united states environmental protection agency washington ... · (co" i 10 united states...

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UNITED STATES ENVIRONMENTAL PROTECTION AGENCYWASHINGTON, D.C. 20460

OFFICE OF CHEMICAL SAFETYAND POLLUTION PREVENTION

Mr. Montague DixonSyngenta Crop Protection, LLCPOBox 18300Greensboro, NC 27419-8300

„... JAN 3 1 2013

Subject: Gramoxone SL 2.0EPA Registration Number 100-1431Resubmission by email dated January 21,2013Label amendment '

Dear Mr. Dixon:

The labeling referred to above, submitted in connection with registration under theFederal Insecticide, Fungicide, and Rodenticide Act (FIFRA), as amended, is acceptable.. Astamped copy of your label is enclosed for your records. This label supersedes all previouslyaccepted labels.

You must submit one (1) copy of the final printed label before you release the product forshipment. Products released for shipment after eighteen (18) months from the date of this lettermust bear the new revised label. If these conditions are not complied with, the registration willbe subject to cancellation in accordance with FIFRA §6(e). Your release for shipment of theproduct constitutes acceptance of these conditions.

If you have any questions, please contact Hope Johnson at (703)305-5410 or [email protected].

Sincerely,

Kable Bo DavisProduct Manager 25Herbicide BranchRegistration Division (7505P)

[Booklet]

RESTRICTED USE PESTICIDEDUE TO ACUTE TOXICITY

FOR RETAIL SALE TO AND USE ONLY BY CERTIFIED APPLICATORS ORPERSONS UNDER THEIR DIRECT SUPERVISION AND ONLY FOR THOSE USES

COVERED BY THE CERTIFIED APPLICATOR'S CERTIFICATION.

Gramoxone SL 2.0

GROUP HERBICIDE

Herbicide

A Weed, Grass, and Harvest Aid Desiccant/Defoliant Herbicide

Active Ingredient:Paraquat dichloride (1,1'-dimethyl-4,4'-bipyridinium dichloride) 30.1%Other Ingredients: 69.9%Total: 100.0%

Contains 2.0 pounds paraquat cation per gallon as 2.762 pounds salt per gallon.Contains alerting agent (odor), emetic, and dye.

EPA Reg. No.100-1431

EPA Est.

Product ofFormulated in

KEEP OUT OF REACH OF CHILDREN.

**r •*.%*•

JAN 3 12013Sacfe? fee Pefe^

| £-3 C:EKH'c2. fOI" iBS

I B?A Res- Sfo,! =.

DANGER / POISONPELIGRO

Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted endetalle. (If you do not understand the label, find someone to explain it to you in detail.)

c Tb-2-

• NEVER PUT INTO FOOD, DRINK OR OTHER CONTAINERS.• IF SWALLOWED, TAKE IMMEDIATE ACTION AS PRESCRIBED IN FIRST AID

STATEMENT. SYMPTOMS ARE PROLONGED AND PAINFUL.• DO NOT USE OR STORE IN OR AROUND THE HOME.• DO NOT REMOVE CONTENTS EXCEPT FOR IMMEDIATE USE.• THE ODOR OF THIS PRODUCT IS FROM THE ALERTING AGENT WHICH HAS

BEEN ADDED, NOT FROM PARAQUAT.

1 gallon2.5 gallons30 gallons120 gallons

gallonsNet Contents

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CU10

FIRST AIDContains Paraquat, a Bipyridylium Herbicide

If swallowed SPEED IS ESSENTIAL. Immediate medical attention is required. Ifavailable, give an adsorbent such as activated charcoal, bentoniteor Fuller's Earth.Call a poison control center or doctor immediately for treatmentadvice.Do not give anything by mouth to an unconscious person.

If inhaled Move person to fresh air.The odor of this product is from the alerting agent, which has beenadded, not from the paraquat.If person is not breathing, call 911 or an ambulance.Call a poison control center or doctor for further treatment advice.

If in eyes Hold eye open and rinse slowly and gently with water for 15-20minutes.Remove contact lenses, if present, after the first 5 minutes, thencontinue rinsing eye.Call a poison control center or doctor for treatment advice.

If on skin orclothing

Take off contaminated clothing.IMMEDIATELY wash with soap and water and rinse for 15-20minutes. Prolonged contact will cause severe irritation. Contactwith irritated skin or a cut or repeated contact with intact skin mayresult in poisoning.GET MEDICAL ATTENTION. Call a poison control center or doctorfor treatment advice.

NOTE TO PHYSICIANRefer to the booklet 'Paraquat Poisoning. A Practical Guide to Diagnosis, First Aid andHospital Treatment' (http://www.svngenta.com/pqmedguide). Administer eitheractivated charcoal (100g for adults or 2g/kg body weight in children) or Fuller's Earth(15% solution; 1 liter for adults or 15ml/kg body weight in children). NOTE: The use ofgastric lavage without administration of an adsorbent has not shown any clinical benefit.Do not use supplemental oxygen. Eye splashes from concentrated material should betreated by an eye specialist after initial treatment. With the possibility of late onsetcorneal ulceration, it is advised that patients with paraquat eye injuries are reviewed byan eye specialist the day after first presentation. Use treatment that is appropriate forchemical burns. Intact skin is an effective barrier to paraquat, however contact withirritated or cut skin or repeated contact with intact skin may result in poisoning.Have the product container or label with you when calling a poison control center ordoctor, or going for treatment.

HOT LINE NUMBERFor 24-Hour Medical Emergency Assistance (Human or Animal)

Or Chemical Emergency Assistance (Spill, Leak, Fire or Accident)Call

1-800-888-8372

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PRECAUTIONARY STATEMENTS

HAZARDS TO HUMANS AND DOMESTIC ANIMALS

DANGER /POISONPELIGRO

May be fatal if swallowed. Fatal if inhaled. Do not breathe spray mist. Wear a dustmist NIOSH-approved respirator with any N, R, P, or HE filter. Causes substantial buttemporary eye injury. Wear protective eyewear (face shield required whenmixing/loading). Harmful if absorbed through skin. Do not get in eyes, on skin, or onclothing. Avoid contact with skin.

IMPORTANT: Inhalation is an unlikely route of exposure due to low vapor pressure andlarge spray droplet size, but mucosal irritation or nose bleeds may occur. Prolongedcontact with this concentrated product can irritate your skin.

Personal Protective Equipment (PPE)Applicators and other handlers (other than Mixers and Loaders) must wear:

• Long-sleeve shirt and long pants• Shoes plus socks• Protective eyewear• Chemical Resistant Gloves - Category A (e.g. barrier laminate, butyl rubber,

nitrile rubber, neoprene rubber, natural rubber, polyethylene, polyvinyl chloride(PVC) or Viton®)

• A dust mist NIOSH-approved respirator with any N, R, P, or HE filter

Mixers and Loaders must wear:• Long-sleeve shirt and long pants• Shoes plus socks• A dust mist NIOSH-approved respirator with any N, R, P, or HE filter• Chemical Resistant Gloves - Category A (e.g. barrier laminate, butyl rubber,

nitrile rubber, neoprene rubber, natural rubber, polyethylene, polyvinyl chloride(PVC) or Viton)

• Chemical resistant apron• Face shield

Discard clothing and other absorbent materials that have been drenched or heavilycontaminated with this product's concentrate. Do not reuse them. Followmanufacturer's instructions for cleaning/maintaining PPE. If no such instructions for

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washables exist, use detergent and hot water. Keep and wash PPE separately fromother laundry.

