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    Characterization of sewage and design of sewage treatment plant

    A THESIS SUBMITTEDIN A!TIA"

    #U"#I""MENT$# THE!E%UI!EMENT#$!THE

    DE&!EE $#

    BachelorofTechnology inCi'ilEngineering

    B(

    FALGUNIK.P.MISHRA,108CE001NILADRIBIHARIMAHANTY,108CE020

    Department

    ofCi'ilEngineeringNationalInstit)te

    ofTechnolog(*!o)r+ela

    ,-.

    ,

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    Characterizationofsewageanddesignofsewagetreatmentplant

    A THESIS SUBMITTEDIN A!TIA"

    #U"#I""MENT$#THE!E%UI!EMENT#$!THE

    DE&!EE $#

    BachelorofTechnology inCi'ilEngineering

    B(

    FALGUNIK.P.MISHRANILADRIBIHARIMAHANTY 

    Undersuer!"s"#n#$Pr#$.K%'"K%r%rP

    %u'

    Department

    ofCi'ilEngineeringNationalInstit)te

    ofTechnolog(*!o)r+ela

    ,-.

    ,

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    NationalInstituteofTechnologyR

    ourkela

    CERTIFICATE

    Thisistocertifythatthethesisentitled“Characterizationofsewageanddesigno

    fsewagetreatmentplant”submittedbyFalguniKrishnaPrasadMishra,Roll

    o!"#$C%##"andiladri&ihariMahanty,Rollo!"#$C%#'#inpartialfulfillm

    entofthere(uirementsfortheawardof&achelorofTechnologydegreeinCi)il%

    ngineeringattheational*nstituteofTechnology,Rour+elaisanauthenticwor 

    +carriedoutbythemundermysuper)isionandguidance!

    Tothebestofmy+nowledge,thematterembodiedinthethesishasnotbeensubm

    ittedtoanyotherni)ersity-*nstitutefortheawardofany.egreeor.iploma!

    Date/ 0rof12A2$"I21AU"3

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    ACKN()LEDGEMENT

    M(heart4)i'erswiththethrillforo5eringgratit)detothoseindi'id)als

    whohelpedmeincompletionofthepro6ect1Themostid(llicpointofprese

    ntingathesisistheopport)nit(tothan+thosewhoha'econtri7)tedtoit1

    Unfort)natel(*thelistofac+nowledgingnomatterhowe8tensi'eisalwa

    (sincompleteandinade4)ate1 Indeedthispage ofmention

    shallne'er7ea7letoto)chthehorizonofgenero)snessofthosewhoten

    deredtheirhelp tome1#irstofall*I wo)ld li+etoe8pressm(

    gratit)deando7ligationstorof2a+oli21a)l*forher+indnessinallowin

    gmeforintrod)cingthepresenttopicandforherinspiringdirection*cons

    tr)cti'e6)dgmentand'al)a7lepropositionsthro)gho)tthispro6ectwor

    +1Ne8t*Iwo)ldli+etothan+Mr1N1Chaitan(a2a')ri*ah1D1scholarforhisr

    elentlesshelpwitho)tan(complain1

    Iamsincerel(than+f)ltohimforhise5ortinimpro'ingm(contents of 

    thispro6ect1

    Iamalsothan+f)ltorof1N1!o(0HeadoftheDepartment3forassigningm

    ethisinterestingpro6ectandforhis'al)a7les)ggestionsand7oostsat'a

    rio)sstagesofthewor+1Acom7inationofthisnat)reco)ldne'erha'e7e

    enattemptedwitho)treferencetoandinspirationfromthewor+sofothe

    rswhosedetailsarementionedinreferencesection1Iac+nowledgem(in

    de7tednessto allof them1

    "ast7)tnotleast*m(sincerethan+stoallm(friendswhoha'epatientl(e

    8tendedall sorts ofhelpfor achie'ingthis)nderta+ing1

    #A"&UNI2!ISHNA!ASADMISH!ANI"AD!IBIHA!IMAHANT9.-:CE--

    .

    .-:CE-,-

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    Dept1 of 

    Ci'ilengineeringNationalInsti

    t)te ofTechnolog(

    !o)r+ela;--:

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    CONTENTS   PAGE

    /istoffiguresandtables i

    0bstract ii

    1. INTRODUCTION

    "! *ntroduction   '

    "! 1b2ecti)esofthe study   3

    "! /iteratureRe)ie   4

    2. MONITORINGPROTOCOLS'!"   5tudy 0rea $

    '!'   5amplingTechni(ues $

    3!   ANALYSISTECHNIQUES

    3!" Methodologyformeasurementofp7)alue ""

    3!' Methodologyformeasurementof0l+alinity "'

    3!3 MethodologyformeasurementofTurbidity "4

    3!4 Methodologyformeasurementof0cidity "83!8 MethodologyformeasurementofChloride "9

    3!: MethodologyformeasurementofResidualChlorine";

    3!9 MethodologyformeasurementofTotal5olids ";

    3!$ Methodologyformeasurementof.1 '"

    3!; Methodologyformeasurementof&1. '"

    3!"# Methodologyformeasurementofhardness '3

    3!"" Methodologyformeasurementofcarbonatesand bicarbonat

    es '83!"' Methodologyformeasurementofmetals ';

    4!   RESULTSANDDISCUSSION4!"   Tabulations 3'

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    8!   DESIGNOFSEWAGETREATMENTPLANT   3;

    :!   TIMELINEOFTHEPROJECT   48

    9!   CONCLUSION   49

    $!   REFERENCES   4;

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    i

    LISTOFTABLES PAGE

    "!

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    ii

    ABSTRACT

     TheNationalInstit)teofTechnolog(

    !o)r+elaisoneofthemostimportanted)cationalinstit)tesinthestateof$rissawithalargen)m7erofpeopleresidinginitscamp)sconsistingof 

    an)m7erofla7oratoriesof'ario)sdepartments*residential)nits*acad

    emic7loc+s andn)m7erof hostels1

    Ast)d(ondomesticwastewatercharacterizationhas7eenperformedf 

    ollowed7(thedesignofsewagetreatmentplant1Thepresentst)d(in'ol

    'estheanal(sisofpH'al)e*totalsolids*totals)spendedsolids*hardnes

    s*acidit(*al+alinit(*chloride*chlorine*B$D*D$andhea'(metalss)chasIron*Copper* ?inc*

    Magnesi)m*Nic+el*Chromi)m*"ead*Calci)m*Al)mini)m*Silicon*

    otassi)m1

    Asewagetreatmentplantis4)itenecessar(torecei'ethedomesticand

    commercialwasteandremo'esthematerialswhichposeharmforgener

    alp)7lic1Itso76ecti'eistoprod)ceanen'ironmentall(@

    safe)idwastestream0ortreatede)ent3andasolidwaste0ortreatedsl)dge3s)ita7lefor disposal orre)se0)s)all( as farm fertilizer31

     Thesamplingsofthedomesticwastefromhostelsha'e7eendoneindi5e

    renttimesoftheda(toha'eana'eragedataofthemeas)redparameter

    s1Thea'erage'al)esofpH*T)r7idit(*Acidit(*Chloride*!esid)alChlorin

    e*Hardness*TotalSolid*B$D*D$*Al+alinit(*TotalIronContent*?incCont

    ent*otassi)m*Copper*Magnesi)m*Nic+el*Chromi)m*"ead*Calci)m*

    Al)min)mandSilicon are fo)nd o)t1

    A sewagetreatment plant has7eendesignedwith thetreatment

    )nits*a7arscreenofdimension.1

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    .

