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The Lower–Middle Jurassic of the Anholt borehole:implications for the geological evolution of the easternmargin of the Danish Basin

Ole B. Nielsen, Marit-Solveig Seidenkrantz, Niels Abrahamsen, Birthe J. Schmidt, Eva B. Koppelhus,Helle Ravn-Sørensen, Uffe Korsbech and K. Gynther Nielsen

This study of Upper Pliensbachian – Bajocian/Bathonian deposits in a borehole drilled on the islandof Anholt, Denmark incorporates sedimentology, biostratigraphy (palynomorphs and foraminifera),palaeomagnetism and coal petrology. The studied succession records a gradual change from marineinner shelf storm-influenced clays to mainly terrestrial sands, clays, and lignite containing a flora ofmainly freshwater algae and pollen. The regression was initiated at the Pliensbachian–Toarcianboundary and marine influence ceased during Bajocian–Bathonian times; the regression thus tookplace earlier at Anholt than in the centre of the Danish Basin. The sediments in the Anholt boreholeare referred to the Fjerritslev and Haldager Sand Formations. Although the Lower–Middle Jurassicboundary is commonly placed at the boundary between the two formations, our data indicate thatat Anholt the upper Fjerritslev Formation (member F-IV) is of Aalenian age. The Lower–Middle Jurassicboundary occurs close to the boundary between members F-III and F-IV of the Fjerritslev Formation.

In contrast to other Lower–Middle Jurassic successions in the North Sea region, smectites ofinferred volcanic origin are preserved in the Anholt section, suggesting limited burial and henceless intense diagenetic illitisation or chloritisation of smectites. A down-hole increase in diagen-etic influence is reflected by the increase down-section both in the thermal stability of kaoliniteand in the vitrinite reflectance. Kaolinite of inferred authigenic origin forms a white powder inthe quartz-dominated sands of the Haldager Sand Formation; this kaolinite is thermally veryunstable and is interpreted to be of late diagenetic, post-uplift origin. The vitrinite reflectancedata indicate that the Jurassic formations have been exposed to thermal maturation correspond-ing to burial to a depth of 1000–1200 m below their present depth. Post-maturation uplift of theorder of 1 km probably occurred partly during Late Cretaceous – Paleocene inversion in the Kattegatarea and partly during Oligocene–Recent regional uplift, the latter being the most important ofthe two uplift phases. Palaeomagnetic data indicate that the main carrier of magnetic remanenceis fine-grained magnetite. The stable remanence shows a pronounced inclination shallowing, whichis attributed to post-depositional compaction.

Keywords: Danish Basin, Fennoscandian Border Zone, Lower–Middle Jurassic, Anholt borehole, biostratigraphy,

palaeomagnetics, sedimentology, clay mineralogy, organic petrology, geochemistry

O.B.N. & M.-S.S., Department of Earth Sciences, University of Aarhus, C.F. Møllers Allé, DK-8000 Århus C, Denmark.

E-mail: geololen@aau.dk

N.A., Department of Earth Sciences, University of Aarhus, Finlandsgade 6–8, DK-8200 Århus N, Denmark.

B.J.S., Statoil, Exploration Division, Forushagen, N-4035 Stavanger, Norway.

E.B.K., Geological Survey of Denmark and Greenland, Geocenter Copenhagen, Øster Voldgade 10, DK-1350 Copenhagen

K, Denmark. Present address: Royal Tyrrell Museum of Palaeontology, Box 7500, Drumheller T0J 0Y0, Alberta, Canada.

H.R.-S., Samfundsteknik A/S, Vesterballevej 4–6, Fredericia Miljøcenter, DK-7000 Fredericia, Denmark. Present address:

Bascon A/S, Åboulevarden 21, P.O. Box 510, DK-8100 Århus C, Denmark.

U.K. & K.G.N.*, Ørsted-DTU, Building 327, Technical University of Denmark, DK-2800 Lyngby, Denmark. *Retired.

