valley water management companyttrick 1-3 ~~' -1 ~ to ivlckittrlck 1-3 ualiey water management...
TRANSCRIPT
TELEPHONE (661) 410-7500
VALLEY WATER MANAGEMENT COMPANY7500 MEANY AVE.
BAKERSFIELD, CALIFORNIA 93308
June 15, 2015
Mr. Ronald HolcombCentral Valley Regiona9 Water Qua}ity Control Board1685 E StreetF~'esr~o, ~4 937f36
De~o~ fir. Holcomb:
FAX (661) 410-7506
Valley Water Manageme~~'Company (VWMC) has enclosed with this letter technical report asummary table presenting analytical data as required by CVRWQCB's order (Order) under theCalifornia Water Code Directive Pursuant to Section 13267, dated April 1, 2015 and received byVWMC ore April 6, 2015.
Produced water in the ponds at our facilities listed in Appendix A of the Order was sampled andanalyzed by Zalco Laboratories, Inc. in accordance with the water quality analysis and reportingrecgub~ements outlined in Appendix B of the Order. VWMC staff observed the sampling at eachfacility and Za9co's s~~~f performed the sampling in accordance with the required practices. Ininstances where a pond at one o~ WVMC's facilities was determined to be dry and/orpermanently out of service, Zalco verified this and issued a report on the attempted samplingevent. In addition, s~uv~~les collected in March 215, prior to the Order, by Precision Analyticaland processed by Zalco are included in the sumrviary table and on the enclosed location maps.
Enclosed with this letter technical report and submitted ~Bectronically by VWMC, you wa0~ ~u~~ asummary table providing the analytical d~t~ as well as s~o~ple dates, facility names, locationsand other available information as req~o~~~ by the Order. In addition, V1A/MC has enclosedsimple facility location maps with sample locations shown.
Any questions regarding ~hcs subc~nittal may be directed to me at (661 410-7500,czimmerman~vwwater.~um, or at the address in this letterhead.
Sincerely,
Chris~au~~ Zormmerc~~~Regulatory ~~~lementa~ion &ComplianceV~Iley ~l~ter Management Company
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Ualiey Water Management Company
McKitt~ick 1 FacilityKem Caun#y
Figure 3
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IncomEng wastewater
Ditch from A~cK'~ttrick 1
Temporary pondsadded for
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i ~A
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~cf~ittric~ 1-3 Facility
Gravity drainageKern County
pipesFigure 2
LEGEND
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Gravity drainagepipes
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Fiel
d:
Lease:
Faci
lity
Lat
/Lon
g
Zalc
o Sample ID#
Dates) Sample Taken
Sample Name/Location (Ke
y):
detection
reporting
Constituent
limi
tli
mit
Unit
s
TDS @ 180~C
10
mg/L
l.l.K, ilil@ LL, S@CilOfl nnLt~"I.L4,
subdivision (a
)(2)
(A) metals
Anti
mony
and
/or an
timo
ny compounds
0.07
2mg/L
Arsenic an
d/or
ars
enic
compounds
0.19
0.2
mg/L
Barium
11
mg/L
Bery
lliu
m0.05
0.1
mg/L
Cadmium
0.07
0.1
mg/L
Chromium
0.18
0.5
mg/L
Cobalt
0.06
1mg/L
Copper
0.16
0.5
mg/L
Fluoride
0.13
1mg/L
Lead
0.13
0.5
mg/L
Merc
ury
00
mg/L
Molybdenum
0.13
1mg/L
Nickel
0.5
0.5
mg/L
Sele
nium
0.35
0.5
mg/L
Silver
0.03
0.2
mg/L
Thal
lium
0.24
0.5
mg/L
Vanadium
0.04
1mg/L
Zinc
0.07
0.5
mg/L
BTEX
Ng/L
Benzene
Ng/L
Tolu
ene
~g/L
Ethy
lben
zene
Ng/L
Xylenes
~g/L
TPH a,a,a-Trifluorotoluene
0.001
0.001
mg/L
Gaso
line
Range Hyd
roca
rbon
s0.
015
0.05
mg/L
Edis
onEd
ison
MWSS/BV
C-P
lant
Fee 34
Race
trac
k Hill
McKi
ttri
ck No. 1
35.354961/-118.860055
35.392863/-118.821173
35.386157/-119648724
1505108-01
1505107-01
1505109-01
1505089-01
1505090-01
5/8/2015
5/8/2015
5/8/2015
5/7/2015
5/7/2015
CP-1
P-1
P-1
CP-1
CP-2
2400
2500
2400
11000
11000
ND
ND
ND
ND
ND
ND
ND
ND
0.078
0.066
0.37
0.42
0.4
1.2
1.3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.11
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.15
ND
ND
ND
2410
798
42.3
7.41
5.32
2210
496
17
49.5
31.8
64.2
213ND
ND
ND
1110
417
31.5
34.2
19.3
N D
N D
N D
0.0084
0.00795
7.26
2.94
0.224
0.132
0.103
Motor Oi
l Range Hydrocarbons
25
mg/k
gDiesel Range Hydrocarbons
310
mg/k
gPo
lynu
clea
r aromatic hydrocarbons
Acenapthene
0.5
10
~g/L
Acennapthylene
0.5
10
fag/
LAn
thra
cene
0.7
10
~g/L
Benzo(a)anthracene
0.8
10
~g/L
Benzo(b)fluoranthene
0.7
10
~g/L
Benzo(a)pyrene
0.7
10
~g/L
Benzo(g,h,i)perylene
0.8
10
Ng/L
Chrysene
0.8
10
~g/L
Dibe
nzo(
a,h)
anth
race
ne0.6
10
fag/L
Fluoranthene
0.8
10
Ng/L
Fluorene
0.5
10
Ng/L
Inde
no(1
,2,3
-cd)
pyre
ne10
~g/L
Napthalene
10
~g/L
Phenanthrene
0.7
10
Ng/L
Pyrene
0.8
10
Ng/L
Radionuclides li
sted
under CCR, ti
tle 22,
Table 64442
Radium-2
26pCi/L
Radium-228
2pCi/L
Gross alp
ha par
ticl
e activity (excluding
15
pCi/L
rado
n and uranium)
Uranium
20
pCi/L
Cations:
Sodium
70
mg/L
Calcium
0.05
mg/L
Magnesium
0.05
mg/L
Potassium
0.5
mg/L
Iron
0.1
mg/L
Stro
ntiu
m0.1
mg/L
Anions:
Nitrate
1.86
20
mg/L
Chlo
ride
1.2
500
mg/L
Sulfate
0.31
5mg/L
Carb
onat
e10
mg/L
Bica
rbon
ate
10
mg/L
Brom
ide
0.15
1mg/L
Boron
0.1
mg/L
Trace Elements (including):
Lithium
0.01
0.1
mg/L
2.05
N D
2.34
16.7
9.69
2.01
3.93
2.14
10.8
7.86
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
37.7ND
ND
ND
ND
ND
5.00ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4.75
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
780
830
780
5200
5900
79
75
69
160
160
10
11
11
49
49
11
11
10
82
83
ND
0.17
0.17
0.11
0.1
1.1
1.1
1.1
4.3
4.3
ND
ND
ND
ND
ND
1300
1300
1300
5800
7300
9.7
9.9
9.9
140
140
ND
ND
ND
ND
ND
350
370
350
550N D
5.6
5.7
5.6ND
47
13
12
12
48
~48
0.33
0.32
0.3
1.9
1.9
Strontium
0.1
m g/
L 1.
1 1.
1 1.
1 4.3
4.3
Manganese
0.03
mg/L
0.092
0.087
0.03
8 0.
08
0.085
Iron
0.1
mg/L
ND
0.17
0.17
0.11
0.1
ZALCO LABORATORIES, INC.
