uk-spain organometallic chemistry symposium...the first uk-spain organometallic chemistry symposium...
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UK-SPAINOrganometallic Chemistry Symposium
17-19 September 2019University of AlcaláAlcalá de HenaresMadrid, Spain
www.usocs2019.com
PROGRAMME
LOCAL COMMITTEE
Marta E. G. MosqueraGerardo JiménezJesús CanoVanessa TaberneroJuan Carlos FloresCristina García-YebraCarlos Yélamos
PresentationThe first UK-Spain Organometallic Chemistry Symposium (USOCS2019) will be held in Alcalá de Henares, Spain, in September 17th-19th.
The Organizing Committee cordially welcomes you to attend to this meeting where we will celebrate the full diversity of modern organometallic chemistry research from both countries. In addition, the symposium will include a plenary lecture from Professor Luis Oro, recipient of the RSC´s Lord Lewis Prize in 2018. This meeting will provide a forum in which the research of established and early-career inorganic chemists working in Spain or the UK can present their work and enjoy networking opportunities. Invited lectures from Spanish and British leading researchers as well as oral and poster contributions have been programmed.
Eva Hevia - Strathclyde University Richard Layfield - Sussex University
Marta E. G. Mosquera - Alcalá University
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PROGRAM
Registration
Opening Ceremony
IT1: Robert Mulvey
IT2: Ana Carmen Albéniz
IT3: José Goicoechea
Lord Lewis Award Ceremony: Luis Oro
Welcome Mixer
15:00
16:00
16:15
16:45
17:15
17:45
19:15
Tuesday, 17th September 2019 IT9: Richard Layfi eld
IT10: María Giménez
Joaquín García-Álvarez, Claire Brodie, Mª Ángeles Fuentes, Alberto Hernán-Gómez, Martí Garçon
Coffee Break
Poster presentations
University Visit
Conference dinner
15:00
15:30
16:00
17:00
17:30
19:00
21:00
Wednesday, 18th September 2019
IT4: Dominic S. Wright
IT5: Concepción Gimeno
IT6: Lucía Riera
Coffee Break
IT7: Eva Hevia
IT8: Miquel Costas
Manfred Bochman, Montserrat Diéguez,Christopher J. Whiteoak, Sonia Infante,Miguel Palenzuela
Lunch Break
09:00
09.30
10:00
10:30
11:00
11:30
12:00
13:00
Thursday, 19th September 2019
IT11: Debbie Kays
IT12: Jesús Campos
Flash presentations
Coffee Break
Tatsumi Ochiai, Antonio J. Martínez Martínez, Elena Cuéllar, Sanjiv Prashar
IT13: Charlotte Willians
IT14: Pedro J. Pérez
Closing remarks
09:30
10:00
10:30
11:15
11:45
12:45
13:15
13:45
Tuesday, 17th September
16.00 OPENING CEREMONY
16.15
Session 1: Chair: Cristina García Yebra
IT1: Robert Mulvey - University of Strathclyde, UK
Alkali Metal Organometallics: Masters of Mediation
16.45
IT2: Ana Carmen Albéniz - Centro de Innovación en Química y Materiales Avanzados Universidad de Valladolid, ES
Faster Palladium-Catalyzed Coupling ReactionCooperating Ligands and Co-Solvents
17.15IT3: José Goicoechea - University of Oxford, UK
From Chemical Curiosities to Versatile Reagents: Heavy Analogues of the Cyanate Ion
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17.45
LORD LEWIS AWARD CEREMONY. PLENARY TALK
LOT1: Luis Oro - Instituto de Síntesis Química y Catálisis Homogénea Universidad de Zaragoza - CSIC, ES
From Organometallic Complexes to Homogeneous Catalysis: Forty years of Platinum Group Metal Chemistry
19.15 WELCOME MIXER
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Wednesday, 18th September
09.00
Session 2: Chair: Marta E. G. Mosquera
IT4: Dominic S. Wright - University of Cambridge, UK
