wets L "Your Full Service Chemistry Laboratory" / West Coast Technical Service Inc.17605 Fabrica Way / Cerritos, California 90701 / (213) 921 -9831 or (714) 523-9200~»w.M»rnm ,Report

C r>t/^ i* ! * i1 ••- ! ' , " .L f(r^-;l)/T_^At^s ^^ /

Prepared For

Date Received

U.S. Environmental Protection AgencyCurtis Building 6th \ Walnut St., 35A-30Philadelphia, PA 19106

Attn: Jeffrey HassP.O. No.

3-26-82 6502

April 22,

IiiJob No. 1

23352 :Description of Samples

1982

RECEIVEDMAYlIlSfe.

!n_environmen:, •

Enclosed is the data for ERA Samples numbers C5047, C5048. Casenumber 904. Chain of Custody was received. At the time of theanalyses, Decafluorobiphenyl (surrogate) was not available for thestandard solutions, therefore it was not quantitated in the reporteddata. Phenol D5 (surrogate) was not detected in the samples analyzed,but it was noted to be spiked at 400,000ug/kg.

We would appreciate a telephone call if you have any questions regarding this report Page 1 of pages.

I certify thai this report truly represents the findings of work performed by me.or under my direct supervision.

Richard AmanoSenior Chemist

a AD proved

D.J, Northington, Ph.D.Technical Director

This report pertains only lo the samples investigated and Goes not necesSB'ily apply lo olhe' apparently identical or similar materials This reoo't is submitted loMhe eidusive use o* the client to >Any reproduction ot this report 0' use of this Laboratory s name tor atoerliSiiQ or publicity purposes without written authorization is prohibited

it is aOO'essed

ORGANIC BENCH SHEET

Project * £?? NEIC Sample * 2foO

Analyst

Region Sample #

7Hazardous Spot Test Results

Initial pH

Date- Extracted //{, /

H - Volatile Organics (VGA)

HI Sample Aliquot/Solvent

H2 Sample Aliquot/Solvent

Vi ̂ g/

A o g/ fr>ml Hexadecane

rol Methanol

0 - Base/Neutral, Acid, TCDD Extracts

Amount Surrogate Added per Aliquot 0, (

Amount Spike Added per Aliquot ____ •

f-4[\J /j A I

Spike Codes

Jl Sample Aliquot/Solvent

\32 Sample Aliquot/Solvent

JC Combination of 01 & 02

UY fr&J-fr#- g/f Q ml CH2C12

y^o _q/ /^) ml CH2Cl2

g/ ml CH2C12pH Adj.-NO ^Y£§

— 6N NOAH_ 6N H2S04

Shipping Volume

JC Base/Neutral, Acid, TCDO G.C. Screening

Run f Date Analyst

Needs Concentration NO -Y YES_

K - Pesticides/ PCB Extraction

Kl Sample Aliquot/Solvent

K2 Sample Aliquot/Solvent/ & 9/ (O

A G 9/ /0

ml Hexane

ml Hexane

COIWENTS -V

NEIC Sample No. 633-260

PREPARATION PARAMETER RESULTS AND EXTRACTSORGANIC

________ Region Sample No. SO-2

CK.P

Sample Description Waste PVC from off grade bath pit - Earth Lagoon (Project: StaufferCollection Date 3-9-82 TIME 12:10 Reagent Blank Chem1calJ633:261

PARAMETERPercentage of sample(by volume)i moisturepHAlkalinityAcidity

Conductivity

Oxidants (spot test)OxidantsSulfide (spot test)Sulfide

Cyanide (spot test)CyanideDescription

AQUEOUS, NO. 1

_4

Ufa

TDSi -TDSp -

N/A

ng/1 as CaCO-5mR/L as CaCO*^

mg/LmR/L

mg/L

mg/L

i

SOLIpA NO . 2

SAOX

^LO

f l R I 0 0 3 7 9GR»^iiC CONTBOLS CORTOR*nOH BUFFALO. NF* YORK

QUANTJTATION REPORT FILE: 23332F1

DATA: 23352F1.TI84/18/82 19:43:60SAMPLE: 085847CONDS.: EXT 4/14/82 B.25G TO 5MLSFORMULA: SENS213 INSTRUMENT: 4821 LEIGHT: 8.800SUBMITTED BY: BNAP047 ANALYST: RA *592 ACCT. NO.: FC112581

AMOUNT-AREA * REF.AMNT/CREF.AREA* RESP.FACT)

NO NAME1 2,4,6-PHENOL D3 (INTERNAL STANDARD)2 61B N-NITROSO-DIMETHYLAMINE3 1BB SIS (2-CHLOROETHYL) ETHER4 24A 2-CHLOROPHENOL5 26B 1.3-DICHLOROBENZENE6 27B U4-DI CHLOROBENZENE7 1,2-DICHLOROBENZENE8 42B BIS (2-CHLOROISOPROPYL) ETHER9 12B HEXACHLOROETHANE18 PHENOL11 PHENOL D-5 (SURROGATE)12 2-fLUQROPHENOL (SURROGATE)13 PYRIDINE D6 (SURROGATE)14 NAPHTHALENE D8 (INTERNAL STANDARD)15 63B N-NITROSO-DI-N-PROPYLAMINE16 NITROBENZENE17 ISOPHORONE18 57A 2-NITROPHENOL19 34A 2,4-DIMETHYLPHENOL28 43B BIS (2-CHLOROETHOXY) METHANE21 31A 2,4-DICHlOROPHENOL22 8B 1,2,4-TRlCHLOROBENZENE23 55B NAPHTHALENE24 52B HEXACHLOROBUTADIENE25 22A 4-CHLORO-M-CRESOL26 538 HEXRCHLOROCYCLOPENTADIENE27 21A 2,4,6-TRICHLOROPHENOL28 288 2-CHLORON^PHTHALENE29 778 ACENftPHTHALENE30 71B DIMSTHYLPHTHflLATE31 36B 2,5-DIKITROTOLUENE32 NITROBENZENE D-5 (SURROGATE)33 2-FLUORBIPHEMYL (SURROGATE)34 PHENftNTHREHE DIG (INTERNAL STANDARD)35 IB BCEhAPHTHENE36 59ft 2,.->-DJNITROPHE:MOL37 3SD 2^-DINITROTOLUcNE3839 88843 408 4-CHLORQPHENYLPHENYL ETHER41 70S DIETHYLPHTHALATE42 60A 4,6-DIMITRO-O-CRESQL43 62B N-NITROSODIPHENYLAMINE44 378 1,2-DIPHENYLHYDRAZINE45 41B 4-EROHOPHENOXYBENZENE45 98 HEXACHLOROBENZENE47 64A PENTACHLOROPHENOL

flR/00380

NO484950515253545556575859606162636465666768697071727374757677787988

NAMEBIB PHENANTHRENE78B ANTHRACENE68B DI-N-8UTYLPHTHALATE39B FLUORANTHEHE84B PYRENEALPHA BHCGAMMA 8. BETA BHCDELTA-5HCHEPTACHLORALDRINPYREHE DID (SURROGATE)CHRYCTE D12 (INTERNAL STANDARD)SB GENZIDINE67B 3UTYLBENZYLPHTHALATE72B fiEMZO Cfl) ANTHRACENE7SB CHHY3ENE2£S 3,3'-PICHLOROBENZIDINE665 BIS (2-ETHYLHEXYL) PHTHALATE693 D!-N-OCTYLPHTHALATE

DIELDRIN4,4'-DDD4,4'-DDTBETA EHDOSULFANENDOSULFAN SULFATEENDRINALPHA ENDOSULFANBENZO (A) PYRENE D-12 (INTERNAL STANDARD)74B BENZO (B) FLUORANTHENE73B BENZO (A) PYRENEB3B INDENO-1,2.3 (C.D) PYRENE828 DIEENZO CA.H) ANTHRACENE798 BENZO (G,H,I) PERYLENE