Engineering Controls

When handlers use closed systems, enclosed cabs, or aircraft in a manner that meetsthe requirements listed in the Worker Protection Standard (WPS) for agriculturalpesticides [40 CFR 170.240(d)(4-6)], the handler PPE requirements may be reduced ormodified as specified in the WPS.

User Safety RecommendationsUsers should:

• Wash hands before eating, drinking, chewing gum, using tobacco or using thetoilet.

• Remove clothing/PPE immediately if pesticide gets inside. Then washthoroughly and put on clean clothing.

• Remove PPE immediately after handling this product. Wash the outside ofgloves before removing. As soon as possible, wash thoroughly and change intoclean clothing.

Environmental Hazards

Wildlife: This product is toxic to wildlife. Do not apply directly to water or to areaswhere surface water is present or to intertidal areas below the mean high water mark.Do not contaminate water when cleaning equipment or disposing of equipmentwashwaters.

Drift: Gramoxone SL 2.0 is a contact herbicide that desiccates all green plant tissue.Paraquat dichloride is a nonselective herbicide and will cause damage to nontargetcrops and plants if off-target movement occurs. Extreme care must be taken to ensurethat off-target drift is minimized to the greatest extent possible. Do not apply underconditions involving possible drift to food, forage, or other plantings that might bedamaged or the crops thereof rendered unfit for sale, use, or consumption. Do notapply when weather conditions favor drift from treated areas. To avoid drift, do notmake aerial applications during periods of thermal inversion. Refer to the local statelaws, regulations, guidelines and spray drift information contained in the Directions forUse section for proper application to avoid off-target movement.

Physical and Chemical Hazards

This product is mildly corrosive to aluminum and produces hydrogen gas which mayform a highly combustible gas mixture. Do not mix or store in containers, spray tanks,nurse tanks, or such systems made of aluminum or having aluminum fittings. Thisproduct is compatible with high density polyethylene and rubber lined steel containers.

1f

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CONDITIONS OF SALE AND LIMITATION OF WARRANTY AND LIABILITY

NOTICE: Read the entire Directions for Use and Conditions of Sale and Limitation ofWarranty and Liability before buying or using this product. If the terms are notacceptable, return the product at once, unopened, and the purchase price will berefunded.

The Directions for Use of this product must be followed carefully. It is impossible toeliminate all risks inherently associated with the use of this product. Crop injury,ineffectiveness or other unintended consequences may result because of such factorsas manner of use or application, weather or crop conditions, presence of other materialsor other influencing factors in the use of the product, which are beyond the control ofSYNGENTA CROP PROTECTION, LL'C or Seller. To the extent permitted byapplicable law, Buyer and User agree to hold SYNGENTA and Seller harmless for anyclaims relating to such factors.

SYNGENTA warrants that this product conforms to the chemical description on the labeland is reasonably fit for the purposes stated in the Directions for Use, subject to theinherent risks referred to above, when used in accordance with directions under normaluse conditions. To the extent permitted by applicable law: (1) this warranty does notextend to the use of the product contrary to label instructions or under conditions notreasonably foreseeable to or beyond the control of Seller or SYNGENTA, and, (2) Buyerand User assume the risk of any such use. TO THE EXTENT PERMITTED BYAPPLICABLE LAW, SYNGENTA MAKES NO WARRANTIES OF MERCHANTABILITYOR OF FITNESS FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS ORIMPLIED WARRANTY EXCEPT AS WARRANTED BY THIS LABEL.

To the extent permitted by applicable law, in no event shall SYNGENTA be liable forany incidental, consequential or special damages resulting from the use or handling ofthis product. TO THE EXTENT PERMITTED BY APPLICABLE LAW, THEEXCLUSIVE REMEDY OF THE USER OR BUYER, AND THE EXCLUSIVE LIABILITYOF SYNGENTA AND SELLER FOR ANY AND ALL CLAIMS, LOSSES, INJURIESOR DAMAGES (INCLUDING CLAIMS BASED ON BREACH OF WARRANTY,CONTRACT, NEGLIGENCE, TORT, STRICT LIABILITY OR OTHERWISE)RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, SHALL BE THERETURN OF THE PURCHASE PRICE OF THE PRODUCT OR, AT THE ELECTIONOF SYNGENTA OR SELLER, THE REPLACEMENT OF THE PRODUCT.

SYNGENTA and Seller offer this product, and Buyer and User accept it, subject to theforegoing Conditions of Sale and Limitation of Warranty and Liability, which may not bemodified except by written agreement signed by a duly authorized representative ofSYNGENTA.

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D1RECTIONS FOR USERESTRICTED USE PESTICIDE

It is a violation of Federal law to use this product in a manner inconsistent with itslabeling.

Do not apply this product in a way that will contact workers or other persons, eitherdirectly or through drift. Only protected handlers may be in the area during application.For any requirements specific to your State or Tribe, consult the agency responsible forpesticide regulation.

DO NOT USE AROUND HOME GARDENS, SCHOOLS, RECREATIONAL PARKS,GOLF COURSES OR PLAYGROUNDS.

AGRICULTURAL USE REQUIREMENTS

Use this product only in accordance with its labeling and with the Worker ProtectionStandard, 40 CFR part 170. This Standard contains requirements for the protection ofagricultural workers on farms, forests, nurseries, and greenhouses, and handlers ofagricultural pesticides. It contains requirements for training, decontamination,notification, and emergency assistance. It also contains specific instructions andexceptions pertaining to the statements on this label about personal protectiveequipment (PPE) and restricted-entry interval. The requirements in this box onlyapply to uses of this product that are covered by the Worker Protection Standard.

For Chemical Fallow, Early Postemergence Broadcast in Peanuts and DormantSeason Applications, and "Between Cutting" Applications in Alfalfa: Do notenter or allow worker entry into treated areas during the restricted-entry interval (REI)of 12 hours.

For Harvest Aid and Desiccation Applications, Preplant or Preemergence(Broadcast or Banded), and Postemergence Directed Spray: Do not enter orallow worker entry into treated areas during the restricted-entry interval (REI) of 24hours.

PPE required for early entry to treated areas that is permitted under the WorkerProtection Standard and that involves contact with anything that has been treated,such as plants, soil, or water, is:

• Coveralls• Shoes plus socks• Protective eyewear• Chemical Resistant Gloves - Category A (e.g. barrier laminate, butyl rubber,

nitrile rubber, neoprene rubber, natural rubber, polyethylene, polyvinyl chloride(PVC)orViton).

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NON-AGRICULTURAL USE REQUIREMENTS

The requirements in this box apply to uses of this product that are NOT within thescope of the Worker Protection Standard for agricultural pesticides (40 CFR Part 170).The WPS applies when this product is used to produce agricultural plants on farms,forests, nurseries, or greenhouses.

DO NOT enter or allow others to enter the treated area until sprays have dried.AVOID working in spray mist.

KEEP all unprotected persons out of operating areas or vicinity where there may bedanger of drift.

Certain states may require more restrictive reentry intervals; consult your StateDepartment of Agriculture for further information.

USE INSTRUCTIONS AND INFORMATION

Do not apply this product through any type of irrigation system.

When Gramoxone SL 2.0 is applied at less than 10 gallons per acre finished sprayvolume, a drift control or spray deposition additive SHOULD be used. Refer to theadditive label for use directions.

Spray Drift Information

Avoiding spray drift at the application site is the responsibility of the applicator. Theinteraction of many equipment-and-weather-related factors determine the potential forspray drift. The applicator and the grower are responsible for considering all thesefactors when making decisions.

The following drift management requirements must be followed to avoid off-target driftmovement from aerial applications to agricultural field crops. These requirements donot apply to forestry applications, public health uses or to applications using dryformulations.

