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    Introduction

    Any industrial activity involves some risk orhazard in terms of fire, explosion, toxic

    releases etc. which lead to injuries, loss of life

    & property ultimately adversely affecting the

    environment as a whole if not managedcorrectly resulting

    Truly speaking, any industrial installation

    should have Zero risk situation, but, it isimpossible to achieve it.

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    The potential causes for accidents are:

    Increasing production.

    Storage Volume.Competitive technology.

    Use of hazardous substances.

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    Risk Assessment & Risk Management

    gives a framework for :

    Setting regulatory priorities

    Decision Makingthat cut across various

    environmental areas.

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    Environmental Risk Assessment may bebroadly defined as a scientific enterprise in

    which facts and assumptions are used to

    estimate the adverse effects on human

    health or the environment that may resultfrom exposures to specific pollutants or

    other toxic agents.

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    Environmental Risk Management

    refers to a decision making processinvolving risk assessment, technological

    feasibility, economic information about

    cost and benefits, statutory

    requirements, public concerns etc.

    Risk Communication is the exchange

    of information about risk.

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    RISK ASSESSMENT :

    It is the systematic examination of anactual or proposed industrial installation:

    (1) to identify potential hazard to occur

    &

    (2) to identify the possible consequences

    from these hazards which would assist indecision making for reducing risk to anacceptable level.

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    ALARP:

    Mgmt. must take all measures to

    reduce risks as low as reasonably

    practicable. (ALARP) and this is achievedthrough a technique called Risk

    Assessment orRisk Analysis.

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    What is Hazard?

    It is the property of a substance or a

    situation which has the potential to

    cause harm.

    The potential hazards can be of fire,

    explosion and release of toxic &harmful gases.

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    HAZARD

    By hazard we mean any physical activity,

    situation or condition with the potential to causeharm, like:

    Human injury or death

    Damage to the environmentDamage to physical assets

    Loss of production

    The words threat and danger are sometimesused with a similar meaning as hazard.

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    Hazard Categories

    Hazards may generally be classified as:1. Natural hazards (e.g., Flooding, earthquake, storm,

    lightning).

    2. Technological hazards (e.g., industrial facilities,

    structures, technical equipment, transportation systems,consumer products, pesticides, herbicides,

    pharmaceuticals).

    3. Societal hazards (e.g., assault, war, arson, terrorism,

    sabotage, communicable disease).4.

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    What is Risk?

    It is related to the consequences of identified

    hazard. It may also be defined as theunwanted consequences from a particular

    activity.Risk has two variables:

    (a) Magnitude of consequences

    (b) Probability or frequency of the occurrence.

    So, Risk = Frequency of the occurrence

    Magnitude of consequences

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    What Is Risk?

    An expectation of loss

    Always an element of uncertainty

    Always refers to future

    Usually covers both severity and likelihood of a loss

    Usually refers to unwanted consequences

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    The consequences of an accident may be

    classified in different categories, as

    1.P

    ersonnel consequencesFatalities

    Impairment

    2. Environmental damage

    3. Economic loss

    Damage to material assets

    Production/service loss

    4. Information loss

    4. Image loss(i.e., damage to reputation)

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    Why Risk Assessment (Objectives ofRA):

    (1) To prioritize safety investments : Allorganizations have limited resources.Risk assessment can be used toprioritize risks and ensure that

    investment is directed to the greatestrisks.

    (2) Risk estimates aids in decision making.

    (3) Corporate Mgmt develops positive publicrelations with employees, communityand the Govt.

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    RISK EVALUATION:

    There are four steps in the evaluation of arisk.

    (1) Hazard Identification

    (2) Exposure Assessment

    (3) Hazard Assessment

    (4) Risk Characterization

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    (1) HAZARD IDENTIFICATION:

    It is an analysis to determine which of the

    discharges from a process or an accidentalrelease will be a potential danger to public

    health. E.g. Chemicals such as CO, HCl and

    unburned organics would be established as

    potential sources of risk for an incinerator.

    The means of identifying hazard is complex.

    Various methods are used to collect and

    evaluate toxic properties ( properties that

    indicate the potential to cause biological injury,

    disease or death under certain exposure

    conditions).

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    HAZARD IDENTIFICATION:(Cont..)

    Methods:(1) EPI-DEMIOLOGICAL STUDY: Use of

    epidemiological studies deal with theincidence of disease among groups of people.

