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Prepared by: AECOM 105 Commerce Valley Drive West, Floor 7 905 886 7022 tel Markham, ON, Canada L3T 7W3 905 886 9494 fax www.aecom.com Project Number: 60267668 Date: May 13, 2015 Vale Limited / Glencore Limited Annual SO 2 Report Submission SO 2 Monitoring Network for Sudbury January to December 2014

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Page 1: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

Prepared by:AECOM105 Commerce Valley Drive West, Floor 7 905 886 7022 telMarkham, ON, Canada L3T 7W3 905 886 9494 faxwww.aecom.com

Project Number:60267668

Date:May 13, 2015

Vale Limited / Glencore Limited

Annual SO2 Report SubmissionSO2 Monitoring Network for SudburyJanuary to December 2014

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AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission

Rpt 2014 Annual So2 Report.Final

Statement of Qualifications and Limitations

The attached Report (the “Report”) has been prepared by AECOM Canada Ltd. (“Consultant”) for the benefit of the client(“Client”) in accordance with the agreement between Consultant and Client, including the scope of work detailed therein (the“Agreement”).

The information, data, recommendations and conclusions contained in the Report (collectively, the “Information”):

· is subject to the scope, schedule, and other constraints and limitations in the Agreement and the qualificationscontained in the Report (the “Limitations”)

· represents Consultant’s professional judgement in light of the Limitations and industry standards for the preparationof similar reports

· may be based on information provided to Consultant which has not been independently verified· has not been updated since the date of issuance of the Report and its accuracy is limited to the time period and

circumstances in which it was collected, processed, made or issued· must be read as a whole and sections thereof should not be read out of such context· was prepared for the specific purposes described in the Report and the Agreement· in the case of subsurface, environmental or geotechnical conditions, may be based on limited testing and on the

assumption that such conditions are uniform and not variable either geographically or over time

Consultant shall be entitled to rely upon the accuracy and completeness of information that was provided to it and has no obligationto update such information. Consultant accepts no responsibility for any events or circumstances that may have occurred since thedate on which the Report was prepared and, in the case of subsurface, environmental or geotechnical conditions, is not responsiblefor any variability in such conditions, geographically or over time.

Consultant agrees that the Report represents its professional judgement as described above and that the Information has beenprepared for the specific purpose and use described in the Report and the Agreement, but Consultant makes no otherrepresentations, or any guarantees or warranties whatsoever, whether express or implied, with respect to the Report, theInformation or any part thereof.

The Report is to be treated as confidential and may not be used or relied upon by third parties, except:

· as agreed in writing by Consultant and Client· as required by law· for use by governmental reviewing agencies

Consultant accepts no responsibility, and denies any liability whatsoever, to parties other than Client who may obtain access tothe Report or the Information for any injury, loss or damage suffered by such parties arising from their use of, reliance upon, ordecisions or actions based on the Report or any of the Information (“improper use of the Report”), except to the extent thoseparties have obtained the prior written consent of Consultant to use and rely upon the Report and the Information. Any damagesarising from improper use of the Report or parts thereof shall be borne by the party making such use.

This Statement of Qualifications and Limitations is attached to and forms part of the Report and any use of the Report is subjectto the terms hereof.

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AECOM105 Commerce Valley Drive West, Floor 7 905 886 7022 telMarkham, ON, Canada L3T 7W3 905 886 9494 faxwww.aecom.com

Rpt 2014 Annual So2 Report.Final

May 13, 2015

Ministry of the Environment and Climate ChangeSudbury District Office199 Larch St., Suite 1201Sudbury, OntarioP3E 5P9

Dear District Manager:

Project No: 60267668Regarding: Annual SO2 Report Submission

SO2 Monitoring Network for Sudbury – January to December 2014

Enclosed is the Annual SO2 Report Submission for the Sudbury SO2 Monitoring Network. On behalf of Vale andGlencore, AECOM prepared the attached annual report that includes presentation of monitoring data from Januaryto December 2014.

Please do not hesitate to contact me at (905) 390-2026, or by E-mail at [email protected] if you haveany questions or require further information.

Sincerely,AECOM Canada Ltd.

Danielle Arsenault, P. Eng.Environmental Engineer

cc: Celeste Dugas Mary Dubel Chad Pearson Marc GasconAir Quality Analyst Vale Limited Superintendent of Environment Manager, Product SupportMinistry of the Environment and Climate Change (Technical Services) Glencore Bestech199 Larch Street, Suite 1201 337 Power Street Sudbury Integrated Nickel Operations 1040 Lorne Street, Unit 3Sudbury, ON Copper Cliff, ON Falconbridge, ON Sudbury, ONP3E 5P9 P0M 1N0 P0M 1S0 P3C 4R9

Chris Ransom Andrew W. Taylor Environmental Coordinator Senior Environmental Analyst Glencore Vale Limited Sudbury Integrated Nickel Operations 337 Power Street Falconbridge, ON Copper Cliff, ON P0M 1S0 P0M 1H0

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AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission

Rpt 2014 Annual So2 Report.Final

Distribution List

# of Hard Copies PDF Required Association / Company Name

1 Yes Ministry of Environment and Climate Change

1 Yes Vale

Yes Glencore

Yes Bestech

Revision Log

Revision # Revised By Date Issue / Revision Description

0 Halim Abdihalim April 14, 2015 Original

1 Halim Abdihalim May 08, 2015 Final

AECOM Signatures

Report Prepared By:Halim Abdihalim, E.I.T.Air Quality Compliance Specialist

Report Reviewed By:Danielle Arsenault, P. Eng.Environmental Engineer

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Rpt 2014 Annual So2 Report.Final i

Executive SummaryBestech was retained by Vale and Glencore to operate and maintain eighteen (18) SO2 monitoring stations in the Sudbury area.AECOM Canada Ltd. (AECOM) was retained by Bestech to perform data analysis and reporting on their behalf. Regular qualityassurance checks, data analysis and monthly, quarterly and annual reporting to the Ministry of the Environment and ClimateChange (MOECC) are key components of this assignment.

This annual report presents an overview of the SO2 concentrations observed at each of the monitoring stations and themeteorological conditions observed at STN77025 and STN1Glencore for a one (1) year period from January 1st to December 31st,2014. This report also includes an overview of the monitoring equipment inventory, site visits, audits and valid data collectionperformance parameters. These components provide a summary of the operational aspects of the monitoring network.

This report includes statistical analysis of the measured SO2 data for the eighteen (18) monitoring stations and meteorologicaldata for two (2) met stations equipped with meteorological instrumentation.

Bestech performs all field related activities, station maintenance and calibration, raw data retrieval, editing and storage. AECOMperforms the necessary data quality assurance, statistical analysis and reporting functions.

A summary of the monitoring stations and the annual arithmetic mean SO2 concentrations from January 1st to December 31st,2014 is presented in Table 1.

Table 1. Annual Arithmetic Mean SO2 Concentrations for January to December 2014

Station Measurements Annual Arithmetic Mean SO2Concentration (ppb)

STN77012 (Skead) SO2 2.4STN77013 (Hanmer) SO2 1.1

STN77028 (Coniston) SO2 1.8STN77065 (Garson) SO2 2.1

STN77075 (New Sudbury) SO2 2.0STN77203 (Science North) SO2 1.7

STN77206 (Rayside) SO2 0.8STN77218 (Copper Cliff) SO2 1.9STN77225 (Kelly Lake) SO2 1.4STN77227 (Kinsmen) SO2 0.9

STN77228 (Dozzi Park) SO2 1.7STN77230 (Spruce Street) SO2 3.3

STN77231 (Algonquin) SO2 1.4STN77330 (Union) SO2 2.6STN77600 (Edison) SO2 2.6

STN77601 (Parkinson) SO2 3.1STN77602 (Sunderland) SO2 2.3STN77603 (Wahnapitae) SO2 1.2

Notes: Annual AAQC for SO2 = 20 ppb

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Rpt 2014 Annual So2 Report.Final ii

All SO2 monitoring stations met the minimum performance criterion of 90% valid data availability as shown Table 2. The annualvalid data collection for the eighteen (18) monitoring stations was based on 8,760 hours.

Table 2. Summary of SO2 Annual Valid Data Collection for 2014

Station Annual Valid Data Collection (%)

STN77012 (Skead) 99.6%STN77013 (Hanmer) 99.7%

STN77028 (Coniston) 99.7%STN77065 (Garson) 99.7%

STN77075 (New Sudbury) 99.4%STN77203 (Science North) 99.6%

STN77206 (Rayside) 99.6%STN77218 (Copper Cliff) 99.8%STN77225 (Kelly Lake) 99.7%STN77227 (Kinsmen) 99.7%

STN77228 (Dozzi Park) 99.7%STN77230 (Spruce Street) 99.7%

STN77231 (Algonquin) 99.7%STN77330 (Union) 99.7%STN77600 (Edison) 99.7%

STN77601 (Parkinson) 99.2%STN77602 (Sunderland) 99.0%STN77603 (Wahnapitae) 99.8%

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Tables 3 and 4 summarize the annual percent valid data collection at STN77025 and STN1Glencore, respectively. Overall, allthe meteorological parameters met the 90% valid data availability criteria.

Table 3. Summary of Annual Valid Data Collection for Meteorological Data @ STN77025

Met Parameter

(STN77025)

Valid Data Collection

(%)

Temperature Elevation @ 12.5 m (T1) 100.0%Temperature Elevation @ 91 m (T3) 99.5%

Delta T (DT2) 98.4%Wind Direction Elevation @ 12.5 m (WD1) 98.9%Wind Direction Elevation @ 91 m (WD3) 100.0%Wind Speed Elevation @ 12.5 m (WS1) 100.0%Wind Speed Elevation @ 91 m (WS3) 100.0%

Table 4. Summary of Annual Valid Data Collection for Meteorological Data @ STN1Glencore

Met Parameter

(STN1Glencore)

Valid Data Collection

(%)

Temperature Elevation @ 2 m (T1) 99.9%Temperature Elevation @ 60 m (T3) 99.9%

Delta T (DT2) 99.9%Wind Direction Elevation @ 60 m (WD1) 99.9%

Wind Speed Elevation @ 60 m (WS1) 99.9%

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Table of Contents

Statement of Qualifications and LimitationsLetter of TransmittalExecutive Summary

pa ge

1. Introduction .................................................................................................................................. 11.1 General Overview .......................................................................................................................................... 1

2. Summary of Overall Operations.................................................................................................. 22.1 Parameters Monitored ................................................................................................................................... 22.2 Inventory of SO2 Equipment ........................................................................................................................... 32.3 Meteorological Measurement Equipment ........................................................................................................ 62.4 Summary of Site Visits – Bestech ................................................................................................................... 62.5 MOECC Audits .............................................................................................................................................. 72.6 Data Loss and Backup ................................................................................................................................... 8

3. Percent Valid Data Statistics ..................................................................................................... 103.1 SO2 Valid Data Collection Performance ........................................................................................................ 103.2 Meteorological Valid Data Collection Performance ........................................................................................ 11

4. Annual Statistics ........................................................................................................................ 124.1 Hourly SO2 Concentrations Overview ........................................................................................................... 124.2 Maximum Daily SO2 Concentrations ............................................................................................................. 134.3 Summary of Measured SO2 Concentrations Above AAQC ............................................................................ 144.4 Source Contribution Assessment for Measured SO2 Concentrations Above AAQC......................................... 154.5 Annual SO2 Average Concentrations Overview ............................................................................................. 16

5. Annual SO2 Results Comparison .............................................................................................. 18

6. References ................................................................................................................................. 20

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Table of Contents

List of Tables

Table 1. Annual Arithmetic Mean SO2 Concentrations for January to December 2014 ........................................................... iTable 2. Summary of SO2 Annual Valid Data Collection for 2014 ........................................................................................ iiTable 3. Summary of Annual Valid Data Collection for Meteorological Data @ STN77025................................................... iiiTable 4. Summary of Annual Valid Data Collection for Meteorological Data @ STN1Glencore ............................................ iii

Table 2-1. Parameters Monitored at Sudbury SO2 Monitoring Network .................................................................................... 2Table 2-2. SO2 Analyzer Inventory......................................................................................................................................... 3Table 2-3. Station Upgrades and Replacements in 2014 ........................................................................................................ 4Table 2-4. Calibration Summary at Each Monitoring Station in 2014 ....................................................................................... 6Table 2-5. MOECC Audits at Each SO2 Monitoring Station – Date & Result ............................................................................ 7Table 2-6. MOECC Audit Outcomes ...................................................................................................................................... 7Table 3-1. SO2 Valid Data Collection at Each Monitoring Station .......................................................................................... 10Table 3-2. Meteorological Valid Data Collection Performance @ STN77025 ......................................................................... 11Table 3-3. Meteorological Valid Data Collection Performance @ STN1Glencore ................................................................... 11Table 4-1. Maximum Hourly SO2 Concentrations – January to December 2014 .................................................................... 12Table 4-2. Maximum Daily SO2 Concentrations – January to December 2014 ....................................................................... 13Table 4-3. SO2 Measured Concentrations above AAQC ....................................................................................................... 14Table 4-4. Source Contribution Assessment for the Measured SO2 Concentrations above the Hourly AAQC.......................... 15Table 5-1. Average Annual SO2 Concentrations for 2013 and 2014 ...................................................................................... 18

List of Figures

Figure 4-1. Annual Mean SO2 Concentration – January to December 2014 ........................................................................... 17Figure 5-1. Annual Mean SO2 Concentrations Comparison ................................................................................................... 19

Appendices

Appendix A. Equipment InventoryAppendix B. Summary of Site Visits & Resolved IssuesAppendix C. Figure

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1. IntroductionBestech was retained by Vale and Glencore to operate and maintain eighteen (18) SO2 monitoring stations in the Sudbury area.AECOM Canada Ltd. (AECOM) was retained by Bestech to perform the data analysis and reporting on their behalf. Bestech andAECOM conducted this work from January to December 2014. This annual report is a component of the reporting requirementsthat Vale and Glencore must provide to the Ministry of the Environment and Climate Change (MOECC).

This report has been prepared following the guidance of the report issued by the MOECC Operations Manual for Air QualityMonitoring in Ontario (MOECC, March 2008). AECOM is responsible for reporting monitoring data while Bestech is responsible forcalibration and maintenance of the monitoring equipment.

This annual report summarizes the measured ambient SO2 concentrations at the eighteen (18) monitoring stations and themeteorological conditions from the two (2) meteorological stations (STN77025 and STN1Glencore), located in Sudbury andFalconbridge, Ontario.

1.1 General Overview

There are currently eighteen (18) SO2 monitoring stations and two (2) meteorological stations situated in Sudbury and itssurrounding area. Prior to April 2004, eleven (11) of these monitoring stations and one (1) meteorological station (STN77025)were owned and operated by the MOECC. Since then, the ownership and responsibility for maintenance, calibration and datareporting have been transferred jointly to Vale and Glencore and the following changes have occurred:

· In 2007, two (2) new stations were added as the twelfth and thirteenth stations (STN77230 and STN77231).· In May 2008, four (4) stations (STN77600, STN77601, STN77602 and STN77603) and one (1) MET station

(STN1Glencore) were included in the reporting for the Sudbury SO2 Monitoring Network. They had been previouslyreported by Glencore.

· In December 2009, STN77201 (Mikkola) was relocated from 150 Patricia Street to 1 Mikkola Road and renamedSTN77227 (Kinsmen).

· In November 2013, STN77330 (Union) was added to the monitoring network as the eighteenth station. Bestech andAECOM were retained by Vale and Glencore to administer this monitoring network on their behalf.

Bestech has calibrated all of the eighteen (18) stations in accordance with the MOECC Operations Manual for Air QualityMonitoring in Ontario (March 2008). Bestech and AECOM have carried out daily data checks, data editing and monthly datachecks.

A map showing the location of the monitoring stations, the MET stations and the Vale and Glencore sites is presented in AppendixC.

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2. Summary of Overall Operations2.1 Parameters Monitored

The parameters monitored at the Sudbury SO2 Monitoring Network stations are mainly SO2 concentrations, wind speed, winddirection, and ambient temperatures. Table 2-1 presents the parameters monitored at each of the monitoring stations.