• The distance of the outer most nozzles on the boom must not exceed % the lengthof the wingspan or rotor.

• Nozzles must always point backward parallel with the air stream and never bepointed downwards more than 45°.

Where states have more stringent regulations, they shall be observed.

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The applicator should be familiar with and take into account the information covered inthe Aerial Drift Reduction Advisory Information

Aerial Drift Reduction Advisory Information(This section is advisory in nature and does not supersede the mandatory labelrequirements.)

Information on Droplet Size

The most effective way to reduce drift potential is to apply large droplets. The best driftmanagement strategy is to apply the largest droplets that provide sufficient coverageand control. Applying larger droplets reduces drift potential, but will not prevent drift ifapplications are made improperly, or under unfavorable environmental conditions (seeWind, Temperature and Humidity, and Temperature Inversions).

Controlling Droplet Size

• Volume - Use high flow rate nozzles to apply the highest practical spray volume.Nozzles with higher rated flows produce larger droplets.

• Pressure - Do not exceed the nozzle manufacturer's recommended pressures. Formany nozzle types lower pressure produces larger droplets. When higher flow ratesare needed, use higher flow rate nozzles instead of increasing pressure.

• Number of Nozzles - Use the minimum number of nozzles that provide uniformcoverage.

• Nozzle Orientation - Orienting nozzles so that the spray is released parallel to theairstream produces larger droplets than other orientations and is the recommendedpractice. Significant deflection from horizontal will reduce droplet size and increasedrift potential.

• Nozzle Type - Use a nozzle type that is designed for the intended application. Withmost nozzle types, narrower spray angles produce larger droplets. Consider usinglow-drift nozzles. Solid stream nozzles oriented straight back produce the largestdroplets and the lowest drift.

Boom Length

For some use patterns, reducing the effective boom length to less than % of thewingspan or rotor length may further reduce drift without reducing swath width.

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Application Height

Applications must not be made at a height greater than 10 feet above the top of thelargest plants unless a greater height is required for aircraft safety. Making applicationat the lowest height that is safe reduces exposure of droplets to evaporation and wind.

Swath Adjustment

When applications are made with a crosswind, the swath will be displaced downwind.Therefore, on the up and downwind edges of the field, the applicator must compensatefor this displacement by adjusting the path of the aircraft upwind. Swath adjustmentdistance should increase, with increasing drift potential (higher wind, smaller drops,etc.).

Wind

Drift potential is lowest between wind speeds of 2-10 mph. However, many factors,including droplet size and equipment type determine drift potential at any given speed.Application must be avoided below 2 mph due to variable wind direction and highinversion potential. NOTE: Local terrain can influence wind patterns. Every applicatorshould be familiar with local wind patterns and how they affect spray drift.

Temperature and Humidity

When making applications in low relative humidity, set up equipment to produce largerdroplets to compensate for evaporation. Droplet evaporation is most severe whenconditions are both hot and dry.

Temperature Inversions

Applications must not occur during a temperature inversion because drift potential ishigh. Temperature inversions restrict vertical air mixing, which causes small suspendeddroplets to remain in a concentrated cloud. This cloud can move in unpredictabledirections due to the light variable winds common during inversions. Temperatureinversions are characterized by increasing temperatures with altitude and are commonon nights with limited cloud cover and light to no wind. They begin to form as the sunsets and often continue into the morning. Their presence can be indicated by groundfog; however, if fog is not present, inversions can also be identified by the movement ofsmoke from a ground source or an aircraft smoke generator. Smoke that layers andmoves laterally in a concentrated cloud (under low wind conditions) indicates aninversion, while smoke that move upward and rapidly dissipates indicates good verticalair mixing.

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Sensitive Areas

The pesticide must only be applied when the potential for drift to adjacent sensitiveareas (e.g. residential areas, bodies of water, known habitat for threatened orendangered species, non-target crops) is minimal (e.g., when wind is blowing awayfrom the sensitive areas).

USE INFORMATION

Gramoxone SL 2.0 is a contact herbicide used to control or suppress a broad spectrumof emerged weeds. Gramoxone SL 2.0 controls most small annual weeds - bothbroadleaves and grasses, and suppresses perennial weeds by destroying green foliage.Gramoxone SL 2.0 can also be used as a desiccant/defoliant at harvest.

Gramoxone SL 2.0 is formulated as a liquid which contains 2 pounds of activeingredient per gallon. The formulation contains a nontoxic odor and an emetic (anagent which will induce vomiting if the product is swallowed). The odor is included inthe formulation to help prevent accidental ingestion of Gramoxone SL 2.0.

Gramoxone SL 2.0 is rapidly absorbed by green plant tissue and interacts with thephotosynthetic process to produce superoxides which destroy the plant cells.Gramoxone SL 2.0 requires actively growing green plant tissue to function. Thoroughcoverage of all green foliage is essential for effective weed control and for effective cropdesiccation/defoliation. Gramoxone SL 2.0 is not as effective on drought-stressedweeds, weeds with little green foliage (i.e., mowed or cut weeds), or mature woody barkof trees and vines.

Clay and organic matter rapidly tie up Gramoxone SL 2.0. As a result, Grarhoxone SL2.0 has no residual soil activity to affect later-planted crops or later germinating weeds.

ROTATIONAL CROPS

All rotational crops may be planted immediately after the last application of GramoxoneSL2.0.

RAINFASTNESS

Because Gramoxone SL 2.0 is rapidly absorbed by the weed foliage, rain occurring 15-30 minutes or more after application will have no effect on the activity of Gramoxone SL2.0.

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APPLICATION

Since Gramoxone SL 2.0 is a contact-type herbicide, it is essential to obtain completecoverage of target weeds to get good control. Improper application technique and/orapplication to large, stressed, or mown weeds will usually result in unacceptable weedcontrol and unacceptable crop desiccation/defoliation. Complete coverage is alsoessential for good crop desiccation/defoliation. See details below for specificapplication instructions.

USE OF A NONIONIC SURFACTANT OR CROP OILCONCENTRATE/METHYLATED SEED OIL

Always add one of the following (failure to use one of the following atrecommended rates will result in reduced performance of Gramoxone SL 2.0).

Nonionic Surfactant: For ground and aerial application, add nonionic surfactantcontaining 80% or more surface-active agent at a minimum of 0.25% v/v (2 pt/100 gal)of the finished spray volume.

Crop Oil Concentrate: Add a nonphytotoxic crop oil concentrate or methylated seedoil containing 15-20% approved emulsifier, at 1.0% v/v (1 gal./100 gal) of the finishedspray volume for ground applications. For aerial applications, add 1 pint of crop oilconcentrate per acre. Do not use crop oil concentrate when using Gramoxone SL 2.0for cotton harvest aid.

Use an adjuvant that meets the requirements of the Chemical Producers andDistributors Association (CPDA) adjuvant certification program.

NOZZLE SELECTION

The use of flat-fan nozzles will result in the most effective application of Gramoxone SL2.0. Flood nozzles are generally not as good as flat fans since they produce largeuneven droplets. The use of flood nozzles may result in reduced weed control due toinadequate coverage.

WHEN SPRAYING LESS THAN 20 GALLONS OF SPRAY CARRIER PER ACRE, USEONLY FLAT FAN NOZZLES AS RECOMMENDED IN THE CHART BELOW.

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Table 1. Nozzles, Pressures and Setup.

