toxicity values (ug/m3) used by mpca for air toxics comparisons

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Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons Chemical Name CAS Acute Air Concentration Acute Air Concentration Source Cancer based Air Conc Cancer-based Air Concentration Source Non-Cancer Chronic Air Concentration Non-Cancer Chronic Air Concentration Source 11H- Benz[b,c]aceanthr ylene 202-94-8 1.00E-01 HRV 4H- Cyclopenta[d,e,f]c hrysene 202-98-2 1.80E-02 MDH Acetaldehyde 75-07-0 470 CAL EPA 5.00E+00 HRV 9 IRIS Acetamide 60-35-5 5.00E-01 CAL EPA Acetone Cyanohydrin 75-86-5 2 PPRTV Acetonitrile 75-05-8 60 HRV Acrolein 107-02-8 5 HBV 0.4 HBV Acrylamide 79-06-1 1.00E-01 IRIS 6 IRIS Acrylic acid 79-10-7 6000 CAL EPA 1 IRIS Acrylonitrile 107-13-1 1.00E-01 HRV 2 IRIS Adiponitrile 111-69-3 6 PPRTV Aldehydes 00-07-9 94 HRV 2.00E+00 MDH 0.08 CAL EPA Aldrin 309-00-2 2.00E-03 IRIS Aliphatic Hydrocarbon Streams (Midrange) VARIOUS 100 PPRTV Allyl chloride 107-05-1 1.70E+00 CAL EPA 1 IRIS Aluminum 7429-90-5 5 PPRTV Aminoanthraquin one, 2- 117-79-3 1.10E+00 CAL EPA Ammonia 7664-41-7 3200 HRV 80 HRV Amyl Alcohol, tert- 75-85-4

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Page 1: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Toxicity Values (ug/m3) Used by MPCA for Air Toxics ComparisonsChemical Name CAS Acute Air

ConcentrationAcute Air

Concentration SourceCancer based

Air ConcCancer-based Air

Concentration SourceNon-Cancer Chronic

Air ConcentrationNon-Cancer Chronic

Air Concentration Source

11H-Benz[b,c]aceanthr

ylene

202-94-8 1.00E-01 HRV

4H-Cyclopenta[d,e,f]c

hrysene

202-98-2 1.80E-02 MDH

Acetaldehyde 75-07-0 470 CAL EPA 5.00E+00 HRV 9 IRIS

Acetamide 60-35-5 5.00E-01 CAL EPA

Acetone Cyanohydrin   

75-86-5    2 PPRTV

Acetonitrile 75-05-8 60 HRV

Acrolein 107-02-8 5 HBV 0.4 HBV

Acrylamide 79-06-1 1.00E-01 IRIS 6 IRIS

Acrylic acid 79-10-7 6000 CAL EPA 1 IRIS

Acrylonitrile 107-13-1 1.00E-01 HRV 2 IRIS

Adiponitrile    111-69-3    6 PPRTV

Aldehydes 00-07-9 94 HRV 2.00E+00 MDH 0.08 CAL EPA

Aldrin 309-00-2 2.00E-03 IRIS

Aliphatic Hydrocarbon

Streams (Midrange)

VARIOUS 100 PPRTV

Allyl chloride 107-05-1 1.70E+00 CAL EPA 1 IRIS

Aluminum    7429-90-5     5 PPRTV

Aminoanthraquinone, 2-

117-79-3 1.10E+00 CAL EPA

Ammonia 7664-41-7 3200 HRV 80 HRV

Amyl Alcohol, tert-

75-85-4

Page 2: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Aniline 62-53-3 6.30E+00 CAL EPA 1 IRIS