NO12345678

.9101112131415161718192021

MXE SCAN TIME REF RRT METH97 352 6:27 1 1.800 A BB

NOT FOUNDNOT FOUNDNOT FOUNDNOT FOUND -NOT FOUNDNOT FCpilL

77 M3p 7:54 1 1.224 A SBNOT FDn r̂oNOT FDIJIO .

?S

z a e o o i a u

iQOQO°)V

92*91 Van 000*0* *t-6t>ZZ

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zi*£ van scr'2 '91102^ft * fit T i*^rt ftf* T * A * 1 T "^

fS'6 van UA*eg- 'T96S£

V £-

8£*e van 000*82 'st-9S£_ |£*L|- x'̂ pD .̂'j?-^^1?)-7^-1-1 r*

101* INnOUb b3db

GNflOd IONCNftCd ION

88 b 888*1 S2 12*22 2GT?I t'SZCNHDi 13N

QNHQd IONQNnOd IONaNHDd IONGNnOd IONQNOOd ION

JtfciQQd ION8A * £68' I 6S BZ!92

NO787988

NO123456789181112131415161718192621222324252627282938313233343536373839404142434445454748435851

rvE SCAN TirE REF R1NOT FOUNDNOT FOUNDNOT FOUND

RETCL) RATIO~i4:777778888549888999918181011121212131414812171414141515151515161516171717171920

!::!::::::i:::::::jj••;;:!:;;••:j::;:IJ:•::::•:!:

002112132828511226263824135531403820505459831038491932524705073746351633590929394355025548003551574644

0

0

00

0

0

8

1

i

080

.92

.96

.95

.93

.99

.98

.98

.88

.80

.99

.99

.99

RRTCL)10001111111001000000881111

i

00000000008881111

.^,,..•...,.f..,,..,,....,.,,,,.,..........,.,.....

08059799099202502587812615915918672059000904285785392297197898799300505116821723927236236S395855265000804820844053873882885897984897946958991006011114168

RATIO1.88

1.0S

1.071.06

1.00

1.01

1.01

1.88

1.90

1.080.990.99

20.00

2.44

8.211.15

20.00

0.44

0.42

20.00

22.77

0.1?0.137.43

AREA

AMNT(L)20.0850.0050.0858.8058.8058.0058.0050.0050.0050.0050.0050.0050.0820.0850.0050.0050.8058.0058.8050.0058.0050.0050.0058.0050.0050.0050.0050.0050.0050.0058.0050.0050.0020.0050.0650.0858.0050.0050.0050.8050.0050.0050.0050.0050.8050.8050.0050.0058.0050.0050.00

ArtDUNT XTOT

R.FAC1.008

0.014

0.0050.018

1.000

0.004

R.FACCL)1.0000.4111.1300.9688.8281.0798.8900.2880.6040.2321.3240.7658.3691.0003.0230.1100.4020.1440.3380.47B0.3020.379

0.009

1.000

0.404

0.0020.0020.226

1.8400.1668.2760.1068.2088.6760.5700.6120.1048.1388.3221.0008.5860.0280.1420.0670.7190.3940.8860.8450.2110.0110.2130.3160.1258.3320.9341.5188.971

RATIO1.80

8.85

0.008.02

1.00

0.01

0.01

1.00

0.46

0.000.000.15

f lR I00383

NO"525354555657SB59606162636465666768697071727374757677787988

RETCL)21:1516:5117:3518:6919:0520:3921:1524:1121:1923:2524:1924:2324:2823:0126:2921:5421:5222:4223:2521:2123:2022:1922:2927:1824:2024:2029:5223:5230:16

RRTIO

1.001.000.991.60

1.00i.ee

i.eo

RRTCL)1.1970.9490.9911.0231.0751.1S31.1971.0666.0760.9626.999I.0C21.0961.6291.0890.9010.8996.9330.9620.8788. 9550.9170.S£4! . 0ns9.3r20.992LOSS1.0SS1. 102

RATIO

i.eei.ee1.001.60

i.oei.ee

1.60

AMNT

26.8420.00

0.6415.51

23.B616.63

4e.ee

AttrrcL)se.ee50.06

iee.eese.ee56.00se.ee56.6026.6050.0658.6656.6050.0050.0850.60so.ee56.665B.eese.ee56.6050.0050.00se.ee50.0046.0050.005D.OO59.90£ ~ . " TSu.uO

R.FflC R.FAC(L)1.0280.1578.1270.0960.118

0.2251.0000.0010.339

0.7040.698

1.000

6.0230.4191.6000.1101.0948.9348.6860.3111.4762.0990.3390.395O.S120.4060.0368.8870.1640.0401.380

•0.7570.7570.4431.3142.258

RATIO

0.541.000.010.31

0.480.33

1.00

A R I 0 0 3 0 U

BIC04/18/82 19:43t00SAMPLE: C05047RANGE: G 1,1700 LABEL: N 0. 4.0 QUAN: A 0. 1.0 BASE: U 20. 3

DATA: 23352F1 tlCALI: FC 11 2581 11 SCANS 290 TO 1780

o

BIC_ 1795

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DUAL MASS SPECTBUnW/18/82 19:43:88 + 7:54SAKPLE: W9M7ENHAHCED

01 14.6 n

DUAL HASS SPECTBUH84/18/82 19:43t89 + 15:49SAMPLE: C85847EHHAHCED (S 15B 2N 0T)

DATA: 23352F1 9955 BASECALIt FC112581 II BlCt

43/ H9381. / 2399.

7.3-

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141,

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DUAL MASS SPECTBU194/18/82 19:43:00 + 19:33SAMPLE: C05047ENHANCED

DATA: 23352F1 11273CALh FC112581 11

BASE tt/Ei H9/ H9Bid 70,/ 1995.

52.

<oCD

150

1116.

DUAL HASS SPECTBUTI84/18/82 19:43:08 + 23:28SAIfPLEi C85847EHIAHCED (S 15B 2H 0T)

2.3-

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58.8-

188.8

\:

DUAL HASS SPECTBUH04/18/82 19:43:86 + 25:66SAHFLE: C85647EIWAHCED (S 15B 2H 6T)

DATA: 23352F1 11364CALl: FCU2581 II

BASE n/E,- H9/ 149KICi 619./ 2675.

9.1-

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C15.H24.0H UT iiyI PK 2@5SAi'lK iIII 1642FIT 987J

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II VT 220t PK 285BANK 2IN 12178FIT 839

C16.Hi2.01898

H VT 228B PK 228BANK 3IN 4497FIT. 837,

H/E 48

LIBBABY SEABCHSAMPLE: C85847EMIAKCEB (S 15B 2H 6T>

DATA: 23352F1 I 795CALIt

BASE M/E: 295BIG:

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LIBBABY SEABCH84/18/82 19:43t88 + 21:54SAMPLE: C85847ENHANCED (S 15B 2N 8T>

DATA: 23352F1 11196CALIi K112581 I 1

BASE 11/Ei 57BICi 17631.