Maximum SizeSpray Pressure(at nozzle)Maximum Nozzle SpacingDirection of Spray PatternMaximum SpeedSpray Overlap(at each edge)

Nozzle TypeFlat Fan

830-50

psi30"

Down10 mph

30%

Flood15

30-50psi40"

Down10 mph

50%

Flat-Fan Nozzles30% (60% Total) Overlap

/ x, " - -~ 'j\^f -••' .- NX3 ' ' v - _ . - -wv?- . • z^

Flood Nozzles50% (100% Total) Overlap

Using nozzles, pressures, or setups different from the above chart will result inreduced control.

SPRAY CARRIER

Always use clean water (free of mud or clay), clear liquid nitrogen, or complete clearliquid fertilizers as the carrier when spraying Gramoxone SL 2.0. Muddy water, orsuspension-type fertilizers containing clay, can inactivate Gramoxone SL 2.0. Neveruse suspension-type fertilizers containing clay as the spray carrier. If using a completeclear liquid fertilizer containing high phosphate levels as the spray carrier, always usethe higher rate of Gramoxone SL 2.0 and surfactant.

Note: When using liquid fertilizers such as 28% N as a spray carrier, it is important thatnonionic surfactant still be used with Gramoxone SL 2.0. Liquid fertilizer carriers cannotsubstitute for surfactant.

RATES OF GRAMOXONE SL 2.0

Follow rates listed with each use of Gramoxone SL 2.0. Use the higher label rateswhen weeds are dense or large. Also, use higher label rates for harvest aid when cropvegetation is dense. For broadcast applications of Gramoxone SL 2.0 with backpack

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sprayers, the application rate must not exceed 0.50 Ibs. a.i./A (one quart) in a minimumof 30 gallons of spray solution per acre.

SPRAY VOLUME

Follow minimum spray volumes listed with each use of Gramoxone SL 2.0. These areminimum volumes only, and spray volumes should be increased as necessary toobtain complete coverage of the target weed or plant without runoff from the foliage.

WHEN SPRAYING LESS THAN 20 GALLONS OF SPRAY CARRIER PER ACRE,TARGET WEEDS SHOULD NOT EXCEED 6 INCHES IN HEIGHT.

APPLICATION TIMING

Gramoxone SL 2.0 should be applied to emerged weeds when they are small.Weeds 1-6 inches in height are the easiest to control. Larger weeds may be moredifficult to control. When weeds have been grazed or mowed, thus removing much ofthe green foliage, allow the weeds to regrow to a height of 2-4 inches before spraying ifpossible. Similarly, when forage or grain crops have been harvested prior to spraying,weeds present in the field will also have been cut. To allow for adequate green foliageto remain on weeds in this situation, raise cutter bars as high as possible from theground to cut stubble and weeds at a greater height.

BURNDOWN OF GRASS COVER CROPS OR VOLUNTEER CEREALS

When using Gramoxone SL 2.0 for control of grass cover crops or volunteer cereals,best results are obtained when Gramoxone SL 2.0 is applied prior to tillering or afterboot stage. This is especially important with a wheat cover crop or volunteer wheat.Treatments made between tillering and boot stage will generally not provide completecontrol. Do not expect complete control of perennial cover crops.

ENVIRONMENTAL CONDITIONS

Gramoxone SL 2.0 is active over a wide range of environmental conditions. Coolweather (below 55°) will slow the activity of Gramoxone SL 2.0, as will cloudy, overcastweather, but will not affect performance.

SPOT SPRAYING

When only small areas are to be sprayed with labeled applications, it is advantageousto mix small quantities of Gramoxone SL 2.0. To aid in mixing small quantities, thefollowing table should be consulted.

r \h-15-

If The Broadcast Rate Per Acre forGramoxone SL 2.0 is:

11/2pts.2 pts.

21/2 pts.3 pts.

Add The Following Amount of GramoxoneSL 2.0 To 1 Gallon of Water

1/3 fl. oz.3/8 fl. OZ.1/2 fl. OZ.

2/3 fl. OZ.

Always add Vz-Vz fl. oz. of a nonionic surfactant for each gallon of spray. When spotspraying in this manner, spray to thoroughly wet the foliage, but not to the point ofrunoff.

TANK MIXING FOR IMPROVED BURNDOWN OF DIFFICULT WEEDS ANDRESIDUAL WEED CONTROL

Photosynthetic Inhibitor Herbicides

Difficult weeds can often be controlled by tank mixing Gramoxone SL 2.0 with otherherbicides. The addition of herbicides which are also photosynthetic inhibitors (PSI) willslow the activity of Gramoxone SL 2.0, allowing Gramoxone SL 2.0 to thoroughlydistribute itself within the treated leaf. The resulting level of control is usually greaterthan if Gramoxone SL 2.0 was applied alone.

Gramoxone SL 2.0 may be applied in tank mixture with the following PSI herbicides:

AAtrex® HerbicideAtrazineBicep Magnum®Bicep II Magnum® HerbicideBicep Lite II Magnum® HerbicideBoundary® 6.SEC HerbicideCanopy® HerbicideCaparol® 4L Herbicide

Cotoran® HerbicideLorox® HerbicidesLorox Plus® HerbicidePrincep® HerbicideSencor® HerbicideSinbar® HerbicideSpike® Herbicide

Refer to respective product label(s) for rates of application, directions for use,limitations, cautions and for a list of weeds controlled.

Improved Weed Control With PSIs

Control of difficult weeds listed below and annual grass control will be enhanced by theaddition of a PSI herbicide. For best results a second application is needed.

l n 6to-16-

Barnyardgrass Horseweed (Marestail)Broadleaf signalgrass MorninggloryCheatgrass Pennsylvania SmartweedCocklebur Perennial Weeds (suppression only)Fall Panicum Prickly lettuceGiant Ragweed SedgesKnotweed TansymustardKochia VelvetleafLambsquarters Volunteer wheatMalva (Cheeseweed) Spiderwort

Improved Control of Perennial and Annual Broadleaf Weeds

When perennial broadleaf weeds such as Canada thistle, bindweed, dandelion, etc. ordifficult to control annual broadleaf weeds such as giant ragweed or morningglory arepresent, tank mixes with 2,4-D ester (Low Volatile), 2,4-DB, Clarity®, Banvel®, orFlexstar® where labeled, will help improve control. Tank mixing the amine formulationof 2,4-D with Gramoxone SL 2.0 may result in reduced grass control.

Order of Tank Mixing

In general, Gramoxone SL 2.0 tank mixes with other products should be mixed asfollows:

1. Fill spray tank Yz full with clean water or other approved carriers such as clearliquid fertilizer. •

2. Add nonionic surfactant to tank3. Begin tank agitation and continue throughout mixing and spraying.4. Add dry formulations (WP, DF, etc.) to tank.5. Add liquid formulations (SC, EC, L, etc.) to tank.6. Add Gramoxone SL 2.0 to tank.7. Add crop oil concentrate or methylated seed oil to tank where needed.8. Fill remainder of spray tank.

Always refer to labels of other pesticide products for mixing directions and precautionswhich may differ from those outlined here.

Since many of the herbicides listed on this label are available in several types offormulations, it is advisable to perform a jar test to check physical compatibility.

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PRECAUTIONS AND RESTRICTIONS

EQUIPMENT/CONTAINER

Flush all spray equipment with water after use each day. Gramoxone SL 2.0 iscorrosive to aluminum. Aluminum spray equipment and aluminum aircraft structuresthat are exposed to spray solution or spray drift should be flushed thoroughly with waterimmediately after use.

In dry areas, dust stirred up by high winds or equipment tires can coat weed or plantleaves and reduce Gramoxone SL 2.0 activity. Avoid applying Gramoxone SL 2.0 inextremely dusty conditions.

