.- ' ~1 >^~^^

332 ^

121417927G.

,, c 1143620.2.5-1 /-~^334

1190 1200 1216 122911:14 11:19 11;25 11;31

/ \ ± 0.500

/ \ 322.&96^/ Y^^ ^^i^SiQ

y ^-^ vs^^

// \ ± 0.500

DATA: ST5840921N #1350CALI ; F5840921 #20

2.0 BASE; U 20, 3

1 ' 1

1 ' 1

12291519.10420.'-r- i |

" .^\[(.(-<•"

1

U 0 ^ :-• 5 3

' l ' l1230 124811:36 11:42

SCAHS

± 0.509

± 0.566

± 0.560—,———

1250 SCAM

1185 TO 1255

5513210.320.096

71843S0.

71803.328.098

133888.332.099

'

179456.334.100

11:48 T I M E

M I D MASS CHROMATOGRAMS DATA: ST5840921N #1350 SCANS 1135 TO 125509/21/84 1S:15;08 CftLI; F5840921 ft20SAMPLE: 2UL OF 40NG/UL TCDD CALI STDtt5RANGE; G 1,1350 LABEL: N -4. 2.5 QUAN; A 4. 2.0 BASE; L) 20, 3

260.0-1 11026409.

12165513210.32416230. 320.036

t 9.509

267776.

1214133704.849894. 332.699

± 0.599

0 0 3 .-: :S 6

1190 1200 1210 1220 1236 1243 1250 SCflH1 1 ; ' 4 1 1 ; 1 9 11:25 11:31 11:36 ll!42 ll!43 TIME

MID MASS CHROMATOGRAMS09/20/84 7:01:08SAMPLE; 2UL OF CPSMRANGE; G 1.1545 LABEL;

DATA: DH5840920 #1CALI; F5840920 #10

SCAHS 1138 TO 1266

46592.

257.077± 0.500

54208.

320.096± 0.500

68096.

322.096± 0.500

9760.

323.037± 0.500

1260 SCAN11:45 TIME

MID MASS CHROMATOGRAMS DATA: DH5840920 #1 SCANS 1190 TO 1260Q9/2Q--84 7:01:00 CftLl! F5840920 #10SAMPLE: 2UL OF CPSMRANGE; G 1/1545 LABEL; N -4, 2.5 QUANi A 4> 2.8 BASE; U 20, 3122943636.

35.9. 2?2004- 43776.

119914746.89442.

328.098± 0.500

12511426.6558.

r?o

97792.

332.099i 0.500

0 0 :• ^ 3 3

121856.

334.180± 0.500

1193 1200 1210 1228 1230 1240 1250 1260 SCAN11:06 1 1 : 1 1 11:17 11:23 11:28 11:34 11:39 11:45 TIME

44.5-1320

55.9-1322

35.9-1328

80.3-1332

100.9-]334

1111

MID MASS CQ9/29/S4SAMPLE: 2LRANGE; G

119914746.89442.

\-^=^-. j —

i 1 • I '98 1288 1210:@6 1 1 : 1 1 l l ! l 7

;HR011ATOGRAMS7:01:00A- OF CPSM1,1545 LABEL;

1 i- | i j1227

121658.648815,

, ,.. . , . „ .,„. J . , . , , . - - , , J -„.„.122967S87.

, „ , ( - 346416.l^ib ,^\.28105. / \130480. / \

" T

N -A, 2

121621301.93154.

5

1 ' " " 1 • I-" I - " • — i "122943636.232004.

1227 ' ' '97659.523887.

1 • 11220 123011;23 11;28

8UAN:

GC

A 4, 2.0122954090.267278.

ATA: DH5840920 #1ALIs F5840920 #10BASE; U 20- 3

124130427.160836.

124138024.194007.

i 1 •

005

1240lls34

SCANS

124833239.16TO09.

1 . , . - . . . , , . .

124841884.228422.

' 11250Hs39

12511426.6558.

.':' '"•'

1190 TO 1260

54208.320.096± 0.500

->-, . — , , , - ^

68096.322.096± 0.500

" ^ ' 1

43776.328.098± 0.500

, ,-...-.^

97792.332.099± 0.500

' 1

121856.334.100

t 0.508' • 1

1260 SCAN11:45 TIME

MID MASS CHROMATOGRAMS09/20/S4 7:01:00SAMPLE; 2UL OF CPSHRANGE: G 1,1545 LABEL:

DATA;CALI;

DH5840920 #1F5840920 #10

SCANS 1196 TO 1268

68096.

322.096± 9.500

97792,

332.099± 0.500

1260 SCAN11;45 TIME

13.3-1257

15.2-1320

13.9-1322 .

79.4-1332

iee.8-1334

MID MASS CHROMATOGRAMS09/-20/84 7; 32; 00SAMPLE: 2UL OF 0.2NG/UL TCDO STD MIX CALUtlRANGE: G 1,1800 LABEL; N -4- 2.5 QUAN; A

122517031.88760.

1192 /\929. / \3203. y \^

122519291.102757.

/V1225

24309.131856./"\/V

1223102900.551203.

/V1223

129543.685231.

/ \i \

L -..-,.. .- i .. ,... ;-^,,,1286 • i22011:11 : • 11823

DATA: ST5840920 #1350CALI; F5840920 #10

4, 2.0 BASE: U 20, 3

1 • 1

1 ' ' I —

0 0 ~'J -

, - ..,-.....,„,-.,,, .^y.^,.^,. .

1 '' " • ' , ' ' ' ^ ' (*,l'-i'-1240 H I1260;.11:34 . . ' .•^5^11^45;

SCANS 1185 TO

12751466.6144.

1

i -;"-

' 1

4 '!

' "•yl;, '""' • ',' ' -^i1!!'* ' ^'

1280• . . ; . - 11^6

1285

17216.257.077

± 0.500

196B0.320.896

± 0.500

24480.322.096

± 0.500

103040.332.899

± 0.500

129792.334.100

± 0.500

SCAN; TIME

15.2-1320

18.9-1322

12.3-1328

79.4-j332

100.0-1334

MID MASS C09/20/84SAMPLE; 2LRANGE: G

CO^Q

11928192,69696.

o -.CO ^0 t!

1 ! -

1190 ; ' ^11:06 : -

;HROMATOGR7:32;08JL OF 0.2N1,1358

r+-o-i(\

-'3\l

'^-

1

1

;;H;:1^

AMSG/UL TCDD STDLABEL: N -4,

\<s~•~s-4

' 1 '

,^ ;^T- ^

^ • . . 1 - .; ' 1210E. L , . Uil?

MIX2.5

— •"—r

CALI#1QUAN; A

1223102900.551203.y Y

• . . ' .

1:^• ; 11s

DATA; ST5£CALl! F584

4- 2.0 BASE; U122519272.102320.

122524369.131856.

122415G55.78928.

1223129543.685231.

————^T-——3 ; 123823 • 11:28

34092?32820,

±

±

0 0 3 : ' 4

0 #1350#133

124011:34

SCANS 1185 TO 125

±

2±

1 i • - • 1125011:39

5

19680.320.0960.500

24480.322.0960.500

15952.328.098

0.500

103040.332.099

0,500

129792.334.1080.580

SCANTIME

MID MASS CHROMATOGRAMS DATA: ST5840920 #1350 SCANS 1185 TO 125509^-20/84 7; 32; 00 CALI: F5840920 #10SAMPLE: 2UL OF 0.2NG/UL TCDD STD MIX CALUtlRANGE; G 1-1350 LABEL; N -4, 2.5 QUAN; A 4, 2.0 BASE: U 20, 3

38.2-i 33360.

122519272.162329. 320.996

± 0.503

200.0-1 206080.

1223102960.551203. 332.093

± 0.500

0 0 3 ..- - 3

—I————'————1————'————1————'———1————i————I——~~1————!————'———|————11190 1200 1210 1220 1230 1240 1250 SCAN11:06 11:11 11:17 11:23 11:28 11:34 11;39 TIME

MID MASS CHROMATOGRAMS09/'20^84 11:53:00SAMPLE; 2UL OF 0.2NG/'UL TCDD STD MIX CALUtlRANGE: G 1-1800 LABEL; N -4, 2.5 QUAN: A

122413538.

,, c £9215.13.5-i /\257

122415434.

,, „ 79988.15.3-1 /\328

122419405.

19.1. 104<14•322

-'•••" ' | • .."•r—""" | - ••" "i"""-- "•1222

81489.79.4. 439e79-332

———,——————,——————,——————j——————,—————1222

102702.100.0. 5W47-334

i 1 . 1 i1230 1220l l s l l 11;23

1191 / \899. / \3857. y Y^^

A 320.096± 0.500

/ \/ \ ± 0.500

/ \/ V , * 0.508

/ \ 0 0 5/ \ ± 0.500

DATA: ST5840920A #1350CALI; F5840920 #10

4- 2.8 BASE; U 20, 3

1 • 1

1 • 1

1 • 1

1 ' 11248 12G0lli34 11-.45

SCANS 1185 TO

12751166.6952.

'

' 1

, . - „ „ , . , , , , „ .

' 1

^ ' 4 4

128011:56

1285

13984.257.077

± 0.500

15776.

19648.322.096

81664.332.099

102312.334.100

SCANTIME

DATA: ST5840920A #1350CALI; F5840928 #10

SCANS 1185 TO 1255

15.3-i326

13.1-1322

12.9-1328

79.4-1332

180.0-1334

RANGE; G 1-1350 LABEL; N-4- 2.5 QUAN: A 4, 2.0 BASE122415351.78545.

122419414.

.^ 104646.

|————^-..,, —,————|————i.,, , , , ,122313036.

1191 68312.6208. /\29504. / \

122281489.439879.

1222" ' 102702.

0 r-) 549747.^ 'h /^\o 'y / \.c~ /

1190 1280 1210 1220 1211:06 1 1 : 1 1 11:17 11:23 11

: U 20, 3

15776.320.096± 0.508

p — — — — 1 1 1 •

19648.322.096± 0.500

^^ 13248.X- 328.098t ± 0.500

rn^ 81664.

'^ 332.099g ± 0.500

102912.003 . ' 4 ;3 334.100

± 0.500

38 1246 1250 SCAH;28 11:34 11:39 TIME

MID MASS CHROMATOGRAM5 DATA: ST5840920A »1350 SCANS 1185 TO 125509/20/84 11:53:00 CALI; F5840920 #10SAMPLE: 2UL OF 0.2NG/UL TCDD STO MIX CALUtlRANGE: G 1,1350 LABEL: H -4, 2.5 BUAN: A 4, 2.0 BASE; U 20, 3

38.6-1 31552.

320.096± 0.500

200.0-1 163328.

332.039± 0.500

0 0 3 '-.: ^ 6

1190 1200 1210 1220 1230 1240 1250 SCAN11:06 11:11 11;17 11:23 11:28 11:34 11:39 TIME

SCANS 1175 TO 1475DATA: OH5840920A <tl600CALI; F5848920 #10

MID MASS CHROMATOGRAMS09/20/34 12:18;00SAMPLE; 2UL OF CPSMRANGE; G LI 880 LABEL; H -41226

30276.155736.

2.5 QUAH: A 4 - 2 . 0 BASE: U 20. 3

A * Ft i^^lfOO.44.8-1 n320

122539341.

58.2-, 2021e6-322

12255756.

„ . 1191 28332.°-'~1 3066. A. - - i l l '

323

122455075.

81.6. 298269-332

—r——1——i——i——i——i——i——|——i——i——r—1224

67412.100.0-. 3M574-334

—i——i——[——i——i——i——i——|——i——i——i—1200 125011:11 lls39

A / V Y \

/Jwv1663b. , \ A A

A A / V / W

^

v

132911673.89657.

————^———

132915237.117542.

————^———13292405.14493.

.,^.^A,.^,

i . , , , i .

1300 135012:67 12:35

13785355.33260.^ . .

13787350.46152.i^> i |

13771041.6290.

••L-«,rt-^p.—pw .

'

0

—I——1——1———[——1——1——1———1——i——1———1—

1400 1450 SCAN13

1414539.1632.1——i——i——i——i——|

1413859.4188.

' '

^-r-p^tfpi-KVYMwyy^-

. ,

0 ? - 4 7

;63 13:31 TIME

30304.329.096

± 0.500

' '

39360.322.096

± 0.500

' '

5912.323.097

± 0.500

55168.332.099

± 0.500

' '

67584.334.100

± 0.580

MID MASS CHROMATOGRAMS09/20/84 12;18:00SAMPLE; 2UL OF CPSMRANGE: G 1.1600 LABEL: N-4, 2.5

DATA; DH5840920A #1600CflLI; F5840920 #10

SCANS 1190 TO 1260

QUAN; A 4, 2.0 BASE: U 20.122625556.132382. 1238

17288.91719.

25824.

257.077± 0.500

30304.

329.096± 0.500

39360.

322.096± 0.500

5912.

323.0S7± 0.500

1260 SCANlli45 TIME

MID MASS CHROMATOGRAMS DATA; DH5840920A #1600 SCANS 1190 TO 126009-/20/84 12; 13; 00 CALI: F5840320 #10SAMPLE; 2UL OF CPSMRANGE: G 1,1600 LABEL: N -4- 2.5 QUAN; A 4, 2.0 BASE; U 20, 31225

28587.42.6-, 16W1- 28800.

328.098± 0.500

12451618.10246.

55168.

332.099± 0.500

———i————|——--T1224

67412.364574.

-,——^_———^

67584.

334.100± 0.500

0 0

1198 1290 1210 1220 1230 1240 1250 1260 SCAN11;06 Hill 11;17 11:23 11:28 11:34 11:39 11:45 TIME

MID MASS CHROMflTOGRAMS09/28/84 12i18;88SAMPLE: 2UL OF CPSMRANGE! G 1,1600 LABEL; N -4,

44.8-, 1212320

58.2-, 1212322

42.6-1328

————i————1————i————|————,——

55001.81.6-1332

100.0-1

334 .