Analytical &Consulting Services
4309 Armour AvenueBakersfield, California 93308
June 12, 2015
Christine L. TimmermanValley Water Management Company7500 Meany AvenueBakersfield, CA 93308
(661) 395-0539FAX (661)_ 395-3069
TEL: (661) 205-2885FAX: (661) 410-750Q
Project ID:RE: 1505107
Dear Christine L. Zimmerman:
Zalco Laboratories, Inc. received 1 samples on 5/8/2015 for the analyses presented in the following report.
We appreciate your business and look forward to serving you in the future. Please feel free to call our office if youhave any questions regarding these test results.
Sincerely,
,~
/ '
Juan MaganaProject ManagerCC:
NSS: Non Sufficient Sample H: Exceeds Analysts Hold Tirne TTLC: Total Threshold Limit Concentration STLC: Soluble Threshold Limit Concentration TCLP: Toxicity CharecteristicLeaching Procedure MCL: Maximum Contaminant Level ': See Case NarrativeThe results in This report apply to the samples analyzed in accordance with tha chain of custody document. This anatytical report must be reproduced in its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-6°C.Mlcrobfologicaf analysts requires samples to be at least 4-10°C when received at the laboratory. For additional information regarding the limitations of themethods) referred to, please call us at fi63-395-0539.
ZALCO LABORATORIES, INC.
Analytical &Consulting Services
4309 Armour AvenueBakersfield, California 93308
(661) 395-0539FAX (661) 395-369
Valley Water Management Company Project: RWQCB Oilfield Ponds - 2Q2015 Work Order Na.: 15051077500 Meany Avenue Project #: Reported: 06/12/2015Bakersfield, CA 93308 Attention: Christine L. Zimmerman Received: 05/08/2015 13:45
Lab Sample 1D: 1505107-01 Collected By: Justin Graves
Client Sample Id: C-Plant Fee 34 P-1 Date Collected: 5/8/2015 8:50:OOAM
Date DateAnalyte Results PQL Units Flag Method Prepared Analyzed Init.
Alkalinity
Total Alkalinity 370 10 mglL SM 23208 5/8!15 5/8/15 SAMBicarbonate {HCO3) 370 10 mg/L SM 23208 5/8/15 5/8/15 SAMCarbonate (CO3) <10 10 mg/L SM 23208 5/8/15 5/8N5 SAMHydroxide (OH) <10 10 mg/L SM 23208 5!8/15 5!8115 SAM
CAM, Toxicity (17 Metals) TTLC Limits
Antimony <0.20 0.20 500 mg/L SW846 60108 5!11/15 5/12/15 SSArsenic <0.020 0.020 500 mg/L 5W846 60106 5111/15 5112J15 SSBarium 0.42 0.10 10000 mg/L SW846 60106 5111/15 5/12/95 SSBeryllium <0.01Q 0.010 75 mg/l SW846 60108 5/11/75 5112175 SSCadmium X0.010 0.010 100 mg/L SW846 60106 5!17/15 5/12115 SSChromium <0.050 0,050 25x0 mg/L SW846 60106 5!11/15 5/12/15 SSCobalt ~O.iO 0.10 8D00 mg/L SW846 6014B 5/11/15 5J92/15 SSCopper D.71 0.050 2500 mg/L SW846 60108 5/71/15 5/12/15 SSLead X0.050 0.050 1000 mg/L SW846 60106 5!11/15 5/12/15 SSMercury <0.0020 0.0020 20 mg/L SW846 7470A 5!12/15 5/92/15 SSMolybdenum <0.10 0.10 3500 mglL SW846 60106 5/11/15 5/12/15 SSNickel <0.050 0.050 2000 mg/L SW846 60108 5!11/15 5/12/15 SSSelenium <0.05 0.05 700 mg/L SW846 60108 511'1/15 5/12115 SSSilver <0.020 0.020 500 mg/L SW846 60108 5111/15 5/i2f15 SSThallium <0.50 0.50 700 mg/L SW846 60108 5/11/15 5/12/15 SSVanadium <0.10 0.10 2400 mg/L SW846 60108 5111/15 5h2l15 5SZinc 0.15 0.050 5000 mg/L SW846 60108 5/11/15 5/12!15 SS
General Chemistry MCL Limits
Fluoride <5.0 5.0 2 mglL EPA 300.0 5!8/15 5!8!15 MSSNitrate as NO3 <100 100 45 mg/L EPA 300.0 5/8/15 5/8/15 MSSElectrical Conductivity 4.4 0.010 mmhos/cm SM 25108 5!8/15 516(15 SAMBromide 5.7 0.10 mg/L EPA 300.0 5/8/15 5/8/15 MSSChtaride 1300 100 mg/L EPA 304.0 5/8/15 5/8/15 MSSpH 7.68 pH Units EPA 150.1 5/8195 5/8!15 SAMSulfate as SO4 9.9 0.50 mg/L EPA 300.0 5/8/15 5/8/15 MSSTotal Dissolved Solids 2500 10 mg/L SM 2540C 5!8/15 5/8115 SAM
Hardness
NSS: Non Sufficient Sample H: Exceeds Analysts Hold Time 1"fLC: Total Threshold limit Concentration STLC: Soluble Threshold Limit Concentration TCLP' Toxicity CharacteristicLeaching Procedure MCL: Maximum Contaminant Level ': See Case NarrativeThe results in this report apply to the samples analyzed in accordance with the chain of custody document. This analytical report must be reproduced in its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-fi°C.Microbiological analysis requires samples to be at least 4-10°C when received at the laboratory. For additional information regarding the limitations of themethods) referred to, please call us at 661-395-0539.
ZALCO LABORATORIES, INC.Analytical &Consulting Services
4309 Armour AvenueBakersfield, California 93308
(661) 395-0539FAX (661) 395-3069
Valley Water Management Company Project: RWQCB Oilfield Ponds - 2Q2015 Work Order No.: 15051077500 Meany Avenue Project #: Reported: 06112/2015Bakersfield, CA 93308 Attention: Christine L. Zimmerman Received: 05/08/2015 13:45
Lab Sample ID: 1505107-41 Collected By: Justin Graves
Client Sample ID: C-Plant Fee 34 P-1 Date Collected: 5!8!2015 8:50:OOAM
Date DateAnalyte Results PQL Units Flag Method Prepared Analyzed Init.