11

1 \l^x

11

1-PEMTANOL. 2-ETHYL-4-METHVL-

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REPORT FILE: 23352V4DATA: 23352 V4.T I04/06/82 13:^ 3/16/S2 11L IN 50MLS H20FORMULA: BFBE05 INSTRUfENT: 4021 UEISHT: e.000SUOMiTTCD 3Y: VOLQ23 RHfiUYST: D? fr53? rtCCT. NO.: FC1 12

fiMOUMT-fiREfl * REF.ftrtiVCKEF.AREn* RESP.FACT)

NO12345678o

101112131415If17181920212223242526272029303132333435

NO123456789

10

NPMErRQMnCHL3ROf!ETHnHE (INTERNAL STANDARD)

45V CHLQRGMcTHANE46V ERCMOtCTHANEBSV VINYL CHLORIDE1GV CHLOROETHAME44V rCTHVLEHE CHLORIDE

2V nCPOLEINIV ACRYLONITRILE

49V TP I CHLCSOFLUOROMETHANE29V 1 . 1-D ICHLOROE-HYLENE13V 1,1-DICHLUSQEtHANE30V TPfiNS- 1 . 2-D JCHLOROETHYLENE23V CHLOROFORMIGV 1,2-DICHLOROE'HANEII V 1 . 1, 1-TRICULOROETHANEGV CASE-ON TETRXHLOniDE

43V BRQMODICHLORQMETHANE1,2-DICHLOROETHANE D-4 (SURROGATE)

1,4-DICHLOROEUTANE (INTERNAL STANDARD)32V 1 . 2-D ICHLOROPROPANE33V TR^NS- 1 , 3-D ! CHLOROPROPENEBrV TP. ICHLCItCETH'd.ENE

4V GEK2ENE33V CIS-1, 3-D I CHLOROPROPENEKV 1, K2-TRICHLOROETKANH51V D IPROMOCHLORCMETHANE47V EROHDFORM65V TETRnCHLOROuTHYLENE15V 1. 1.2.2-TETRACHLOROETHANE86V TOLUENE07V CHLOROBENZENE38V ETHYLBEM2EHEBENZENE D-6 CSUrJROGflTE)I-CHLORO-2-BROMOFROPANE (SURROGATE)ETHYLBEH2ENE D-10 (SURROGATE)

tVE SCAN TIÎ REF RRT METH AREA128 94 4:51 1 1.000 A BB 23461.NOT FOUNDNOT FOUNDNOT FCUNDNOT FOUND

34 64 3:18 1 0.681 A BC 29519.56

NO:n1213141516171819202122*h**2j>242526272329303132333435

NO1234567891011121314151617181320212223242526272B29

n?E *. SCRNNOT FOUNDNOT FOUND83 14*-98 ,t29/NOT FOUNDNOT FOUNDNOT FOUND65 12755 27263 177

NOT FOUND.130 Uflfl-^O i Qf7o »36NOT FOUND97 !BQNOT FOUNDNOT FOUNDNOT FOUNDNOT FOUND91 2G9

TIKE REF RRT HE1H

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C P' /- 1 - •i -. ; - :QUANWftTION REPORT FILE: 23352V3

DATA: 23352V3.TI04*-S6/S2 13:06:03SAMPLE: EEflGENT SLflNK 633-261 0.--« •« iC.**-j/*f£Cr+CONDS.i 1ML EXTRftCT IN 33MLS H20FORMULA: EF8205 INSTRUMENT: 4021SU3MITTEL '

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HID MASS CHBOMATOGBAIIS•4/19/82 21:25:99SAMPLE: C5048-DIOXIHBAHGE: G 1. 8 UK EL: H 3*

DATA: 23352D2 1174CALIt FCI12581 fll

QUAH: A 1. 1.8 BASE: U 58, 3

SCANS 159 TO

1892t42

5376.

237.977± 9̂ 599

1852:46

187

SCAH jTIBET4

s-

-s13 &

-S

i9

85

Is

£15

lien Ktf&c

. 3L

. T9V

3-6;t<.tfJL

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îfll..

. V/6,

-^v

AD_

.57T

^JL

L

P. E. PEST, MIXFH3 200ISO 62 HPR 013 11:26:420

CHRNHEL 4 RUN 5 FILE 7 METHOD 5

INDEX 1 CflLIBRflTIOH

HftllE CONC RT RRER KF

123

R-BHCG-BHCB-BHCHEPTD-BHCRLDRIN1011

HEPT-EPOXfl-ENDODDEDIELDRINEHDRIN

17 .DDO-B-ENDDDTEND-flLDEND-SULF22

METHOXV

TOTfiLS

f -' r~:\s i .: _(Red)

. 2

.2

.87

. 2

. 51-2

.2

. 424

.2,2. 51

->• -». 57.23

1. 111

6. 922

861051171341661882022182422813092584485105406547107779301030124015101743

626626353491

1353481294091730411067651485679594676104790

105874720661010621210341260561998

130519147739S552522585510750109694

2102040

SsI111mt

J.

1

1

Lmt

X_J^XLX.1S-*.'-

926700647000193900533800291300479700

529300172200505300605200247200

435100259200271800203500

109700

NEW FILE

NRME

R-BHCG-BHCB-BHCHEPTD-EHCRLDRIHHEPT-EPOXR-ENDODDEDIELDRINEHDRINDDD-B-ENDDDTEND-RLDEND-SULFMETHOXV

RT

133166138202217242357447509540653776928102812401741

KF

926700647000198900532300291300479700529300172300505200605200247200425100259200371800203500109700

STD

flRIOOl*38

C r- < /"s t * i * i• f \ i >_- ' • - . -

L50S

.741

P.E,PEST,MIXPHS 200ISO

CHflNNEL 4 RUN 6

INDEX 2

NRME CONC

62 RPR 013 12:09:330

FILE 7 METHOD 5

RT RRER KF

12

fl-BHCG-BHCB-BHCHEPT0-BHCRLDRIN

910

HEPT-EPOXfl-ENDOODEDIELDRINENDRIH16

DDD-B-EHDDOTEHD-RLD

. 201

. 194

. 843

.199

. 507

. 197

.196

. 416

. 194

.193

. 521

. 296

. 534

. 227

86104133166iee201

. 2172432303093574475085406527107759281028

65902542

1858961255381685871062631478159438474124671

10368071746979371166521288632109

12888913844684485

\S.j111.•J.1JLL^1-j_i1L1_i

926700647000198900533800291300479700

529300172300505300605200247200

435100259200371600

A R I 0 0 4 3 9

END-SULF21

METHOXV

TOTflLS

1. 1

. 985

6. 805

124115081741

22364011335103027

2065757

S 203500•it••- 109700

•fij219

442

510566

632

717

802

§?£310

977

D.090

197

417

C.657

h-830

ARIOOHO

P. E. PEST, MIXPHS 200ISO

CHflNNEL 4 RUN 7

82 flPR 013 12:27:010

FILE 7 METHOD 5

W 6. •s 1 •:00CD

2193Wc-Ol337391431

504

532

658720

795

920

063

JL197

400

517

fl.660

P.E.PEST,MIXPHS 200ISO

CHflHMEL 4

INDEX 8

NRME

1R-BHCG-BHCB-BHC

RUN 13

CONC

. 002

. 005

. 057

82 flPR 013 14:52:100

FILE 7 METHOD 5

RT

106135167180

RREfl KF

1857 S1983 S 9267003081 ^ 64700011261 •-_ 198900

P.E.PEST,MIXPHS 200ISO 82 flPR 013 15:16:150CHflNHEL 4 RUH 14 FILE 7 METHOD 5

•MMMMMB*

IMOEX

NRHE

1

TOTfiLS

327391

504

530

802

L197

L410

L660

CONC RT

13

RRER

1117 L

1117

lO

KF

f lRIOOH3

P.E.PEST,MIXPHS 200ISO 82 flPR 013 15:40:440

11 IT

CHflNNEL 4

INDEX 10

NRttE

1R-BHCG-BHCB-BHCflLDRINHEPT-EPOXEND-SULFMETHOXV

TOTflLS

RUN 15

COHC

005003059009002034078

.196

FILE

RT

10513616617826039111971660

o

METHOD

T-% f /-. I -, t » J

' - • • ' • -

(..-:.; ro

RREfl

11755072509011765.4513101569448526

44105

KF

SX 926700< 647000•-. 198900479700

L 529300203500

.. 109700

967

067

197

413

L560

L660

LB13

RRlQQkkk

(Red) COcoP. E. PEST/MIXPHS 200ISO

CHftHHEL 4 RUN 16

INDEX 11

NflME CONC

82 ftPR 013 16:05:540

FILE 7 METHOD 5

12

R-BHCG-BHCB-BHCRLORINHEPT-EPOXENO-RLDHETHOXV

TOTRLS

023017201004002003033

. 284

RT

10612513416617826038810671660

RREfl

166714191

2177411351399331808122711343603

101692

KF

11^ 9267001 647000S 1989001 479700529300

1 371800< 109700

ARIOOH5

CO.870

E. PEST, PIIXPHS 200ISORNNEL 4 RUN 17

DEX 12

(IE CONC

82 APR 013 16:30:470FILE 7 METHOD 3

RT RREfl KF

1BHC•BHC '•BHC.DRIM67:PT-EPOX9

10RIN0-B-ENDD-flLO13D-SULF15THOXV

TRLS

ô T̂ -srft

fftffir

C —— "24Jfas _=̂̂ 557-̂""̂ 447

*̂ So/̂ —— "T40

.559

.099

.016

.033

.021

.006

. 004

. 007

.023

.252

1.048

5 OAL

1 ———— 42

^̂ ^̂ _̂ i,4Hsŝ ^̂ ^̂ ^̂ s2a icJ

108138̂17821026123032936638671276210631130119713631667

Q U£nc

; J4

TT~./

169541318463197124779265865616296211226610014051636259630345795103627676

808163

G£*—-i»