Anthanthrene 191-26-4 1.40E-02 MDH

Antimony 7440-36-0 0.2 HRV

Antimony Compounds

0-00-1 0.2 HRV

Antimony trioxide 1309-64-4 0.2 HRV

Aramite 140-57-8 1.40E+00 IRIS

Arsenic 7440-38-2 0.2 CAL EPA 2.00E-03 HRV 0.015 CAL EPA

Arsenic Compounds

0-00-2 0.2 CAL EPA 2.00E-03 HRV 0.015 CAL EPA

Arsenic Trioxide 1327-53-3 0.2 CAL EPA 2.00E-03 HRV 0.015 CAL EPA

Arsine 7784-42-1 200 HRV 0.05 IRIS

Azodicarbonamide 123-77-3 0.007 PPRTV

Benz[e]aceanthrylene

199-54-2 7.10E-03 MDH

Benz[j]aceanthryIene

202-33-5 9.10E-05 MDH

Benz[l]aceanthryIene

211-91-6 1.10E-03 MDH

Benzene 71-43-2 1000 HRV 1.30E+00 HRV 30 IRIS

Benzidine 92-87-5 2.00E-04 HRV

Benzo(j)fluoranthene

205-82-3 1.90E-02 MDH

Benzo(k)fluoranthene

207-08-9 1.90E-01 MDH

Benzo[a]anthracene

56-55-3 2.80E-02 MDH

Benzo[a]pyrene 50-32-8 5.60E-03 MDH

Benzo[b]fluoranthene

205-99-2 7.10E-03 MDH

Page 3: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Benzo[c]fluorene 205-12-9 2.80E-04 MDH

Benzo[g,h,i]perylene

191-24-2 6.30E-01 MDH

Benzyl chloride 100-44-7 240 CAL EPA 2.00E-01 CAL EPA 1 PPRTV

Beryllium 7440-41-7 4.00E-03 HRV 0.02 IRIS

Beryllium Compounds

0-00-3 4.00E-03 HRV 0.02 IRIS

Biphenyl, 1,1- 92-52-4

Bis(2-ethylhexyl)phthala

te (DEHP)

117-81-7 4.20E+00 CAL EPA

Bis(chloromethyl)ether

542-88-1 2.00E-04 HRV

Boron Trichloride 10294-34-5 20 PPRTV

Bromobenzene 108-86-1 60 IRIS

Bromochloromethane

74-97-5

Bromoform 75-25-2 9.10E+00 IRIS

Bromomethane 74-83-9 5 HRV

Bromopropane, 1- 106-94-5 50000 HBV 20 HBV

Butadiene, 1,3- 106-99-0 660 CAL EPA 2.00E-01 HBV 2 IRIS

Butyl alcohol, sec-   

78-92-2     30000 PPRTV

Butyl Cellosolve (ethylene glycol

monobutyl ether)

111-76-2 14000 CAL EPA 13000 HRV

Cadmium 7440-43-9 6.00E-03 HRV 0.02 CAL EPA

Cadmium Compounds

0-00-4 6.00E-03 HRV 0.02 CAL EPA

Caprolactum 105-60-2 50 CAL EPA 2.2 CAL EPA

Page 4: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Carbon disulfide 75-15-0 6000 HRV 700 HRV

Carbon Monoxide 630-08-0 23000 CAL EPA

Carbon tetrachloride

56-23-5 1900 CAL EPA 1.70E+00 IRIS 100 IRIS

Carbonyl sulfide 463-58-1 100 PPRTV

Cellosolve Acetate (ethylene glycol monoethyl

ether acetate)

111-15-9 100 HRV 300 CAL EPA

Cerium Oxide and Cerium

Compounds

1306-38-3 0.9 IRIS

Chlordane or (57-74-9)

12789-03-6 1.00E-01 IRIS 0.7 IRIS

Chlorinated Paraffins (C12, 60% Chlorine)

108171-26-2 4.00E-01 CAL EPA

Chlorine 7782-50-5 290 HRV 0.2 CAL EPA

Chlorine Oxide (CLO2)

10049-04-4 0.2 IRIS

Chloro-1,1-difluoroethane, 1-

(HCFC-142b)

75-68-3 50000 IRIS

Chloroacetophenone, 2-

532-27-4 0.03 HRV

Chlorobenzene 108-90-7 1000 CAL EPA

Chlorobenzotrifluoride, 4-   

98-56-6    300 PPRTV

Chlorodifluoromethane (HCFC-22)

75-45-6 50000 IRIS

Chloroform 67-66-3 150 HRV 4.30E-01 IRIS 300 CAL EPA

Page 5: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Chloronitrobenzene, o-   

88-73-3

Chloronitrobenzene, p-   

100-00-5    0.6 PPRTV

Chloro-o-phenylenediamine

, 4-

95-83-0 2.20E+00 CAL EPA

Chloro-o-toluidine, p-

95-69-2 1.30E-01 CAL EPA

Chloropicrin 76-06-2 29 CAL EPA 0.4 CAL EPA

Chloroprene 126-99-8 3.30E-02 IRIS 20 IRIS

Chromic acid mists and

dissolved Cr(VI) aerosols

18540-29-9 8.00E-04 HRV 0.008 IRIS

Chromium 7440-47-3 8.00E-04 HRV 0.008 IRIS

Chromium (Hexavalent) (particulate)