Geological Survey of Denmark and Greenland Bulletin 1, 585–609 (2003) © GEUS, 2003

586

During Early and Middle Jurassic times, a major depo-sitional basin, the Danish Basin, extended across mostof Denmark and into the modern North Sea. It wasdemarcated by the Baltic Shield to the north and north-east and by the Ringkøbing–Fyn High to the south, andwas linked with the Danish–Polish Trough to the south-east (Sorgenfrei & Buch 1964; Michelsen 1978; Libor-iussen et al. 1987). Previous studies have shown thatthe upper part of the Lower Jurassic Fjerritslev Formationwas characterised by a transgressive phase followedby a regressive phase, from open marine conditionsduring the Pliensbachian – Early Toarcian to a morerestricted marine setting during the Late Toarcian(Michelsen 1978, 1989a). During the Middle Jurassic, theprograding deltaic or braided river sediments of theHaldager Sand Formation were deposited in the north-eastern part of the basin (Michelsen 1978, 1989b; Koch1983; Michelsen et al. 2003, this volume).

This study presents a Lower–Middle Jurassic sectionfrom a 306 m deep borehole, drilled in 1990 on Anholt,a small Danish island in the centre of the Kattegat(Fig. 1). During the Jurassic, Anholt was situated nearthe eastern margin of the Danish Basin. A compositesection was attained by means of three boreholes,Anholt II, III, and IV, spaced less than 20 m apart. Onlythe latter two extended into Jurassic sediments. Theboreholes penetrated 104 m of Quaternary sedimentsbefore reaching the Jurassic. The drilling site has an ele-vation of about 2 m above present-day sea level. Alldepths noted are referred to this point.

The aims of the study were to evaluate the age, thepalaeoenvironmental setting and the post-depositionalhistory of the Jurassic succession. To achieve this goal,studies were carried out in biostratigraphy, sediment-ology, coal petrography, and palaeomagnetism. Thematerial from 104–230 m consists largely of ditch cut-

Kattegat

Sweden

Anholt

Jylland Denmark

Uglev-1

Frederikshavn City-1

Skagen-3

50 km

2 km

8°E

57°N

55°N

12°E

Terne-1

Gassum-1Hobro-1

Stenlillewells

Bornholm

Skåne

Skagerrak

Ringkøbing–

Fyn High

Danish Basin

Skagerrak–Kattegat Platform

Sorgenfrei–TornquistZone

DPT

Øresund

Well

Normal fault

Areas of Late Cretaceousand Early Tertiary inversion

Basement high

Børglum-1

Fig. 1. Map showing the structural outline of the Fennoscandian Border Zone (Sorgenfrei–Tornquist Zone and Skagerrak–KattegatPlatform) and the Danish Basin, and the location of boreholes and outcrops mentioned in the text (structural outline from Petersenet al. 2003, this volume). The inset map of Anholt shows the location of the investigated borehole. DPT, Danish–Polish Trough.

587

tings, together with the few available core samples,whereas the samples from below 230 m are all core sam-ples (Fig. 2). Below 250 m, core recovery was almost100%, whereas the interval above 250 m is only repre-sented by few, incomplete cores. The latter cores seemmainly to represent clay or silt-rich lithologies, whereas

levels with sand are less commonly represented, andprimary sedimentary structures might have beendestroyed. In ditch cuttings samples, the proportion ofclay-sized particles is probably under-represented, aspart of the only slightly consolidated clay-rich layers wasincorporated with the drilling fluid during coring.

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phyFig. 2. Chronostratigraphy, biostratigraph-

ical zonation, total organic carbon (TOC)content, and reworked palynomorphs ofthe lower 200 m of the Anholt borehole(slightly modified from Seidenkrantz etal. 1993). Quat., Quaternary; m b.s.,metres below surface.

BiostratigraphyThe age of the sediments is based on the biostrati-graphical analysis. This part of the study has been pre-viously reported in detail (Seidenkrantz et al. 1993) andhere we only present a synopsis of that study. Thepreparation of the samples was undertaken using stan-dard techniques (Meldgaard & Knudsen 1979; Dybkjær1988; Poulsen et al. 1990) and the analysis resulted inthe establishment of four palynological and four ben-thic foraminiferal zones (Fig. 2).