. [ i | .1190 1200 1210ll!06 11:11 ll!l7

12955.59637.^\ / \^y v Y1 , 1 ,16800.81179.^\^ y \^y ^ Y ± 0-500

1——————i———'—~r— •-

/ \ 1245

^ ^

/ Y ± 0.500

DATA; DH5840920ACALl! F5840920 #10

2.5 QUAN: A 4, 2.0 BASE: U 20- 31226

30111. ,„,153752 IJ-"'^-s" 18261./ \ 93836.

122539330. ,..-2e^7- 21328397./ \ 125937.

122528587.161871.

1224

296782.

122467412.364574.

/ \ u oy ^1220 1230 124011:23 11:28 11;34

#1600

124519575.99832.

124526568,134680.

1618.10246.

5 1'-? ^ O

SCANS

1

1

± 0.500

1

1

± 0.500

125011:39

1190 TO 1260

30304.320.096

39360.322.896

1

28890.328.098

.,„, ..„„.„„ ^

55168.332.999

' 1

67584.334.100

' 11260 SCAN11:45 TIME

M I D MASS CHROMATOGRAMSBS-'Ze. 12;18;00SAMPLE! 2UL OF CPSflRANGE: G 1,1600 LABEL; N -4- 2.5

DATA: DH5840920A #1600CALI; F5840920 #10

QUAN; A 4, 2.0 BASE: U 20, 3122539330.201927.

SCANS 1196 TO 1268

39360.

322.096± 0.500

55168.

332.099± 0.500

1260 SCAN11;45 TIME

MID MASS CHR011ATOGRAMSQ9/23/84 16:23:00SAMPLE: CPSMRANGE: G 1,1800 LABEL

DATA: DH5840929B #1500 SCANS 1175 TO 1475CflLI: F5840329 1»10

N -4, 2.5 QUAN: A 4 - 2 . 0 BASE; U 20- 3122526396.135348.43.4-1

326

56.4n322

8.6-1323

81.8-1332

'

106.0-1334

i—^——,——.——,——)——j——,——.——,——,——j——,——,——^,120B 1250 130011:11 11:39 12;07

1192698.2016.

/ \ ± 0.500

iO^^ID.

/v/V/Ai ' ' 1 ' '' i •i '———i—^~1224

34457.177379.

A/VA12255126.26745.

Y f | \ { 7^——•jt—p^-^vy^pn-^fn-yf.1223

49918.266840.

!\1223

61028.328664.

A

132910338.77944.

-^———

132813276.100356.

' ' ' —r

13281863.13572.

135012:35

13774954.29299.i ' P—i——|—i——i——i—

6923. H133^5- 2867520.' ' ' ' ' ' '

1378706.3812.

' " • i -nr —^-T-

—i——i——i——|——i—-——————————————1 — — — — I — — — — 1 — — — — — — — — ! 1 1 — —

0 0 :' •;• ^ 2

140013;03

26560.320,096

± 0.500

• 1 • •

34496.322.896

± 0.500

5264.323.097

± 6.500^'^- f-

56048.332.999

± 0.500

. i , ,

61184.334.100

i 1 i i1450 SCAN13:31 TIME

MID MASS CHROMATOGRAMSQ9/29.--84 16; 23; 60SAMPLE: CPSMRANGE; G 1,1500 LABEL; N -4,

OATA; DH5849929B #1503CALI; F5840920 #10

SCANS 1199 TO 1260

22304.

257.077± 0.500

26560.

320.096± 0.500

34496.

322.096± 0.500

5264.

323.097± 0.500

1260 SCAN11:45 TIME

M I D MASS CHROMATOGRAMS09/20/84 15;23;00SAMPLE; CPSMRANGE; G L1500 LABEL: N -4,

DATA;CALI;

DH5840920B #1508F5840920 #10

SCANS 1198 TO 1260

BASE: U 20,

24928.

323.038± 0.500

50048.

332.099± 0.500

61184.

334.100± 0.500

120011:11

121011:17

122011:23

123011:28

124011:34

125011:39

1260 SCAN11:45 TIME

MID MASS CHRONATOGRAtIS09--20./84 16:23; 00SAMPLE; CPSMRANGE: G 1-1508 LABEL: N -4,

DATA;CALI;

DH5840920B #1503F5340920 #18

SCANS 1190 TO 1269

2.5 QUAH; A 4, 2.0 BASE; U 20,1225

26307.133974- l^.

83118.

SCANS 1185 TO 1285MID MASS CHROMATOGRAMS09/20/84 16;55;68

DATA; ST5840920B #1350CALI; F5340928 #10

4, 2.0 BASE: U 20, 3SAMPLE! 2UL OF 0.2NG/UL TCDD STD, CALUtlRANGE; G 1-1800 LABEL; N-4, 2.5 QUAN; A1212

14657.83S39.l3.3-i

257

15.7-1328

20.1-1322

ai-3-i332

100.0-1

334

°^ 14912.

/ \ ^ 2%. 257.977/ \^ Si. ^iL121217322.98^2• 17568./ \ 320.096

/ \ ± 0.500

121222367.129a9- 22592./ \ 322.896/ \ ± 0.500

121191022.

534459- 91136./ \ 332.099/ \^ ± 0.500

1211112019.6^95- 112128./ \ 00:.' -.' :i 7 334.100/ \ * 0.500

1200 1220 1240 1260 1280' SCAN11:11 ll!23 n;34 ll!45 ll!56 TIME

M I D MASS CHR011ATOGRAMS09/20-'84 16; 55; 00SAMPLE; 2UL OF 0.2NG/UL TCDD STD, CALI#1RANGE: G 1,1358 LABEL: N -A, 2.5 QUAN: A A.

121217322.

,- -, 98112.15.7-1 , /r-^,320

1———••••I i | i ] |1212

22354.20.1. 128404-322

————1————i————|————i————|————i————1———1212

14821.13.4. 8%36-328

121191022.

81.3-1332

1211112019.

100.0-, e55e95-

334

1 ' 1 ' 1 ' 11198 1209 1210 122611:06 11:11 11:17 11:23

-?• / \—? / \

/ •\

^ \^

/ \ 1238/ \ 1402.y ^^^ 7018-534459.

0- / \/ -K ' ± 0-500

/ \ 0 0 : - )/ \ ± 0.509

DATA; ST5840920B #1350CALI; F5840928 #10

2.0 BASE; U 20, 3

1 • 1

± 0.500

l • 1

-^

t y .

i • i

1238 124011:28 11:34

SCANS 1185 TO

± 0.500

'

i [- •" •

'

l

13 0

125011:39

1255

17568.320.096

22592.322.096

15056.328.098

± 0.500

'

91136.332.099

'

112128.334.100

—iSCANTIME

MID MASS CHROMATOGRAMS DATA; ST5840920B #1350 SCANS 1185 TO 125509/20/S4 16:55.-00 CALI: F5840920 #10SAMPLE: 2UL OF 0.2NG/UL TCOO STD, CALHdRANGE: G 1,1350 LABEL; N -4, 2.5 QUAN: A 4, 2.0 BASE; U 20, 3

35136.

320.096± 0.500

182272.

332.099* 0.509

0 0

—1——^——j———I———^——I———I———I———I———,———I——,

1208 1210 1228 1230 1240 1250 SCANH i l l 11:17 lli23 11:28 11;34 11:39 TIME

SCANS 1185 TO 1285MID MASS CHROMATOGRAMS DATA: ST5840920C <tl350CALl! F5848920 »10

4- 2.0 BASE: U 20, 3

89-/20/84 21;17;00SAMPLE: 2UL OF 0.2NG/UL TCDD STD, CALHHRANGE! G 1,1800 LABEL; N -4- 2.5 QUAN; A

122418788.59220.13.5-1

257

122412363.

15.2. 73W-328

122417030.

20.8n "A48-322

122267529.

81.6. 399359-332

———i———————1——————————————^—————————1222

82819.106.0. 51SS37-334 .

' 1 ' 1 '1200 122011;11 lli23

•JSi.i.'a.

f \/ \ ± 0.500

/ \^ ± 0.500

/ \ ± 0.500

/ \ t 0.580

/ \ 0 0 :/• .' b 0 334.100/ \ ± 0.500

11232.257.077

1 • l • 1

12624.320.096

17216.322.096

1 ' 1 ' 1

67712.332.099

1 • l • l

82944.

1 i i — — — — — — — — — —1240 1260 1280 SCAN11;34 11:45 11;56 TIME

15.2-1320

28.8-1322

13.1-1328

81.6-]332

100,0-1

334 .

MID MASS CHROMATOG09/20/84 2l!l?!00SAMPLE; 2UL OF 0.2RANGE: G 1,1350

<„

1— .„ ^ . , , - . , , , , ^... „ . . , , 1 — — . , . . , ] i | , ] , |122410673.63528.

^(•<-

•f.d

1 ' 1 i 1 " 1 ' 1 '122282819.516637.

119911:06

122417038.99348.

•V'-0>

11200Hill

RAMSNG/UL TCDDLABEL: N

122267529.399359.

1211

ST-4,

10; 1 7

0, CA2.5

LUtlQUAN;

1211

DC

A 4, 2.0122412363.73707.

1 '20;23

ATA; ST584092(ALIs F5840920BASE; U 20,

1^——r

1 '123011;28

3C #1350»103

0 0 :-) 6

i124011:34

SCANS 1185 TO 125

±

±

±

1±

125011;39

5

12624.320.0960.500

17216.322.0960.500

10880.328.0980.500

67712.332.099

0.590

82944.334.1000.500

SCAMTIME

MID MASS CHROMATOGRAMS DATA: ST5840920C #1350 SCANS 1185 TO 125509/20/S4 21:17:00 CALIi F5840320 #10SAMPLE; 2UL OF 0.2NGAJL TCDD STD, CALI#1RANGE: G 1,1350 LABEL: N -4, 2.5 QUAN: A A, 2.0 BASE: U 28, 3

37.3-] 25248.

320.096± 0.500

135424.

332.0991 0,500

00:' ; b 2

-n——'—————i——i——r-"—\———i——i —•'——i—————i——i1190 1260 1210 1220 1230 1240 1250 SCAN11;06 11:11 11:17 11:23 11:28 11;34 11:39 TIME

DATA: DH5840920C #1425 SCANS 1175 TO 1425CALI; F5840920 #10

MID MASS CHROMATOGRAMS89/20/84 21;43;00SAMPLE; 2UL OF CPSMRANGE; G 1,1890 LABEL: N1226

63104.346432.

-4- 2.5 QUAN; A 4, 2.0 BASE; U 20, 3

46.4-1320

122682432.

60.6-]322

122611624.

8.8-1323

1225189900.

81.0. 675/;13-332

1225135806.

100.0-, 825933-

334

1 . i i I i1200 1250l l ; l l 11:39

346432.

A/\/Y\454832.

AM62356.A/Vw/ \/ \ t 0.500

.

133030214.237671.

/V1329

39399.300299.

f\—i——i——|——i——r i "r

13305368.40736./\-i—i i i i ' i i

A n n -: ..) .•-, •;:

130012:67

137814634. 1413102510. 1908.y\ 11599.

' ' ' ' ' ' '

137819404. 1413129151. 2537.//"Y^ 14262.1 . . . . T— ,

13772662.16764.^

——1———i———i———i———i———i———i—'—r-

u \J -• .- \J „'

i 0.500

1350 140012:35 13:03

63104.320.096

± 0.500

82432.322,096

± 0.500

11984.323.097

± 0.500

116080.332.099

135936.334.180

SCANTIME

MID MASS CHROflATOGRAMS09/20/'84 21; 43; 00SAMPLE; 2UL OF CPSMRANGE; G 1,1425 LABEL: M -4, 2.5

DATA; DH5840920C #1425CALI: F5840920 #10

QUAN: A 4, 2.0 BASE; U 20- 3122G

50413. 123828U63. 48448.

230769,

SCANS 1193 TO 1260

50432.

257.077± 0.500

63104.

320.096± 0.500

82432.

322.096* 0.500

11904.

323.037± 0.500

; ;1260 SCAN^' '11:45 TIME

MID MASS CHROMATOGRAMS DATA; DH5840920C #1425 SCANS 1198 TO 1269ea^e. 21:43 .•00 CALI; F5840920 #10SAMPLE: 2UL OF CPSMRANGE; G 1-1425 LABEL: N -4, 2.5 QUAN; A 4, 2.0 BASE: U 20- 3

12265634S.

41.6-, 343414. 5gg^_

328.098± 0.500

12441312.6014.

110080.

332.099± 0.500

135936.

334.100± 0.500

1199 1288 121U 1226 1239 1246 1250 1269 SCAN1 1 ; 9 6 l l s l l l l s l ? 11;23 11;28 11:34 11:33 11:45 TIME

MID MASS CHROMATOGRAMS09/20/84 2l!43;00SAMPLE: 2UL OF CPSMRANGE: G 1-1425 LABEL: N -A, 2.5

DATA: DH5840920C #1425CALI; F5840320 #10

SCANS 1190 TO 1260

QUAN; A 4, 2.0 BASE: U 28,122663104.346432.

1225109900.675113. 110080.

332.099± 0.560

1225135906.825939./^\ 0 0 2- C) (J

135936.334.100± 0.500

119611:86

120311:11

121811:17

122011:23

123011:28

1240ll!34

125011:39

1260 SCAN11:45 TIME

MID MASS CHROMATOGRAMS09/20/84 21.-43;00SAMPLE; 2UL OF CPSMRANGE: G 1,1425 LABEL: N -4, 2.5

DATA: DH5840920C #1425CALI; F5840320 #10

QUAN; A 4, 2.0 BASE: U 20/ 3122682122.450541.