18540-29-9 8.00E-04 HRV 0.1 IRIS

Chromium Compounds

0-00-5 8.00E-04 HRV 0.008 IRIS

Chrysene (Benzo(a)phenant

hrene)

218-01-9 5.60E-02 MDH

Coal Tar 8007-45-2 2.00E-02 HRV

Cobalt 7440-48-4 1.10E-03 PPRTV 0.006 PPRTV

Coke Oven Emissions

0-00-7 2.00E-02 HRV

Copper 7440-50-8 100 CAL EPA

Copper Compounds

00-03-1 100 CAL EPA

Cresidine, p- 120-71-8 2.30E-01 CAL EPA

Page 6: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Cresol, m- 108-39-4 600 CAL EPA

Cresol, o- 95-48-7 600 CAL EPA

Cresol, p- 106-44-5 600 CAL EPA

Cresols/Cresylic acid (isomers and

mixture)

1319-77-3 600 CAL EPA

Cumene 98-82-8 400 IRIS

Cupferron 135-20-6 1.60E-01 CAL EPA

Cyanide (Cyanide ion, Inorganic

cyanides, Isocyanide)

57-12-5 700 HRV 3 HRV

Cyanide Compounds

0-00-8 700 HRV 3 HRV

Cyclohexane 110-82-7 6000 IRIS

Cyclohexanone 109-94-1 700 PPRTV

Cyclopenta[c,d]pyrene

27208-37-3 1.40E-02 MDH

DDT 50-29-3 1.00E-01 IRIS

Diaminoanisole, 2,4-

615-05-4 1.50E+00 CAL EPA

Diazene, Diphenyl 103-33-3 3.20E-01 IRIS

Dibenz(a,h)acridine

226-36-8 5.60E-02 MDH

Dibenz(a,j)acridine 224-42-0 5.60E-02 MDH

Dibenz[a,h]anthracene

53-70-3 5.60E-04 MDH

Dibenzo(a,e)pyrene

192-65-4 1.40E-02 MDH

Dibenzo(a,h)pyrene

189-64-0 6.20E-03 MDH

Page 7: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Dibenzo(a,l)pyrene

191-30-0 1.90E-04 MDH

Dibenzo(c,g)carbazole, 7H-

194-59-2 5.60E-03 MDH

Dibenzo[a,e]fluoranthene

5385-75-1 6.20E-03 MDH

Dibenzo[a,i]pyrene

189-55-9 9.10E-03 MDH

Dibromo-3-chloropropane,

1,2-

96-12-8 5.00E-03 CAL EPA 0.2 IRIS

Dichloro-2-butene, 1,4-

764-41-0 2.40E-03 PPRTV

Dichloro-2-butene, cis-1,4-

1476-11-5 2.40E-03 PPRTV

Dichlorobenzene(p), 1,4-

106-46-7 9.10E-01 CAL EPA 800 IRIS

Dichlorobenzenes 25321-22-6 9.10E-01 CAL EPA 800 IRIS

Dichlorobenzidene, 3,3-

91-94-1 2.90E-02 CAL EPA

Dichlorodifluoromethane (CFC-12)

75-71-8

Dichloroethyl ether (Bis(2-

chloroethyl)ethe

111-44-4 3.00E-02 IRIS

Dichloroethylene (1,1-) (Vinylidene

chloride)

75-35-4 200 IRIS

Dichloroethylene, trans-1,2-

156-60-5   60 PPRTV

Dichloropropene, 1,3-

542-75-6 2.50E+00 IRIS 20 HRV

Page 8: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Dichlorvos 62-73-7 0.5 HRV

Dicyclopentadiene 77-73-6

Dieldrin 60-57-1 2.20E-03 IRIS

Diesel exhaust particulate

0-02-4 5 HRV

Diethanolamine 111-42-2 3 CAL EPA

Diethylene Glycol Monobutyl Ether

112-34-5 0.1 PPRTV

Diethylene Glycol Monoethyl Ether   

111-90-0    0.3 PPRTV

Difluoroethane, 1,1-

75-37-6 40000 IRIS

Diisopropyl Ether   

108-20-3    700 PPRTV

Dimethyl aminoazobenzene

60-11-7 7.70E-03 CAL EPA

Dimethyl formamide

68-12-2 30 HRV

Dimethylamino ethanol, 2-

108-01-0

Dimethylbenz[a]anthracene, 7,12-

57-97-6

Dimethylhydrazine, 1,1-

57-14-7

Dinitropyrene, 1,6- (BaP)