Hardness
Hardness (as CaCO3) 240 2.0 mg/L SM 23406 5/15115 5115/15 SS
Metals
Lithium
Metals - As Received
Magnesium
Potassium
Sodium
Calcium
Iron
Boron
Barium
Copper
Silica (Si~2)
Strontium
Manganese
Petroleum Hydrocarbons
0.32 0.10 mglL EPA 200.7 5/15/95 5/15/15 SS
11 0.050 mg/L EPA 200.7 5115/35 5/15115 SS
11 0.50 mgiL EPA 200.7 5115/95 5h5l15 55
830 70 mglL EPA 200.7 5/15/15 5/15/15 SS75 0.050 mg/L EPA 200.7 5/15/15 5/15/15 SS0.17 0.10 mg/L EPA 200.7 5/15115 5/15/15 SS12 0.10 mg/L EPA 200.7 5/15/15 5/15/15 SS0.46 0.10 mg/L EPA 200.7 5/15/15 5115/15 5S0.054 0.050 mg1L EPA 200.7 5/15/15 5/15/15 SS60 4.0 mgli. EPA 200.7 5/15/15 5/15115 SS1.1 0.10 mg/L EPA 200.7 5/15/95 5/15/15 SS0.087 0.030 mg/L EPA 200.7 5/15/15 5/15115 SS
Diesel Range Hydrocarbons 3.93 0.50 mglL SW846 8015B 5/20/15 5121/15 BIGGasoline Range 2.94 0.250 mg/L SW846 80158 5/20/i5 5120/15 HlPHydrocarbonsMotor Oil Range <0.15 0.15 mg/L SW846 80156 5120/15 5/21/15 BIGHydrocarbons
Surrogates °/, Recovery Recovery Limits Flag
a,a,a-Trilluorotolurne lU3 G9-125 5/2U/IS 15:05
Semivolatile Organic Compounds
Indeno(1,2,3-cd)pyrene <10.0 10.0 uglL SW846 8270C 5/14/15 5/20/15Naphthalene <10.0 10.0 uglL SW846 8270C 5/14/15 5/20/15Acenaphthytene <10.0 10.0 ug/L SW846 8270C 5!14/15 5/20115Acenaphthene <10.0 10.0 uglL SW846 6270C 5/14115 5/20/15Fluorene <10.0 10.0 ug/L SW846 8270C 5/14/15 5!20/15Phenanthrene 5.0 10.0 ug/L SW846 8270C 5/14/95 5!20115Anthracene <10.0 10.0 ug/L SW846 8270C 5/14/15 5120115
NSS: Non Sufficient Sample H: Exceeds Analysis Hold Time TTLC: Total Threshold Limit Concentration S7LC: Soluble Threshold Limit Concentration TCLP: Toxicity CharacteristicLeaching Procedure MCL: Maximum Contaminant Level ': See Case NarrativeThe results in this report apply to the samples analyzed in accordance with the chain of custody document. This analytical report must be reproduced In its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-6°C.Microbiological analysis requires samples to be at least 4-10°C when received at the laboratory. For additional information regarding the limitations of themethods) referred to, please ca11 us at 661-395-0539.
JMM
JMM
JMM
JMM
JMM
JMM
JMM
ZALCO LABORATORIES, INC.
Analytical &Consulting Services
4309 Armour Avenuey Bakersfield, California 93308
(661) 395-0539FAX (661) 395-3069
Valley V1later Management Company Project: RWQCB Oilfield Ponds - 2Q2015 Work Order No.: 1505107
7500 Meany Avenue Project #: Reported: 06/12/2015
Bakersfield, CA 93308 Attention: Christine L. Zimmerman Received: 05/08/2015 7 3:45
Lab Sample Id: 1505107.01 Collected By: Justin Graves
Clfent Sample ID: C-Plant Fee 34 p-1 Date Collected: 5!8/2015 8:50:OOAM
Date Date
Analyte Results PQL Units Flag Method Prepared Analyzed Init.
Semivolatile Organic Compounds
Fluoranthene <10.0 10.0 ug/L SW846 8270C 5/14/95 5/2Q/15 JMM
Pyrene <10.0 10.0 uglL SW846 8270C 5/14/15 5/20/15 JMM
Benzo (a) anthracene <10.0 10.0 ug/L SW846 8270C 5114/15 5/20/15 JMM
Chrysene <10.0 10.0 ug/L SW846 8270C 5114!'15 5/20/15 JMM
Benzo (b) Auoranthene <10.0 10.0 ug/L SW846 8270C 5/14115 5/20/15 JMM
Benzo (k) fluoranthene <10A 10.0 ug/L SW846 8270C 5/14/'!5 5/20/15 JMM
Benzo (a} pyrene <i0.0 10.0 ug/L 5W846 8270C 5/14/75 5!20!75 JMM
Dibenz (a,h) anfhracene <10.0 10.0 ug/L SW846 8270C 5/14/15 5120175 JMM
Benzo {g,h,i) perylene <10.0 10.0 ug/L SW846 8270C 5114/15 5/20/15 JMM
Surragetes %Recovery Recovery Limits Flag
Nitrobenzene-d5
2-Fluorobipheny[
Terphenyl-dl4
Subcontracted Analyses
Gross Alpha <15.Q
Radium-226 <3.00
Radium-228 <2.00
Uranium (ug/L) <20.0
Volatile Organic Compounds
m, p-Xylene 278
benzene 798
Xylenes, total 417
Methyl tent-Butyl Ether <5.00
Ethylbenzene 213
Toluene 498
o-Xytene 138
41.3 U-95
3G.0 U-92
9.4) 0-1 UU
5/20! 15 14 28
S/?0!15 14:28
5/20115 14:28
95.0 pCi/L SM 7110C 5116115 5/19N5 MCS
3.00 pCVL E903.1 5/18!15 5/21/15 MCS
2.00 pCUL EPA Ra-05 5!28/15 5/30/15 MCS
20.0 pCi/L E908 5/27/15 5127/15 MCS
25.0 ug/L SW846 82608 5/20/15 5/20/15 HLP
250 ug/L SW846 82608 5120/15 512Q/75 HLP
ug1L SW846 82606 5!20/15 5!20/15 HLP
5.00 ug/L SW8A6 82606 5!20/15 5/20/15 HLP
25.0 ug/L SW846 82608 5120!15 5120/15 WLP
25.0 uglL SW84S 82608 5/20/15 5!20/15 HLP
25.0 uglL SW846 82608 5!20115 5/20!15 HLP
Surrogates %Recovery Recovery Limits Flag
1,2-Dichloroethane-d4 84,0• 89-165 S-GC 5/20!15 9;19
1'olucnc-dR 40.2 h5-124 5120']5 9:19
4-Bron~afluarobenzene 93.2 94-114 5/20!15 9:19
NSS: Non Suffictenf Sample H: Exceeds Analysis Hold Time 7TLC: To(ai Threshold Limit Concentration STLC: Soluble Threshold limit Concentration TCLP: 7o~ticity CharacteristicLeaching Procedure MCL: Maximum Contaminant Level `: 5ee Case NaRativeThe results in this report apply to the samples analyzed in accordance with the chain of custody document. This anelyiicat report must be reproduced in its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-6°C.Microbiological analysis requires samples to be at least 4-10°C when received at the laboratory. For additional information regarding the limitations of themethods) referred to, please call us at 661-395-0539.
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CHAIPU OF CUSTODY, ID#~i~~
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~ ZALC~ LABQRATORIES, 1NC.
4309 Armour Avenue, Bakersfield, C
A 93308 {661 } 3
95-0539 FAX (661) 395-3069
av~~+nv.zalcolabs.com2186 Eastman A
venue, Suite 143, Ventura, C
A 93003, (8057 477-0114, Fax (
805) 477-0125
+ ~~` ~~
ANAI_YS1S REQUESTED
Client PO:
Project ID:
Quote lD:
COMPANY
1Jalle Water Mana ement Com an
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Turnaround Time:
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State Form
Notes
CANTACT
Christine L. Zimmerman
PHONE
661-205-28$5 F.vc
ADDRESS 700 Mean Ave.
Bakersfield Ca. 9
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SAh1PLER (SIGNATU )
LAB#
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SAMPL
SCRIPTION
DATE
TIME
ll`PE'
1C-Plant Fee 3a P-1
5!8/20458.50
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12
XX
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Justin Graves
Zalco Laboratories Inc. 05/08/15
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'Sample Type Key:
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ar~angemants are made. Hazardous samples will b
e returned to client
LPG-Liquid Petroleum G
as; ~L-Oil; P
-Petroleum; S-Solid/Soil; ST-Storm water
or disposed of ai client's expense. WW-Wastewater
ZALCO LABORATORIES, INC.Anaiyticai &Consulting Services
4309 Armour AvenueBakersfield, California 93308
.tune 12, 2015
Christine L. ZimmermanValley Water Management Company7500 Meany AvenueBakersfield, CA 93308
(661) 395-0539FAX (661) 395-3069
TEL: (661 } 205-2885FAX: {667) 410-7500
Project ID:RE: 1505108
Dear Christine L. Zimmerman:
Zalco Laboratories, Inc. received 1 samples an 5/8/2095 for the analyses presented in the following report.
