tianjin explosion – a chemist’s view - fpa australia · • tianjin was a large but preventable...
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TIANJIN EXPLOSION – A CHEMIST’S VIEW
Dr John AllumRegional DirectorHawkins and Associates (formerly HFS-Asia)
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HAWKINS AND ASSOCIATES
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HAWKINS INTERNATIONAL OFFICES
Dr John Allum
Dr Chun Chan
Ms Jessica Ng
Dr Sophie Parsons
Ms Yvonne Tung
Hong Kong Singapore
Dubai
Dr David Rose
Dr Nick Coogan
Dr Chris Wareham
Graham Cooper
Corporate Providerof Expert Services
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UK TEAM(SLIGHTLY BIGGER)
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OUTLINE
Corporate Providerof Expert Services
The Incident
Warehouse storage and shipping risks
Compliance and Issues
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THE EXPLOSION (1)
• 2251 hours, 12 August, a fire was discovered at Ruihai International Logistics
• 1st explosion at 2334 (~45 min later)
• 2nd explosion 30 seconds later
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THE NATURE OF THE EXPLOSIONS
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CHEMICALS STORED AT WAREHOUSE
Chemical Quantity Class Nitrocellulose 496 4.1 Flammable solid / self-
reactive substance
Ammonium Nitrate 800 5.1 Oxidizing substance
Potassium nitrate 1046 5.1 Oxidizing substance
Sodium cyanide 360 6.1 Toxic substance
Total quantity of DG stored at the warehouse and immediate area
~ 4,800 mt at logistics areaA further 11,400 mt in the warehouses
1 – 9
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THE EXPLOSION (2)
• 173 deaths, 8 missing, and 797 non-fatal injuries
• Cause of fire – nitrocellulose (NC)
• Cause of explosion – ammonium nitrate (AN)• According to a BAM report (German research institute on explosives),
equivalent to about 450 tons of TNT
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SIMILAR LARGE SCALE EXPLOSIONS
• Oppau Germany – 1921, 4500 tonnes of AN exploded causing damage more than 30 km away
• Texas City Disaster – 1947, the SS Grandcamp, loaded with 7,700 mt of ammonium nitrate, exploded in port
• Toulouse – 2001, 300 tonnes of ammonium nitrate exploded
• Plus…
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THE AFFECTED ZONES
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THE AFTERMATH
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HAWKINS (HFS-ASIA)
Contamination assessment
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DEBRIS FROM THE EXPLOSION VISIBLE AT ALL TIERS
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PHOTOIONISATION DETECTOR AND CYANIDE DETECTOR USED BEFORE SAMPLING
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WIPE SAMPLING FOR POLYAROMATIC HYDROCARBONS AND CYANIDE
Adhesive templates used for swab samples
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THE IMPORTANCE OF CHAIN OF CUSTODY
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WHAT WENT WRONG
• A nitrocellulose fire – Hawkins investigate at least 2 – 3 of these incidents a year ( a known hazard)
• Storage of AN close to flammable materials
• Difficult to stop happening again without strong compliance and training
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PROBLEMS WITH THE CODES
• There are problems in IMDG codes, but in general good
• However, shippers, manufacturers and logistics companies sometimes seek out and abuse grey areas in the codes
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EXAMPLES OF PROBLEMS
• 4.3 cargoes (emit flammable gases when wet) are tested with distilled water
• Ship’s stores – not governed by the code• IMDG cargoes shipped as bulk cargo i.e. not in containers
(ferrosilicon)• Charcoals and 4.1 cargoes• Expandable polystyrene beads, as below
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EXPANDABLE POLYSTYRENE (EPS) BEADS
IMDG UN 2211• Pentane – Flammable gas
• LEL of 1.4% and a UEL of 7.8%
• Heavier than air gas likely to accumulate in low-lying areas
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EXPANDABLE POLYSTYRENE (EPS) BEADS
Class 9 cargo – miscellaneous DG cargoPacking group 3Special provisions: 207 & 965
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FLEXIBLE INTERMEDIATE BULK CONTAINER (FIBC) PACKAGING
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IMDG CODE
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ONLINE ADVICE FROM A REPUTABLE CHEMICAL COMPANY
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U.S. DEPARTMENT OF TRANSPORTATION
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THE OUTCOME
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SUMMARY
• Tianjin was a large but preventable incident.
• There were significant storage issues on site, typical of many industrial fires/ explosions
• Lessons can be learnt from the incident need all sections of the DG goods industry to be involved. Manufacturer, Logistics and Storage, shippers, insurers, IMO and Local Governments. Training, resources, along with strong encouragement and enforcement
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