Table 2-1. Parameters Monitored at Sudbury SO2 Monitoring Network

Station ID Location Data

STN77012 (Skead) Bowlands Rd, Skead P0M 2Y0 SO2

STN77013 (Hanmer) 4896 Notre Dame, Hanmer P0M 1H0 SO2

STN77028 (Coniston) 103 Edward St., Coniston P0M 1M0 SO2

STN77065 (Garson) 3610 Falconbridge Hwy, Garson P3L 1E6 SO2

STN77075 (New Sudbury) 1400 Barrydowne Rd., Sudbury P3A 3V8 SO2

STN77227 (Kinsmen) 1 Mikkola Rd, Lively P3Y 1A5 SO2

STN77203 (Science North) Science North 3rd Floor, Sudbury P3E 5S9 SO2, Solar Radiation

STN77206 (Rayside) 3535 Regional Road 15, Chelmsford P0M 1L0 SO2

STN77218 (Copper Cliff) 43 Veteran St., Copper Cliff P0M 1N0 SO2

STN77225 (Kelly Lake) 1379 Stephen St., Sudbury P3E 2ME SO2

STN77228 (Dozzi Park) 15 Glover St., Sudbury P3C 5M5 SO2, Barometric Pressure

STN77230 (Spruce Street) 636 Spruce St., Sudbury P3C 1R2 SO2

STN77231 (Algonquin) 2646 Algonquin Rd, Sudbury P3E 4X6 SO2

STN77330 (Union) Union and Marconi P0M 1N0 SO2

STN77600 (Edison) 6 Edison Rd, Falconbridge P0M 1S0 SO2

STN77601 (Parkinson) Parkinson Rd, Playground, Falconbridge P0M 1S0 SO2

STN77602 (Sunderland) Lot 4, Sunderland Rd., Garson P3L 1E6 SO2

STN77603 (Wahnapitae) Dryden Twp, Wahnapitae P0M 3C0 SO2

STN77025 (CKNC Tower @ Frood) 699 Frood Rd., Sudbury P3C 5A3Temperature, Wind Speed and Wind

Direction at 12.5 m and 91 m elevations

STN1Glencore (Met Tower @ Glencore) 6 Edison Rd, Falconbridge Bsmt of XPS P0M 1S0Temperature at 2 m and 60 m

elevations, Wind Speed and WindDirection at 60 m elevation

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2.2 Inventory of SO2 Equipment

The existing SO2 sampling equipment is based on pulsed fluorescence SO2 analyzers. For instrument calibrations, two (2)methods are used. First, an SO2 permeation tube inside the SO2 analyzer provides a stable gas source and a nightly zero andspan is performed automatically. The measured span value is compared to the value at the time of the last external calibrationusing a known source. The auto calibration is performed at the end of one hour and the beginning of the next so that both hoursmaintain valid data as each hour maintains over 75% valid data.

Second, on a monthly basis or when required, the SO2 instrument is calibrated using an external SO2 source. This source isprovided from a permeation gas dilution calibrator and zero air generator. The external calibrator is compared to a known SO2

standard (lab bench analyzer) at regular intervals and also checked with the local MOECC SO2 standard (MOECC office benchanalyzer).

There is one (1) type of analyzer in use in the current system: TECO 43I. In 2013, the remaining TECO 43C models used at themonitoring stations were replaced with newer TECO 43I models. The older TECO 43C models were retained as spares. Table 2-2lists each of the analyzer types, the age of the unit, measurement range and the station where it is located.

Table 2-2. SO2 Analyzer Inventory

SO2 Analyzer Type Quantity Age Measurement Range(ppb)

Station

TECO 43I 20 < 7 years 0 – 10 000

SkeadHanmerConistonGarson

Science NorthRayside

Kelly LakeKinsmen

Dozzi ParkSpruce Street

EdisonParkinson

SunderlandWahnapitae

UnionSudbury INO Spare #1Sudbury INO Spare #2

Vale Spare #1Vale Mobile

TECO 43C 3 ~ 14 years 0 – 10 000Vale Spare #2Vale Spare #3Vale Spare #4

TECO 43I 3 < 2 years 0 – 10 000New SudburyCopper CliffAlgonquin

Notes: INO = Integrated Nickel Operations

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Table 2-3 lists all of the station upgrades and replacements that were made in 2014 including the month in which the upgrades orreplacement occurred.

Table 2-3. Station Upgrades and Replacements in 2014

Station ID Upgrades Month of Upgrade

CKNC Met Tower Changed CF card September

STN77012 (Skead)

Configured Teco alarm July

Performed annual preventative maintenance July

Changed CF card July

STN77013 (Hanmer)

Performed annual preventative maintenance May

Changed CF card May

Configured Teco alarm July

STN77028 (Coniston)

Performed annual preventative maintenance May

Changed CF card May

Installed new permeation tube into analyzer June

Configured Teco alarm July

STN77065 (Garson)

Configured Teco alarm July

Installed new permeation tube July

Performed annual preventative maintenance October

Changed CF card October

STN77075 (New Sudbury)

Replaced temperature sensor January

Replaced PLC power supply and analog January

Replaced UPS January

Configured Teco alarm March

Performed annual preventative maintenance May

Changed CF card October

STN77203 (Science North)

Configured Teco alarm April

Replaced solar sensor May

New Science North Website software installed September

Installed long exhaust tube November

Performed annual preventative maintenance April

Changed CF card April

STN77206 (Rayside)

Upgraded PLC program February

Configured Teco alarm March

Performed annual preventative maintenance May

Changed CF card May

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Station ID Upgrades Month of Upgrade

Installed small UPS May

STN77218 (Copper Cliff)

Configured Teco alarm July

Upgraded PLC program April

Performed annual preventative maintenance May

Changed CF card May

STN77225 (Kelly Lake)

Configured Teco alarm April

Installed small UPS May

Performed annual preventative June

Changed CF card June

STN77227 (Kinsmen)

Installed large UPS January

Configured Teco alarm April

Performed annual preventative maintenance May

Changed CF card May

Installed small UPS May

Replaced router November

STN77228 (Dozzi Park)

Repaired air conditioning April

Configured Teco alarm April

Changed CF card August

Performed annual preventative maintenance September

STN77230 (Spruce Street)

Configured Teco alarm April

Replaced zero air canister April

Performed annual preventative maintenance July

Changed CF card July

STN77231 (Algonquin)

Repaired air conditioning unit May

Configured Teco alarm July

Performed annual preventative maintenance May

Changed CF card June

STN77330 (Union)

Configured Teco alarm July

Performed annual preventative maintenance October

Changed CF card October

STN77600 (Edison)

Replaced SO2 analyzer with Glencore spare unit January

Replaced small UPS May

Configured Teco alarm July

STN77601 (Parkinson)Configured Teco alarm July

Replaced SO2 analyzer with Glencore spare unit November

STN77602 (Sunderland) Configured Teco alarm July

STN77603 (Wahnapitae) Changed CF card July

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The SO2 and meteorological data is collected using the Bestech data acquisition system which downloads station information tothe Bestech office in Sudbury. Additional details on the data back-up process are provided in Section 2.6.

Appendix A presents the equipment inventory for 2014 with all relevant details for each of the eighteen (18) monitoring stations.

2.3 Meteorological Measurement Equipment

There are two (2) stations equipped with meteorological measurement systems to provide continuous weather data: the CKNCMET station and the Glencore MET station.

The STN77025 MET station is located at the CKNC transmission tower. It is a dedicated meteorological station that takesmeasurements of temperature, wind speed and wind direction at 12.5 m and 91 m elevations.

The second meteorological tower is designated as STN1Glencore, which is a dedicated meteorological station that takesmeasurements of temperature at 2 m and 60 m elevations and wind speed and wind direction at a 60 m elevation. A back-upanemometer was also added at a 24.3 m (80 foot) elevation in December 2013.

2.4 Summary of Site Visits – Bestech

During the period from January to December 2014, each monitoring station was calibrated once per month resulting in (12)calibrations during the year for each station. Additional site visits were made for MOECC audits and when the stations experiencedinstrumentation or server problems. Table 2-3 identifies the calibration dates at each of the monitoring stations.

Table 2-4. Calibration Summary at Each Monitoring Station in 2014

Station ID Jan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec

STN77012 (Skead) 29 Jan 25 Feb 10 Mar 08 Apr 12 May 11 Jun 17 Jul 22 Aug 16 Sept 08 Oct 14 Nov 17 Dec

STN77013 (Hanmer) 02 Jan 11 Feb 10 Mar 03 Apr 05 May 04 Jun 04 Jul 13 Aug 13 Sept 01 Oct 11 Nov 23 Dec

STN77028 (Coniston) 09 Jan 03 Feb 17 Mar 01 Apr 07 May 17 Jun 08 Jul 12 Aug 03 Sept 02 Oct 06 Nov 02 Dec

STN77065 (Garson) 15 Jan 14 Feb 11 Mar 10 Apr 09 May 11 Jun 14 Jul 14 Aug 05 Sept 08 Oct 13 Nov 22 Dec

STN77075 (New Sudbury) 06 Jan 05 Feb 12 Mar 10 Apr 14 May 04 Jun 21 Jul 14 Aug 19 Sept 03 Oct 14 Nov 02 Dec

STN77203 (Science North) 24 Jan 13 Feb 17 Mar 15 Apr 14 May 27 Jun 22 Jul 29 Aug 25 Sept 27 Oct 10 Nov 19 Dec

STN77206 (Rayside) 02 Jan 10 Feb 11 Mar 08 Apr 06 May 09 Jun 04 Jul 13 Aug 05 Sept 01 Oct 11 Nov 16 Dec

STN77218 (Copper Cliff) 06 Jan 06 Feb 21 Mar 30 Apr 16 May 30 Jun 18 Jul 26 Aug 09 Sept 06 Oct 25 Nov 18 Dec

STN77225 (Kelly Lake) 13 Jan 04Feb 14 Mar 07 Apr 13 May 03 Jun 18 Jul 06 Aug 15 Sept 17 Oct 12 Nov 05 Dec

STN77227 (Kinsmen) 13 Jan 03 Feb 06 Mar 22 Apr 02 May 03 Jun 07 Jul 26 Aug 04 Sept 06 Oct 12 Nov 01 Dec

STN77228 (Dozzi Park) 21 Jan 12 Feb 27 Mar 14 Apr 12 May 12 Jun 21 Jul 20 Aug 29 Sept 16 Oct 17 Nov 19 Dec

STN77230 (Spruce Street) 30 Jan 14 Feb 13 Mar 14 Apr 16 May 12 Jun 22 Jul 28 Aug 26 Sept 27 Oct 28 Nov 22 Dec

STN77231 (Algonquin) 09 Jan 04 Feb 14 Mar 02 Apr 07 May 11 Jun 08 Jul 12 Aug 03 Sept 02 Oct 06 Nov 01 Dec

STN77330 (Union) 23 Jan 06 Feb 26 Mar 03 Apr 23 May 25 Jun 21 Jul 28 Aug 04 Sept 07 Oct 27 Nov 30 Dec

STN77600 (Edison) 23 Jan 24 Feb 20 Mar 16 Apr 21 May 24 Jun 16 Jul 25 Aug 24 Sept 24 Oct 19 Nov 10 Dec

STN77601 (Parkinson) 23 Jan 19 Feb 20 Mar 16 Apr 20 May 24 Jun 16 Jul 19 Aug 24 Sept 24 Oct 21 Nov 10 Dec

STN77602 (Sunderland) 22 Jan 19 Feb 13 Mar 16 Apr 21 May 25 Jun 16 Jul 25 Aug 23 Sept 22 Oct 19 Nov 09 Dec

STN77603 (Wahnapitae) 22 Jan 18 Feb 18 Mar 17 Apr 20 May 24 Jun 15 Jul 19 Aug 23 Sept 22 Oct 20 Nov 09 Dec

Appendix B presents an overall summary of all site visits due to instrumentation and server problems at each station.

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2.5 MOECC Audits

A representative from the Sudbury District MOECC office conducts audits at each station on a quarterly basis. Table 2-4summarizes the dates when the audits were performed and the outcomes.

Table 2-5. MOECC Audits at Each SO2 Monitoring Station – Date & Result

STATION IDFirst Quarter Second Quarter Third Quarter Fourth Quarter

Date MonitorPerformance Date Monitor

Performance Date MonitorPerformance Date Monitor

Performance

STN77012 (Skead)M

arch

18,1

9,24

,25

and

26,2

014

Criteria Met

June

9,13

,16,

17,1

8an

d19

,201

4

Criteria Met

Sep

tem

ber8

,10,

11,1

2,17

and

24,2

014

Criteria Met

Dec

embe

r4,8

,10,

11,1

2,an

d18

,201

4

Criteria Met

STN77013 (Hanmer) Criteria Met Criteria Met Criteria Met Criteria Met

STN77028 (Coniston) Criteria Met Criteria Not Met Criteria Met Criteria Met

STN77065 (Garson) Criteria Met Criteria Met Criteria Met Criteria Met

STN77075 (New Sudbury) Criteria Met Criteria Met Criteria Met Criteria Met

STN77227 (Kinsmen) Criteria Met Criteria Met Criteria Met Criteria Met

STN77203 (Science North) Criteria Met Criteria Met Criteria Met Criteria Met

STN77206 (Rayside) Criteria Met Criteria Met Criteria Met Criteria Met

STN77218 (Copper Cliff) Criteria Met Criteria Met Criteria Met Criteria Met

STN77225 (Kelly Lake) Criteria Met Criteria Met Criteria Met Criteria Met

STN77228 (Dozzi Park) Criteria Met Criteria Met Criteria Met Criteria Met

STN77230 (Spruce Street) Criteria Met Criteria Met Criteria Met Criteria Met

STN77231 (Algonquin) Criteria Met Criteria Met Criteria Met Criteria Met

STN77330 (Union) Criteria Met Criteria Met Criteria Met Criteria Met

STN77600 (Edison) Criteria Met Criteria Met Criteria Met Criteria Met

STN77601 (Parkinson) Criteria Met Criteria Met Criteria Met Criteria Met

STN77602 (Sunderland) Criteria Met Criteria Met Criteria Met Criteria Met

STN77603 (Wahnapitae) Criteria Met Criteria Met Criteria Met Criteria Met

There were a total of four (4) audits performed by the MOECC at the eighteen (18) monitoring stations between January 2014 andDecember 2014.

All audits (which were recorded in the MOECC Audit Reports) met the MOECC criteria, with the exception of STN77028 (Coniston)during the second quarter. Overall, the audits indicate good performance at each of the monitoring stations. The one (1)deficiency is noted in Table 2-6.

Table 2-6. MOECC Audit Outcomes

Audit DeficiencyNo.

Station ID Deficiency Corrective Action Audit Date

1 77028(Coniston)

Analyzer was repairedand it was not calibratedcorrectly prior to its return

to service.

· Added QA checks tocalibration records to confirmcalibration changes

· Created a span correctionform and procedure so thatchanges are executedcorrectly

· AQM data was correctedaccordingly to reflect the truevalue of SO2 data collected.

June 16, 2014

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Audit DeficiencyNo.

Station ID Deficiency Corrective Action Audit Date

As per MOECC audit report,the data was adjusted by -12% from June 14, 2014(14:00) to June 16, 2014(09:30).)

· Analyzer maintenancemanual was added thataccompanies the Analyzershould it be replaced at thestation.

2.6 Data Loss and Backup

BESTECH maintains a back-up of the raw data for each station on the Programmable Logic Controller (PLC) using a compactflash card. These compact flash cards were exchanged at fifteen (15) of the stations maintained by BESTECH. The old compactflash cards containing the 2014 data are currently in storage at the BESTECH Lorne office.

The Sudbury SO2 network data is collected over high speed internet connections. These changes have had a direct impact on datacollection and processing times further improving data reliability and relevance. In addition, changes were made to the systemsredundancy capabilities where the implementation of auto switching capabilities has been added. These improvements assigna dial up modem as the backup communication protocol following high speed network connection failure at any or all the stations.Furthermore, the systems database is now simultaneously seamlessly backed up via a SQL database replication bridge. Thissystem enables the storage of all raw and processed data for future or current data retrieval and storage. The secondary server,known as the standby backup clone, is also capable of being swapped into becoming the primary processing server, should theprimary server fail. Server swaps are performed at regular intervals to ensure transferability, should a hardware failure occur onthe primary processing server. Hence, this feature further improves data redundancy and insures maximum system up time andfunctionality.

During 2014, server swaps occurred on:

· March 12th – switch from standby server 116 to primary server 115· October 15th – switch from primary 115 to standby server 116

A redundant AQM Disaster Recovery (AQM DR) server is installed at the BESTECH Manufacturing office at the Norcat trainingcenter in Sudbury. This system runs simultaneously to the main AQM system at the Lorne location but does not have dial-upmodems for redundant data collection on AQM station Internet failures. This AQM DR system is used when a connection failureoccurs from Glencore to the AQM system at the BESTECH Lorne office and during server swaps. Prior to performing serverswaps, Glencore’s Sudbury INO operations failover to the AQM DR System at the Norcat location while maintenance is performed.Once server swaps are complete, Glencore’s Sudbury INO operations switch back to the main AQM system. The AQM DR at theNorcat location is not used for official data reporting and archiving purposes.

A Teco analyzer general alarm was added to the AQM system in 2014. This alarm triggers when one of the measured parametersin the Teco falls outside of a desired range (i.e. air pressure, air flow, chamber temperature, lamp voltage, etc.). This alarm, oncetriggered is captured as a flag along with the collected data. This flag, in turn generates an alarm in the AQM System and alertsthe BESTECH support team via Email and SMS so that they can respond immediately to the alarm. This provides addedconfidence that analyzers are operating correctly in real time and reduces possible data invalidation upon failures, as the time offailure is known.

The highest number of invalid hours recorded in a month at the SO2 monitoring stations in 2014 occurred in November atSTN77601 (Parkinson), which resulted in 44 invalid hours. This was mainly due to instrument problems that occurred fromNovember 19th to November 21st, 2014.

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The highest number of invalid hours recorded in a month at either of the two MET stations was 95 invalid hours. This occurred atduring the month of May. The TEM3 instrument at STN77025 (CKNC) experienced instrument problems from May 15th to May19th, 2014.

A summary of incidents that resulted in data losses for each of the SO2 monitoring stations and MET stations is presented inAppendix B.

