Title Cover & Contents

Author(s)

Citation Bulletin of the Institute for Chemical Research, KyotoUniversity (1982), 59(5-6)

Issue Date 1982-03-15

URL http://hdl.handle.net/2433/76964

Right

Type Others

Textversion publisher

Kyoto University

ISSN 0023-6071

BULLETIN OF THE INSTITUTE

FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

Vol. 59, No 5,-%,6

Published bi-monthly by

THE INSTITUTE FOR CHEMICAL RESEARCH KYOTO UNIVERSITY

KYOTO, JAPAN

November, 1981

(Bull. Inst. Chem. Res., Kyoto Univ.)

INSTITUTE FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

Director

Toshio TAKADA

Members of Council

Yoshichika Baz・rno E�hi FuJiTa Hiroshi IrraGaxi

Yuzo INouYE Ken-ichi KATAYAMA Ryozo KITAMuRu

Naokazu KoizuMr Michio KURATA Shinzaburo OxA

Malaya OKANO Tatsuo Ooi Kenji Song

TOSI710 TAKADA MIt$LII'LI TAKANAMI HICIekU111 TAKEKOSHI

Tohru TAKENAKA Natsu UYEDA Takuji Yarrasu

Publication Committee

E�hi FuJiTa Ken-ichi KaTaYanza Tadashi KOKUBO

Seishi MATsuKI Tatsuo Ool Nobuyuki SuGITA

Business Staf£

TetSUO FUJIMOTO Sel l IJIRI 51101CI71 MATSUMURA

I$istory of Publications

Term Vol. Title Published

Jan.,1929Dec.,1947-1-16羅 欝 一 ・・・…-m ・・-m・-ly

…il・1933- 10Jahre lnstitutf� chemische Fo「schung -

March,1949

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March 1950_ 化学研穽所報告 . .・・pt.・'195220-30(Bulletin of the lnstitute fo

search) 「Chemical Re- Qua「te「1y

The Commemoration Volume for the SilverDec., 1951 - Jubilce -

(化学研究 所創立二十五周年記念号)

Jan.,onwa,d、195331No. i一 纏 轟 誹繍t三t"tefo「Chem'ca1 Resea「ch Bi-m・n・hly

Special lssue on the Commemoration of theNov.,1966 No6 FortiethAnniversary ‐

Nov.・19・654N o.6韓 灘 黙 隷 野tめ 漁 一

CONTENTS

Katsuyuki Tanizawa, Tatsuo Yamamoto, and Kenji Soda: Properties of In- ducible Kynureninase of Neuropora crassa .............................................311

Nobuyuki Esaki, Hidehiko Tanaka, Tatsuo Yamamoto, and Kenji Soda: Further Characterization of L-Methionine 1-Lyase and Enzymatic Syn- thesis of Sulfur Amino Acids ............................................................321

Shigeo Tanimoto, Tatsuo Oida, Kouhei Hatanaka, and Masaya Okano: The Reaction of 2, 2'-[1, 2-Ethanediylbis(thio)]bis-1, 3-dithiolane with

Carbonyl Compounds .....................................................................332

Tsutomu Tagano, Yasuo Wada, Shigeo Tanimoto, and Masaya Okano: The Reaction of Cyclic Olefins with Chloromethyl Methyl Sulfide in Ace-

tonitrile .......................................................................................337

Takekazu Ishida and Hiromasa Mazaki: Partial Destruction of the Meissner State in Multiconnected Josephson Network .........................................343

Notes

Sakae Uemura, Akio Toshimitsu, Yoshihisa Kozawa, and Masaya Okano: Preparation and Characterization of Several New Palladium (II) Chloride

Complexes of Alkyl and Aryl Selenocyanates .......................................350

Sakae Uemura, Akio Toshimitsu, Yoshihisa Kozawa, and Masaya Okano: Selenodemercuration of Phenyl- and p-Tolymercury (II) Compounds ........ 354

Reviews

Eiichi Takenouchi, Donka K. Nikolova, Hidehiko Tanaka, Tatsuo Yamamoto, and Kenji Soda: Lysine Biosynthesis in Yeasts ....................................357

Eiichi Fujita, Yoshimitsu Nagao, Manabu Node, and Masahito Ochiai: The Chemistry of Diterpenoids in 1979. Part—II .......................................381

The Papers Published by the Staff Members of the Institute from July 1980 to June 1981 .................................................................................399

ISSN 0023-6071

BULLETIN OF THE INSTITUTE

FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

Vol. 59

Published bi-monthly by

THE INSTITUTE FOR CHEMICAL RESEARCH KYOTO UNIVERSITY

KYOTO, JAPAN

1981

(Bull. Inst. Chem. Res., Kyoto Univ.)