MicrofaunaForaminifera are only present in the lower part of thesection and cannot be correlated with faunas from otherdeposits in the region. With the exception of the low-ermost zone (FA), the assemblages almost exclusivelyconsist of agglutinated species (Seidenkrantz et al. 1993),whereas Jurassic foraminiferal assemblages in sur-rounding areas are dominated by calcareous species,mainly nodosarids (Nørvang 1957; Bang 1968a, b, 1971,1973; Norling 1972). In general, the foraminiferal assem-blages have a very low diversity and several samplesare barren. The lower foraminiferal zone (FA) mainlycontains nodosarid genera such as Astacolus andPlanularia. The deposit also contains ammonite frag-ments, bivalves, and gastropods. In contrast, Zone FB(304–288 m) is dominated by the agglutinated generaAmmobaculites, Bulbobaculites, Kutsevella, and Haplo-phragmoides. The fauna of Zone FC is essentiallyrestricted to one species of Ammobaculites, whereasZone FD yields Ammobaculites, Bulbobaculites and afew Kutsevella (Seidenkrantz et al. 1993). The foramini-fera are of a Boreal affinity not previously found thisfar to the south (Nagy & Seidenkrantz in press).

PalynologyThe palynomorph assemblages allow close correlationto other sections from Denmark, Germany, and Britain(Fig. 3; Schulz 1967; Lund 1977; Bertelsen 1979; Woollam& Riding 1983; Hoelstad 1985; Dybkjær 1991; Riding &Thomas 1992; Koppelhus & Nielsen 1994; Koppelhus& Batten 1996).

Palynomorph Zone PA

Based on the presence of Nannoceratopsis spp.,Luehnda spinosa Morgenroth 1970, and Mendicodiumreticulatum Morgenroth 1970. This assemblage corre-lates well with Zone C3 in the Hobro-1 borehole in cen-tral Jylland (Bertelsen 1979) and the top of the Cere-brocellenites macrooverrucosus Zone in the Gassum-1borehole in central Jylland (Dybkjær 1991) from theDanish Basin and with the Luehndea spinosa Zone inthe British part of the North Sea (Riding & Thomas1992). Further possible correlations are with the Luehndaspinosa Zone and the uppermost ChasmatosporitesZone, both from the Bagå Formation of Bornholm(Koppelhus & Nielsen 1994) in the Danish–Polish Troughand from the Rya Formation in the Øresund area (Fig. 3;Koppelhus & Batten 1996). Recent palynological studyof the Neill Klinter Group, Jameson Land, East Greenland(Koppelhus & Dam 2003, this volume) permits corre-lation of Zone PA from Anholt with Assemblage Zone2 of the Neill Klinter Group at the Albuen section. Thecombined evidence suggests a Late Pliensbachian agefor Zone PA.

Palynomorph Zone PB

Based on the acme of Spheripollenites together withCorollina, Ischyosporites variegatus (Couper) Schulz1967 and Manumia delcourtii (Pocock) Dybkjær 1991.The zone is correlated with Zone C4 from the Hobro-1borehole (Bertelsen 1979) and the Spheripollenites–Leptolepidites Zone in the Stenlille boreholes (Dybkjær1991) of the Danish Basin. It can also be correlatedwith Zone I of the Bagå Formation (Hasle Klinkerfabrikclay pit of Bornholm; Hoelstad 1985) and the Nanno-ceratopsis gracilis and Spheripollenites–LeptolepiditesZones from the Bagå Formation (Korsodde section,Bornholm; Koppelhus & Nielsen 1994) in the Danish–Polish Trough. The Spheripollenites–Leptolepidites Zoneis also known from the Rya Formation in the Øresundarea (Koppelhus & Batten 1996) and from AssemblageZone 5 in the Neill Klinter Group in East Greenland(Koppelhus & Dam 2003, this volume). The age is con-sidered to be Toarcian.

Palynomorph Zone PC

Based on abundant Perinopollenites elatoides Couper1958 together with Callialasporites turbatus (Balme)

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Dev 1961, Nannoceratopsis gracilis Alberti emend. vanHelden 1977, and Nannoceratopsis senex van Helden1977. This palynomorph assemblage correlates with thePerinopollenites elatoides Zone from the Stenlille bore-holes in the Danish Basin (Dybkjær 1991), Zone II fromthe Bagå Formation at the Hasle Klinkerfabrik clay pit,Bornholm (Hoelstad 1985) and the lower part of theCallialasporites–Perinopollenites Zone from the BagåFormation in Borehole 107 and the Korsodde section,Bornholm (Koppelhus & Nielsen 1994). The zone isalso recognised in the Rya Formation in the Øresundarea (Fig. 3; Koppelhus & Batten 1996) and fromAssemblage Zone 6 in the Neill Klinter Group, EastGreenland (Koppelhus & Dam 2003, this volume). Thiscorrelation suggests an Aalenian age for Zone PC.

