unit b chemistry and the environment
TRANSCRIPT
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Science 30
Unit B – Chemistry and the Environment
Outcome 2: Students will analyze the sources of organic compounds and their effects
on the environment.
Specific Outcome 2.1: Identify and name carbon compounds, using
International Union of Pure and Applied Chemistry (IUPAC) nomenclature that
contain up to three carbon atoms in the parent chain and a single occurrence
of one type of functional group, including simple halogenated hydrocarbons,
alcohols, carboxylic acids and esters.
Specific Outcome 2.2: Describe the common uses of hydrocarbons, including
simple halogenated hydrocarbons, alcohols, carboxylic acids and esters.
Textbook reference pages: p. 241 – 278 in Science 30
ORGANIC CHEMISTRY
ETHER BUNNIES! https://www.youtube.com/watch?v=2DBSQswHTsw
FLASHBACK TO SCIENCE 20
Organic compound naming – page 9 of your data booklet has everything you will
need.
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-ane, -ene, -yne
Name Formula
METH 1 Carbon
ETH 2 Carbons
PROP 3 Carbons
BUT 4 Carbons
PENT 5 Carbons
HEX 6 Carbons
HEPT 7 Carbons
OCT 8 Carbons
NON 9 Carbons
DEC 10 Carbons
A. SINGLE BONDS End with -ANE
Butane
B. DOUBLE BONDS End with -ENE
Ethene
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C. TRIPLE BONDS End with -YNE
Ethyne
Saturated vs. Unsaturated:
- Saturated hydrocarbons - only single bonds between carbon atoms
- Unsaturated hydrocarbons - one or more double or triple bonds between carbon
atoms
How do we know how to draw them with a single, double or triple bond?
CnH(2n+2) All single bonds
CnH(2n) One double bond, all the rest are single
CnH(2n-2) One triple bond, all the rest are single
Examples: Will there be single, double or triple bonds???
A. C6H14 single bonded
B. C6H10 triple bonded
C. C5H10 double bonded
Remember the general formulas: Alkanes – CnH2n+2
Alkenes – CnH2n
Alkynes – CnH2n-2
Alkane
Alkene
Alkyne
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Practice Drawing:
Chemical
Formula Structural Drawing
Saturated or
Unsaturated
C5H12
saturated
C5H10
unsaturated
C5H8
unsaturated
C6H14
saturated
C6H6 (circular)
Benzene
unsaturated
C6H12
unsaturated
Alkanes
- saturated hydrocarbons
- generic formula is C2Hn+2
- find the longest continuous chain of carbons...this is the parent chain. Name it by
the number of carbons (1=meth, 2=eth, 3=prop...see pg. 9 of data book). End
the name in 'ane'
Examples:
C-C-C-C C-C-C C-C-C-C
C C
C
butane
hexane
butane
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Branched Alkanes:
- alkane with smaller carbon groups attached (an alkyl group)
- Find the longest continuous chain of carbon atoms - this is the parent chain.
- Name the parent chain just like you would for the continuous alkanes
- Circle the branches (alkyl groups)
- Name each alkyl group using the prefix that corresponds to the number of
carbons (1 = meth,
2 = eth...) and use the suffix 'yl’
- Number the carbons on the parent chain to show the location of each alkyl
group (number them so that the alkyl groups occur at the lowest carbon number
possible)
To put the name all together:
- start with the alkyl groups. Put them in alphabetical order (order them by the
alkyl, not the carbon number).
- number the alkyl groups, using commas between numbers and hyphens
between numbers and letters.
Examples:
Branched Alkenes and Alkynes
- Alkenes - unsaturated hydrocarbon containing one or more carbon-carbon
double bond
- Alkyne - unsaturated hydrocarbon containing one or more carbon-carbon triple
bond
3-ethylhexane 2-methylpentane 3,4-dimethylhexane
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Naming these branches:
- alkenes end in “ene,” alkynes end in “yne”
- the double or triple bond must be included in the parent chain (it cannot be in a
branch)
- number the chain so that the carbons with the double or triple bond receive the
lowest number possible
- write the name of the parent chain. Indicate where the double or triple bond is
by including the number in between the prefix and the suffix.
o Eg. but-1-ene --the double bond is between carbon 1 and 2
- Find any branches off of the parent chain and name them in the same way as
you did for alkanes.
Practice:
4-methyl-2-hexene 2,4-dimethyl-1-hexene
2,3,3-trimethyl-2-pentane
2-ethyl-4-methyl-1-hexene
2,4-dimethyl-1-hexene 2,3-diethyl-1-heptene
propene ethane
methane
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6 – ethyl-4,5-dimethyloct-2-yne
2,2-dimethylpropane
2-methylprop-1-ene
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CYCLIC HYDROCARBONS
BENZENE
- A benzene ring is a hexagonal arrangement of 6 carbon molecules.
o The ring is arranged like this:
- Benzene may also have alkyl or other functional groups as branches.
o For example:
- Benzene rings may also be called aromatic rings or phenyl rings
- Despite having double bonds, benzene is a very stable molecule
o Benzene demonstrates unique bonding - the 'extra' electrons are shared
by all the carbons...in other words, the true structure cannot be
accurately represented by any one structure.
- Benzene may also be represented like this:
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FUNCTIONAL GROUPS
- A functional group is an arrangement of single atoms or groups of atoms, other
than carbon or hydrogen, attached to an organic molecule.