    CHATE!.

    INTR(DUCTI(N

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    ,

    .1.  Introd)ction/

    oll)tionin its7roadestsenseincl)desall

    changesthatc)rtailnat)ral)tilit(ande8ertdeleterio)se5ectonlife1Thecrisistriggered7(therapidl(growingpop)lationandind)strialization

    withtheres)ltantdegradationoftheen'ironmentca)sesagra'ethreatt

    othe4)alit(oife1Degradationofwater4)alit(isthe)nfa'ora7lealterat

    ionoftheph(sical*chemicaland7iologicalpropertiesofwaterthatpre'e

    ntsdomestic*commercial*ind)strial*agric)lt)ral*recreationalandoth

    er7eneFcial)sesofwater1Sewageandsewagee)entsare

    thema6orso)rcesofwaterpoll)tion1Sewageismainl(composedofh)m

    anfecalmaterial*domesticwastesincl)dingwash@waterandind)strialwastes1

     Thegrowingen'ironmentalpoll)tionneedsfordecontaminatingwaste

    waterres)lt in

    thest)d(ofcharacterizationofwastewater*especiall(domesticsewag

    e1Inthepast*domesticwastewatertreatmentwasmainl(conFnedtoor

    ganiccar7onremo'al1!ecentl(*increasingpoll)tioninthewastewaterl

    eadstode'elopingandimplementingnewtreatmenttechni4)estocontrolnitrogenandother priorit( poll)tants1

    SewageTreatmentlantisafacilit(designedtorecei'ethewastefromd

    omestic*commercialandind)strialso)rcesandtoremo'ematerialstha

    tdamagewater4)alit(andcompromisep)7lichealthandsafet(whendi

    schargedintowaterrecei'ings(stems1Itincl)desph(sical*chemical*a

    nd7iologicalprocessestoremo'e'ario)scontaminantsdependingonit

    sconstit)ents1Usingad'ancedtechnolog(itisnowpossi7letore@)sesewagee)entfordrin+ing water1

     Thepresentst)d(comprisesthest)d(on4)alit(ofdomesticwastewate

    rthatisdischargedfromtheHBHallofNationalInstit)teofTechnolog(*!o

    )r+ela*thro)ghthe+itcheno)tletsand7athroome)ents1Thest)d(inc

    l)descharacterizationtestsforpH'al)e*acidit(*al+alinit(*chloride*res

    id)alchlorine*t)r7idit( GD$1

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    .1,  $76ecti'es ofthe st)d(/

     Theprincipalo76ecti'eofwastewatertreatmentisgenerall(toallowh)

    manandind)striale)entsto7edisposedofwitho)tdangertoh)manh

    ealthor)naccepta7ledamagetothenat)ralen'ironment1Anen'ironm

    entall(@

    safe)idwastestreamisprod)ced1Nodangertoh)manhealthor)nacc

    epta7ledamagetothenat)ralen'ironmentise8pected1Sewageincl)d

    esho)seholdwasteli4)idfromtoilets*7aths*showers*+itchens*sin+san

    dsoforththatisdisposedof'iasewers1Sewagealsoincl)des

    li4)idwaste from ind)str(and commerce1

     The o76ecti'es of thest)d(are/

    .1 h(sical*chemicaland 7iologicalcharacterizationof

    thedomesticwaste water from hostels of NIT*!o)r+ela

    ,1 Comparisonwiththeprescri7ed standard

    1 Design of the sewagetreatment plant1

    (*ser!%+"#n#$S+ud-astewatersamplesfromthe+itchene)ent

    andthe7athroomwasteofHomiBha7haHallof !esidence1

     Thepresencest)d(isdesignedtocollectwastewatersamplefromHBH1

     Thest)d(incl)desalso MSSHall1

     The following ph(sicalcharacteristics were st)died/

    i1 $do)r

    ii1 Taste

    iii1 Colo)r

    i'1 #loata7les

    '1 T)r7idit(

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     The following chemicalcharacteristicswerest)died/

    i1 TotalIron

    ii1 Copper

    iii1 ?inci'1 otassi)m

    '1 "ead

    'i1 Al)min)m

    #ordeterminationofinorganicnon@

    metallicconstit)entswedeterminedthe/

    i1 Al+alinit(ii1 Acidit(

    iii1 Chloride

    i'1 !esid)alChlorine

    '1 S)lphate

    'i1 h1 of thesample

    'ii1 Biochemical$8(gen Demand

    'iii1 Dissol'ed $8(gen

    .1 "iterat)re !e'iew /

    Ps"/%'/%r%/+er"s+"/#$%s+e%+er-

    (d#ur-Itdependsonthes)7stanceswhicharo)seh)manreceptorcells

    oncomingincontactwiththem1)rewaterdoesntprod)ceodo)rortast

    esensations1Th)swastewaterwhichcontainsto8ics)7stanceshasp)n

    gentsmellwhichma+esiteas(todisting)ish1$do)risrecognizedasa4)alit(factora5ectingaccepta7ilit( of drin+ingwater1

     Theorganicandinorganics)7stancecontri7)testotasteorodo)r1The)l

    timateodo)rtastingde'iceistheh)mannose1Theodo)rintensit(isdon

    e7(thresholdodo)r test

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    T%s+e- The senseof tasteres)ltmainl(from

    chemicalstim)lationofsensor(ner'eendingsintong)e1#)ndamentals

    ensationsoftasteare*7(

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    con'entionmorethan7(researche'idence*salt*sweet*7itter*andso)r1

     Theratingin'ol'esthefollowingsteps/a3dil)tionseriesincl)dingrando

    m7lan+sisprepared73initialtastingofa7o)thalfthesample7(ta+ingwa

    terintomo)thandholdingitforse'eralsecondsanddischargingitwitho

    )tswallowing1c3#orminganinitial6)dgmentontheratingscaled3aFnalr

    atingmadeforthesamplee3rinsingmo)thwithtasteandodo)rfreewate

    r f3resting1

    C#'#ur-Colo)rinwaterres)ltsfromthepresenceofnat)ralmetallicionss)chas#eorMg*h)m)sandpeatmaterials*plan+tonsandweeds1Itisremo'edtoma+ewaters)ita7leforgeneralandind)strialapplications1Aftert)r7idit(isremo'edtheapparentcolo)randthatd)etos)spendedmatteris fo)nd o)t1

