transport properties of lithium hectorite-based composite electrolytes

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2002 electric properties, superconductors, semiconductors electric properties, superconductors, semiconductors D 8000 38 - 013 Transport Properties of Lithium Hectorite-Based Composite Elec- trolytes. Physically gelled composite electrolytes based on lithium hectorite clay and carbonate solvents (ethylene carbonate, propylene carbonate, and dimethyl carbonate) are shown to be attractive candidates for use in rechargeable lithium-ion batteries requiring high discharge rates. Room- temperature conductivities as high as 2·10 -4 S/cm are observed in these systems. Lithium-ion transference numbers as high as 0.98 are measured by the dc polarization method using Li metal electrodes. — (RILEY, MICHAEL; FEDKIW, PETER S.; KHAN, SAAD A.; J. Electrochem. Soc. 149 (2002) 6, A667-A674; Dep. Chem. Eng., N. C. State Univ., Raleigh, NC 27695, USA; EN) 1

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Page 1: Transport Properties of Lithium Hectorite-Based Composite Electrolytes

2002 electric properties, superconductors, semiconductors

electric properties, superconductors, semiconductorsD 8000

38 - 013Transport Properties of Lithium Hectorite-Based Composite Elec-trolytes. — Physically gelled composite electrolytes based on lithiumhectorite clay and carbonate solvents (ethylene carbonate, propylene carbonate,and dimethyl carbonate) are shown to be attractive candidates for use inrechargeable lithium-ion batteries requiring high discharge rates. Room-temperature conductivities as high as 2·10−4 S/cm are observed in thesesystems. Lithium-ion transference numbers as high as 0.98 are measured bythe dc polarization method using Li metal electrodes. — (RILEY, MICHAEL;FEDKIW, PETER S.; KHAN, SAAD A.; J. Electrochem. Soc. 149 (2002) 6,A667-A674; Dep. Chem. Eng., N. C. State Univ., Raleigh, NC 27695, USA; EN)

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