LIMITATIONS AND PRECAUTIONS

• For Cotton Harvest Aid: Do not pasture livestock in treated fields or feed treatedfoliage.

• DO NOT use around home gardens, schools, recreational parks, or playgrounds.

• In preplant and preemergence (to the crop) uses, do not apply to soils lacking clayminerals, i.e., peat, muck, pure sand, artificial planting media.

• Seedbeds and plantbeds should be formed as far ahead of planting and treatmentas possible to permit maximum weed and grass emergence prior to treatment.

• To reduce germination of new weeds, seeding or transplanting should be done witha minimum amount of soil disturbance.

• Gramoxone SL 2.0 used for preplant weed control over the top of plastic mulch maydamage transplants which come in contact with the plastic. Sufficient rainfall orsprinkler irrigation to cause wash-off prior to planting may be needed to preventdamage to the crop.

• Weeds and grasses emerging after application of Gramoxone SL 2.0 will not becontrolled or suppressed.

• Unless otherwise indicated, crop plants emerged at time of application may beseverely injured or killed if contacted by sprays of Gramoxone SL 2.0.

( h to-18-

PARAQUAT-RESISTANT WEED MANAGEMENT

Some naturally occurring weed biotypes resistant to paraquat may exist through normalgenetic variability in any weed population. The repeated use of herbicides with thesame mode of action is known to lead under certain conditions to a selection of resistantweeds. Certain agronomic practices reduce the likelihood that resistant weedpopulations will develop and integrated strategies are known to manage such problemweeds.

The active ingredient in Gramoxone SL 2.0 is paraquat, a mechanism of action Group22 herbicide, which inhibits Photosystem I.

Within the USA specific biotypes of a number of species, including horseweed/marestail(Conyza canadensis), hairy fleabane (Conyza bonariensis), goosegrass (Eleusineindica) and American black nightshade (Solanum americanum) have become resistantto paraquat.

General principles of herbicide resistance management:

Apply integrated weed management practices. Use multiple herbicide mechanisms ofaction with overlapping weed spectrums in rotation, sequences or mixtures.

Use the full specified herbicide rate and proper application timing for the hardest tocontrol weed species present in the field.

Scout fields after herbicide application to ensure control has been achieved. Avoidallowing weeds to reproduce by seed or to proliferate vegetatively.

Monitor site and clean equipment between sites.

For annual cropping situations also consider the following:

Start with a clean field and control weeds early by using a burndown treatment or tillagein combination with a preemergence residual herbicide as appropriate.

Use cultural practices, such as cultivation and crop rotation, where appropriate.

Use good agronomic principles that enhance crop competitiveness.

Contact your local extension specialist, certified crop advisor, and/or manufacturer forherbicide resistance management and/or integrated weed managementrecommendations for specific crops and resistant weed biotypes.

-19-

Since the occurrence of resistant weeds is difficult to detect prior to use, Syngentaaccepts no liability for any losses that may result from the failure of Gramoxone SL 2.0to control resistant weeds.

APPLICATION INSTRUCTIONS AND CROP USE DIRECTIONS

The following tables indicate use patterns, rates, minimum spray volumes, preharvestintervals and other precautions, restrictions and comments specific to each crop. Readand follow directions carefully.

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ssar

y.•

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not a

llow

spr

ay to

con

tact

cac

ao p

lant

s as

inju

rym

ay r

esul

t. U

se a

shi

eld

for

youn

g tre

es.

• D

o no

t spr

ay u

nder

win

dy c

ondi

tions

.•

Do

not g

raze

trea

ted

area

s or

feed

trea

ted

cove

rcr

ops

to li

vest

ock.

,-

O -!2CM <"

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pply

whe

n w

eeds

are

suc

cule

nt a

nd g

row

th i

s 1-

6".

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n ca

ssav

as,

do n

ot m

ake

mor

e th

an 3

app

licat

ions

per

crop

sea

son.

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yam

s do

not

mak

e m

ore

than

2 a

pplic

atio

ns p

ercr

op s

easo

n.D

o no

t allo

w s

pray

to c

onta

ct c

assa

vas

or y

ampl

ants

as

inju

ry m

ay r

esul

t.•

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not s

pray

und

er w

indy

con

ditio

ns.

> D

o no

t gra

ze tr

eate

d ar

eas

or fe

ed t

reat

ed f

orag

e to

lives

tock

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O

t/jeno^

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n CM

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se h

ighe

r sp

ray

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mes

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ter

cove

rage

as

dens

ity o

f stu

bble

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op r

esid

ue o

r w

eeds

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ease

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r do

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ener

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k be

st w

ithG

ram

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e S

L 2.0

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poss

ible

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nk m

ix w

ithA

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ine

for

max

imum

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ndow

n an

d re

sidu

al

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0 TO

ns c "30 0 cm0) co E(D fl) Ow o: o

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rop

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pplic

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ed.

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y gr

ound

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licat

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ly 5

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er a

cre.

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pply

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utili

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zzle

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• S

pray

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rodu

ce s

eed.

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olun

teer

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at a

nd d

owny

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me

cont

rol a

re b

ette

r,'

with

late

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ust o

r ea

rly S

epte

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r ap

plic

atio

ns.

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nk m

ix w

ith A

trazi

ne M

arks

man

® H

erbi

cide

, or

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man

d® H

erbi

cide

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enha

nced

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ndow

n an

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sidu

al w

eed

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rol.

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ank

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in,

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cor

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orbu

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wn

and

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trol

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rass

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ds.

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efer

to th

e pr

oduc

t la

bels

for

spe

cific

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rat

es fo

ryo

ur s

oil t

ype,

use

dire

ctio

ns,

caut

ions

and

a li

st o

fw

eeds

con

trolle

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er to

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mic

al F

allo

w U

se In

form

atio

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ctio

n.

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• A

pplic

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n sh

ould

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mad

e M

arch

1 t

o A

pril

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r to

spr

ing

rain

s to

con

serv

e m

oist

ure.

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olun

teer

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ier

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ontr

ol a

fter

the

boot

stag

e, b

ut s

oil

moi

stur

e lo

ss w

ill b

e gr

eate

r.•

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at

leas

t 2.0

pts

. of

Gra

mox

one

SL

2.0

per

acre

with

a P

SI

(see

Photo

synth

etic

Inhib

itor

Her

bici

des

sect

ion)

for

vol

unte

er w

heat

or

dow

nybr

ome

cont

rol

in t

he s

prin

g.•

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er to

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mic

al F

allo

w U

se In

form

atio

nse

ctio

n.•

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mix

with

met

ribuz

in,

(Sen

cor)

for

bur

ndow

nan

d re

sidu

al c

ontro

l of g

rass

and

bro

adle

af w

eeds

.•

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er to

the

met

ribuz

in,

(Sen

cor)

labe

l for

use

rat

esfo

r yo

ur s

oil t

ype,

use

dire

ctio

ns,

caut

ions

, an

dw

eeds

con

trolle

d.

•

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mat

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lt yo

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in id

entif

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the

bla

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yer,

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non

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c

• In

itiat

e sp

rays

in la

te J

une

to e

arly

Jul

y an

d re

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ust

if re

grow

th o

ccur

s.•

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low

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licat

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inst

ruct

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in

post

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rect

ed s

pray

sec

tion

abov

e.

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^jcoO

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mer

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ere

cted

spr

ayS

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hwee

dra

dica

tion

rogr

am

CL -0 U LU CL

CO

*1 °>

* §

Z ifK£O -oO £

S.Eilj 2ES

« A

pply

as

a di

rect

ed s

pray

ont

o gr

assy

wee

ds a

ndw

itchw

eed

befo

re w

itchw

eed

bloo

ms.