     Tristim)l)s* Spectroscopic and latin)m co7alt methodis)sed1

    T#+%' s#'"ds- Itrefersto matterss)spended ordissol'edinwater

    andwastewater1Solidsa5ectthewaterore)ent4)alit(ad'ersel(inan

    )m7erofwa(s1aterwithhighl(dissol'edsolidsarenotpalata7leandm

    a(ca)seph(siologicalreaction in transientcons)mer1

    Alimitof--mg

    dissol'edsolidsJ"isdesira7lefordrin+ingwaters1E'aporationmethodi

    s)sedtoseparatetotalsolidsandtheirweightisfo)nd o)t1

    F'#%+%*'es-$neimportantcriterionfore'al)atingthepossi7lee5ecto

    fwastedisposalintos)rfacewateristheamo)ntofoata7lematerialint

    hewaste1Twogeneralt(pes of oating mattersare fo)nd

    0i3 artic)latematters li+e Kgrease7allsK

    0ii3 "i4)idcomponentcapa7leofspreadingasthin'isi7leFlmo'erlarge

    areas1

    Itisimportant7eca)seitacc)m)latesonthes)rfaceandma(containpa

    thogenic7acteriaand'ir)ses1

    Tur*"d"+-Clarit(ofwaterisimportantinprod)cingprod)ctsdestined

    forh)mancons)mptionandinman(man)fact)ring)ses1Itis ca)sed7(

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    =

    s)spendedmatters)chascla(*silt*Fnel(di'idedorganicandinorganic

    matter*sol)7lecoloredorganiccompo)nds1T)r7idit(isane8pressionof 

    theopticalpropert(thatca)seslightto7escatteredanda7sor7edrathe

    rthantransmittedinstraight linesthro)gh

    thesample1Thestandardmethodfordeterminationoft)r7idit(has7ee

    n7asedontheLac+soncandlet)r7idimeter andNephlometer1

    Ce"/%'/%r%/+er"s+"/#$%s+e%+er-

    Chemicalcharacteristicsofwaterstatethepresenceofmetalstheirtreat

    ment*thedeterminationofinorganicnon@

    metallicconstit)entsandthedeterminationoforganicconstit)ents1He

    regoesa7riefdescriptionofallthee8periments weha'e performed1

    B"#'#3"/%'/%r%/+er"s+"/#$%s+e%+er-

    ater4)alit(hasa+e(roleindecidingthea7)ndance*speciescomposit

    ion*sta7ilit(*prod)cti'it(andph(siologicalconditionofindigeno)spop

    )lationsofa4)aticcomm)nities1Theire8istenceisane8pressionofthe4

    )alit(ofthewater1Biologicalmethods)sedfore'al)atingwater4)alit(i

    ncl)dethecollection*co)ntingandidentiFcationofa4)aticorganisms1

    Mostmicroorganisms+nowntomicro7iologistscan7efo)ndindomestic

    wastewaterli+eBacteria*rotozoa*ir)ses*andAlgae1

    lan+tons*eriph(ton*Macro@ph(ton*Macro@

    in'erte7rates*#ish*Amphi7iansandA4)aticreptilesarethe7ioticgro)p

    ofinterdependentorganism1astewatercontains'ast4)antitiesof7a

    cteriaandotherorganisms1Aero7ic7acteria7rea+downorganicmatteri

    nthepresenceofa'aila7leo8(gen1Anaero7ic7acteriadisintegrateorg

    anicmatterwhichissh)to5fromfreeo8(gen*s)chasintheinteriorofamassoffecesoradead7od(1Theprod)ctsofanaero7icdecompositionha'

    eane8tremel(na)seatingodor1 Matter

    inwhichthisconditione8istsissaidto7eseptic1

    Am)ltit)deofthe7acteriainwastewaterarecoliform7acteria/thosefo)

    ndin thedigesti'etractofnormalh)mans1It

    isthesecomparati'el(fewpathogenicorganismsthatposethegreatest

    p)7lichealthhazard1astewaterwhichisnotproperl(treatedma(e'en

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    t)all(Fnditswa(intoacomm)nit(water

    so)rceandspreadwater7ornediseases

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    <

    CHAPTER2

    M(NIT(RINGPR(T(C(LS

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    :

    ,1.   St)d(Area/

    Achie'ementofasafeandhealthf)lwor+placeistheresponsi7ilit(ofano

    rganization*thepeopleresidingintheplaceandthewor+erswhoaregi'e

    nthechargetoprotecttheen'ironment1astedisposalandminimizatio

    nandpoll)tionpre'entionsho)ld7ethepreferredapproach1Stringentp

    enaltiesfor the improper disposal ofwastessho)ld7eadopted1

    !o)r+elais one ofthe most signiFcantind)strialh)7sinthe state of 

    $rissa1IthasgotanintegratedSteellantan)m7erofspongeironind)str

    ies*cementman)fact)ring)nit*chemicals*e8plosi'es*ceramicsanddi

    stiller()nitsandlarge n)m7erof small andmedi)mind)stries1

    NIT!o)r+elaisoneofthemostimportanted)cationalinstit)tesinthesta

    te of$rissawhichhas alargen)m7erofpeopleresidinginitscamp)s*

    an)m7erofla7oratoriesof'ario)sdepartments*residential)nits*acad

    emic7loc+s andn)m7erof hostels forthest)dentsst)d(ing here1

     Thefollowingisthelistofwor+placewhichisthemainso)rcesofpoll)tion

    generating )nitin the st)d( area/

    a3Homi Bha7haHall of !esidence NIT!o)r+ela*

    73HallNit !o)r+ela

    ,1,   SamplingTechni4)es/

    astewatersamplesha'e7eencollectedincontaminationfreesamplin

    g7ottlesof.---ml0T)rsonma+e3fromthe+itchene)entandthe7athroom wasteofHomiBha7haHallof!esidence1

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    >

    Rourke!

    F"#. 2.1M!$o% NITRourke!

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    .-

    CHAPTER4

    ANALYSISTECHNI5UES

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    .

    .

    4.1METH(D(L(GYF(RMEASUREMENT(FH6ALUE7ELE

    CTR(MERICMETH(DS

     Thenegati'elogarithmofconcentrationofh(drogeniongi'esthepHofa

    sample1pH'ariesfrom=@

    :inwastewatersample*d)etoh(drol(sisofsaltsof7asesandacids1Car7

    ondio8ide*H(drogenS)lphideandAmmoniawhicharedissol'eda5ect

    pH'al)eofwater1pH'al)ema(7emorethan>inal+alinespringsandthe

    pHma(7eore'enlessthanforacidicones1Ind)strialwastesdoa5ectt

    hepHasitdependson7)5ercapacit(ofwater1pH'al)eofwatersamplei

    nla7changes7eca)seofloss@ora7sorptionofgases*reactionswithsediments*chemicalreactionta+i