Main Group Macrocycles; Design Concepts and New Host-Guest Chemistry
09.30IT5: Concepción Gimeno - Instituto de Síntesis Química y Catálisis Homogénea CSIC-Universidad de Zaragoza, ES
Synthesis and Applications of Novel Organogold Complexes
10.00IT6: Lucía Riera - ICNN, CSIC Universidad de Oviedo, ES
Dearomatization and Ring-Opening of 2,2’-Bipyridine and 1,10-Phenanthroline Ligands
10.30 COFFEE BREAK
11.00
Session 3: Chair: Stuart Robertson
IT7: Eva Hevia - University of Strathclyde, UK
Tailoring Organozinc Reagents for Chemical Cooperativity
11.30IT8: Miquel Costas - Institut de Química Computacional i Catàlisi Universitat de Girona, ES
FeV complexes of relevance in enzymology and organic synthesis
12.00 P1: Manfred Bochmann - University of East Anglia, UKCarbene complexes of Cu, Ag, Au as OLED photoemitters
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12.00
OP2: Montserrat Diéguez - Universitat Rovira i Virgili, ESImproved generations of catalysts for the synthesis of elusive chiral synthons
OP3: Christopher J. Whiteoak - Sheffield Hallam University, UKAccess to Unusual Heterocyclic Compounds Utilizing a Key Cobalt-Catalyzed C-H Functionalization Approach
OP4: Sonia Infante - IMDEA Nanociencia, ESOrganometallic tethered compounds with a coordinative bound capable of hijacking/releasing a proton
OP5: Miguel Palenzuela - Universidad de Alcalá, ESCombined catalytic action of homometallic and heterometallic aluminum species to generate polymeric nanoparticles
13.00 LUNCH BREAK
15.00
Session 4: Chair: Manfred Bochman
IT9: Richard Layfield - University of Sussex, UK
High-Temperature Lanthanide Single-Molecule Magnets
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15.30IT10: María Giménez - Centro Singular de Investigación en Química Biológica y Materiales Moleculares Universidad de Santiago de Compostela, ES
Developing sustainable carbon hybrid materials
16.00
OP6: Joaquín García-Álvarez - Universidad de Oviedo, ESSynergistic combination of metal-catalyzed organic reactions with enzymes or organolithium reagents (RLi) in water and Deep Eutectic Solvents
OP7: Claire Brodie - Durham University, UKInvestigating the Reduction and Reactivity Chemistry of Cobalt Diphosphine Complexes
OP8: Mª Ángeles Fuentes - University of Oxford, UKPhosphine/borane frustrated Lewis pairs chemistry supported by xanthene scaffolds
OP9: Alberto Hernán-Gómez - Universitat de Girona, ESCatalytic Alkane Functionalization Via Iron-Carbene Insertion Reaction
OP10: Martí Garçon - Imperial College London, UKUnusual Bonds between Magnesium and Transition Metals: New Opportunities in Catalysis
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17.00 COFFEE BREAK
17.30
POSTER SESSION
Heterobimetallic Lanthanide Isocarbonyl Complexes as Single-Molecule MagnetsRichard Collins, Jinkui Tang,Richard A. Layfield
Unusual ligand rearrangement of N-phosphinoguanidinato compoundsFernando Carrillo-Hermosilla, Estefanía Huergo, Rafael Fernández-Galán, Alberto Ramos, Antonio Antiñolo, Antonio Rodríguez-Diéguez, Daniel García-Vivó
Decarbonylation Processes in k3 -(N^C^C) Gold (III) CarboxylatesEstíbaliz Merino, Hélène Beucher, Alexandre Genoux, Thomas Fox,Cristina Nevado
Bipy and phen ring-opening at Re(I) carbonyl complexesPurificación Cañadas, Julio Pérez, Lucía Riera
Reactivity of Phosphine-Stabilized Silylene Rhodium ComplexN. Almenara, J. I. Miranda, A. Rodríguez-Diéguez, M. A. Garralda, M. A. Huertos