1sss1L1111L1iSSs

926700198900291300479700

529300

247200435100371800

203500

109700

•

L310

.743

P. E. PEST, MIXPHS 200ISO

CHRNHEL 4 RUN 13

INDEX 13

NRME CONC

123

fl-BHCQ-BHCB-BHCHEPT0-BHCflLDRIH1011

HEPT-EPOXfl-ENDOODEOIELDRINENDRIN17

ODO-B-ENDDOTENO-flLDENO-SULF

22METHOXV

TOTflLS

82 APR 013 15:53:470

FILE 7 METHOD 3

RT flREfl KF

211204891193556205

2044241982527

30954922311

965

861051171341661882022172432803093374475105405547107779301027124015101743

671327272946

1956471320751772221032441619339820713693904

108261730901001521212341303341309

1344371423818471722578510484105831

\\S-*.111-iJ.JL1jj1_,_,1L1LS\\_

926700647000198900533800291300479700

529300172300505300605200247200

435100259200371800203500

109700

5.973 2125027

15.6-

181 _

109.0-1

188 _

16.7-1

266 „

10.3-

442 __

I ;

hASS OtttmATOGRAHS DATA: SE54SEM3215 fei SCAMS 4C9 TO04/19/82 16:04:60 —rf n,_t CALI: FC 112531 01SAIIPLE: FUSED SILICA SSiSITlVW ^c '/(OtftN *>^vx*£*£»JtAHGEi G It 800 UCFX: H 3. 4.0 IRMM: A i. 1.0 BASE: U 54, 3

52817663.22J3I.

1 625fl 5364.

468 I A339. / 1^ .

——— i ——— , ——— | ——— | ——— | ——— , — •*,_: —— , ——— , ——— ——— , ——— , — i_^ ——— , ——— - ——— , ——— , ——— , ——— , ——— - ——— , ——— ,_J — f-^| - -i - — i ——— i ——— i ——— r528

113152.

[ 5811269.

' 5 . 8 • • • • • - • • • - - . - - - •18889.26901.

. . . . . . . . . . . . . | R . . . . . . . . . . . . . .

11696.13169.

i i , , | , , r •• r -f — r •— 1 -1 •! i | i~ ™i " ~i •' - r- - 1 - - i- T- -T —— r- -j- — t — i ——— f— -iCd 450 500 550 669 659:29 8:15 9:10 10:05 lf:t& 1 « ^

760 ;t

ji

17600. •

I84.B55

1

113152:.

18ft. 056 CO± ».50aj-C3

— 1 _or

188801 **

i

11696.

442. 132± 0.500

,7??-^ §?*!t !'

: tj'l?y 188.8-

i

58.8-

!

•

•

i

MASS SPECTBUH84/19/82 I6t84t68 4 10: 13SAMPLE: FUSED SILICA SEISlTlVltYENHANCED (S 15B 2N OT)

i «

4

51

3

i.: •

77

691

TJ.f"*! • 1 '"T'H

tio

i

0

*

f

Y

t49,,r'• »7^ 16r'•i •" ' h\*\ ̂ i l - i

i58

6

i| J L2332:

j)i4

2-

Vr

25

• *

2

,'T T ''T1

258

ftATAs SE54SEHS215 S55? BASE H/E: 193CALIi FC 112581 81 B1C: 50560.

442

••** '

• •

5 • . •; . -

• •

1 T 3?3. 354,. 483 T* ' ' 1 r l''~t ' 1 ' 1 ' 1 ' p 1 M ' 1 ' 1 ' 1 ' 1 ' 1 ' 1 ' f • | • i • i • i •"!

} 380 358 4G9 450 i

*

4

- 7144.i

•

'

cn5-CDCD

or .

•

•

•

u

. ,T DATA: SE54SENS215 * 557 BASE fVE: 19B& 16:64:00 + 18:13 CALI: FC1125B1 * I RIC: 58560.

it FUSED SILICA SENSITIVITY- ĈED (S 15B 2N 8T>

41 0.00 8.88 6. MINIMA MIN INTEN: 6.AAA * n MavTMa444MASS

41.8843.0044.3949.8851.8052.8055.0856.8057.6850.0665.0867.8669.0878.0871.8875.0877.0078. aa61.0082. aa83.6004.8885.0893.0895.0096.0096.0899. 60ioi.ee107.00106.00110.00111.08112.06113.00127.08128.80129.08135.00141.00149.60155.03156.00167.00160.80169.00175.80179.80160.08161,06

X Rft X RIC

5.59 0.7910.50 1.482.46 8.356.50 6.8742. S3 6,051.68 8,243.18 6.453.53 8.5824.24 3.434.83 8.578.91 0.130.41 6.0625.03 3.542.49 0.359.46 1.340.98 0.1453.92 7.623.39 0.486.64 8.120.71 8.101.61 0.231.18 0.175.92 0.040.41 0.060.32 6.050.27 6.040.71 8.101.46 0.216.36 6.058.36 1.181.26 Q.IB21.86 3.092.74 0.398.42 0.860.67 0.0948.21 6.313.32 0.475.61 0.790.18 6.830.23 8.802.11 0.308.42 0.860.DQ 0.111.66 0.241.60 6.230.13 8.028.79 6.110.76 8.111.23 0.100.40 0.07

• 0 MAXIMAINTEN. "~ " ~~~ """

399.750.176.36.

3666.128.227.252.1732.288.65.29.

1788.178.676.78.

3852.242.68.51.115.84.423.29.23.19.51.164.26.597.90.

1562.196.38.48.

3444.237.481.13.42.151.38.57.120.114.9.56.54.92.34.

MASS

186.60187.00188.00193.00196.60196.00199.60264.80285.80286.60267.60211.00217.00221.00223.00224.80225. an227. fit)229.60242.80244.80245.00246.00255.00256.80256.80273.80274.00275.00276.00277.00296. OR297.00303.0Q323.00334.80352.00354.00365.80372.60483.30421.80423. 00424.60441.60442. BO443.00444.00

X RA X RIC

9.78 1.382.59 8.378.21 8.030.22 8.631.66 0.15

180.08 14.136.44 6.911.53 0.224.33 8.6126.13 2.842.65 8.378.27 8.842.79 8.393.42 0,481.02 0.14

11.44 1.622.30 0.321.30 8.180.34 3.050.14 0.829.31 1.328.97 0.146.24 6.6348.15 6.885.75 8.810,48 0.071.20 8.173.89 6.5522.31 3.152.59 6.370.67 0.093.19 6.450.18 8.830.15 6.021.39 Q.206.70 0.100.15 0.020.25 0.841.44 6.268.74 8.196.25 8.648.26 8.633.11 0.446.4G 0.0711.66 1.6580.24 12.4715.12 2.141.11 0.16

INTEN.

699.165.15.16.77.

7144.468.109.309.1438.189.19.199.244.73.817.164.93.24.10.

665.€9.17.

3440.411.34.86.278.1594.185.48.226.13.11.99.58.11.IB.183.53.10.14.

222.33.633.6384.1680.73.