SCANS 1190 TO 1260

82432.

322.096± 0.530

110080.

332.099± 0.500

1260 SCAN11:45 TIME

f lID MASS CHROMATOGRAMS03/20/34 23;35;83SAMPLE: 2UL OF 0.2NG/'UL TCDD STD, CALI#1RANGE: G 1,1880 LABEL; N -4, 2.5 QUAN; A

12259233.

12.0n 56987-257

122511586.

,„ -, 71784.14.7-i ,^-\320

122515732.

20.0n 93/300-322

122364958.

81.6-, 23QW-332

122379666.

100.0-, 499%3-

334 .

1289 1220H i l l 11;23

/ \ 332.099/ \^ ± 0.508

/ \ 0 0 3/ \, ± 0.500

DATA; ST5840920D #1350CALIs F5840920 #10

4- 2.8 BASE; U 20, 3

— ] , ,

1 1 1

± 0.500

1 • 1

1 • 1

1240 126011;34 lli45

SCANS 1185 TO

1276778.3488.

± 0.500

'

'

'

-:' 6 ^

128011:56

1285

9568.257.077

± 0.500

11744.320.896

15968.322.096

65083.

79744.334.100

SCANTIME

09^20^84 a^Si'ee"'""" CALI: F5848920 ttl0

RANGE; G 1,1356 LABEL; N -4,'2.5 QUAN; A 4, .2..0 BASE; U 20, 3

14.7-i '328

"£• •

20.3-1322

12.8-1323

81.6-]332

100.0-1

334

1190 1200 1210 1220 1230 124011

<•-0 / \

/ V^^ ± 0.500

"-> / \/ V^^ ± 0.580

/ \, ± 8.500

'0^- / \Q / \^^ ± 0.500

± 0.500

MID MASS CHROMATOGRAtIS DATA: ST5840320D #1350

-tr.in i->-. - .i- s-SAMPLE; 2UL OF 0.2NG/UL TCOD STD, CALUtl122511580.71784.

' ' ' ' ' 1225 '15642.91206.

12259949.60226.

122364937.397775.

122379666.490583.^\ u o :' ^

^y ^-^

;06 11:11 11;17 11;23 11:28 11:34

SCANS 1185 TO 1255

11744.320.096

1

15968.322.B96

1

10208.328.098

1

65088.332.099

i ] -I

79744.0 ' 334.100

1250 SCAN11:39 TIME

MID MASS CHROMATOGRAMS DATA: ST5840920D #1358 SCANS 1185 TO 125509/20/84 23;35:09 CALI; F5840320 #10SAMPLE; 2UL OF 0.2NG/-UL TCDD STD, CALUtlRANGE; G 1,1350 LABEL; N -A, 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

23488.

122511580.''1784. 320.096

± 0.500

130176.

332.899± 6.500

00;:' " 7 0

1198 1260 1210 1228 1239 1240 1250 SCAN11;06 llsll 11;17 ll!23 11;28 11:34 11:39 TIME

• LD

C3

• ^

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-

MID MASS CHROMATOGRAMS09/20/'84 23:57:00SAMPLE: CPSMRANGE; G 1,1491 LABEL: N-4, 2,

DATA; DH5840920D #1CALI: F5840920 #10

5 QUAN: A 4, 2.0 BASE: U 20, 3122630020.162865. 1237 1344^ 20208. 18703.

115808. 105439.

SCANS 1190 TO 1260

30272.

257.077± 0.500

37248.

320.096± 0.500

48192.

322.096± 0.580

6592.

323.097±•0.500

1260 SCAN11:45 TIME

SCAMS 1190 TO 1260MID MASS CHROMATOGRAMS DATA: DH5840920D #109/20/84 23:57:00 CALI: F5840920 #10SAMPLE; CPSMRANGE: G 1-1491 LABEL; N -4, 2.5 QUAN; A 4/2.0 BASE: U 20/ 3

i&/35136.220501. 35328.

12441346.

-6682.

328.098± 6.500

-I————'————T1224

68026.417247. 68096.

332.993± 0.500

85120.

334.180s ± 8.500

1260? SCANHi 45 TIME

MID MASS CHROTOTOGRAMS09.-20/84 23:57; 08SAMPLE: CPSMRANGE: G 1 ,1491 LABEL; N -4, 2.5

DATA: DH58409200 ttlCALI; F5840929 #10

QUAN; A 4, 2.0 BASE; U 28, 31226

2% 1237 1244288702. ^g^ 24890.133085. 140538.

SCANS 1190 TO 1260

MID MASS CHROMATOGRAM589/20/84 23:57:00SAMPLE; CPSMRANGE; G 1,1491 LABEL; N -4- 2.5

DATA;CALI:

DH5840920D #1F5840920 #10

SCAMS 1190 TO 1260

QUAN: A 4, 2.0 BASE: U 20, 3122548087.268588. 4S132.

322.096± 0.500

68096.

332.699± 0.500

1268 SCAH11;45 TIME

10.2-1257

13.6-n328

17.8-1322 .

73.7-1332

100.0-1

334 .

MID MASS CHROMATOGRAMS DATA; ST5840921P #1350 SCANS 1185 TO 128509/21/84 19:25:00 CALIi F5840321 #20SAMPLE: 2UL OF 8.2NG/UL TCDD CALI STD #1RANGE: G L1800 LABEL: N -4, 2.5 QUAN; A 4, 2.0 BASE: U 20, 31211

6647.41M0- 6928./ \ 257.677/ \ ± 0.500

12118914.5G988- 9248./ \ 320.096/ V ± 0.500

121111988.783 8- 12128./ \ 322.096/ \ ± 0,503

120949981.331499- 50112./ \ 332.093/ \ ± 0.500

120967868.4533n- 67968./ \ 00 -' • ' 7 b 334.100/ \ ± 0.508

1200 1220 1240 1269 1280 SCANl l ; 1 9 11:31 11:42 11:53 12:05 TIME

MID MASS CHROMATOGRAMSas.' i. 19:25:00SAMPLE; 2UL OF 0.2NG/UL TCDD CALIRANGE! G 1/1350 LABEL: N -4, 2.5 QUAN: A

12118914.5690S.13 .b-i /"•

320

' ' ' ' 121111988.

17.8-, 78328-322

12117892.

12.3n ^-328

120949981.

73.7. 33H";332

1 ' 1 ' 11209

67868.IQQ Q 453311.100.0-1 /-^

334

————,————j————,————^————.———1199 1208 121011:14 11:19 11;25

/ 's^ ± 0.500

y " - 1 .33^ fyr--o.s^

/ \ 0 0 5 9 7 7y

DATA: ST5840921P #1350CALI: F5840921 tt20

STD (tl

'

' 1

1

s^-— . ^S^io— i — — r — — — i —122611:31

4, 2.0 BASE: U 20, 3

i • l

i ' l

l • l

l • l

i————]————i————]———1230 124611:36 11:42

SCANS

'

'

'

—i————|————i1250 SCAN

1185 TO 1255

9248.320.096

12128.322.096

± 0.500

8336.328.098

± 0.500

"1 -~^'

50112.332.899

± 0,508

'

67968.334.100

± 0.500

11:48 TIME

LO

O(n

CTs> ir»

en®g

g

a0

(")

ss» 0M

CL. »

<r —i

&^

o o

Qin 10

—«oi

8:

) (N

)C3

•I

:® 0

1'in

uL

;>

(SO

:OT.

m i-

LHO

O<X S

UJ ••

S-<

3 LU

MS

.a

£§

S§

M I D MASS09/21/84SAMPLE: 2UL OF CPSMRANGE: G

121156891.

39,1-1329

121176544.

52.5-1322

121110201.

-, , 58685.r . l-i .•'.323

1209107522.

73.8-, 688M3-332

—i——i——i~ ~ i -1—1209

145379.iee.0n 934^2-334

—i——i——[—- i -i—120011:19

331522.

, A .A V'—i——r~—r——i——S—

440784.

A/V"—T———r"——11——^———i———i———[———i———i———r——i———|———i———i———i———

• A rA / V

!\.

/V

CHROMATOGRAMS19S48.-00

1,1800 LABEL:

1

\A 299241.

1313, A 36341-

^

A± 0.500

1

• • 1 '125011:48

DATA: OH584e921ft ttl450CALIi F5840921 #20

N -4, 2.5 QUAN: A 4, 2.0

131327012.

—————^^

278723.

A13124709.37764.

.. ./\..

130012:16

BASE: U 29, 3

136013006.84736.^^

136017081.118176.y^

13612338.16262./-^

0 0

135012:44

13951462.10669.

13942107.13528., — ]

± 0.500

? •) !• •?

' 1140013:13

SCANS

± 0.500

± 0.500

± 0.500

1458 SCAN

1175 TO 1450

57024.320.996

' ' 1

76544.322.896

' ' 1

10400.

323.097

107648.332.099

' ' '

145920.334.106

13:41 TIME

MID MASS CHROMATOGRAMS DATA; DH5848921A #145@ SCANS 1190 TO 126009/'21/84 19:48:00 CAI-I : F5840921 tt20•-.fiiin i • .'in "i 1 1 " 1 1

0 0 ;' 9 3 ",'

107648.

332.099± 0.500

145920.

334.100± 0.590

1260 SCAN11;53 TIME

MID MASS CHROMATOGRAMS09/21/84 19:48:00SAMPLE; 2UL OF CPSMRANGE; G 1.1450 LABEL; N -A, 2.51211

56891.1198 331522.32115.

178781.

DATA: DH5840921A #1453CALI; F5840921 #20

QUAN: A 4, 2.0 BASE; U 20, 3

SCANS 1190 TO 1260

1209107431.68G280.

57024.320.096± 0.500

76544.322.036± 0.500

53248.328.098± 0.500

107648.332.099± 0.500

0 0 - ' 145920.334.100t 0.500

119811;14

120011;19

121011:25

122911;31

123811:36

124011:42

125911:48

1260 SCAN11:53 TIME

SCANS 1190 TO 1260MID MASS CHROMATOGRAMS DATA; DH5840921A #1450eS-^l.W 19.-43800 CALI; F5340921 #20SAMPLE; 2UL OF CPSMRANGE; G 1,1450 LABEL; N -4- 2.5 QUAN; A 4, 2.8 BASE; U 28, 3

121176544.440784.

122960736.

76544.

322.096± 0.500

107643.

332.099± 0.580

1268 SCAN11:53 TIME

SCANS 1185 TO 1260MID MASS CHROMATOGRAMS09/21/84 21!54;00

DATA: ST5840921Q #1260CALI; F5840921 #20

A 4, 2.0 BASE; U 20- 3SAMPLE; 2UL OF 0.2NG/UL TCOD STD, CALI #1RANGE; G 1,1800 LABEL; H-4, 2.5 QUAN:1208

15038.83658.10.2-1

257

13.9-1326

18.1-1322

74.8-]332

100.0n334

/ Y1208

20892.115614.

/ \ 320.096/ \^ ± 0.500

120827062.149540.y \1207

113052.640703.

/\^

1206151126.853663.y \

1190 1200 1218l l ! l4 11;19 ll!25

15360.257.077

± 0.500

21088.

27328.322.096

± 0.500r— l • 1 --""•l•••——n••r•—•—r-••N"-•|-M . . . , . . . . . . . . . )

113152.332.099

± 0.500

0 0 :•• ':' • i /1 151296.334.100

± 0.500

| i | i r i | i |1220 1238 1249 1259 1263 SCAN11;31 ll!36 11:42 ll!48 11;53 TIME

MID MASS CHROMATOGRAMS89/21/84 21:54:00SAMPLE; 2UL OF 0.2NG/UL TCDD STD, CALI #1RANGE: G 1,1260 LABEL; N -4, 2.5

120820892.

13.9n 1^614-320

1298270G2.

18. In 1495^-322

, ..„„, ..,..,——,-..„ ,„ , ...,,„129817636.

11.8n 98W-328

1207113052.

74.8. 640703-332

1206151126.

100.0n ^W-

334

1133 1298 121011:14 11:19 11;25

/ V^ ± 0.500

/ -V , , ± 0.508

/ \ 1227

1 ' 1 • 1 ''

/ \ 332.099/ V ± 0.500

/ \^ ± 9.560

' 1 * 1 '

DATA; ST5840921QCALI; F5S40921 #20

QUAN; ft 4 - 2 . 0 BflSE: U 20- 3

1 ' '• 1 '

^5iG-4 ^ - C.S^

10b4.6525.

===——1———1 n 1 '

1 ' 1 ' !

0

^^fcl,———[--'—•-——1—————]—————1—————]—————1—————1—————1

1220 123011;31 11;36

#1260

1

1

± 0.508

0 -" ' .->

124011;42

SCANS

——,——————

b

1250 SCHtl11;4S TIME

1185 TO 1255

21088.320.096

27328.322.096

'

17888.323.098

1 '

113152.

'

151296.334.100

MID MASS CHROMATOGRAMS DATA: ST5840921Q #1260 SCANS 1185 TO 125509-''21.''34 21:54:00 CALI; F5840321 #20SAMPLE: 2UL OF 0.2NG/'UL TCDO STD, CALI #1RANGE; G 1,1260 LABEL; N -4- 2.5 OUAN: A 4, 2.0 BASE: U 20, 3

37.3-1 42176.

320,096± 0.500

•r——-T •i'

226304.

332.099± 0.500

1190 1209 1213 1220 1230 1240 1256 SCAN11.-14 1 1 : 1 9 11:25 11;31 11:36 ll!42 11:48 TIME

SCANS 1175 TO 1475DATA; DH5840921fr-ttlCALl! F5840921 #20

MID MASS CHROMATOQRAMS09/21/84 22:19:00SAMPLE: CPSMRANGE: G 1,1800 LABEL; N121240672.223504.