We appreciate your business and look forvvard to serving you in the future. Please feel free to call our once if youhave any questions regarding these test results.
Sincerely,
.._ _,
Juan MaganaProject ManagerCC:
NSS: tJon 5u~elent Sample H: Exceeds Analysis Hold Time TTLC: Total Threshold Limit Concentration ST~C: Soluble Threshold Limit Concentration TCLP: Toxicity CharectoristicLeaching Procedure MCL: Maximum Contaminant Level ': See Case NarrativeThe results in this report apply to the samples analyzed in accordance with the chain of custody document. This analytica3 report must be reproduced in its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-6°C.Microbiological analysis requires samples to be at least 4-10°C when received at the laboratory. For additional information regarding the limitations of themethods) referred to, please cal! us at 661-395-0539.
ZALCO LABORATORIES, INC.Analytical &Consulting Services
4309 Armour AvenueBakersfield, California 93308
(661) 395-0539FAX (661) 395-3069
Valley Water Management Company Project: RWQCB Oilfield Ponds - 2Q2015 Work Order No.: 15051087500 Meany Avenue Project #: Reported: 06/12/2015
Bakersfield, CA 93308 Attention: Christine L. Zimmerman Received; 05/08/2015 13:45
Lab Sample ID: 1505108-09 Collected By: Justin Graves
Client Sample ID: Edison C-Plant Fee 34 CP-1 Date Collected: 5/8/2015 9:0O;OOAM
Date date
Analyte Results PQL Units Flaq Method Prepared Analyzed Init.
Alkalinity
Total Alkalinity 350 10 mg/L SM 23208 518!15 518115 SAM
Bicarbonate (HCO3) 350 10 mg/L SM 23208 5/8/15 518/15 SAM
Carbonate (CO3) <10 10 mg/L SM 23208 5/8115 5/8/15 SAM
Hydroxide (OH) <10 10 mg/L SM 2320B 5/8/15 5/8/15 SAM
CAM, Toxicity (17 Metals) TTtC Limits
Antimony 10.20 0.20 500 mg/L SW846 60106 5/11/15 5/12/15 S5Arsenic <0.020 0.020 500 mg/L SW846 601~B 5/11/15 5/i2/15 SSBarium 0.37 0.10 10000 mg/L SW846 fi0708 5/11115 5112/15 SSBeryllium <0.010 0.010 75 mglL SW846 60108 5/11/15 5/12/15 SSCadmium <0.010 0.010 t00 mg/L SW84660108 5h 1/15 5/12!!5 SSChromium <0.050 0.050 2500 mg/L SW846 60108 5/11/15 5/12/15 SSCobalt <0.10 0.10 8000 mg/L SW846 6p10B 5/11/15 5112/15 SSCopper <0.050 0.050 2500 mglL SW846 60108 5/11/15 5/12/15 SSLead <0.050 4.050 1000 mglL SW846 60108 5/11/75 5/12/15 SSMercury <0.0020 0.0020 20 mg1L 5W846 7470A 5/12/15 5!12115 SSMolybdenum <0.10 0.10 3500 mg1L SW846 60108 5h 1!15 5/12/15 5SNickel <0.050 0.050 2000 mglL SW846 60108 5/11/35 5/12/15 SSSelenium <0.05 0.05 100 mg/L 5W846 60148 5/11/i5 5/12!15 SSSilver <0.020 0.020 500 mg/L SW846 60108 5/11/15 5/12/15 SSThallium ~U.50 0.50 700 mg/L SW846 60108 5/11/75 5/12/95 SSVanadium <0.10 0.10 2400 mg/L SW846 60108 5/11/15 5!12/15 SSZinc <0.050 0.050 5000 mg/L SW846 60'1flB 5!11/15 5/12/15 SS
General ChemistryMCL Limits
Fluaride <O.iO 0.10 2 mg/L EPA 300.0 5/8/15 5/8M5 MSSNitrate as N~3 <2,00 2.00 45 mg/L EPA 300.0 5/8/15 5/8/15 MSSElectrical Conductivity 4.4 0.010 mmhos/cm SM 25108 5/8/15 5/8/i5 SAMBromide 5.6 0,10 mg/L EPA 30Q.0 518/15 5/8/15 MSSChloride 1300 100 mg/L EPA 300.0 5/8/15 5/8/15 MSSpH 7.56 pH Units EPA 150.1 518115 5/8/15 SAMSulfate as SO4 9.7 0.50 mg/L EPA 300.0 5/8115 518115 MSSTotal Dissolved Solids 2400 1U mg/L SM 2540C 5/8/15 5/8115 SAM
Hardness
NSS: Non Sufticlent Sample H: Exceeds Analysis Hold Time TTLC: Total Threshold Limit Concentration STLC: Soluble Threshold Limit Concentration TGLP: Tpxicity CharacteristicLeaching Procedure MCL.: Maximum Contaminant Level "~ See Case NarrativeThe results in this report apply to the samples analyzed (n accordance with the chain of custody document. This analytical report must be reproduced in its entirety.
Note: Samples analysed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-6°C.Microbiological analysis requires samples to be at least 4-10°C when received at the laboratory. For additional information regarding the limitations of themethods) referred to, please call us at 661-395-0539.
ZALCO LABORATORIES, INC.Analytical &Consulting Services
4309 Armour AvenueBakersfield, California 93308
(661) 395-0539FAX (661 } 395-3069
Valley Water Management Company Project: RWQCB Oilfield Ponds - 2Q20i5 Work Order Na.: 1505108
7500 Meany Avenue Project #: Reported: 06/92/2015
Bakersfield, CA 93308 Attention: Christine L. Zimmerman Received: 05/08/2015 13:45
Lab Sample ID: 1505108-01 Collected By: Justin Graves
Client Sample ID: Edison C-Plant Fee 3Q CP-1 Date Collected: 5/8/2015 9:0O:OOAM
Date Date
Analyte Results Pt2L Units Flag Method Prepared Analyzed Init.
Hardness
Hardness (as CaCO3) 240 2.0 mg/L SM 23408 5/15115 5/15/15 SS
Metals
Lithium
Metals - As Received
Magnesium
Potassium
Sodium
Calcium
Iron
Boron
Barium
Copper
Silica (Si02}
Strontium
Manganese
Petroleum Hydrocarbons
0.33 0.10 mg/L EPA 200.7 5!15115 5/15/15 SS
10 0.050 mglL EPA 2b0.7 5115!15 5/15/15 SS
i 1 0.50 mg/L EPA 200.7 5115195 5/15/15 SS
780 70 mg/L EPA 200.7 5/15/15 5/15115 SS
79 0.050 mg(L EPA 200.7 5115/15 5/15/15 SS
<0.90 0.10 mg/l. EPA 200.7 5/15/15 5115/15 SS
13 0.10 mgJL EPA 200.7 5/75/15 5/15115 SS
0.43 0.10 mgJL EPA 200.7 5/15!15 5/15/15 SS
0.052 0.050 mglL EPA 200.7 5/15/15 5/15/15 SS
59 4.0 mglL EPA 2fl0.7 5!15!15 5115/15 SS
1.1 0.10 mg/L EPA 200.7 5!15/15 5/15/15 SS
0.092 0.030 mg/l EPA 200.7 5/15/15 5115!15 SS
Diesel Range Hydrocarbons 2.01 0.05 mg/L SW846 80158 5120!15 5/21/15 BIG
Gasoline Range 7.26 0.250 mglL SW846 80158 5/20/15 5/20/'!5 HLPHydrocarbonsMotor Oil Range 2.05 q.15 mg/L SW846 80158 5/20!15 5/21h5 BIGHydrocarbons
Surrogates % Recovery Recovery Limits Flag
a,a,a= I'ri tluorotoloene 11 I 69-125 5/20/ 1 5 1 S:US
Semivolatile Organic Compounds
Indeno(1,2,3-cd)pyrene <10.0 10.0 ug/L SW846 B270C 5114/35 5/2Q/'15
Naphthalene 37.7 10.0 ug/L SW848 82700 5/14!75 5/20h5
Acenaphthylene <10.0 10.0 uglL SW846 82700 5/14!15 5120/15
Acenaphthene <10.0 10.0 uglL SW846 82700 5/14!15 5/20115
Fluorene <10.0 10.0 ug/L SW846 82700 5114(15 5/20/15
Phenanthrene <10.0 70.0 ug/L SW84fi 82700 5/14!15 5/20N5
Anihracene <10.0 10.0 ug/L SW846 82700 5/14!15 5120115
NSS: Non Su~cient Sample H: Exceeds Analysis Hold Time TTLC: Total Threshold Limit Concentration STLC: Soluble Threshold Limit Concentration TCIP: Toxicity CharacteristicLeaching Procedure MCL: Maximum Contaminant Level ': 5ee Case Na~ativeThe rosults in this report apply to the samples analyzed in accordance with the chain of custody document. This analytical report must be reproduced in its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-fi°C.Microbiological analysis requires samples to be at least 4-10°C when received at the laboratory. For addi#tonal information regarding the limitations of themethods) referred to, please call us at 661-395-0539.