Novel Iridapyrazole based complexes, reactivity and catalytic activityItxaso Bustos, María Ángeles Garralda, Claudio Mendicute-Fierro
Synthesis, structure, and properties of monopentamethylcyclopentadienyltitanium (III) dihalide complexesEstefanía del Horno, Reyes Jiménez-Aparicio, Miguel Mena, Adrián Pérez-Redondo, José Luis Priego, Carlos Yélamos
Ligands with a pyridone or amido functionality: Assessment of their cooperating ability in the Pd-catalyzed direct arylation of arenesCintya Pinilla, Vanesa Salamanca, Francisco Villalba, Ana C. Albéniz
Nano Base Metal Catalysts: Synthesis and CharacterisationAlana Smith, Phil Dyer, Simon Beaumont, Xavier Baucherel, Leon van de Water
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17.30
Graphene-based Heterogeneous Cu-catalysts in Borylation ReactionsM. Franco Fernández, M. Tortosa, M. B. Cid
Synthesis and Characterization of Cyclopentadienyl Sulfur Niobium ComplexesElena Álvarez-Ruiz, Manuel Gómez, Cristina Hernández-Prieto, Avelino Martín, Miguel Mena, Cristina Santamaría
Digold C-C Cross Coupling Reactions: Mechanistic InsightsJuan Miranda-Pizarro, Jesús Campos, Ernesto Carmona
The interaction of the light with ortho-palladated azlactones: different pathwaysEsteban P. Urriolabeitia, Carlos Cativiela, Pablo Sánchez, Alexandra Pop, Cristian Silvestru
Synthesis of bis (amino acids) with cyclobutane skeleton through selective [2+2]-photocycloaddition of oxazolones and thiazolonesSonia Sierra, David Dalmau, Alexandra Pop, Cristian Silvestru, Carlos Cativiela, Esteban P. Urriolabeitia
Cyclobutadienyl Chemistry of the Rare-Earth ElementsJames Durrant, Benjamin M. Day, Richard A. Layfield
Gold-catalyzed regiodivergent cyclization of alkynylcyclobutanesM. Soledad Garre, David Sucunza, Estibaliz Merino, Enrique Aguilar, Patricia García-García, Juan J. Vaquero
New Advances in Rhodium-Catalyzed Olefin HydrophosphinationVictor Varela, Ana M. Geer, José A. López, Miguel A. Ciriano, Cristina Tejel
Stereoselective synthesis of versatile trifluoromethyl substituted borocyclopropanes.Julia Altarejos, David Sucunza, Ana Caballero, Pedro J. Pérez, Juan J. Vaquero, Javier Carreras
Outher-Sphere Alkoxylation of Olefins promoted by Inner-Sphere Oxygen ActivationCristina Tejel, Paula Abril, M- Pilar del Río, Agustí Lledós, José A. López, Miguel A. Ciriano
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17.30
Uranium complexes with bulky tetraaryloxide ligandsRory P. Kelly, Tatsumi Ochiai, Francis Y. T. Lam, Megan L. Seymour, Jordann A. L. Wells, Laurent Maron, Polly L. ArnoldMagnetic Bistability in Coordination NanohoopsMaría José Heras Ojea, Lewis C. H. Maddock, Benjamin M. Day, Fu-Sheng Guo, Jeff M. Van Raden, Daniel Pividori, Jordi Cirera, Ramesh Jasti, Karsten Meyer, Eliseo Ruiz, Richard A. LayfieldGraphene-Supported Gold Nanoparticles Capped with NHC Ligands: A New Method to Synthesize an Active and Recyclable Catalysts for the Hydration of AlkynesDavid Ventura-Espinosa, Santiago Martín, José A. MataCoordination Versatility of Bidentate COC and Tridentate CNC Ligands Containing 1,2,3-Triazol-5-ylidenesGregorio Guisado-Barrios, Lewis C. Tolley, Daniela I. Bezuidenhoutβ(Z)-vinylsilanes produced by hybrid graphene-based alkyne hydrosilylation NHC-rhodium catalystBeatriz Sánchez-Page, M. Victoria Jiménez, Jesús J. Pérez-Torrente, Patricia Álvarez, Javier BlascoAn Organometallic Approach to Magnesium Aluminate Complexes for Rechargeable Battery ElectrolytesStuart