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3. Percent Valid Data StatisticsOverall, all parameters met the performance criteria with an annual valid data collection greater than 90% at the eighteen (18) SO2

monitoring stations and the meteorological towers (STN77025 and STN1Glencore).

The following sections summarize the valid data collection performance for SO2 and for the meteorological data collected fromJanuary to December 2014.

3.1 SO2 Valid Data Collection Performance

For the overall annual period, SO2 data availability at eighteen (18) of the monitoring stations met the 90% performance criterion.

Table 3-1. SO2 Valid Data Collection at Each Monitoring Station

Station IDFirst Quarter

Valid DataPerformance (%)

Second QuarterValid Data

Performance (%)

Third QuarterValid Data

Performance (%)

Fourth QuarterValid Data

Performance (%)

Annual ValidData

Performance (%)

STN77012 (Skead) 99.8% 99.7% 99.0% 99.8% 99.6%STN77013 (Hanmer) 99.7% 99.8% 99.7% 99.8% 99.7%

STN77028 (Coniston) 99.8% 99.4% 99.8% 99.8% 99.7%STN77065 (Garson) 99.8% 99.6% 99.7% 99.7% 99.7%

STN77075 (New Sudbury) 98.4% 99.8% 99.8% 99.7% 99.4%STN77203 (Science North) 99.7% 99.7% 99.8% 99.2% 99.6%

STN77206 (Rayside) 99.7% 99.6% 99.6% 99.4% 99.6%STN77218 (Copper Cliff) 99.8% 99.7% 99.8% 99.8% 99.8%STN77225 (Kelly Lake) 99.8% 99.6% 99.8% 99.6% 99.7%STN77227 (Kinsmen)** 99.8% 99.6% 99.7% 99.8% 99.7%STN77228 (Dozzi Park) 99.7% 99.6% 99.8% 99.6% 99.7%

STN77230 (Spruce Street) 99.8% 99.7% 99.6% 99.6% 99.7%STN77231 (Algonquin) 99.7% 99.6% 99.7% 99.7% 99.7%

STN77330 (Union)* 99.7% 99.6% 99.6% 99.7% 99.7%STN77600 (Edison) 99.8% 99.6% 99.7% 99.8% 99.7%

STN77601 (Parkinson) 99.8% 99.6% 99.8% 97.7% 99.2%STN77602 (Sunderland) 98.4% 98.2% 99.7% 99.7% 99.0%STN77603 (Wahnapitae) 99.8% 99.8% 99.7% 99.8% 99.8%

Total Hours 2,160 2,184 2,208 2,208 8,760

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3.2 Meteorological Valid Data Collection Performance

For the overall annual period, all of the meteorological parameters at STN77025 (CKNC Tower) and STN1Glencore met the 90%valid data collection criteria.

Table 3-2. Meteorological Valid Data Collection Performance @ STN77025

Met Parameter (STN77025)First Quarter

Valid DataCollection (%)

Second QuarterValid Data

Collection (%)

Third QuarterValid Data

Collection (%)

Fourth QuarterValid Data

Collection (%)

Annual ValidData Collection

(%)

T1 (Temperature @ 12.5 m) 100.0% 100.0% 100.0% 100.0% 100.0%T3 (Temperature @ 91 m) 100.0% 95.7% 99.5% 98.4% 99.5%

DT2 (Delta T) 100.0% 95.7% 99.5% 98.4% 98.4%WD1 (Wind Direction 1 @ 12.5 m) 100.0% 100.0% 100.0% 100.0% 98.9%WD3 (Wind Direction 3 @ 91 m) 100.0% 100.0% 100.0% 100.0% 100.0%WS1 (Wind Speed 1 @ 12.5 m) 100.0% 100.0% 100.0% 100.0% 100.0%WS3 (Wind Speed 3 @ 91 m) 100.0% 100.0% 100.0% 100.0% 100.0%

Total Hours in Period 2,160 2,184 2,208 2,208 8,760

Table 3-3. Meteorological Valid Data Collection Performance @ STN1Glencore

Met Parameter (STN1Glencore)First Quarter

Valid DataCollection (%)

Second QuarterValid Data

Collection (%)

Third QuarterValid Data

Collection (%)

Fourth QuarterValid Data

Collection (%)

Annual ValidData Collection

(%)

T1 (Temperature @ 2 m) 100.0% 99.5% 100.0% 100.0% 99.9%T3 (Temperature @ 60 m) 100.0% 99.5% 100.0% 100.0% 99.9%

DT2 (Delta T) 100.0% 99.5% 100.0% 100.0% 99.9%WD1 (Wind Direction 1 @ 60 m) 100.0% 99.5% 100.0% 100.0% 99.9%

WS1 (Wind Speed 1 @ 60 m) 100.0% 99.5% 100.0% 100.0% 99.9%Total Hours in Period 2,160 2,184 2,208 2,208 8,760

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4. Annual StatisticsThis section details the maximum hourly, daily, and annual arithmetic mean SO2 concentrations at each of the eighteen (18) SO2

monitoring stations.

The annual mean is calculated as the mean of twelve (12) monthly means and it requires the collection of 75% valid data (6,570valid hourly means out of a possible 8,760 hours). A valid monthly mean requires at least twenty-three (23) valid daily means. Avalid daily mean requires at least eighteen (18) valid hourly averages out of twenty-four (24) hours as described in the “OperationsManual for Air Quality Monitoring in Ontario” (March, 2008).

For further details regarding the monthly statistics, refer to the four (4) Quarterly Reports, which summarize the monthly SO2 andmeteorological data statistics (issued in May 2014, August 2014, November 2014 and February 2015). This section also comparesthe 2014 annual data with the 2013 annual data.

4.1 Hourly SO2 Concentrations Overview

The maximum hourly average SO2 concentration from January to December 2014 was found to be at STN77075 (New Sudbury)with a concentration of 286 ppb in July 2014. The second highest maximum hourly SO2 concentration was found at STN77228(Dozzi Park) with 278 ppb in March 2014.

Table 4-1 illustrates the maximum hourly SO2 concentrations at each of the monitoring stations.

Table 4-1. Maximum Hourly SO2 Concentrations – January to December 2014

Station IDMaximum Hourly Mean SO2 (ppb)

Jan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec Max

STN77012 (Skead) 139 142 132 130 75 159 105 132 102 102 104 58 159STN77013 (Hanmer) 74 45 53 67 13 79 32 130 89 67 43 24 130

STN77028 (Coniston) 139 128 115 98 104 88 64 114 80 80 91 94 139STN77065 (Garson) 108 125 141 147 91 160 159 52 135 73 72 186 186

STN77075 (New Sudbury) 92 160 173 121 170 78 286 78 165 62 78 82 286STN77203 (Science North) 33 94 107 36 26 24 79 32 110 96 77 163 163

STN77206 (Rayside) 73 81 134 77 45 96 34 55 149 23 17 56 149STN77218 (Copper Cliff) 101 48 167 180 37 136 77 63 225 92 93 36 225STN77225 (Kelly Lake) 57 30 58 36 103 48 257 202 249 93 40 42 257STN77227 (Kinsmen) 36 29 70 208 20 100 24 55 152 63 49 13 208

STN77228 (Dozzi Park) 34 56 278 45 24 28 87 35 92 57 52 114 278STN77230 (Spruce Street) 90 67 132 75 54 98 99 46 74 74 68 82 132

STN77231 (Algonquin) 51 46 127 118 89 53 219 50 146 249 88 104 249STN77330 (Union) 96 105 97 98 42 71 50 84 73 113 92 39 113STN77600 (Edison) 117 117 87 113 87 249 140 74 131 92 89 167 249

STN77601 (Parkinson) 135 122 95 151 177 214 142 175 107 99 93 127 214STN77602 (Sunderland) 48 120 98 164 144 53 73 75 50 80 55 170 170STN77603 (Wahnapitae) 208 112 53 50 39 31 101 84 55 54 52 90 208

Notes: Hourly SO2 AAQC = 250 ppb

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4.2 Maximum Daily SO2 Concentrations

The maximum daily average SO2 concentration from January to December 2014 was measured at STN77075 (New Sudbury) witha concentration of 47.6 ppb in February 2014. The second highest maximum daily SO2 concentration was found at STN77065(Garson) with 44.4 ppb in February 2014. Table 4-2 illustrates the maximum daily SO2 concentrations at each of the monitoringstations.

Table 4-2. Maximum Daily SO2 Concentrations – January to December 2014

Station IDMaximum Daily Mean SO2 (ppb)

Jan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec Max

STN77012 (Skead) 21.7 12.5 16.3 15.2 11.9 26.2 30.8 16.0 12.7 16.1 13.2 5.0 30.8STN77013 (Hanmer) 11.9 6.0 9.0 7.1 1.9 11.1 3.7 14.1 7.3 7.1 3.9 4.0 14.1

STN77028 (Coniston) 30.8 11.7 15.5 13.3 10.2 10.1 6.3 7.5 9.0 10.5 5.0 12.9 30.8STN77065 (Garson) 13.0 44.4 13.5 9.4 14.7 14.7 17.0 5.8 11.3 6.4 8.3 17.3 44.4

STN77075 (New Sudbury) 10.8 47.6 21.4 8.8 28.3 16.9 28.0 10.8 10.5 9.2 4.8 6.4 47.6STN77203 (Science North) 11.0 7.3 14.5 7.4 4.3 3.1 7.2 3.8 10.2 10.6 7.9 22.4 22.4

STN77206 (Rayside) 5.1 9.4 23.4 6.4 2.0 7.4 2.6 4.1 13.8 2.3 1.9 6.2 23.4STN77218 (Copper Cliff) 17.4 7.2 12.4 23.8 8.9 19.1 11.2 11.1 16.0 15.7 23.8 6.1 23.8STN77225 (Kelly Lake) 3.8 3.8 11.8 6.6 14.8 5.3 17.0 12.9 12.5 5.9 5.7 9.2 17.0STN77227 (Kinsmen) 5.0 2.9 27.0 30.4 2.8 15.7 4.0 7.4 16.6 9.5 4.3 1.1 30.4

STN77228 (Dozzi Park) 4.7 8.9 14.2 6.4 4.2 3.3 10.5 8.3 10.2 7.8 5.5 10.9 14.2STN77230 (Spruce Street) 23.3 21.8 12.4 12.9 10.3 21.6 16.3 6.3 12.2 6.8 15.0 12.5 23.3

STN77231 (Algonquin) 8.4 2.8 14.3 16.8 11.8 5.6 15.5 7.8 13.3 13.3 8.1 8.3 16.8STN77330 (Union) 22.8 12.3 24.8 31.5 5.4 30.0 10.3 13.8 13.3 17.5 13.0 4.8 31.5STN77600 (Edison) 12.8 39.0 10.4 26.8 13.2 16.5 14.6 11.6 11.0 8.8 9.0 16.0 39.0

STN77601 (Parkinson) 14.3 39.0 12.0 25.9 27.3 17.1 13.6 18.0 10.0 9.1 9.3 12.7 39.0STN77602 (Sunderland) 6.3 24.5 20.6 35.1 19.7 6.2 13.2 11.0 6.7 7.3 8.5 14.6 35.1STN77603 (Wahnapitae) 26.0 9.5 8.8 7.7 3.2 3.4 6.8 15.4 5.6 6.5 3.6 10.5 26.0

Notes: Daily SO2 AAQC = 100 ppb

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4.3 Summary of Measured SO2 Concentrations Above AAQC

During the period of January to December 2014, there were a total of three (3) hourly measured SO2 concentrations above thehourly AAQC of 250 ppb. There were no measured SO2 concentrations above the daily AAQC limit of 100 ppb.

Table 4-3 lists the total measured SO2 concentrations above the hourly and daily AAQC limits for the reporting period.

Table 4-3. SO2 Measured Concentrations above AAQC

Station IDJan – Mar 2014 Apr – June 2014 Jul – Sept 2014 Oct – Dec 2014 Total

Hourly Daily Hourly Daily Hourly Daily Hourly Daily Hourly Daily

STN77012 (Skead) 0 0 0 0 0 0 0 0 0 0STN77013 (Hanmer) 0 0 0 0 0 0 0 0 0 0

STN77028 (Coniston) 0 0 0 0 0 0 0 0 0 0STN77065 (Garson) 0 0 0 0 0 0 0 0 0 0

STN77075 (New Sudbury) 0 0 0 0 1 0 0 0 1 0STN77203 (Science North) 0 0 0 0 0 0 0 0 0 0

STN77206 (Rayside) 0 0 0 0 0 0 0 0 0 0STN77218 (Copper Cliff) 0 0 0 0 0 0 0 0 0 0STN77225 (Kelly Lake) 0 0 0 0 1 0 0 0 1 0STN77227 (Kinsmen) 0 0 0 0 0 0 0 0 0 0

STN77228 (Dozzi Park) 1 0 0 0 0 0 0 0 1 0STN77230 (Spruce Street) 0 0 0 0 0 0 0 0 0 0

STN77231 (Algonquin) 0 0 0 0 0 0 0 0 0 0STN77330 (Union) 0 0 0 0 0 0 0 0 0 0STN77600 (Edison) 0 0 0 0 0 0 0 0 0 0

STN77601 (Parkinson) 0 0 0 0 0 0 0 0 0 0STN77602 (Sunderland) 0 0 0 0 0 0 0 0 0 0STN77603 (Wahnapitae) 0 0 0 0 0 0 0 0 0 0

Total # of Measured SO2Concentrations above AAQC 1 0 0 0 2 0 0 0 3 0

Notes: 1-hr AAQC for SO2 = 250 ppb24-hr AAQC for SO2 = 100 ppb

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4.4 Source Contribution Assessment for Measured SO2 Concentrations Above AAQC

As per the Operations Manual, each of the measured SO2 concentrations above the AAQC is to be evaluated by wind speed andwind direction data for source contribution assessment. There were a total of four (4) measured SO2 concentrations above thehourly AAQC limit in 2014.

Table 4-4 presents the date and hour of the measured SO2 concentrations above the hourly AAQC limit, the station where it wasmeasured and the corresponding wind speed and direction data for this assessment. The table also identifies the potential SO2

source, solely based on the hourly wind direction measured at the closest meteorological station and the assumption that the ValeSmelter and Glencore Smelter are the major sources of SO2. The Vale Nickel Refinery is typically a low SO2 emitter but underexceptional meteorological events may also contribute as a source if SO2 emissions are trapped under a low inversion.

The location of STN77025 (CKNC Tower) provides MET data that is closer in proximity (within five (5) kilometres) to the ValeSmelter site. The Glencore site is located approximately seventeen (17) kilometres from CKNC MET station (STN77025). TheGlencore MET station (STN1Glencore) is located on the Glencore site, northwest of the smelter. It is approximately twenty-one(21) kilometres from the Vale Smelter. The Vale Nickel Refinery is located approximately four and a half (4.5) kilometressouthwest of the Vale Smelter.

A map showing the locations of the Vale Smelter and Nickel Refinery, Glencore Smelter and the monitoring stations is presented inAppendix C.

Table 4-4. Source Contribution Assessment for the Measured SO2 Concentrations above the Hourly AAQC

StationDate & Time ofMeasured SO2Concentration

SO2Concentration

(ppb)

Closest METStation

MET data Potential Upwind SO2SourceWS1 WD1 WS3 WD3

Dozzi Park(STN77228)

Mar-21-201413:00 – 14:00

278 CKNC Tower 4 km/hr 185° 5 km/hr 191° Vale Smelter / Vale NickelRefinery

New Sudbury(STN77075)

Jul-25-201410:00 – 11:00

286 CKNC Tower 20 km/hr 233° 28 km/hr 228° Vale Smelter / Vale NickelRefinery

Kelly Lake(STN77225)

Jul-30-201411:00 – 12:00

257 CKNC Tower 6 km/hr 298° 8 km/hr 309°Vale Smelter/ Vale Nickel

Refinery

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4.5 Annual SO2 Average Concentrations Overview

The monthly average and resulting annual arithmetic mean SO2 concentration in 2014 for each monitoring station are summarizedin Table 4-5. The annual average value is calculated by dividing the sum of the valid monthly mean SO2 concentrations for eachstation by the total number of valid months in the year.

The maximum annual mean SO2 concentration (3.3 ppb) occurred at STN77230 (Spruce Street). The annual AAQC for SO2 is 20ppb. Overall, the annual arithmetic means ranged from 0.8 to 3.3 ppb as illustrated in Table 4-5.