-4, 2.5 QUAN: A 4, 2.0 BASE; U 20, 3

38.1-1320

49.3-1322

6691.6.4-1

323

U^—F-

73.3-. 458589-332

' ' 1

106632.100.0n 62^87- O 0 :'' . ' o 7334

1206 125011;

A

A' ' 1

A

/ V ± 0.508j \

a-fw\.

121252568.297637.

AMl i i 1 | I l i 1 j l i t

1211

37088.

(VA^i——1, .1., -. p^r^-——-^).^^

121078688.

A1210

19 11:48

131316331.121672.

———^-

131321349.153296.

f\

13132967.1879G.

. A,,' ' '

' ' ' '

r- i | i i i130012:16

13617997,43442.^\-

13618896.60167.^ -1-

13611189.6154.-^. r ~ ' '

l

135012:44

1396962.3564.

13961166.4208.i t i i i f r i i i

14433629.33136.

"•——f-^-r—P--

l

i i | • i i140013:13

1-^ i |——r-

1446486.1952.

• • 1 •

145013:41

t

'

t

±^"'T—

± 0.500

'

—i—

40784.320.096

0.500

52608.322.096

0.500

6848.323.697

0.500

78348.332.B99

106752.334.100

SCANTIME

MID MASS CHR011ATOGRAMS09/21/-84 22; 19; 88SAMPLE; CPSMRANGE; G 1,1550 LABEL: N-4; 2.5

121239536.

r •DATA: DH5840921ft'#lCALI; F5840921 #20

QUAN: rt 4, 2.8 BASE: U 20- 3

SCANS 1190 TO 1260

30624.

257.077t 0.500

40704.

320.096± 0.508

52608.

322.096± 0.500

6848.

323.097± 0.508

1260 SCAN11:53 TIME

, '^MID MASS CHROMATOGRAMS DATA: DH5840921A #189/21/34 22:19:80 CALI; F5840921 lt20SAMPLE! CPSMRANGE; G 1,1550 LABEL; N-4- 2.5 QUAN: A 4, 2.0 BASE: U 28, 31211

38624.230406.

12291433.7428.

SCANS 1190 TO 1260

38720.

328.098± 0.500

78848.

332.099± 0.500

0 0 ^ - •-' S ^

186752.

334.100± 0.500

123011:36

124011;42

125011:48

1260 SCAN11:53 TIME

MID MASS CHROIWTOGRflllS09/21/84 22;19!00SAMPLE: CPStIRANGE: G 1-1550 LABEL: N - 4 , 2.5

121240672.

223504.

C.:DATA: DH5840921A #1CALI; F5840921 #20

QUAN; A 4, 2.9 BASE: U 20, 3

1223 123824517. 2b,_52126336. 153632.

SCANS 1190 TO 1260

1210106632.624287. 0 0

119011:14

120011:19

1210lli25

1220ll!31

123011:36

124011:42

1250lli48

MID MASS CHROMATOGRAMS09/21/84 22:19:00SAMPLE! CPSMRANGE! G 1-1550 LABEL: N -A, 2.51212

52568.297637.

^ -'vDATA; DH5840921A #1CALI; F5840921 #20QUAN; A 4< 2.0 BASE; U 20, 3

SCANS 1190 TO 1260

52608.

322.096± 0.500

78848.

332.099± 0,500

1260 SCAN11;53 TIME

SCANS 1175 TO 1475MID MASS CHROMATOGRAMS DATA! DH5840924 #1650CALIi F5840924 #20

2.5 QUAN; A 4-2.0 BASE: U 20, 309/24/84 7!46;00SAMPLE; 2UL OF CPSMRANGE: G 1,1808 LABEL; N -4,1204

41731.238058.43.2. "ww- 1306

328

120451334.

53.2. 2%54e- 1306322

12046766.

7.2-, 37772- 1306323

120374016.

76.8. 460071-332

120396512.

100.0. 5^311-

334

—1———1———[———1——1———1——"I—|———1—' 1 —r 1 ——i———1-

1200 1250 1309ll;19 11;49 12:16

\ , ' 17876./ \ A A 135994.A VY\ A

^•^——^^•^————^————^^^•^————^^————^——————^^•^^^•^l——————'^—————f^^^———————^B^^^^

U , • 21368.. ( \ f\/\ 168575./v /VY\ A

\ , . 2687.\ /\f\ 13038.

^ A. ./Vl\. ^ . . . .........A ,

1\

1 \ 334.100j \

1353 ....7378. 38847635. 1139./\ 6048.

^^^^^^^^^^pBM^I.nw^w^MJ.HW .W^^——. ^^^^^^——^^M^ .B .W.H^W

13539757. 1389

63CT2- 3%.

14364221.

1352 35187.1260. A6218. / \." ; ^

' • \ ^ • 1 -r^ - 1 T •

1435487.156K

' ' ' ' ' ' ' ' ' ' ' '

0 0 ^ :i '• 2

' ' i ' i i i i i i i i i i1350 1400 145012:44 13:13 13:41

41792.320.096

± 0.500——p—

51392.322.696

± 0.500

'

6976.323.097

± 0.500

74240.332.099

± 0.508

96640.

± 0.500

SCANTIME

MID MASS CHROMATOGRAMS69/24^34 7; 46; 00SAMPLE; 2UL OF CPSMRANGE: G 1,1650 LABEL; N -4,

DATA; OH5840324 #1CALI: F5840924 #21

2.5 QUAN; A 4, 2.0 BASE; U 29- 3120528893.166069. 1216 1223

20454. 19412.169989. H4795.

SCANS 1178 TO 1249

29184.

257.077± 0.500

41792.

320.696± 0.500

51392.

322.996± 0.500

6976.

323.897± 0.500

1240 SCAN11;42 TIME

MID MASS CHROMATOGRAMS DATA; DH5840924 #1650 SCANS 1198 TO 1260©9/24./84 7; 46; 08 CALI; F5849924 »20SAMPLE; 2UL OF CPSMRANGE; G 1,1650 LABEL: N -4, 2.5 QUAN; A 4- 2.0 BASE: U 28- 3

120435858.

„-, . 224447. .,„„.37.5-i /"\, 36224.

328.098t 0.580

12221386.8542.

12521255.4289.

74248.

332.099± 0.500

0 0 3 .-; • ' 4

96640.

334.108± 6.500

1190 1200 1210 1220 1230 1249 1250 1260 SCAN11:14 1 1 : 1 9 11:25 11:31 11S36 11:42 11:48 11:53 TIME

MID MASS CHROMATOGRAMS39/24/34 7:46;80SAMPLE: 21JL OF CPSMRANGE; G 1,1658 LABEL: N -4,

43.2-|329

1204

53.2-1 1191322

37.5-1328

76.8-]332 .

1 , , ,

160.0-1 596311. yg^e.

334

l ' | i1170 1188 119011:82 11;08 11;14

119117597.91522.^\. y v--^ T v^21675.110425.

, , l ,

/ v-^ ± 3.500

/ \^ ± 0.500

DATA: DH5840924 #1CALI: F5840324 #21

2.5 QUAN: A 4,1204

4171G.237829.

50895,292724.

/'/^\\ ! 468.2' /-^X/ \^ ,/^^^T ' ± 0-500

120435858.224447.

129373993.458820.

——,—————,———1203

96512.

120011:19

2.8 BASE: U 20, 3

1216 122305579 28718.141309. ^68195.

121630785.

1 ' 1 i

12221386.

' -- - 8542.1 • l •

-r1 ' " i 1 " • ' •

u u ->

1210 122611:25 ll!31

SCANS

± 0.500

I

1

- ^

123611:36

1170 TO 1240

41792.320.096

51392.322.096

36224.328,098

74240.332.099

' 1

334.100

1240 SCAN11:42 TIME

MID MASS CHROMATOGRAMS09 24/84 7:46:00SAMPLE; 2UL OF CPSMRANGE; G 1,1658 LABEL; N - 4 , 2.5

DATA;CALI; DH5840324 #1650F5848924 #28

SCANS 1170 TO 1240

QUAN: A120450895.292724.

4. 2.0 BASE; U 20, 3

51392.

322.096± 0.580

74240.

332.099± 0.500

1240 SCAN11:42 TIME

MID MASS CNROMATOGRAMS89/24/84 8:41:00SAMPLE; 2UL OF 0.2NG/UL TCDD STD flIX, CALUtlRANGE: G 1,1880 LABEL; N-4 , 2.5 QUAN: A

12057867.

10.1. 51424-257

128510930.

14.0-. 64394-328

120513392.

,7 , 84233.-" -"I /' "^322 .

120359353.

74.0^ 3^939-332

1- 1 ' 1 ' 11203

80971.108.8-1334

1190 1200 121011:14 1 1 - i q 1l!?5

/ \ 1225 257.077/ \^ 3504800•. ± e-500

/ v^^ ± 3.500

/ Y^^ ± 8.500

588371.

/ ^v/ V^^ ± 0.500

DATA: ST5840924 #1300 SCANS 1185 TO 1240CALI; F5840924 tt21

4, 2.0 BASE; U 28, 3

8112.

l • l • 1

11216.320.096

13744.322.096

± 0.500

l • l • 1

59520.332.099

i ] i i i •• -|

0 0 .5 : ' ~ 7 80384.334.100

'" ' 1 ' 1 l ' ' "11220 1230 1240 SCAN11:31 11:36 11:42 TIME

MID MASS CHROMATOGRAMS09/24/84 8:4l!08SAMPLE! 2UL OF 0.2NG/UL TCDO STD MIX, CALUtlRANGE; G 1,1380 LABEL; N -4- 2.5 QUAN; A1205

10930.64394.

DATA:CALL-

ST5840924 #1390F5S40924 #21

SCANS 1185 TO 1255

4, 2.0 BASE; U 20, 3

MID MASS CHROMATOGRAMS DATA; ST5840924 #1300 SCANS 1185 TO 1230BS. ^ 8;41;88 CALI; F5840924 »21SAMPLE: 2UL OF 0.2NG/UL TCDD STD MIX- CALI#1RANGE: G 1,1300 LABEL; N -4, 2.5 QUAN; A 4- 2.0 BASE; U 20, 3

37.7-1 22432.

320.096± 0.500

119040.

332.899± 0.500

0 0 :' } ••}

119011:14

1200 1210 1220 1230 SCANH ; 1 9 11;25 ll!31 11;36 TIME

SCANS 1185 TO 1230M I D MASS CHROMATOGRAMS DATA: ST5840924A #1300CALI: F5840924 #21

BASE; U 20, 3BS .. 13s 25s 00SAMPLE: 2UL OF 0.2NG/UL TCDD STD MIX- CALUtlRANGE: G 1,1800 LABEL; N -4, 2.5 Q1JAN: A 4, 2.0

12099484.60424.

SCANS 1175 TO 1450DATA: DH5840924B #1450CALI: F5848924 #21

MID MASS CHROMATOGRAMS09/24 84 18:09:00SAMPLE: 2UL OF CPSMRANGE: G 1-1800 LABEL; N120923281.149305.

-4, 2.5 QUAN; A 4, 2.0 BASE: U 20, 3

38.9-1320

49.5-1322

7.3-1323

72.8-1332

100.0-1

334 .

149305.

UM1209

29717.193265.

A/V)12094159.25687.

A M1267

436B9.306901.

A.1207

59907.423727.

.A120811:19

rv\\ ,

' --T^

1 1 1 1

125011:49

131113023.

102176.

/V131117156.136383.

A13112341.16360.

•^^A^AAr^ ' y,/.——J^^-. .

130012:16

13585954.42306.W

13588225.58556.

. |

13571373.9222.

————^^ f '

135012:44

^" i ~^i y! ^^r"-'

0

1391796.5308.

13931872.5640,

0 4 0 0 1

140013:13

23328.320.096

± 0.500

~1——l——1

29728.322.896

± 0.5001 -T |

4384.. 323.097

/ \ ± 0.500

-r?-—^—

43712.332.099

± 8.500

60032.334.100

± 0.500

1450 SCAN13:41 TIME

MID MASS CHROMATOGRAMS09/24/84 18:39:00SAMPLE; 2UL OF CPSMRANGE: G 1-1450 LABEL;

120918834.

1195 113521.12183.

376.

DATA:CALI;

DH5840924B #1450F5840924 #21

SCANS 1190 TO 1260

N -4, 2.5 QUAN: A 4; 2.0 BASE: U 20- 3

19200.

257.877± 9.500

23328.

320.096± 0.500

29728.

322.096t 0.500

4384.

323,097± 3.500

1260 SCAN11:53 TIME

MID MASS CHROMATOGRAMS09-/24/-84 13:09:60SAMPLE; 2UL OF CPSMRANGE; G 1-1450 LABEL;

12092009S.143368.

DATA;CflLI:

DH5840924B #1450F5840924 #21

SCANS 1190 TO 1260

H -4, 2.5 QUAN: A 4, 2.0 BASE: U 20/ 3

0 0 -" Q 0 3

28320.

328.098± 0.500

43712.

332.099± 0.500

60032.

334.168± 0.508

119011:14

120011:19

121011:25

122011:31

123811:36

124011:42

125811:48

1260 SCAN11;53 TIME

MID MASS CHROMATOGRAMS09/24--84 13:09!00SAMPLE: 2UL OF CPStIRANGE: G 1-1450 LABEL;1209

23882.1195 146943.13389.74331.

DATA:CALI;

DH5840924B #1450F5840924 #21

SCANS 1190 TO 1260

N -4, 2.5 QUAN: A 4 - 2 . 0 BASE: U 20, 3

MID MASS CHROMATOGRAMS09/24/84 18;09;00SAMPLE; 2UL OF CPSMRANGE; G 1-1450 LABEL:1209

29703.193077.

DATA: DH5840924B #1450CALI; F5840924 #21

N -4, 2.5 QUAN: A 4, 2.0 BASE; U 20, 3

SCANS 1190 TO 1260

29728.