    The study attempts to correlate incidence ofdisease like cancer from an emission by

    evaluation of people with a particular disease

    and people without the disease.

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    HAZARD IDENTIFICATION: (Cont..)

    Methods:(2) BIOASSAY: Long term animal bioassays

    ( an evaluation of disease in a laboratory animal)

    is a very common method for hazard

    identification. e.g. Increased tumor incidence inlaboratory animals is the primary health effect

    considered in animal bioassay. Exposure testing

    for a major portion of an animals lifetime (2 -3

    years for rats and mice) provides information ondisease susceptibility, primarily for

    carcinogenicity ( the development of cancer).

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    (2) EXPOSURE ASSESSMENT:

    This determines how much of an emission actually

    reaches the receptor. Human exposure includesingestion (eating or drinking), dermal contact (

    contact with the skin) & inhalation.

    These means of exposure are pathways to the

    human body. Thus, there is no risk withoutexposure.

    The exposure assessment attempts to define the

    route, amount, frequency and duration of

    exposure of a given population to a toxic

    substance. The principal pathways of exposure

    generally considered in exposure assessment are

    atmospheric transport, surface and ground water

    trans ort in estion of food materials etc.

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    (2) HAZARD ASSESSMENT :

    A hazard assessment is a determination of the

    relationship between the amount of exposure andthe risk to public health.

    A person can drown in water, but that does not

    mean that a glass of water is a danger to health.

    Obviously, what defines a danger is not

    necessarily the presence of a particular chemical

    but rather the amount of that substance one is

    exposed to. This amount is called dose.

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    HAZARD ASSESSMENT : (Cont..)

    Hazard assessment is also referred to as Dose

    response assessment.

    Dose is usually expressed as milligrams of

    chemical received per kilogram of body weight per

    day.For toxic substances other than carcinogens, a

    threshold dose must be exceeded before a health

    effect will occur. For many substances, there is a

    dosage level below which there is no harm.However, at some given dosage, the threshold, a

    health effect will occur ( or, at least be detected).

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    (4) RISK CHARACTERIZATION:

    It estimates the health risk associated withthe process under investigation.

    This characterization gives a number that

    represents the probability of adverse healtheffects from that process or from a

    substance released in that process.

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    RISK CHARACTERIZATION:(Cont)

    Once a risk characterization is made, the

    meaning of that risk must be evaluated.

    Public health agencies generally only

    considerrisk greater than 10 in 1 million

    to be significant risks warranting action.

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    MEASURE OF RISK

    Though the risks to the people from

    industrial hazards may be in the form of

    injuries , exposure to harmful releases etc.,

    risks are generally measured in terms of

    deaths (since there is better accuracy indata pertaining to death).

    Risks are generally expressed as(1) Individual risks

    (2) Societal risks.

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    (1) Individual Risk ( IR) :

    This is the risk to an individualperson. It is the probability of death

    occurring as a result of an accident at plant

    or an installation or a transport route.A simple way to express an IR is the FATAL

    ACCIDENT RATE (FAR).

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    Individual Risk ( IR) : (Cont)

    FATAL ACCIDENT RATE (FAR) is

    the number of fatalities per 108 exposedhours.

    One person works on average = 7.5 hrs /day

    One person works on average= 7.55= 37.5hrs/wk

    One person works on average = 37.552wks(yr) =

    1950 hrs/year ( Say, 2000 hrs.)

    Thus, 1000 persons in lifetime (50 yrs) would work

    = 1000502000 = 100000000 i.e. 108 exposed hrs.

    Exposed hours is the mean hrs. at work

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    Individual Risk ( IR) : (Cont)

    FATAL ACCIDENT RATE (FAR)

    typically varies in the range of 1 - 30.

    FAR of 1 means one fatal accident over

    1000 working lifetimesor,

    One fatal accident per 50 yrs. For a site

    employing 1000 people.

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    RISK CHARACTERIZATION:(Cont)

    (2) Population Risk (PR) :

    This is also known as group risk from

    an activity.

    It is the relationship between frequency of an

    accident and total number of people harmed.The is often plotted as FN curve showing the

    cumulative frequency (F) of accidents and Number

    of fatalities( N).

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    1.To prioritize safety investment (All organizations

    have limited resources. RA can be used toprioritize risks and ensure that investments is

    directed to the greatest risks).

    2. To make planning & decision especially for

    areas like plant design, plant safety reviews,

    preparation of emergency / disaster plan etc.