Palynomorph Zone PD

Characterised by Perinopollenites elatoides, Calliala-sporites turbatus, C. dampieri (Balme) Dev 1961, C.microvelatus Schulz 1966, C. minus (Tralau) Guy 1971,Densoisporites scanicus Tralau 1968, Neoraistrickiagristhorphensis (Couper) Tralau 1964, Sestrosporitespseudoalveolatus (Couper) Dettmann 1963, Gleichenii-dites conspiciendus (Bolchovitina) Krutzsch 1959, andG. senonicus Ross 1949. This assemblage suggests acorrelation with Zone D in Hobro-1 (Bertelsen 1979),with Zone III from the Bagå Formation (HasleKlinkerfabrik clay pit; Hoelstad 1985), and with theupper part of the Callialasporites–Perinopollenites Zone,also from the Bagå Formation on Bornholm (Bagå beds,section 1; Koppelhus & Nielsen 1994). The age of theassemblage is considered to be Middle Jurassic, prob-ably within the Bajocian/Bathonian interval.

Palaeomagnetic studiesThe continuous record of palaeomagnetic anomaliesderived from the deep-sea record only reaches back tothe late Middle Jurassic (base of M29 of the top Callovian;Harland et al. 1990). Older reversal chronology there-fore relies upon palaeomagnetic polarity studies of indi-vidual stratigraphical sections (Ogg et al. 1984; Steineret al. 1985, 1987; Gradstein et al. 1994). The aim of thepresent palaeomagnetic study was to contribute to thegradually increasing knowledge of reversals in Mesozoictimes. This palaeomagnetic study is the first of its kindin the Danish area, as previous studies from the areafocussing upon pre-Quaternary strata are few (e.g.Abrahamsen 1994; Ali et al. 1994), and none of thesewere from the Jurassic.

Magnetic methods and resultsA total of 122 samples were collected for magnetic stud-ies from the cored sections in Anholt III and IV. Thesamples were obtained by pressing one-inch cylindri-cal polystyrene holders into argillaceous parts of the stiffsediment. Most of the samples are from the Toarcian(78 samples), whereas 17 are from the Aalenian, and27 are from the Bajocian/Bathonian section. All sam-ples were routinely measured in a Molspin Ltd. spin-ner magnetometer and subsequently step-wisedemagnetised in 5, 10, 20, and 30 mT alternating fields(AF) (three orthogonal directions inside metal shields)and remeasured after each step.

In order to determine the carriers of the magneticremanence, eight samples were treated in step-wiseincreasing pulse-magnetic fields up to 0.6 T (Fig. 4). The

159.61 m189.27 m249.49 m252.33 m

121.01 m160.54 m121.32 m186.93 m

0.0 0.1 0.2 0.3 0.4 0.5 0.6

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Fig. 4. IRM (isothermal remanentmagnetisation) performed on eightsamples, which show saturation between0.2 and 0.3 T, suggesting magnetite to bethe carrier of the remanence.

591

IRM (induced remanent magnetisation) typically satu-rates in fields between 0.2 and 0.3 T, indicating that themagnetic carriers are dominated by magnetite rather thanhematite or goethite. As the MDF (median destructivefield) for most samples is well above 30 mT, this sug-gests that the magnetic minerals are dominated bysingle- or pseudosingle-domain magnetites, probably ofdetrital origin. The NRM (natural remanent magnetisa-tion) intensity is low, typically 1–2 mA/m, with extremesof about 0.4 and 4.5 mA/m (Fig. 5). The magnetic de-clination is not known, as the cores were not orientedin azimuth. The AF cleaned inclination (30 mT) is shownin Figure 6.

The present latitude of Anholt is 56.7°N, which isequivalent to a central axial dipole inclination of I0 =71.8°. However, nearly all the inclinations are muchcloser to 0° than expected (Fig. 6). Only 16 out of the122 samples show inclinations more than ± 30° from0°. During the Jurassic, the Danish area had a latitudi-

nal position not significantly south of today (Press &Siever 1982), indicating that this pronounced inclina-tion shallowing cannot be due to plate drift alone, butrather was caused by either remagnetisation or com-paction (Abrahamsen 1992). As both polarities are found,secondary magnetisation is unlikely to be the cause. Theinclination shallowing in the sediment is thus probablydue to compaction.