322,096± 0.500

43712.

332.099± 0.500

1260 SCAN11:53 TIME

MID MASS CHROMATOGRAMS DATA:CALI;09/20/84 18;22;08 \

SAMPLE: 2UL OF 50UL CONC., METHOD BLANK (10,0^,)RANGE; G 1-1800 LABEL; N - 4 , 2.5 QUAN: A 4, 2.0

T2365MB #1350F5840920 #10

SCANS 1185 TO 1285

MID MASS CHROMATOGRAMS09/20/34 18:22:09SAMPLE: 2UL OF 50UL CONC., METHOD BLANKRANGE; G 1,1350 LABEL; N -4, 2.5 QUANi A

DATA: T2365MB #1330CALI: F5840320 #10

4, 2.0 BASE; U 20, 3

SCANS 1185 TO 1255

SCANS 1180 TO 1250DATA! DH5840924A #1509CALI: F5S40924 #21

MID MASS CHROMATOGRAMSe9/-24/84 13855:80SAMPLE; 2UL OF CPSM#3RANGE: G 1,1506 LABEL: N -4, 2.5 QUAN: A 4- 2.0 BASE: U 20,

120840345. 1229

23901 ^^^^P- 29737-•"-—1' /'^v I'l'il'i?130907. / \ I""l"':'•

MID MASS CHROMATOGRAMS09/24/34 l7!45s80SAMPLE! 2UL OF 0.2NG/'UL TCDD STD, CALI #1RANGE; G 1,1800 LABEL; N-4, 2.5 QUAN;

DATA:CALI;

ST5840924B #1260F5840924 #21

SCANS 1185 TO 1230

1207124206.881479.

13440.257.977± 0.590

16352.328.836± 8.500

20672.322.896± 0.500

91003.332.099± 0.509

124416.334.108± 0.500

1230 SCAN11;36 TIME

MID MASS CHROMATOGRAMS09/24/84 17;45:00SAMPLE; 2UL OF 0.2NG/'UL TCDD STD- CALI #1RANGE; G 1-1260 LABEL: N-4, 2.5 QUAN;

DATA: ST5840924B #1260CALI: F5840324 #21

SCANS 1185 TO 1230

A 4, 2 . 9120916110.112166.

BASE: U 20,

1207124206.881479.

0 0 4 0 1

119011:14

120011:19

121011;25

122011:31

MID MASS CHROMATOGRAMS DATA: ST5840924B #1260 SCANS 1185 TO 123009/24/84 17;45;80 CALI; F5S48924 #21SAMPLE: 2UL OF 0.2NG/UL TCDD STD, CALI #1RANGE; G 1,1260 LABEL: N -4, 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

35.9-1 32704.

320.096± 0.500

182016.

332.099± 8.560

0 0 - 0 •! 2

119011:14

1200 121011:19 11:25

122011:31

1230 SCAN11:36 TIME

MID MASS CHROMATOGRAMSQ9y24/84 13;25800SAMPLE: 2UL OF 0.2NGA)L TCDD STD MIX, CALIttIRANGE; G 1,1300 LABEL; N-4, 2.5 QUAN; A 4, 2.01209

11653.73982.

DATA: ST5840924A #1300CALI; F5840924 #21

BASE: U 20, 3

SCAMS 1185 TO 1230

120915914.103818.

120810381.67578.

120793032.621514. 0 0 4 0 1 :->

1190l l ! l4

120011:19

121011:25

122011:31

MID MASS CHROMATOGRAMS DATA; ST5840924A B1300 SCANS 1185 TO 123003/24/84 13:25:88 CALI; F5848324 #21SAMPLE; 2UL OF 0.2NG/'UL TCOD STD MIX; CALUtlRANGE; G 1,1390 LABEL: N -4, 2.5 QUAN: A 4, 2.0 BASE; U 20, 3

MID MASS CHROMATOGRAMS09/24./84 13:55:80SAMPLE; 2UL OF CPSMtt3RANGE: G 1,1800 LABEL; N -4- 2.5

12261195 , 34488.

39.6-1320

12261194 , 45773.

51.7-1322

12261194 . 5965.

323

L^-—)———;———i———i———,———,———F^-^-1207

75276.73.2n 49^15-332

1207102936.

100.0n ™3-334

1200 125011:19 11:48

24006. A ,224495.I32720- / \ /\AA / V Y \30954. A ,295656.^•/V/A4176. A. ,40153.

-/VYV

]\f\

I \ ± 0.500

DATA: DH5840924A #1500CALI: F5840924 #21

QUAN; A 4 / 2 . 9 BASE: U 20, 3

131022828.170816.

———————^—————1310

29972.223047,

/\'

13104184.39784.

/V1 , , I 1

± 0.500

1 ' ' ' '

0 0 ^ '-; ; 5

130012; 16

SCANS 1175 TO

75570.^-

—1———i———i—

12:44

135710746.

135713924.93296./"\^

13562101.12124.^\

• 1 ' '1350

1375

40832.320.096

± 0.500

53248.322.096

± 0.500

7336.323.097

± 0.590

75392.332.099

103040.334.100

SCANTIME

MID MASS CHROMATOGRAMS09/24/84 13;55;09SAMPLE; 2UL OF CPSM»3RANGE: G 1,1500 LABEL;

DATA;CALI:

DH5840324A #1590F5340924 »21

SCANS 1180 TO 1250

-4, 2,5120840345.245093.

QUAN: A 4, 2.0 BASE: U 20-

MID MASS CHROMATOGRAMS09/24/84 13; 55; 03SAMPLE! 2UL OF CPSM#3RANGE; G 1,1500 LABEL; M -4, 2.5

120832217.196371.

OATA: DH5840924A #1CALI: F5348324 #21

QUAH; A 4, 2.0 BASE; U 20. 3

SCANS 1180 TO 1259

32608.

257.077± 8.580

40832.

320.096± 0.500

53248.

322.036± 8.539

7936.

323.697± 0.500

1256 SCAN11:48 TIME

NID MASS CHROMATOGRAMS DATA: DH5840924A #1508 SCANS 1180 TO 125089/24/'34 13; 55; 00 CALI; F5840924 #21SAMPLE: 2UL OF CPSM#3RANGE: G 1,1500 LABEL; N -4, 2.5 QUAN; A 4, 2.0 BASE: U 20, 31208

35977.35.1-1 229rae- 36160.

328.098± 0.500

75392.

332.099± 0.500

1297102936.690303.

0 0 .. 0 -'

103040.

334.100± 0.509

1188 1190 1200 1210 1220 1230 1240 1250 SCANll!08 11;14 1 1 ; 1 9 ll!25 11;31 11:36 11:42 11;48 TIME

MID MASS CHROMATOGRAMS DATA; T23G5MB #1350 SCANS 1185 TO 1255139/2^84 18; 22.-00 CALI; F5S40920 #10SAMPLE: 2UL OF 50UL CONC., METHOD BLANKRANGE: G L1350 LABEL; N - 4 , 2.5 QUANs A 4, 2.0 BASE; U 20, 3

>~

148992.

122474327.41%96- 332.093

± 8.509

0 0 ^ 0 1

1198 1268 1210 1220 1230 1240 1250 SCAN11:86 Hill 11;17 11:23 11:28 ll!34 l l ! 3 9 TIME

MID MASS CHROMATOGRAMSOS- O- 19; 93:80SAMPLE: 2UL OF 50UL CONC., DF0939-01RANGE; G 1-1800 LABEL; N -4, 2.5

12241520.

„ , 7360.3.4-1 /"l

257

12242027.

. -, 10027.4.7-i ^320

' 1 ' I12232693.

5.9. l3w-322

122240690.

S0.7n 22934S-332

122250539.

109.0-, 290893-334 .

1209 122911:11 11:23

/ \

/ \/ \ ± 0.500

/^y^^-^^-^A^^^,——^————^

/ \

/ \! \ ± 0.500

/ \ 0 0 ^ 0/ \ ± 0.500

DATA; T2365 #1350CALIi F5848920 #10

(10.13G), IFBQUAN; A 4, 2.0 BASE; U 20, 3

-- ^ yv-^^ ^-^^Y^^l • 1

'^^-^-^-^^^--^^^^^-^^-^/^^^——>^^-~^^l • l

^^ — — — — v — — ^ , p , , ^

i • i

' 1 ' 11248 126611:34 11;45

SCANS 1185 TO

12751191.6063./y^./—^v-"'——i—

"1^-"--^p^

'••••' ! )

128011;56

1285

1744.257.077

-t 0.508

2360.328.896

3088.322.096

± 0.500

40960.332.099

50752.334.100

SCANTIME

MID MASS CHROMATOGRAMS DATA: T2365 #1350 SCANS 1185 TO 125509/26/84 19:83:00 CALI; F5840920 #10SAMPLE: 2UL OF 50UL CONC., DF0039-31 <10.13G>, IFBRANGE: G 1-1350 LABEL; N -4- 2.5 QUAN: A 4, 2.0 BASE; U 20, 31224

2027.4.7-i

320

5.9-1322

40.0-1328

80.7-1332

180.0-1334

x ^/ \ . ^ O - - " • 328.096/ V u ± 0 . 5 0 0

12232693. / i?,^11 449 7 - •'"T— G) 3008./ \ 322.096/ '- . ± 0.500

. - ^>^———^^————— - . . t ^ - . .r^^-.^^^ ^——.....^r^^^,,^^^————————————————————^-'•'^^S „.——-———'^^———^^ , -^^S ^^

122320040.112224"^— 20320.

/ \ 9341 328-098/ V SSi. i 0-5001 I ' 1 ' 1 • • r !———r———T=———————————<•"^ •

122240690.

^ 229348- 40960.^- -^ / \ 332.099

/ \ ± 0.508|————j————,————^————i——.-,„,,, r~-^11 r'" r-- - i i • " ] ...—T...... i——••-.,

122250609.291510. o6& c-o7^/^\ <. ^ 0 0 - U 2 1 507J./ \ ^,-' 334.100

/ •\ t 0.500

1190 1200 1210 1220 1230 1240 1250 SCAN11S0G l l s l l 11:17 11:23 11:28 11:34 11:39 TIME

MID MASS CHROMATOGRAMS DATA; T2365 #1358 SCANS 1185 TO 1255Q3/26/84 19!03;00 CALI: F5840920 <tl0SAMPLE; 2UL OF 58UL CONC., DF0939-61 <18.13G), IFBRANGE; G 1,1350 LABEL; N -4, 2.5 QUAN: A 4- 2.0 BASE: U 20, 3

11.5-1 4720.

320.896± 0.500

81920.

332.099± 0.500

1190 1200 1210 1226 1230 1240 1250 SCAN11-.96 1 1 : 1 1 11:17 11;23 11:28 ll!34 11:39 TIME

MID MASS CHROMATOGRAMS09/20^84 19;30;00SAMPLE! 2UL OF 50UL CONC., OF0039-02RANGE; G 1,1808 LABEL; N - 4 - 2.5

12171403,

^ , 7064.2.l-i /^.257

12181551.

2.3-,328

12171850.

„ c 9683.2.6-i /^322

/ \ ± 0.580

121665547.

Q, „ 368824.*'-~1 f^\

332

121680656.

100.0-. 457424. ^

334 .

1200 122011:11 11:23

————————————————————————————-A————f-—————-^-————————

.^ ^A/A/^YJ-——^\r^

8055.

A '/ \// \ -L n cno

k^-r-^—'^^/ '^

/ \ 322.096

^^^^^^^/^^r-^^A———————-\^-^-~~"*—'^———————r^———•"•——i———————~-p————————i————————i————————i————————i————————i———————-T————

/ '\ ± 0.500

/ \ ± 0.500

DATA: T2366 #1350CALI; F5840920 »10

(9.98G), IFBQUANs A 4 - 2 . 0 BASE: U 20, 3

12671239599.2811.

————/^^•u-^/V——?r———————7.-^/v—-^^^^^l • 1

o^i ^rrc- ^Q-16" l ^

~'————i————' •^/^"^'

i • i

^0 0

1240 126011:34 11;45

SCANS 1185 TO

1046.5528.

/^' 1

v ^^^^^^^'\ /^-

^—••^Y/•"A^-\ —^ ---

'

'. •^ ?. '.".

' i128011; 56

1285

1656.257.677

— ± 0.500

1832.320.096

2080.

65664-332.099

80768.334.100

SCANTIME

SCANS 1185 TO 1255MID MASS CHROMATOGRAMS DATA: T2366 #135009/20 84 19:30:00 CALI; F5840920 #10SAMPLE: 2UL OF 50UL CONC., DF0039-02 (9.980, IFBRANGE: G 1,1350 LABEL; N -4, 2.5 QUAN: A 4- 2.0 BASE: U 20, 31218

1489.7283.2.2i

320

1 ' [ ' 1 ' 1 '12171830.

,, c 9184.2.6-1 /'--.322

A^-^s,^^^—^/\^/^——-^^-—————-K^—1217

32384.40.3. 1883^328

1216£5547.

81.3n 368824-332

121680G5G.

inn a 457424.100.0-1 ^-\

334

1— | i | i T i | i1190 1200 1216 122011:66 11:11 11:17 11:23

f J-0-J*

/-\^-— ^- ———•"•''• \ / ~\^' \^

/-' • ./ \ + fl.TOfl

/ \ 1235 1243 323.038/ '\ 782. 1464. ± 0.500

/ V ± 0.500

/ \^ ± 8.50Q

1800.320.396

——————————————————————————————————————————± 0.500

^^-( p^^^^^Y^^-i

2080.322.896

---^-^,-^-^/r^^^^~'^^^..^^\... ^/- ,-/ ^ i ^ - | ^ i

32512.

