uop unity™ hydrotreating products · hydroprocessing technology you can rely on new unit design,...
TRANSCRIPT
© 2018 UOP LLC. A Honeywell Company All rights reserved.
UOP UNITY™ Hydrotreating ProductsSatyam Mishra
19 February 2018 Honeywell UOP ME-TECH SeminarDubai, UAE
UOP 8080A-0
Outline
1
UOP 8080A-1
Introducing ULTIMet™UOP Unity™ Hydroprocessing
Catalyst Portfolio
• Unity™ Case Story 1:
Hydrotreating catalyst
enabling ULSD production
• Unity™ Case Story 2:
Hydrotreating catalyst in
Hydrocracking pretreat
service
• Unity™ Case Story 3:
Successful commercialization
of HYT 4118 (Co-Mo
Catalyst) in ULSD service
UNITY
Unity
Honeywell UOP
Hydrotreating and Hydrocracking
Unified approach
Universal compatibility
Unity
UOP 8080A-2
2
Unity Means…Hydroprocessing Technology You Can Rely On
New Unit Design, Revamp, Process, Technology & Equipment Capabilities
3
0
40,000
80,000
120,000
160,000
200,000
1950 1955 1960 1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 2020
Lic
en
se
d C
ap
ac
ity,
BP
SD
Award Year
UOP Hydroprocessing Experience
Unionfining Units
Unicracking Units
• Naphtha Hydrotreating
• Coker Naphtha Hydrotreating
• Gasoline Selective Desulfurization
• Kerosene Hydrotreating
• Distillate Hydrotreating
• VGO (Cat Feed) Hydrotreating
• Fixed-Bed Resid Hydrotreating
Unity Hydroprocessing Catalysts
4
Innovation Built on 50 Years in Hydroprocessing
UOP 8080A-4
UOP Unity Hydrotreating Catalysts Can Help Refiners Meet Market Demands
Catalysts Meeting Expectations At All Units
01 02
CASE STUDY CASE STUDY
HYT-6219 in ULSD Service HYT-6119 Hydrocracking Pretreat Service
03
CASE STUDY
HYT-4118 Commercialization in
ULSD Service
5
Unity Case Story 1: Enabling On-Spec ULSD Production
6
UOP 7200-6Objective: Deliver EURO V Only With a Change in Catalyst
Cycle Objectives
• Achieve cycle length• Successfully produce 10ppm• No revamp
Operating conditions:
• 70 bar(g) Reactor Inlet H2 PP
• 740 Nm3/m3 H2 to Oil,
UOP Catalyst solution:
Feed Composition
Unity
Hydroprocessing
Catalysts
UOP Unity
HYT-6219
Feed Details Blend
Source Imported
Blend
45% LCGO27% CN
15% SRD13% LCO
API 43
Specific Gravity 0.81
Sulfur, Wt-% 0.3
Nitrogen, wt-ppm 1100
Bromine Number 35
150°C+ (300°F+) Content, Wt-% 85*
* Est from Naphtha Yield
UOP Service and Sales Support Unit Troubleshooting
7
HYT-6219 Allowing 10% Increased Unit Throughput
ULSD Case Story #1
Base+20
Base+15
Base+10
Base+5
Base
Base-5
Base-10
Pro
du
ct
Su
lfu
r, w
pp
m
High activity of HYT-6219
Allowing Customer to Increase
Feed Rate 10% Above Design
& Still Make ULSD product
0 20 40 80 100 120 140 180
Operating Days Since Start of Run
60 160
Gasoline, Sulfur, wppm
Diesel Sulfur, wppm
Product Sulfur
Reactor BypassClosed
Target Operation
Unity Case Story 1:HYT-6219 Enables Meeting ULSD Specifications
Product Quality Before usage
Sulfur, wt-ppm 50 – 150
Cetane Index 46 – 51
After Reload with HYT-6219
3 - 8
48 – 53
Unity Catalyst and Service Key Enabler for EURO V Diesel
Achieved diesel quality is better than EURO V
Unity catalyst and UOP sales support/service key for this achievement
8
UOP Unity Hydrotreating Catalysts Can Help Refiners Meet Market Demands
Catalysts Meeting Expectations At All Units
01 02
CASE STUDY CASE STUDY
HYT-6219 in ULSD Service HYT-6119 Hydrocracking Pretreat Service
03
CASE STUDY
HYT-4118 Commercialization in
ULSD Service
9
Unity Case Story 2: Upgrading Petrochemical Feedstocks
UOP 7200-10Flexibility to Upgrade to Petrochemicals Feedstock
Cycle Objectives
• Achieve cycle length
• Improve naphtha quality and yield for downstream petrochemical production
Type of hydrocracking technology
• Non-UOP hydrocracking unit design
Feed Composition
• VGO/LCGO/HCGO
Conversion:
• 90% vol
UOP Catalyst solution:
Unity
Hydroprocessing
Catalysts
UOP Unity
HYT-6119
UOP Unity
Naphtha HC
10
Reactor Temperatures
Robust Hydrocracking Pretreat in Severe Conditions
11
HYT-6119 delivers
improved stability
Pretreat Reactor Temperatures
0 100 200 300 400 500 600 700
Operating Days Since Start of Run
R-6101 WABT
WABT Normalized to Average Conditions
Proposal Predicted WABT at Design Conditions
No
rmali
zed
Avera
ge B
ed
Tem
pera
ture
, °C
11
Nitrogen Slip from HC Pretreat Reactor
Excellent HDN Activity with HYT-6119 Catalyst
12
Effluent Nitrogen
0 100 200 300 400 500 600
Calendar Days Since Start of Run
Nit
rog
en
, W
t-p
pm
Pretreat Outlet N (ppm)
Target Operation
12
No
rma
lize
d A
ve
rag
e B
ed
Te
mp
era
ture
, °C
Hydrocracking Catalyst Performance
Unity Delivers Improved Heavy Naphtha for Petrochemical Use
13
Improved Stability