Table 4-5. Annual Mean SO2 Concentrations – January to December 2014

Station IDMonthly Mean SO2 (ppb) Annual

MeanJan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec

STN77012 (Skead) 2.4 3.6 3.7 2.1 1.8 3.1 3.8 1.6 2.7 2.0 1.8 0.8 2.4STN77013 (Hanmer) 1.9 1.3 1.2 1.0 0.2 1.4 0.6 1.3 1.4 1.1 0.8 0.7 1.1

STN77028 (Coniston) 3.4 2.6 3.6 1.9 1.3 0.9 1.2 0.9 1.2 1.6 1.4 1.7 1.8STN77065 (Garson) 2.0 4.7 3.0 2.4 1.5 1.5 3.1 1.1 2.0 1.4 1.2 1.5 2.1

STN77075 (New Sudbury) 2.0 4.3 3.4 1.4 1.6 1.4 3.7 1.0 2.1 1.1 0.8 0.7 2.0STN77203 (Science North) 2.2 1.9 2.1 2.4 0.2 0.6 1.6 0.9 1.3 2.1 2.0 2.8 1.7

STN77206 (Rayside) 1.0 0.9 2.9 1.0 0.5 0.6 0.2 0.7 0.6 0.3 0.2 0.9 0.8STN77218 (Copper Cliff) 3.1 1.3 1.8 1.0 0.2 3.7 2.0 1.3 2.2 2.3 2.4 1.2 1.9STN77225 (Kelly Lake) 1.3 1.0 2.1 3.0 0.9 0.5 2.0 1.5 1.1 1.1 1.1 1.5 1.4STN77227 (Kinsmen) 0.9 0.5 1.9 0.8 0.7 1.9 0.2 0.4 2.0 0.6 0.3 0.1 0.9

STN77228 (Dozzi Park) 1.8 2.3 2.6 1.2 0.5 0.8 2.5 1.6 1.7 2.4 1.7 1.4 1.7STN77230 (Spruce Street) 5.2 5.1 4.5 2.3 1.3 2.6 5.0 1.3 2.9 2.3 4.1 2.5 3.3

STN77231 (Algonquin) 2.1 0.6 1.8 2.1 0.6 0.4 1.7 1.5 1.2 2.0 0.9 1.4 1.4STN77330 (Union) 4.0 2.5 3.0 4.7 0.8 3.1 1.8 3.0 1.8 2.6 1.8 1.7 2.6STN77600 (Edison) 2.2 4.9 3.3 3.1 2.7 2.1 2.6 2.4 1.8 1.8 1.6 2.2 2.6

STN77601 (Parkinson) 2.0 5.2 3.3 5.1 4.3 2.3 2.6 3.7 2.1 2.7 1.4 1.9 3.1STN77602 (Sunderland) 2.2 4.8 4.2 3.9 1.9 0.8 2.2 1.7 1.1 1.1 1.0 2.3 2.3STN77603 (Wahnapitae) 2.6 2.0 2.0 0.9 0.4 0.3 0.6 1.6 0.8 0.8 0.8 1.3 1.2

Note: Annual AAQC for SO2 = 20 ppbA valid monthly mean requires at least twenty-three (23) valid daily means

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The annual average SO2 concentrations for each station are below the annual AAQC of 20 ppb as depicted in Figure 4-1.

Figure 4-1. Annual Mean SO2 Concentration – January to December 2014

0

5

10

15

20

25

Annu

alSO

2Av

erag

eC

once

ntra

tion

(ppb

)

STATION ID

2014 Annual Mean (ppb)

Annual AAQC Limit (ppb)

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5. Annual SO2 Results ComparisonThis section compares the monthly SO2 average concentrations from January to December 2014 (2014 data) versus Januaryto December 2013 (2013 data). Figure 5-1 presents a graphical comparison.

Overall, the 2014 SO2 annual average concentrations are very similar to the concentrations recorded in 2013. Of the eighteenmonitoring stations seven (7) stations had annual concentrations decrease from the previous year, nine (9) stations hadannual concentrations increase from the previous year, and one (1) station had no change. The remaining station (Union) didnot have a valid annual average concentration in 2013 and therefore a comparison could not be made.

A comparison of each monitoring stations’ annual arithmetic means for the previous annual reporting period (January toDecember 2013) and this reporting period (January to December 2014) is shown in Table 5-1.

Table 5-1. Average Annual SO2 Concentrations for 2013 and 2014

STATION ID2013 Annual SO2

Average Concentration(ppb)

2014 Annual SO2

Average Concentration(ppb)

Difference(ppb)

STN77012 (Skead) 2.1 2.4 0.3STN77013 (Hanmer) 1.1 1.1 0.0

STN77028 (Coniston) 2.3 1.8 -0.5STN77065 (Garson) 2.1 2.1 0.0

STN77075 (New Sudbury) 2.0 2.0 0.0STN77203 (Science North) 1.7 1.7 0.0

STN77206 (Rayside) 0.9 0.8 -0.1STN77218 (Copper Cliff) 2.5 1.9 -0.6STN77225 (Kelly Lake) 1.8 1.4 -0.3STN77227 (Kinsmen) 1.8 0.9 -1.0

STN77228 (Dozzi Park) 1.7 1.7 0.0STN77230 (Spruce Street) 3.6 3.3 -0.3

STN77231 (Algonquin) 2.0 1.4 -0.6STN77330 (Union) 3.4 2.6 -0.8STN77600 (Edison) 2.4 2.6 0.2

STN77601 (Parkinson) 3.1 3.1 0.0STN77602 (Sunderland) 2.3 2.3 -0.1STN77603 (Wahnapitae) 1.7 1.2 -0.5

Notes: Annual AAQC = 20 ppb

The maximum annual arithmetic mean SO2 concentration in 2014 occurred at STN77230 (Spruce Street) with 3.3 ppb. Overall, theannual average SO2 concentrations ranged from 0.8 to 3.3 ppb in 2014.

The maximum annual arithmetic mean SO2 concentration in 2013 occurred at STN77230 (Spruce Street) with 3.6 ppb. Overall, theannual average SO2 concentrations ranged from 0.9 to 3.6 ppb in 2013.

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Figure 5-1. Annual Mean SO2 Concentrations Comparison

As illustrated in Figure 5-1, the average annual SO2 concentrations were lower at ten (10) stations in 2014 compared to the sameperiod in 2013. There was an increase at two (2) stations, in 2014 compared to the same period in 2013 and it remained the sameat six (6) stations.

On average, SO2 concentration in 2014 was 1.9 ppb. In 2013, the average SO2 concentration was 2.1 ppb. The largest increasewas observed at STN77012 (Skead) with a 0.3 ppb increase from 2013 to 2014.

0

5

10

15

20

25An

nual

SO2

Aver

age

Con

cent

ratio

n(p

pb)

STATION ID

2013 Annual Mean (ppb)

2014 Annual Mean (ppb)

Annual AAQC Limit (ppb)

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6. ReferencesMinistry of the Environment and Climate Change. Operations Division –Technical Support Section. “Operations Manual for AirQuality Monitoring in Ontario”. March, 2008.

“Vale Limited / Glencore Limited: 2014 First Quarterly Report, SO2 Monitoring Network for Sudbury, January, February & March2014”. May, 2014.

“Vale Limited / Glencore Limited: 2014 Second Quarterly Report, SO2 Monitoring Network for Sudbury, April, May & June 2014”.August, 2014.

“Vale Limited / Glencore Limited: 2014 Third Quarterly Report, SO2 Monitoring Network for Sudbury, July, August & September2014”. November, 2014.

“Vale Limited / Glencore Limited: 2014 Fourth Quarterly Report, SO2 Monitoring Network for Sudbury, October, November &December 2014”. February, 2015.

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Appendix AEquipment Inventory

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Station 77230 Spruce Street January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 0615817071 Thermo Scientific 43i New 1Modem 2ABLX9LF3282 US Robotics 5686 New 1Phone line n/a n/a n/a New 1Electrical power n/a n/a n/a New 1UPS 3B0536X02276 APC ES750BB-CN New 1Instrument rack n/a n/a n/a New 1Desk/chair n/a n/a n/a New 0Cooling System BU199709043Y Comfortaire CA1826ER-A New 1Heating System n/a Dimplex 6010012300 Good 2Shelter 0906-02 Rotek AMS-812 New 1Fire extinguisher 500037 General C-5R Good 1PLC Assembly n/a Allen Bradley Compactlogix New 1Indoor temp. sensor n/a AMPROBE TMA-1 Good 1High Speed Modem 314750002807604701011008 Motorola SB5101N New 1Router C2171G425629 Linksys BEFSR41 New 1Thermostat Honeywell New 1

Station 77025 CKNC Met Tower January 2015

SerialNumber Make Model Condition Quantity Comments

Aerovane, WS WD 81623, 80254 R.M Young 05103 VK Good 2Meteorological tower n/a n/a n/a n/a 1Met. Temperature sen. 11671, 11672 R.M Young 41342VC Good 2Modem 2ABLX9LF3283 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aUPS n/a n/a n/a n/a n/aInstrument rack n/a n/a n/a n/a 1Desk/chair n/a n/a n/a n/a n/aHeating/cooling syst n/a n/a n/a n/a n/aPLC Assembly n/a Allen Bradley Compactlogix Good 1 Installed with upgrade 2006Shelter n/a n/a n/a n/a n/aHigh Speed Modem 166958826410697201012100 Motorola BEFSR41 New 1Router C572B016758 Linksys BEFSR41 New 1

Digital Thermostat

Installed with upgrade 2006Moved over from Ash Street StnCable Modem

New Installed Dec/06Installed with upgrade 2006

Paid by ValeInstalled in 2007Installed with upgrade 2006Desk and chair

688-9342 paid by BESTECH

Equipment

EquipmentReplaced November 2013Owned by CKNC

Rented from CKNC

Replaced November 2013Installed with upgrade 2006673-4948 Paid by BESTECHPart of the rental agreementNo UPSOld 8 footNo desk or chairNo A/C Heated by CKNC

VALE AND SUDBURY INO AQM ASSET LIST AS OF January 2015

VALE ASSETS

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Station 77075 New Sudbury January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 1333159842 Thermo Scientific 43i New 1Modem 2ABLYACE052 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aUPS n/a APC BE750G New 1Instrument rack n/a n/a n/a Good 1Desk/chair n/a n/a n/a Good 1Heating/cooling syst n/a n/a n/a n/a n/aShelter n/a n/a n/a n/a n/aFire extinguisher VU556393 Kidde P340ABC-VB-2 Good 1PLC Assembly n/a Alan Bradley Compactlogix Good 1 Installed with upgrade 2006Indoor temp. sensor n/a Veris TEAJS New 1High Speed Modem 7179365 ZHONE 6211-I2-200 New 1 DSL ModemRouter C2161G117274 Linksys BEFSR41 New 1

Station 77227 Kinsmen January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 0806027502 Thermo Scientific 43i Good 1Vacuum pump n/a n/a n/a n/a 1Modem 2ABLX9LF3281 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a 1UPS n/a APC BE750G New 1Instrument rack CZF197023 Hammond n/a Good 1Desk/chair n/a n/a n/a old 1Cooling System 0808VV00162 Carrier KCA018301P Good 1Heating System n/a Dimplex 6010010300 Good 2Shelter n/a n/a n/a Good 1Fire extinguisher VP-473315 Kidde P340ABC-VB-2 Good 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed with upgrade 2006Indoor temp. sensor n/a AMPROBE TMA-1 Good 1High Speed Modem 314158918615984101011001 Motorola SB5101U New 1Router n/a Linksys BEFSR41 New 1Thermostat Honeywell (digital) New 1

5 footDesk and chair

New December 2009

Installed with upgrade 2006692-5258 Paid by BESTECH100 amp paid by BESTECHInstalled Jan 2014

EquipmentInstalled Vale spare July 2013

Desk onlyNo A/C Heated by Cambrian

Installed Jan 2014

Equipment

Paid by Cambrian College566-3224 Paid by BESTECH

Installed Jan 2014

Installed December 2013Installed with upgrade 2006

Installed November 2014Cable Modem

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Station 77203 Science North January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 0905535060 Thermo Scientific 43i Good 1Modem 2ABLX9LF5437 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aUPS 3B0551X74673 APC BE725B Good 1Instrument rack n/a n/a n/a Good 1Desk/chair n/a n/a n/a Good 1Heating/cooling syst n/a n/a n/a n/a n/aShelter n/a n/a n/a n/a n/aFire extinguisher n/a n/a n/a n/a n/aPLC Assembly n/a Allen Bradley Compactlogix Good 1 Installed with upgrade 2006Glass Manifold n/a n/a n/a Good 1 Inlet glass manifoldIndoor temp. sensor n/a Omega TAC80B-T Good 1High Speed Modem 150758629304107401013031 Motorola SBS101 New 1 Cable ModemRouter C2171G425671 Linksys BEFSR41 New 1

Station 77206 Rayside January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 818330854 Thermo Scientific 43i New 1Modem 2ABLX9LF3285 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aUPS 300835X31698 APC BE-750G-ON Good 1Instrument rack n/a Hammond C2F197023BK1 Good 1Desk/chair n/a n/a n/a Good 1Cooling system 1265900511129150400 Heat Controller, Inc. RAD-123H New 1Heating System n/a Dimplex 6010012300 Good 2 2 baseboard heatersShelter n/a n/a n/a New 1Fire extinguisher H651079C General C-TCP-5J Good 1PLC Assembly n/a Allen Bradley Compactlogix Good 1 Installed with upgrade 2006Indoor temp. sensor n/a Veris TEAJS New 1High Speed Modem 16695826410718401012100 Motorolla SB5101 Good 1 Cable ModemRouter C2181H312281 Linksys BEFSR41 Good 1Thermostat Honeywell New 1 Digital thermostat

installed Nov 2013

Old desk and chairInstalled May 2013

EquipmentReplaced on Sept 11 2008

5 foot

EquipmentInstalled Vale spare July 2013Installed with upgrade 2006522-3665 Paid by BESTECHPaid by Science North

desk. No chairSupplied by Science NorthScience NorthScience North

Installed with upgrade 2006897-5182 Paid by BESTECH100 amp paid by Vale

New Sept 2008

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Station 77218 Copper Cliff January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 1333159844 Thermo Scientific 43i New 1Modem 2ABLX9LF3284 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a 1UPS 4A1349PO5659 APC BE750G New 1Big UPS PPY8X2000002 CyberPower PR1000LCDTXL2Ua New 1 Installed March 2013Instrument rack n/a Rittal n/a Good 1Desk/chair n/a n/a n/a old 1Cooling System BU199844043Y Climette CA1826ER-A New 1Heating System n/a Dimplex 6010012300 Good 2 2 baseboard heatersThermostat n/a Honeywell n/a Good 1 Digital thermostatShelter 0906-01 Rotek AMS-812 Good 1Fire extinguisher VU-556395 Kidde P340ABC-VB-2 Good 1PLC Assembly n/a Allen Bradley Compactlogix n/a 1 Installed with upgrade 2006Indoor temp. sensor n/a AMPROBE TMA-1 Good 1High Speed Modem 14005861250139560203301 Motorola SBS101 New 1 Cable ModemRouter 1 C2171G452636 Linksys BEFSR41 New 1Router 2 P1NK192000156 Dlink DI-604UP Good 1Ethernet Switch DR87394000370 Dlink DSS-5+ Good 1 5 port 10/100 ethernet switch

Station 77225 Kelly Lake January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 834433440 Teco 43i Good 1Modem 2ABLX9LF5436 US Robotics 5686 New 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a New 1 Paid by ValeUPS 4B1330P21250 APC BE750G New 1Instrument rack n/a n/a n/a New 1 Installed with upgrade 2006Desk/chair n/a n/a n/a New 0 Desk and chairCooling System 904TA00250 Comfort Aire RAD-183B New 1Heating System n/a Dimplex n/a Good 2Shelter n/a Rotek n/a New 1 New July 2009Fire extinguisher VU-556394 Kidde P340ABC-VB-2 Good 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed with upgrade 2006Indoor temp. sensor n/a Veris TEAJS New 1High Speed Modem JCIEA3700037V Superlink SL2800 New 1 Cable ModemRouter C2171G425629 Linksys BEFSR41 New 1Thermostat Honeywell New 1 Digital Thermostat

EquipmentInstalled December 2013

Installed with upgrade 2006

Installed with upgrade 2006682-4140 Paid by BESTECH

From old Copper Cliff STN

Installed May 2014

New with shelter

Installed with upgrade 2006

Installed with upgrade 2006

Paid by Vale

Old desk and chair

EquipmentInstalled in March 2010

Installed September 2012

523-6298 Paid by BESTECH

Installed May 2014

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Station 77228 Dozzi Park January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 1215853081 Thermo Scientific 43i Good 1Modem 2ABLY1VF0463 US Robotics Sportster 33.6 New 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a 1UPS 3B0709X01912 APC ES750BB-CN New 1Instrument rack n/a Hammond C2F195623BK1 New 1Desk/chair n/a n/a n/a n/a n/aCooling System EU158523130Y Comfort Aire New 1Heating System n/a Dimplex 6010012300 New 2 Installed with ShelterShelter 0307-04 ROTECK AMS812 New 1Fire extinguisher VU-556396 Kidde P340ABC-VB-2 Good 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed with ShelterBarometer BP 02734 RM Young 61205V Good 1 Installed 2005Indoor temp. sensor n/a AMPROBE TMA-1 Good 1High Speed Modem 140058529215802602031001 Motorola SBS101 New 1 Cable ModemRouter C2171G425648 Linksys BEFSR41 New 1Thermostat Honeywell (digital) New 1

Station 77231 Algonquin January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 1333159843 Thermo Scientific 43i New 1Modem 2ABLY1VF0756 US Robotics Sportster 33.6 New 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a 1UPS 3B0709X01912 APC ES750BB-CN New 1Instrument rack n/a Hammond C2F195623BK1 New 1Desk/chair n/a n/a n/a New 0 Chair onlyCooling System 1265900511130150397 Comfortaire RAD-123H New 1Heating System n/a Dimplex 6010012300 New 2 Installed with ShelterShelter 0307-05 ROTECK AMS58 New 1Fire extinguisher VU-974358 Kidde P340ABC-VB-2 New 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed with upgrade 2006Indoor temp. sensor 06021774 Tsentry Model 140 Good 1High Speed Modem 140058706239990502039001 Motorola SBS101 New 1 Cable ModemRouter C2171G425629 Linksys BEFSR41 New 1Thermostat n/a Honeywell n/a New 1 Digital thermostat

EquipmentVale spare installed March 2013

564-9819 Paid by BESTECH second 564-9774100 amp paid by Vale

Installed with Shelter

522-2142 Paid by BESTECH100 amp paid by BESTECHInstalled with ShelterInstalled with Shelter

New station - 2007Installed with Shelter

Serial number under velcro.

