the powder book - zirpro · 2020. 2. 21. · coatings, refractory parts, material for electronics,...

$: THE POWDER BOOK - ZirPro · 2020. 2. 21. · coatings, refractory parts, material for electronics, structural and conductive ceramics, decorative ceramic parts Fused and sintered$
T H E P O W D E R B O O K

Tabl

e of

con

tent

01 A b o u t Z i r P r o

• Introduction to ZirPro ..............................................2• Locations ...............................................................3• Manufacturing processes .........................................4• Selection guide ......................................................5

07M o n o c l i n i c z i r c o n i a g r a d e s

• ZirPro’s monoclinic ZrO2 offer ....................................6• Thermal ZrO2.........................................................7 - CC Zirconia ..................................................9 - CS Zirconia ................................................11 - CF Zirconia ................................................13• Chemical ZrO2 ......................................................8 - CZ/CZP Zirconia ........................................15 - CZE Zirconia ..............................................17

I N T R O D U C T I O N T O Z I R P R O

Saint-Gobain ZirPro manufactures and supplies zirconium-based beads, powders and grains for a wide variety of industrial applications

2

• ZirPro’s yttria-doped ZrO2 offer ..............................18 - Positioning of yttria-doped zirconia ................19 - CY3Z .........................................................21 - GY3Z-R60 ..................................................23 - CYnZ/GYnZ ...............................................25• Co-Doped alumina-toughened ZrO2 ........................26 - UprYZe-Shock .............................................27 - UprYZe-Intense ............................................28• Pigmented ZrO2 ...................................................29 - ColorYZe ...................................................29

18D o p e d - z i r c o n i a g r a d e s

31 • Monoclinic zirconia ..............................................31• Doped zirconia ....................................................32

Z i r P r o ’ s p o w d e r s p e c i f i c a t i o n s

Monoclinic and doped zirconia powders for applications in ceramic pigments, thermal barrier coatings, refractory parts, material for electronics, structural and conductive ceramics, decorative ceramic parts

Fused and sintered grinding beads for paints, inks & coatings, mineral pigments & fillers, ceramics, electronics & batteries, food, pharmaceutical & cosmetics, agrochemicals, pigments, dyes & dispersions, mining

Zr chemicals for automotive catalysis, paint-driers, antiperspirants, paper-coating, TiO2 pigments coating, leather tanning

Fused beads from 0 to 0.8mm for blast cleaning (tool cleaning, deburring, descaling), surface preparation, surface finishing (automotive, consumer electronics, sport goods), shot-peening(suspension springs, pinion gears, fan blades)

ZIRCONIUM OXIDE POWDERSZIRCONIUM OXIDE POWDERS

MICROGRINDING BEADS

ZIRCONIUM CHEMICALS

SURFACE TREATMENT MEDIA

43

F R A N C EL e P o n t e t

I TA L YM e z z o c o r o n a

U S AB o w, N H

U S AWo r c e s t e r , M A

B R A Z I LS ã o P a u l o

J A PA NO s a k a

Z I R P R O ’ S L O C AT I O N S M A N U FA C T U R I N G P R O C E S S E S A N D P R O D U C T S AT A G L A N C E

C H I N AH a n d a n

C H I N AS h a n g h a i

F R A N C EC a v a i l l o n

U N I T E D K I N G D O MS a i n t - H e l e n s

G E R M A N YK ö l n

S O U T H K O R E AS e o u l

MANUFACTURING PLANTS

• Le Pontet (France)

• Bow, NH (USA)

• Handan (China)

R&D CENTERS

• Cavaillon (France)

• Shanghai (China)

COMMERCIAL OFFICES

• Saint-Helens (United Kingdom)

• Köln (Germany)

• Mezzocorona (Italy)

• Worcester, MA (USA)

• São Paulo (Brazil)

• Shanghai (China)

• Seoul (South Korea)

• Osaka (Japan)

For contact details please see p.36

Z i r P r o P o w d e r s : 4 0 Ye a r s o f e x p e r i e n c e a t y o u r s i d e

M o n o c l i n i c T h e r m a l Z i r c o n i a : s t a n d a r d p u r i t y ( 9 7 % t o 9 9 . 5 % )

B O W ( U S A )L E P O N T E T ( F r a n c e )

PURIFICATION

CF10

CF02 CF02-LS

ELECTROFUSIONCHEMICAL TREATMENT

PLASMA FUSIONCHEMICAL TREATMENT Zircon sand

CS05

CS02

CS01

CC02

CC01

CS10

MILLINGMILLING

CC05

CC10 PURIFICATION

CF-Extra

PURIFICATION MILLING

MILLING

Zirpro offers the largest zirconia powder portfolio adressing the specificities of several markets such as aeronautics, automotive, electronics and telecommunications by providing stable and consistent supply of quality powders.

Thanks to Zirpro technical leadership, strong experience and market knowledge, our experts are able to recommend the right zirconia depending on your application or to co-develop products for new applications.

Coarse

L egend : Monoc l i n i c z i r con i a Doped Z i r con i a

Fine

C h e m i c a l Z i r c o n i a : h i g h p u r i t y ( > 9 9 . 9 % ) , m o n o c l i n i c a n d d o p e d p o w d e r s

H A N D A N ( C h i n a )

CZ/CZP lumps

CALCINATION

CHEMICAL REACTIONSDOPING

CALCINATION

FINE MILLING PIGMENTATION FINE MILLING

CHEMICAL REACTIONSCALCINATION

CZE

ZOC

BINDING

Monoclinic Zirconia Doped Zirconia

H A N D A N ( C h i n a ) *Some specialty grades are made in Europe (eg. UprYZe)

GYZ

BINDING

ColorYZe-G

CYZFine

ColorYZe

BINDING

UprYZe-G

FINE MILLING

UprYZeCYZ

MAIN APPLICATIONS OF ZIRPRO’S ZIRCONIA-BASED POWDERS, GRANULES AND FEEDSTOCKS

Applications

Products

Monoclinic thermal ZrO2 grades

Monoclinic chemical ZrO2 grades Doped-yttria ZrO2 grades UprYZe

ColorYZe (page 29)

CC(page 9)

CS(page 11)

CF(page 13)

CZ / CZP(page 15)

CZE(page 17)

CY3Z(page 21)

GY3Z(page 23)

CYnZ(page 25)

UprYZeShock

(page 27)

UprYZeIntense

(page 28)

Pigments for ceramic tile decoration

Stone polishing

Thermal barrier

coatings

Glass and gemstones

Refractrory parts (bricks,

foundry filters…)

Material for electronics (PZT, MLCC)

Functional filler/additive (polishing slurry,

composite...)