    3. To estimate financial risks.

    4. To develop positive public relations withemployees, community and the Govt.

    5. To get approval of projects.

    Objectives of Risk Assessment

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    6. To compare the estimated individual & societal

    risks against acceptance criteria.

    7. To identify major risk contributors and to

    recommend remedial measures for risk reduction.

    8. To carry out cost benefit analysis for the

    implementation of the remedial measures.

    9. To address land use planning issues includingsuitability of location, layout and design.

    10. To develop appropriate contingency plan.

    Objectives of Risk Assessment (Cont)

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    Components of Risk Assessment:

    Quantitative Risk Assessment ( QRA) includes:

    (1) System Description

    (2)H

    azard Identification(3) Scenario Selection

    (4) Consequence Estimation

    (5) Likelihood Estimation

    (6) Risk Estimation

    (7) Utilization of Risk Estimates

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    System Description:

    It is the compiled process information that are neededfor the Risk Analysis. e.g.

    (1) Site Location

    (2)Weather Data

    (3) Process Flow Diagrams (PFD)

    (4) Piping & Instrument Diagram (P & ID)

    (5) Layout Drawing(6) Effluent & Emission Summary

    (7) Operating & Maintenance Procedures

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    Hazard Identification:

    It includes:

    (1) Checklists

    (2) Preliminary Hazard Analysis (PHA)

    (3) Hazard & Operability (HAZOP) Studies It is a

    methodology for identifying and dealing with potentialproblems in industrial processes, particularly thosewhich would create a hazardous situation or a severeimpairment of the process.

    (4) Failure Mode and Effects (FMEA) -I

    t prioritizespotential failures by looking into the probability ofoccurrence and likelihood of failure.

    (5)What if Analysis

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    Scenario Selection:

    It is used to list out all accidental releasescenarios that have the potential to impact the

    members of the public outside the installation

    boundary. It considers:

    (1) Nature of the hazardous substance released &

    its operating T, P etc.

    (2) Inventory of hazardous substance

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    Consequence Estimation:

    It is used to determine the potential for damageor injury from particular incidents.

    By using this technique, the areas of the site

    which would be affected in the event of anemergency is located.

    Outcomes of an incident are analyzed using

    source & dispersion models and Explosion & Fire

    Models.

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    Likelihood / Frequency Estimation:

    It is used to estimate the frequency or

    probability of occurrence of an incident.

    Estimates may be obtained from historicalincident data.

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    Risk Estimation:

    It combines the consequences and likelihood ofall incident outcomes from all selected

    incidents to provide a measure of risk. This

    involves mapping the accident areas and risk

    pattern.

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    Utilization ofRisk Estimates:

    It is the process by which the result from arisk analysis is used to make decisions.

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    What is MaximumCredible Accident

    (MCA) Analysis?It is a tool used to find the maximum potential

    damage an accident can cause.

    It helps in the identification of most vulnerablesections of the installation and facilities that

    pose maximum possible risk if the hazardous

    materials are released as a result of a failure.

    This may be due to leakage from a crack or

    fracture of the process vessel, vents, pump seals

    or overflow of a tank or vessel.

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    What is MaximumCredible Accident

    (MCA) Analysis? ( Cont.)The extent of consequences arising from the

    hazardous substances will largely depend on

    quantity released, location, wind condition anddensity of population.

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    Accident Scenarios ofRisk Potential

    (1) BLEVE( Boiling Liquid Expanding Vapor Explosion):

    This is a type of explosion that can occur when a vessel containing a

    pressurized liquid is ruptured. Such explosions can be extremelyhazardous.

    A BLEVE results from the rupture of a vessel containing a liquidsubstantially above its atmospheric boiling point. The substance isstored partly in liquid form, with a gaseous vapor above the liquid filling

    the remainder of the container.

    The primary cause is usually an external flame impinging on the shellof a vessel leading to sudden rupture of the shell.

    The explosion is sufficient to cause fragments of the container to fly overlarge distances of few kms. The released liquid results into a fire ballhaving intense heat.

    It causes intense damage to life and property.

    LPG Storage vessels in petroleum installations can cause severe BLEVE.

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    A BLEVE erupting from a tanker

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    Accident Scenarios ofRisk Potential ( Cont)

    (2) UCVE ( Unconfined Vapor Cloud Explosion):

    When a flammable gas or liquid

    escapes into the atmosphere and mixes

    with air , an explosive gas or vaporcloud can form.