R

eapp

ly if

regr

owth

occ

urs.

• F

ollo

w a

pplic

atio

n in

stru

ctio

ns i

n po

stem

erge

nce

dire

cted

spr

ay s

ectio

n ab

ove.

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tic

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• D

o no

t exc

eed

12 p

ints

Gra

mox

one

SL

2.0

(3 Ib

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tive

ingr

edie

nt)

per

acre

per

sea

son

for

all

uses

cco

tton.

<n

H1o0

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M- *

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se D

irect

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ton I

T3

• A

pply

prio

r to,

dur

ing

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fter

plan

ting,

but

bef

ore

crop

em

erge

nce.

« Fo

r fa

llow

bed

trea

tmen

t, be

ds s

houl

d be

pre

form

eto

per

mit

max

imum

wee

d an

d gr

ass

emer

genc

epr

ior

to t

reat

men

t.•

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ding

sho

uld

be d

one

with

a m

inim

um o

f soi

ldi

stur

banc

e.

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T3C

l.y

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co

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• F

or c

ontro

l of v

olun

teer

bar

ley

in p

refo

rmed

seed

beds

.CO COco coen eno inT~

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0.

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T3CUCO

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CO

TT

ON

(Cal

iforn

ia o

alon

e)•

Ref

er to

Goa

l la

bel

for

spec

ific

use

dire

ctio

ns a

ndre

stric

tions

, an

d w

eeds

con

trolle

d.

COcoeno-r"

c

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repl

ant o

r F

allo

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co

c

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TT

ON

Goa

l™ H

erb

Mix

• A

pply

as

a br

oadc

ast s

pray

bef

ore,

dur

ing

or a

fter

plan

ting,

but

bef

ore

crop

em

erge

nce.

» Fo

r im

prov

ed b

urnd

own

or r

esid

ual c

ontro

l, .

Gra

mox

one

SL

2.0

may

be

tank

mix

ed w

ith th

efo

llow

ing

herb

icid

es:

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oran

, D

ual M

agnu

m,

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uron

®,

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ton-

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arol

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iuro

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ra (

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plan

t O

nly)

, M

SM

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wl,

Zor

ial®

.•

Whe

n ta

nk m

ixin

g w

ith C

otor

an D

F o

r M

etur

on D

F,

follo

w m

ixin

g in

stru

ctio

ns in

the

Ord

er o

f T

ank

Mix

ing

sec

tion

care

fully

and

mai

ntai

n co

nsta

ntag

itatio

n.•

Whe

n ta

nk m

ixin

g w

ith a

ny o

f the

her

bici

des

liste

dab

ove,

ref

er to

that

pro

duct

's la

bel f

or s

peci

ficdi

rect

ions

and

res

trict

ions

and

for

a li

st o

f w

eeds

cont

rolle

d.

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8

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ALFALFA

Table 2. New Seedlings - Suppression and control of broadleaf weeds andgrasses in new alfalfa seedlings grown for hay (California only)

For Control of:Spikeweed(4 inches tall or less)Volunteer Small Grain(8 inches tall or less)Fiddleneck(6 inches tall or less)ShepherdspurseAnnual BluegrassChickweedRed Maids(6 inches tall or less)

Rate/ Ac reFor Suppression

8 fl. oz.

8-1 6fl.oz.

8-1 6fl.cz.

16-32fl. oz.---

For Control16-24fl. oz.

32 fl. oz.

32 fl. oz.

-16-32fl. oz.16-32fl. oz.16-32fl. oz.

Do not use the 8.0 fl. oz. rate unless the alfalfa has at least 3 trifoliate leaves; the 16.0fl. oz. rate unless the alfalfa has 6 trifoliate leaves; or rates over 16.0 fl. oz. unless thereare 9 trifoliate leaves.

RESIN SOAKING

Pines (Loblolly, Shortleaf, Longleaf, Slash, Virginia, Pond, Pitch, and Spruce Pines)

Tree Selection - Select trees to be treated from stands on sites not subject to periodsof extreme drought stress as the desiccating effect of Gramoxone SL 2.0 to pines isaccentuated during such periods, causing a reduction in the amount of oleoresindeposited in the xylem. Select trees to be treated from vigorous, nonstagnated stands,either natural or planted. In stagnated stands or commercial timber stands, plantreating with Gramoxone SL 2.0 not sooner than three years after a commercialthinning.

Application Directions - Apply Gramoxone SL 2.0 diluted in water to a suitable woundin the tree trunk to bring the treatment into contact with the xylem (sapwood).

Bark Streaks or Cuts: This type of wound is made using a standard or rotary barkhack or a chainsaw chipping tool employed in naval stores work to remove a single 1-inch wide streak of bark about 1-2 ft. from ground level. The total length should notexceed 1/3 of the tree circumference. Multiple streaks or cuts can result in seriousgirdling of the trunk and premature death of the tree. A coarse spray (about 1.7-5.0 ml.)Gramoxone SL 2.0 solution (1-5% cation, wt./wt. basis) should be applied to runoff tothe exposed xylem, using a low-pressure sprayer. The amount of spray required percut depends on tree circumference and the length of cut or streak (1/3 of

r-60-

circuinference). For a 9-inch diameter tree, 3 ml. of spray will cover the 1-inch widestreak. Using 3 ml. of a 3 or 6% Gramoxone SL 2.0 solution will result in application of60 or 120 mg. Gramoxone SL 2.0 per streak.

Time of Treatment: Resin soaking can occur from treatments made any time of theyear; however, cool season treatments under nondrought conditions usually result inless severe pine beetle infestations and longer tree life.

Interval Between Treatment and Tree Harvest: The interval between application ofGramoxone SL 2.0 and tree harvest should be a minimum of 6 months and preferablyfrom 12-24 months. Intervals of over 6 months may not be possible under conditions ofdrought or serious pine beetle attacks, which may make early harvest necessary. TheGramoxone SL 2.0 treatment may encourage beetle attack, or may cause prematuredeath of the tree. Desiccation of the xylem tissue, rather than the desired resinsoaking, may occur, and is more likely at higher dosage rates.

Effect on Stem Growth: Gramoxone SL 2.0 treatment can result in reduced stemgrowth during the interval between treatment and tree harvest.

Dilution Table for Gramoxone SL 2.0 (2.0 Ibs. cation per gallon):

Concentration of CationDesired (Wt./Wt. Basis)

To 1 Gallon ofGramoxone SL 2.0 Add the Following

No. Gals, of Water:0.2%0.5%1.0%2.0%3.0%4.0%5.0%

118.846.822.910.96.94.93.7

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Conversion TableGramoxone SL 2.0 to Be Applied

Ounces16.024.032.040.048.056.064.0

Pints1.01.52.02.53.03.54.0

Lb. a.i.0.250.3750.50.6250.750.8751.00

Acres/Gallon8.006.004.003.202.662.282.00

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-80-

STORAGE AND DISPOSAL

Do not contaminate water, food, or feed by storage and disposal.

Pesticide Storage

Store at temperatures above 32°F.

Pesticide Disposal

Pesticides wastes are acutely hazardous. Improper disposal of excess pesticide, spraymixture, or rinsate is a violation of Federal law. If these wastes cannot be disposed ofby use according to label instructions, contact your State Pesticide or EnvironmentalControl Agency, or the Hazardous Waste representative at the nearest EPA RegionalOffice for guidance.