Structural ceramics

Dental

Decorative ceramic parts

Oxygen sensors

SOFC / OTM

6

: raw material for yellow MgPSZ - : raw material for white MgPSZ - : raw material for white MgPSZ or yttria-stabilized zirconia

5 6

M O N O C L I N I C Z I R C O N I A

M O N OC L I N I C

N I AZ I R C O

Selection guide

Applications

Products

ZirPro Chemical Zirconia GradesZirPro Thermal Zirconia Grades

Thermal zirconia grades are manufactured using ZirPro proprietary processes which combine zircon sand fusion and chemical treatments.

ZirPro offers three grades of thermal zirconia: CC, CS and CF. Thermal zirconia are manufactured in France for CC and CS grades and in the USA for CF grades.

Chemical zirconia grades are made by chemical route starting from zirconium oxychloride.

ZirPro offers two grades of chemical zirconia: CZ/CZP and CZE.All chemical grades are manufactured in ZirPro plant in China.

THERMAL ZIRCONIA GRADES OFFER HIGHER REACTIVITY THAN FUSED POWDERS THANKS TO THEIR UNIQUE DENDRITIC PARTICLE MORPHOLOGIES

CHEMICAL ZIRCONIA GRADES ARE HIGH PURITY POWDERS WHICH OFFER A BROAD RANGE OF PARTICLE SIZE DISTRIBUTION AND REACTIVITY

87

CC GRADESStandard thermal grades

CS GRADESPremium thermal grades,

purer version of CC Grades

CF GRADESMost reactive thermal grades

thanks to finer dendritic morphologies

3 µm 3 µm 3 µm

More info on page 9 More info on page 11 More info on page 13

*: ICP - **: Titration method - ***: Laser diffraction - ****: B.E.T. measurement*: ICP for CC/CS and XRF for CF - **: Sedigraph 5100 for CC/CS and Microtrac for CF - ***: B.E.T. measurement a: Does not include CF-Extra

Purity* (wt%)

D50** (µm) SSA*** (m²/g)ZrO2 + HfO2 SiO2 Na2O

CC 98.8 0.50 0.20 3.5 – 0.7 3.0 – 6.0

CS 99.0 0.10 0.02 3.5 – 0.6 1.5 – 6.5

CFa 99.0 0.10 – 0.40 0.05 7.0 – 1.0 4.5 – 7.5

ThermalZirconia Grades

Purity (wt%)D50*** (µm) SSA**** (m²/g)

ZrO2 + HfO2* CI**

CZ >99.9 <1000 2.5 – 25 5.0 – 8.0

CZP >99.9 <200 5.0 – 15 2.0 – 3.0

CZE >99.9 <200 0.4 – 0.7 6.0 – 25.0

Chemical Zirconia Grades

M A I N A P P L I C AT I O N S

• Thermal barriers coatings• Pigments for tile decoration• Material for electronics (PZT, MLCC)

• Magnesia-stabilized zirconia parts

• Refractory parts (bricks, foundry filters,...)

• Stone polishing

• Glass and gemstones


• Thermal barrier coatings (TSP, EBPVD ingot)

• Structural ceramics by co-milling (Mg-PSZ, Y-TZP)

• Materials for electronics (PZT, MLCC)

MONOCLINIC ZIRCONIA

More information on page 9






CZ / CZP GRADESHigh purity zirconia aggregates with a broad range of achievable particle size

CZE GRADESZirconia fine powders exhibiting

high reactivity and purity

1 µm

More info on page 15 More info on page 17

1 µm

T

herm

al Z

rO2

Purity

Reactivity

CF02-LS

CF-Extra

CF10 CF02

CC10 CC01CC02

CS10 CS01CS02

Purity

Particle size

CZP-15CZP-5

CZ-25CZ-3

CZE-S1CZE-M1

CZE-G1

CZ-5

• Foundry filters

• Functional filler/additive (polishing slurry, composite, ...)

• Oxygen sensors, fuel cells

C

hem

ical

ZrO

2

Thermal ZrO2

CC Zirconia

PA C K A G I N G

S A F E T Y D ATA S H E E T AVA I L A B L E O N R E Q U E S T

CC grades are thermal zirconia made by fusion of zirconium silicate at high temperature combined with chemical treatments. Thanks to ZirPro unique process, CC powders offer higher reactivity than fused zirconia.

CC powders offer a wide range of d50 and SSA:• D50 from 3.5 µm to 0.7µm• Typical specific surface areas from 3.0 to 6.0 m²/g

CC POWDERS SHOW HIGH REACTIVITY THANKS TOA UNIQUE DENDRITIC MORPHOLOGY

THE CC10 TYPICAL GRAIN MORPHOLOGY IS ROUNDISH AND MAINTAINED EVEN AFTER MILLING

CC grades are recommended for applications requiring pure thermal zirconia powders.

Industrially produced in France using the highest standards of production to ensure continuous supply and consistent quality.

• 25kg moisture proof paper bags

• 500kg, 1MT big-bags

Measured value (µm)

D50

CC10 3.5

CC05 1.5

CC02 0.9

CC01 0.6


D50

CC10 5.0

CC05 1.5

CC02 0.8

CC01 0.7

Th

erm

al Z

rO2 - C

C Z

ircon

ias

109

*: I.C.P. - **: Loss weight at 105°C - ***: Loss weight from 105°C to 1000°C

(1) Typical values. For product specifications please refer to page 31

C H E M I C A L A N A L Y S I S ( 1 )

PA R T I C L E S I Z E & S P E C I F I C S U R FA C E A R E A ( 1 )

*: Sedigraph 5100 - **: B.E.T. measurement

Particle size*(µm)Specific surface area** (m²/g) D10 (µm) D50 (µm) D90 (µm)

CC10 1.0 3.5 8.5 1.3 – 4.3

CC05 0.7 1.5 3.4 2.0 – 5.0

CC02 0.4 0.9 1.8 3.0 – 6.0

CC01 0.3 0.7 1.4 4.5 – 7.0

CC10 CC05Milling

Cumulative (%)

PSD by Laser (Horiba)

PSD by Sedigraph

diameter (µm)

diameter (µm)

PA R T I C L E S I Z E D I S T R I B U T I O N S E D I G R A P H V S . L A S E R

00,1

0,1

1

1

10

100

25

25

50

50

75

75

100

100

Cumulative (%)

MillingCC02

Ther

mal

ZrO

2 - C

C Z

ircon

ias

Chemistry* (wt%)L.O.I.***

(wt%)SiO2 Na2O Al2O3 TiO2 Fe2O3 CaO H2O**

CC10

0.50 0.20 0.10 0.10 0.04 0.03 0.10 0.20CC05

CC02

CC01

3 µm 3 µm 3 µm


• Thermal barrier coatings

• Pigments for ceramic tile decoration

• Refractory parts (bricks, foundry filters, ...)