4193. 8131." ••—r" • '"•T - i - r- i '

65664.332.099

1 ' 1 ' 1 '

o n . . ; . . 80768-334.100

1 ' 1 ' 1 1

1230 1248 125U SCAM11:28 11:34 11:33 TIME

MID MASS CHROMATOGRAMS DATA: T236G #1350 SCANS 1185 TO 125509/29/'84 19:38; 00 CALI; F5840920 #10SAMPLE; 2UL OF 50UL CONC., DF0039-02 (9.980- IFBRANGE: G 1,1350 LABEL; N-4, 2.5 QUAN; A 4. 2.0 BASE; U 28- 3

131328.

332.099± 0.500

0 0

1199 1290 1210 1220 1230 1240 1253 SCAN11 : 9 6 1 1 ; 1 1 11;17 ll!23 11:28 11:34 11:39 TIME

MID MASS CHROMATOGRAMS09/20-/84 28:09:80SAMPLE: 2UL OF 59UL CONC, DF8039-03RANGE: G 1,1880 LABEL: N -4, 2.5

1.7-1257

l • l • i •

1.9-1320

2.5-1322 .

79.6-,332

1 ' 1 ' 1 '

100.0-1334

119B 1299 121011:06 l l s l l 11:17

/—. / ' ^ ± 0.500. . /"Y J^ V. ./ V./ \ J^, -, .A. ^^—J—^' \/^ '\> J^

/ \^ ± 8.500- i ji.^—i-.^——^^-w——^—^—^^^s^^

y '\ ± 0.500^~^~]-- i ' •^|^'>--^ j i^-

DATA; T2367 #1260CflLIi F5840920 #10

(9.95G)- IFBQUAN; A 4, 2.0 BASE: U 20, 3

12242472.14668.

r\12252604.12892.

/\

12253433.16966.

/X1 '

1223122488.682417.

/ \

1 '1223

154037.845463.

122011;23

• 1 ' ———1 " ^

1 ' ^ • ^ i " i

T • 1 •

00 . :

I 1 1 '1230 124011:28 11:34

SCANS 1185

V-/ —^——

' - ^ ' ^ ^ -

"" ''T "r

± 0.500

1

' 2 0

t 0.500

1 '125011:39

TO 1260

2688.257.077

2944.328.096

1

3816.322.096

1

122624.332.099

1

154112.334.100

11260 SCAN11:45 TIME

MID MASS CHROMATOGRAMS09/20/84 20; 09.-00SAMPLE; 2UL OF 50UL CONC,RANGE; G 1,1268 LABEL;

1.9-1320

1225

-, c 16966. /2•51 /\ t"

322

^ , , , ,

59141.38.5-, y2951-329

1—— | i | r •••••

79.6-1332

1— | i | - ,

100.0. <^. ^ ^

334

1— | i i . .1190 120911:06 11;11

/ "'•Y ± 0.500

/ V ^°y '\ - ± 0.500

/ V ± 0.500

/ \ ± 8.500

/ \^ ± 0.500

DATA; T2367 #1260CrtLI; F5840928 #10

DF0039-03 <9.S5G), IFBN -4; 2.5 BUAN; A 4 - 2 . 0 BASE: U 20.

12252595.12796.

3433.

1225

1223122488.682417.

1 ' 1 ' 11223

154037.

/ \

1210 1220 123911;17 11;23 11:28

3

, ^ - Y ^

^Cjl i.^-

T — — " ' \ — — — —

1

5^°0 0 ••.

124011:34

SCANS 1185 TO

A ^W

i11""''^i"- ^

I

'

' " 1 ""

,'' f- i

125811:39

1255

2944.320,096

3816.322.096

59264.328.098

122624.332.099

—i

154112,334.100

—iSCAMTIME

MID MASS CHROMATOGRAMS DATA; T23G7 #1260 SCANS 1185 TO 125503/20/84 20:09;00 CALI: F5S40920 #10SAMPLE; 2UL OF 50UL CONC, DF0039-83 ( 9 . 9 5 G ) , IFBRANGE: G 1,1260 LABEL: N -4, 2.5 QUAN; A 4, 2.0 BASE: U 20. 3

4.8-1 5888.

12252595.12796. 320.096

± 0.500

200.0-1 245249.

1223122488.682417. 332.099

± 0.500

0 0 4 •J

1 1 1 1 1 1 11190 1200 1210 1220 1230 1240 1250 SCAN11:86 1 1 : 1 1 11:17 11:23 11:28 11:34 11:39 TIME

5.5-,257

6.6-i320

8.0-,322

81.3-1332

100.0-1334 .

MID MASS CHROMATOGRAMS DATA; T2368 #1260 SCANS 1185 TO 126009/20/84 20!34:00 CALI: F5S40920 #10SAMPLE: 2UL OF 50UL CONC- DF0039-04 '10.200- IFBRANGE; G 1-1800 LABEL; N -4, 2.5 QUAN; A 4, 2.0 BASE; U 20- 31227

9332.49010. 37,7/\ 1252 9' 1 2-/ \ 2282. 257.077/ '\ 18904. ± 0.500

122611237.6a42L 11648./ \ 1584. 320,096/ V^ 8400. ± 0-500

122613984.8e248- , 14176./ \ 2316 322.096/ \ 14152. ± 0-500

1225143768.781-544- 143872./ \ 332.099/ \ ± 8.560

1225176563.988032- 176896./\ 0 0 . . 0 2 ^ 334.100/ X t 6.500

1190 1203 1210 1220 1238 1240 1258 1260 SCAN11:95 1 1 ; 1 1 ll!l7 H;23 ll!28 ll!34 11:39 1 1 ; 45 TIME

MID MASS CHROMATOGRAMS09^20/84 20:34;08SAMPLE! 2UL OF 50UL CONC, DF0039-04 '10.20G), IFBRANGE; G 1-1260 LABEL: N - 4 , 2.5 QUAN;

6.5-1320

8.0-i322

39.4-1328

81.3-1332

1 • 1 • 1 "

106.0-1334 .

1 ' 1 ' 1 ' ' 1 ' 11190 1203 1210 1220 1238 124011:06 11;11 11:17 11;23 11:28 11;34

/ \ 1247 wo aqc/ \ 1-5RR 320.036/ \. idwb. , n, c,aa^/ Y^ J882^

/ \ ± 0.500

/ \ U U '.'. •J - ---

DATA: T2368 #1260CALI: F5840920 #10

A 4. 2.0 BASE: U 20, 3122611198.59946.

1226 ' ' '13839.76342./ •

/ \ paas 322.896y v, i2 -. ^ i • i ^—"" r" ^^^^——

122669570.394000.

r^-—i———i^^'1-^'——i——1225

143768.781544.

1225176563.988032.

SCANS 1185 TO 1255

11472.

14112.19d7

69760,1251 328.098

33052. ± 0-500

i

143872.332.099

]

176896.334.100

± 0.500

——i————[————i1250 SCAN11;39 TIME

MID MASS CHROMATOGRAMS DATA; T2368 #1260 SCANS 1185 TO 125599/20/84 20:34:00 CALIi F5840920 «10SAMPLE; 2UL OF 50UL CONC- DF0039-04 '10.20G), IFBRANGE: G 1,1260 LABEL; N -4, 2.5 QUAN: A 4, 2.0 BASE: U 20. 3

15.9-] 22944.

320.096± 0.500

12471386.4882.

287744.

1225143768.781544. 332.899

± 8.500

—I————,———^————i————^————,———^————————^————————^————————^———,1190 1209 1218 1220 1239 1240 1258 SCAN11:06 11:11 11:17 11:23 11:28 11:34 11;39 TIME

SCANS 1185 TO 1260MID MASS CHROMATOGRAMS DATA; T2369 #126009 20/84 20;55:08 CALI; F5840920 #10SAMPLE; 2UL OF 50UL CONC, DF0039-05 <9.99G), IFBRANGE; G 1-1800 LABEL; N -4, 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

1198 1225^o 1127.1660.

257.077± 0.500

1648.328.096± 0.500

1840,322.096± 0.500

80.4-1332

100.0-1

334 .

1225148840.870947.

1190 1260 1210 1220 123011;06 11:11 11:17 11:23 11:28

1133

±

140 0 4 ;; 3 • - 3;

±• l ^ ' •• -^ l.I'.,,. . • . . 1 • j 1. •

12401 1250 i 126011.-34. 11;39 i ll!45

9808.2.0990.500

8992.4.16138,588

SCANTIME

MID MASS CHROMATOGRAMS09/20/84 20:55:00SAMPLE; 2UL OF 50UL CONC, DF0039-05 ( 9 . 9 9 G ) ,RANGE! G 1,1260 LABEL: N -4, 2.5 QUAN: A

DATA; T2369 #1260CALI; F5840920 #10

IFBA, 2.6 BASE: U 20, 31228

1361.6800.

SCANS 1185 TO 1255

1225119509.702703.

1225148840.870947.

119611:06

120011:11

121011:17

MID MASS CHROMATOGRAMS DATA; T2369 #126009/20/84 20:55:00 CALI; F5840920 »10SAMPLE; 2UL OF 5011L CONC- DF8039-05 ( 9 . 9 9 G ) , IFBRAMGE; G 1-1260 LABEL; N -4, 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

SCANS 1185 TO 1255

1130ll;e6

120911:11

1210ll!l7

1225119599.702703.

125611:39

SCANS 1185 TO 1285MID MASS CHROMATOGRAMS DATA; T2370 #1358e9/28-'84 22:10:00 CALI; F5840920 #10SAMPLE; 2UL OF 50UL CONC., DF0039-06 (10.02G), IFBRANGE: G 1-1880 LABEL: N-4- 2.5 QUAN: A 4- 2.0 BASE; U 20, 31228

5225.25988.

SCANS 1185 TO 1255MID MASS CHROMATOGRAMS DATA: T2370 #135009/20/84 22;10;00 CALI; F5840320 »10SAMPLE: 2UL OF 50UL CONC., DF0039-06 00.02G), IFBRANGE; G 1,1350 LABEL; N - 4 , 2.5 QUAN: A 4 - 2 . 0 BASE: U 20, 3

12286476.

p 34384.^ '206 1214c ^ iddR- 1961.

MID MASS CHROMATOGRAMS DATA; T2370 #1350 SCANS 1185 TO 125509/20 34 22:10:00 CALI: F5840920 #10SAMPLE! 2UL OF 50UL CONC.- OF0039-06 <10.02G), IFBRANGE; G 1,1350 LABEL; N -4, 2.5 QUAM: A 4, 2.0 BASE: LI 20, 3

18.2-1 13952.

320.096± 0.500

1190 1209 1210 1220 1230 1240 1256 SC.AH11:06 l l ; l l ll!l7 11:23 11:28 11:34 11:39 TiriE

MID MASS CHROMATOGRAMS09/20/84 22!33;00SAMPLE; 2UL OF 50UL CONC-RANGE: G 1-1800 LABEL;

DF0039-07 (10.15G)-N -4- 2.5 QUAN: A

DATA; T2371 #1260CALI: F5840920 #10

IFB4, 2.0 BASE; U 20- 31231

5531. i24131805. 3687.

20817.

SCANS 1185 TO 1260

MID MASS CHROMATOGRAMS09/20/84 22;38;00SAMPLE: 2UL OF 58UL CONC,RANGE; G 1-1260 LABEL:

DF0039-07 (10.15G)/N -4- 2.5 QUAN; A

IFB4, 2.

12963165.17472.

DATA: T2371 #1260CALI; F5840920 #100 BASE: U 20, 31230

7848.41955.

SCANS 1185 TO 1255

1228119480.777347.

C 0 0 ^ 'J .i

119011:66

120011:11

121Q11:17

1226n;23

123011;28

124011:34

125811;39

HID MASS CHROMATOGRAMS09/20/84 22:38:00SAMPLE; 2UL OF 50UL CONC, DF0039-07 (10.15G), IFBRANGE; G 1,1260 LABEL; N -4, 2.5 QUAN: A 4. 2.0

DATA: T2371 #1260CALI; F5840920 #10

BASE; U 20, 3

SCANS 1185 TO 1255

12083404.27456. 1242

674.2409.

119611:06

120011:11

121011:17

122011;23

MID MASS CHROMATOGRAMS DATA; T2372FC #1260Q9/24/84 16;49.-00 CftLI; F5840S24 #21SAMPLE; 2UL OF 50UL CONC- DF8939-09 (100ML), FC DRANGE: G 1,1800 LABEL; N-4- 2.5 QUAN: A 4, 2.0 BASE; U 20, 3

SCANS 1185 TO 1233

584.322.936± 0.500

19236.332.839± 0.500

25920.334.100± 9.508

1230 SCAN11;36 TIME

MID MASS CHROMATOGRAMS DATA: T2372FC #1260Q9./24/84 16:49:80 CALI: F5S40924 #21SAMPLE: 2UL OF 50UL CONC. DF0039-88 (100«L>, FC DRANGE; G 1,1260 LABEL: N -4, 2.5 QUAN: A 4, 2.0 BASE; U 28, 3

SCANS 1185 TO 1230

57£.

329.036± 0.503

584.322.896± 0.500

9024.328.098± 0.500

19296.332.S39± 0.500

25920.334.100± 0.500

1230 SCAN1 1 ; 3 6 TIME

en <s)cri CT<s inI'M ®COn

SCANS 1185 TO 1285MID MASS CHROMATOGRAMS DATA: T2373 #1350eS- e t 23i05!00 CALI; F5840920 #10SAMPLE! 2UL OF 50UL CONC., DFe839-09 (10.05G), IFBRANGE; G 1,1800 LABEL: N -4, 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

1760.257.877± 0.500

704.322.09S± 0.500

77952.332.099± 8.509

99840.334.100± 0.500

12801 1 : 1 1

122011:23

1240lli34

126011;45

1280 SCAN11;56 TIME

MID MASS CHROMATOGRAMS DATA: T2373 #135009 20--84 23:05;80 CALI; F5840920 #10SAMPLE: 2UL OF 50UL CONC., DF0039-09 (10.05G), IFBRANGE; G 1,1350 LABEL; N -4, 2.5 QUAN; A 4, 2.0 BASE; U 20, 3

SCANS 1185 TO 1255

704.322.096± 0.500

39336.328.098± 0.500

77352.332,099± 0.500

99840.334.100± 0.500

1250 SCAN11;39 TIME

MID MASS CHROMATOGRAMS DATA: T2373 #1350 SCANS 1185 TO 125539/28^84 23; 05; 00 CALI; F5840920 #10SAMPLE; 2UL OF 50UL CONC.- DF0039-09 <10.05G), IFBRANGE; G 1-1350 LABEL: N -4» 2.5 QUAN; A 4 , 2.8 BASE; U 20- 3

200.0-1 155904.