JMM
JMM
JMM
JMM
JMM
JMM
JMM
(661 } 395-0539FAX (661) 395-3069
Valley Water Management Company Projecf: RWQCB Oilfield Ponds - 2Q2015 Work Order No.: 1505108
7500 Meany Avenue Project #: Reported: ~6/i2/2015
Bakersfield, CA 93308 Attention: Christine L. Zimmerman Received: 05/08/2015 13:45
Lab Sample ID: 1505108-01 Collected By: Justin Graves
Client Sample 1D: Edison C-Plant Fee 34 CP-1 Date Collected: 5/8/2015 9:0O:O~AM
Date Date
Analyte Results PQL Units Flag Method Prepared Analxzed Init.
Semivolatile Organic Compounds
Fluoranthene <10.0 10,0 uglL SW846 8270C 5/14/15 5/20115 JMM
Pyrene <10.0 10.0 ug/L SW846 82700 5/14/15 5/20/15 JMM
Benno {a) anthracene <10.0 70.0 uglL SW846 82700 5114/15 5/20/15 JMM
Chrysene <10.0 10.0 uglL SW846 82700 5114/15 5/20/15 JMM
Benno (b) tluoranthene X10.0 10.0 uglL SW846 82700 5/14115 5/20/15 JMM
Benno (k) fluoranthene <i0.0 10.0 ug/L SW846 82700 5/14N5 5120115 JMM
Benno (a) pyrene <10.0 10.0 ug/L SW846 82700 5/74!15 5/20/15 JMM
Dibenz (a,h) anthracene <10.0 1Q.0 ug/L SW846 82700 5/14!15 5/20/15 JMM
Benno (g,h,i) perylene X10.0 10.0 ug/L 5W846 82700 5!14!15 5/24/15 JMM
Surrogates % Recorery Recovery Limits Plag
nitrobenzene-d5
Z-Fiuorobiphenyl
Terphenyl-dl4
Subcontracted Analyses
Gross Alpha <15.0
Radium-226 <3.Q0
Radium-226 <2.00
Uranium (ug/L} <20.0
Volatile Organic Compounds
m,p-Xylene 759
Qenzene 2410
Xylenes, total 1114
Methyl tert-Butyl Ether <5.00
Ethyibenzene 64.2
Toluene 2210
o-Xylene 354
39.8 U-95
30.7 0-)2
12.1 0-IQO
5/20/15 14:28
5/2U/1 S 14:28
5/2U/ 15 14:28
15.0 pCUL SM 71100 5/26115 5127/15 MCS
3.00 pCUL E9Q3.1 5/18/15 5122!15 MCS
2.00 pCi/L EPA Ra-05 5/28/15 5/30195 MC5
20.0 pCi/L E908 5/29/15 5!29!15 MCS
25.0 uglL SW846 82608 5120/15 5/24!15 HLP
250 uglL SW84fi 82606 5!20/95 5/20/15 HLP
uglL SW846 82608 5/20/75 5/20115 HLP
5.00 uglL SW846 82608 5/20/15 5/20115 HLP
5.00 ug/L SW846 82808 5/20/15 5/20/15 HLP
254 ug/L SW846 82608 5/20/15 5120!15 HLP
25.0 ug/L SW846 82608 5/20/15 5/20/15 HLP
Surrogates °/a Recovery Reco►~erp L(mits Flag
1,2-Dichlorocthane-d4 93.3 89-165 5/2AlIS' 9:19
Toluene-dR 98.R h5-124 5/20115 9:19
4-Bromolluorobcnzcne 89.4' 94-114 S-GC 5/20115 9:19
NSS: Non Sufficient Sample H: Exceeds Analysis Hald Time 77LC: Total Threshold Lfmit Concentration STLC: SolublQ Threshold Umit Concentration TCLP: Toxicity CharacteristicLeaching Procedure MCL: Maximum Contaminant Level ': See Case NartativeThe rosults in this report apply to the samples analyzed In accordance with the chain of custody document. This analytical report must be reproduced in its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0.6°C.
Microbiological analysis requires samples to be at least 4-10°C when received at the laboratory. For additional information regarding the Umitations of the
meihod(s) referred to, please call us at 661-395-0539.
June 1, 2015 Lab ID : SP 1505247-001Customer ID : 2-249
Zalco Laboratories, Inc.4309 Armour AvenueBakersfield, CA 93308-4573
Description :1505108-01Project :1505108
Sampled OnSampled ByReceived OnMatrix
Sample Result -Radio
May 8, 2015-09:0Not AvailableMay 12, 2015-11:30Water
Constituent Result t Error MDA Units MCL/ALSample Preparation
Method Date/ID
Sample Analysis
Method Date/ID
Radio Chemistry
ross Alpha 5.44 f 5.34 7.l 1 15/5 900.0 os~z~ns•os:oo 9000 05/27/15-10:00pCi/L C ] 50604b 2A 1507943
otal Alpha Radium1.21 t 4.436 0.470 p Ci/I, 3 9~3.o OS/18/15-19:30 4a3 ~ osnzris-o~:ao
226) z~~~sos~~~ ZAiso~boo
ranium ~.fl~~ f fl.t~~9 Q.3~~p Cl/j, 2Q gpg.~ 05/29/15-06:15
90A.0 US/29/15-17:312P150622d 2A1508054
a 228 0.423 f 1.32 0.506 p Ci/L 2 Ra - os o$~8~~ 5-19:30 ~a - os a5/30/15-~ 3:002P1505775 2A1508030
--ND=Non-Detected. PQL=Practical Quantitation Limit. Containers: (J') Plastic Preservatives: N/A * PQL adjusted for dilution.
MDA =Minimum Detec~atrle Activity (Calculated at the 95%confidence level) =Data utitized by DHS to detern~ine matrix interference.MCL / AL =Maximum Contamination Level /Action Level. Alpha's Action Level of S pCi/Lis based on the Assigned Value (AV).AV =Assigned Value{Gross Alpha Result + (0.8d x Crrvrj). CCR Section 64442: Drinking Water Compliance Note: Do the followingIf Gross Alpha's (AY) exceeds 5 pCilL run Uranium. If Gross Alpha's (AV} minus Uranium exceeds 5 pCi/L run Radium 226.
Drinking Water Compliance:Gross Alpha (AV) minus Uranium is less than or equal to 15 pCi1I.Uranium is less than or equal to 20 pCi/LRadium 226 +Radium 228 is less than or equal to 5 pCi/L
Note: Samples are held for 3-6 months prior to disposal.
