topic 8: acids and bases
DESCRIPTION
Topic 8: Acids and Bases. Theories of acids and bases Properties of acids and bases Strong and weak acids and bases The pH-scale. 8.1 Brönsted -Lowry Acid - base Theory. The protolytic reaction : Reaction of an acid with water : H Cl (g) + H 2 O H 3 O + + Cl - - PowerPoint PPT PresentationTRANSCRIPT
Topic 8: Acids and Bases• Theories of acids and bases• Properties of acids and bases• Strong and weak acids and bases• The pH-scale
• The protolytic reaction:Reaction of an acid with water:HCl (g) + H2O H3O+ + Cl-
Reaction of a base with water:NH3 (g) + H2O ↔ OH- + NH4
+
8.1 Brönsted-Lowry Acid - base Theory
Oxonium ion
Hydroxide ion
Draw the reaction formulas when these substances react with water as acids:HNO3
H2SO4
CH3COOH
Draw the reaction formulas when thise substances react with water as bases:CH3NH2
CO32-
Nitric acidHNO3+ H2O H3O+ + NO3
-
Sulphuric acidH2SO4 + H2O H3O+ + HSO4
–
HSO4 –
+ H2O H3O+ + SO42-
Etanoic acidCH3COOH + H2O ↔ H3O+ + CH3COO-
MethylamineCH3NH2 + H2O ↔ OH- + NH4
+
Carbonate ionCO3
2- + H2O ↔ OH- + HCO3
-
Brönsted-Lowry Acid - base Theory
• Acid: proton donor• Base: proton acceptor
Conjugate acid-base pair
CH3COOH + H2O CH3COO- + H3O+
Acid1 Base2 Base1 Acid2
State for each reaction which reactant is acid and which is base
a) HSO4- + H2O ↔ SO4
2- + H3O+
b) NH3 + H2O ↔ NH4+ + OH-
c) HCO3- + H2O ↔ CO3
2- + H3O+
d) HCO3- + H2O ↔ H2CO3 + OH-
e) H3O+ + OH- ↔ 2 H2O
State for each reaction which reactant is acid and which is base
a) HSO4- + H2O ↔ SO4
2- + H3O+
acid baseb) NH3 + H2O ↔ NH4
+ + OH-
base acid c) HCO3
- + H2O ↔ CO32- + H3O+
acid based) HCO3
- + H2O ↔ H2CO3 + OH-
base acide) H3O+ + OH- ↔ 2 H2O base acid
Which of these are conjugated acid/base-pairs?
a) HSO4-/SO4
2- b) H2SO4
-/SO42-
c) NH3 /NH4+
d) HCO3-/CO3
2- e) CO3
2-/H2CO3
f) H3O+/OH-
Which of these are conjugated acid/base-pairs?
a) HSO4-/SO4
2- c) NH3 /NH4
+ d) HCO3
-/CO32-
What is the rule?
The carboxyl group
Amphiprotic• Water can act both as an acid and as a base;
H3O+ H2O OH-
• Such compounds are said to be amphiprotic (ampholytic).
Monoprotic Polyprotic
• Monoprotic: CH3COOH CH3COO-
Acetic acid
• Diprotic: HOOC-COOH -OOC-COO-
Oxalic acid
• Triprotic: H3PO4 PO43-
Phosphoric acid
• Polyprotic
Arrhenius Acid-Base Theory
• Acid: H+ Hydrogen ion / Proton– Acidic solutions contain H+ / H3O+
(oxonium, hydroxonium or hydronium ion)
• Base: OH- Hydroxide ion– Alkaline solutions contain OH-
Alkaline = Water soluble base
Lewis Acid-Base Theory
• Lewis acid: electron pair acceptor, – e.g. H+, AlCl3, BF3
• Lewis base: electron pair donor, – e.g. OH-, NH3
• A Lewis acid-base reaction involves the formation of a covalent bond. The Lewis base provides the electrons in that bond. This kind of covalent bond is called dative covalent bonds (see topic 13) or co-ordinate covalent bond.
• Its no difference between a normal covalent bond and a dative covalent bond except the origin of the electrons. Sometimes an arrow is used instead of a line to show that it's a dative bond e.g. H3NBF3.