• Stone polishing

• Glass and gemstonesThermal barrier coatingsPigments for ceramic tile decoration

Thermal ZrO2

CS Zirconia


PA C K A G I N G


CS grades are obtained through the purification of CC thermal zirconia leading to powders with increased purity together with a better control of the specific surface area (SSA).Similarly to CC grades, CS powders show zirconia particles with unique and uniform dentritic morphology offering higher reactivity than fused zirconia.

A large range of d50 and SSA is achievable:• D50 from 3.5µm to 0.6µm• Typical specific surface area from 1.5 to 6.5 m2/g

CS GRADES EXHIBIT SUPERIOR PURITY COMPARED TO CC GRADES

THE ROUNDISH GRAIN MORPHOLOGY IS CONSERVED AFTER MILLING

CS powders are used in applications requiring reactive premium grades of thermal zirconia with high level of purity.

Industrially manufactured in France using the highest standards of production to ensure continuous supply and consistent quality.

• Material for electronics (PZT, MLCC)

• Magnesia-stabilized zirconia ceramics (MgPSZ),

a ceramic composed of CS powders exhibits a

yellow color

• Refractory parts (bricks, foundry filters, ...)

• 25kg moisture proof paper bags


Sedigraph Typical value (µm)

D50

CS10 3.5

CS05 1.3

CS02 0.8

CS01 0.6

Laser Typical value (µm)

D50

CS10 4.3

CS05 1.4

CS02 0.7

CS01 0.6

Th

erm

al Z

rO2 - C

S Zi

rcon

ias

1211




*Sedigraph 5100 - **B.E.T. measurement


CS10 1.0 3.5 8.0 1.0 – 2.5

CS05 0.6 1.4 2.9 2.0 – 3.5

CS02 0.4 0.8 1.4 4.0 – 5.5

CS01 0.3 0.6 1.2 5.7 – 7.0

CS10 CS05Milling

Cumulative (%) PSD by Sedigraph

PSD by Laser (Horiba)

diameter (µm)

diameter (µm)

PA R T I C L E S I Z E D I S T R I B U T I O N S E D I G R A P H V S . L A S E R

00,1

0,1

1

1

10

100

25

25

50

50

75

75

100

100

Cumulative (%)

MillingCS02

Ther

mal

ZrO

2 - C

S Zi

rcon

ias

Medical application of PZT

Chemistry* (wt%)L.O.I.***

(wt%)SiO2 Na2O Al2O3 TiO2 Fe2O3 CaO H2O**

CS10

0.08 0.02 0.08 0.06 0.02 0.02 0.10 0.20CS05

CS02

CS01

3 µm 3 µm 3 µm

*I.C.P. - **Loss weight at 105°C - ***Loss weight from 105°C to 1000°C

Particle size* (µm)Specific surface area

(m²/g)**D10 D50 D90

CF10 0.8 7.0 35.0

CF02 0.5 1.0 5.5 4.5 – 7.5

CF02-LS 0.5 1.0 13.0

Thermal ZrO2

CF Zirconia


CF grades are thermal zirconia powders produced by the fusion of zirconium silicate using plasma arc followed by chemical treatments.The plasma technology enables achieving the highest reactivity among all thermal zirconia grades regardless of the particle size.

CF zirconia offers high specific surface area typically around 6 m²/g and particle size ranging from 7.0 to 1.0 µm.Soft agglomerates around 95µm are also available for specific applications (see CF grade on next page).

CF POWDERS EXHIBIT HIGHER REACTIVITY THAN CC GRADESTHANKS TO FINER DENDRITIC MORPHOLOGIES

CF powders are recommended for applications requiring pure thermal zirconia with high reactivity.

Manufactured in the USA using the highest standards of production to ensure continuous supply and consistent quality.

CF10 / CF02:

• Thermal barrier coatings

• Magnesia-stabilized zirconia ceramics (MgPSZ),

a ceramic composed of CF powders exhibits a yellow color

• Pigments for ceramic tiles decoration

• Refractory parts (bricks, ...)

• Stone polishing

CF02-LS:

• Material for electronics (PZT, MLCC)

• Magnesia-stabilized zirconia ceramics (MgPSZ)

Th

erm

al Z

rO2 - C

F Zi

rcon

ias

1413


PA C K A G I N G

S A F E T Y D ATA S H E E T AVA I L A B L E O N R E Q U E S T• 25kg moisture proof paper bags


Ther

mal

ZrO

2 - C

F Zi

rcon

ias

Thermal barrier coatings

CF GRADES FINE AND UNIFORM MICROSTRUCTURE IS CONSERVED AFTER MILLING

CF02 CF02-LSMilling Purification

CF10

3 µm

PA R T I C L E S I Z E & S U R FA C E A R E A ( 1 )

*Microtrac - **B.E.T. measurement


Chemistry* (wt%)L.O.I.** (wt%)SiO2 Na2O Al2O3 TiO2 Fe2O3 CaO

CF100.40 0.05 0.05 0.05 0.04 0.04 0.20

CF02

CF02-LS 0.10 0.05 0.05 0.05 0.03 0.03 0.20

*XRF - **Loss weight from 105°C to 1000°C

CF-Extra consists of soft agglomerates of zirconia powders with a typical d50 of 95μm.It is suitable for applications requiring high reactivity with lower purity requirements than CF10.Also the soft agglomeration brings some process benefits by increasing the powder flow ability.Other sizes of CF-extra ranging from 95 to 1 μm are available on request.CF-Extra is used, for example, for coral and pink pigment manufacturing.

CF-EXTRA IS AGGLOMERATED CF POWDERS

*Microtrac - **B.E.T. measurement


CF-EXTRA 1.3 95.0 <200 4.5 – 7.5

Chemistry* (wt%)L.O.I.** (wt%)SiO2 Na2O Al2O3 TiO2 Fe2O3 CaO

CF-EXTRA 0.90 0.05 0.20 0.10 0.05 0.05 0.30

*XRF - **Loss weight from 105°C to 1000°C

D50 of CF grades measured by laser (Horiba) are different from Microtrac measurements:CF-10=5.7µm ; CF02=1.2µm ; CF02-LS=0.6µm

3 µm 3 µm 3 µm

Chemical ZrO2

CZ/CZP Zirconia

PA C K A G I N G


CZ AND CZP ARE HIGH PURITY CHEMICAL ZIRCONIA POWDERS OFFERING A BROAD RANGE OF ACHIEVABLE PARTICLE SIZE DISTRIBUTION

CZ AND CZP POWDERS ARE MADE OF AGGREGATES OF VERY FINE ZIRCONIA PARTICLES

CZ and CZP grades are recommended for applications requriring high purity chemical zirconia powders such as found in aeronautics, electronics or automotive markets.