Corporate Offices 8. Laboratory Office & i.aboratory Office 8~ Laboratory563 E. Lindo Avenue 3442 Empress Drive, Suite QChico, CA 95926 San Luis Obispo, CA 93401TEL: (530)343-5818 TEL: (805)783-2940FAX: (530)343-3807 FAX: (805)783-2912CA FLAP Certification No. 2670 CA ELAP Certification No. 2775
ONice &Laboratory853 Corporation Street 250D Stagecoach RoadSanta Paula, CA 93060 Stockton. CA 952 i 5TEL' (805)392-2004 TEL: (209)942-0182Env FAX: (803)525-4172 / Ag FAX: {805)392-2063 FAX: (209)942-0423CA EL.AP Certification No. 1573 CA ELAP Certification No. 1563
Page 3 of 4
Office 8 laboratory9415 W. Goshen Avenue~lsalia, CA 93291TEL: (559)734-9473FAX:(55~J)734-8435CA FLAP Certification No. 2810
=~:t:"- °W
CHAiN OF CUSTODY, ID#~
ZALCO LABORATORIES, INC.
4309 Armour Avenue, Bakersfield. C
A 93308 (661) 395-0539 FAX (661) 395-3069
v~~nnvzalcoiabs.:,~m2186 Eastman Avenue, Suite 103, Ventura, C
A 93003, {805) 477-0114, Fax (
SOS) 477-0125
ANALYSIS REQUESTED ~ L,J~.J
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Project ID:
Quote iD:
COMPANY
Valle Water Mana ement Com an
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COMMENTS
Turnaround Time:
Routine {# working days)
Rush Sy
Working Days
EDT
State Form
Notes
CONTACT
Christine L. Zimmerman
PHONE
667-205-28$5 F~vc
AooR~ss 7500 Mean Ave.
~
Bakersfield Ca. 9
e -Mai czimmerma
at o
SAMPLER (SIGNATURE)
~.
LAB #
SAMPL 9ESCR TION
DATE
TIME
TYPE '
1Edison C
-Plant Fee 34 CP-1
5/8!20159:00
AQ
~2
XX
XX
XX
~,~:.~~:
. .
~ f.,
:".
'
't:
Justin Graves
Zalco Laboratories (nc. 05/08115
N V I t
. Samples Discarded 3
0 days after results unless other
arrangements are made. Hazardous s
amples will b
e returned to client
or disposed of at ctienYs expense.
Sample Type Key:
Aq-Aqueous; BS-Biosolid; DW-Drinfcing Water, G
W-Groundwater, G-Gas
lPG-liquid Petroleum Gas; OL-Oil; P
-Petroleum; S-So1idlSoil; ST-Storm water
WW-Wastewater
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June 12, 2015
ZALCO LABORATORIES, INC,Analytical &Consulting Services
4309 Armour AvenueBakersfield, California 93308
Christine L. ZimmermanValley Water Management Company7500 Meany AvenueBakersfield, CA 93308
(661 J 395-0539FAX {661) 395-3069
TEL: (661) 205-2885FAX: (661) 410-7500
Project ID:RE: 1505109
Dear Christine L. Zimmerman:
Zalco Laboratories, Inc. received 1 samples on 5/8/2015 for the analyses presented in the following report.
We appreciate your business and look forward to serving you in the future. Please feel free to call our once if youhave any questions regarding these test results.
Sincerely,
~_._._.
Juan MaganaProject ManagerCC:
NSS: Non Su~cient Sample H: Exceeds Analysis Hold Time TTLC: Total Threshold ~(mlt Concentration STLC: Soluble Threshold Limit Concentration TCLP: Toxicity Characteristicleaching Procedure MCL: Maximum Contaminant level ': See Case NarrativeThe results in this report apply to the samples analyzed In accordance wish the chain of custody document. This analytical report must be reproduced In its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-6°C.Microbiological analysis requires samples to be at least A-10°C when received at the laboratory. For additional information regarding the limitations of themethods) referred to, please call us at 661-395-0539.
ZALCO LABORATORIES, INC.Analytical &Consulting Services
4309 Armour AvenueBakersfield, California 93308
(661) 395-0539FAX (661) 395-3069
Valley Water Management Company Project; RWQCB Oilfield Ponds - 2Q2015 Work Order No.: 75051097500 Meany Avenue Project #: Reported: 06/12/2015
Bakersfield, CA 93308 Attention: Christine L. Zimmerman Received: 05/08/2015 13:45
Lab Sample ID: 1505109-01 Collected By: Justin Graves
Client Sample ID: Edison Reacetrack Hill P-1 Date Collected: 5/8/2015 9:40:OOAM
Date Date
Analyte Results PQL Units Flaa Method Prepared Analyzed tnit.
Alkalinity
Total Alkalinity 350 90 mg/L SM 23208 518/15 5/8/15 SAMBicarbonate (HCO3) 350 10 mg/L SM 23208 5/8/15 5/8/15 SAMCarbonate (CQ3} <10 10 mglt SM 23206 518/15 5!8!15 SAMHydroxide (OH) <10 10 mglL SM 23208 5/8/15 518115 SAM
CAM, Toxicity (17 Metals) TTLC Limits
Antimony <0.20 0.20 500 mglL SW846 60108 5111!15 5N 2/15 SSArsenic <0.020 0.020 500 mglL SW846 60108 5/11h5 5/12/15 SSBarium O.QO 0.10 90000 mg1L SW846 60908 5/11/15 5/12/15 SSBeryllium <0.010 0,010 75 mg1L 5W846 64108 5/11/15 5/12/15 SSCadmium <0.010 0.010 'JDD mg/L SW846 60108 5/1 i/15 5/12/15 SSChromium <0.050 0.050 2500 ~ mg/L SW8d6 60108 5111/15 5112115 SSCobalt <0.10 O.iO 8000 mg/L SW846 6010B 5/11/15 5112115 SSCopper <0.050 0.050 2500 mg/L SW846 60108 5!11/15 5/12/15 SSLead <0.050 0.450 1000 mg/L SW846 60108 5/11/15 5112/15 SSMercury <0.0020 0.0020 20 mg/L SW846 7470A 5/12/15 5112!15 SSMolybdenum <0.10 0.10 3500 mg/L SW846 60706 5/11!15 5/12/15 SSNickel <0.050 0.050 2000 mglL SW846 60108 5/11/15 5112115 SSSelenium <0.~5 0.05 100 mg1L SW846 60108 5/1 i/15 5112/15 SSSilver <0.020 0.020 500 mgll SW846 60106 5111/15 5112!15 SSThallium <0.50 0.50 700 mg/L SW846 60106 5/11/15 5112/15 SSVanadium <0.1Q 0.10 2400 mg/L SW846 60106 5!11/15 Sf12/15 SSZinc <0.050 0.050 5000 mg/l. SW846 60i0B 5/11/15 5112/15 SS
General ChemistryMCL Limits
Fluoride <0.10 0.10 2 mg/L EPA 300.0 518!15 516/15 MSSNitrate as NO3 <2.00 2.00 45 mg/L EPA 300.0 5/8/15 5/8/15 MSSElectrical Conductivity 4.3 0.010 mmhos/cm SM 25108 518/15 5/8115 SAMBromide 5.6 0.10 mg/L EPA 300.0 5!8/15 5/8/15 MSSChloride 1300 100 mg1L EPA 300.0 5!8115 5/8115 MSSpH 7.98 pH Units EPA 150.1 5!8/15 5/8/15 SAMSulfate as SO4 9.9 0.50 mg/L EPA 300.0 5/8/15 5/8115 MSSTotal Dissolved Solids 2400 10 mg/L SM 2540C 5/8/15 5/8/15 SAM
Hardness
NSS: Non SuKciont Sample H: Exceeds Analysis Hold Time TTLC: Total Threshold Limit Concentration STLC: Soluble Threshold Lim(t Concentration TCLP: Toxicity Characteristicleaching Procedure MCL: Maximum Contaminant Level ': See Case NarralNeThe results in ihls report apply to the samples analyzed in accordance with the chain of custody document. This analytical report must be reproduced in its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-6°C.Microbiological analysis requires samples to be at least 4-10°C when received at the laboratory. For additional information regarding the limitations of themethods} referred !o, please call us at 661-395-0539.