Contents of Volume 59, 1981

Hidekuni Takekoshi, Seishi Matsuki, Katsuo Mashiko, and Naomoto Shika- zono: Rf Structure of Superconducting Cyclotron for Therapy Ap-

plication .......................................................................................1 Shigeru Kakigi, Kiyoji Fukunaga, Takao Ohsawa, Seiji Tanaka, Akira

Okihana, Hitoshi Nakamura-Yokota, Tuguhisa Sekioka, and Noboru Fujiwara: Excited States of 4He Investigated via the 4He (a, ap) 3H

Reaction at 119 MeV .....................................................................9 Takeshi Mukoyama: A Computer Code to Calculate the Parameters Used for

Radiation Shielding against r Rays ...................................................15 Toshiro Takabatake, Hiromasa Mazaki, and Teruya Shinjo: High Field

Mossbauer Study of Dilute Ir-(Fe) Alloys ..........................................20 Shunji Kakiuchi and Takeshi Mukoyama: Effect of Chemical State on the

Decay Rate of 51Cr ........................................................................27 Shunji Kakiuchi and Hiromasa Mazaki: Estimation of Superconducting

Effect on the Decay Rate of 99mTc ......................................................36 Seishi Matsuki, Hidekuni Takekoshi, Yoshinaga Nakayama, and Yukinobu

Saito: A 31 cm Model Superconducting Cyclotron Magnet, I .................40 Tatsumi Mizogawa, Yasuyuki Nakayama, and Tatsumi Tawaratani: Angular

Distribution of Slow Positrons from MgO Moderator .............................49 Yoshio Oka, Yasuo Kita, Tetsuya Hanai, and Naokazu Koizumi: Dielectric

Properties of Gelatin-Water System in a Megahertz Region .....................56 Naoki Sugimoto, Muneo Sasaki, and Jiro Osugi: Influence of Pressure on

Primary Kinetic Isotope Effects of the Proton-Transfer Reaction between 4-Nitrophenyl-nitromethane and 1, 1', 3, 3 '-Tetramethylguanidine in

Toluene and Dichloromethane .........................................................63 Masaaki Katao, Kiyoshi Kudo, and Nobuyuki Sugita: Kinetic Study on

Palladium Dichloride-catalyzed Carbomethoxylation of Styrene under Compressed Carbon Monoxide in a Redox System.................................72

Heng Phala, Kiyoshi Kudo, and Nobuyuki Sugita: Kinetic Studies on the Carbonylation of Amine Using Compressed Carbon Dioxide and

Hydrogen ....................................................................................88 Masahiko Kurakado, Shinji Tachi, Rintaro Katano, and Hiromasa Mazaki:

Laser-Induced Signals from Superconducting Tunnel Junction..................106 Sadayuki Mori: Absolute Rate Constants for the Reactions 0(3P) Atoms with

Methyl Formate and Acetaldehyde ...................................................116 Sadayuki Mori: Primary Processes in the Reaction of Oxygen Atoms with

Acrolein .......................................................................................128 Naohiro Soga: Structural Dependence of Bulk Modulus of Inorganic

Glasses .........................................................................................147 Kazumasa Matusita and Sumio Sakka: Kinetic Study on Non-Isothermal

ii

Crystallization of Glass by Thermal Analysis .......................................159 Sumio Sakka, Kanichi Kamiya, and Masaaki Hayashi: EXAFS of Germani-

um Atoms in Germanate Crystals and its Application to Chemical State Analysis of Germanate Glasses ...........................................................172

Tomozo Nishikawa and Yasunori Okamoto : Diffusional Creep of Polycrystal- line Mn—Zn Ferrite ........................................................................184

Toru Aoki: Nonaqueous Liquid-Liquid Extraction of Manganese from Ethylene Glycol Solution with Trioctylphosphine Oxide ..........................191

Noboru Miyata and Hiroshi Jinno: Mechanical Properties of PbO—B2O3 Immiscible Glasses ..........................................................................196