332.999± 0.500

0 0 4 0 ., u

1190 1200 1216 1229 1230 1240 1250 SCAN11:06 1 1 : 1 1 11:17 11:23 11:28 11:34 11;39 TIME

SCANS 1185 TO 1285MID MASS CHROMATOGRAMS DATA: T2374 #135009/21/84 20!37-, 00 CALI; F5840921 #20SAMPLE! 2UL OF 50UL CONC.. DF0039-10 ( 9 . 9 5 G ) , IFBRANGE: G 1-1800 LABEL: N -A, 2.5 QUAM; A 4 , 2.0 BASE: U 20- 31261

2634.20690.n -, ^;tl0-)0.3.2-1 A^-^

257 / ^

MID MUSS CHROMATOGRAMS DATA; T2374 #135009/21/34 20:37:00 CALI: F5848921 #28SAMPLE: 2UL OF 50UL CONC., DF0839-10 ( 9 . 9 5 G ) , IFBRANGE: G 1,1350 LABEL; N -A, 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

SCANS 1185 TO 1255

MID MASS CHROMATOGRAMS DATA; T2374 #135009/21/84 20;37;80 CALI; F5840921 #20SAMPLE; 2UL OF 50UL CONC.- DF0039-10 (9.9 5 G ) , IFBRANGE; G 1-1350 LABEL; N -4. 2.5 QUAN; A 4 , 2.0 BASE: U 20, 3

SCANS 1185 TO 1255

MID MASS CHROMATOGRAMS09/21/84 21:31:00SAMPLE: 2UL OF 56UL CONC.RANGE: G 1,1800 LABEL;

12138323.

10.9-, 50972-257

121310852.

14.1-1320

121314643.

19.3-, 90226-322

- T -—r - - - -i1212

58317.3J8503.

332

121178165.

•180.0-, 508263-334 .

i [ i120011:19

70168.

/ \ 328.036

/ V^ ± 0.500

/ \\

^

- . , , DATA: T2374)<S\^c,oV)\\^ -Ji'f'1 CALI: F534092

, OF8939-10NS (9.99G), IFBN -4, 2.5 QUAN; A 4- 2.0 BASE: U 20,

i • r T

. ± 0.500

l • l •

Y^" i i '

I ' 1 '

0• - ' • '334.106

± 0.509

1220 1240lls31 ll!42

#13501 #20

3

12631855.

14026.

'

± 0.500

'

'

U 4 0 b 0

'126011:53

SCANS 1185 TO 1285

8560.257.077

t 8.500

11072.

1

14364.322.096

58496.332.093

'

78336.S , ^ •

; < •—,——^—..——,———1288 SCAN12:05 TIME

•; ^'"M I D MASS CHROMATOGRAMS ^f DATA; T23?4lS #135809^21•/84 21;31;00 . O f ^ i ' ' ' ^ CALI; F5840921 #20SAMPLE! 2UL OF 50UL CONC.- DF0039-10NS (9.99G), IFBRANGE; G 1,1358 LABEL; N -4, 2.5 QUAN; A 4, 2.0 BASE: U 20. 3

SCANS 1185 TO 1255

121310852.70168.14.1-i

320

121314629.

19.0. 89836-322

121328203.

.„. . 187656.3b.4-i ^"^328

121258317.378503.

332

I ' 1 ' ' 1 ' 1 ' 1 ' 1 '1211

78165..00.0-j ; , ,, 50^ ',, 0 0 4 0 5 1334

1 ' l ' 1 ' 1 ' 1 ' 1 '1190 1200 1210 1220 1236 124011:14 11:19 11:25 H!?)l )1;?!fi 11:4?

roioo.

/ \y ^-^^^

y \^^ ± 0.500

/ \ 1237/ Y^^ 1032.

^/ '-—— ' 4797.

'. . y". , : • ' " • ' ' ' • f \

/ Y, ± 0.500- '' ~~~~~-^-—

11072.320.096

± 0,500

'

14864.322.096

I '

28488.323.098

± 0.500

1 " l

58496.332.099

± 0.509

1

78336.334.100

1 1

1250 SCAN11;4F! TIMF

<^M I D MASS CHROtlATOGRAMS ,,J DATA: T2374NS #1350 SCANS 1185 TO 125509/21/84 21; 31; 60 Li^'^^Wr' CALI; F5840921 #20SAMPLE; 2UL OF 50UL CONC.- OF0039-ieNS <9.99G), IFBRANGE; G 1,1350 LABEL: N -4, 2.5 QUAN; A 4- 2.0 BASE: U 20, 3

332.099± 0.500

119Q 1290 1219 1228 1230 124B 1250 SCAH1 ! ; 1 4 l l ! l 9 11:25 ll.-Sl 11:36 11.-42 11:48 TIME

SCANS 1185 TO 1239flID MASS CHROMATOGRAMS DATA; T2376 #130889/24/84 9; 28:08 CALI; F5848924 4t21SAMPLE; 2UL OF 50UL CONC.- OF0039-12(10.07GMS); IFBRANGE: G 1-1800 LABEL; N -4- 2.5 QUAN: A 4, 2.0 BASE: U 28, 31206

766.3244.

1284101227.63S143. 0 0 4 0

12201 1 ! - ? 1

SCANS 1185 TO 1230MID MASS CHROMATOGRAMS DATA: T2376 #138009/24/84 9:20:00 CALI: F5840924 #21SAMPLE; 2UL OF 50UL COMC., DFe039-12(ie.07GMS)- IFBRANGE; G 1,1380 LABEL: N-4, 2.5 QUAN: A 4, 2.0 BASE; U 20, 312B7991.

A .5784.^

MID MASS CHROMATOGRAMS DATA: T2376 #1300 SCANS 1185 TO 123009/24/84 9:20;00 CALI; F5840924 »21SAMPLE: 2UL OF 50UL CONC., DF0039-12«0.07GMS), IFBRANGE; G 1.1360 LABEL: N -4- 2.5 QUAN; A 4/ 2.0 BASE; U 20< 3

147968.

332.099± 0.500

0 0 4 0 L) L.

1190l l! l4

—1————————I————————1————————r~~'————1————————'————————|1200 1210 1220 1230 SCAN11:19 11:25 ll!31 11:36 TIME

MID MASS CHROMATOGRAMS DATA: $2377 «130009/-24./84 9:44:08 CALI: F5840924 »21SAMPLE; 2UL OF 50UL CONC., DF0039-13<10.58Gt1S)- IFBRANGE; G 1,1800 LABEL: N-4, 2.5 QUAN: A 4, 2.0 BASE: U 20, 31206

99392.692592.

SCANS 1185 TO 1230

99968.257.077± 0.500

127104.320.036± 0.500

1206161028.1002150,

1204110641.696991.

0 0 ''i. :-; -J b

122011;31

110720.334.100t 0.500

1230 SCAN11:36 TIME

MID MASS CHROMATOGRAMS DATA: S2377 #130009/24-/84 9 ; 44; 08 CALI; F5840324 #21SAMPLE: 2UL OF 59UL CONC.- DF0039-13(10.50GMS), IFBRANGE: G 1-1300 LABEL; N -4, 2.5 QUAN; A A, 2.8 BASE; U 20; 31206126814.

779007.

SCANS 1185 TO 1230

127104.328.096± 0.500

1266161028.1002150. 161280.

322.896± 0.500

39744.328.098± 0.500

81792.332.899± 0.530

110720.334,100± 0.580

1230 SCAN11:36 TIME

;:,-••"MID MASS CHROMATOGRAtIS DATA; ,52377 #1300 SCANS 1185 TO 123009/24/84 9:44:00 CALI: F5840924 #21SAMPLE: 2UL OF SOUL CONC., DF0039-1300.50GMS), IFBRANGE: G 1,1380 LABEL: N -4, 2.5 QUAN; A A, 2.0 BASE; U 20» 3

200.0-1 254208.

320.096± 0.500

163584.

332.899± 0.500

1220 1230 SCANH.'il t 1 •Ifi TTMF

-I-' i--'DATA: ^2378 #1275CALI; F5S40924 »21

BASE; U 20, 3

SCANS 1185 TO 1230MID MASS CHROMATOGRAMS09/24/84 10:05:00SAMPLE; 2UL OF 50UL CONC.. DF0039-14C10.08GMS)- IFBRANGE; G 1-1860 LABEL: N -4, 2.5 QUAN: A 4. 2.0

2588.13830.

SCANS 1185 TO 1230MID MASS CHROMATOGRAMS DATA; S2378 #127583/24-'84 10:05:00 CALI: F5840924 #21SAMPLE: 2UL OF 50UL CONC., DF0939-14(10,08GMS)- IFBRANGE; G 1-1275 LABEL: N-4, 2.5 QUAN: A 4, 2.0 BASE; U 20, 31207

2903.16586.

1206134228.838501.

122011:31

vMIO MASS CHROMATOGRA11S DATA: S2378 #1275 SCANS 1185 TO 123089/24/84 10; 05; 00 CALI: F5840924 lt21SAMPLE: 2UL OF 50UL CONC., DF0039-14(10.e8GMS), IFBRANGE: G 1,1275 LABEL: N -A, 2.5 QUAN; A 4; 2.0 BASE: U 28- 3

.5-i 6560.

320.096± 0.500

200960.

332.899± 0.500

1230 SCAN11-W TTMF

•]..-

MID MASS CHROMATOGRAMS DATA; S2379 #127509^24.'S4 10:39:00 CALI; F5840924 «21SAMPLE; 2UL OF 50UL CONC.- DF0939-15<10.14GMS), IFBRANGE; G 1-1800 LABEL: N -4, 2.5 QUAN: A 4- 2.0 BftSE; U 20, 3

SCANS 1185 TO 1230

848.

257.077± 0.500

464.320.896± 0.583

512.322.096± 0.500

99968.332.099± 0,500

136960.334.100± 0.508

1239 SCAN11:36 TIME

MID MASS CHROMATOGRAMS DATA: 2379 #1275CALI: F5848924 #21

BASE; U 20, 399/24/84 10:39:00SAMPLE: 2UL OF 50UL CONC., DFe039-15(10.14GMS), IFBRANGE: G 1,1275 LABEL; N -4, 2.5 QUAN; A 4- 2.0

SCANS 1185 TO 1238

464.

320.996t 0.500

512.322.696± 8.500

46784.328.098± 0.500

39368.332.899± 0.500

136960.334.100± 0.500

1230 SCAN11; '1 f i TTMF

MID MrtSS CHROMATOGRAMS DATA: ^2379 #127509/-24/-84 10; 39; 00 CALI; F5840924 #21SAMPLE; 2UL OF 50UL CONC., DF0039-l5<10.14GH5)/ IFBRANGE: G 1.1275 LABEL: N -A. 2.5 QUAN; ft 4, 2.0 BASE; U 20, 3

SCANS 1185 TO 1230

928.

320.096± 0.500

19993G.

0 U i: 'J

332,099± 8.500

119011;14

120011:19

121011825

12201l!3l

1230 SCAN1l!3e TTMF

MID MASS CHROMATOGRAMS DATA; 2380 #1275eS -W 11:04:08 CALI; F5S40924 »21SAMPLE; 2UL OF 50UL CONC., DF0039-1G<10.01G11S), IFBRANGE: G 1-1880 LABEL; N-4- 2.5 QUAN; A 4, 2.0 BASE: U 20, 3

SCANS 1185 TO 1230

624.328,096± 0.500

512.322.096± 0.500

91264.332.893± 0.500

123136.334.100± 0.500

1230 SCAN11:36 TIME

MID MASS CHROHATOGRAMS09/24/S4 11:04:88SAMPLE! 2UL OF 50UL CONC., DF0039-16Q0.01GMS)- IFBRANGE; G 1,1275 LABEL: N -4; 2.5 QUAN; A 4, 2.0

I , i""DATA; 32380 #1275CALIs F5840924 #21

BASE; U 29, 3

SCANS 1185 TO 1230

624.

320.896± 0.500

1204122839.766191. 0 0 -4 : ) 6 (.

512.322.936± 0.500

42384.328.098± 0.500

91264.332.099± 0.500

123136.334.100± 0.500

119011:14

1200ll!l9

121011:25

122011:31

1230 SCANn;36 TIME

MID MASS CHROMATOGRAMS DATA: 2380 #127509/24/84 11:04:00 CrtLI; F5840324 #21SAMPLE; 2UL OF 50UL CONC.- DF0039-1600.01GMS), IFBRANGE; G 1-1275 LABEL; N -4, 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

SCANS 1185 TO 1230

1248.

320.096± 0.500

182528.