Normalized WABT
0 100 200 300 400 500 600 700
Operating Days Since Start of Run
R-6102 WABT
WABT Normalized to Average Conditions
Proposal Predicted WABT at Design Conditions
Unity Case Story 2 -Hydrocracker Products Feed The Aromatics Complex:
14
UOP 7200-14Understanding of the Big Picture Behind Refinery Operations
VGOLCGOHCGO Heavy
Naphtha
Hydrocracker
DesaltedCrude Oil
Cumene
p-XyleneNaphtha
BenzeneAromaticsComplex
BTX
CrudeFractionation
CCR
Results
• Unity portfolio delivers improved heavy naphtha product properties
• The achieved heavy naphtha properties enable extra $9 million per year of aromatics production
Unity
Hydroprocessing
Catalysts
UOP Unity
HYT-6119
UOP Unity
Naphtha HC
Cycle Objectives
• Achieve cycle length
• Increase naphtha quality and yield for downstream petrochemical production
UOP Unity Hydrotreating Catalysts Can Help Refiners Meet Market Demands
Catalysts Meeting Expectations at All Units
01 02
CASE STUDY CASE STUDY
HYT-6219 in ULSD Service HYT-6119 Hydrocracking Pretreat Service
03
CASE STUDY
HYT-4118 Commercialization in
ULSD Service
15
16
Cycle Objectives
• Meet or Exceed cycle length
• Diesel Sulphur of < 10 wt-ppm
Operating conditions:
• 29 barg Reactor Inlet (23 bara I/L H2 PP)
• 250 Nm3/m3 H2 to Oil,
• LHSV 1.8 – 2.3 h-1
Our Catalyst solution:
Feed Quality
Feed Details Blend
Source Indigenous
Blend 100% SRD
API 42
Specific Gravity 0.815
Sulfur, Wt-% 0.2
D-86 IBP, ºC 175-190
D-86 50%, ºC 220-240
D-86 FBP, ºC 340-370
Unity
Hydroprocessing
Catalysts
UOP Unity
HYT-4118
Unity Case Story 3Successful Commercialization of HYT-4118
UOP 8080A-16
0 10 20 30 40 50 60 70
Pro
du
ct
Su
lph
ur,
Wt-
pp
m
WA
BT,
°C
Calendar Days on Stream
Product Sulphur Target = 10 ppm
UOP Services
helped to optimize
unit operations
Base
+ 10 C
+ 20 C
+ 30 C
EOR WABT
Unity Integrates Catalyst and Service for Cycle Improvements
17
HYT-4118 Industrial Performance
HYT-4118 delivers
robust performance
HYT-4118 delivers
excellent sulfur
removal
Expected cycle to exceed target cycle length by 50%** Assuming operating conditions and feed
properties and targets remain, based on HYT activity & stability
Unity Case Story 3Successful Commercialization of HYT-4118
18
Cycle Objectives:
• Meet or Exceed Cycle Length
• Diesel Sulphur of < 10 wt-ppm
Unity
Hydroprocessing
Catalysts
UOP Unity
HYT-4118
UOP Unity Provides Flexibility:
Estimate 50% Cycle Increase
OR 30% Higher Capacity
Flexibility with More Difficult Feedstocks
Unity as Enabler for ULSD Production Improvement
Our Catalyst solution:
Unity Means…Access to a Global Network of Experts
Developing Strong Partnerships With You
19
Regional service team members collaborating with deep subject matter experts
Understanding of the big picture behind refinery operations
Knowledge of upstream & downstream units and
their interactions
Unmatched experience in servicing of hydroprocessing units worldwide
Seamless technology transfer from unit design, to unit start-up and catalyst reload
Unity Hydroprocessing Catalysts
20
Innovation Built on 50 Years in Hydroprocessing
UOP 8080A-20
21
UOP 8080A-21
Created to Help Refiners Be More Profitable While Meeting Shifting Market Demands
22
Refining customers tell us that they want a solution to:
• Get more profit from difficult feeds
• Go longer between catalyst change-outs
• Operate at higher feed rates to improve utilization
• Increase volume swell
A Customized Loading of ULTIMet and HYT-6219 Can Enable These Goals
23
Performance Testing With Heavy VGO
HYT
6219 + =
Improved
• HDS Activity
• HDN Activity
• Aromatics Saturation
UOP 8080A-23Tailored Catalyst Loading Specifically for Your Plant
ULTIMet
24
Premium Catalyst Solution that:
• Requires higher hydrogen availability
• Helps increase profits and margins from difficult feeds
• Provides additional catalyst loading flexibility
• Has the stability and durability for longer periods between change-outs
• Can be operated at higher feed rates
• Boosts volume sell
UOP 8080A-24Or to Put It Simply, Use ULTIMet and Achieve More
Commercial Success of UOP Unity Hydrotreating Catalysts
UOP Hydrotreating Catalysts Gaining World Wide Acceptance
UnityHoneywell UOP
Operating with difficult feeds in
high severity operations
Activity and stability are on
par or better than expectations
Product quality enabling
profitability
Robust catalysts to handle
operating upsets
25
26
UOP 8080A-26
27
https://twitter.com/HoneywellUOP https://www.linkedin.com/company/uop
https://www.uop.com/
https://www.youtube.com/user/Honeywell https://www.accessuop.com/
Q & A
UOP 8080A-27