42397-64-8 5.60E-04 MDH

Dinitropyrene, 1,8- (BaP)

42397-65-9 5.60E-03 MDH

Dinitrotoluene, 2,4-

121-14-2 1.10E-01 CAL EPA

Page 9: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Dioxane, 1,4- (1,4-Diethylene

dioxide)

123-91-1 3000 HRV 2.00E+00 IRIS 30 IRIS

Diphenylhydrazine, 1,2-

122-66-7 4.50E-02 IRIS

Epichlorohydrin (l-Chloro-2,3-

epoxypropane)

106-89-8 1300 CAL EPA 8.00E+00 HRV 1 IRIS

Epoxybutane, 1,2- 106-88-7 20 HRV

Ethoxyethanol, 2- (ethylene glycol

monoethyl ether)

110-80-5 400 HRV 200 IRIS

Ethyl acetate 141-78-6 70 PPRTV

Ethyl Acrylate 140-88-5 8 PPRTV

Ethyl benzene 100-41-4 10000 HRV 4.00E+00 CAL EPA 1000 IRIS

Ethyl carbamate (Urethane)

51-79-6 3.40E-02 CAL EPA

Ethyl chloride (Chloroethane)

75-00-3 100000 HRV 10000 IRIS

Ethyl Methacrylate   

97-63-2    300 PPRTV

Ethylene dibromide

(Dibromoethane)

106-93-4 5.00E-02 HRV 9 IRIS

Ethylene dichloride (1,2-Dichloroethane)

107-06-2 3.80E-01 IRIS 400 CAL EPA

Ethylene glycol 107-21-1 400 CAL EPA

Ethylene oxide 75-21-8 3.30E-03 IRIS 30 CAL EPA

Ethylene thiourea 96-45-7 7.70E-01 CAL EPA

Page 10: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Ethylidene dichloride (1,1-Dichloroethane)

75-34-3 6.30E+00 CAL EPA

Fluoranthene 206-44-0 7.10E-02 MDH

Fluorides (except hydrogen fluoride)

1101 13 CAL EPA

Formaldehyde 50-00-0 94 HRV 2.00E+00 MDH 9 CAL EPA

Formic Acid    64-18-6   

Glutaraldehyde 111-30-8 0.08 CAL EPA

Glycol ethers 0-01-2 90 HRV 20 IRIS

Heptachlor 76-44-8 7.70E-03 IRIS

Heptachlor epoxide

1024-57-3 3.80E-03 IRIS

Heptachlorodibenzodioxin, All

Isomers

00-08-5 2.50E-06 MPCA 0.004 MPCA

Heptachlorodibenzofuran,

1,2,3,4,6,7,8-

67562-39-4 2.50E-06 MPCA 0.004 MPCA

Heptachlorodibenzofuran,

1,2,3,4,7,8,9-

55673-89-7 2.50E-06 MPCA 0.004 MPCA

Heptachlorodibenzofuran, All

Isomers

00-08-4 2.50E-06 MPCA 0.004 MPCA

Heptachlorodibenzo-p-dioxin, 1,2,3,4,6,7,8-

35822-46-9 2.50E-06 MPCA 0.004 MPCA

Hexachlorobenzene

118-74-1 2.20E-02 IRIS

Hexachlorobutadiene

87-68-3 4.50E-01 IRIS

Page 11: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Hexachlorocyclohexane (technical

grade)

608-73-1 2.00E-02 IRIS

Hexachlorocyclohexane, alpha-

319-84-6 5.60E-03 IRIS

Hexachlorocyclohexane, beta-1,2,3,4,5,6-

319-85-7 1.90E-02 IRIS

Hexachlorocyclopentadiene

77-47-4 0.2 IRIS

Hexachlorodibenzodioxins, All

Isomers

00-08-3 2.50E-07 MPCA 0.0004 MPCA

Hexachlorodibenzofuran,

1,2,3,4,7,8-

70648-26-9 2.50E-07 MPCA 0.0004 MPCA

Hexachlorodibenzofuran,

1,2,3,6,7,8-

57117-44-9 2.50E-07 MPCA 0.0004 MPCA

Hexachlorodibenzofuran,

1,2,3,7,8,9-

72918-21-9 2.50E-07 MPCA 0.0004 MPCA

Hexachlorodibenzofuran,

2,3,4,6,7,8-

60851-34-5 2.50E-07 MPCA 0.0004 MPCA

Hexachlorodibenzofurans, All

Isomers

00-08-2 2.50E-07 MPCA 7171 MPCA

Hexachlorodibenzo-p-dioxin, 1,2,3,4,7,8-

39227-28-6 2.50E-07 MPCA 0.0004 MPCA

Hexachlorodibenzo-p-dioxin, 1,2,3,6,7,8-

57653-85-7 7.70E-06 IRIS 0.0004 MPCA

Page 12: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Hexachlorodibenzo-p-dioxin, 1,2,3,7,8,9-