0 0 ^

332.099± 0.500

119011:14

1200ll!l9

121011;25

122011:31

1230 SCAN11:36 TIME

MID MASS CHROMATOGRAMS09/24/84 11:27:00SAMPLE; 2UL OF 56UL CMC.,RANGE: G 1.1800 LABEL;

DF0039-17C10.45GMS), IFBN -4, 2.5 QUAN: A 4, 2.0

DATA:CALI;

•r;^^--'S2781 Ttl275F5840924 #21

SCANS 1185 TO 1230

BASE; U 20; 3

416.328.896± 0.500

480.322.096± 9.500

80648.332.099± 0.500

109824.334.100± 0.500

1230 SCAN11:36 TIME

MID MASS CHROMATOGRAMS09/24/84 11:27:00SAMPLE: 2UL OF 50UL CMC.,RANGE: G LI 275 LABEL;

DF0039-17(10.45GMS), IFBN -4- 2.5 QUAN: ft 4, 2.0

Tr'.-;! f:--DATA: 52781 #1275CALI: F5840924 #21

SCANS 1185 TO 1230

BASE: U 20- 3

1205109681.685287. 0 0 4 " 6 3 109824.

334.160± 0.508

119011;14

120011:19

121011;?5

122011:31

1230 SCAN1 1 : 3 6 TTMF

/ ':;^ ^.<""MID MASS CHROIWTOGRAMS DATA; -S2781'#127509/24/84 11.•27;08 CALI; F5840924 #21SAMPLE; 2U. OF 50UL CNC.- DF0039-17(10.45GMS), IFBRANGE; G 1,1275 LABEL: N -4, 2.5 QUAN; A 4, 2.8 BASE; U 20, 3

SCANS 1185 TO 1230

0 0 4 ' i 7 0

11901 1 - 1 4

120011; iq

121011 •W

12201)-'!)

MID mSS CHROMATOGRAMS , , DATA; ^2782 »1275CALI; F5840924 #21

BASE: U 20, 3

09/24/84 11; 58; 80 c.-^ ^ .?-,('••'SAMPLE; 2UL OF 50UL CONC.--OF039-18(10.07GMS), IFBRANGE: G 1.1800 LABEL: N - 4 - 2.5 QUAN: A 4, 2.0

SCANS 1185 TO 1230

1267228004.1517880. 0 0 k 0 7 1

12201 1 - ^ 1

MID MASS CHROMATOGRAMS DATA: -S2782 #1275CALI; F5840924 #21

BASE: U 29, 3

W/2^94 1 1 ; 5S; 00 l c i i -!' \ ' l^v 'SAMPLE; 2UL OF 50UL COMC.- DF939-18(10.e7GMS)- IFBRANGE: G 1 -1275 LABEL; N -4, 2.5 QUAN: A 4, 2.8

SCANS 1185 TO 1238

120717083S.1154380.

1207228004.1517880,

M I D MASS CHROflATOGRAMS „ , , DATA; S2782 #127509/24/84 11; 58:08 J'.-.'l ( ' . • ' ' ' I ' ""'.'•' CALI; F5S40924 (t21SAMPLE; 2UL OF 50UL CONC., DF039-18<10.07GMS>, IFBRANGE; G 1.1275 LABEL; N - 4 , 2.5 QUAHs A 4, 2.0 BASE: U 28; 3

SCANS 1185 TO 1230

6144.

320.096± 8.509

342016.

332.B99± Q.598

1230 SCAN11!^ TTMF

TCDD DMA BEPORT • PARTIAL SCAN CONFIRMATIONCASE NO. 30.W/U7

Response Rat ios 'A Relative Abundances*

Sampledumber 320/322 320/324 257/322 257/259 194/196 160 161 194 196 257 259 320 322 324

prc'--o^,3 . Ib . r? . 3'?- ,'??- 1 4 3 - - ,o y 37 •f0 '(5 't-'0 -S2

Standardnumber 320/3;; 3?0/32« 257/322 257/259 194/196 160 161 194 196 257 Z59 320 3ZZ 324

T'.-i'P • 7^ ). b ,^fc I - 0 1 ' - ) 1.5^ 1 i l 2i '^ 3fc 33 ?s' ioo ^y

"f ielat ive to m/e 322

0 0 4 " 7

-. 1L ! I "lI——; lJ'[ LSl

u~i ir:i ir-i1& Qi-l l:-j

^ L---1

"T •AJ

€:•

;

^

|

l'T !!,^ . i

w =» , ,

?J I'''! ,." .;

— Li1 L.'l,s ---•; a

1— -Ja a ' 3 i: i<x

S i^ (- i(3 ,•'

I— ^-""

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SCANS 1185 TO 1230MID MASS CHROMATOGRAMS89/24/84 12;18;80SAMPLE; 2UL-SAMPLE; 2UL-OF 50UL (€OMC. - DF0039-190.97GMS), IFBRANGE: G "'I,'1880''LABEL: N-4, 2.5 QUAN: A 4, 2.0 .BASE: U 20, 31213

1489.9643. 2080.

257.077± 0.500

992.320.096± 0.500

1204166568.1120750.

1008.322,096± 0.500

122752.332.099± 0.500

166656.334.100± 0.500

122011:31

1230 SCAN11:36 TIME

MID MASS CHROMATOGRAMS09^24-/S4 12:18:08SAMPLE: 2UL-70F 50Ufa CThRANGE: G 1/1808 LffiE

••) i^--'DATA: S2383 #1275CALI; 'F5840324 #21

.- DF0039-190.97GMS), IFB: N -4, 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

12131489.9643.

SCANS 1185 TO 1230

A

1295122592.792575.

1204166568.1120750.

119011;14

120011-19

1210ll!9S

1220l l ! 3 1

SCAMS 1185 TO 1230MID MASS CHROMATOGRAMS09/24 84 12:18:00

DATA; S2383 #1275CALI; F5848924 #21

SAMPLE; 2UL OF 50UL,CQyC. - DF0033-19<9.97Gt15). IFBRANGE; G •-IrliPSi/ t.fiBS.L: N -4, 2.5 QUAN: A 4- 2.0 BASE: U 20- 3

1204166568.1120750.

119011:14

120011:19

121011:25

122011:31

DATA; &383 #1275 SCANS 1185 TO 1230MID MASS CHROMATOGRAMS03-/24/84 12:18;00 CALI; F5840924 «21SAMPLE! 2UL.OE 50UL CONC., DF8039-190.37GMS), IFBRANGE: G U^TS ^-A8EB: N -4- 2.5 QUANs A 4, 2.0 BASE; U 20- 3

119011:14

1200ll!l9

1210lli25

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M I D MASS CHROMATOGRAMS DATA; S2784-#l27589/24/84 14:29:00 CALI; F5840924 #21SAMPLE: 2UL OF.SaULXQNC., DF0039-26<10.17GMS), IFBRANGE; G ^1^18887 WGEL: N -A, 2.5 QUflN: ft 4, 2.0 BASE; U 20- 3

SCANS 1185 TO 1230

720.257.077± 0.500

688.320.096± 0.500

1198100944.6EB169.

122011;31

101120.334.100± 8.500

1230 SCAN11:36 TIME

MID MASS CHROMATOGRAMS09--24/84 14:29:00SAMPLE; 2UL ,OF iSBUL, CORANGE: G {,1275 "

, DF8039-20(10.17GMS), IFBN -4, 2.5 QUAN: A 4, 2.0

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SCANS 1185 TO 1230

BASE: U 20- 3

1198100944.660169.

121011:25

122011:31

060^00<^W

DATA: •S2784-ftl275MID MASS CHROMATOGRAMS09/24-/S4 14:29:00 CALI; F5840924 #21SAMPLE; 2U4-OF 59UL COW;. - DFe039-20(10.17G(1S). IFBRANGE; G ^,12-K VLWSit N-4, 2.5 QUAN; A 4- 2.0 BASE: U 20, 3

SCANS 1185 TO 1230

122011:31

MID MASS CHROMATOGRAMS09/24^84 14;49:08SAMPLE: 2UL OF 50U|- WRANGE; G i, 18^ ''TLttE

•T''v6r>-"'DATA: S278511275CALI; F5840924 #21

'., OF9039-21(10.0G11S), IFBL N -4- 2.5 QUAN: A 4, 2.0 BASE: U 20, 3

12076130.

40694.

SCANS 1185 TO 1230

MID MASS CHR011ATOGRAMS09/24-/84 14; 49 seeSAMPLE: 2UL OF 501 1. CObRANGE; G a,12TOVL®Bt

1C.- DF0e33-21<ie.0G11S), IFBL; N -4- 2.5 QUAN: A 4, 2.

12087431.46832.

••j'Tl-.vf1^\.",'t^

DATA:-S2785 #1275CALI; F5348924 »21

0 BASE: U 20- 3

SCANS 1185 TO 1230

£601700"r^^'^'"^'

M I D MASS CHROMATOGRAHS DATA;-S2785-»1275 SCANS 1185 TO 1230es^-^ 14:49:08 CALI; F5840924 #21SAMPLE: 2UL-OF 58Ui, WW" OF0039-21(19.0GMS)- IFBRANGE: G Vl'2?5 ^LWffi: N -4, 2.5 QUAN: A 4- 2.0 BASE; U 20, 3

15360.

320.096± 0.500

122240.

332.099± 0.500

119011:14

1200 12101 1 : 1 9 lls25

122011:31

1230 SCAN11:36 TIME

MID MASS CHROMATOGRAMS09/24-/84 15; 16; 00SAMPLE: 2l)L OF50UL,CfflRANGE: G v \i\Wvm

DATA: T2386 #1CALI; F5848924 #21

1C, DF0039-22 (10.00G); IFB;L: N -4- 2.5 QUAN; A 4 - 2 . 0 BASE: U 20- 3

12114348.27640.

SCANS 1185 TO 1230

1209139899.939251.

4752.257.077± 0.500

5536.326.836± 0.500

6576.322.096± 0.500

181632.332.099± 8.508

140032.334.100± 0.500

119011:14

120011:19

121011:25

122011:31

1230 SCAN11;36 TIME

MID MASS CHROT1ATOGRAMS09^-24/84 15:16!80SAMPLE; 2Uk-OF 50UL COHRANGE; G 'l Se "LABE

DATA: T2386 ttlCALI: F5840924 #21

;, DF9039-22 (10.90G), IFB1: N -A, 2.5 QUAN: A 4, 2.8 BASE; U 20, 3

12115332.33268.

SCAHS 1185 TO 1230

5536.320.996± 0.500

—112116255.38872.-0 S5

1209101464.686285.

—11209

139899.939251 .-0.'?^

1190l l i l 4

120011:19

1230 SCAN11:36 TIME

6576.322.096± 0.500

47940.328.098± 0.500

101632.332.099± 0.500

140032.334.100± 0.500

MID MASS CHROMATOGRAMS DATA; T2386 #1 SCANS 1185 TO 123009/24/84 15;16;08 CALI; F5848924 #21SAMPLE; 2UL OF 50UL fiOblp- DF0039-22 <10.e8G); IFBRANGE: G l/hfeB^LyBH-: N -4, 2.5 QUAN: A 4, 2.0 BASE; U 20, 3

11072.

12115332.33268. 320.096

± 0.500

203264.

332.899± 0.500

1 ' I • 1 • I ' I1190 1200 1210 1220 1230 SCAN11:14 1 1 ; 1 9 11;25 11:31 11:36 TIME

MID MASS CHROMATOGRAMS09/24/84 15:38!00SAMPLE! 2LIL OF 50UL.CQ]RANGE: G Z-lt.lSflet7 LftB

DATA: T2386D ttlCALI: F5840324 #21

iC, DF0039-22 DUPLICATE (10.BIG), IFBL: N -4. 2.5 Q<JflN; A 4, 2.0 BASE: U 20, 3

12113780.23082.

SCANS 1185 TO 1230

MID MASS CHROMATOGRAMS09/24^84 15:38;88SAMPLE: 2UL OF 50UL,CflRANGE: G 0 t-i ?9

DATA; T2386D ftlCALI; F5840924 tt21

DFe039-22 DUPLICATE (10.81G), IFBN -4, 2.5 QUAN; A A, 2.0 BASE: U 20, 31211

4578.28688.

SCANS 1185 TO 1230

12116007.36996. -O.S'6

1209117589.792672.-0.')^

119911;14

120011;19

660^00MID MASS CHROWTOGRAtIS DATA; T2386D #1 SCANS 1185 TO 1230es . 15; 38; 00 CALI; F5840924 #21SAMPLE: 2UL OF,50UL/rONC, DF0039-22 DUPLICATE <10.B1G), IFBRANGE: G ^KiSey WtXL-. N -4- 2.5 QUAN: A 4, 2.0 BASE: U 26, 3

9632.

12114578.28688. 320.096

± 0.500

173056.

332.699± 0.500

1190 120011;14 11:19

— 1 — — — — — — — — ' — — — — — — — — 1 — — ' — — — — — — — — 11210 1220 1230 SCAN11;25 11:31 11:36 TIME

o(mooMID MASS CHROMATOGRAMS DATA; T2387 #1260 SCANS 1185 TO 123909/24/84 15;59;80 CALI; F5840924 #21SAMPLE; 2ULnOE SBUh CTNC, DF0039-23 (10.50G), IFBPnili:!"- n • y i"?rti "i i-inn • ll • t . ?.'~i niiDH- n 'f. ?.R PWF! n ?o. 'i

(.) L y 0 0SCANS 1185 TO 1230DATA: T2388 #1260

i i l l l . l w-m'i-M II-•1n in new riiRnMnTonRnM^(».i. .i "l <r . ; " ' - rn ^

SCAMS 1185 TO 1230MID MASS CHROMATOGRAMS DATA: T2338 #12S009/24^4 16!25:00 CALI; F5840924 »21SAMPLE; aJU-iOF ^elfi OONC- OF0039-24, (18.07G), IFBRANGE: G 1,1260 LABEL; N -4< 2.5 QUAN: A 4, 2.0 BASE; U 20, 3

i,. ^ ^Sc^2__ „ ,4 .J - ^^-7

320.096± 0.500

1760.

20704.

332.099± 0.500

1190n;14

12001 1 : 1 9

12101 1 ! ? ^

1220H - t )

1230 SCANf l • ? f i TTMF