ZALCO LABORATORIES, INC.' Analytical &Consulting Services
4309 Armour Avenue>: Bakersfield, California 93308~.
(661) 395-0539FAX (661) 395-3069
Valley Water Management Company Project: RWQCB Oilfield Ponds - 2Q2015 Work Order No.: 1505109
7500 Mea~y Avenue Project #: Reported: 06/12/2015
Bakersfield, CA 93348 Attention: Christine L. Zimmerman Received: 05!08/2015 13:45
Lab Sample ID: 15051U9-01 Collected By: Justin Graves
Client Sample 1D: Edison Reacetrack Hill P-1 Date Collected: 5/8/2015 9:40:OOAM
Date Date
Anaiyte Results PAL Units Flag Method Prepared Analyzed Init.
Hardness
Hardness (as CaCO3) 220 2.0 mg/L SM 23408 5/15/15 5!15/15 SS
Metals
Lithium
Metals - As Received
Magnesium
Potassium
Sodium
Calcium
Iron
Boron
Barium
Gopper
Silica (Si02)
Strontium
Manganese
0.30 0.10 mg/L EPA 200.7 5/15/15 5/15/15 SS
11 0.050 mg/L EPA 200.7 5!15/15 5/15/15 SS
10 0.50 mg/L EPA 200.7 5/15/15 5/15/15 SS
780 70 mg1L EPA 200.7 5/15/15 5/15/15 SS
69 0.050 mg/L EPA 200.7 5/15/15 5/15/15 SS
0.17 O.iO mg/L EPA 200.7 5!15!15 5!15115 SS
12 0.10 mg/L EPA 200.7 5!15!15 5/15/15 SS
0.47 0.10 mg/L EPA 200.7 5!15(15 5115115 SS
0.052 0.050 mg/L EPA 200.7 5/15/15 5/15/95 SS
62 4.0 mglL EPA 200.7 5/15/15 5/15/15 5S
1.1 0.10 mg/L EPA 200.7 5/15/15 5/'15115 SS
0.038 0.030 mglL EPA 200.7 5115!15 5h 5/15 SS
Petroleum Hydrocarbons
Diesel Range Hydrocarbons 2.14 0.05 mg/L SW848 80156 5/20/15 5/21/15 BIG
Gasoline Range 0.244 0.050 mg/L SW646 80156 5120115 5/20/15 HLPHydrocarbonsMotor Oi! Range 2.34 0.15 mg/L SW846 80156 5!20/15 5/21/15 BIGHydrocarbons
Surrogates % Recof'cry Recovery Limits Flag
~i,a,a-Tritluorotoluene 88.G G9-f25 5/20115 IS:US
Semivolatile Organic Compounds
Indeno('f,2,3-cd)pyrene <10.0 10.0 uglL SW846 8270C 5/14h5 5/20N5
Naphthalene <10.0 10.0 ug/L SW846 8270C 5/14!15 5/20!15
Acenaphthylene <10.0 10.0 ug/L SW846 8270C 5/14/15 5/20!15
Acenaphthene <10.0 10.0 ug/L SW846 8270C 5/14/15 5/20!15
Fluorene <10.0 10.0 ug/L SW846 8270C 5/14N 5 5/20/15
Phenanthrene <10.0 10.0 ug/L SW846 8270C 5114/15 5/20N5
Anthracene <10.0 10.0 ug/L SW846 8270C 5!14!15 5/20/15
NSS; Npn Sufficient Sample H: C-xceeds Analysis Hold Time 7TLC: Total Threshold Lfmft Concentration STLC: Soluble Threshold Limil Concentration TCLP: Toxfclty CharacteristicLeaching Procedure MCL: Maximum Contaminant Level ': See Case NarrativeTho results in this report apply to the samples analyzed in accordance with the chain of custody document. This analytical report must be reproduced !n its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-6°C.Microbiological analysis requires samples to be at least Q-10°C when received of the laboratory. For additional information regarding the limitations of themethod{s) referred to, please call us at 661-395-0539.
JMM
JMM
JMM
JMM
JMM
JMM
JMM
ZALCO LABORATORIES, INC.Analytical &Consulting Services
4309 Armour AvenueBakersfield, California 93308
(661) 395-0539FAX (661) 395-3069
Valley Water Management Company Project: RWQCB Oilfield Ponds - 2Q2015 Work Order No.: 15051097500 Meany Avenue Project #: Reported: 06/12/2015
Bakersfield, CA 93308 At#ention: Christine L. Zimmerman Received: 05/08/2015 13:45
Lab Sample (D: 1505109-07 Collected By: Justin Graves
Client Sample ID: Edison Reace#rack Hill P-1 Date Collected: 5/8/2015 9:40:OOAM
Analyte Results PCli. Units Flag Method
Date
Pregared
Date
Analyzed Init.
Semivolatile Organic Compounds
Fluoranthene <10.0 10.0 uglL SW846 8270C 5114/15 5/20/15 JMMPyrene <10.0 10.0 ug/L SW846 8270C 5114/95 5/20!15 JMMBenzo (a) anthracene <10.0 10.0 ug/L SW846 8270C 5/14/75 5/20/15 JMMChrysene <10.0 10.0 ug/L SW846 8270C 5/14/'15 5/20!15 JMMBenzo (bj Iluoranthene X10.0 10.0 ug/i. SW846 8270C 5/14!15 5120/15 JMMBenzo (k) fluoranthene <10.0 10.0 uglL SW846 827QC 5/14/15 5/20/15 JMMBenzo {a) pyrene <10.0 10.0 ug1L SW846 8270C 5/14/15 5120/75 JMMDibenz (a,h) anihracene <10.0 10.0 ug/L 5W84S 8270C 5114/15 5/20/15 JMMBenzo (g,h,i) perylene <10.0 10.0 ug/L SW846 8270C 5/14/15 5/20/15 JMM
Surrogates %Recovery Recovery Limits ~~ag
T~'itrobenzene-d5
2-Fluorobiphenyl
7erpficnyl-d!4
Subcontracted Analyses
Gross Alpha <15.0
Radium-226 X3.00
Radium-228 <2.00
Uranium (ug/L) X20.0
Volatile Organic Compounds
m,p-Xylene 10.0
Benzene 42.3
Xylenes, total 37.5
Methyl tert-Butyl Ether <5.00
Ethylbenzene <5.00
Toluene 17.0
o-Xylene 21.5
34.0 0-95 5120lI S 142834.2 0-H2 5/2U/IS 14289.95 D-IUU SI20!15 14:28
15.0 pCi/L SM 7110C 5(26115 5!27/15 MCS
3.00 pCilL E903.1 5/18/15 5/22(15 MCS2.00 pCi/L EPA Ra-05 5128/15 5/30/15 MCS20.0 pCi1L E908 5!29/75 5/29/15 MCS
5.00 uglL SW846 82608 5/20/15 5120115 NLP
5.00 ug/L SW846 82608 5/20/15 5/20/15 HLP
ug/L SW846 82608 5120/15 5!20115 HLP
5.00 ug/l SW846 82608 5/20/15 5120/15 HLP
5.00 ug/L SW846 82606 5/20115 5120(15 HLP
5.00 ug/L SW846 826Q6 5/20/15 5!20/15 HLP
5.00 ug/l. SW846 82608 5(20/15 5/20/15 HLPSurrogates % Reca~~ery Recovery Limits Flag
1,2-Dichlorocthanc-d4 91.8 R9-1b5 5/20/15 9:19Toluene-dR 84.8 65-124 5/20/15 9:194-Arumofluorobenyene 97.4 9A-114 5120/15 9:19
NSS: Non Su~cfent Sample H: fxcoeds Analysts Hold Time 17LC: Total Threshold Limit Concentration STLC: Soluble Threshold Limit Concentration 7CLP: Toxicity Characteristicleaching Procedure MCL: Maximum Contaminant Level ': See Case NarrativeThe results in this report apply to the samples analyzed In accordance with the chain of custody document. This analytical report must be reproduced in Its entirety.