19408-74-3 7.70E-06 IRIS 0.0004 MPCA

Hexachloroethane 67-72-1 2.50E+00 IRIS 30 IRIS

Hexamethylene-1,6-diisocyanate

822-06-0 0.01 HRV

Hexane 110-54-3 5.00E+01 PPRTV 2000 HRV

Hexanone-2 591-78-6 30 IRIS

Hydrazine 302-01-2 2.00E-03 HRV 0.2 CAL EPA

Hydrazine sulfate 10034-93-2 2.00E-03 HRV

Hydrochloric acid (hydrogen chloride)

7647-01-0 2700 HRV 20 HRV

Hydrogen cyanide 74-90-8 700 HRV 3 HRV

Hydrogen fluoride (Hydrofluoric acid)

7664-39-3 240 HRV 14 CAL EPA

Hydrogen selenide 7783-07-5 5 CAL EPA

Hydrogen sulfide 7783-06-4 42 CAL EPA 2 IRIS

Indeno(1,2,3-cd)pyrene

193-39-5 7.70E-02 MDH

Isophorone 78-59-1 2000 CAL EPA

Isopropyl alcohol 67-63-0 3200 CAL EPA 7000 CAL EPA

Lead 7439-92-1 8.30E-01 CAL EPA 0.15 NAAQS

Lead Chromate 7758-97-6 8.00E-04 HRV 0.008 IRIS

Lead Compounds 0-01-3 8.30E-01 CAL EPA 0.15 NAAQS

Lindane (all isomers)

58-89-9 3.20E-02 CAL EPA

m- and p-Xylenes 00-07-8 43000 HRV 100 IRIS

Maleic anhydride 108-31-6 0.7 CAL EPA

Page 13: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Manganese 7439-96-5 0.2 HRV

Manganese Compounds

0-01-4 0.2 HRV

Manganese Dioxide

1313-13-9 0.2 HRV

Mercury (elemental)

7439-97-6 0.6 CAL EPA 0.3 IRIS

Mercury Compounds

0-02-3 0.6 CAL EPA 0.3 IRIS

Methacrylonitrile 126-98-7 30 PPRTV

Methanol 67-56-1 25000 HRV 20000 IRIS

Methoxyethanol, 2- (ethylene

glycol monomethyl ether EGME)

109-86-4 90 HRV 20 IRIS

Methyl acrylate 96-33-3 20 PPRTV

Methyl bromide (Bromomethane)

74-83-9 2000 HRV 5 HRV

Methyl Cellosolve Acetate

110-49-6 90 CAL EPA

Methyl chloride (Chloromethane)

74-87-3 90 IRIS

Methyl chloroform (1,1,1-Trichloroethane)

71-55-6 140000 HRV 5000 IRIS

Methyl ethyl ketone (2-Butanone)

78-93-3 10000 HRV 5000 IRIS

Methyl Hydrazine 60-34-4 1.00E-02

Methyl isobutyl ketone (Hexone)

108-10-1 3000 IRIS

Page 14: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Methyl isocyanate 624-83-9 1 CAL EPA

Methyl methacrylate

80-62-6 700 HRV

Methyl tert butyl ether

1634-04-4 3.80E+01 CAL EPA 3000 IRIS

Methylcholanthrene, 3-

56-49-5 1.00E-03 MDH

Methylchrysene, 5-

3697-24-3 5.60E-03 MDH

Methylene bis(2-chloroaniline),

4,4-

101-14-4 2.30E-02 CAL EPA

Methylene Bromide

74-95-3

Methylene chloride

(Dichloromethane)

75-09-2 10000 HRV 2.00E+01 HRV 600 IRIS

Methylene diphenyl

diisocyanate (MDI)

101-68-8 0.6 HRV

Methylenedianiline, 4,4-

101-77-9 2.20E-02 CAL EPA 20 CAL EPA

Michler's ketone 90-94-8 4.00E-02 CAL EPA

N- Nitrosomethyleth

ylamine

10595-95-6 1.60E-03 CAL EPA

Naphtha, High Flash Aromatic

(HFAN)   