• The term Lewis acid is often just used for acids that aren’t Brönstedt acids
• The formation of complex ions, topic 13, is usually Lewis acid-base reactions
8.2 Properties of acids in solution
• They have pH<7• They taste sour• They react with bases and metals• Where can you find:
Hydrochloric acidSulphuric acidAcetic acidCarbonic acid
Properties of bases in solution
• They have pH>7• They feel ”slippery”• They react with acids• Where can you find:
AmmoniaSodium bicarbonateCalcium carbonate
8.3 Strong acidsTotally dissociated
Hydrochloric acid: HCl + H2O Cl- + H3O+
chloride
Nitric acid: HNO3+ H2O NO3- + H3O+
nitrate
Sulphuric acid: H2SO4 + H2O HSO4-+ H3O+
hydrogensulphate
HSO4- + H2O SO4
2-+ H3O+
sulphate
HCl + H2O H3O+ +Cl-
Start 100% 0% End 0% 100%
Weak acidsPartially dissociated
• Ethanoic acid, (Acetic acid)CH3COOH + H2O CH3COO- + H3O+
ethanoate ion(acetate ion)
• Carbonic acid, H2CO3 +H2O HCO3
- + H3O+
hydrogen carbonate ion
HCO3- +H2O CO3
2- + H3O+
carbonate ion
CH3CH2COOH + H2O H3O+ + CH3CH2COO-
start 100% 0%end 99% 1%
If the concentration is the same for the strong and the weak acid:
– The strong acid is more acidic than the weak acid– The strong acid has a higher concentration of
hydroxonium ions than the weak acid– The strong acid has higher conductivity
http://phet.colorado.edu/en/simulation/acid-base-solutions
Strong basesContaining the OH- ion
• All group I hydroxides: NaOH(s) + H2O Na+ + OH-
• Group II hydroxides Ba(OH)2 + H2O Ba2+ + 2 OH-
Weak basesPartially dissociated
• Ammonia NH3 + H2O NH4
+ + OH-
• Ethylamine CH3CH2-NH2 + H2O CH3CH2-NH3
+ + OH-
The anions from carbonic acid; CO3
2- and HCO3-
• Alkaline properties• Often water soluble salts
• H2CO3 + H2O HCO3- + H3O+
Conjugated acid and base pair
Acid Base Base Acid
• HCO3- + H2O CO3
2- + H3O+Conjugated acid and base pair
Acid Base Base Acid
IndicatorsAcidic Neutral Basic
Litmus red blue
BTB (red) yellow green Blue
Phenolphthalein colourless colourless cerise
Universal paper (red) (green) (blue)
Some typical reactions of acids- salt formations
• Neutralisation• Reactions with metals or metal oxides
Neutralisation- exothermic, no equilibrium
Acid + base salt + waterHCl + NaOH NaCl + H2OH2SO4 + KOH HNO3 + Ba(OH)2
Neutralisation
H2SO4 + 2 KOH K2SO4 + 2 H2O 2 HNO3 + Ba(OH)2 Ba(NO3)2 + 2 H2O
http://chem-ilp.net/labTechniques/AcidBaseIdicatorSimulation.htm
With basic metal oxides
Acid + metal oxide salt + water
CuO + 2 HCl CuCl2 + H2O
To synthesise a salt from a noble metal you can’t start with metal + acid (Why?)
Carbonates and hydrogen carbonates
Carbonates+ acids salt+ carbon dioxide+ waterNa2CO3 + 2 HCl 2 NaCl + CO2 + H2O
CaCO3 + HCl KHCO3 + H2SO4
Carbonates and hydrogen carbonates
CaCO3 + 2 HCl 2 CaCl2 + CO2 + H2O
2 KHCO3 + H2SO4 2 K2SO4 + 2 CO2 + 2 H2O
With metals
Acid + metal salt + hydrogen gas
Mg + 2 HCl MgCl2 + H2
Al + H2SO4 ? ? Na + H3PO4 ? ?
More noble metals (Cu, Ag, Au) doesn’t react with HCl or H2SO4 . They demand more oxidative acids (HNO3) and will then give other gases than H2 (N2O)
Acid + metal salt + hydrogen gas2 Al + 3 H2SO4 Al2(SO4)3 + 3 H2
6 Na + 2 H3PO4 2 Na3PO4 + 3 H2
8.4 The pH-scale
pH = -log[H3O+]
• pH = -log[H3O+] => change in one pH unit = 10 times difference in [H3O+]
• pH=5 pH= 3 => 100 times more acidic.• pH=8 pH= 11 => 1000 times more basic.
• pH-meter, pH-paper• [H3O+] = 10-pH
http://phet.colorado.edu/en/simulation/ph-scale