Container Handling [less than 5 gallons]

Non-refillable container. Do not reuse or refill this container. Offer for recycling ifavailable. Triple rinse container (or equivalent) promptly after emptying. Triple rinse asfollows: Empty the remaining contents into application equipment or a mix tank anddrain for 10 seconds after the flow begins to drip. Fill the container % full with water andrecap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank orstore rinsate for later use and disposal. Drain for 10 seconds after the flow begins todrip. Repeat this procedure two more times. Then offer for recycling if available orpuncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by stateand local authorities, by burning. If burned, stay out of smoke.

Container Handling [greater than 5 gallons]

Refillable container. Refill this container with pesticide only. Do not reuse this containerfor any other purpose. Cleaning the container before final disposal is the responsibilityof the person disposing of the container. Cleaning before refilling is the responsibility ofthe person refilling. To clean container before final disposal, empty the remainingcontents from this container into application equipment or mix tank. Fill the containerabout 10 percent full with water. Agitate vigorously or recirculate water with the pumpfor 2 minutes. Pour or pump rinsate into application equipment or rinsate collectionsystem. Repeat this rinsing procedure two more times. Then offer for recycling ifavailable or puncture and dispose of in a sanitary landfill, or by incineration, or by otherprocedures allowed by state and local authorities.

For help with any spill, leak or fire involving this material, call 1-800-888-8372.

CONTAINER IS NOT SAFE FOR FOOD, FEED OR DRINKING WATER!

r r-81-

AAtrex®, Ambush®, Bicep Magnum®, Bicep II Magnum®, Bicep Lite II Magnum®,Boundary® 6.SEC, Callisto®, Caparol®, Devrinol®, Dual Magnum®, Gramoxone SL2.0, Flexstar®, Karate®, Lexar®, Lumax®, Princep®, Reglone®, Solicam®, Zorial®, theALLIANCE FRAME, the SYNGENTA Logo, and the PURPOSE ICON are Trademarksof a Syngenta Group Company

Accelerate® trademark of Cerexagri, Inc.

Authority®, Canopy®, Harmony® Extra, Gemini®, Karmex®, Krovar®, Linex®, Lorox®,Lorox Plus™, Sinbar®, Velpar®, and Viton® trademarks of E. I. du Pont de Nemours &Company, Inc.

Balance®, DEF®, Dropp®, Hoelon®, Prep™ and Sencor® trademarks of BayerCropScience

Banvel®, Basagran®, Clarity®, Distinct®, Frontier®, Guardsman®, Marksman®,Prowl®, Pursuit®, and Scepter® trademarks of BASF Ag Products

Butoxone® and Cotoran® trademarks of Makhteshim-Agan of North America, Inc.

Butyrac® trademark of Agri Star/Albaugh, Inc.

Command® trademark of FMC Corporation

Cotton-Pro® and Meturon® trademarks of Griffin LLC

Degree™, Degree Xtra™, and Harness® trademarks of Monsanto AgriculturalCompany

Ethephon® trademark of Micro Flo Company LLC

Folex® trademark of AMVAC Chemical Corporation

Firstrate™, Fultime™, Goal™, Spike®, and Surflan® trademarks of Dow AgroSciences

Harvade® trademark of Uniroyal Chemical Company

©201X Syngenta

For non-emergency (e.g., current product information), callSyngenta Crop Protection at 1-800-334-9481.

( 83-82-

Manufactured for:Syngenta Crop Protection, LLCP.O. Box 18300Greensboro, North Carolina 27419-8300

SCP 1431A

-83-

(Base/Container Label)

RESTRICTED USE PESTICIDEDUE TO ACUTE TOXICITY

FOR RETAIL SALE TO AND USE ONLY BY CERTIFIED APPLICATORS ORPERSONS UNDER THEIR DIRECT SUPERVISION AND ONLY FOR THOSE USES

COVERED BY THE CERTIFIED APPLICATOR'S CERTIFICATION.

Gramoxone SL 2.0HERBICIDE

Herbicide

A Weed, Grass, and Harvest Aid Desiccant/Defoliant Herbicide

Active Ingredient:Paraquat dichloride (1,1'-dimethyl-4,4'-bipyridinium dichloride) 30.1%Other Ingredients: 69.9%Total: 100.0%

Contains 2.0 pounds paraquat cation per gallon as 2.762 pounds salt per gallon.Contains alerting agent (odor), emetic, and dye.

EPA Reg. No. 100-1431

EPAEst.

See directions for use in attached booklet.

AGRICULTURAL USE REQUIREMENTSUse this product only in accordance with its labeling and with the Worker ProtectionStandard, 40 CFR part 170. Refer to supplemental labeling under "Agricultural UseRequirements" in the Directions for Use section for information about this standard.

• NEVER PUT INTO FOOD, DRINK OR OTHER CONTAINERS.• IF SWALLOWED, TAKE IMMEDIATE ACTION AS PRESCRIBED IN FIRST AID

STATEMENT. SYMPTOMS ARE PROLONGED AND PAINFUL.• DO NOT USE OR STORE IN OR AROUND THE HOME.• DO NOT REMOVE CONTENTS EXCEPT FOR IMMEDIATE USE.« THE ODOR OF THIS PRODUCT IS FROM THE ALERTING AGENT WHICH HAS

BEEN ADDED, NOT FROM PARAQUAT.

Gramoxone SL 2.0 and the Syngenta logo are trademarks of a Syngenta GroupCompany

©201X Syngenta

r-84-

Manufactured for:Syngenta Crop Protection, LLCP.O. Box18300Greensboro, NC 24719-8300

1 gallon2.5 gallons30 gallons120 gallons

gallonsNet Contents

r-85-



Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted endetails. (If you do not understand the label, find someone to explain it to you in detail.)

FIRST AIDContains Paraquat, a Bipyridylium HerbicideIf swallowed: SPEED IS ESSENTIAL. Immediate medical attention is required. Ifavailable, give an adsorbent such as activated charcoal, bentonite or Fuller's Earth.Call a poison control center or doctor immediately for treatment advice. Do not giveanything by mouth to an unconscious person.If inhaled: Move person to fresh air. The odor of this product is from the alertingagent, which has been added, not from the paraquat. If person is not breathing, call911 or an ambulance. Call a poison control center or doctor for further treatmentadvice.If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes.Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.Call a poison control center or doctor for treatment advice.If on skin or clothing: Take off contaminated clothing. IMMEDIATELY wash withsoap and water and rinse for 15-20 minutes. Prolonged contact will cause severeirritation. Contact with irritated skin or a cut or repeated contact with intact skin mayresult in poisoning. GET MEDICAL ATTENTION. Call a poison control center or doctorfor treatment advice.NOTE TO PHYSICIANRefer to the booklet 'Paraquat Poisoning. A Practical Guide to Diagnosis, First Aid andHospital Treatment1 (http://www.svngenta.com/pqmedguide). Administer eitheractivated charcoal (100g for adults or 2g/kg body weight in children) or Fuller's Earth(15% solution; 1 liter for adults or 15ml/kg body weight in children). NOTE: The use ofgastric lavage without administration of an adsorbent has not shown any clinical benefit.Do not use supplemental oxygen. Eye splashes from concentrated material should betreated by an eye specialist after initial treatment. With the possibility of late onsetcorneal ulceration, it is advised that patients with paraquat eye injuries are reviewed byan eye specialist the day after first presentation. Use treatment that is appropriate forchemical burns. Intact skin is an effective barrier to paraquat, however contact withirritated or cut skin or repeated contact with intact skin may result in poisoning.Have the product container or label with you when calling a poison control center ordoctor, or going for treatment.HOT LINE NUMBER: For 24-Hour Medical Emergency Assistance (Human or Animal)Or Chemical Emergency Assistance (Spill, Leak, Fire or Accident) Call 1-800-888-8372.