    This flammable mixture will explode ifignited causing extensive damage to the

    surroundings.

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    Accident Scenarios ofRisk Potential ( Cont)

    (3) Jet Fires:

    Ejection of a flammable liquid from avessel, pipe etc. can give rise to a jet flameif the material ignites. It is not easy tohandle since a large jet flame has asubstantial reach ( sometimes 50 m ormore).

    The jet flames from a pressure relief valvescan cause adjacent vessels to overheat andburst giving rise to BLEVE ( Boiling liquidexpanding vapor explosion).

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    Accident Scenarios ofRisk Potential

    Toxic Dispersion:

    The hazard due to toxic chemical depends

    on the condition of exposure and the type of

    chemical. It can range from suddenexposure at high concentrations to

    prolonged exposure at low concentrations.

    A very large release of toxic chemical ( Cl orH2S) usually have greater disaster potential

    than fires or explosion.

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    Risk Management & Control

    After assessing the risks , one recognizes the

    courses of actions that would control and

    minimize the risks to human health, property

    and environment ( objective ofRisk Mgmt.)

    Risk Mgmt. involves resource

    allocation, cost benefit analysis,

    acceptable risks etc.

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    Risk Management & Control ( Cont.)

    Risk Mgmt. involves:

    (1) Reduction of risks to acceptable limits byjudicious investments.

    (2) Relocating the activities on alternate sites /

    routes

    (3) Taking appropriate considerations whenbuying Insurance Policy of installations

    with potential high risks.(4) Preparing Emergency / Disaster plans to

    handle effectively any emergency situationswith minimum damages.

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    Risk Management & Control ( Cont.)

    Effective Risk Mgmt. Depends on:(1) Sound standards of engineering design

    must be used.

    (2) Quality control procedures must ensurethat all equipment conforms to designstandards and specifications.

    (3) All equipment must be inspected,

    maintained and tested at suitableintervals.

    (4) Personnel must be experienced and

    trained.

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    Risk Acceptance / Tolerance

    The result of a risk assessment is aquantification of risk.

    It brings the level of risk that is acceptable to

    public, authorities & the industry. But, thequestion is how much risk can be acceptable

    or tolerable.

    The risk from an activity should be judgedagainst the benefits from the activity, since no

    activity can claim to be totally risk free.

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    Risk Acceptance Criteria:

    Since all industrial activities involve risks

    including risks of fatality ( may be

    employees engaged in the activity or,

    common public outside).When an industrial activity imposes risk

    common public, it especially becomes the

    concern of regulators to assess the risk &evaluate it.

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    Risk Acceptance Criteria: (Cont)

    A good risk criteria should recognize:

    (1) Level of risk which is so high that it isconsidered unacceptable/ intolerableregardless of the benefits derived from theactivity.

    (2) Level of risk which is low enough to beconsidered negligible.

    (3) Level of risk in between that is to beconsidered tolerable subject to their being

    reduced to As Low As is ReasonablyPracticable (ALARP).

    Risks become tolerable when all practicablemeasures are taken to reduce risk to ALARP.

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    Risk Assessment Matrix

    Risk Assessment Matrix is a tool for ranking

    different activities / projects in terms of their

    potential benefit and the likely risks/cost in

    implementing them.

    It is a tool that standardizes qualitative riskassessment and facilitates the

    categorization of risk from threats to health,

    safety, environment and companyreputation.I

    Ri k A t M t i (C t )

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    Risk Assessment Matrix (Cont..)

    I

    Likelihood Consequences

    Catastro

    phic

    (5)

    Major

    (4)

    Moderate

    (3)

    Minor

    (2)

    Insignific

    ant

    (1)

    Almost

    Certain (5)

    10 9 8 7 6

    Likely (4) 9 8 7 6 5

    Possible (3) 8 7 6 5 4

    Unlikely (2) 7 6 5 4 3

    Rare (1) 6 5 4 3 2

    Ri k A t M t i (C t )

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    Risk Assessment Matrix (Cont..)

    IRisk

    Score

    Risk Description What should be done?

    9 - 10 Extreme Immediate action required

    7 - 8 High Action plan required,

    senior mgmt. attentionneeded

    5 - 6 Moderate Specific monitoring or

    procedures required,

    mgmt. responsibility mustbe specified

    2 - 4 Low Manage through routine

    procedures