ORIGINAL19S

FUSED SILICfl SENSITIVITY * ! » ICi 50568*ICED (S 15B 2N 0T)

350 a.w 0.00 mHM Mm INTENI ^

TNTEN. loa* Rfi flT IVE:352.00 a.17 0t02 ..354.00 e.29 a.84 ^365.29 1.63 0.20 103.372.00 0.84 0>JO

£w ..«u

8in

a

3*2THO>—>+2=(C^J^o—^EES&ta*"5 »3

SMJ<

s îia

g iirf

*>

S-

rii

-in

h ea

-S

(p^y) §

MASS SPECTDU194/19/82 16:94:06 + 9:39SA/tFLE: FUSED SILICA SBISITIVITYENHANCED IS 15* 2N »T)

DATA: SE54SEIIS215 0518CALI: FCU2581 ttl

BASE rt/E: 266BIG: 80896.

50.0H

266 r 11712.

ooLO-rrCDoor .

i ' n i " i • M i i i i i i300 359 459

26̂180.8-

58.8-

HASS SPECTBU184/19/82 16:84:08 + 11:27SAMPLE: FUSED SILICA SENSITIVITYENHANCED

Q MriTATION REPORT FILE: 6NAP047

DATA: DNflFB47.TI04/18/62 12:27:80iAMPLE: SeUG/Tt. 6502 FUSED SILICA STANDARD

CONDS.: FSCCFORMULA: SEH5213 INSTRUMENT: 4021SUBMITTED BY: BNAP047 ANALYST: DP

ORIGINAL(Red) I

UEIGHT: 6.000ACCT. NO.: FC112581

AMOUNT-AREA * REF.AMNT/CREF.AREA* RESP.FACT)

NO NAME1 2,4,6-FHENOL D3 (INTERNAL STANDARD)2 18B BIS (2-CHLOROETHYL) ETHER3 24A 2̂ -CKLOROPHENOL4 27B 1,4-DICHLORGBENZENE5 1.2-DICHLOROBENZENE6 42B BIS (2-CHLOROISOPROPYL) ETHER7 12B HEXACKL3ROETHANE8 PHENOL9 PHENOL D-5 (SURROGATE)10 PYRIDINE D6 (SURROGATE)11 NAPHTHALENE DG C INTERNAL STANDARD)12 63B H-HITROSO-DI-li-PROPYLAMIHE13 NITRO»?EN2EHE14 ISOPHOROHE15 S7A 2-HITROPHENCL16 34n 2. 4-D IMETHYLFHEKCL17 43B BIS (2-CHLOROETHOXY) METHANE18 31fl 2,4-DICHLOROPHEMOL19 BB 1,2,4-TRICHLOROBENZENE20 55B HnPHTHALEHE21 520 HCXfiCHLORQEUTADIENE22 22fl 4-CHLORO-M-CRE£CL23 53B HEXACHLOROCYCLOPENTADIENE24 21 A 2,4,S-TRICHLOROPHENOL25 28B 2-CHLCRONAPHTHALENE26 77B ACENAPHTHrtLEKE27 71B DrM£THYLPHThfiLflTE28 3GB 2, S-D INITROTOLUENE29 NITTOEcNZEHE D-5 (SURROGATE)30 2-FLUOPQIPHEHYL (SURROGATE)31 PHENANTHHENE DID (INTERNAL STANDARD)32 IB RCCNftPHTH^HE33 59 A 2 . 4-D IN I TROPHEHOL34 35B 2, 4-D I N I TROTOLUENE35 4-NITRCFHENOL36 eeo FLDQPCHE:37 42B 4-CHLOROPHENYLPHENYL ETHER38 708 DIETHYLPHTHflLATE39 6e A 4, 6-D IN I TRO-0-CRESOL ,40 62B N-NITROSODIPKENYLftMINE41 378 1,2-I»IPHENYLHY3RAZINE42 41B 4-GPnMOPH£r'OXY6ENZEHE43 9B HEXfiCHLO^OBENZENE44 64A PENTACHLOPCPHENCL45 BIB PHEHftHTHRENE46 7EB ANTHRnCEKE47 6£0 D I -N-GUTYLPHTHnLflTE

ARIOOl*55

ft'u494950515253543556575859606162636465£66768697071727374757677737980

NO123456789101112131415161718192021

"NAME393 FLUORftHTHENE8*B PYRENEALPHA 0HCGAMMA 8. BETA BHCDELTA-BHCHEPTACKLCRALDRIHPYRENE 010 (SURROGATE)CHRYSENE D12 (INTERNAL STANDARD)53 BENZ1DINE67B 9U7YLBEHZYLPHTHALATE2RB 3,3'-DICHLORCBENZIDINE668 SIS (2-ETHYLHEXYL) PHTHALATE69B D I -N-OCTYLPHTHALATE4, 4* -DDEDIELDRIN4,4'-DDD4.4*-DDTBETA EJDOSULFANENDOSULFAN SULFATEENDR1NALPHA ENDOSULFANBENZO (3) PYRENE D-12 (INTERNAL STANDARD)748 CENZO (B) FLUORfiNTHENE73B BENZO (A) PYRENES?B INDEHO-1,2.3 CC,D) PYRENE82B DIEENZO CA,H) ANTHRACENE798 BENZO CG.H, I) PERYLENE61B N-NITRQSQ-DIMETHYLAM1NE26B 1 . 3-D ICHLOROBENZENE2-FLUQRCPHENOL CSURROGATE)72B EEMZO (A) ANTHRACENE768 CHRYSENE

M/E SCAM TIME REF RRT METHS7 387 7:86 1 1.000 A BB93 303 7:31 1 8.990 A BB128 284 7:02 1 0.992 A BB146 400 7:20 1 1.034 * VB146 419 7:41 1 1.083 A BB77 443 8:07 1 1.145 A BB117 454 8:19 1 1.173 A BB94 454 8:19 1 1.173 A BBNOT FOUND56 227 4:10 1 0.587 * W136 549 10:04 11 1.000 P BB130 458 8:24 1! 0.834 A BB123 460 8:35 11 8.852 A 8882 466 8:33 11 8.849 A BB139 506 3:17 11 0.922 A BB122 529 3:42 11 0.964 fl B893 535 9:40 11 0.974 » OB162 543 9:54 11 0.9B4 * BV180 545 9:59 11 0.993 A 80128 552 10:07 11 1.605 A BB225 579 10:37 11 1.855 ft BB

AREA11461331682786632238240407645165416478

2849372122111106293120111497398125.11 5 B29955,39447,IOS435,15890,

ORIGINA(Red)

AMOUNT20.08072.97455.578£0.19355.91661.24954.21959.821

13.47320.00031.17530.66935.33728.50852.69Q56.3B343.15254.95548.42147.222

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

*TQT6.541.991.511.641.521.671.431.61

0.370.540,859.840.960.781.431.531.171.471.321.23

Kb222324252627282938313233343536373839434142434445464743495G515253545556575859606162636465666768697071727374757677

~f1/£*1422371961621521631651281721531541841651391662841491981687724828426617817314928223218118118127226321224318414925214914924679235235195272811SS2642522522762782767414G

SCAN645SG9£897317557G67634£S6=8969778797817829845856861Q7087587091S9329639739791673113411609229649951Q4411281157132811671291133813661449119511941241127911671276121712Z8149313331323162916291656221392

TIME11:4312:1612:38-12:5113:5014:3314:358:3312:4317:4614:1614:3714:5915:1215:2915:4215:4715:5716:3215:5716:5017:0517:3917:5017:5619:4720:4721:1616:5417:4018:1419:8820:4121:1324:2121:2423:2924:3225:0326:3421:5421:5322:4523:2721:2423:2422:1?22:3127:2924:3224:3229:5223:5230:154:037:11

REF RRT111111111111111111313131313!3131313131313131313131313!31313131313!315656565656565G5656565656565670707070707011

1.1751.2191.2551.2771.3751.3951.4010. 8431.2711.0008. 8038.8220.8430.8568.8720.8838.8890.8988.9030.8980.9470.9620.9941.0041.0091.1141.1701.1970.9510.9951.0271.0771.1641.1941.8000.0790.9651.0081.0291.0913.9000.8990.9340.9630.8790.9610.9168.9251.0000.G930.8931.0871.087i.mi0.5711.013

METHR BBft 88A 88A BBA BBA BBA BBA BBA BBA BBA BBA BBA BB.A 88

BVBBVBBBVBBV

A BBA BBA BBWWVBVBW

A BBA BBA B8A 88A BBA BBP BBA BB* VB* BV* VB* VBA B8A BBA BBA GBA 88A BBA BBA BBA BB* BV* BVA BBA BBA OBA BBA BB

AREA28424.6778.20348.77372.64418.71866.11923.12883.92543.38008.55128.1040.14743.5358.68840.36730.85260.2161.20403.785.

