the structure and dynamics of solids
DESCRIPTION
Electronic resonances A core electron is excited and creates a spin polarised photoelectron Exchange split final states act as a filter of the spin Magnetic sensitivity comes through the spin-orbit coupling and exchange and has strong polarisation dependence (MOKE) Courtesy W. Kuch, Freie Universität BerlinTRANSCRIPT
![Page 1: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/1.jpg)
The Muppet’s Guide to:The Structure and Dynamics of Solids
Magnetic Reflectivity
![Page 2: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/2.jpg)
∂
Electronic resonancesA core electron is excited and creates a spin polarised photoelectronExchange split final states act as a filter of the spin
Magnetic sensitivity comes through the spin-orbit coupling and exchange and has strong polarisation dependence (MOKE)
Courtesy W. Kuch, Freie Universität Berlin
![Page 3: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/3.jpg)
∂
XMCD Examples at Resonant Edges
From Magnetism by J. Stöhr and H.C. Siegmann, Springer
![Page 4: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/4.jpg)
∂
Circular Polarised LightA photon is a spin-one particle which carries ±1 unit of L
along its direction of motion. This angular momentum is transferred to the absorbing material.
.Right Circular, +Pc, s=+1
Left Circular, -Pc, s=-1
s=HelicityM
Faraday Effect
![Page 5: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/5.jpg)
∂
Detecting XMCDTransmission Thin Samples
Drain CurrentField Sensitive, AnisotropicEscape Depth ~3nm
FluorescenceEscape Depth ~1mm, AnisotropicSecondary processes
PEEM – ESG group at the ALShttp://xraysweb.lbl.gov/peem2/webpage/Home.shtml
![Page 6: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/6.jpg)
∂
Element Specific M-H loops
-1
0
1
-10 -5 0 5 10
IronCobalt
Field (mT)
Mag
netis
atio
n (M
/MS)
-1
0
1
2
3
630 640 650 660 670
Energy (eV)
XMC
D -
Diff
/Sum
(flip
ping
ratio
%)
-1.0
-0.5
0
0.5
1.0
-400 -200 0 200 400
Field (Oe)
Flip
ping
Rat
io (
FR/F
RM
AX)
MnSb
-10
0
10
680 720 760 800 840
Energy (eV)
Diff
eren
ce (%
)
FeCoZr
Mn
![Page 7: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/7.jpg)
∂
Resonant X-ray ‘Magnetic’ Scattering
Im.E f Em
Absorption spectroscopy sensitive to the exchange split final state and the split core levels (spin-orbit). Basis behind XMCD.
2
Re ImScattering f E f E
Resonant elastic scattering is sensitive to the same terms but contains both the real and imaginary terms to the scattering factor.
2p
3d
Circular polarised x-rays. Element specific.
![Page 8: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/8.jpg)
∂
On Resonance – Scattering Factor
Resonant processes enter the scattering factor through f’ and f’’ and must describe the initial and final state.
0, Magmf iq mq f ff f i
From XAS obtain f’’ From XMCD obtain m’’
Use Kramers-Kronig transforms to obtain the real parts of the scattering factors and thereby f(q,).
![Page 9: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/9.jpg)
∂
Scattering amplitude
Scattering is sensitive to both the real and imaginary components which are related via the Kramers-Kronig transforms.....
0, , ,f q f q f m if m
The magnetic dependent absorption (XMCD) gives a magnetic dependence on the real part of the scattering factorFe
From Magnetism by J. Stöhr and H.C. Siegmann, Springer
![Page 10: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/10.jpg)
∂
Electric Dipole Transition 0 1 2
0ˆ ˆ ˆˆ ˆ ˆ ˆ ˆ ˆf i f i f if r Z F i mF m m F
Resonant and non-resonant charge scattering
Circular Dichroism and Kerr Effect
Linear Dichroism and the Voigt Effect
F0, F1, F2 are all complex numbers containing the scattering factors and depend on the incident energy, and therefore resonance.
![Page 11: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/11.jpg)
∂
q-space
0
2
4
6
8
10
-10 -8 -6 -4 -2 0 2 4 6 8 10
10 keV0.707 keV
2>180°
>180°<0°
Si (004)d=1.358Å
d=10Å
qx(Å-1)
q z(Å-1
)
Diffraction
Small AngleScattering & Reflectivity
![Page 12: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/12.jpg)
∂
Reflections from Surfaces
http://www.glenspectra.co.uk
jj j
jo
A fA
rN Re2
2
m
4Im
22 f
ArN
j j
jo
A
j
jjfrn
21
2
1n i
![Page 13: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/13.jpg)
∂
Reflectivity from layered systems
Intensity is proportional to layer thickness and the refractive index of the layers (electron density).Roughness modifies the reflection and transmission coefficients - interface roughness
Sensitivity <1Å. Max. thickness - 1000Å. Max Roughness - 35 Å
Based on Simple Optical Theorems:Snell’s LawFresnel’s Law
![Page 14: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/14.jpg)
∂
[FeCoZr/AlZr]x20
• Periodicities in the sample give rise to different beat frequencies in spectra. Profile proportional to FT{electron density profile)• Roughness modifies the Fresnel reflection and transmission coefficients and hence the overall fall-off.