On account of the presence of several major gaps insampling caused by lithological variation (coarse-grainedsections were either not recovered or not sampled forpalaeomagnetic studies) as well as due to the dominantshallow inclinations, the reversal chronology basedupon the material from Anholt is poorly constrained.A tentative interpretation is shown in Figure 6, but amore detailed magnetostratigraphical correlation toother palaeomagnetic records such as the detailedsequence from the Bajocian–Bathonian of south Spain(Steiner et al. 1987) is not justified at present.

0 1 2 3 4 5100

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Fig. 5. NRM (natural remanent magnetisation) intensity vs. depth.Most NRM intensities are between 0.5 and 2.5 mA/m, with anaverage of 1.5 mA/m. m b.s., metres below surface.

-30-60-90 0

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Fig. 6. Suggested polarity interpretation of the Jurassic inclina-tion record from the Anholt borehole. Black, normal polarity;white, reversed polarity; grey, intervals in which polarity ismixed or undetermined; zigzag line, significant intervals in whichpolarity data is lacking; m b.s., metres below surface.

LithologyA preliminary sediment description was performed dur-ing the drilling operation. A more detailed descriptionwas made subsequently, both of cores and cuttings sam-ples, and black-and-white and colour photographs ofthe cores were taken. X-ray photographs were taken ofselected 1 cm thick slices of the core material. Immediatelyafter drilling, a SNG-log (Spectral Natural Gamma-raylog) was obtained from the Anholt IV borehole.Preliminary results were published by Nielsen (1992).

MethodsThe following analyses were carried out:

1. Grain-size analysis using wet sieving (> 63 µm frac-tion) and settling in Andreassen tubes (< 63 µm frac-tion).

2. Bulk sediment geochemistry comprising TOC (totalorganic carbon) and sulphur analysis measured in aLECO induction furnace, as well as measurements byAtomic Absorption Spectrophotometry (AAS) of thecontent of the main elements: Si, Al, Fe, Ca, Mg, Mn,Na, and K.

3. Mineralogical composition of both bulk samples andof the clay fraction using X-ray Diffraction (XRD).Samples for bulk mineralogy were dried in a fur-nace at 105°C for 16 hours, and ground in a mortar.The powder was mounted in the sample holder with-out preferred orientation. Samples for clay mineral-ogy were dispersed in distilled water, sieved througha 63 µm mesh, and the < 2 µm fraction was obtainedby repeated decantation in distilled water. The < 2 µmfraction was smeared onto glass plates in order toobtain preferred orientation of the clay minerals. Theglass plates with the clay film were X-rayed in variousconditions: air-dried, ethyleneglycol-treated and afterheating to different temperatures (Nielsen et al. 1989).

4. Some of the samples were heated at a rate of 2°Cper minute in a Differential Thermal Analysis/ThermalGravimetry (DTA/TG) instrument in order to determinethe temperatures for oxidation of organic compoundsand to release the OH-groups of the phyllosilicateminerals. The change in weight from these processeswas determined. The analyses were performed bothon bulk samples and on the clay fractions (0–2 µm,

0–1 µm, and 1–2 µm) and were followed by heatingto 468°C. This temperature was kept constant for 8hours and the weight loss from the release of OH-groups as a function of time was recorded. A tem-perature of 468°C was chosen, because the DTA/TGcurve indicated that approximately 465°C was thethreshold temperature for the dehydroxylation processat the heating rate used. The time in minutes for therelease of half of the OH-groups was calculated.

5. The same samples were exposed to heating in stepsof 25°C from 450–600°C followed by XRD analysisin order to observe the decomposition of the crys-tal structure in kaolinite.

Results and discussion

Sedimentary facies

The clays and sands from 306–201 m are referred to theFjerritslev Formation (Figs 2, 7; Michelsen 1978). In thelower part (c. 306–231 m), the SNG-log is rather uni-form and the sediment consists of a relatively homo-geneous, greyish green clay with a low median grain-size(Fig. 8). This interval is equivalent to member F-III ofthe Fjerritslev Formation (Michelsen 1978).

The lowermost c. 6 m are characterised by a slightlysandy and bioturbated clay (Figs 7, 8) with ammonites.Pure clay lithologies make up 50–70% of each core, theremainder comprising silty clay layers and fine-grainedsand laminae. Above this basal unit, the clay is com-monly non-bioturbated and contains less than 1% sand,except for very thin laminae of fine-grained sand ofinferred storm origin. Silty clays form between 1 and30% of each core, whereas pure clay makes up 70–99%of each core. Upwards, especially above 260 m, the stormsand layers become coarser and thicker, up to a few mil-limetres, and the sand content in the clay layers increasesto 4–6% (Fig. 8). Some sand laminae are cross-laminated.