Small desk, no chair

New shelter - 2007

EquipmentInstalled December 2013

Installed with Shelter

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Station 77012 Skead January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 1026444319 Thermo Scientific 43i Good 1Modem 2ABLYAQF0562 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a 1Small UPS 3B0709X01841 APC ES750BB-CN New 1Big UPS G092B25208 EATON 5PX3000RT2U Good 1 3000 VAInstrument rack n/a Hammond C2F195623BK1 New 1Desk/chair n/a n/a n/a Good 1Cooling System EU158204130Y Climette CA1826ER-A New 1Heating System n/a Dimplex 6010012300 New 2Shelter 1007-07 ROTECK AMS812 Good 1Fire extinguisher H651070C General C-TCP-5J Good 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed with upgrade 2006Indoor temp. sensor n/a AMPROBE TMA-1 Good 1High Speed Modem 8632271 Zhone S211-I3-200 Good 1 Cable ModemRouter C572B016758 Linksys BEFSR41 New 1Thermostat Honeywell New 1 Digital Thermostat

Station 77013 Hanmer January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 700319945 Thermo Scientific 43i New 1Modem 2ABLY9GE3698 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a 1Small UPS 3B0709X03793 APC BE750BB-CN New 1Big UPS G092B2504 EATON 5PX3000RT2U Good 1 3000 VAInstrument rack n/a Hammond C2F195623BK1 New 1Desk/chair n/a n/a n/a Good 1Cooling System EU158532130Y Climette CA1826ER-A New 1Heating System n/a Dimplex 6010012300 New 2Shelter 1206-03 ROTECK AMS812 New 1Fire extinguisher YW-971218 Ansul Sentry A05 New 1PLC Assembly n/a Allen Bradley Compactlogix Good 1 Transferred to new shelterIndoor temp. sensor n/a Veris TEAJS New 1High Speed Modem 140058701949675602039001 Motorola SBS101 New 1 Cable ModemRouter C2161G112723 Linksys BEFSR41 New 1Thermostat n/a Honeywell (digital) Good 1 replaced thermostat contactor Nov2013

Installed temp sensor in May 2014

Installed with Shelter

Installed with ShelterInstalled with Shelter

New shelter - December 2006Installed with shelter

Installed with upgrade 2006969-5153 Paid by BESTECH100 amp service paid by Sudbury INOInstalled with Shelter

Small desk and chair

Small desk and chair

Equipment

Equipmentinstalled Sudbury INO spare Nov.2013

Installed with Shelter

Installed with Shelter

100 amp service paid by Sudbury INO

Installed with ShelterInstalled with Shelter

New Shelter - October 2007

Installed with Shelter

Installed with upgrade 2006969-1247 Paid by BESTECH

Sudbury INO ASSETS

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Station 77028 Coniston January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 0806027499 Thermo Scientific 43i Good 1Modem 2ABLYACE1061 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aSmall UPS 380535X10177 APC BE750BB-CN New 1Big UPS G092B25207 EATON 5PX3000RT2U Good 1 3000 VA UPSInstrument rack n/a n/a n/a old 1Desk/chair n/a n/a n/a old 1Cooling System 11635808101061592 Comfort Aire RADS-101G Good 1Heating System n/a n/a n/a Good 2 Unmarked baseboard heatersThermostat n/a Ouellet n/a Good 1 Digital thermostatShelter n/a Pacwill n/a New 1Fire extinguisher H651059C General C-TCP-5J Good 1PLC Assembly n/a Allen Bradley Compactlogix Good 1 Installed with upgrade 2006Indoor temp. sensor n/a AMPROBE TMA-1 Good 1High Speed Modem 140058523033867101021001 Motorola SBS101 New 1 Cable ModemRouter C2171G425476 Linksys BEFSR41 New 1

Station 77065 Garson January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 1018243126 Thermo Scientific 43i New 1Modem 2ABLYATE0749 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aSmall UPS 3B1208X10974 APC BE750G New 1Big UPS G092B25183 EATON 5PX3000ET2U Good 1Instrument rack n/a n/a n/a old 1Desk/chair n/a n/a n/a old 1Cooling System 1163580810106151593 Comfort Aire RADS101G Good 1Heating System n/a n/a n/a n/a 2 Unmarked baseboard heatersThermostat n/a Ouellet n/a Good 1 Digital thermostatShelter n/a Pacwill n/a New 1Fire extinguisher L441052C General C-TCP-5JH Good 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed with upgrade 2006Indoor temp. sensor n/a Veris TEAJS New 1High Speed Modem 355581203414764659550017 Motorola SBG6580 Good 1 Cable ModemRouter C2171G425666 Linksys BEFSR41 New 1

Large desk and blue chair

100 amp service paid by Sudbury INOInstalled August 2012

5 foot

Replaced Feb 2013

Small desk and chair

Installed Sept 2010Serviced yearly

Sudbury INO spare installed Oct.2013

EquipmentInstalled with upgrade Sept 2010Installed with upgrade 2006693-1756 Paid by BESTECH

Equipment

Serviced yearly

5 foot

Installed Sept 2010

100 amp service paid by Sudbury INO750 VA UPS

694-4692 Paid by BESTECHInstalled with upgrade 2006

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Station 77600 Edison January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 1222354209 Thermo Scientific 43i Good 1Modem 2ABLYX9LF7981 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aSmall UPS 3B0746X71371 APC BE750G-CN New 1Big UPS n/a EATON 9130 New 1 Installed in July 2014Instrument rack n/a n/a n/a old 1Desk/chair n/a n/a n/a old 1Cooling System/Heating System F08F02571E Trane PTEE1501UA8A Old 1Shelter n/a n/a n/a old 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed in April 2008Indoor temp. sensor 08016898 Tsentry 140-100HV New 1High Speed Modem 073G4FX1TDN9 Motorola SB5101 New 1 Cable ModemRouter C2181H3122 Linksys BEFSR41 New 1

Station 77601 Parkinson January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 1218153498 Thermo Scientific 43i Good 1Modem 3ABLY2213320 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aSmall UPS 3B0746X67850 APC BE750G-CN New 1Big UPS 1 n/a EATON 9130 Good 1 3000VA replaced July 2014Big UPS 2 n/a EATON 9130 Good 1 3000VAInstrument rack n/a n/a n/a old 1Desk/chair n/a n/a n/a old 1Cooling System/Heating System F05W00481A Trane PTED1C0JCA Old 1Shelter n/a n/a n/a old 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed in April 2008Indoor temp. sensor 08016899 Tsentry 140-100HV New 1High Speed Modem 073G4FX1TF66 Motorola SB5101 New 1 Cable ModemThermostat n/a Honeywell n/a Old 1 Analog thermostatRouter C2181H312199 Linksys BEFSR41 New 1

Installed in April 2008

699-3453 Paid by Sudbury INO

750 VA

EquipmentInstalled November 2013Installed with upgrade 2006

Installed in April 2008

Wooden shelf as desk

EquipmentSudbury INO spare installed Apr.2013Installed with upgrade 2006699-3372 Paid by Sudbury INO

750 VA

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Station 77602 Sunderland January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 806027501 Thermo Scientific 43i Good 1Modem 2ABLYCLD2726 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aSmall UPS 3B0746X73814 APC BE750G-CN New 1Big UPS GE203A0250 EATON 9130 Good 1 3000 VAInstrument rack n/a n/a n/a old 1Desk/chair n/a n/a n/a old 1Cooling System/Heating System A98C02965 Trane PTEC1501GCA old 1Shelter n/a Pacwill n/a New 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed in April 2008Indoor temp. sensor 08016901 Tsentry 140-100HV New 1High Speed Modem 073G4FX1W852 Motorola SB5101 New 1 Cable ModemThermostat n/a Honeywell n/a Good 1 Digital thermostatRouter C2181H312289 Linksys BEFSR41 New 1

Station 77603 Wahnapitae January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 0806027503 Thermo Scientific 43i Good 1Modem 3ABLYCJH4747 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aSmall UPS 3B1229X21248 APC BE750G-CN New 1Big UPS GE321A1210 EATON 9130 Good 1 3000 VAInstrument rack n/a n/a n/a old 1Desk/chair n/a n/a n/a old 1Cooling System/Heating System A01B00485 Trane PTEC1501GCA old 1Shelter n/a n/a n/a old 1PLC Assembly n/a Allen Bradley Compactlogix New 1 Installed in April 2008Indoor temp. sensor 08016900 Tsentry 140-100HV New 1High Speed Modem 073G4FSGN8X3 Motorola SB5101 New 1 Cable ModemRouter C2181H312267 Linksys BEFSR41 New 1

Installed in April 2008

750 VA Replaced October 2013

Installed with upgrade 2006694-5381 Paid by Sudbury INO

Installed in April 2008

EquipmentInstalled May 2013

Installed May 2010

Installed with upgrade 2006693-5013 Paid by Sudbury INO

750 VA

EquipmentInstalled Sudbury INO spare Apr.2013

Page 40: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

Station Glencore Met Tower January 2015

SerialNumber Make Model Condition Quantity Comments

Ultrasonic, WS WD n/a R.M Young 85004 Good 1Meteorological tower n/a n/a n/a n/a 1Met. Temperature sen. n/a R.M Young 41382VC Good 2Solar radiometer na Kipp & Zonen SP lite Good 1Modem 2ABLY7SG2073 US Robotics 5686 Good 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a n/aUPS 5B0751T59507 APC BE650R-CN New 1Desk/chair n/a n/a n/a n/a n/aHeating/cooling syst n/a Trane n/a n/a n/aPLC Assembly n/a Allen Bradley Compactlogix Good 1 Installed in June 08Shelter n/a n/a n/a Good 1High Speed Modem n/a n/a n/a n/a n/a No high speedRouter C2181H312214 Linksys BEFSR41 New 1

Station 77330 Union January 2015

SerialNumber Make Model Condition Quantity Comments

Analyzer 0710321459 Thermo Scientific 43i New 1Modem 2ABLY1VF0439 US Robotics Sportster 33.6 Used 1Phone line n/a n/a n/a n/a 1Electrical power n/a n/a n/a n/a 1UPS 3B1227X25221 APC BE750G New 1Instrument rack n/a Hoffman n/a Used 1Desk/chair n/a n/a n/a n/a n/aCooling System 904TA0000067 Comfort Aire RAD-183B Used 1Heating System n/a Dimplex 6010012300 New 2Shelter n/a Rotek AMS-812 New 1Fire extinguisher VU-556396 Kidde P340ABC-VB-2 New 1PLC Assembly n/a Allen Bradley Compactlogix New 1Indoor temp. sensor n/a Veris TEAJS New 1High Speed Modem 355581219901000702010017 Motorola SBG6580 New 1Router 10820C64212303 Linksys E1200 New 1Thermostat Ouellet (digital) New 1

Installed November 2012Installed November 2012Installed November 2012

Installed November 2012Used brown desk / Grey chairInstalled November 2012

Installed November 2012Installed November 2012

Installed November 2012

Installed November 2012

Installed November 2012

EquipmentInstalled November 2012Installed November 2012682-9838 Paid by BESTECH100 Amp service paid by ValeInstalled November 2012

Installed in June 08Installed in June 08699-3240 Paid by Sudbury INOPaid by Sudbury INOReplaced Mar 19 2009

EquipmentInstalled Oct. 2014

Installed in June 08

Page 41: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

BESTECH OFFICE AQM Spare Parts January 2015

MANUFACTURER DESCRIPTION QTY SERIAL Manufacturer Condition

PART NUMBER 96000-02 40 ftRT0600-20 150 ft2020-2104 12020-2536 52020-2540 52020-2541 52020-3618 12020-5143 22020-2105 14119 78919 114800 10101035-00 1204668 3204668 17 USED8884 1100862-00 18888 1100533-00101411-00 1102029-01 1101024-00 1100T3-S61 1102701-00 2112021-00 2102891-00 14291 2 1 New 1 Used102888-00 2

2Teco 43i 1 818330854Teco 43c 1 515812182 Vale SpareTeco 43c 1 4-58476-316 Vale SpareTeco 43c 1 4-58475-318 Parts Only8774 2CCA4-S316 5CMC44N-S316 2CMC46N-S316 1CPA4-S316 3CTA4-S316 1ACQ108PW 1 MQA1LSB0438ACQ108GPW 1 NM10RS50740

1131 140958

1769-ECR 11

1606-XLP 1CFB11512038 HS 14-40 X 3/8 75 USED24205 2

1CA8600-PM-0001 3G 12/01-F 2650360 2CA8600-PM-0010 3

Tubing ConnectionThermo Scientific S02 AnalyzerSabio Station ToolsPLCTubing Miscellaneous

Tubing 1/8"Tubing 1/4"Purafil (per pound)Fuse, PCB Mount 1A 250VFuse, PCB Mount 4A 250VFuse, PCB Mount 6.3A 250VInlet FilterPump Rebuild Kit, 2020Purakol Charcoal (per pound)Capillary (Red)Capillary (Yellow Blue)Capillary O-RingDC Input Cable to Mother BoardDiaphragm and Valve (no washers)Diaphragm and Valve KitFlash Intensity (Photocell Assembly)Measurement Interface Board AssemblyMirror AssemblyMotherboard AssemblyPermiation OvenPermiation TubePMT High Voltage Power SupplyS02 Analyzer ValveSample Filter Spanner WrenchShock Bumper KitTerminal Board PCB Assembly DB37MScrubber AssemblyTerminal Board PCB Assembly DB37FHandle SetTeco 43iTeco 43cTeco 43cTeco 43cTrigger Board Assembly Teco 43I

1/4 T ConnectionAir ConditionerAir ConditionerAPC Backup UPS 750VAC

Wall Mount Temperature Transmitter24V 3.5A Power SupplyCompact I/OCompact Logix L35EPower SupplyTubeaxial Fan

ThreadlockerPower Cable w/ ground Machine screws w/ lock nuts and bracketsRotary Vane Pump

Machine screws and lock nuts

Saint Gobain

SabioSabioSabioSabioSabioSabioSabio

Thermo ScientificThermo ScientificThermo Scientific

Nova TechThermo ScientificThermo ScientificThermo ScientificThermo ScientificThermo ScientificThermo ScientificThermo Scientific

Thermo ScientificBio Chem-Valve

Thermo ScientificThermo ScientificThermo ScientificThermo ScientificThermo ScientificThermo Scientific

Whirlpool

Thermo ScientificThermo ScientificThermo ScientificThermo Scientific

TEAJSPneonix Contact

Allen BradleyAllen BradleyAllen BradleyCircuit-Test

Loctite

Whirlpool

Thomas Pumps

Honeywell Backup Station Heater

STL Round Combination Machine Screws

Page 42: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

Appendix B Summary of Site Visits & Resolved Issues

Page 43: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for January 2014

The following are the flagged conditions for each station for January 2014.

Vale Sites

Algonquin 77231

January 9, 2014: Monthly calibration from 14:07 – 14:54. 1 invalid hour(s).

Copper Cliff 77218

January 6, 2014: Monthly calibration from 14:46 – 15:40. 1 invalid hour(s).

Dozzi Park 77228

January 21, 2014: Monthly calibration from 11:33 – 12:32. 2 invalid hour(s).

Kelly Lake 77225

January 13, 2014: Monthly calibration from 14:46 – 16:11. 1 invalid hour(s).

Kinsmen 77227

January 13, 2014: Monthly calibration from 13:11 – 14:05. 1 invalid hour(s).

January 24, 2014: Brief negative under range at 20:22. 0 invalid hour(s).

New Sudbury 77075

January 6, 2014: Monthly calibration from 12:46 – 13:42. 1 invalid hour(s).

January 11, 2014 6:18 – January 12, 2014 10:47: Instrument problems followed by servicing and

calibration. 29 invalid hour(s).

January 13, 2014: Servicing from 9:52 – 10:06. 0 invalid hour(s).

Rayside 77206

January 2, 2014: Monthly calibration from 13:48 – 14:52. 1 invalid hour(s).

Science North 77203

January 10, 2014: Power outage from 8:06- 8:25. 1 invalid hour(s).

January 24, 2014: Monthly calibration from 14:32 – 15:25. 2 invalid hour(s).

Spruce St 77230

January 30, 2014: Monthly calibration from 14:58 – 15:52. 1 invalid hour(s).

Union 77330

January 23, 2014: Monthly calibration from 14:54 – 15:47. 1 invalid hour(s).

CKNC Met

DT2

Nothing to report

Page 44: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

TEM1

Nothing to report

TEM3

Nothing to report

WD1

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

January 9, 2014: Monthly calibration from 11:47 – 12:43. 1 invalid hour(s).