Masakazu Matsui, TOru Aoki, and Tetsu Kumagai: Forced-Flow Chroma- tography of Rare Earths Using Sensitive Spectrophotometry .................... 207

Yoshiro Moriya: Factors Affecting the Hydration of Silicate Glass ............... 212 Tadashi Kokubo and. Hiroshi Takagi: Alkali-Resistant BaO—TiO2—SiO2

Glasses .........................................................................................224 Toshio Maki: Use of Magnesium-Alminium and Zinc-Alminium Hydroxy-

compounds as Adsorbents of Uranium Ions in Aqueous Solutions ....................234 Yasuhiro Kobayashi, Shigetoshi Muranaka, Yoshichika Bando, and Toshio

Takada: Chemical Transport Reaction of Niobium Oxides ....................248

Guan-Wen Chen, Hiroko Sato, Toshio Hayashi, Kohei Kugo, Yasuharu Noishiki, and Akio Nakajima: Microheterophase Structure, Permeability,

and Biocompatibility of A-B—A Tri-Block Copolymer Membranes Com-

posed of Poly (r-ethyl L-glutamate) as the A Component and Polybutadiene as the B Component ........................................................................267

Akiyoshi Kawaguchi, Seiji Isoda, Masayoshi Ohara, and Ken-ichi Katayama: Radiation-Induced Phase Transition of Paraffins ...................................284

Yoshisuke Tsunashima, Norio Nemoto, Yutaka Makita, and Michio Kurata : Analysis of Particle-Size Distributions by a Dynamic Scattering Apparatus

with a Time Interval Digitizer .........................................................293

Katsuyuki Tanizawa, Tatsuo Yamamoto, and Kenji Soda: Properties of Inducible Kynureninase of Neuropora crassa ..........................................311

Nobuyoshi Esaki, Hidehiko Tanaka, Tatsuo Yamamoto, and Kenji Soda: Further Characterization of L-Methionine r-Lyase and Enzymatic Syn-

thesis of Sulfur Amino Acids ............................................................321 Shigeo Tanimoto, Tatsuo Oida, Kouhei Hatanaka, and Masaya Okano: The

Reaction of 2, 2'-[1, 2-Ethanediylbis(thio)]bis-1, 3-dithiolane with Car- bonyl Compounds...........................................................................332

Tsutomu Tagano, Yasuo Wada, Shigeo Tanimoto, and Masaya Okano: The Reaction of Cyclic Olefins with Chloromethyl Methyl Sulfide in Ace- tonitrile .......................................................................................337

Takekazu Ishida and Hiromasa Mazaki: Partial Destruction of the Meissner

State in Multiconnected Josephson Network .........................................343

111

Notes

Toshio Ibuki: Fluorescence Spectra of HC1+ in the Photoionization of HC1 by 58.4—Nanometer Radiation ...............................................................142

Sakae Uemura, Akio Toshimitsu, Yoshihisa Kozawa, and Masaya Okano: Preparation and Characterization of Several New Palladium(II) Chloride

Complexes of Alkyl and Aryl Selenocyanates .......................................350 Sakae Uemura, Akio Toshimitsu, Yoshihisa Kozawa, and Masaya Okano :

Selenodemercuration of Phenyl- and p-Tolylmercury(II) Compounds......... 354

Reviews

Masamichi Wada and Susumu Kawamura: Some Glass-Ceramics for Special Applications .................................................................................256

Eiichi Takenouchi, Donka K. Nikolova, Hidehiko Tanaka, Tatsuo Yamamoto, and Kenji Soda: Lysine Biosynthesis in Yeasts ...................................357

Eiichi Fujita, Yoshimitsu Nagao, Manabu Node, and Masahito Ochiai: The Chemistry of Diterpenoids in 1979. Part—II .......................................381

The Papers Published by the Staff Members of the Institute from July 1980 to June 1981 .................................................................................399

iv

Author Index to Volume 59, 1981

Aoki, Toru ...................................................................................191, 207 Bando, Yoshichika ................................................................................248 Chen, Guan-Wen .................................................................................267 Esaki, Nobuyoshi .................................................................................321 Fujita, Eiichi .......................................................................................381 Fujiwara, Noboru.................................................................................9 Fukunaga, Kiyoji .................................................................................9 Hanai, Tetsuya ....................................................................................56 Hatanaka, Kouhei................................................................................332 Hayashi, Masaaki .................................................................................172 Hayashi, Toshio ...................................................................................267 Ibuki, Toshio .......................................................................................142 Ishida, Takekazu .................................................................................343 Isoda, Seiji..........................................................................................284