At 231 m, a carbonate-cemented lignite conglomer-ate (Fig. 9) marks the lower boundary of member F-IVof the Fjerritslev Formation (Michelsen 1978). This mem-ber continues up to 201 m and is characterised bysandier sediments with more numerous and thickersand layers intercalated with the clay layers. The sandlayers show an upwards increase in the content of veryfine pebbles from 1.6–8.5% in the lower part to 11–23%in the upper part (Fig. 8).

The upper part of the Jurassic succession (201–104 m)is referred to the Haldager Sand Formation (Michelsen

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Litho-strat.

Chrono-stratigraphy

LithologyTh

(ppm)U

(ppm)K% Total GR

log U/Th Th/K U/K Comments

0 0 4 m b.s.

20 5 0

Bedding tilted (up to 20°)

Horizontal bedding

Calcite-cemented lignite conglomerateSiderite concretions

Siderite concretions

Siderite concretionsPyrite and siderite concretions

Siderite concretions

Burrows

Horizontal bedding

Concretions

Silt

Clay

Till

Carbonate

Lignite clasts

Gravel

Coarse-grained sand

Medium-grained sand

Fine-grained sand

Silty sand

Silty clay

Fig. 7. Integrated log combining lithostratigraphical and lithological data with the Spectral Natural Gamma-ray log (SNG). Quat., Quaternary;Pliens., Pliensbachian; m b.s., metres below surface.

594

1978). This part has a markedly higher content of sandwith brown coal fragments. The lithology of the HaldagerSand Formation shows a cyclic variation which is alsoevident on the gamma-ray log (Fig. 7). Intervals (1–10 mthick) of medium-grained sand with lignite fragmentsalternate with 1–5 m thick units of silty clay with highTOC contents (Fig. 2). Lignite layers, a few centimetresthick, also occur locally. The observed variations inlithology might be explained by lateral migration ofchannels in a delta-plain or floodplain setting.

SNG-log analysis

The thorium (Th), uranium (U), potassium (K), andintegrated gamma-ray signals from the Spectral NaturalGamma-ray log (SNG-log; Fig. 7) obtained from theAnholt IV borehole show some significant variationsthroughout the Jurassic section. The main carrier ofpotassium is believed to be phyllosilicates (clay min-erals and mica), as almost no potassium feldspar wasobserved. Uranium is normally concentrated in layersrich in organic matter but may also be present in someheavy minerals. The Th-content is somewhat greater inkaolinite than in other clay minerals, but some heavyminerals contain relatively high concentrations of Th (seebelow). The log signal is very uniform in member F-IIIof the Fjerritslev Formation. The only exceptions arecharacteristic negative peaks where carbonate and pyrite

concretions and sand laminae are present (Fig. 7). Thelower gamma-ray values probably indicate a lower con-centration of Th, U and K in the carbonate concretionsthan in the surrounding compacted clay, suggestingthat carbonate cementation took place shortly afterdeposition and prior to significant concentration of K,Th and U due to compaction of the clays. The log sig-nature of member F-IV is markedly different from thatof the Haldager Sand Formation, mainly due to varia-tions in lithology. The fine-grained layers are enrichedin K-containing phyllosilicates and U-containing organicmatter relative to the coarser layers. Part of the Th con-tent is probably also related to kaolinite particles, whichare more common in the finer size fractions.

Uranium and thorium anomalies in the SNG-log

Some thin layers in member F-IV of the FjerritslevFormation and in the lowermost part of the HaldagerSand Formation (around 195 m) have higher concen-trations of Th, and to some extent also U (Fig. 7). Thesmaller Th and U anomalies are all located within thecoarsening-upwards marine member F-IV, whereas thetwo strong anomalies are located within the lower levelsof the generally non-marine Haldager Sand Formation(environmental interpretations from Michelsen 1978,1989a). The K content is constant or even relatively lowin these layers (see also the element ratios in Fig. 7).

10 000

1000

100

10

1

90 115 140 165 190 215 240 265 290 315

Med

ium

gra

in s

ize

(µm

)

Depth (m b.s.)