    ngplacewithinthesample7ottle1ThereforepH'al)esho)ldprefera7l(7

    edeterminedat

    thetimeofcollectionofsample1pHcan7edeterminedelectrometricall(

    orcalorimetricall(1Theelectrometricmethodismoreacc)rate7)tre4)i

    resspecialapparat)s1Thecalorimetricmethodissimpleandre4)iresles

    se8pensi'eapparat)s*andiss)cientl(acc)rateforgeneralwor+1

    PRINCIPLE

     ThepH'al)eisfo)nd7(meas)rementoftheelectromoti'eforcegenera

    tedinacell1Itismade)pofanindicatorelectrodewhichisreacti'etoh(dr

    ogenionss)chasaglasselectrode1henitisimmersedinthetestsol)tio

    nthecontact7etweenreferenceelectrode0)s)all(merc)r(Jcalomelel

    ectrode3*andthetestsol)tiontheelectromoti'eforceismeas)red1ApH

    meter*thatis*ahighimpedance'oltmeterismar+edintermsofpH1arie

    tiesofelectrodesha'e7eens)ggestedforthedeterminationofpH1Theh

    (drogengaselectrodeistheprimar(standard1&lasselectrodeincoordi

    nationwithcalomelelectrodeisgenerall()sedwithreferencepotential

    pro'ided7(sat)ratedcalomelelectrode1Theglasselectrodes(stemis7

    asedonthetheor(thatachange*of.pH)nitprod)cesanelectricalchang

    eof>1.mat,OC1Themem7raneoftheglassformsapartition7etwee

    ntwoli4)idsofdi5eringh(drogenionconcentrationth)sapotentialispr

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    od)ced7etweenthetwosidesofthemem7ranewhichisproportionaltot

    hedi5erence in pH7etweentheli4)ids1

     The apparat)s)sedare/

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    .

    ,

    •   pHmeter@

    ithglassandreferenceelectrode0sat)ratedcalomel3*prefera7l

    (with temperat)re compensation1

    •   Thermometer @ ithleast Co)nt of-1OC1

    PR(CEDURE-

     Theinstr)mentisstandardizedafterre4)iredwarm@

    tipperiod1A7)5ersol)tionofpHneartothatofthesampleis)sed1Theele

    ctrodeischec+edagainstatleastoneadditional7)5erofdi5erentpH'al

    )e1Thetemperat)reofthewaterisfo)ndandiftemperat)recompensati

    onisa'aila7leintheinstr)mentsitisad6)sted1Theelectrodesarerinsedandgentl(wipedwithsol)tion1Ifnecessar(*theelectrodesareimmerse

    dintothesample7ea+erorsamplestreamandstirredataconstantrateto

    pro'idehomogeneit(ands)spensionofsolids1!ateofstirringisminimiz

    edandtheairtransferrateattheair@waterinterfaceofthesampleis

    noted1 ThesamplepHandtemperat)re is noted1

    1, METH(D(L(GYF(RMEASUREMENT(FALKALINITY 

     Thesampleli4)idforanal(sissho)ld7eeitherfreefromt)r7idit(orsho)l

    d7eallowed to settle 7efore anal(zing it1

     The apparat)s)sedare/

    • pHMeter

    •   B)rette @ -@ml capacit(1

    •   Magnetic Stirrer

    Assem7l(The

    reagents)sedare/

    •   Distilledater@pHm)st7egreaterthan=1-1IncasethepHfalls7elow=1-*itshall7e7oiledfor.min)tesandcooledtoroomtemperat)re1

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    •   S)lph)ricAcid@

    1=mlofconcentrateds)lph)ricacidisdil)tedwithoneliterwithdis

    tilledwater1

    •   StandardSol)tionof S)lph)ricAcid@ -1-,N1

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    .

    •   henolphthaleinIndicator@

    -1gofphenolphthaleinin.--mlismi8ed* ./. 0'J'3 alcohol

    water mi8t)reis ta+en1

    •   Mi8edindicatorSol)tion@Dissol'e-1-,gmeth(lredand-1-.g7romocresolgreenin

    .--ml*P* eth(lorisoprop(lalcohol1

    PR(CEDURE-

    ,-mlofsampleispipettedintoa.--@

    ml7ea+er1,todropsofphenolphthaleinindicatorisaddedtothesampl

    eifthepHofthesampleisa7o'e:11ItisthentitratedwithstandardH,S$

    sol)tiontillthepin+coloro7ser'ed7(indicator6)stdisappears0e4)i'ale

    nceofpH:131The'ol)meofstandardH,S$sol)tion)sedisrecorded1,t

    odropsofmi8edindicatorisp)ttothesol)tioninwhichthephenolphthal

    einal+alinit(has7eendetermined1Thesol)tionistitratedwithstandard

    acidtolightpin+color0e4)i'alenceofpH@

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    .

    1   METH(D(L(GY F(R THE DETERMINATI(N(FTURBIDITY-

    PRINCIPLE/ Theintensit(oflightscattered7(thesample)nderdeFnedconditionsis

    comparedwiththeintensit(oflightscattered7(astandardreferences)

    spension)nderthesameconditions*formsthe7asisofdeterminationof 

    t)r7idit(1

    Highertheintensit(ofscatteredlightshigherthe'al)eoft)r7idit(1#orm

    azinpol(merisgenerall()sedast)r7idit(standard7eca)seitismorere

    prod)ci7lethanothert(pesofstandards)sedpre'io)sl(1Thet)r7idit(

    ofapartic)larconcentration of#ormazins)spensionisdeFned as-Lac+sont)r7idit()nits1Thesames)spensionof#ormazinhasat)r7idi

    t(ofappro8imatel(

    -)nitswhenmeas)redonLac+soncandlet)r7idimeter1Th)st)r7idit()

    nits7asedonthe#ormazinpreparationclosel(appro8imatethosederi'

    edfromLac+soncandlet)r7idimeter7)titma( not alwa(s7eidentical

    tothem1

     The apparat)s)sedare/•   SampleT)7es-

     Thesamplet)7essho)ld7eofclearandcolorlessglass1

    •   T)r7idimeter

     The reagents)sedare-

    •   T)r7idit(@#ree ater

    •   He8ameth(lene Tetramine Sol)tion

    •   H(drazine S)lphateSol)tion•   T)r7idit(StandardS)spension I0 #ormazin3

    •   T)r7idit(StandardS)spensionII

    PR(CEDURE- TU!BIDIMETE!CA"IB!ATI$N@

     Theman)fact)rersoperatinginstr)ctionsisfollowed1Thestandardson

    t)r7idimeterco'eringtherangeofinterestaremeas)red1Iftheinstr)me

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    ntisalread(cali7ratedinstandardt)r7idit( )nits* thisproced)re

    willchec+the acc)rac( of cali7ration1

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    .