Industrially manufactured in Zirpro zirconia plant in China based on state-of-the-art industrial process.

• 25kg plastic drums

• 1MT big-bags

C

hem

ical

ZrO

2 - C

Z/C

ZP Z

ircon

ia

1615


C H E M I C A L A N A L Y S I S


*Laser diffraction - **B.E.T. measurement


D50

CZ-25 23.0

CZ-5 4.0

CZ-3 2.3

Che

mic

al Z

rO2 - C

Z/C

ZP Z

ircon

ia


• Thermal barrier coatings (TSP, EBPVD ingot)

• Magnesium-stabilized zirconia ceramics

(MgPSZ), a ceramic composed of CZ

or CZP powders exhibits a white color

• Foundry filters

• Glass and gemstones

• Polishing slurries

• High intensity pigments for ceramic

tile decoration

• Functional filler/additive

(polishing slurry, composite, ...) EB-PVD ingots

Chemistry* (ppm)

SiO2 Na2O Al2O3 TiO2 Fe2O3 Cl**L.O.I.***

(wt%)

CZ-3

<100 <50 <100 <50 <50 <1000 <1.0CZ-5

CZ-25

CZP-5<100 <50 <100 <50 <50 <200 <1.0

CZP-15

T Y P I C A L PA R T I C L E S I Z E D I S T R I B U T I O N B Y L A S E R

CZ and CZP grades are derived from zirconium oxychloride.

CZP grades are preferred for sensitive application due to its lower chlorine level (Cl < 200ppm) compared to CZ powders (Cl < 1000ppm).

Available particle size distribution ranges from 2.5 to 25µm. Other particle size is achievable on request. Pleace contact us!


CZ-3 1.0 2.5 <20.0 6.0 – 10.0

CZ-5 1.0 4.5 <20.0 4.0 – 8.0

CZ-25 3.0 25.0 <100 3.0 – 7.0

CZP-5 1.0 4.5 <20.0 1.0 – 5.0

CZP-15 1.0 15.0 <100 0.5 – 4.0

Cumulative (%)

diameter (µm)00,1 1 10 100

25

50

75

100


D50

CZP-15 13.1

CZP-5 4.0

* I.C.P. - **Titration method - ***Loss weight from 105°C to 1000°C

CZ grades

Cumulative (%)

diameter (µm)00,1 1 10 100

25

50

75

100

CZP grades

Other particle sizes from submicronic powders to dense and larger aggregates (lumps) are available on request (typical batch size 500kg to 5000kg). Do not hesitate to contacts us!

CZP-15

5 µm

CZP-5

5 µm

Chemical ZrO2

CZE Zirconia

Che

mic

al Z

rO2 - C

ZE Z

ircon

ia

17

CZE POWDERS ARE CHEMICALLY PROCESSED FINE ZIRCONIA GRADES COMBINING HIGH REACTIVITY AND PURITY

CZE grades are made by precipitation of zirconium oxychloridefollowed by a precise calcination and milling enabling an accurate control of the final powder reactivity.

Three grades of CZE with specific surface areas ranging from 6 to 25 m²/g are commercially available.Other specific surface areas and particle size are achievable on request (typical batch size: 500kg).




CZE-S1 0.1 0.4 <2.0 4 – 8

CZE-M1 0.1 0.4 <2.0 14 – 18

CZE-G1 0.1 0.7 <3.0 23 – 27

Foundry Filter


• Foundry filters

• Electronic ceramics: lead zirconate

titanate (PZT), multilayer ceramic

capacitors (MLCC), oxygen sensors,

fuel cells, oxygen transport membranes

• Structural ceramics by co-milling with: o Yttrium oxide to manufacture yttria-stabilized zirconia o Magnesium oxide to manufacture white magnesia-stabilized zirconia

• Fillers in composites Solid Oxide Fuel Cell (SOFC)


Chemistry* (ppm)

SiO2 Na2O Al2O3 TiO2 Fe2O3 Cl**L.O.I.***

(wt%)

CZE-S1 <200

<200

<200

<200

<100

<100

<50

<50

<50

<50

<100

<200

<0.5

<1.5CZE-M1

CZE-G1


PA C K A G I N G

• 25kg plastic drums

* I.C.P. - **Titration method - *** Loss weight from 105°C to 1000°C(1) Typical values. For product specifications please refer to page 31

CZE grades are the ideal choice for high-end applications requesting fine chemical zirconia powders with high level of purity such as encountered in electronics or automotive markets.

Industrially manufactured in China using state-of-the-art chemical and milling processes to ensure high and consistent level of quality.

18

Y T T R I A - D O P E D Z I R C O N I A

Y T T R I AD O P E D

N I AZ I R C O

ZirPro 3 mol% yttria-doped zirconia grades are produced using a chemical process.Different grades are available, depending on the ceramic processing method used:• CY3Z grades are recommended for the manufacturing of ceramics parts by casting, injection molding or additive manufacturing.• GY3Z grade is suitable for the fabrication of ceramic parts by uniaxial pressing or cold isostatic pressing.

All 3 mol% yttria-stabilized zirconia are manufactured in ZirPro’s plant in China.

ZIRPRO OFFERS 3MOL% YTTRIA-STABILIZED ZIRCONIA POWDERS (CY3Z) AND GRANULES (GY3Z) FOR THE MANUFACTURING OF HIGH PERFORMANCE CERAMIC PARTS

2019

YTTRIA-DOPED ZrO2 POWDERS AND GRANULES

Yttr

ia-D

oped

ZrO

2

500 nm


• High purity (>99.9%) powders with a strict control of particle size distribution

• Two grades are available:

CY3Z-R (7m²/g) and CY3Z-M (15m²/g). Both grades are available with or

without alumina addition (0.25wt%) for improved reactivity

• Suitable for casting, injection molding and additive manufacturing

• Enable to manufacture parts with high mechanical performance

D50* (µm) SSA**(m²/g)Y2O3 Al2O3

CY3Z-MA0.2 15 5.4 ±0.2

0.25 ± 0.05

CY3Z-MS <0.02

CY3Z-RA0.3 7 5.4 ±0.2

0.25 ± 0.05

CY3Z-RS <0.02


Purity*** (wt%)

*Laser diffraction - **B.E.T. measurement - ***XRF


20 µm


• Based on high purity (>99.9%) CY3Z-RA powders (7m²/g)

• Addition of 0.25wt% Al2O3 for improved reactivity

• Contain 3wt% of ZirPro advanced binder system

• Easy-to-press granules for uniaxial pressing and cold isostatic pressing (CIP)

• High flowability

*Laser diffraction - **Hall cup - ***XRF

Granule D50* (μm) Loose bulk density** (g/cm3)

Flowability** (g/s)Y2O3 Al2O3

GY3Z-R60 60 1.3 >0.85 5.4 ±0.2 0.25 ± 0.05

Purity*** (wt%)

CY3Z-MA / CY3Z-MS CY3Z-RA / CY3Z-RS GY3Z-R60

VALVES

PLUNGERS

BEARINGS

GRINDING MEDIA

WEAR-RESISTANT PART

OPTICAL FIBER CONNECTORS

DENTAL APPLICATIONS

BIOMEDICAL


Valve Optical fiber connectorsStructural ceramic parts Dental standard grades

Thanks to ZirPro’s versatile chemical process, grades containing yttria from 4 to 10 mol% are achievable.These grades enable to obtain high performance ceramics with tailored properties such as electronic, thermal conductivity or hydrothermal resistance.