Fjerritslev FmHaldager Sand FmQuat.

Fig. 8. Median grain-size values; note thelogarithmic scale on the y-axis. Somereservations should be made concerningthe results of the grain-size analysis ofthe F-IV member (231–201 m), as nocores were recovered from this interval.The sediments are only slightly consoli-dated, and the more fine-grained partsmight therefore have been incorporatedin the drilling fluid. m b.s., belowsurface.

The base-level of the gamma-ray signal is relativelyhigh in the clay lithologies of the Fjerritslev Formation,but considerably lower in the Haldager Sand Formation.Low gamma signals are normal for sand layers. Ditchcuttings samples and samples from the very few coresfrom these low gamma-ray intervals are dominated bysand thus supporting the log interpretation. However,the very poor core recovery in this section of the bore-hole did not allow very precise sampling of undisturbedTh-rich intervals, so the reason for the high concen-trations of this element is unclear.

Similar peaks of Th and U are found in Jurassic,Cretaceous and Miocene deposits in other Danish bore-holes (Korsbech & Nielsen 1991; Korsbech 1992). Thesame phenomenon is seen in sections with excellentcore recovery of Lower Cretaceous fine-grained sandin the Skagen-3 borehole. Here, the coarse silt fractioncontains a considerable proportion of heavy minerals(mainly zircons; H. Friis, personal communication 1992).The same observation has been made by Conner &Kelland (1975a, b) in a Jurassic sandstone in a NorthSea well; zircons and other heavy minerals such asmonazite, rutile and epidote commonly contain a sub-stantial amount of Th, and it was suggested that thismight be the source for the relatively high content ofthis element. The same explanation may be applicableto the Jurassic in the Anholt cores.

An examination of some older borehole logs indi-cates that layers enriched in heavy minerals may be acommon phenomenon in Jurassic sandstones in Den-mark. Although SNG-logs were not run in these oldboreholes, we propose that some of the peaks observedon natural gamma-logs in the Jurassic and LowerCretaceous sediments of the Frederikshavn City-1 andBørglum-1 boreholes are due to a high content of heavyminerals. Larsen (1966) detected several samples withzircon contents of up to 60% of the non-opaque, non-micaceous heavy fraction. Higher gamma signals are nor-mally found in these layers.

The concentrations of Th and U between 198 and190 m are shown on Figure 10; note that the U and Thpeaks are displaced slightly (5–10 cm) relative to oneanother. The scales were chosen in order to equate theheights of the Th and U peaks at 193.9 m. The ratiobetween the Th and U concentrations here is 5:1. Incontrast, the Th:U ratio for the peaks at 195 m is about10:1; note that minor fluctuations occur within thesepeaks at 195 m. This variation in the Th:U ratio mayimply that some separation of the heavy minerals hastaken place, probably based on differences in grainsize and density.

Bulk mineralogy

The mineralogical composition of the Jurassic succes-sion of the Anholt borehole is relatively simple; it com-prises only stable, detrital minerals and a few authi-genic/diagenetic minerals. The detrital minerals arequartz, clay minerals (including mica) and very littlefeldspar; the authigenic/diagenetic minerals are pyrite,calcite and siderite. Authigenic feldspars have been

595

Fig. 9. Core photograph of part of the interval from 232.6–231.1m b.s., Fjerritslev Formation, F-III member, uppermost Toarcian.Opposing faces of a single slabbed core piece are illustrated.The dark clasts are lignite fragments, up to 7 cm in length, in amatrix of calcite-cemented clayey, silty sandstone. Width of coreis 10 cm.

596

reported in Middle Jurassic sediments elsewhere in theNorth Sea Basin (Nielsen & Friis 1985), but were notobserved in this borehole.

The mineralogical variation mainly reflects the grain-size variation and the location of pyrite and carbonateconcretions of predominantly sideritic composition. Theboundary to the overlying Quaternary sediments isclearly marked by a distinct increase in feldspars andamphiboles, i.e. minerals with a relatively low resist-ance to chemical weathering.