    •   T)r7idit(lessthanUnits@ Thesampleissha+entodispersethesolids1Air7)77lesdisappeargrad)all(1Sampleintot)r7idimetert)7eispo)redcaref)ll(andt)r7idit

    ('al)eisdirectl(readfromtheinstr)mentscale1

    •   T)r7idit(greaterthan-Units;Ift)r7idit('al)esaremorethan-)nits*thesampleisdil)tedwithcleardistilledwatertocompareand7ringthe'al)eswithinrange1Thereadingsareta+enofthedil)tedsample1Thenthet)r7idit(iscomp)tedoftheoriginalsamplefromthet)r7idit( of the dil)tedsample andthedil)tionfactor1

    CALCULATI(N-Calc)latethet)r7idit( of dil)tedsamples*)sing thefollowing

    e4)ation/T)r7idit( )nitsQ A80BRC3JC

    here*

    A Q

    t)r7idit()nitsfo)ndindil)tedsample*BQ

    'ol)mein ml ofdil)tion water )sed*and

    C Q'ol)meof sample in mlta+en fordil)tion1

    1   METH(D(L(GY F(R THE DETERMINATI(N(FACIDITY-

    PRINCIPLE-Acidit(ofwateristhen)mericall(e8pressi7lecapacit(toreactwithastro

    ng7asetoadesignatedpH1Itma(7edeFnedase4)i'alentconcentratio

    nofh(drogenionsinmgJl1Thee4)ationinitssimplestformis asfollows/

    HRR Na$HQ H,$RNaR

     The apparat)s)sedare/

    • pHMeter

    •   B)rette --@ml capacit(1

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    •   Magnetic

    StirringDe'iceThe

    !eagents)sedare/

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    .

    =

    •   Distilledater

    •   otassi)mAcid hthalate

    •   Sodi)mH(dro8ideSol)tion-.N1

    S#d"udr#9"des#'u+"#n:

    1N=

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    .

    <

    C%'/u'%+"#n:Acidit( in thesample iscalc)latedas

    follows/Acidit( at

    pH1

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    acidtoco)nteractatotalal+alinit( of.-mgasCaC$Jl

    totheproper pHina.--ml sample1

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    .

    :

    a3 ,-mgs@diphen(lcar7azone* @$ml1concentrationnitric

    acidand-mg8(lenec(anol##in.--ml>percenteth(lalcoholorisopr

    op(lalcohol1Thesampleisstoredinadar+7ottleinarefrigerator1Thisrea

    gentisnotsta7leindeFnitel(1Deterioration ca)ses a slowend

    pointandhigh res)lts1

    Standardmerc)ricnitratetitrant@

    ,1gmerc)ricnitrateHg0N$3,or,1gHg0N$31.,H,$isdissol'edin.

    --mldistilledwatercontaining-1,mlconcentratednitricacid1Itisdil)t

    edto6)stlessthan.liter1!eplicatesare)sedcontaining1-- ml

    standardsodi)mchloridesol)tionand.-mgsodi)m7icar7onate0NaHC$3dil)tedto.--mlwithdistilledwater1Itisad6)stedto-1-..NandaF

    nalstandardizationof.1--mlQ--gCl@ismade1It is storedawa(from

    light in adar+ 7ottle1

    Mi8edindicatorreagent@

    -1-gdiphen(lcar7azonepowderand-1-g7romophenol7l)epowderi

    sdissol'edinpercenteth(lorisoprop(lalcoholanddil)te

    to.--mlwiththesame alcohol1-1..Nstandard merc)ricnitrate is )sedas titrant1

    PR(CEDURE-

    .--mlsampleista+ens)chthatthechloridecontentislessthan.-mg1.1

    -mlindicatoracidiFerreagentsarep)t1pHisconformedtoa7o)t:forhig

    hl(al+alineoracidwaters7eforeaddingindicator@acidiFerreagent1

    -1..NMerc)ricNitrateistitratedwiththesol)tiontoadeFnitep)rpleen

    dpoint1Thesol)tiont)rnsfromgreen7l)eto7l)eafewdrops7eforetheendpoint1

     The7lan+isdetermined7(titrating.--mldistilledwatercontaining.-

    mgof sodi)m7icar7onate1

    her

    e*

    Chloride* mgJl Q0.;,3 8N 8-

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    .

    >

    .Q 'ol)me in ml ofsil'er nitrate )sed7(the sample*

    ,Q 'ol)me in ml ofsil'er nitrate )sedin the 7lan+

    titration*Q 'ol)me in ml of sampleta+en fortitration

    and

    NQ normalit( ofsil'er nitrate sol)tion1

    1=   METH(D(L(GY F(R THE DETERMINATI(N(FRESIDUALCHL(RINE-

    Itismeas)redasthechlorineleftinthewaterafterthere4)iredcontactpe

    riodwhichwillens)recomplete+illingof7acteriaando8idationoftheorg

    anic matter)s)all(

    afreechlorineresid)eisconsideredto7es)cient1The

    reagents)sedare

    •   $@ Tol)idine @ drops

    PR(CEDURE-$@

     Tol)idineisaddedtothesampleandmi8edthoro)ghl(1After.to,-min

    )testhecolo)risde'eloped1Thecomparatorwasplacedtomatchthecol

    o)rofthesample1The'ol)meofindicator)sedwasnoteddown1&eneral

    l(theconcentration of resid)alchlorine m)st 7e.@,mgJl1

    1

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    •   E'aporatingDish

    •   Steam@Bath

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    ,

    -

    •   Dr(ing$'en

    •   Desiccator

    •   Anal(ticalBalance

    PR(CEDURE-

    .1 Thecleane'aporatingdishisheatedto.:-OCfor.ho)r1Itiscooled*desic

    cated*weighed andstoredin desiccator)ntil itis read(1

    ,1 The'ol)meofthesampleisselectedwhichhasresid)e7etween,and,

    -mg*prefera7l(7etween.>-and,--mg1This'ol)mema(7efo)ndo)

    tfrom'al)esofspeciFccond)ctance1Ifameas)ra7leresid)ehasto7eo7taineds)ccessi'eali4)otsof sample can 7eaddedtothesampledish1

    1 This'ol)meispipettedtoaweighede'aporatingdishplacedonasteam@

    7ath1Adr(ingo'encan7e)sedtoperforme'aporation1Topre'entoiling

    andsplatteringofthesamplethetemperat)resho)ld7eloweredtoaro)

    nd>:OC1Thedishista+entoano'[email protected]*or.@

    .:.OCanddriedtoconstantmass*aftercompletee'aporationofwaterfr

    omtheresid)e1Itisdonetillthedi5erenceinthes)ccessi'eweighingislessthan

    -1mg1Toeliminatenecessit(ofchec+ingforconstantmassdr(ingforal

    ongd)ration0)s)all( . to,ho)rs3 isdone1The

    timefordr(ingtoconstantmasswithagi'ent(peofsamplewhenan)m7

    erofsamplesofnearl(same t(peare to7eanal(zed can 7e

    determined7(trial1

    1 Thedishisweighedassoonasithascooled1!esid)eisa'oidedtosta(forlongtimeassomeresid)esareh(groscopicandma(a7sor7waterfromd

    esiccant whichma(not7ea7sol)tel(dr(1

    CALCULATI(N@

     Thetotalresid)eiscalc)lated)singthefollowinge4)ation/

     Totalresid)e*mgJlQ .---8MJ

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    ,

    .