Edison 77600

January 23, 2014: Monthly calibration from 10:32 – 12:08. 2 invalid hour(s).

Garson 77065

January 15, 2014: Monthly calibration from 13:03 – 14:04. 1 invalid hour(s).

Hanmer 77013

January 2, 2014: Monthly calibration from 12:01 – 12:59. 1 invalid hour(s).

Parkinson 77601

January 23, 2014: Monthly calibration from 9:16 – 10:14. 1 invalid hour(s).

Skead 77012

January 29, 2014: Monthly calibration from 14:57 – 15:46. 1 invalid hour(s).

Sunderland 77602

January 22, 2014: Monthly calibration from 11:48 – 12:51. 1 invalid hour(s).

Wahnapitae 77603

January 10, 2014: Servicing from 11:01 – 11:41. 1 invalid hour(s).

January 22, 2014: Monthly calibration from 9:58 – 10:59. 1 invalid hour(s).

Xstrata Met

DT2

Nothing to report

TEM1

Nothing to report

Page 45: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

TEM3

Nothing to report

WD

Nothing to report

WS

Nothing to report

Page 46: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for February 2014

The following are the flagged conditions for each station for February 2014.

Vale Sites

Algonquin 77231

February 4, 2014: Monthly calibration from 9:29 – 10:30. 2 invalid hour(s).

Copper Cliff 77218

February 6, 2014: Monthly calibration from 11:20 – 12:22. 2 invalid hour(s).

Dozzi Park 77228

February 12, 2014: Monthly calibration from 11:23 – 12:16. 2 invalid hour(s).

Kelly Lake 77225

February 4, 2014: Monthly calibration from 11:46 – 12:44. 1 invalid hour(s).

February 4, 2014: Brief negative under range at 15:14. 0 invalid hour(s).

Kinsmen 77227

February 3, 2014: Monthly calibration from 14:29 – 15:19. 2 invalid hour(s).

New Sudbury 77075

February 5, 2014: Monthly calibration from 14:32 – 15:30. 2 invalid hour(s).

Rayside 77206

February 10, 2014: Servicing and monthly calibration from 12:58 – 14:09. 1 invalid hour(s).

Science North 77203

February 13, 2014: Monthly calibration from 13:55 – 14:48. 1 invalid hour(s).

Spruce St 77230

February 14, 2014: Monthly calibration from 13:56 – 15:01. 1 invalid hour(s).

Union 77330

February 6, 2014: Monthly calibration from 13:16 – 14:29. 2 invalid hour(s).

CKNC Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD1

Nothing to report

Page 47: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

February 3, 2014: Monthly calibration from 12:46 – 13:35. 1 invalid hour(s).

Edison 77600

February 24, 2014: Monthly calibration from 12:56 – 13:44. 1 invalid hour(s).

Garson 77065

February 14, 2014: Monthly calibration from 12:04 – 13:04. 1 invalid hour(s).

Hanmer 77013

February 11, 2014: Monthly calibration from 10:29 – 11:32. 2 invalid hour(s).

Parkinson 77601

February 19, 2014: Monthly calibration from 13:47 – 14:48. 1 invalid hour(s).

Skead 77012

February 11, 2014: Monthly calibration from 12:21 – 13:13. 1 invalid hour(s).

Sunderland 77602

February 19, 2014: Monthly calibration from 11:02 – 12:08. 1 invalid hour(s).

February 27, 2014 at 4:00 - February 28, 2014 at 7:30: Instrument problems followed by servicing. 28

invalid hour(s).

Wahnapitae 77603

February 18, 2014: Monthly calibration from 10:09 – 11:06. 1 invalid hour(s).

Xstrata Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD

Nothing to report

WS

Nothing to report

Page 48: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for March 2014

The following are the flagged conditions for each station for March 2014.

Vale Sites

Algonquin 77231

March 14, 2014: Monthly calibration from 11:34 – 13:04. 2 invalid hour(s).

March 18, 2014: MOE audit from 13:04 – 13:28. 1 invalid hour(s).

Copper Cliff 77218

March 19, 2014: MOE audit from 12:47 – 13:14. 0 invalid hour(s).

March 21, 2014: Monthly calibration from 8:46 – 9:40. 1 invalid hour(s).

Dozzi Park 77228

March 25, 2014: MOE audit from 12:23 – 12:56. 1 invalid hour(s).

March 27, 2014: Monthly calibration from 13:46 – 14:49. 1 invalid hour(s).

Kelly Lake 77225

March 14, 2014: Monthly calibration from 9:20 – 10:25. 2 invalid hour(s).

March 19, 2014: MOE audit from 10:32 – 10:56. 1 invalid hour(s).

Kinsmen 77227

March 6, 2014: Monthly calibration from 13:10 – 14:35. 2 invalid hour(s).

March 14, 2014: Brief under range from 18:21 and 18:35. 0 invalid hour(s).

March 19, 2014: MOE audit from 11:46 – 12:13. 0 invalid hour(s).

March 28, 2014: Brief under range from 7:11, 7:28 and 8:36. 0 invalid hour(s).

New Sudbury 77075

March 12, 2014: Monthly calibration from 11:03 – 12:09. 1 invalid hour(s).

March 18, 2014: MOE audit from 11:54 – 12:20. 1 invalid hour(s).

March 28, 2014: Servicing from 11:50 – 12:32. 1 invalid hour(s).

Rayside 77206

March 11, 2014: Monthly calibration from 12:54 – 13:58. 1 invalid hour(s).

March 13, 2014: Servicing from 11:28 – 11:53. 1 invalid hour(s).

March 14, 2014: Brief under range at 18:21 and 18:34. 0 invalid hour(s).

March 25, 2014: MOE audit from 10:57 – 11:29. 1 invalid hour(s).

March 28, 2014: Power outage from 7:11 – 7:27 and 7:31 – 8:35. 2 invalid hour(s).

Science North 77203

March 17, 2014: Monthly calibration from 13:32 – 14:24. 2 invalid hour(s).

March 19, 2014: MOE audit from 9:46 – 10:13. 0 invalid hour(s).

Spruce St 77230

March 25, 2014: MOE audit from 13:14 – 13:45. 1 invalid hour(s).

March 27, 2014: Monthly calibration from 8:46 – 10:03. 1 invalid hour(s).

Page 49: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Union 77330

March 13, 2014: Monthly calibration from 12:53 – 13:54. 1 invalid hour(s).

March 26, 2014: MOE audit from 9:13 – 9:44. 1 invalid hour(s).

March 28, 2014: Servicing from 14:21 – 15:10. 1 invalid hour(s).

CKNC Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD1

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

March 17, 2014: Monthly calibration from 11:17 – 12:19. 2 invalid hour(s).

March 18, 2014: MOE audit from 9:27 – 9:56. 1 invalid hour(s).

Edison 77600

March 20, 2014: Monthly calibration from 12:20 – 13:13. 1 invalid hour(s).

March 24, 2014: MOE audit from 9:37 – 10:06. 1 invalid hour(s).

Garson 77065

March 11, 2014: Monthly calibration from 10:25 – 11:20. 2 invalid hour(s).

March 18, 2014: MOE audit from 10:13 – 10:38. 1 invalid hour(s).

Hanmer 77013

March 10, 2014: Monthly calibration from 9:52 – 11:03. 1 invalid hour(s).

March 13, 2014: Servicing from 10:24 – 10:48. 1 invalid hour(s).

March 25, 2014: MOE audit from 9:58 – 10:29. 1 invalid hour(s).

Parkinson 77601

March 20, 2014: Monthly calibration from 10:54 – 11:51. 1 invalid hour(s).

March 24, 2014: MOE audit from 10:25 – 10:57. 1 invalid hour(s).

Skead 77012

March 10, 2014: Monthly calibration from 11:53 – 12:51. 1 invalid hour(s).

Page 50: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

March 26, 2014: MOE audit from 11:02 – 11:35. 1 invalid hour(s).

Sunderland 77602

March 20, 2014: Monthly calibration from 9:04 – 10:13. 1 invalid hour(s).

March 24, 2014: MOE audit from 11:58 – 12:32. 1 invalid hour(s).

Wahnapitae 77603

March 21, 2014: Monthly calibration from 12:46 – 13:44. 1 invalid hour(s).

March 24, 2014: MOE audit from 13:04 – 13:32. 1 invalid hour(s).

Xstrata Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD

Nothing to report

WS

Nothing to report

Page 51: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for April 2014

The following are the flagged conditions for each station for April 2014.

Vale Sites

Algonquin 77231

April 2, 2014: Monthly calibration from 13:02 – 14:03. 1 invalid hour(s).

April 4, 2014: Brief power outage at 6:02. 0 invalid hour(s).

April 7, 2014: Brief power outage from 9:01 – 9:03. 0 invalid hour(s).

April 17, 2014: Servicing from 12:50 – 13:31. 1 invalid hour(s).

Copper Cliff 77218

April 2, 2014: Servicing from 7:55 – 8:26 and 8:33 – 9:09. 1 invalid hour(s).

April 21, April 30, 2014: Monthly calibration from 12:47 – 13:46. 1 invalid hour(s).

Dozzi Park 77228

April 3, 2014: Servicing from 13:56 – 14:22 and 14:25 – 14:36. 1 invalid hour(s).

April 4, 2014: Power outage at 4:36, 4:44 and 5:51 – 7:08 and missing data due to power outage from 7:09

– 7:19. 2 invalid hour(s).

April 5, 2014: Brief power outage from 8:27 – 8:30. 0 invalid hour(s).

April 7, 2014: Brief power outage from 9:01 – 9:04. 0 invalid hour(s).

April 14, 2014: Brief power outage at 11:57. 0 invalid hour(s).

April 14, 2014: Monthly calibration from 12:21 – 13:17. 2 invalid hour(s).

April 14, 2014: Brief power outage from 14:14 – 14:16. 0 invalid hour(s).

April 14, 2014: Brief negative under range at 14:17. 0 invalid hour(s).

April 14, 2014: Brief power outage at 14:18. 0 invalid hour(s).

April 14, 2014: Brief negative under range at 14:19. 0 invalid hour(s).

Kelly Lake 77225

April 4, 2014: Brief power outage at 4:36. 0 invalid hour(s).

April 4, 2014: Brief negative under ranges from 4:37 – 4:38. 0 invalid hour(s).

April 4, 2014: Brief power outage at 4:44. 0 invalid hour(s).

April 4, 2014: Brief negative under ranges at 4:46. 0 invalid hour(s).

April 4, 2014: Brief power outage from 5:51 – 6:52. 1 invalid hour(s).

April 7, 2014: Brief power outage from 9:01 – 9:04. 0 invalid hour(s).

April 7, 2014: Monthly calibration from 13:38 – 14:37. 2 invalid hour(s).

April 24, 2014: Servicing from 9:02 – 9:17, 9:37 – 9:48 and 10:09 – 10:18. 1 invalid hour(s).

Kinsmen 77227

April 4, 2014: Brief negative under ranges at 4:36 – 4:38, 4:46, 5:51 and 12:20. 0 invalid hour(s).

April 5, 2014: Brief negative under range at 1:48, 5:08 and 5:38. 0 invalid hour(s).

April 22, 2014: Servicing from 9:47 – 9:57, 10:22 and 10:32 – 10:54. 1 invalid hour(s).

April 22, 2014: Monthly calibration from 11:18 – 12:17. 2 invalid hour(s).

New Sudbury 77075

April 10, 2014: Monthly calibration from 9:33 – 10:26. 2 invalid hour(s).

Page 52: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Rayside 77206

April 4, 2014: Brief power outage at 4:36. 0 invalid hour(s).

April 4, 2014: Brief negative under ranges at 4:37 – 4:38. 0 invalid hour(s).

April 4, 2014: Brief power outage at 4:44. 0 invalid hour(s).

April 4, 2014: Brief negative under range at 4:46. 0 invalid hour(s).

April 4, 2014: Power outage from 5:51 – 8:22. 3 invalid hour(s).

April 4, 2014: Brief power outage at 10:49. 0 invalid hour(s).

April 4, 2014: Brief negative under range from 10:50 – 10:51. 0 invalid hour(s).

April 8, 2014: Monthly calibration from 8:27 – 9:34. 2 invalid hour(s).

Science North 77203

April 4, 2014: Brief power outage at 4:36. 0 invalid hour(s).

April 4, 2014: Brief negative under ranges at 4:37 – 4:38. 0 invalid hour(s).

April 4, 2014: Brief power outage at 4:44. 0 invalid hour(s).

April 4, 2014: Brief negative under range at 4:46. 0 invalid hour(s).

April 4, 2014: Power outage from 5:51 – 6:52. 1 invalid hour(s).

April 4, 2014: Brief negative under range from 6:53 – 6:54. 0 invalid hour(s).

April 7, 2014: Power outage from 9:01 – 9:04 . 0 invalid hour(s).

April 15, 2014: Monthly calibration from 9:46 – 10:39. 1 invalid hour(s).

April 25, 2014: Servicing from 12:46 – 12:59, 13:13 – 13:22 and 13:53 – 13:59. 1 invalid hour(s).

Spruce St 77230

April 4, 2014: Brief power outage at 4:36, 4:44, 5:51 – 6:12. 0 invalid hour(s).

April 4, 2014: Missing data due to power outage from 6:13 – 6:40. 1 invalid hour(s).

April 4, 2014: Brief power outage at 6:41. 0 invalid hour(s).

April 4, 2014: Brief negative under range at 6:43. 0 invalid hour(s).

April 5, 2014: Brief power outage from 8:27 – 8:28. 0 invalid hour(s).

April 14, 2014: Monthly calibration from 9:40, 9:41 and 9:53 – 11:00. 1 invalid hour(s).

April 15, 2014: Servicing from 11:44 – 12:08. 1 invalid hour(s).

April 21, 2014: Brief power outage at 13:29. 0 invalid hour(s).

Union 77330

April 3, 2014: Monthly calibration from 8:54 – 9:59. 1 invalid hour(s).

April 4, 2014: Power outage at 4:36, 4:44, 4:45, 5:51 – 6:19 and missing data due to power outage from

6:20 – 7:19. 2 invalid hour(s).

April 4, 2014: Brief power outage and negative under range at 7:21 and 7:22. 0 invalid hour(s).

April 5, 2014: Brief power outage from 8:27 – 8:29. 0 invalid hour(s).

April 7, 2014: Brief power outage from 9:01 – 9:03. 0 invalid hour(s).

April 9, 2014: Servicing from 12:56 – 13:12 and 13:17. 0 invalid hour(s).

CKNC Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

Page 53: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

WD1

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

April 1, 2014: Monthly calibration from 13:29 – 14:24. 2 invalid hour(s).

Edison 77600

April 5, 2014: Missing data due to power outage from 5:34 – 7:38. 3 invalid hour(s).

April 16, 2014: Monthly calibration from 13:08 – 14:10. 1 invalid hour(s).

Garson 77065

April 5, 2014: Brief negative under range at 7:06. 0 invalid hour(s).

April 10, 2014: Monthly calibration from 11:30 – 12:29. 2 invalid hour(s).

Hanmer 77013

April 3, 2014: Monthly calibration from 11:03 – 12:11. 1 invalid hour(s).

Parkinson 77601

April 5, 2014: Brief negative under range at 5:33 and 7:17. 0 invalid hour(s).

April 5, 2014: Servicing due to power outage from 7:20 – 7:51. 1 invalid hour(s).

April 16, 2014: Monthly calibration from 11:28 – 12:35. 2 invalid hour(s).

Skead 77012

April 5, 2014: Missing data due to power outage from 6:40 – 7:05. 1 invalid hour(s).

April 5, 2014: Brief negative under range at 7:06. 0 invalid hour(s).

April 8, 2014: Monthly calibration from 11:12 – 12:05. 1 invalid hour(s).

Sunderland 77602

April 5, 2014: Missing data due to power outage from 2:56 – 4:46. 2 invalid hour(s).

April 5, 2014: Brief negative under range from 8:00 – 8:01. 0 invalid hour(s).

April 16, 2014: Monthly calibration from 8:50 – 9:48. 1 invalid hour(s).

Wahnapitae 77603

April 17, 2014: SO2 analyzer was swapped out with spare calibrated instrument from 8:53 – 9:20. 1

invalid hour(s).

April 17, 2014: Servicing from 18:51 – 19:03. 0 invalid hour(s).

April 29, 2014: Servicing from 14:04 – 14:18. 0 invalid hour(s).

Xstrata Met

Page 54: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD

Nothing to report

WS

Nothing to report

Page 55: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for May 2014

The following are the flagged conditions for each station for May 2014.

Vale Sites

Algonquin 77231

May 7, 2014: Monthly calibration from 11:10 – 12:16. 2 invalid hour(s).

May 23, 2014: Power outage from 9:04 – 9:22. 1 invalid hour(s).

May 26, 2014: Servicing from 10:26 – 10:40. 0 invalid hour(s).

Copper Cliff 77218

May 16, 2014: Monthly calibration from 12:27 – 13:22. 2 invalid hour(s).

May 26, 2014: Servicing from 09:45 – 10:05. 0 invalid hour(s).

Dozzi Park 77228

May 12, 2014: Monthly calibration from 12:06 – 13:11. 1 invalid hour(s).

Kelly Lake 77225

May 7, 2014: Brief power outage at 13:58. 0 invalid hour(s).