D. Robertson, Scott A. BrownGreen large-scale production of piezoelectric bioplastics.Valentina Sessini, Marta E. G. MosqueraImidazolium-2-Amidinates: role as ligands for main group metals and in C-Cl bond activation processesDavid Sánchez-Roa, Marta E. G. Mosquera, Juan Cámpora, Tomás Cuenca, María Fernández-MillánTitanium (IV)-modified silica@magnetic nanocomposites. Synthesis and application as efficient nanocatalysts for sulfide oxidation with H2O2Joan Martín Vinueza, Gerardo Jiménez, Vanessa TaberneroNew Heterometallic aluminium alkali metal compounds with oximate ligandsJesús Damián Burgoa, Tomás Cuenca, Marta E.G. MosqueraHomoleptic Trigonal Planar Uranium Complex Induced by High PressureTatsumi Ochiai, Amy N. Price, Jacob J. Shephard, Victoria Berryman, Polly L. Arnold, Simon Parsons, Nikolas Kaltsoyannis
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19.00 VISIT TO THE HISTORIC BUILDING OF THE UNIVERSITY OF ALCALÁ
21.00CONFERENCE DINNER Parador de Alcalá (C/ Colegios 8)
17.30
Functional model of catecholase based on Schiff basesAida Jaafar Arias, Aaron Terán More, Ana E. Sánchez Peláez, Ángel Gutiérrez Alonso, María del Carmen Torralba Martínez Multifunctional molecular materials combining optical and liquid crystal propertiesBrais González, Cristián Cuerva, José A. Campo, Mercedes Cano, Carlos Lodeiro Monocatenar and dicatenar β-diketonylpyridinium salts: ionic liquid crystalsM. Eugenia Aznárez, Arturo Pareja, Cristián Cuerva, José A. Campo, Mercedes Cano, Carlos Lodeiro Phytohormones as bridging ligands in diruthenium complexesIsabel Coloma, Miguel Cortijo, Inés Fernández-Sánchez, Santiago Herrero, Reyes Jiménez-Aparicio, José L. PriegoNew insights in the electronic structure of formamidinate-supported Ru2
5+ compounds by Raman resonant spectroscopyA. Inchausti, A. Lobato, S. Herrero, R. González-Prieto, R. Jiménez-Aparicio, M. Taravillo, V. G. Baonza[Ru2Cl(DArF)x(O2CMe)4-x] compounds as starting materials for macromolecules and RNA probesA. de Marcos Galán, A. Inchausti, A. Manchado-Parra, R. González-Prieto, S. Herrero, R. Jiménez-AparicioNMR studies of diruthenium-protein compoundsAarón Terán More, Jose Manuel Pérez-Cañadillas, Santiago Herrero, Reyes Jiménez-AparicioCoordination capacity of thymine-1-acetate towards diruthenium complexes with open-paddlewheel structureMiguel Cortijo, Inés Fernández-Sánchez, Santiago Herrero, Reyes Jiménez-Aparicio, Aarón TeránRemote Functionalized Bidentate Phosphine-based Ruthenium(II) Catalysts for Ethanol/Methanol Upgrading to Advanced Biofuels Folasade J. Sama Richard L. Wingad, Duncan F. Wass
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10.30
FLASH PRESENTATIONS
FP1: Verónica Conejo Rodríguez – Universidad de Valladolid, ESd8···d10 RhI···AuI Interactions in Rh 2,6-Xylylisocyanide Complexes with Au(CN)2–: Bond Analysis and Crystal Effects
FP2: Anindita Chakraborty - University of Sussex, UKLanthanide Cyclobutadienyl Sandwich Complexes
FP3: Alice Johnson - University of Oxford, UKBis(imino)pyridine Rhodium Complexes for Amine-Borane Dehydropolymerisation
Thursday, 19th September
09.30
Session 5: Chair: Fernando Carrillo-Hermosilla
IT11: Debbie Kays - University of Nottingham, UKSmall molecule activation and catalysis using coordinatively unsaturated complexes
10.00IT12: Jesús Campos - Instituto de Investigaciones Químicas. Universidad de Sevilla - CSIC, ESFrustration versus Interaction in Bimetallic Systems