    here*

    M Q mass in

    mgoftotalresid)e*and9

    Q'ol)mein mlofthe sample1

    1:  METH(D(L(GYF(RMEASUREMENT(FD(-

     The apparat)s)sedare/

    •   Inc)7ation7ottles

    •   D$ meter

    •   Airinc)7ator

    PR(CEDURE-

    ateris+eptininc)7atorandamagneticstirrerisp)tinsidethe7ottle1Th

    emagneticstirrerisincessantl(rotatedinsidethe7ottle1Thenwiththeh

    elpofD$meterreadingsarenoted1TheFrstreadingista+enatthe7otto

    m* secondat mid@point and third

    attopofthe7ottle1Th)sthea'erageof thereadingswillgi'ethe

    dissol'edo8(gen present inthe watersample1

    1>  METH(D(L(GYF(RMEASUREMENT(FB(D-

    PRINCIPLE-

     The7iochemicalo8(gendemand0B$D3testis7asedmainl(ontheclassi

    Fcationof7iologicalacti'it(ofas)7stance1Aproced)remeas)resthedi

    ssol'edo8(gencons)med7(micro@

    organismswhilecapa7leofta+ingando8idizingtheorganicmatter)nde

    raero7icconditions1Thestandardtestconditionletsininc)7atingthesa

    mpleinanairtight7ottle*in dar+ atare4)ired temperat)re for speciFc

    time1

     The apparat)s)sedare/

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    ,

    ,

    i3 Inc)7ationBottles/The7ottlehascapacit(of--ml1Ithasnarro

    wnec+withe'enmo)thand

    hasgro)ndglassstoppers1New7ottlesarecleanedwithNh(dr

    ochloricacidors)lph)ricacidandrinsedwithdistilledwater1Inn

    ormal)se*7ottlesonce)sedforin+lersproced)resho)ldonl(

    7erinsedwithtapwaterfollowed7(distilledwater1D)ringinc)7

    ationwaterisaddedtothearedmo)thofthe7ottletimetotime*

    toens)repropersealing1

    ii3 AirInc)7ator/Airinc)7ationwiththermostaticall(controlled,

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    ,

    1.-METH(D(L(GYF(RTHEDETERMINATI(N(FHAR

    DNESS-

    Pr"n/"'e-

     Thismethodiscontingent)ponthepowerofeth(lenediaminetetraaceti

    cacid 0C.-H.$:N,3

    oritsdisodi)msalttoformsta7lecomple8eswithcalci)mandmagnesi)

    mions1henthed(eeriochrome7lac+T0EBT3isaddedtoasol)tioncont

    ainingcalci)mandmagnesi)mionsatpH.-1-awineredcomple8isform

    ed1Thissol)tionistitratedwithstandardsol)tionofdisodi)msaltofEDTA

    *whiche8tractscalci)mandmagnesi)mfromthed(ecomple8andthed

    (eischanged7ac+toitsoriginal7l)ecolo)r1Eriochrome7lac+Tis)sedtoi

    ndicatetheend@

    pointforthetitrationofcalci)mandmagnesi)mtogether1

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    ,

     The reagents)sedare/

    i.   B)5er sol)tion0NHCl R NH$H3

    ii1 Standardcalci)msol)tion

    Eriochrome7lac+ .indicator sol)tion

    Inhi7itors

    H(dro8(lamine h(drochloridesol)tion

    otassi)mferroc(anidecr(stals

    Sodi)ms)lphideinhi7itor

    Sodi)mc(anidesol)tion

    StandardEDTAsol)tion

    PR(CEDURE-

    ,1-mlofstandardcalci)msol)tionispipettedinaporcelain7asi

    n1The'ol)meisad6)stedto-mlwithdistilledwater1.ml7)5ers

    ol)tionis)sed1.to,dropsofindicatorisp)t1Aftercontin)o)sstirr

    ing)ntilthereddishtingedisappears*itisnttitrated1#ewdropsof 

    sampleattosecond inter'al areadded1 At theend point the

    colo)r is s+( 7l)e1

    #ordrin+ing*s)rfaceandsalinewaters-

    Anali4)otofwatersampleispipetted*inaporcelaindishor.-@

    ml7ea+er1The'ol)meist)nedtoappro8imatel(-ml1.mlh(dro

    8(lamineh(drochloride0NH$H1HCl3isaddedtothesol)tion1,m

    lof7)5ersol)tionismi8edsoastoachie'epHof.-1-to.-1.1,mls

    odi)mc(anideorsodi)ms)lphideinhi7itorsol)tionisp)tiftheen

    dpointisntsharp1IfC)*?n*7*CoandNiarea7sentandif 

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    ,

    thesamplecontainslessthan-1,mgof#eand-1-,mgofMntheadditio

    nofNaCNorNa,Sma(7eomitted1,mlofEriochrome7lac+Tindicatorsol

    )tionisaddedandtitratedwithstandardEDTAsol)tionstirringrapidl(int

    he7eginning1Itisstirredslowl(towardstheendwhenallthetracesofred

    andp)rplecolo)rdisappearandsol)tionisclears+(7l)e in colo)r1

    #orwastewatersandhighl(poll)tedwaters-

    Anali4)otofthesampleisdigestedwithmlofdistilledconc1HN$ina7e

    a+eronahotplate1Itise'aporatedtoneardr(nesswhileens)ringthatth

    esampledoesnot7oil1Digestionwithnitricacidisrepeatedtillthedigest

    ateislightincolo)r1Itise'aporatedtoneardr(nessandcooled1"ittleamo

    )ntof./.h(drochloricacid0ml3 isaddedand warmedon a steam@7ath todissol'e theresid)e1