20570.31820.9522.89201.98736.162651.99676.97889.14097.22471.8486.18957.2238.£4511.29030 .2256.77653.22261.113708.154751.21612.23646.34706.24978.2280.5834.18696.2507.26203.22261.22261.13754.56324.68259 .10105.23375.

AMOUNT46.19.51.65.65.72.55.104.154.20.53.11.46.27.43.47.44.16.42.36.43.53.28.50.46.49.44.41.40.73.34.45.38.81.20.6.49.47.59.51.40.45.49.38.45.46.37.44.48.39.39.25.49.46.51.43.

90218021565921835460981843000667S9516492060010000134360782057508468692711765073574361001624421626360610004136694633449799858908604576014390529280005945948P4240981007G44

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STOT1.280.521.391.791.771.971.512.854.200.541.460.331.270.741.171.291.200.451.150.391.191.470.791.371.261.351.211.131.091.990.941.231.052.218.540.171.351.291.621.411.121.251.361.C51.241.261.011.221.091.031.086.731.341.231.391.19

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NO787980

NO123456789

ie111213141516171819202122232425262720293Q313233343536373839404142434445464748495051

-nxE" SCflN TIME REF RRT MEJH112 232 5:21 1 0.755 A 88228 1326 24:19 56 0.998 ABB228 1331 24:24 56 1.082 A BB

RETCL)7:007:127:137:287:518:128:268:268:384:139:558:318:488:339:209:509:549:59

10:0310:1018:3811:4912:1912:3212:5213:4714:8314:678:37

12:4317:3514:1614:3314:5915:0915:2915:3915:4315:5516:0215:5516:4317:0017:3517:5117:5713:4623:4421:1516:5117:35

RATIO RRT(L)1.010.970.970.980.980.990.998.99

0.991.010.980.990.990.390.999.990.990.990.991.00.00.00.01.00.00.03.00

0.991.081.811.001.601.001.38i.oe1.001.801.001.001.001.001.011.001.E0.00.03.00.63.00.01

1.0000.9900.9921.025i.EJ781.1261.1591.1591.1868.5901.0008.8428.3570.3530.9220.9710.3780.9870.9931.0051.0511.1631.2171.2391.2721.3621.33Q1.3950.8551.2651.0600.8040.8200.8440.8538.8730.8Q20.8858.8970.9340.8370.9460.9580.9911.0261.0111.1M1.1301.1970.9490.931

PATIO1.00.80.00.01.00.02.01

1.01

0.991.800.990.990.391.000.991.001.001.001.001.001.011.001.011.001.011.011.800.991.001.001.00l.QO1.001.001.001.001.001.001.001.001.00.00

1.00 .1.001.G31.001.00i.nn1.001.00

fiMNT20.0072.9755.5968.1955.9261.2554.2259.02

13.4720.0831.1830.8735.3128.5152.6956.3043.1554.0648.4247.2246.9019.1851.22€5.6665.2272.3555.61

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AREA20474.70164.67440.

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R.FAC R.FACCL)1.8E01.158

. 0.9731.1258.8390.2670.5770.226

0.0991.0008.0230.1140.3350.1248.4230.55Q0.3220.4241.1440.1710.3C68.0730.2190.0320.6920.7720.1288.1380.9351.0080.5800.0118.1550.0560.7240.3870.8970.0230.2150.0080.2160.3350.1000.9391.0391.7121.0491.0236.1480.11G

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NO"1112131415161?1619202122232425262723233U3132333435

HO1234567B31011121314151617181329212223242526272829

M/E SCPN TIME REF RRT63618393 •57117836555637513073"5971271731648591112ies347738

FETCL)4:541:141:452:812:233:213:4(13:564:274:455:235:566:126:437:367:518:376:4814:039:099:189:4(318:1410:1410:1410:0412:0213:5413:43

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Exhibit B^Page 43 of

I____I____1____t____I____1____fQ*t«

i______I______t____ I (_ t 1

~J•~c-c.fr i_ CO .

. _ ® ^KJtr̂ ^u?

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1_____I_____I_____1____ t_____t___ _t1

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FSCC Ongoing QC Data — Ajrea Counts for the Internal Standards Versus.Time

Form IS

(Red)

?.un nc Analyst

a/* Ion Abundance Criteria S?£C S?£C ') \ SPEC if !I

51 30-60Z Of 3333 193

63 less rhaa 2* of S333 69

70 1*93 thaa 2* of zaaa 69 O

127 40-602 of M33 193

137 less Chaa 1" of =as3 198 ' Ni Q

193 Sa3e peak, 100Z rslacive abundance

159 3-31 of =aa3 193

273 10-302 of =aaa 198 2.O

363 1* Of =333 i1

44' 1*33

grcat-r ;haa -01 of =ajs 198 6-O - i

443 ; 17-232 or zasa 442

Z, A

Ixaaple 37.

A R I O O ^ S I202

\/C!r7 OR. AL

ORGANICS ANALYSIS DATA SJCET^^ga 2 |$ampIa~NMibar

Laboratory Maad CoavuChan

Lab Saw I* 10 NO. I335"7

QCRapcrtMO. (9-50

VOLATIU5

2V acrolvln

3V •CTYlonltrll*

4V Mnz«n«

6V carton trtr«cMorld»

TV diloro6«nz«n«

10V l,2-dlchlororm«n«

11V 1J,1-trlctiloro*t1wi«

13V 1,1-dlettloro t̂ian*

14V 1,1,2-rrlcMorocthwi*

19V 1,U2,2-t«trachloro«ttwn«

16V cftloro*ttwn«

19V 2*ehlorovrtivl vinyl «ttwr

23V chlorofom

29V 1,t-dlchlororrtiV)«n«

30V 1,2-trans-dlchloromiYl«n«

32V 1,2-dlctilaroprop«n*

33V 1t3-dlctiloropropvl«n«

38V vtnylbanzan*

44V Mthyl«n« eMorld*

45V Mttiyl ehlorld*

46V Mtttyl broild*

47V braofar*

4«V dleMorobroMMthan*

49V trfchlorof luoroMtlwn*

90V dlchlarodlfluoraMttwn*

51V ehlorodlbranMthm*

S5V tvfrBcMorMThylww

•6V tollMIW

87V trlehloro«tftyl«n«

88V vinyl ehlarldt

ug/l

M>

NX)

NO

toNO

M>

M)

ND

ND

ND

NO

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

89P

90P

9tP

92P

93P

94P

95P

96P

97P

98P

99P

100P

J01P

102P

103?