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10.30
FP4: Marta Navarro - Universidad Rey Juan Carlos, ESBimetallic Aluminium Scorpionates For Coupling of CO2 And Epoxides Into Cyclic Carbonates Under Mild Conditions
FP5: Matthias Dirk Boegear - Universidad de Zaragoza, ESNovel arene Ru (II) compounds with N-phenanthroline glycosylamine ligands as potential anticancer agents
FP6: Elena de la Torre Rubio - Universidad de Alcalá, ESNovel arene Ru (II) compounds with N-phenanthroline glycosylamine ligands as potential anticancer agents
FP7: Ana Carrasco - IMDEA Nanociencia, ESPotent Half-Sandwich Iridium (III) Complexes as Mitochondria-Targeted Anticancer Drugs
FP8: Francisco Villalba - Universidad de Valladolid, ESCoupling of Reactive Carbene Precursors: Isolation of Intermediate Palladium Complexes
FP9: Alberto Abéngozar - Universidad de Alcalá, ESBN-Arenes: Synthesis, Reactivity and Properties
11.15 COFFEE BREAK
15
12.45IT13: Charlotte Willans - University of Leeds, UKElectrochemical Generation of Catalysts using Batch and Flow Technology
13.15IT14: Pedro Pérez - Centro de Investigación en Química Sostenible Universidad de Huelva, ESThe reactivity of alkanes towards metal-carbene electrophiles
13.45 CLOSING REMARKS
11.45
Session 6: Chair: Juan Carlos Flores
OP11: Tatsumi Ochiai - University of Edimburg, UKHomoleptic Trigonal Planar Uranium Complex Induced by High Pressure
OP12: Antonio J. Martínez Martínez - Universidad de Huelva, ESCatalytic Upgrading of Light Hydrocarbons: Solid–State Molecular Organometallic Nanoreactors
OP13: Elena Cuéllar - IMDEA Nanociencia, ESDeprotonation studies, luminescent properties and catalytic CO2 reduction activity of Re(CO)3 complexes with pyrazole and (3-(2-pyridyl)pyrazole)
OP14: Sanjiv Prashar - Universidad Rey Juan Carlos, ESSpanish Metallocenes with a British accent. Titanocene Functionalized Mesoporous Silica Nanoparticles in the Fight against Cancer
The congress venue is the Colegio San Ildefonso of the University of Alcalá. Inside this building you will fi nd in the ground fl oor the Salon de Actos, the main room were the session will take place. Poster session will be located in the fi rst fl oor.
Colegio Mayor de San IldefonsoPlaza de San Diego, s/n28801 Alcalá de Henares (Madrid)
CONFERENCE VENUE
ASSEMBLY HALL
POST
ER E
XHIB
ITIO
N
TRAIN STATION
BUS STATION
COLEGIO DE SAN ILDEFONSOOPENING CEREMONY, COFFEE BREAKS, LUNCHES AND WELCOME MIXER
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MAP OF DOWNTOWN ALCALÁ DE HENARES
PARADOR DE ALCALÁCONFERENCE DINNER▲
Coffee breaks will be offered in Filosofos’ quadrangle, outside the cafeteria.
Lunch will be offered in St. Tomás de Villanueva’s quadrangle, inside of the restaurant.
Conference dinner will be served in the Parador de Alcalá located in Colegios St. 8.
COFFEE BREAK, LUNCHAND CONFERENCE DINNER
INTERNET ACCESS
Free Wi-Fi access will be available at Colegio Santo Tomás. SSID Name: fgua-uahPassword: fgua-uah-2019
VISIT TO THE HISTORIC BUILDING OF THE UNIVERSITY OF ALCALÁ
The walking tour over the historic building of the University of Alcalá will be held on Wednesday, 18th September at 19:00 h. Meeting point: main entrance of Colegio Santo Tomás.
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NOTES
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PROGRAMME
UK-SPAINOrganometallic Chemistry Symposium
17-19 September 2019University of AlcaláAlcalá de HenaresMadrid, Spain
www.usocs2019.com