    Note.@#orwaterwith'er(lowhardness0lessthanmgJl3micro7)retteis

    )sed1

    Note,@

    Samplesizema(7eselecteds)chthattheres)ltlies7etween,--to --

    mgJlofhardness0asCaC$31

    CALCULATI(N/ The hardnessiscalc)lated as follows/

     Totalhardness0asCaC$3* mgJl Q.---.J,

    here*

    .Q ol)me in mlof the EDTAstandardsol)tion)sedin the

    titration1,Q ol)me in mlof the sampleta+enforthetest1

    1..METH(D(L(GY F(R THE DETERMINATI(N(FCARB(NATESANDBICARB(NATES-

    7TITRIMETRICMETH(D

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    ,=

    PRINCIPLE-

    otentiometricmethodis)sedtodothetitration1henolphthaleinis)se

    dasanindicator1Thetotal$H @*C$@@*andHC$@

    contentisFrstfo)ndo)t7(titrationwithstandardacid)singmeth(loran

    geJ7romocresolgreenindicator1E4)alportionofthesampleistitrateda

    gainstthesameacid)sing

    phenolphthaleinJmetacresolp)rpleindicator1

     The apparat)s)sedare/

    i1 Electrometric Titrator

    ii1 Titration essel

    iii1 Magnetic Stirreri'1 ipettes*ol)metric

    '1 #las+s* ol)metric

    'i1 B)rettes*Borosilicate &lass

    'ii1 ol(oleFn Bottles

     The reagents)sedare/

      Sodi)mCar7onateSol)tionVAppro8imatel( -1-N•   StandardH(drochloric MidV-1.N

    •   StandardH(drochloricAcid V-1-,N

    •   Meth(l $rangeJBoromocresol&reen Indicator

    •   Metacresol)rpleIndicator Sol)tion

    •   henolphthalein Sol)tion

    PR(CEDURE-

    S%'eS";e

    "argeamo)ntofcar7onateand7icar7onateconcentrationsarefo)ndin

    wastewaterthereforeasinglesamplesizeandnormalit(oftitrantisdic

    )lttospecif(1Ifal+alinit(islessthan.---mgasCaC$ Jl*,-mlof 

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    ,

    <

    sampleista+enandtitrated with-1-,NHCl1 Ifal+alinit(

    ismorethan.---mg as CaC$Jl*ml of thesampleis titratedwith

    -1.Nh(drochloric acid1The endpointma(7edetermined7(an( of the

    following/

    a3B(colo)r change* and

    73otentiometricall(1

    P#+en+"#e+r"/T"+r%+"#n

    Distilledwateris)sedtorinsetheelectrodesandtitration'essel1Sample

    pHismeas)red1Standardh(drochloricacidisaddedingrowthsof-1mlo

    rless*sothatachangeoflessthan-1,pH)nitsocc)rperincrement1Magn

    eticstirreris)sedtomi8thoro)ghl(andsteadil(1Splashingisa'oidedata

    llcost1ThepHisrecordedafterreading7ecomesconstant1Thec)m)lati'

    emillilitersoftitrantaddedarerecordedaftermi8t)reistitratedtopH:11

     Thetotalamo)ntoftitrant)sedisrecorded1Astheendpoint7orders

    onsmalleradditions ofal+aliare done1

    CALCULATI(N-

    henolphthaleinal+alinit(iscalc)lated7()singthe'ol)meofacid)sedf 

    orphenolphthaleinendpoint1Itcan7etitratedpotentiometricall(topH

    :11Thetotalal+alinit(isfo)ndo)t7()singthe'ol)meofacid)sedfor7r

    omocresolgreenendpointor titrated potentiometricall( topH11

    her

    e*

    Al+alinit(0CaC$mgJl3 QA 8N8-Jmlof sample1

    AQ ml of

    standardacid1NQ

    Normalit(ofacid1

     Theres)ltso7tainedfromthephenolphthaleinandtotalal+alinit(deter

    minationscan7e)sedtocalc)latethecar7onateand7icar7onateconce

    ntrationsasCaC$1ThemethodspeciFestheentireal+alinit(to7icar7o

    nate*car7onateandh(dro8ide1Itass)mesthea7senceofother0wea+3i

    norganicororganicacids*s)chassilicic*phosphoricand7oric

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    ,

    :

    acids1Sincethecalc)lationsaremadeonastoichiometric7asis*ionconc

    entrations inthestrictestsensearenotrepresentedin the res)lts1

    Sothe(ma(di5ersigniFcantl(fromact)alconcentrationsespeciall(at

    pHgreater than.-1 According tothiso)tline

    a3 Car7onate0C$@@3al+alinit(ispresentwhenphenolphthaleinal+alinit(is

    not zero7)t is lessthantotalal+alinit(W

    73 H(dro8ide0$H@3al+alinit(ispresentifphenolphthaleinal+alinit(ismore

    thanhalf of the totalal+alinit(

    c3 Bicar7onate0HC$@3al+alinit(ispresentifphenolphthaleinal+alinit(isl

    essthanhalf of thetotalal+alinit(1

     Theserelationshipsma(7ecalc)lated7(thefollowingschemewherei

    sphenolphthaleinal+alinit(andT istotalal+alinit(1Thesmaller'al)eofor0T;

    3ista+enintoacco)nt1Afterthatcar7onateal+alinit(e4)alstwicethes

    maller'al)e1Ifthesmaller'al)eis*the7alance0T;

    ,3is7icar7onates'al)e1henthesmaller'al)eis0T;

    3the7alance0,;T3ish(dro8ides'al)e1The res)ltsare

    e8pressedasCaC$1

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    ,

    >

    1.,METH(D(L(GYF(RTHEDETERMINATI(N(FMETALS-

    PRINCIPLE-

     TheAtomicA7sorptionSpectrometeris)sedtodeterminethecontentso

    fmetalsinthewastewatersample1Theprincipleassociatedhereisalight

    7eamisg)idedthro)ghtheameintoamonochromatorandthentoadet

    ectorthatmeas)restheamo)ntoighta7sor7ed7(theatomizedeleme

    ntintheame1#oreachmetalthereisonedistincta7sorptionwa'elengt

    h*soaso)rcelampformedofthatelementis)sed1Thisma+esitfreefroms

    pectralinterference1Theamo)ntofenerg(ofthecharacteristicwa'ele

    ngtha7sor7edintheameisproportionaltotheconcentrationoftheele

    mentinthesample1Theameemissionmethodprod)cesgoodres)lts

    fordetermination of metals1

     Thee5ectsofmetalsinwaterandwastewaterrangefrom7eneFcialthro

    )ghtro)7lesometodangero)sl(to8ic1Someareessential7)tothersad'

    ersel(a5ectwatercons)mers*wastewatertreatments(stemsandrece

    i'ingwaters1#lameandelectro@

    thermalmethodsaregenerall(applica7le at moderateconcentrationle'els1

    .1 SamplingandSamplepreser'ation/Beforecollectingsamplefractio

    nto7eanal(zedisdecided1Errorsintrod)cedd)ringsamplingandsto

    rageista+encareof1The7estsamplingcontainersaremadeof4)artz

    andT#E1

    ,1 Thesampleispreser'edimmediatel(afteracidif(ingwithconcentrat

    ednitric acid11 Contaminatedmetalsfromcontainers*distilledwater*ormem7rane

    Flters area'oidedintrod)ction1

    1 #oranal(sisofmicrogram@per@literconcentrationsofmetals*air7ornecontaminantsintheformof'olatilecompo)nds*d)st*sootandaerosolspresent inla7orator( air7ecomesigniFcant1

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     Thepresencesofman(metalsweretested7(atomica7sorptionspectro

    meter anal(sis1

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    -

     The apparat)s)sedis/

    AtomicA7sorptionSpectrometer made )pof 

    •   "ightemitting so)rce1

    •   B)rner ;remi8t(pe*introd)cesspra(intocondensingcham7er1

    •   !eado)t ;The displa( )nit1

    •   "amps;HollowCathodet(pe1

    •   ress)re red)cing'al'es1

    •   ent1

    PR(CEDURE-

     Thesamplepreparationdependsonthemetalweneedtomeas)re1The

    man)fact)rersoperationman)alisst)diedandtheinstr)ment

    isoperated1Ahollowcathodelampforthere4)iredmetalisinstalled1The

    slitwidthissetaspertheman)al1Theinstr)mentiswarmed)pto,-min)

    testilltheenerg(so)rcesta7ilizes1Airist)rnedonandtheowrateisad6)

    stedaspertheman)fact)rersspeciFcation1Theinstr)mentiscali7rate

    d1di5erentconcentrationofstandardmetalsol)tionispreparedandth

    e7lan+isanal(zed1Theinstr)mentiszeroed1Thestandardsol)tionsareanal(zedanda7sor7anceisrecorded1Acali7ratedc)r'eisprepared7(p

    lottingonalineargraphpaper1A7sor7anceofstandard's1theconcentra

    tionisplotted1Thenthesampleisanal(zedandtheconcentration of 

    eachmetal ion 0in microgramper liter3 iscalc)lated1

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    .