Available as powder for casting (CYnZ) or as ready-to-press granules for pressing (GYnZ).

For more information please refer to page 25.

GRADES WITH OTHER YTTRIA CONTENT ARE ALSO AVAILABLE

CY3Z POWDERS

GY3Z READY-TO-PRESS GRANULES

Y

ttria

-Dop

ed Z

rO2

CY3Z GRADES ARE HIGH PERFORMANCE YTTRIA-DOPED ZIRCONIA POWDERS

CY3Z grades are easy-to-process powders recommended for applications requiring high performance ceramic parts.

Industrially manufactured in China using a state-of-the-art chemical process to ensure excellent performance and consistent high quality.

Yt

tria-

Dop

ed Z

rO2 - C

Y37

2221

PA C K A G I N G

• 25kg plastic drum S A F E T Y D ATA S H E E T AVA I L A B L E O N R E Q U E S T


• Technical ceramics:

optical fiber connectors, plungers,

valves, bearings, grinding media,

biomedical

CY3Z grades are 3 mol% yttria-stabilized zirconia powders made by chemical process.Their high purities (>99.9%) and the tight control of CY3Z powder physical characteristics enable the manufacturing high performance zirconia ceramic parts.

Two grades of CY3Z with different specific surface area are available: • CY3Z-R grade (SSA of 7m²/g) is used for the manufacturing of ceramic parts by injection molding, additive manufacturing or casting.• CY3Z-M grade with (SSA of 15m²/g) is recommended for the manufacturing of small size ceramic parts with fine microstructure by injection molding or additive manufacturing.

CY3Z-R and CY3Z-M are available without alumina (CY3Z-RS, CY3Z-MS) or with 0.25wt% alumina (CY3Z-RA, CY3Z-MA) for improved reactivity.

Yttri

a-D

oped

ZrO

2 - C

Y37

CY3Z-MA CY3Z-MS CY3Z-RA CY3Z-RS

Sintering Temperature (°C) 1350 – 2h 1400 – 2h 1450 – 2h 1500 – 2h

Density >6.05

Bending Strength (MPa)* 1000

Fracture Toughness (MPa.m0.5)** 5.5

Hardness (HV0.3/15)*** 1250

Hydrothermal resistance**** +++ ++ + =

*4 points bending MOR (ISO 6872) - **DCM (ISO 14627) - ***Vickers indentation (ISO 6507)****Ceramic part immersed in water at 135°C (5h - P=2bars)

C E R A M I C P R O P E R T I E S



Particle size*(µm) Specific surface area** (m²/g) Ceramic part features

D50 D90

CY3Z-MA0.2 <1.0 15 Fine ceramic microstructure

High hydrothermal resistanceCY3Z-MS

CY3Z-RA0.3 <1.0 7 Easy-to-process

High mechanical performanceCY3Z-RS

*Laser diffraction - ** B.E.T. measurement


Chemistry (wt%)

Al2O3* Y2O3* SiO2** Na2O** TiO2** Fe2O3**L.O.I.***

(wt%)

CY3Z-MA 0.25 ± 0.05

5.40 ± 0.20

<0.02 <0.02

<0.005 <0.005 <1.0CY3Z-MS <0.02

CY3Z-RA 0.25 ± 0.05

CY3Z-RS <0.02

*XRF method - **I.C.P. - ***Loss weight from 20 to 1000°C

CY3Z-M AND CY3Z-R GRADES ALLOW TO OBTAIN FINE MICROSTRUCTURE

Ceramic part based on CY3Z-MA powder Ceramic part based on CY3Z-RA powder

1 µm

Yttria-Doped ZrO2

CY3Z

1 µm

Structural ceramic parts Optical fiber connectors

GY3Z-R60 GRADE IS A READY-TO-PRESS POWDER ENABLING THE MANUFACTURING OF HIGH PERFORMANCE ZIRCONIA PARTS

GY3Z-R60 is recommended for manufacturing of high performance zirconia parts made by uniaxial pressing or cold isostatic pressing (CIP).

Industrially manufactured in China using a state-of-the-art chemical process to ensure excellent performance and consistent high quality.

Yt

tria-

Dop

ed Z

rO2 - G

Y3Z-

R60

2423

PA C K A G I N G

• 20kg plastic drum S A F E T Y D ATA S H E E T AVA I L A B L E O N R E Q U E S T


• Technical ceramics:

plungers, valves, bearings,

wear resistant part, biomedical

• Dental standard grades

GY3Z-R60 grade is made of 3 mol% yttria-stabilized zirconia ready-to-press granules produced by spray-drying of CY3Z-RA powderwith 3wt% binders.The high purity of GY3Z-R60 combined with its fine particle size distribution allow the manufacturing of zirconia part with high mechanical performance.

Thanks to its advanced binder system, GY3Z-R60 is an easy-to-press grade suitable for both uniaxial pressing and cold isostatic pressing (CIP).

Yttri

a-D

oped

ZrO

2 - G

Y3Z-

R60

GY3Z-R60

Green density* 3.0

Sintered density* (1450°C – 2hrs) ≥6.05

Bending strength (MPa)** 1000

Fracture Toughness (MPa.m0.5)*** 5.5

Hardness (HV0.5)**** 1250



C H E M I C A L & P H Y S I C A L A N A L Y S I S

Chemistry (wt%)

Y2O3* Al2O3* SiO2** Na2O** TiO2** Fe2O3**L.O.I.***

(wt%) SSA****(m²/g)

GY3Z-R60 5.40 ± 0.20 0.25 ± 0.05 <0.02 <0.02 <0.005 <0.005 2.5 – 3.5 6.0 – 8.0

*XRF method - **I.C.P. - ***Loss weight from 20 to 1000°C - ****B.E.T. measurement

G R A N U L E S P H Y S I C A L P R O P E R T I E S ( 1 )

Granule size* (µm) Loose bulk density** (g/cm3)