64724-95-6    100 PPRTV

Naphthalene 91-20-3 200 HBV 9.00E+00 MDH 9 HBV

Page 15: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Naphtho[2,3-e]pyrene

193-09-9 1.90E-02 MDH

Nickel 7440-02-0 11 HRV 2.00E-02 HRV 0.014 CAL EPA

Nickel Compounds 0-01-5 11 HRV 2.00E-02 HRV 0.014 CAL EPA

Nickel oxide 1313-99-1 11 HRV 3.80E-02 CAL EPA 0.02 CAL EPA

Nickel refinery dust from the

pyrometallurgical process

0-02-5 11 HRV 4.00E-02 IRIS 0.014 CAL EPA

Nickel sulfide (NI3S2)

12035-72-2 11 HRV 2.00E-02 HRV 0.014 CAL EPA

Nitric acid 7697-37-2 130 HRV

Nitroacenaphthene, 5-

602-87-9 2.80E-01 MDH

Nitroaniline, 2-    88-74-4

Nitroaniline, 4-    100-01-6    6 PPRTV

Nitrobenzene 98-95-3 2.50E-01 IRIS 9 IRIS

Nitrochrysene, 6- 7496-02-8 5.60E-04 MDH

Nitrofluorene, 2- 607-57-8 5.60E-01 MDH

Nitrogen dioxide (NO2)

10102-44-0 470 HBV

Nitromethane 75-52-5 1.10E+00 PPRTV 5 PPRTV

Nitropropane, 2- 79-46-9 20 HRV

Nitropyrene, 1- 5522-43-0 5.60E-02 MDH

Nitropyrene, 4- 57835-92-4 5.60E-02 MDH

Nitrosodiphenylamine, p-

156-10-5 1.60E+00 CAL EPA

N-Nitrosodiethylami

ne

55-18-5 2.30E-04 IRIS

Page 16: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

N-Nitrosodimethyla

mine

62-75-9 7.10E-04 IRIS

N-Nitrosodi-n-butylamine

924-16-3 6.20E-03 IRIS

N-Nitrosodi-n-propylamine

621-64-7 5.00E-03 CAL EPA

N-Nitrosodiphenyla

mine

86-30-6 3.80E+00 CAL EPA

N-Nitrosomorpholin

e

59-89-2 5.30E-03 CAL EPA

N-Nitrosopiperidine

100-75-4 3.70E-03 CAL EPA

N-Nonane 111-84-2 20 PPRTV

Octachlorodibenzofuran,

1,2,3,4,6,7,8,9-

39001-02-0 8.30E-05 MPCA 0.133 MPCA

Octachlorodibenzo-p-dioxin,

1,2,3,4,6,7,8,9-

3268-87-9 8.30E-05 MPCA 0.133 MPCA

Ozone 10028-15-6 180 CAL EPA

PCB 114 (2,3,4,4,5

Pentachlorobiphenyl)

74472-37-0 5.30E-04 Cal EPA 1.3 CAL EPA

PCB 118 (2,3,4,4,5

Pentachlorobiphenyl)

31508-00-6 2.60E-03 Cal EPA 1.3 CAL EPA

Page 17: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

PCB 123 (2,3,4,4,5

Pentachlorobiphenyl)

65510-44-3 2.60E-03 Cal EPA 1.3 CAL EPA

PCB 126 (3,3,4,4,5

Pentachlorobiphenyl)

57465-28-8 2.60E-06 Cal EPA 0.0004 CAL EPA

PCB 156 (2,3,3,4,4,5

Hexachlorobiphenyl)

38380-0804 5.30E-04 Cal EPA 1.3 CAL EPA

PCB 157 (2,3,3,4,4,5

Hexachlorobiphenyl)

69782-90-7 5.30E-04 Cal EPA 1.3 CAL EPA

PCB 167 (2,3,4,4,5,5

Hexachlorobiphenyl)

52663-72-6 2.60E-02 Cal EPA 1.3 CAL EPA

PCB 169 (3,3,4,4,5,5

Hexachlorobiphenyl)

32774-16-6 2.60E-05 Cal EPA 0.0013 CAL EPA

PCB 189 (2,3,3,4,4,5,5

Heptachlorobiphenyl)

39635-31-9 2.60E-03 Cal EPA 1.3 CAL EPA

PCB 77 (3,3,4,4-Tetrachlorobiphen

yl)