Examples of functional groups that we will be covering:
1. Halogenated hydrocarbons
2. Alcohols
3. Carboxylic Acids
4. Esters
1. HALOGENATED HYDROCARBONS
- These are regular hydrocarbons where the hydrogen’s
have been substituted for an element from the
halogens
o Chlorine, Fluorine, Bromine and Iodine
Naming Halogenated Hydrocarbons:
1. Name the parent chain (just like in alkanes/enes/ynes)
2. Find all side chains (just like before!)
a. For halogens, they will be named as follows
i. F – fluoro
ii. Cl – chloro
iii. I – iodo
iv. Br – bromo
3. If one halogen appears more than once, use the appropriate prefix (di, tri....)
4. Number your carbons to have functional groups on lowest address (just like we
did with branches) (if there are double or triple bonds, the bonds take priority.
5. If there is more than one halogen, order them alphabetically.
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Examples:
F
F – C – F tetrafluoromethane
F
Cl F
F – C – C – Cl 1,1,2-trichloro-1,2,2-trifluoroethane
Cl F
Cl
Cl – C – Cl tetrachloromethane
Cl
Br
C = C – C – C – C – C – C – C 3,3-dibromo-1-octene
Br
F F
C = C 1,1,2,2-tetraflouroethene
F F
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Chlorofluorocarbons (CFCs)
- Synthetic organic molecule where hydrogen molecules are replaced with
chlorine and fluorine (also called chlorofluorocarbons)
- Commonly used in air conditioning and refrigeration units
- CFCs are used as propellants in aerosol containers
- CFCs are also used in the manufacture of plastic foam products
2. ALCOHOLS
- Alcohols are a group of organic molecules that have a hydroxyl
functional group attached to a hydrocarbon
- A hydroxyl functional group is an oxygen atom bonded to a hydrogen
- Often times you will see it written as R-OH where R is your hydrocarbon
- Alcohols are one of the most important classes of organic molecules
H H H
H – C – C – C – O – H HYDROXYL FUNCTIONAL GROUP
H H H
Naming Alcohols
- Find the hydroxyl functional group (OH) Circle it!
- Determine the parent chain, numbering to place the hydroxyl group on the
lowest number
- Name the parent chain as we did before
- Change the ending to 'ol' to indicate that it is an alcohol
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Examples:
H
H – C – O – H methanol
H
H H
H – C – C – O – H ethanol
H H
H
H O H
H – C – C – C – H propan-2-ol
H H H
Draw the following propan-1-diol
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3. CARBOXYLIC ACIDS
- Vinegar (Ethanoic Acid) is a carboxylic acid
- Take a look at the structural diagram of vinegar and think about how
it is different than an alcohol
H O
H – C – C
H O – H
- Alcohols can be converted to carboxylic acids by adding certain types of
bacteria
- Ethanol (alcohol because of the “ol”) is converted into ethanoic acid (vinegar)
- Carboxylic acids contain both a hydroxyl group (OH) and a carbonyl group
(C=O).
o The hydroxyl group and the carbonyl group together form a carboxyl (this
is what makes a carboxylic acid).
SPECIAL NOTE ABOUT CARBOXYLIC ACIDS:
- Any carboxylic acid can react with water to form hydronium ions (H3O+)
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Naming Carboxylic Acids:
1. They are named the EXACT same way as alcohols, except instead of an “ol”
ending you will use an “ioc acid” ending
2. You will never need the address of the carboxyl group because of the double
bond. The carbon would be completely overloaded if you tried to put the
carboxyl group in the middle of the chain.
H O
H – C – C ethanoic acid
H O – H
O
H – C methanoic acid
O – H
2-methylbutanoic acid
Working Backwards: Draw – Propanoic Acid
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4. ESTERS
- An ester is an organic compound formed by chemical
reactions between an alcohol and a carboxylic acid
- Esters are used for food and cosmetics as they can provide
flavour and odour.
- Reaction of the carboxylic acid and the alcohol also creates a water molecule
Naming Esters
1. You must be able to identify both the alcohol and the carboxylic acid
component of the ester
2. Locate the ester functional group.
3. The part of the molecule attached to the alcohol
a. Name this with the appropriate prefix (it will be named like the alkyl
groups...eg. methyl, ethyl, propyl...)
4. The part of the molecule with the carbon attached to the double bonded O is
the carboxylic acid.
a. Name this with the prefix for the number of carbons (eg. methan, ethan,
propan...)
5. Put the name for the alcohol and the acid together, make the ending “oate”
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Examples:
H H O
C – H
H – C – C – O ethyl methanoate
H H
propyl ethanoate
ethyl ethanoate
butyl propanoate
Draw propyl propanoate
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POLYESTERS
- Polymer - large molecule formed by chemically combining many smaller
molecules
- Plastic - material able to be shaped or moulded with or without heat (a synthetic
polymer)
- Polyester - polymer containing many ester functional groups (created from the
reaction of many alcohols and carboxylic acids)
There are functional groups at both ends of the molecule, allowing the molecule to
grow in both directions. This results in the strength of plastics.
Bioplastics
- An organic polymer is produced by plants or bacteria that can be used in place
of synthetic polymers
- Bioplastics are organic polymers that are produced by extracting a polyester
compound from certain plant tissues.
- Synthetic polymers are NOT biodegradable, bioplastics are.
Practice:
Naming sheet
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Page 277 1, 2, 4, 5, 6
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