104P

109P

106P

107P

108P

109P

HOP111P112P

113P

1Z9B

PESTICIDES

•Idrln

dl«ldrln

ehlordwi*

4,41-ODT

4,4*-OOE

4, 4 '-COO

•1 pha^mdosu 1 f «n

brf»-*odo*ulftn

•ndosulfan tut fata

•ndrln

andrln aldahyda

h«pt«chlor

twptaehlor apoxlda

•Ipha-BHC

bat«-8HC

dalta-OHC

gaaM^HC

PCS- 1242

PCS-1294

PCS- 1221

PCS- 1232

PCS- 1248

PCS- 1260

PCS- 10 16

toxaphana

Of OX INS

RECEIVEDAPR 2 11982ecology -S î

environment, incPhiladelphia

2,3,7,8-tatracMarodibanzo-

p^loxln

ND « WT DETECTED

*LMS ttian 10 ug/l

(OMtlcfdM IMS than, lug/1)

f l R I O O U 8 2

ORGANICS ANALYSIS DATA StCtT - Pag* 3

ORIGINAL(Red)

Lib NMW: HEAD COMPlOCH

QC Aaport No.13357

sampfa Nunbar

A. Surrogatt Splk* Rasults

Compound

d^6wiz«n«

dy*Toluan*

Fluoroofiwiol

dg-At«nol

Aantaf I uorophano I

dg-Nltrobanzan*

Fluor ob Iphwiyl

dg-ttophthalan*

Fraction

VQA

VOA

ACID

ACID

ACID

BN

BN

BN

Conc.(ug/t)

"2.VMH

VL#i

A r̂

(Surrogatas Only)SplkaMdad (ug/l)

20

20

100

too

too

100

100

100

iRaeovar>

ioT

liv

ORIGINS(Red)

QUALITY CONTROL NOTICE

The volatile analysis of sample ___laboratory artifact slloxane at scan

shows the presence of theThe presence of this

compound has resulted from the addition of an antlfoaming agent andmay or may not actually be present in this sample. Slloxane has notbeen listed as one of the non-priority pollutant compounds Identifiedin this sample.

O .

Director, Quality Assurance

ARIOOl*8l»

ORIGINAL(Red)

OMAN ICS ANALYSIS DATA SHEET - Atg* 4

Ub MEAD CCMPUCHEH

QC REPORT NO: lg-5£>

3357SAMPLE NUMBER

B. TENTATIVELY IDENTIFIED COMPOUNDS

12

3

4

5

6

7

8

9

10

11

12

1314

13

16

17

18

19

20

21

22

23

24

23

26

27

28

29

30

CAS / COMPOUND NAME

"̂ /•w. *̂ - ̂ \f ,rj(J

* / .

FRACTION% MAXIMUM SCORE ATTAINED.MASS MATCHING ROUTINES

(SPECIFY)

f lRIOOl»85

ORGAN ICS

laboratory Naw Haad CoapuChan

Ub Saapla ID NO. 13358

OC ftapcrf NO. lf~£O

VOLAT1LES

2V acrolaln

3V acrylonltrfla

4V banzana

6V carton tatrachlorlda

TV ehlorooanzana

10V 1,2-dlehloroathana

11V 1,1,1-trlchloroattiana

13V I.WIchloroattiana

14V 1,1,2-trlehloroathana

13V 1,1,2.2-tatrachloroatftana

16V ehlorowfhana

19V 2-chloroathyl vinyl athar

23V chloroform

29V 1,!-4lehloroathy1ana

30V 1,2-trans l̂chloroathylana

32V 1,2-dlehieropropana

33V 1.3-tflchlorooropvlana

30V athyl banzana

44V a*thy|«na chlerlda

45V aathyl ehlorlda

46V •ethyl proMlda

47V broaofoni

40V dlchlorobroMMttiana

49V trlchlorofluoroMthana

50V dfehlorodlfluoroavthana

51V eh 1 orod 1 broaaa»thana

•5V tatraehloroathvlanaAMW «H 1 - —— -•D* TQIIMnV

•TV trlehloroathylana

MV vinyl ehlorlda

ND • NOT DETECTED

•ANALYSIS

ug/iND

ND

ND

ND

ND

ND

NO

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

NO

ND

ND

ND

ND

DATA SHEET-Paga 2 O4= ^Otl-Co//^^

PESTICIDES ug/l

09P aldrln

90P dlaldrtn

91P chlordana

92P 4,4i-DDT

95P 4V4'-DDE

94P 4, 4 '-000

95P alpha-andoculfan

96P ban-andosulfan

97P andosulfan sulfata

9SP andrln

99P andrln aldahyda

100P haotaehlor

J01P haptaehlor apoxlda

102P alpha-BHC

103P bata-BHC

104P dalta-«HC

105P gaMM DIC

106P PCS- 1242

107P PCS-T254

106P PCS-1221

109P PCS-1232

HOP PCS-1248

11 IP PCS-1260

112P PCS-1016

113P toxaphana

01 OX IKS

129B 2.3.7»S-tatracMorodlbanzo-

p-dloxln

*LMS than 10 ug/l

(pMtfcldM IMS than, lug/I )

f lR IOOt .86

(Red)

CRGANICS ANALYSIS DATA SHEET - fega 3ORIGINAL

(Red)

MEAD COtPUCHEMUb _________

QC Raport te. tt-SO NUMtMT

A, Surrogate Splka Rasults

Compound

dfl Banian*

dg-Toluana

Fluoroptwnol

d^-Aanol

Pantaf I uorophanof

dg-Mltrobafizan*

Fluoroblpnanyl

de-lajpnthalana

Fraction

VOA

VQA

ACID

ACID

ACID

BN

BN

BN

Conc.(ug/l )

V\vH\

ix Ar

Itir

(Surrogatai Only)SplkaAddad (ug/l)

20

20

100

100

100

100

100

100

&Racovary

\ol

11°

ORIGINALQUALITY CONTROL NOTICE

The volatile analysis of sample 1 33S6laboratory artifact siloxane at scan 6e

shows .the presence of the" . The presence of this

compound has resulted from the addition of Tn antifoaming agent andmay or may not actually be present in this sample. Siloxane has notbeen listed as one of the non-priority pollutant compounds identified1n this sample.

JLDirector, Quality Assurance

flR!OOij88

ORGANICS ANALYSIS DATA SHEET - P»g« 4

MEAO COMPUCHEM

ORIGINSv (Red)

REPORT NO: SAMPLE NUCER

B. TENTATIVELY IDENTIFIED CtMPOUNOS

I

2

3

4

3

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

23

26

27

28

29

30

GAS 9 COMPOUND WME

'HO^JL. J*44*-£~

• ,

FRACTION% HAXIMW SCORE ATTAINfcD_MASS MATCHING ROUTINES

(SPECIFY)

AH UUUby

ORGAN 1CS ANALYSIS DATA SHEET-Paga 2Sampl* Mnb«r

- Col 1 36

Labor •Tory NBM Maad CoMpuChan

Ub SMOla ID NO. I3JS^

QC Raport NO. /* .SO

VOLATILES

2V acrolaln

3V aerylonltrlla

4V oanzana

6V carton tatraehlorlda

TV chlorooanzana

10V l.Mlctiloroattwna

11V M.l-trlehlcroatnan*

13V M l̂chloreattuma

14V 1,1,2-trlehloroathana

13V 1,1,2,2-tatraehloroaHwna

16V chloroathana

ug/l

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

19V 2-«hloro*thylvlnyl athar ND

23V chloroform

29V 1,1-dlehloroatttyfana

30V 1,2-tranB l̂chloroattiylana

32V 1 ,2-d lehloropropana

33V 1,3-dlchloroproPYlana

38V atttylbanzana

44V Mtttylana ehlorlda

43V M*tiyl ehlorlda

46V awttiyl broMlda

47V broMfoni

48V dlehiorobroaoMrtnana

49V trlehlorofluoroMthana

90V dlehlorodlfluor«M>thana

31V chlorodlbraa0Mttwia

89V tatrachlororrftylana

86V toluana

87V trlehleroathylana

88V vinyl ehlorlda

ND

ND

ND

ND

ND

ND

ND

NO

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

PESTICIDES

89P aldrln

90P dlaldrln

91P ehlordana

92P 4,41-OOT

93P

94P 4,4'-000

99P «tpha-«ndo«ulfan

96P

9TP andoaulfan tulfata

98P andrln________

99P andrln «lda*>yda100P haptacftlor_____101P haptachlor apoxlda102P alpha-SK:______103P bata-WC______^