32598-13-3 2.60E-03 Cal EPA 0.4 CAL EPA

PCB 81 (3,4,4,5 Tetrachlorobiphen

yl)

70362-50-4 2.60E-03 Cal EPA 0.13 CAL EPA

Page 18: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

PCB105 (2,3,3,4,4 Pentachlorobiphe

nyl)

32598-14-4 2.60E-03 Cal EPA 1.3 CAL EPA

Pentachlorodibenzodioxins, All

Isomers

00-08-1 2.50E-08 MPCA 0.00004 MPCA

Pentachlorodibenzofuran, 1,2,3,7,8-

57117-41-6 8.30E-07 MPCA 0.00133 MPCA

Pentachlorodibenzofuran, 2,3,4,7,8-

57117-31-4 8.30E-08 MPCA 0.000133 MPCA

Pentachlorodibenzofurans, All

Isomers

00-09-0 8.30E-08 MPCA 0.000133 MPCA

Pentachlorodibenzo-p-dioxin, 1,2,3,7,8-

40321-76-4 2.50E-08 MPCA 0.00004 MPCA

Pentachlorophenol

87-86-5 2.00E+00 CAL EPA

Pentane, n-    109-66-0     1000 PPRTV

Petroleum Hydrocarbons, Aliphatic (C7 -

C11)

00-07-7 2.50E+00 PPRTV 5000 HBV

Phenanthrene 85-01-8

Phenol 108-95-2 5800 HRV 200 CAL EPA

Phosgene 75-44-5 4 HRV 0.3 IRIS

Phosphine 7803-51-2 0.3 IRIS

Phosphoric acid 7664-38-2 10 IRIS

Phthalic anhydride 85-44-9 20 CAL EPA

Page 19: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Polychlorinated biphenyls (Aroclors

unspeciated)

1336-36-3 1.00E-01 IRIS 0.0004 CAL EPA

Polychlorinated Dibenzodioxins,

Total

00-05-0 2.50E-08 MPCA 0.00004 CAL EPA

Polychlorinated Dibenzofurans,

Total

00-05-1 8.30E-08 MPCA 0.000133 MPCA

Polychlorinated Dibenzo-P-Dioxins And Furans, Total

00-08-0 2.50E-08 MPCA 0.00004 CAL EPA

Polycyclic Aromatic

Hydrocarbons (PAH)

130498-29-2 5.60E-03 MDH

Polycyclic Organic Matter (POM)

00-01-7 1.10E-01 MPCA/MDH

Polymeric diphenylmethane

diisocyanate

9016-87-9 0.6 HRV

Potassium bromate

7758-01-2 7.10E-02 CAL EPA

Propane sultone, 1,3-

1120-71-4 1.40E-02 CAL EPA

Propionaldehyde 123-38-6 8 IRIS

Propylene 115-07-1 3000 CAL EPA

Propylene dichloride (1,2-

Dichloropropane)

78-87-5 4 IRIS

Page 20: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Propylene Glycol Monomethyl

Ether

107-98-2 2000 IRIS

Propylene oxide 75-56-9 3100 CAL EPA 3.00E+00 HRV 30 IRIS

Pyrrolidine, 1-Nitroso-

930-55-2 1.60E-02 IRIS

Selenium 7782-49-2 20 CAL EPA

Selenium Compounds

0-01-9 20 CAL EPA

Silica (crystalline, respirable, PM4)

7631-86-9 3 HBV

Sodium hydroxide 1310-73-2 8 HRV

Strontium chromate

7789-06-2 8.00E-04 HRV 0.008 IRIS

Styrene 100-42-5 21000 HRV 1000 HRV

Sulfates 14808-79-8 120 CAL EPA

Sulfolane 126-33-0

Sulfur dioxide 7446-09-5 660 CAL EPA

Sulfuric acid (aerosol forms

only)

7664-93-9 120 CAL EPA 1 CAL EPA

Sulfuric Acid mixture w. sulfur trioxide (oleum)

8014-95-7 120 CAL EPA

TCDD Eqivalents, 2,3,7,8-

00-09-1 2.50E-08 MPCA 0.00004 CAL EPA

Tetrachlorodibenzodioxins, All

Isomers

00-08-8 2.50E-08 MPCA 0.00004 CAL EPA

Tetrachlorodibenzofuran, 2,3,7,8-

51207-31-9 2.50E-07 MPCA 0.0004 MPCA

Page 21: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Tetrachlorodibenzofurans, All