May 13, 2014: Monthly calibration from 9:57 – 10:47. 1 invalid hour(s).

May 18, 2014: Brief power outage from 6:33 – 6:45. 0 invalid hour(s).

May 23, 2014: Power outage from 9:04 – 9:22. 1 invalid hour(s).

Kinsmen 77227

May 2, 2014: Annual instrument preventative maintenance and monthly calibration from 10:47 – 11:21,

13:19 – 13:39 and 19:08 – 19:18. 2 invalid hour(s).

New Sudbury 77075

May 14, 2014: Monthly calibration from 9:05 – 10:12. 1 invalid hour(s).

Rayside 77206

May 6, 2014: Monthly calibration from 11:02 – 12:13. 1 invalid hour(s).

May 30, 2014: Annual instrument preventative maintenance from 9:29 – 9:54 and 11:51 – 12:07. 1 invalid

hour(s).

Science North 77203

May 14, 2014: Monthly calibration from 11:06 – 12:11. 1 invalid hour(s).

May 23, 2014: Power outage from 9:04 – 9:22. 1 invalid hour(s).

Spruce St 77230

May 16, 2014: Monthly calibration from 10:46 – 11:47. 1 invalid hour(s).

May 18, 2014: Brief power outage from 6:33 – 6:46. 0 invalid hour(s).

May 22, 2014: Servicing from 10:16 – 10:21. 0 invalid hour(s).

May 23, 2014: Brief power outage at 8:50. 0 invalid hour(s).

Union 77330

May 23, 2014: Monthly calibration from 13:10- 14:18. 2 invalid hour(s).

Page 56: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

CKNC Met

DT2

May 15, 2014: Instrument problems from 5:43 – 10:50. 6 invalid hour(s).

May 15, 2014: Servicing from 10:51 – 11:06. 0 invalid hour(s).

May 15, 2014 at 11:07 to May 19, 2014 at 3:34: Instrument problems. 89 invalid hour(s).

TEM1

May 15, 2014: Servicing from 10:51 – 11:06. 0 invalid hour(s).

TEM3

May 15, 2014: Instrument problems from 5:43 – 10:50. 6 invalid hour(s).

May 15, 2014: Servicing from 10:51 – 11:06. 0 invalid hour(s).

May 15, 2014 at 11:07 to May 19, 2014 at 3:34: Instrument problems. 89 invalid hour(s).

WD1

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

May 7, 2014: Monthly calibration from 9:10 – 10:19. 2 invalid hour(s).

May 15, 2014: Servicing and calibration from 8:46 – 9:47. 1 invalid hour(s).

May 26, 2014: Servicing from 11:06 – 11:20. 0 invalid hour(s).

May 29, 2014: Annual instrument preventative maintenance from 8:09 – 8:36, 10:35 – 11:02, 11:10, and

11:12 – 11:16. 2 invalid hour(s).

Edison 77600

May 21, 2014: Servicing from 8:13 – 8:38. 1 invalid hour(s).

May 21, 2014: Monthly calibration from 9:46 – 10:40. 1 invalid hour(s).

Garson 77065

May 9, 2014: Monthly calibration from 10:30 – 11:41. 2 invalid hour(s).

Hanmer 77013

May 5, 2014: Annual instrument preventative maintenance and monthly calibration from 10:15 – 10:46

and 12:29 – 12:47. 2 invalid hour(s).

Parkinson 77601

Page 57: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

May 20, 2014: Servicing and monthly calibration from 12:14 – 12:31, 13:01 – 13:02 and 13:26 – 14:13. 2

invalid hour(s).

Skead 77012

May 12, 2014: Monthly calibration from 9:48 – 10:45. 1 invalid hour(s).

Sunderland 77602

May 21, 2014: Servicing and monthly calibration from 12:19 – 13:13 and 13:18 – 14:28. 3 invalid hour(s).

Wahnapitae 77603

May 20, 2014: Monthly calibration from 8:32 – 9:33. 2 invalid hour(s).

Xstrata Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD

Nothing to report

WS

Nothing to report

Page 58: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for June 2014

The following are the flagged conditions for each station for June 2014.

Vale Sites

Algonquin 77231

June 11, 2014: Monthly calibration from 13:30 – 15:34. 3 invalid hour(s).

June 17, 2014: Government audit from 10:53 – 11:25. 1 invalid hour(s).

Copper Cliff 77218

June 19, 2014: Government audit from 09:21 – 09:43. 1 invalid hour(s).

June 30, 2014: Monthly calibration from 09:47 – 10:46. 1 invalid hour(s).

Dozzi Park 77228

June 02, 2014: Brief negative under range from 18:47 – 18:49. 0 invalid hour(s).

June 12, 2014: Monthly calibration from 11:46 – 12:46. 1 invalid hour(s).

June 18, 2014: Government audit from 11:50 – 12:22. 1 invalid hour(s).

Kelly Lake 77225

June 02, 2014: Brief negative under range from 18:47 – 18:48. 0 invalid hour(s).

June 03, 2014: Annual instrument preventative maintenance from 12:27 – 13:07 and 14:25 – 14:35. 1

invalid hour(s).

June 17, 2014: Government audit from 11:55 – 12:30. 1 invalid hour(s).

Kinsmen 77227

June 03, 2014: Monthly calibration from 09:24 – 10:25. 2 invalid hour(s).

June 17, 2014: Government audit from 12:52 – 13:21. 1 invalid hour(s).

New Sudbury 77075

June 04, 2014: Monthly calibration from 12:09 – 13:16. 2 invalid hour(s).

June 17, 2014: Government audit from 09:46 – 10:11. 0 invalid hour(s).

June 23, 2014: Brief power outage at 10:02. 0 invalid hour(s).

Rayside 77206

June 09, 2014: Monthly calibration from 13:49 – 14:49. 1 invalid hour(s).

June 18, 2014: Government audit from 09:46 – 10:15. 1 invalid hour(s).

Science North 77203

June 02, 2014: Brief negative under range from 18:47 – 18:48. 0 invalid hour(s).

June 18, 2014: Government audit from 12:46 – 13:13. 0 invalid hour(s).

June 27, 2014: Monthly calibration from 09:48 – 10:45. 1 invalid hour(s).

Spruce St 77230

June 12, 2014: Monthly calibration from 13:33 – 14:34. 2 invalid hour(s).

June 18, 2014: Government audit from 10:46 – 11:21. 1 invalid hour(s).

June 26, 2014: Brief negative under range at 10:57. 0 invalid hour(s).

Page 59: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Union 77330

June 19, 2014: Government audit from 09:50 – 10:16. 1 invalid hour(s).

June 25, 2014: Monthly calibration from 13:30 – 14:38. 2 invalid hour(s).

CKNC Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD1

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

June 06, 2014: Servicing due to faulty permeation temperature sensor from 06:34 – 08:41. 3 invalid

hour(s).

June 10, 2014: Servicing due to installing repaired SO2 analyzer from 13:23 – 14:12. 1 invalid hour(s).

June 10, 2014 at 14:12 to June 16, 2014 at 09:46: Hourly data during this time was edited down 12% due

to government audit being 12% high and not meeting criteria. All data remains the same after editing. 0

invalid hour(s).

June 16, 2014: Government audit from 09:46 – 10:48. 1 invalid hour(s).

June 17, 2014: Monthly calibration from 13:26 – 14:15. 2 invalid hour(s).

Edison 77600

June 08, 2014: Brief negative under range from 06:30 – 06:31 and 10:22. 0 invalid hour(s).

June 13, 2014: Government audit from 12:40 – 13:21. 2 invalid hour(s).

June 24, 2014: Monthly calibration from 12:15 – 13:10. 1 invalid hour(s).

Garson 77065

June 08, 2014: Brief negative under range at 09:51. 0 invalid hour(s).

June 11, 2014: Monthly calibration from 09:30 – 10:42. 2 invalid hour(s).

June 16, 2014: Government audit from 11:05 – 11:29. 1 invalid hour(s).

June 17, 2014: Servicing due to re-calibration / testing calibrator from 11:56 – 12:44. 1 invalid hour(s).

Hanmer 77013

June 04, 2014: Monthly calibration from 9:52 – 11:02. 1 invalid hour(s).

Page 60: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

June 16, 2014: Government audit from 12:52 – 13:21. 1 invalid hour(s).

Parkinson 77601

June 08, 2014: Brief negative under range at 06:49 and 10:11. 0 invalid hours.

June 13, 2014: Government audit from 11:40 – 12:22. 2 invalid hour(s).

June 24, 2014: Monthly calibration from 10:50 – 11:51. 1 invalid hour(s).

Skead 77012

June 11, 2014: Monthly calibration from 11:20 – 12:19. 2 invalid hour(s).

June 16, 2014: Government audit from 11:55 – 12:26. 1 invalid hour(s).

June 27, 2014: Servicing SO2 analyzer from 12:00 – 12:25 and 12:36 – 12:50. 1 invalid hour(s).

Sunderland 77602

June 04, 2014 at 03:11 to June 05, 2014 at 09:33: Data is invalid due to instrument I/O board failure. 31

invalid hour(s).

June 08, 2014: Brief negative under range at 07:00, 07:03 – 07:04, and 07:14. 0 invalid hour(s).

June 13, 2014: Government audit from 09:47 – 10:22. 1 invalid hour(s).

June 25, 2014: Monthly calibration from 08:46 – 09:48. 1 invalid hour(s).

Wahnapitae 77603

June 09, 2014: Government audit from 09:38 – 10:14. 1 invalid hour(s).

June 24, 2014: Monthly calibration from 08:51 – 09:46. 1 invalid hour(s).

Xstrata Met

DT2

June 15, 2014: Power outage from 06:00 – 18:10. 12 invalid hour(s).

TEM1

June 15, 2014: Power outage from 06:00 – 18:10. 12 invalid hour(s).

TEM3

June 15, 2014: Power outage from 06:00 – 18:10. 12 invalid hour(s).

WD

June 15, 2014: Power outage from 06:00 – 18:10. 12 invalid hour(s).

WS

June 15, 2014: Power outage from 06:00 – 18:10. 12 invalid hour(s).

Page 61: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for July 2014

The following are the flagged conditions for each station for July 2014.

Vale Sites

Algonquin 77231

July 08, 2014: Monthly calibration from 12:19 – 13:15. 2 invalid hour(s).

Copper Cliff 77218

July 18, 2014: Monthly calibration from 12:53 – 13:55. 1 invalid hour(s).

Dozzi Park 77228

July 21, 2014: Monthly calibration from 11:27 – 12:23. 2 invalid hour(s).

Kelly Lake 77225

July 18, 2014: Monthly calibration from 10:46 – 11:47. 1 invalid hour(s).

hour(s).

Kinsmen 77227

July 07, 2014: Monthly calibration from 12:51 – 13:41. 1 invalid hour(s).

New Sudbury 77075

July 21, 2014: Monthly calibration from 8:50 – 9:54. 1 invalid hour(s).

Rayside 77206

July 04, 2014: Monthly calibration from 13:10 – 13:59. 1 invalid hour(s).

Science North 77203

July 22, 2014: Monthly calibration from 12:04 – 13:02. 1 invalid hour(s).

Spruce St 77230

July 22, 2014: Monthly calibration from 9:58 – 11:00. 1 invalid hour(s).

July 24, 2014: Servicing from 12:16 – 14:59. 3 invalid hour(s).

Union 77330

July 21, 2014: Monthly calibration from 13:30 – 15:02. 2 invalid hour(s).

CKNC Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD1

Page 62: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

July 08, 2014: Monthly calibration from 10:07 – 11:03. 1 invalid hour(s).

Edison 77600

July 16, 2014: Monthly calibration and servicing from 12:18 – 13:44. 2 invalid hour(s).

Garson 77065

July 09, 2014: Servicing from 12:22 – 12:33 and 13:15 – 13:32. 1 invalid hour(s).

July 14, 2014: Servicing and monthly calibration from 6:34 – 7:38. 2 invalid hour(s).

July 15, 2014: Servicing from 15:17 – 15:27. 0 invalid hour(s).

Hanmer 77013

July 02, 2014: Servicing from 11:55 – 12:09 and 12:19 – 12:47. 1 invalid hour(s).

July 04, 2014: Monthly calibration from 11:29 – 12:29. 2 invalid hour(s).

Parkinson 77601

July 16, 2014: Monthly calibration and servicing from 10:16 – 11:24. 2 invalid hour(s).

Skead 77012

July 17, 2014: Annual instrument preventative maintenance from 11:46 – 12:15 and 13:53 – 14:14. 1

invalid hour(s).

July 17, 2014 at 14:15 – July 18, 2014 at 5:33: Instrument problems. Servicing from 5:34 – 6:33. 17

invalid hour(s)

Sunderland 77602

July 16, 2014: Monthly calibration from 08:49 – 9:49. 1 invalid hour(s).

July 27, 2014: Servicing from 11:50 and 11:54 – 12:16. 1 invalid hour(s).

Wahnapitae 77603

July 1, 2014: Brief negative under range at 13:20 and 22:46. 0 invalid hour(s).

July 15, 2014: Servicing and monthly calibration from 8:32 – 10:30. 3 invalid hour(s).

Xstrata Met

DT2

July 29, 2014: Brief positive over range at 15:33. 0 invalid hour(s).

Page 63: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

TEM1

Nothing to report

TEM3

July 29, 2014: Brief positive over range at 15:33. 0 invalid hour(s).

WD

Nothing to report

WS

Nothing to report

Page 64: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for August 2014

The following are the flagged conditions for each station for August 2014.

Vale Sites

Algonquin 77231

August 12, 2014: Monthly calibration from 13:26 – 14:25. 2 invalid hour(s).

Copper Cliff 77218

August 26, 2014: Monthly calibration from 10:46 – 11:47. 1 invalid hour(s).

Dozzi Park 77228

August 20, 2014: Monthly calibration from 13:50 – 14:49. 1 invalid hour(s).

Kelly Lake 77225

August 20, 2014: Monthly calibration from 12:06 – 13:04. 1 invalid hour(s).

Kinsmen 77227

August 26, 2014: Monthly calibration from 13:13 – 14:20. 2 invalid hour(s).

August 30, 2014: Brief negative under range at 1:42 and 22:46. 0 invalid hour(s).

New Sudbury 77075

August 14, 2014: Monthly calibration from 11:46 – 12:45. 1 invalid hour(s).

Rayside 77206

August 13, 2014: Monthly calibration from 13:47 – 14:39. 1 invalid hour(s).

August 30, 2014: Brief negative under range at 1:42. 0 invalid hour(s).

August 30, 2014: Power outage from 21:17 – 23:37. 3 invalid hour(s).

August 31, 2014: Power outage from 1:50 – 2:25. 1 invalid hour(s).

Science North 77203

August 4, 2014: Brief negative under range at 5:59. 0 invalid hour(s).

August 29, 2014: Monthly calibration from 11:17 – 12:08. 1 invalid hour(s).

August 30, 2014: Brief negative under range at 1:54. 0 invalid hour(s).

Spruce St 77230

August 28, 2014: Monthly calibration from 8:11 – 9:17. 2 invalid hour(s).

Union 77330

August 28, 2014: Monthly calibration from 10:11 – 11:14. 1 invalid hour(s).

CKNC Met

DT2

Nothing to report

TEM1

Page 65: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Nothing to report

TEM3

Nothing to report

WD1

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

August 12, 2014: Monthly calibration from 11:26 – 12:33. 2 invalid hour(s).

Edison 77600

August 25, 2014: Monthly calibration from 12:28 – 13:22. 2 invalid hour(s).

Garson 77065

August 14, 2014: monthly calibration from 13:21 – 14:19. 2 invalid hour(s).

Hanmer 77013

August 13, 2014: Monthly calibration from 11:47 – 12:43. 1 invalid hour(s).

Parkinson 77601

August 19, 2014: Monthly calibration from 10:55 – 11:56. 1 invalid hour(s).

Skead 77012

August 22, 2014: Monthly calibration from 13:11 – 14:00. 1 invalid hour(s).

Sunderland 77602

August 25, 2014: Brief negative under range at 10:20 and 10:21. 0 invalid hour(s).

August 25, 2014: Monthly calibration from 10:48 – 11:50. 1 invalid hour(s).

Wahnapitae 77603

August 19, 2014: Monthly calibration from 8:52 – 9:55. 1 invalid hour(s).

Xstrata Met

DT2

August 6, 2014: Brief power outage at 12:32. 0 invalid hour(s).

August 11, 2014: Brief power outage at 12:51. 0 invalid hour(s).

August 30, 2014: Power outage from 2:35 – 3:10. 1 invalid hour(s).

Page 66: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

TEM1

August 6, 2014: Brief power outage at 12:32. 0 invalid hour(s).

August 11, 2014: Brief power outage at 12:51. 0 invalid hour(s).

August 30, 2014: Power outage from 2:35 – 3:10. 1 invalid hour(s).

TEM3

August 6, 2014: Brief power outage at 12:32. 0 invalid hour(s).

August 11, 2014: Brief power outage at 12:51. 0 invalid hour(s).

August 30, 2014: Power outage from 2:35 – 3:10. 1 invalid hour(s).

WD

August 6, 2014: Brief power outage at 12:32. 0 invalid hour(s).

August 11, 2014: Brief power outage at 12:51. 0 invalid hour(s).