Flowability** (g/s)D50 D90

GY3Z-R60 60 <120 1.3 >0.85

*: Laser diffraction - **: Hall cup

20 µm

ZIRCONIA PARTS BASED ON GY3Z-R60 EXHIBIT A FINE AND NARROW GRAIN SIZE DISTRIBUTION

Average grain size: 0.3µm

1500°C – 2hrs 1530°C – 2hrs

Sintering temperature (°C)

1450°C – 2hrs

1 µm 1 µm 1 µm

Average grain size: 0.4µm Average grain size: 0.5µm

Yttria-Doped ZrO2

GY3Z-R60

*Uniaxial pressing 100MPa - **4-points MOR (ISO 6872) - ***DCM (ISO 14627) - ****Vickers indentation (ISO 6507)

GY3Z - R60 granules

Structural ceramic parts Dental standard grades

CYNZ AND GYNZ ARE STABILIZED ZIRCONIA WITH DIFFERENT AMOUNT OF YTTRIA FOR THE MANUFACTURING OF HIGH PERFORMANCE CERAMIC

CYnZ/GYnZ are recommended for applications requiring high performance ceramic with tailored properties (e.g. electronic and/or thermal conductivity).

Manufactured in China using state-of-the-art chemical process to ensure excellent performance and consistent high quality.Yt

tria-

Dop

ed Z

rO2 - C

YnZ/

GYn

Z

2625

CYnZ grades are yttria-stabilized zirconia powders made by chemical process. The high purity (>99.9%) and the possibility to tune the yttria content enable to obtain high performance ceramic with tailored properties such as electronic, thermal conductivity or hydrothermalresistance.Different level of alumina, typically from 0.25wt% to 5wt%, can be added to adjust the ceramic performance.

Available as dry sub-micron powders for casting (CYnZ), as well as granules with organic binders for pressing (GYnZ). Specific level of yttria and alumina are achievable on request (typical batch size 500-1000kg).

(1) Typical values


Yttria amount* Particle size** (µm) Specific surface area (m²/g)***

Strength****(MPa)

Ceramic feature obtained from CYnZ powderwt% mol% D50 D90

CY3Z 5.4 3 1000 Reference(cf. p.21)

CY4Z 7.1 4 1000 Increased hydrothermal stability

CY5Z 8.8 50.3 <1.0 5 – 9

> 500 O2 conductionThermal barrier properties

CY8Z 13.7 8 > 300 Highest electronic conductivity

*XRF - **Laser diffraction - ***B.E.T. measurement - ****3-pt bending strength


Chemistry (wt%)*

Y2O3 SiO2 Na2O Al2O3** TiO2 Fe2O3

L.O.I.*** (wt%)

CYnZ 5 – 15 <0.02

<0.02 0 – 5 <0.005 <0.005 ≤1.0

*XRF method for Al2O3 & Y2O3, ICP for the other - **Al2O3 amount can be tailored depending on the application***Loss weight from 20°C to 1000°C (for granules L.O.I. ~3wt%)

Yttria-Doped ZrO2

CYnZ/GYnZ


• O2 sensors

• Oxygen transport membranes (OTM)

• Solid oxide fuel cells (SOFC)

• Thermal barrier coatingsOxygen sensors


PA C K A G I N G

• 25kg plastic drums for CYnZ

• 20kg plastic drums for GYnZ

26

A D VA N C E D D O P E D - Z I R C O N I A

Discover ZirPro’s latest additions to its powder portfolio:

• UprYZe-Shock and its outstanding toughness

• UprYZe-Intense and its exceptional resistance to harsh conditions

• ColorYZe pigment zirconia grades designed for decorative applications

A D VA NC E D

D O P E D

N I AZ I R C O

UPRYZE-INTENSE IS CO-DOPED ALUMINA-TOUGHENED ZIRCONIA MATERIAL LEADING TO CERAMIC PART WITH HIGH RESISTANCE TO WEAR AND HYDROTHERMAL DEGRADATION

UprYZe-Intense is the ideal choice for ceramic parts subjected to high wear and/or humid conditions like found in food, medical or industrial applications.

Industrially produced using the highest standards of production to ensure continuous supply and consistent quality.

UprYZe-Intense grade is a co-doped alumina-toughened zirconia reinforced with alumina-based platelets.

Thanks to its tailored composition and unique microstructure, UprYZe-Intense provides: • A wear resistance equivalent to best-in class alumina-toughened zirconia• No hydrothermal degradation even in very harsh environment.

UprYZe-Intense is offered either as a dry powder (UprYZe-Intense) for injection molding or casting or as ready-to-press granules (UprYZe-Intense G) for uniaxial pressing or CIP.


Powder particle size* (µm)D50

Granules size* (µm)D50

Specific surface area** (m²/g)

UprYZe-Intense 0.2 / 8.5

UprYZe-Intense G 0.2 60 8.5


*Laser diffraction - **B.E.T. measurements


Chemical analysis* (wt%)

Y2O3 + CeO2 Al2O3 SiO2 Na2O Fe2O3 TiO2

L.O.I.** (wt%)

UprYZe-Intense10.5± 0.7 25± 1.0 <0.02 <0.02 <0.005 <0.005

≤1.0

UprYZe-Intense G 2.5 - 3.5

*XRF for Y2O3, CeO2 and Al2O3, ICP for the remaining other elements - **Loss weight between 20°C and 1000°C

Co-Doped Alumina-Toughened ZrO2

UprYZe-Intense

Density Wear resistance*(mm3)

Hydrothermal resistance**

Bending strength***(MPa)

Hardness**** (HV05)

UprYZe-IntenseUprYZe-Intense G ≥ 5.38 0.01

Part remains intact after 24h in water at 250°C/40bars

800 1450


*Abrasion test (ASTM G174) - **After ageing 24hrs in water at 250°C/40bar - ***3 points bending (NF EN843-1) - ****Vickers indentation (ISO 6507)


• Pump components

• Ceramic parts for food industry

• Wire drawing

• Can toolings


PA C K A G I N G

• 20kg cardboard box

UPRYZE-SHOCK IS A CO-DOPED ALUMINA-TOUGHENED ZIRCONIA MATERIAL ALLOWING TO ACHIEVE CERAMIC PARTS WITH OUTSTANDING TOUGHNESS AND SHOCK RESISTANCE

UprYZe-Shock is suitable for applications demanding high toughness and/or shock resistance such as, for instance, encountered in automotive or oil & gas sectors.

Industrially produced using the highest standards of production to ensure continuous supply and consistent quality.

C

o-D

oped

Alu

min

a-To

ughe

ned

ZrO

2/ U

prYZ

e-Sh

ock

2827

UprYZe-Shock grade is a co-doped alumina-toughened zirconia reinforced with alumina-based platelets.Based on a specifically engineered composition and a unique microstructure, UprYZe-Shock provides outstanding mechanical performance: • Toughness of 15MPa.m0.5

• Bending strength of 1000MPa• Improved impact resistance: +50% vs. CY3Z type grade.