Isomers

00-08-6 2.50E-07 MPCA 0.0004 MPCA

Tetrachlorodibenzo-p-dioxin,

2,3,7,8-

1746-01-6 2.50E-08 MPCA 0.00004 CAL EPA

Tetrachloroethane, 1,1,1,2-

630-20-6 1.40E+00 IRIS

Tetrachloroethane, 1,1,2,2-

79-34-5 1.70E-01 IRIS

Tetrachloroethylene

(Perchloroethylene)

127-18-4 20000 HRV 2.00E+00 MDH 15 MDH

Tetrafluoroethane, 1,1,1,2-

811-97-2 80000 IRIS

Tetrahydrofuran 109-99-9 2000 IRIS

Thioacetamide 62-55-5 5.90E-03 CAL EPA

Toluene 108-88-3 37000 HRV 400 HRV

Toluene diamine, 2,4-

95-80-7 9.10E-03 CAL EPA

Toluene diisocyanate, 2,4-

584-84-9 9.10E-01 CAL EPA 0.07 CAL EPA

Toluene-2,6-diisocyanate

91-08-7 9.10E-01 CAL EPA 0.07 CAL EPA

Toluenediisocyanate (mixed isomers)

26471-62-5 9.10E-01 CAL EPA 0.08 HRV

Toxaphene (chlorinated camphene)

8001-35-2 3.10E-02 IRIS

Trichlorobenzene, 1,2,4-

120-82-1 2 PPRTV

Page 22: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Trichloroethane, 1,1,2-

79-00-5 6.30E-01 IRIS

Trichloroethylene 79-01-6 6 MDH RAA 2.00E+00 MDH 2 MDH

Trichlorofluoromethane (CFC-11)

75-69-4

Trichlorophenol, 2,4,6-

88-06-2 3.20E+00 IRIS

Trichloropropane, 1,2,3-

96-18-4 0.3 IRIS

Trichloropropene, 1,2,3-   

96-19-5    0.3 PPRTV

Triethylamine 121-44-8 2800 HRV 7 IRIS

Trimethylbenzene, 1,2,3-   

526-73-8     60 IRIS

Trimethylbenzene, 1,2,4-   

95-63-6     60 IRIS

Vanadium Pentoxide, (V2O5)

1314-62-1 30 HRV 1.20E-03 PPRTV 0.007 PPRTV

Vinyl acetate 108-05-4 200 HRV

Vinyl bromide 593-60-2 3 IRIS

Vinyl chloride 75-01-4 180000 CAL EPA 1.00E+00 HRV 100 IRIS

Xylenes 1330-20-7 43000 HRV 100 IRIS

Xylenes, m- 108-38-3 43000 HRV 100 IRIS

Xylenes, o- 95-47-6 43000 HRV 100 IRIS

Xylenes, p- 106-42-3 43000 HRV 100 IRIS

Zinc chromate 13530-65-9 8.00E-04 HRV 0.008 IRIS

Page 23: Toxicity Values (ug/m3) Used by MPCA for Air Toxics Comparisons

Chemical Name CAS Acute Air Concentration

Acute Air Concentration Source

Cancer based Air Conc

Cancer-based Air Concentration Source

Non-Cancer Chronic Air Concentration

Non-Cancer Chronic Air Concentration

Source

Toxicity Value Acronyms and Sources

Toxicity Value Descriptions

1The toxicity values reported above are defined as the concentration of a chemical (or mixture of chemicals) that is likely to pose little or no risk to human health.

2Acute toxicity values are compared to 2nd high 24 hour air concentrations multiplied by 10 (to estimate hourly maximum)

3Chronic toxicity values are compared to 95% upper confidence limit of the arithmetic mean (to be 95% confident that the mean is not underestimated)

410% of total chromium is assumed to be hexavalent chromium (the carcinogenic form of chromium)

Acronym Toxicity Source Full Name URL link to Toxicity Source

1HRV MDH Health Risk Value http://www.health.state.mn.us/divs/eh/risk/guidance/air/table.html

2HBV MDH Health Based Value http://www.health.state.mn.us/divs/eh/risk/guidance/air/table.html

3Cal EPA California Environmental Protection Agency Office of Environmental Health Hazardhttp://oehha.ca.gov/air/hot_spots/

4 IRIS USEPA Integrated Risk Information System http://www.epa.gov/IRIS/

5PPRTV EPA Provisional Peer Reviewed Toxicity Values for Superfund http://hhpprtv.ornl.gov/