-86-

[BACK LABEL]



PRECAUTIONARY STATEMENTS

HAZARDS TO HUMANS AND DOMESTIC ANIMALS

May be fatal if swallowed. Fatal if inhaled. Do not breathe spray mist. Wear a dustmist NIOSH-approved respirator with any N, R, P, or HE filter. Causes substantial buttemporary eye injury. Wear protective eyewear (face shield required whenmixing/loading). Harmful if absorbed through skin. Do not get in eyes, on skin, or onclothing. Avoid contact with skin.

IMPORTANT: Inhalation is an unlikely route of exposure due to low vapor pressure andlarge spray droplet size, but mucosal irritation or nose bleeds may occur. Prolongedcontact with this concentrated product can irritate your skin.

Environmental Hazards

Wildlife: This product is toxic to wildlife. Do not apply directly to water or to areaswhere surface water is present or to intertidal areas below the mean high water mark.Do not contaminate water when cleaning equipment or disposing of equipmentwashwaters.

Drift: Gramoxone SL 2.0 is a contact herbicide that desiccates all green plant tissue.Paraquat dichloride is toxic to nontarget crops and plants if off-target movement occurs.Extreme care must be taken to ensure that off-target drift is minimized to the greatestextent possible. Do not apply under conditions involving possible drift to food, forage, orother plantings that might be damaged or the crops thereof rendered unfit for sale, use,or consumption. Do not apply when weather conditions favor drift from treated areas.To avoid drift, do not make aerial applications during periods of thermal inversion.Refer to the local state laws, regulations, guidelines and spray drift informationcontained in the Directions for Use section for proper application to avoid off-targetmovement.

Physical and Chemical HazardsThis product is mildly corrosive to aluminum and produces hydrogen gas which mayform a highly combustible gas mixture. Do not mix or store in containers, spray tanks,

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nurse tanks, or such systems made of aluminum or having aluminum fittings. Thisproduct is compatible with high density polyethylene and rubber lined steel containers.

[Warranty Statement on 30, 120, Bulk Only]CONDITIONS OF SALE AND LIMITATION OF WARRANTY AND LIABILITY

NOTICE: Read the entire Directions for Use and Conditions of Sale and Limitation ofWarranty and Liability before buying or using this product. If the terms are notacceptable, return the product at once, unopened, and the purchase price will berefunded.

The Directions for Use of this product must be followed carefully. It is impossible toeliminate all risks inherently associated with the use of this product. Crop injury,ineffectiveness or other unintended consequences may result because of such factorsas manner of use or application, weather or crop conditions, presence of other materialsor other influencing factors in the use of the product, which are beyond the control ofSYNGENTA CROP PROTECTION, LLC or Seller. To the extent permitted byapplicable law, Buyer and User agree to hold SYNGENTA and Seller harmless for anyclaims relating to such factors.

SYNGENTA warrants that this product conforms to the chemical description on the labeland is reasonably fit for the purposes stated in the Directions for Use, subject to theinherent risks referred to above, when used in accordance with directions under normaluse conditions. To the extent permitted by applicable law: (1) this warranty does notextend to the use of the product contrary to label instructions or under conditions notreasonably foreseeable to or beyond the control of Seller or SYNGENTA, and, (2) Buyerand User assume the risk of any such use. TO THE EXTENT PERMITTED BYAPPLICABLE LAW, SYNGENTA MAKES NO WARRANTIES OF MERCHANTABILITYOR OF FITNESS FOR A PARTICULAR PURPOSE NOR ANY OTHER EXPRESS ORIMPLIED WARRANTY EXCEPT AS WARRANTED BY THIS LABEL.

To the extent permitted by applicable law, in no event shall SYNGENTA be liable forany incidental, consequential or special damages resulting from the use or handling ofthis product. TO THE EXTENT PERMITTED BY APPLICABLE LAW, THEEXCLUSIVE REMEDY OF THE USER OR BUYER, AND THE EXCLUSIVE LIABILITYOF SYNGENTA AND SELLER FOR ANY AND ALL CLAIMS, LOSSES, INJURIESOR DAMAGES (INCLUDING CLAIMS BASED ON BREACH OF WARRANTY,CONTRACT, NEGLIGENCE, TORT, STRICT LIABILITY OR OTHERWISE)RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT, SHALL BE THERETURN OF THE PURCHASE PRICE OF THE PRODUCT OR, AT THE ELECTIONOF SYNGENTA OR SELLER, THE REPLACEMENT OF THE PRODUCT.

SYNGENTA and Seller offer this product, and Buyer and User accept it, subject to theforegoing Conditions of Sale and Limitation of Warranty and Liability, which may not bemodified except by written agreement signed by a duly authorized representative ofSYNGENTA.

STORAGE AND DISPOSALDo not contaminate water, food, or feed by storage and disposal.

Pesticide StorageStore at temperatures above 32°F.

Pesticide DisposalPesticides wastes are acutely hazardous. Improper disposal of excess pesticide, spraymixture, or rinsate is a violation of Federal law. If these wastes cannot be disposed ofby use according to label instructions, contact your State Pesticide or EnvironmentalControl Agency, or the Hazardous Waste representative at the nearest EPA RegionalOffice for guidance.

Container Handling [less than 5 gallons]Non-refillable container. Do not reuse or refill this container. Offer for recycling ifavailable. Triple rinse container (or equivalent) promptly after emptying. Triple rinse asfollows: Empty the remaining contents into application equipment or a mix tank anddrain for 10 seconds after the flow begins to drip. Fill the container % full with water andrecap. Shake for 10 seconds. Pour rinsate into application equipment or a mix tank orstore rinsate for later use and disposal. Drain for 10 seconds after the flow begins todrip. Repeat this procedure two more times. Then offer for recycling if available orpuncture and dispose of in a sanitary landfill, or by incineration, or, if allowed by stateand local authorities, by burning. If burned, stay out of smoke.

Container Handling [greater than 5 gallons]Refillable container. Refill this container with pesticide only. Do not reuse this containerfor any other purpose. Cleaning the container before final disposal is the responsibilityof the person disposing of the container. Cleaning before refilling is the responsibility ofthe person refilling. To clean container before final disposal, empty the remainingcontents from this container into application equipment or mix tank. Fill the containerabout 10 percent full with water. Agitate vigorously or recirculate water with the pUmpfor 2 minutes. Pour or pump rinsate into application equipment or rinsate collectionsystem. Repeat this rinsing procedure two more times. Then offer for recycling ifavailable or puncture and dispose of in a sanitary landfill, or by incineration, or by otherprocedures allowed by state and local authorities.

For help with any spill, leak or fire involving this material, call 1-800-888-8372.

CONTAINER IS NOT SAFE FOR FOOD, FEED OR DRINKING WATER!

GRAMOXONESL 2.0 1431 MAS 0812-bb-11-19-12GRAMOXONE SL 2.0 1431 MAS 0812-tb - 11-29-12GRAMOXONE SL2.0 1431 MAS 0812 AMEND NOV2012-clean.pdf000100-01431.20121129.GRAMOXONESL2.0_AMEND_NOV2012.pdf

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GRAMOXONE SL 2.0 1431 MAS 0812 - tb - 1-21-13GRAMOXONE SL 2.0 1431 MAS 0812 AMEND NOV2012-clean.pdf000100-01431.20121129B.GRAMOXONESL2.0_AMEND_NOV2012.pdf

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