UprYZe-Shock is proposed either as a dry powder (UprYZe-Shock) for injection molding or casting or as ready-to-press granules (UprYZe-Shock G) for uniaxial pressing or CIP.

Co-

Dop

ed A

lum

ina-

Toug

hene

d Zr

O2/

Upr

YZe-

Inte

nse


Powder particle size* (µm)D50

Granules size* (µm)D50


UprYZe-Shock 0.2 / 8.5

UprYZe-Shock G 0.2 60 8.5


*Laser diffraction - **B.E.T. measurements


Chemical analysis* (wt%)

Y2O3 + CeO2 Al2O3 SiO2 Na2O Fe2O3 TiO2

L.O.I.** (wt%)

UprYZe-Shock6 ± 0.7 15 ± 1.0 <0.02 <0.02 <0.005 <0.005

≤1.0

UprYZe-Shock G 2.5 - 3.5

*XRF for Y2O3, CeO2 and Al2O3, ICP for the other elements - **Loss weight between 20°C and 1000°C

Co-Doped Alumina-Toughened ZrO2

UprYZe-Shock

Density*Fracture

toughness KIC**(MPa.m1/2)

Bending strength***(MPa)

Hardness****(HV05)

UprYZe-ShockUprYZe-Shock G ≥ 5.64 15 1000 1300


*1450°C for 2hrs in air - **DCM (ISO 14627) - ***3 points bending (NF EN843-1) - ****Vickers indentation (ISO 6507)


• Welding and locating pins

• Kitchen knives

• Advanced structural ceramics

• Ceramic parts in consumer goods Ceramic welding pins


PA C K A G I N G

• 20kg cardboard box

Pump components

Pigmented ZrO2

ColorYZe

COLORYZE ARE PIGMENTED ZIRCONIA POWDERS FOR THE MANUFACTURING OF COLORED CERAMICS

ColorYZe zirconia is used for the manufacturing of decorative advanced ceramics combining outstanding color and gloss, high mechanical strength, superior scratch resistance as well as greater durability.

ColorYZe are manufactured using the highest standards of production to ensure continuous supply and consistent quality.

Pi

gmen

ted

ZrO

2 - C

olor

YZe

3029

PA C K A G I N G

• 20kg cardboard box,

with inner plastic bagsS A F E T Y D ATA S H E E T AVA I L A B L E O N R E Q U E S T


• Watch and jewelry parts

• Electronic device components

(smartphones…)

• Household equipment

• Automotive interior parts

ColorYZe powders are based on high purity Y2O3 doped zirconia.Several colors are available using specific pigmentation systems.

Available as dry submicronic powders for injection molding andcasting (ColorYZe), as well as granules with organic binders for pressing (ColorYZe-G).



Powder particle size* (µm) D50

Granules size* (µm) D50


ColorYZe 0.25 / 7

ColorYZe-G 0.25 60 7


Form Zirconia powder Pigmentation system (wt%)

Binder content(wt%)

ColorYZe dry powder 3mol% Y2O3 stabilized ZrO2

1 – 5 (*) /

ColorYZe-G granules with binders 3mol% Y2O3 stabilized ZrO2

1 – 5 (*) 3

(*) depends on the ColorYZe grade - Final color

Pigm

ente

d Zr

O2 - C

olor

YZe

The final properties of ceramics depend on the pigmentation system.

Sintering temperature* (°C)

Bending strength**(MPa)

Hardness***(HV05)

Fracture Toughness K1C****

(MPa.m1/2)

ColorYZeColorYZe-G 1450 – 1600 >900 1200 – 1400 5.5

*Specific sintering recommendations are provided for each ColorYZe grade - **3 points bending (NF EN843-1)***Vickers indentation - ****DCM (ISO 14627)

A S TA N D A R D PA L E T T E O F C O L O R S

T Y P I C A L P R O P E R T I E S O F F I N A L C E R A M I C S

ColorYZe-Sky Blue

ColorYZe-Snow White

ColorYZe-Navy Blue

ColorYZe-Arctic White

ColorYZe-Night Blue

ColorYZe-Light Grey

ColorYZe-Dark Grey

Above colors may differ from real colors.Additional colors can be developed, upon request, in the frame of specific co-development projects. Please contact us!

ColorYZe-Purple

ColorYZe-Chocolate


ColorYZe zirconia are available in standard color references

Black zirconia watchZirconia kitchen knife

ColorYZe-Black

3231

S p e c i f i c a t i o n s t a b l e

Y T T R I A - D O P E D Z r O 2

Particle size (µm)a Specific Surface Areab

(m²/g)

Chemistryc (wt%) LOId(wt%)

D50 D90 Al2O3 Y2O3 SiO2 Na2O TiO2 Fe2O3

CY3Z-MA 0.25 ± 0.05

CY3Z-MS0.20 ± 0.10 < 1.5 15.0 ± 2.0

<0.025.40 ± 0.20 <0.02 <0.02 <0.005 <0.005 <1.0

CY3Z-RA 0.25 ± 0.05

CY3Z-RS0.30 ± 0.10 < 1.5 7.0 ± 2.0

<0.025.40 ± 0.20 <0.02 <0.02 <0.005 <0.005 <1.0

a : Laser diffraction - b : B.E.T. measurement - c : XRF for Al2O3 and Y2O3 and ICP for the other elements - d : Lost weight from 105°C to 1000°C

C o l o r Y Z e

U p r Y Z e

Particle size (µm)a Specific Surface

Areab (m²/g)


D50 D90 Al2O3Y2O3 + CeO2

SiO2 Na2O TiO2 Fe2O3

UprYZe- Shock 0.20 ± 0.10 <1.0 15.0 ± 1.0 6.0 ± 0.7 <0.02 <0.02 <0.005 <0.005 <1.0

UprYZe-Intense 0.20 ± 0.10 <1.0

8.5 ± 1.025 ± 1.0 10.5 ± 0.7 <0.02 <0.02 <0.005 <0.005 <1.0

UprYZe- Shock G

60 ± 10(granules)

<120(granules) 15.0 ± 1.0 6.0 ± 0.7 <0.02 <0.02 <0.005 <0.005 3.0 ± 0.5

UprYZe- Intense G

60 ± 10(granules)

<120(granules)

8.5 ± 1.025 ± 1.0 10.5 ± 0.7 <0.02 <0.02 <0.005 <0.005 3.0 ± 0.5

a : Laser diffraction - b : B.E.T. measurement - c : XRF for Al2O3, Y2O3 and CeO2, ICP for the other elements - d : Lost weight from 20°C to 1000°C