Phys. Rev. B 80 (13) 134402 (2009),
![Page 15: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/15.jpg)
∂
Amorphous Multilayer Example
Averaged:Layer thicknessInterface widthRefractive index - Density
TPA Hase et al. Phys. Rev. B 80(13) 134402 (2009)
![Page 16: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/16.jpg)
∂
Anomalous Dispersion
Enhance the scattering factor difference between the layers.
0.001
0.1
10
1000
100000
0 0.02 0.04 0.06 0.08
=1.3803Å=1.4800Å
qz(Å-1)
Nor
mal
ised
Inte
nsity
(a.u
.)
-10
-5
0
5
1.0 1.2 1.4 1.6 1.8 2.0
f'
f"
CoCu
Wavelength (Å)
Sca
tterin
g F
acto
r C
orre
ctio
ns, e
lect
rons
0
50
100
150
200
1.0 1.2 1.4 1.6 1.8 2.0
2CoCoCuCuBragg nfnfI
2CoCu ff
![Page 17: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/17.jpg)
∂
Grazing IncidenceScattering
M. Wormington et al. Phil. Mag, Lett. 74(3) 211 (1996)
In-plane q
Out-of-plane q
![Page 18: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/18.jpg)
∂
Resonant magnetic reflectivity
n2
n3
Refractive index now depends on the moment
direction:
1n i
002
2cosen r
f m Ef Ek
02
2cosen r
f E m Ek
On resonance the scattering becomes sensitive to both the structural and magnetic profiles of the element under consideration. Extract magnetic signal through the flipping ratio:
. . I IF RI I
![Page 19: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/19.jpg)
∂
Alloy – Pd resonant Scattering
Sum (left) and flipping ratio (right) determined by reversing the applied field for the alloy sample at 200 K . The flipping ratio shows the same periodicity as seen in the sum signal and changes sign when the incident helicity (±Pc) is reversed.
![Page 20: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/20.jpg)
∂
T=20K
0.05 0.10 0.15 0.20 0.25 0.30
1E-5
1E-4
1E-3
0.01
0.1
1N
orm
alis
ed S
truct
ural
Ref
lect
ivity
qz(Å)-1
0 50 450 500
-1.6
-1.2
-0.8
-0.4
0.0
Stru
ctur
al P
rofil
e (s
catte
ring
leng
th)
qz(Å)-1
Structural
![Page 21: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/21.jpg)
∂
0.05 0.10 0.15 0.20 0.25 0.30-20
-10
0
10
20
Flip
ping
Rat
io (%
)
qz(Å)-1
0 50 450 500
0.00
0.01
0.02
0.03
0.04
Mag
netic
Pro
file
qz(Å)-1
Magnetic dead-layer at interface with buffer and an enhanced moment at the surface
T=20K
Magnetic
![Page 22: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/22.jpg)
∂
Compositional and Magnetic Profiles (Pd)
0 100 200 300 400 5000.0
0.2
0.4
0.6
0.8
1.0
Nor
mal
ised
Com
posi
tion
Depth (Å)
Si Fe Pd
0 100 200 300 400 5000.0
0.2
0.4
0.6
0.8
1.0
Nor
mal
ised
Pro
file
Depth (Å)
Structural Magnetic
![Page 23: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/23.jpg)
∂
PNR from a single layer
10-6
10-4
10-2
100
0 0.05 0.10 0.15
Qz[Å-1]
RE
FLE
CTI
VIT
Y
Courtesy Sean Langridge, ISIS
Directly proportional to mB.
![Page 24: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/24.jpg)
∂
Fe/Pd Example
![Page 25: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/25.jpg)
∂
Comparison of Profiles
• 1.4 and 0.5 ML profiles have the magnitude of the moments fixed by PNR.
• The spatial extent of the Fe moment increases with increasing δ-layer thickness but the induced moment extent remains approximately constant.
• Samples close to half integer coverage appear to induce a higher moment.
![Page 26: The Structure and Dynamics of Solids](https://reader036.vdocuments.site/reader036/viewer/2022081511/5a4d1aec7f8b9ab05997b387/html5/thumbnails/26.jpg)
∂
-8 -6 -4 -2 0 2 4 6 8
-15
-10
-5
0
5
10
15 165 K 215 K 252 K 272 K 296 K
F.R
(%)
Applied Field (mT)
-4 -3 -2 -1 0 1 2 3 4
-4
-2
0
2
4
6 205 K 218 K 235 K 252 K 283 K
F.R
(%)
Applied Field (mT)
Fe edge Pd edge
The remanent magnetisation is extracted by fitting each hysteresis loop to a pair of arctan functions:
Hysteresis Loops – 1.4ML Fe in Pd