August 30, 2014: Power outage from 2:35 – 3:10. 1 invalid hour(s).

WS

August 6, 2014: Brief power outage at 12:32. 0 invalid hour(s).

August 11, 2014: Brief power outage at 12:51. 0 invalid hour(s).

August 30, 2014: Power outage from 2:35 – 3:10. 1 invalid hour(s).

Page 67: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for September 2014

The following are the flagged conditions for each station for September 2014.

Vale Sites

Algonquin 77231

September 3, 2014: Monthly calibration from 12:56 – 14:00. 1 invalid hour(s).

September 8, 2014: Government audit from 10:47 – 11:16. 1 invalid hour(s).

Copper Cliff 77218

September 9, 2014: Monthly calibration from 13:32 – 14:31. 2 invalid hour(s).

September 12, 2014: Government audit from 9:11 – 9:44. 1 invalid hour(s).

Dozzi Park 77228

September 10, 2014: Government audit from 11:08 – 11:44. 1 invalid hour(s).

September 29, 2014: Annual preventative maintenance and monthly calibration from 9:50 – 10:14 and

12:24 – 12:42. 1 invalid hour(s).

Kelly Lake 77225

September 8, 2014: Government audit from 11:50 – 12:20. 1 invalid hour(s).

September 15, 2014: Monthly calibration from 13:17 – 14:20. 2 invalid hour(s).

Kinsmen 77227

September 4, 2014: Monthly calibration from 13:23 – 14:20. 2 invalid hour(s).

September 8, 2014: Government audit from 12:53 – 13:18. 1 invalid hour(s).

New Sudbury 77075

September 10, 2014: Government audit from 9:50 – 10:23. 1 invalid hour(s).

September 19, 2014: Monthly calibration from 11:48 – 12:39. 1 invalid hour(s).

Rayside 77206

September 5, 2014: Monthly calibration from 12:13 – 13:08. 1 invalid hour(s).

September 11, 2014: Government audit from 13:12 – 13:39. 1 invalid hour(s).

Science North 77203

September 10, 2014: Government audit from 12:25 – 12:58. 1 invalid hour(s).

September 25, 2014: Monthly calibration from 9:40 – 10:31. 2 invalid hour(s).

Spruce St 77230

September 10, 2014: Government audit from 13:18 – 13:39. 1 invalid hour(s).

September 26, 2014: Monthly calibration from 10:19 – 11:26. 2 invalid hour(s).

Union 77330

September 4, 2014: Servicing and calibration from 10:58 – 12:29. 2 invalid hour(s).

September 12, 2014: Government audit from 10:46 – 11:16. 1 invalid hour(s).

September 12, 2014: Monthly calibration from 13:28 – 14:42. 2 invalid hour(s).

September 26, 2014: Power outage from 4:02 – 5:04. Missing data from 4:30 – 5:03. 1 invalid hour(s).

Page 68: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

CKNC Met

DT2

September 11, 2014: Invalid range due to TEM3 instrument problems from 1:22 – 13:00. 12 invalid

hour(s).

TEM1

Nothing to report

TEM3

September 11, 2014: Instrument problems from 1:22 – 13:00. 12 invalid hour(s).

WD1

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

September 3, 2014: Monthly calibration from 10:51 – 11:55. 1 invalid hour(s).

September 8, 2014: Government audit from 9:45 – 10:12. 0 invalid hour(s).

Edison 77600

September 17, 2014: Government audit from 12:13 – 12:41. 1 invalid hour(s).

September 24, 2014: Monthly calibration from 12:11 – 13:06. 1 invalid hour(s).

Garson 77065

September 5, 2014: Monthly calibration from 9:50 – 10:56. 1 invalid hour(s).

September 11, 2014: Government audit from 9:48 – 10:24. 1 invalid hour(s).

Hanmer 77013

September 11, 2014: Government audit from 12:16 – 12:43. 1 invalid hour(s).

September 15, 2014: Monthly calibration from 10:47 – 11:40. 1 invalid hour(s).

Parkinson 77601

September 22, 2014: Government audit from 12:02 – 12:34. 1 invalid hour(s).

September 24, 2014: Monthly calibration from 9:47 – 10:47. 1 invalid hour(s).

Page 69: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Skead 77012

September 11, 2014: Government audit from 11:14 – 11:52. 1 invalid hour(s).

September 16, 2014: Monthly calibration from 10:25 – 11:18. 2 invalid hour(s).

Sunderland 77602

September 17, 2014: Government audit from 11:17 – 11:53. 1 invalid hour(s).

September 23, 2014: Monthly calibration from 11:38 – 12:50. 2 invalid hour(s).

September 30, 2014: Brief negative under range at 9:26 and 9:30. 0 invalid hour(s).

Wahnapitae 77603

September 17, 2014: Government audit from 9:55 – 10:28. 1 invalid hour(s).

September 23, 2014: Monthly calibration from 9:28 – 10:24. 2 invalid hour(s).

Xstrata Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD

Nothing to report

WS

Nothing to report

Page 70: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for October 2014

The following are the flagged conditions for each station for October 2014.

Vale Sites

Algonquin 77231

October 2, 2014: Monthly calibration from 12:52 – 13:56. 1 invalid hour(s).

Copper Cliff 77218

October 6, 2014: Monthly calibration from 12:26 – 13:27. 2 invalid hour(s).

Dozzi Park 77228

October 16, 2014: Monthly calibration from 13:13 – 14:16. 2 invalid hour(s).

Kelly Lake 77225

October 17, 2014: Monthly calibration from 10:54 – 11:56. 1 invalid hour(s).

Kinsmen 77227

October 6, 2014: Monthly calibration from 10:18 – 11:20. 2 invalid hour(s).

New Sudbury 77075

October 3, 2014: Monthly calibration from 11:46 – 12:41. 1 invalid hour(s).

Rayside 77206

October 1, 2014: Monthly calibration from 12:46 – 13:49. 1 invalid hour(s).

October 5, 2014: Instrument problems and servicing from 00:38 – 4:43. 5 invalid hour(s).

October 7, 2014: Servicing from 9:18 – 10:04. 1 invalid hour(s).

October 15, 2014: Servicing and calibration from 8:27 – 9:33, 9:43 – 9:49 and 11:06 – 11:26. 3 invalid

hour(s).

Science North 77203

October 27, 2014: Monthly calibration from 11:46 – 12:39. 1 invalid hour(s).

Spruce St 77230

October 27, 2014: Monthly calibration from 13:30 – 14:32. 2 invalid hour(s).

Union 77330

October 7, 2014: Annual preventative maintenance and monthly calibration from 11:33 – 12:00 and 14:09

– 14:32. 2 invalid hour(s).

October 8, 2014: Servicing from 15:20 – 15:28. 0 invalid hour(s).

October 23, 2014: Brief negative under range at 10:07. 0 invalid hour(s).

October 23, 2014: Servicing from 11:17 – 11:24. 0 invalid hour(s).

Page 71: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

CKNC Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD1

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

October 2, 2014: Monthly calibration from 11:03 – 12:00. 1 invalid hour(s).

Edison 77600

October 24, 2014: Monthly calibration from 9:46 – 10:47. 1 invalid hour(s).

Garson 77065

October 8, 2014: Annual preventative maintenance and monthly calibration from 11:51 – 12:24 and 14:21

– 14:36. 2 invalid hour(s).

Hanmer 77013

October 1, 2014: Monthly calibration from 10:47 – 11:42. 1 invalid hour(s).

Parkinson 77601

October 24, 2014: Monthly calibration from 12:21 – 13:22. 2 invalid hour(s).

Skead 77012

October 8, 2014: Servicing and monthly calibration from 10:01 – 11:22. 2 invalid hour(s).

Sunderland 77602

October 22, 2014: Monthly calibration from 11:38 – 12:50. 2 invalid hour(s).

Wahnapitae 77603

October 22, 2014: Monthly calibration from 8:58 – 10:09. 1 invalid hour(s).

Page 72: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Xstrata Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD

Nothing to report

WS

Nothing to report

Page 73: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for November 2014

The following are the flagged conditions for each station for November 2014.

Vale Sites

Algonquin 77231

November 6, 2014: Monthly calibration from 14:30 – 15:37. 2 invalid hour(s).

Copper Cliff 77218

November 25, 2014: Monthly calibration from 14:09 – 15:11. 1 invalid hour(s).

Dozzi Park 77228

November 9, 2014: Power outage from 10:40 – 11:32. 2 invalid hour(s).

November 17, 2014: Monthly calibration from 15:49 – 16:48. 1 invalid hour(s).

Kelly Lake 77225

November 4, 2014: Power outage from 23:05 – November 5, 2014 at 00:06. 1 invalid hour(s).

November 5, 2014: Power outage from 1:46 – 3:32. 2 invalid hours(s).

November 12, 2014: Monthly calibration from 13:55 – 14:53 . 1 invalid hour(s).

Kinsmen 77227

November 12, 2014: Monthly calibration from 11:11 – 12:10. 1 invalid hour(s).

New Sudbury 77075

November 14, 2014: Monthly calibration from 14:17 – 15:21. 2 invalid hour(s).

November 25, 2014: Power outage from 13:23 – 14:01. 1 invalid hours(s).

Rayside 77206

November 11, 2014: Monthly calibration from 14:08 – 15:06. 1 invalid hour(s).

Science North 77203

November 10, 2014: Monthly calibration from 14:32 – 15:32. 2 invalid hour(s).

Spruce St 77230

November 28, 2014: Monthly calibration from 13:54 – 14:53. 1 invalid hour(s).

Union 77330

November 6, 2014: Power outage from 13:42 – 13:50. 0 invalid hour(s).

November 27, 2014: Monthly calibration from 13:31 – 14:35. 2 invalid hour(s).

CKNC Met

DT2

November 24, 2014: Positive over range from 22:47 – 23:07 and 23:12 – 23:14. 0 invalid hour(s).

November 24, 2014 at 22:00 – November 25, 2014 at 4:59: Instrument problems. 7 invalid hour(s).

November 29, 2014 at 17:00 – November 30, 2014 at 20:59: Instrument problems. 28 invalid hour(s).

Page 74: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

TEM1

Nothing to report

TEM3

November 24, 2014: Positive over range from 22:47 – 23:07 and 23:12 – 23:14. 0 invalid hour(s).

November 24, 2014 at 22:00 – November 25, 2014 at 4:59: Instrument problems. 7 invalid hour(s).

November 29, 2014 at 17:00 – November 30, 2014 at 20:59: Instrument problems. 28 invalid hour(s).

WD1

Nothing to report

WD3

November 24, 2014: Positive over range from 14:31 – 14:32. 0 invalid hour(s).

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

November 6, 2014: Monthly calibration from 12:53 – 13:54. 1 invalid hour(s).

Edison 77600

November 19, 2014: Monthly calibration from 13:54 – 14:48. 1 invalid hour(s).

Garson 77065

November 13, 2014: Monthly calibration from 14:20 – 15:19. 2 invalid hour(s).

Hanmer 77013

November 11, 2014: Monthly calibration from 12:13 – 13:10. 1 invalid hour(s).

Parkinson 77601

November 19, 2014: Servicing from 12:39 – 12:57. 1 invalid hour(s).

November 19, 2014 at 12:58 – November 21, 2014 at 4:49: Instrument problems. 40 invalid hour(s).

November 21, 2014: Servicing from 4:50 – 5:11 and 9:57 – 12:24. 3 invalid hour(s).

Skead 77012

November 14, 2014: Monthly calibration from 11:54 – 12:53. 1 invalid hour(s).

Sunderland 77602

Page 75: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

November 19, 2014: Monthly calibration from 10:48 – 12:03. 1 invalid hour(s).

Wahnapitae 77603

November 20, 2014: Monthly calibration from 10:53 – 12:00. 1 invalid hour(s).

Xstrata Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD

Nothing to report

WS

Nothing to report

Page 76: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Data Editing for December 2014

The following are the flagged conditions for each station for December 2014.

Vale Sites

Algonquin 77231

December 1, 2014: Monthly calibration from 11:28 – 12:31. 2 invalid hour(s).

December 8, 2014: Government audit from 11:13 – 11:42. 1 invalid hour(s).

Copper Cliff 77218

December 11, 2014: Servicing from 5:57 – 6:06. 0 invalid hour(s).

December 12, 2014: Government audit from 10:20 – 10:45. 1 invalid hour(s).

December 18, 2014: Monthly calibration from 11:58 – 13:14. 1 invalid hour(s).

Dozzi Park 77228

December 8, 2014: Government audit from 12:56 – 13:30. 1 invalid hour(s).

December 15, 2014: Servicing from 14:24 – 15:03. 1 invalid hour(s).

December 19, 2014: Monthly calibration from 9:40 – 10:53. 2 invalid hour(s).

Kelly Lake

December 5, 2014: Monthly calibration from 11:57 – 13:18 . 2 invalid hour(s).

December 8, 2014: Government audit from 12:06 – 12:42. 1 invalid hour(s).

December 15, 2014: Servicing from 15:36 – 15:59. 1 invalid hour(s).

December 25, 2014: Brief negative under range from 4:06 – 4:08. 0 invalid hour(s).

Kinsmen 77227

December 1, 2014: Monthly calibration from 13:15 – 14:09. 1 invalid hour(s).

December 8, 2014: Government audit from 10:20 – 10:52. 1 invalid hour(s).

New Sudbury 77075

December 2, 2014: Monthly calibration from 13:16 – 14:19. 2 invalid hour(s).

December 10, 2014: Government audit from 14:04 – 14:30. 1 invalid hour(s).

December 19, 2014: Brief negative under range from 9:11 – 9:12. 0 invalid hour(s).

Rayside 77206

December 10 2014: Government audit from 10:22 – 10:52. 1 invalid hour(s).

December 16, 2014: Monthly calibration from 13:50 – 15:04. 1 invalid hour(s).

Science North 77203

December 11, 2014: Government audit from 12:44 – 13:18. 2 invalid hour(s).

December 18, 2014 at 23:42 to December 19, 2014 at 2:12: Power outage. 3 invalid hour(s).

December 19, 2014: Missing data due to power outage from 2:13 – 10:04. 8 invalid hour(s).

December 19, 2014: Monthly calibration from 14:12 – 15:28. 2 invalid hour(s).

Page 77: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Spruce St 77230

December 11, 2014: Government audit from 11:42 – 12:13. 1 invalid hour(s).

December 12, 2014: Servicing from 13:02 – 16:27. 4 invalid hour(s).

December 22, 2014: Monthly calibration from 10:33 – 11:38. 2 invalid hour(s).

Union 77330

December 16, 2014: Government audit from 11:04 – 11:34. 1 invalid hour(s).

December 30, 2014: Monthly calibration from 9:46 – 10:54. 1 invalid hour(s).

CKNC Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD1

Nothing to report

WD3

Nothing to report

WS1

Nothing to report

WS3

Nothing to report

Xstrata Nickel Sites

Coniston 77028

December 2, 2014: Monthly calibration from 10:03 – 11:06. 1 invalid hour(s).

December 11, 2014: Government audit from 13:49 – 14:19. 1 invalid hour(s).

Edison 77600

December 4, 2014: Government audit from 14:11 – 14:38. 1 invalid hour(s).

December 10, 2014: Monthly calibration from 9:53 – 11:08. 1 invalid hour(s).

Garson 77065

December 11, 2014: Government audit from 10:22 – 10:51. 1 invalid hour(s).

December 22, 2014: Monthly calibration from 13:04 – 14:04. 1 invalid hour(s).

Hanmer 77013

December 10, 2014: Government audit from 11:54 – 12:27. 1 invalid hour(s).

December 23, 2014: Monthly calibration from 14:09 – 15:17. 2 invalid hour(s).

Page 78: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

A Division of Boudreau-Espley-Pitre Corporation

1040 Lorne Street, Unit 3, Sudbury, ON P3C 4R9 Tel.(705)675-7720 Fax (705)675-5507

E-mail: [email protected]

Parkinson 77601

December 4, 2014: Government audit from 13:30 – 13:58. 1 invalid hour(s).

December 10, 2014: Monthly calibration from 11:44 – 12:54. 2 invalid hour(s).

December 23, 2014: Brief negative under range at 12:05. 0 invalid hour(s).

Skead 77012

December 10, 2014: Government audit from 12:56 – 13:28. 1 invalid hour(s).

December 17, 2014: Monthly calibration from 14:09 – 15:07. 1 invalid hour(s).

Sunderland 77602

December 4, 2014: Government audit from 12:34 – 13:11. 1 invalid hour(s).

December 9, 2014: Monthly calibration from 13:28 – 14:58. 2 invalid hour(s).

Wahnapitae 77603

December 4, 2014: Government audit from 11:04 – 11:33. 1 invalid hour(s).

December 9, 2014: Monthly calibration from 10:54 – 11:59. 1 invalid hour(s).

Xstrata Met

DT2

Nothing to report

TEM1

Nothing to report

TEM3

Nothing to report

WD

Nothing to report

WS

Nothing to report

Page 79: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

Appendix C Figure

Monitoring Station Location Map

Page 80: Vale Limited / Glencore Limited Annual SO Report ......AECOM Vale Limited / Glencore Limited Annual SO2 Report Submission Rpt 2014 Annual So2 Report.Final ii All SO 2 monitoring stations

Figure C1: Monitoring Station Location Map

Source: Google Earth Pro, February 2014