Granule size

(µm)aSpecific Surface Areab (m²/g)


Loose bulk

densitye

(g/cm3)

Flowabilitye

(g/s)D50 D90 Al2O3 Y2O3 SiO2 Na2O TiO2 Fe2O3

GY3Z-R60 60 ± 10 <120 7.0 ± 2.0 0.25 ± 0.05 5.40 ± 0.20 <0.02 <0.02 <0.005 <0.005 3.0 ± 0.5 1.3 ± 0.1 > 0.8

a : Laser diffraction - b : B.E.T. measurement - c : XRF for Al2O3 and Y2O3 and ICP for the other elements - d : Lost weight from 20°C to 1000°C - e : Hall cup

Particle size (µm)a Specific Surface Areab (m²/g)


D50 D90 Al2O3 Y2O3Pigment system SiO2 Na2O TiO2

ColorYZe- R-Black

0.30 ± 0.05 <1.0 7.0 ± 1.0 1.0 ± 0.1 5.20 ± 0.20 4.0 ± 0.2 <0.02 <0.02 <0.005 <1.0

ColorYZe- Black-G

60 ± 10(granules)

<120(granules) 7.0 ± 1.0 1.0 ± 0.1 5.20 ± 0.20 4.0 ± 0.2 <0.02 <0.02 <0.005 3.0 ± 0.5

a : Laser diffraction - b : B.E.T. measurement - c : XRF for Al2O3 and Y2O3 and ICP for the other elements - d : Lost weight from 20°C to 1000°C

S p e c i f i c a t i o n s t a b l e

M O N O C L I N I C T H E R M A L Z r O 2 G R A D E S

Particle size (µm)a

Specific Surface

Areab (m²/g)

Chemistryc (wt%) LOIe(wt%)

D50 D90 SiO2 Na2O Al2O3 TiO2 Fe2O3 CaO H2Od

CC10 3.5 ± 0.8 ≤11.0 1.3 – 4.3

CC05 1.5 ± 0.4 ≤5.0 2.0 – 5.0

≤1.00 ≤0.50 ≤0.20 ≤0.20 ≤0.10 ≤0.10 ≤0.30 ≤0.50CC02 0.9 ± 0.3 ≤3.0 3.0 – 6.0

CC01 0.7 ± 0.2 ≤3.0 4.5 – 7.0

CS10 3.5 ± 0.7 ≤9.0 1.0 – 2.5

CS05 1.4 ± 0.4 ≤4.0 2.0 – 3.5

≤0.15 ≤0.05 ≤0.20 ≤0.15 ≤0.03 ≤0.05 ≤0.30 ≤0.50CS02 0.8 ± 0.3 ≤2.0 4.0 – 5.5

CS01 0.6 ± 0.2 ≤2.0 5.7 – 7.0

CF-Extra 94 ± 30 ≤220 4.5 – 7.5 ≤1.1 ≤0.10 ≤0.30 ≤0.15 ≤0.10 ≤0.10 - ≤0.50

CF10 7.0 ± 3.0 ≤45.04.5 – 7.5 ≤0.60 ≤0.10 ≤0.10 ≤0.10 ≤0.10 ≤0.10 - ≤0.50

CF02 1.0 ± 0,6 ≤6.5

CF02-LS 1.0 ± 0.4 ≤19.0 4.5 – 7.5 ≤0.15 ≤0.10 ≤0.10 ≤0.10 ≤0.10 ≤0.10 - ≤0.50

a : Sedigraph 5100 for CC/CS, Microtrac for CF - b : B.E.T. measurement - c : ICP for CC/CS, XRF for CF - d : Lost weight at 105°C e : Lost weight from 105°C to 1000°C

M O N O C L I N I C C H E M I C A L Z r O 2 G R A D E S

Particle size (µm)a

Specific Surface

Areab (m²/g)

Chemistryc (ppm) LOId(wt%)

D50 D90 SiO2 Na2O Al2O3 TiO2 Fe2O3 CI

CZ-3 2.5 ± 1.0 <20.0 7.0 – 11.0

CZ-5 4.5 ± 1.0 <20.0 4.0 – 8.0 <100 <50 <100 <50 <50 <1000 <1.0

CZ-25 25.0 ± 5.0 <110 3.0 – 7.0

CZP-5 4.5 ± 1.0 <20.0 1.0 – 5.0

CZP-15 16.5 ± 3.5 <100 0.5 – 4.0

<100 <50 <100 <50 <50 <200 <1.0

CZE-S1 4.0 – 8.0 <200 <100 <0.5

CZE-M10.4 ± 0.1 <2.0

14.0 – 18.0 <200<300

<100 <50 <50<200

<1.5

CZE-G1 0.7 ± 0.2 <3.0 20.0 – 30.0 <1.5

a : Laser diffraction b: B.E.T. measurement - c : ICP to the exception of Cl by titration method - d : Lost weight from 105°C to 1000°C

SAINT-GOBAIN MATERIAIS CERAMICOSAv. Santa Marina, 482Água Branca, São PauloSP, 02675-031, BrazilTel: +55 11 99211 [email protected]

SAINT-GOBAIN ZIRPRO8th Floor, KFAS BD, Teheran-ro 211, Gangnam-gu, Seoul, 06141, South KoreaTel: +82 2 3706 9575/[email protected]

SEPR SAINT-GOBAIN ZIRPRO SHANGHAI OFFICEUnit 08 &09 of F18 and whole F17, Shanghai Point, No.1158 East Da Ming Rd, Shanghai 200082, P.R. [email protected]: +86 21 5552 [email protected]

SAINT-GOBAIN K.K.Kitahama 1-Chome Heiwa Bldg,1-1-14, Kitahama, Chuo-ku, Osaka, 541-0041 JapanTel: +81 (0) 6 4707 [email protected]

SAINT-GOBAIN ZIRPRO UKMill Lane, Rainford, St HelensUnited Kingdom, WA11 8LPTel: +44 (0) 77 952 00 [email protected]

SEPR ITALIA S.P.A. Via del Teroldego, 1/F38016 Mezzocorona TN, ItalyTel: +39 0461 61 67 [email protected]

SEPR KERAMIK GMBH & CO. KGConcordiaplatz 3 – D-51143 KölnGe rmanyTel: +49 (0) 2203-956 [email protected]

SAINT-GOBAIN ZIRPRO1 New Bond St, Worcester, MA01606, USATel: + 508 981 [email protected]

SEPR - SAINT-GOBAIN ZIRPROB.P. 60025 - Bâtiment L - 2539, route de Sorgues

84131 Le Pontet Cedex - [email protected]: +33 4 90 32 70 02

www.zirpro.com

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the powder book - zirpro · 2020. 2. 21. · coatings, refractory parts, material for electronics,...

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