104P dalt«-BHCI03P QIC106P PCS-1242107P PCS-1234

10BP PCS-1221109P PCS-1232HOP PC8-1246

HIP PCS-1260

I12P PCS-1016

1I3P

(Re

ug/l

ND • NOT DETECTED

Ot ox i us

12SB 2,3,7,0-tatraehforodlbanzo-

p^jloKln _______

*LMS than 10 ug/l

(pMtlcldM IMB than, log/I)R R I O O U 9 0

ORGANICS ANALYSIS DATA SHEET - fege 3

Ub NMW: MEAD COMPUCHEH

QC Report to. Sample

A. Surrogate Spike Results

Compound

dft Binz»n«

dg-ToltMn«

Fluor ophaocl

dg-«WOol

tanttf 1 uoroohww 1

dg-Nltrobwiun*

Fluor ob Iphanyl

dg-lteprrfhalwi*

Fr»ctlon

VOA

VOA

ACID

ACID

ACID

BN

BN

BN

Conc.fug/l)

T^.Vll

O^.H'b

N^

(Surrogates Only)Spfk*Added (ug/l)

20

20

100

too

100

100

100

100

iRecovery

113

\\1

1

ORIGINAL(Red)

ORIGlfQUALITY CONTROL NOTICE ' 6Cf

The volatile analysis of sample /335? shows the presence of thelaboratory artifact slloxane at scan 9*3 . The presence of thiscompound has resulted from the addition of an antifoamlng agent andmay or may riot actually be present 1n this sample. Siloxane has notbeen listed as one of the non-priority pollutant compounds Identified1n this sample.

Director, Quality Assurance

flRIOOl*92

ORIGINALOR6UJICS ANALYSIS DATA SHEET - P»g« 4

NEAO COMPUCHEM

QC REPORT NO: SAMPLE NUMBER

B. TENTATIVELY IDENTIFIED COMPOUNDS

12

3

4

5

6

7

B

9

10

11

U

13

u15

16

17

18

19

20

21

22

23

24

29

26

27

28

29

30

CAS t COffOUND NAME

Ao~^

ORGAN ICS

Labor «Yory NBM MMd Ce*puCn«it

Lab Saapla ID NO. ]_33feO

OC Raeert NO. lf-6o

VOLATILES

2V Krolaln

3V •erylonltrll*

4V banzam

6V carton tvtraehlerfd*

TV cnlorooanzan*

10V 1,2-dlcnloroathana

1 IV 1,1. 1-tr ten loro*ftiafi«

13V M-dlehlororttan.

14V 1,1,2-trIchiororttiafi*

19V 1.1,2.2-tvtr*cnlero«tnMt«

16V cnloroathan*

19V 2-chlororttivlvlnyl cttur

23V chloroform

29V 1, Wlchloroatfcylana

30V 1,2-tran«-d1chloroathylan«

32V 1.2 l̂ehlorepropan«

33V t,3-4lcMorooropyl«n«

38V atftylbMzw*

44V Mltiylarw enlorld*

49V aattiyl ehlerld*

46V Mtnyl breiRld*

47V broMofent

48V dlehloroeroanMHian*

49V trtehlerofluoreMltwn*

90V dtehlerodlflueraMtnan*

91V ehlorodlbre*aMth»n«

89V tvtnehloroattiylan*

86V tot urn

87V trlehlerorfhylan*

88V vinyl enlerld*

•ANALYSIS

ug/i

ND

ND

ND

ND

NDND

ND

ND

NO

ND

NO

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

Sanpla Nunbar ' . . ;DATA »€ET-Pag« 2 C^9A*7-^.C/|3/ / ^ ^ ^^

ORIGINAL(Red)..

PESTICIDES ug/1

89P aldrln

90P dUldrln

91P ehlordan*

92P 4,4t-OOT

93P 4,41-ODE

94P 4, 4 1 -000

99P alpna*«ndosulfan

96P twtm-^do.ylf.n

97P andosulftn sulfat*

98P andrln

99P andrln aldafcyd*

100P twptveftlor

101P haotactitor apoxld*

102P alpha-aHC

103P brta-BHC

104P d«lt»-9HC

109P ymum PIC

106P PCS- 1242

107P PCS- 1294

108P PCS-1221

109P PCS- 1232

HOP PCS-1248

111P PCS-1260

112P PCS-1016

113P toxaphan*

01 OX IMS

129B 2.3,7.8-tatraenlorodlbanzo-

p^loxln

ND • NOT DETECTED

*LMS th»n 10 ug/1

(pMTIcldM IMS than, lug/I}

ORGANICS ANALYSIS DATA SHEET - P»g* 3ORIGINAL\(Red)

Lab Nana: MEAD CCNPUCHEM

QC Report Na. («-5o SMpl«

A, Surrogat* Splk* Results

Compound

dg-8«niwi«

dg-ToiiMn*

FluoroptMnol

d«-̂ Mnol

fentaf 1 uoropttvno 1

dg-NltrobMzwt*

Flucr ob lph«nyl

dg-Mphthalwt*

Fr»ctlon

MM

VGA

ACID

ACID

ACID

BN

BN

BN

Cone.(ug/l)

^vM

-W-^

(W

'

(SurrogatH Only)Splk*Addad (ug/t)

20

20

100

100

100

100

100

100

&Racovary

i«1HO

-

QUALITY CONTROL NOTICE

The volatile analysis of sample /33C&Qlaboratory artifact slloxane at scan ee

shows the presence of theThe presence of thisl

compound has resulted from the addition of an antifoaming agent andmay or may not actually be present in this sample. Siloxane has notbeen listed as one of the non-priority pollutant compounds identifiedin this sample.

Director, Quality Assurance

ORIGINAL(Red)

CRGANICS ANALYSIS DATA SHEET - P»g« 4

Ub MEAD CWPUCHEM

QC REPORT NO: SAMPLE MUCER

B. TENTATIVELY IDEKTIFIED COMPOUNDS

12

3

4

5

6

7

e9

10

11

12

13

14

IS

16

17

18

19

20

21

22

23

24

23

26

27

28

29

30

GAS f CCXKXMO WHE

• t̂a-^u. ^« -̂̂ ^

" / ,

mACTION

A

I KAXIMIX SCC«E ATrAlHfeO-MASS MATCHING ROUTINES

(SPECIFY)

R i o o » » y /"

Fisher Scientific Company

ORIGINAChemical Manufacturing) D&QJorP.O. Box 3751 Reagent LaneFair Lawn. New Jersey 07410(201)796-7100Instruments. Apparatus.Furniture. Chemicalsand Diagnosticstor Laboratories

Dr. Stan BambleEcology and Enamel Co.8021 Route 130Pennsauken,N.J. 08110

Catalog No.Lot No.___P.O.No.

W-5 Name & Grade; Water,HPLCAll lots Grade

This is to certify that units of the above-mentioned lot numberwere tested and found to comply with the specifications of thegrade listed. The following are the specifications tested:

AppearanceColor (APHA)Residue after EvaporationHPLC Suitability Test(Gradient Elution Run]

Total Organic CarbonpH at 25°C

Clearfcolorless,liquidNot more than 5Not more than 0.0001%Pass Test

Not more than 180 ppbNot more than 7.0

REPORTED BY:Gin C. HoAnalytical Laboratory Supervisor

(APPROVED BY: -, /V*,.r 'rTji .'

Signed: 3/9/82

Gaston L. PilloriManager of Quality Assurance

AT •AN! A ̂ BOSTON "CHICAGO "CINCINNATI "I CLEVELAND "DALLAS! DETRO'T ^ HOUSTON DlOS ANGELES! lOUI?VIL_Lf '_ MEMPHIS T^ANDO~- PAHKERSBJRG ~ PHILADELPH.A ^ PmSBURGH ~ RAiEiGH - RICHMOND ~. ROCHESTER "' SANIA CLARA , 51 lOJiS ^ w•uj^^intu'- HAL it AX - MONTREAL - OTiAvvA — ourego n iP (̂B|Tt! jTivfv-oj^Efi _ WINNIPEG • MEXICOCIT> • MJMC« WE,

VO«=

EDMOMOM 3 MALlfAX ~ MONTREAL ~*CE PUERTO RICC • S-NGAPDH' • ZURICH S^TO

Fisher Scientific Company

ORIGINAL(Red)

Chemical Manufacturing DivisionP.O Box 3751