    CHATE!

    RESULTSANDDISCUSSI(NS

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    ,

    1. Ta7)lations/

     Ta7le./atercons)mptionof'ario)sresidentialhallsofNI

     T!o)r+ela

     ame ofthe7all

    Capacityoftan+=/itres>   Totalwat

    ersu lie

    5trength

    1&&& 1'&& 2&&& (&&&

    55

    &hatanagar 

    ) 2* ) ) (*&&& 1(&

    M

    ?is)eswaraya

    ) (2 ) ) +''&& (,(

    @. &irla71R    ) (- ) ) '-'&& '2,

    .hirubhai0mba

    ni71R 

    ) +& ) ) ','&& '1+

    M5

    5waminathan7

    ) (- ) ) '''&& 2-,

    7omi&haba71R    ) 1& 1& +''&& '22

    C? Raman71R    ) 1+ ) ) 2&'&& 2+'

    KiranMa2umd

    ar71R 

    ) +' ) ) *'&&& +&

    ?i+ram5arabh

    ai71R 

    ) 1* ) ) (&&& '

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     Ta7le,/atercons)mption7(residential4)artersofNI T!o)r+ela

    Qu!r/erT0$e Nuer o% roo3

    A 1,

    B 22

    C (&

    D '

    E +&

    F 1&-

    G 11*

    FE /0$e F!/3 1-

    B!45eorF!/3 2+

    Tr!63"/F!/3 1-

    D"re4/or73 1

    A'eragewaters)ppliedQ.1 la+h gallonSo* totalwastewater generatedQ :-Pof S)ppliedater

    Q -1:8.1la+h gallonQ .1,la+h gallon

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     The presenceof non@

    metallicconstit)entsandthemetallicconstit)entsfrom the

    wastewater samplewasdetermined1

    .1 Determination ofacidit( content

    S$U!CE  C$NCENT!ATI$

    NIN M

    Bathroomwa

      1=

    2itchenwastewat

      1

     Tap water ,1

    Distilledwat .

    ,1 Determination of chloridecontent

    S$U!CE  C$NCENT!ATI$

    NIN M  STANDA!

    Bathroomwa

     

    - @.--2itchenwa

    stewat

      ..

     Tap water 1

    1 Determination of h of the sample

    S$U!CE H STANDA!D

    2itchenwaste

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    1 Determination of resid)alchlorine

    S"N$ S$U!CE C$NC1 INM STANDA!D

    . 2itchenwaste ,

    . @, ppm, Bath room waste ,

    Tap water .

    , Determination of t)r7idit( of sample

    S"N$ S$U!CE A"UE INNTU

    . Bath room .

    , 2itchenwaste ..=

    Tap water .-

    Ta7lefordetermination of al+alinit(

    Here)tilizationofs)lph)ricacidis)sediszero1Th)sitindicatespresence

    of 7icar7onate1

    S$U!CE  C$NC1

    INSTANDA!

    DC$N

    2itchenwas

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    =

    De+er"n%+"#n #$e+%'s*%+#"/%*s#r+"#nse/+r#e+r

    .1 Totalironcontent

    S"N$ S$U!CE C$NC1 INM&J"

    . 2itchenwaste ,1:=

    , Bathroom waste -1-,

    Tap water -

    ,1 ?inccontent

    S"N$ S$U!CE C$NC1 INM&J"

    . 2itchenwaste -1..

    , Bathroom waste -1-:=

    Tap water .1>

    1 Copper content

    S"N$ S$U!CE C$NC1 INM&J"

    . 2itchenwaste -1-.>

    , Bathroom waste -1-

    Tap water -1--<

    1 otassi)mcontent

    S"N$ S$U!CE C$NC1 INM&J"

    . 2itchenwaste ..1

    , Bathroom waste >1,:

    Tap water ,1>.

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    <

    T%*u'%+"#n$#rs"/%' %nd/e"/%' /%r%/+er"s+"/s"nd"

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    :

    T%*u'%+"#n$#rde+er"n%+"#n#$d":? ..   PERMISSI

    BLE6ALUE

    Me+%'s

    Ir#n03='

    -1-.: ,1:. 1.. -

    N"/&e'03='

    -1-. -1-.. -1- - -1-,

    Cr#"u03='

    -1.. -1,., -1,, -1.. -1-

    Le%d03='

    -1.-. -1->. -1,=. -1-, -1-.

    C%'/"u03='

    1. .,1. .>1

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    >

    CHATE!

    DESIGN (FSE)AGETREATMENTPLANT

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    -

    1.  Designof SewageTreatment lant/

    P'%n+ /%%/"+-

    A'eragewaters)ppl(perda( Q,---litQ-1,mldXA'eragesewagegeneratedperda( Q :Pof s)ppliedwater

    Q -1:X-1,Q-1=mld

    Q=-+ldXX

    A'eragesewagegeneratedper

    ho)rQ=-J,Q.c)mJhrea+ factorQ

    Design owcapacit(0ma8im)m3 Q.8Qc)mJhr

    Xmld;Million literper da(XX+ld;2ilo"iter per da(

    S";"n3 /%'/u'%+"#n $#r /#''e/+"#n "+-!etention

    timere4)iredQhA'eragedesi

    gn owQ .mJh

    Capacit(of collection s)mpQ 8

    .Q=-m

    Ass)me li4)id depth QmArea re4)iredforcollectionpits Q=-JQ

    .,m,"et itis acirc)lar tan+

    rQ .1>m

    ol)me of the pit pro'ide QYJ 8 88

    Q=,1: m

     Th)sAreaof the pit pro'ided Q.,1= m,

    S";"n3 /%'/u'%+"#n #$ *%rs/reen-ea+ discharge Q

    mJhA'eragedischargeQ

    . mJh

    A'erage'elocit( Za'erageowisnt allowedtoe8ceed -1:mJsec

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    A'eragespacing 7etween7ar

    ,-mmThe

    'elocit(Q-1X=-Q.:mJhJ m,

    Crosssectionalarea re4)ired Q owJ'elocit(

    Q J.: Q,1 m,

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    .

    "i4)iddepth re4)iredQ . m

    elocit( thro)ghscreen at

    thepea+owQ.1=mJsecCleararea Q,1J.1= Q.1

    No1of clearspacingQ .1J-1-,Q=

    idth of channel Q0= 8,-3R 0=

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    Q

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    ,

    ol)me ofsl)dgeQ00