Jinno, Hiroshi ....................................................................................196 Kakigi, Shigeru....................................................................................9 Kakiuchi, Shunji ..............................................................................27, 36 Kamiya, Kanichi .................................................................................172 Katano, Rintaro .................................................................................106 Katao, Masaaki ...................................................................................72 Katayama, Ken-ichi .............................................................................284 Kawaguchi, Akiyoshi.............................................................................284 Kawamura, Susumu..............................................................................256 Kawaratani, Tatsumi ...........................................................................49 Kita, Yasuo .......................................................................................56 Kobayashi, Yasuhiro .............................................................................248 Koizumi, Naokazu................................................................................56 Kokubo, Tadashi .................................................................................224 Kozawa, Yoshihisa ........................................................................350, 354 Kudo, Kiyoshi .................................................................................72, 88 Kugo, Kohei .......................................................................................267 Kumagai, Tetsu ...................................................................................207 Kurakado, Masahiko .............................................................................106 Kurata, Michio....................................................................................293 Maki, Toshio.......................................................................................234 Makita, Yutaka....................................................................................293 Mashiko, Katsuo .................................................................................1 Matsui, Masakazu ................................................................................207 Matsuki, Seishi .................................................................................1, 40

Matusita, Kazumasa .............................................................................159

V

Mazaki, Hiromasa ...............................................................20, 36, 106, 343 Miyata, Noboru ...................................................................................196

Mizogawa, Tatsumi ..............................................................................49 Mori Sadayuki ..............................................................................116, 128

Moriya, Yoshiro ...................................................................................212 Mukoyama, Takeshi ..........................................................................15, 27 Muranaka, Shigetoshi ...........................................................................248 Nagao, Yoshimitsu ................................................................................381 Nakajima, Akio....................................................................................267 Nakamura-Yokata, Hitoshi .....................................................................9 Nakayama, Yasuyuki ...........................................................................49 Nakayama, Yoshinaga .............................................................................40 Nemoto, Norio ....................................................................................293 Nikolova, Donka K. ..............................................................................357 Nishikawa, Tomozo ..............................................................................184 Node, Manabu ....................................................................................381 Noishiki, Yasuharu ..............................................................................267 Ochiai, Masahito .................................................................................381 Ohara, Masayoshi ................................................................................284 Ohsawa, Takao....................................................................................9 Oida, Tatsuo.......................................................................................332 Oka, Yoshio .......................................................................................56 Okamoto, Yasunori ..............................................................................184 Okano, Masaya ...............................................................332, 337, 350, 354 Okihana, Akira....................................................................................9 Osugi, Jiro ..........................................................................................63 Phala, Heng .......................................................................................72 Saito, Yukinobu....................................................................................40 Sakka, Sumio ..............................................................................159, 172 Sasaki, Muneo ....................................................................................63 Sato, Hiroko .......................................................................................267 Sekioka, Tuguhisa ................................................................................9 Shikazono, Naomoto .............................................................................1 Soda, Kenji .............................................................................311 321, 357 Soga, Naohiro ....................................................................................147 Sugimoto, Naoki .................................................................................63 Sugita, Nobuyuki..............................................................................72, 88 Tachi, Shinji .......................................................................................106 Tagano, Tsutomu.................................................................................337 Takabatake, Toshio ..............................................................................20 Takagi, Hiroshi ...................................................................................224 Takekoshi, Hidekuni ...........................................................................1, 40 Takenouchi, Eiichi ................................................................................357 Tanaka, Hidehiko ..........................................................................321, 357

vi

Tanaka, Seiji .......................................................................................9 Tanimoto, Shigeo ...........................................................................332, 337 Tanizawa, Katsuyuki ...........................................................................311 Toshimitsu, Akio ...........................................................................350, 354 Tsunashima, Yoshisuke...........................................................................293 Uemura, Sakae ..............................................................................350, 354 Wada, Masamichi ................................................................................256 Wada, Yasuo ................................................................................... 337 Yamamoto, Tatsuo ..................................................................311, 321, 357 Yokota, Hitoshi ...................................................................................9