Note: Samples analyzed for regulatory purposes should be put on ice immediately after sampling and received by the laboratory at temperatures between 0-6°C.Microbiological analysis requires samples to be at least 4-10°C when received at the laboratory. For additional information regarding the limitations of themethods) reierced to, please call us at 661-395-0539.
r~k
~:° -; ~. CHAIN OF CUSTODY, 1D#
ZALC~ LABORATORIES, INC.
4309 Armour Avenue, Bakersfield, C
A 93308 (661) 395-0539 FAX (661) 395-3069
vr~r~~.zaicolabs.cor~n~ 2186 Eastman Avenue, Suite 1
03, Ventura, C
A 93003, {805) 477-0114, Fax {
$OS) 477-0125
ANALYSIS REQUESTED ``~~jl~
Client PO:
Project ID:
Quote ID:
GOMPhNY
Valf~ Water liana
ement Com an
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COMMENTS
Turnaround lime:
Routine (# working days)
Rush By
Working Days
EDT
State Form
Notes
coNracr Christine L. Z
immerman
PHONE
667-205-2885
Fw~
~oRess 750Q Mean Ave.
~Bakersfield C
a. 9
;
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SAMPLER (SIGtJATUR
LAB #
,
SAMPLE DESCRIPTfON
DATE
TIIIAETYPE'
1Edison Racetrack Hill P
-'f5/$/2015
9:40
AQ
12
XX
XX
XX
.i
s~
'.....~
Justin Graves
Falco Laboratories Inc.05108!'(5
` L'
G./
NOTE: Samples Discarded 3
n days after results unless other
arrangements are made. Hazardous samples wi11 be returned to client
Sample Type iCey:
Aq-Aqueous; BS-Biosolid; DW-Drinking Water; GWGroundwater; G-Gas
LPG-Liquid Petroleum G
as; OL-Oil; P
-Petroleum; S-Sa1idlSoil; ST-Storm water
or disposed of at client`s expense. WW-Wastewater
June 1, 201 S Lab ID : SP 150524$-001Customer ID : 2-249
Zalco Laboratories, Inc.4309 Armour AvenueBakersfield, CA 93308-4573
Description :1505109-01Project :1505109
Sampled OnSampled ByReceived 4nMatrix
Samplc Result -Radio
May 8, 2015-09:40Not AvailableMay 12, 2015-11:30Water
Constituent Result f Error MDA Units MCL/ALSample Preparation
Method Date/ID
Sample Analysis
Method Date/YD
Radio Chemistry
ross Alpha $.77 f 5.~2 7.2$ ~ S~5 O9n0.0 ~ 9~~ ~ ~p~l~. 2P1506046 2A 507901U~
otal Alpha Radium ~ ,91 ~ 0.529 0.470 P Ci/L 3 903.E US/18/15-19:30 9p3 ~ osn2ris-os:uo226 2r~sos~~~ 2Ai~o~bno
ranium 0.000 f 0.449 0.300 p Ci/L 20 90R.0 osizvi~s•ob:is21' 1506220
908.0 osr~yi~s-»:sb2A I SOR054
a 22g 0.000 t 1.04 ~.4~d p Cl~l, 2 Ra-OS OS/2$/15-19:302P1505775 Ra-OS ~5/30/IS-12:40
2A1S08029
ND=Non-Detected. PQL=Practical Quantization Limit. Containers: (P) Plastic Preservatives: N/A * PQL adjusted for dilution.
MDA =Minimum Detectable Activity (Calculated at the 95%confidence level) =Data utilized by DHS to determine matrix interference.MCI, / AL =Maximum Contamination Level / Aclion Level. Alpha's Action Level of S pCi/I. is based on the Assigned Value {AV).
AV =Assigned Value(Gross Alpha Result + (4.84 x Crror)). CCR Section 64442: Drinking Water Compliance Note: Do the followingtf Gross Alpha's (AVj exceeds 5 pCi/L run Uranium. If Gross Alpha's (AV) minus Uranium exceeds 5 pCi/L run Radium 226.
Drinking Water Compliance:Gross nlpha (AV} minus Uranium is less than or equal to 15 pCi/LUranium is less than or equal to 20 pCi/LRadium 226 +Radium 228 is Less than or equal to 5 pCi/1,
Note: Samples are held for 3-6 months prior to disposal.
Corporate ONices 8, Laboratory Office &Laboratory Of(Ice 8 Laboratory563 E. Lindo Avenue 3442 Empress Drive, Suite DChico, CA 95926 San Luis Obispo, CA 93407TEL: (530)343-5818 TEI: (805)783-2940FAX: (530)343-3807 FAX: (805)783-2912CA ELAP Certification No. 2fi70 CA ELAP Certification No. 2775
Office &Laboratory853 Corporation Street 2500 Stagecoach RoadSanta Paula, CA 93060 Stockton. CA 95215TEL' (805)392-2000 TEI: (209)942-0182Env FAX: (805)525-4172lAg FAX: (805)392-2063 FAX: {209)942-0423CA Fl AP Certification No. 1573 CA FLAP Certification No. 1563
Page 3 of 4
Office &Laboratory9415 W. Goshen AvenueVisalia, CA 93291TEL: (559)734-9473FAX: (55~J)734-8435CA FLAP Certification No. 2810
-~ ~ ~ ~ ~~
CHAIN 4F CUSTODY, ID#~~~~
., ..t:,.--_ ZALC~ LABORATORIES, fNC.
4309 Armour Avenue, Sakersfielci, C
A 93308 {661) 3
95-Q539 FAX (661) 395-3069
~,nr,r~r.za~cofabs.com~,
2186 Eastman Avenue, Suite 103, Ventura, C
A 930D3, X805) 477-0114, Fax (
805) 477-0125
ANAL YSfS REQUESTED
I ~~I ~%1
Client PO:
Project ID:
Quote ID:
coMpar~r Vatle
Water N9ana
ement Com an
~#
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COMMENTS
Turnaround Time:
Routine (#warkin days)
Rush By
Working Days
EDT
State Form
EMAf L
Notes
cavTACT Ci~ristine L
Zimmerman
PHpNE
661-205-28$5 F~vc
~a~Ess 7500 Mean Ave_
Bakersfield Ca. 9
~ j
czimcnerm at
r
5AFAPLER (SIGNATUR
lAB #
SAMPLE DESCRIPTfON
DATE
TIME
TYPE'
1Edison Racetrack Hill P-1
5l8/20~59:40
AQ
~2
XX
XX
XX
~,
l~.
i ~
f i
~__j:..i
(../
Justin Graves
Zalco Laboratories Inc. 05/08!15
~ L'
tV V I t
: Samples Dfscanied 3
4 days after results unless other
`Sample Type Key:
Aq-Aqueous; BS-Biosolid; D
W-Drinking Water; G
W-Groundwater; G-Gas
arrangements are made. Hazardous samples will b
e returned to client
LPG-Liquid Petroleum G
as; Ql-Dil; P-PetroEeum; S-SalidJSoil; 5
T-Storm water
or disposed of at client's expense. WW-Wastewater