unlocking solar thermochemical potential: markets

14
Copyright © 2020 CEMEX Innovation Holding Ltd., Switzerland, All Rights Reserved Unlocking Solar Thermochemical Potential: Markets, Opportunities, and Challenges Workshop November 12 th , 2020 Dr. Davide Zampini Head of CEMEX Global R&D

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Page 1: Unlocking Solar Thermochemical Potential: Markets

Copyright © 2020 CEMEX Innovation Holding Ltd., Switzerland, All Rights Reserved

Unlocking Solar Thermochemical Potential:

Markets, Opportunities, and Challenges

Workshop – November 12th, 2020

Dr. Davide Zampini

Head of CEMEX Global R&D

Page 2: Unlocking Solar Thermochemical Potential: Markets

CEMEX OPERATIONS A GLOBAL TRADING NETWORK

CE

ME

X –

GLO

BA

L C

ON

STR

UC

TIO

N M

ATE

RIA

LS

Cement

Aggregates

Admixtures

Sustainability

Urbanization Solutions

NET SALES

Millions USD

13,130

FREE CASH FLOW

EBITDA 2,378695

Ready-Mix

Page 3: Unlocking Solar Thermochemical Potential: Markets

CEMEX

PEOPLE

+40.6

CEMENT

THOUSAND EMPLOYEES

65

93

CEMENT AND GRINDING PLANTS

MILLION TONS PRODUCTION CAPACITY

READY-MIX

CONCRETE

1,427

50

PLANTS

MILLION m3 ANNUAL SALES VOLUME

TERMINALS

279

56

LAND DISTRIBUTION CENTERS

MARINE

TERMINALS

262

135QUARRIES

MILLION TONS ANNUAL SALES VOLUME

AGGREGATES

Page 4: Unlocking Solar Thermochemical Potential: Markets

CE

ME

X –

CLIM

ATE

AC

TIO

N

-115

-110

-60

-22

-20-13Carbon Capture, Use

and Storage

Reforestation Offsets

Renewable Power

Transport & Supplies

Ready Mix & Aggregates

Clinker/Cement

Concrete

Ambition 2050:

Cement

Target 2030:

340

kgCO2/m³

Aligned with the 2 Degree scenario of the IEA

Estimated CO2 Footprint for a high strength concrete produced with cement Type I

35%Reduction of CO2

Emissions vs 1990

Baseline

Net-zero CO2

Concrete Globally

kgCO2/ton cementitious

ClinkerCement

800

620 -60-40

520*

1990 2019 2030

Proven technology, focus on

fast deployment and

removing barriers

A significant portion of CO2

mitigation (> 30%) will rely on

technologies not yet fully

developed – not industrially

and commercially viable.

Innovation / R&D.

Page 5: Unlocking Solar Thermochemical Potential: Markets

CO2 Reduction

CO2 Concentration & Capture

CO2 Reutilization

FUEL COMBUSTION

CALCINATION

38% CO2

25% CO2

Calciner

62% CO2

Preheater

13% CO2

CLIN

KE

R M

AN

UFA

CTU

RIN

G P

RO

CE

SS

CHALLENGES

C e m e n t M a n u f a c t u r e D i a g r a m - P i r e s , J . . ( 2 0 1 9 ) . C a r b o n C a p t u r e a n d S t o r a g e .

Page 6: Unlocking Solar Thermochemical Potential: Markets

High Performance High Temperature Solar Heat & Thermo-Chemical Processes

CO2 + H2OPure CO2

Raw meal Clinker

Calcination –>

CO2

Liquid H2O

1500 ⁰C

SO

LA

R-D

RIV

EN

PY

RO

-P

RO

CE

SS

ING

OF C

LIN

KE

R

DRIVE FULL PROCESS WITH SOLAR ENERGY in-line with conventional process flow

NO CO2 emissions

NO fuel costs

Page 7: Unlocking Solar Thermochemical Potential: Markets

High Level Conceptualization – Inspiration of the Aspiration

SO

LA

R-D

RIV

EN

PY

RO

-P

RO

CE

SS

ING

OF C

LIN

KE

R

High Temp. Fluid

(HTF)

Page 8: Unlocking Solar Thermochemical Potential: Markets

C O 2

H 2OC L I N K E R

S Y N G A S G a s o l i n e

D i e s e l

K e r o s e n e

M e t h a n o l

CLO

SIN

G T

HE

CA

RB

ON

CY

CLE

Page 9: Unlocking Solar Thermochemical Potential: Markets

9

Heliostats

Grate coolerRotary kiln

Preheating tower

Receiver

Thermal energy storage (TES) – not displayed

Backup burner – not displayed

Piping

Integration Considerations1. Solar energy demand and availability to

fulfill production process2. Transport and efficiency of the heat

transfer fluid (HTF) and materials3. Energy transfer in kiln4. Impact on thermochemistry of

clinkerization and calcination – quality of clinker

5. Adaptions & modifications of plant components

Concept:

Heat HTF at the top of the solar tower and use HTF toheat up the material and deliver required energy at thepyro-processing stages

INTE

GR

ATIO

N C

HA

LLE

NG

ES

Page 10: Unlocking Solar Thermochemical Potential: Markets

CONFIGURATION INTERVENTION SCHEME

Solar Calcination

Full Solar

INTE

GR

ATI

ON

: S

TEP

-W

ISE H

YB

RID

IZA

TIO

N2 0 2 1

2 0 2 3

2 0 2 6

2 0 2 8

Calcination “Lab” Pilot250kWth

Calcination Pilot1 MWth

Full Solar1 MWth

Full Integration10 MWth

Industrial Scale100 MWth

600 tpd

Page 11: Unlocking Solar Thermochemical Potential: Markets

250 kW Receiver Prototype & Testing reaching 1500 ⁰C (Germany, March 2020)

TE

CH

NO

LO

GIC

AL V

ALID

ATIO

N –

KE

Y M

ILE

STO

NE

S

Page 12: Unlocking Solar Thermochemical Potential: Markets

HTF CLINKERIZATION AND CALCINATIONMaterial Quality & Performance Unaltered

TE

CH

NO

LO

GIC

AL V

ALID

ATIO

N –

KE

Y M

ILE

STO

NE

S

Impact of the Heat Transfer Fluid (HTF) on the heating zones including residence time Heat exchange efficiency between material as a function of CO2/ H2O ratios Shifts of heating curves and phases formation

* Nørskov, L. K., Dam-Johansen, K., Glarborg, P., Jensen, P. A., & Larsen, M. B. (2012). Combustion of solid alternative fuels in the cement kiln burner. Kgs. Lyngby: Technical University of

Denmark (DTU).

Page 13: Unlocking Solar Thermochemical Potential: Markets

BACK UP

Page 14: Unlocking Solar Thermochemical Potential: Markets

SO

LA

R H

EA

T v

s O

TH

ER

SO

UR

CE

S WHY CST (SOLAR THERMAL) - COST OF HEAT

W h i l e t h e r e i s a g r o w i n g i n t e r e s t i n e l e c t r i c a l l y h e a t e d s y s t e m s d r i v e nd i r e c t l y b y c h e a p r e n e w a b l e p o w e r a s a l t e r n a t i v e t o C S T s y s t e m s , e v e n u n d e rv e r y a g g r e s s i v e c o n d i t i o n s C S T h a s t h e u p p e r h a n d .

203 0

203 0

203 0

203 0

203 0

203 0

203 0

203 0

26th SolarPACES Conferenc – Plenary: Green Hydrogen, “Solar thermal pathways for renewable hydrogen and fuel,” Gianluca Ambrosetti, Synhelion