Clay mineralogy

The non-clay minerals of the < 2 µm fraction are dom-inated by quartz, but the quartz content is much lowerin fractions below 1 µm. Chlorite is only present insmall quantities with a slight tendency to decreaseupwards (Fig. 11), presumably due to the diagenetic ori-gin of this mineral. Illite is a common mineral althoughthe measured illite content in the coarser layers is pre-sumed to also include muscovite (identified macro-scopically), as it is difficult to distinguish between thesetwo very similar minerals by XRD. Kaolinite is the dom-inant clay mineral in the coarser sediments. In sandsfrom the Haldager Sand Formation, macroscopic exam-ination revealed a white powder, identified as purekaolinite by XRD. In finer grades of the clay fraction,the kaolinite content is notably lower, due to its nor-mally larger grain-size relative to other clay minerals.

Smectites are present in the lower, fine-grained layers(Figs 11, 12), but decrease in proportion up-section, rel-

0

0

190

198

50Th (ppm)

10U (ppm)

Dep

th (

m b

.s.)

Th

U

Fig. 10. Thorium (Th) and uranium (U) concentrationsbetween 198 and 190 m b.s. The relative concentrations(Th/U) differ for the two peaks, probably reflecting sort-ing processes during sedimentation. m b.s., below sur-face.

100

90

80

70

60

50

40

30

20

10

0

95 104 201 305

% (

cum

ulat

ive)

Quat. Haldager Sand Fm Fjerritslev Fm

KaoliniteChloriteIlliteSmectite

Fig. 11. Clay mineralogy of the < 2 µmfraction. Sum of clay minerals = 100%.The analyses are displayed in strati-graphic order but the horizontal scale isnot directly proportional to depth; thedepth to the main lithostratigraphicdivisions is indicated (in metres belowsurface).

597

ative to the total clay fraction, corresponding to theoverall increase in grain size up-section (Fig. 11). Thepresence of smectite in the Fjerritslev Formation shouldbe noted as smectite is absent in Jurassic and LowerCretaceous sediments in most wells in the Danish Basinand the Danish Central Graben (Nielsen 1979, 1985;Clausen 1982; Nielsen & Friis 1985; Schmidt 1985a;Krabbe 1986; Lindgreen 1991). We believe that the dom-inance of illite and the presence of illite/smectite mixed-layer minerals in Jurassic sediments in most boreholes,excepting Anholt, is the result of substantial diagenetic

illitisation of original smectites due to greater burialdepths and thus exposure to higher temperatures.

The transformation of smectites to illites via mixed-layer phases is primarily dependent on burial history,temperature and time (Dunoyer de Segonzac 1970).The transformation is thus seen at different depths andages in different basins. The process mainly happenswithin a temperature range of 80–115°C, normally cor-responding to a burial depth of 2–4 km in the NorthSea (Środoń & Eberl 1984). Values of these magnitudeshave never been reached for the Anholt sediments. The

4.76

50

5.00

87

5.29

86

5.61

14

5.75

71

7.15

54

10.0

777

14.0

046

16.7

463

18.6

327

20.6

925

22.6

583

33.9

076

5.02

90

7.24

62

9.63

58

10.1

592

13.2

703

14.6

674

16.8

912

18.3

544

22.1

246

30.4

396

32.6

144

ILL

ILL

CHL

CHL

SM

KA/CHL

Heat-treated

Eth.-treated

Fig. 12. X-ray diffractogram of the clayfraction of a sample from the FjerritslevFormation (294.24–294.21 m b.s.). Heat-treated, X-rayed after heating to 500°Cfor 1 hour; Eth.-treated, X-rayed aftertreatment with ethyleneglycol vapour for16 hours at 60°C. Reflection peaks: CHL, chlorite; ILL, illite; KA, kaolinite;SM, smectite. The figures representcrystal lattice spacings in Ångstrøms.

598

illitisation process starts in sediments with vitrinitereflectance values of approximately 0.5 %Ro, possiblyalready at 0.40–0.45 %Ro (Pevear et al. 1980), and Burtner& Warner (1986) proposed on the basis of Rock-Evalanalysis that the process takes place in sediments withTmax values between 430° and 440°C, possibly alreadyat 425°C. In deeply-buried Jurassic successions, such asin the Børglum-1 and Uglev-1 wells, the vitrinitereflectance values for sediments of the FjerritslevFormation are 0.40–0.50 %Ro (Schmidt 1985b), i.e. con-siderably higher than the values from Anholt (0.25–0.40%Ro, see below).

The percentage of smectite normally increases withdecreasing particle size and towards the basin centre.Because of the marginal location of the Anholt bore-hole, it is possible that the sediments contain less detri-tal smectite than contemporaneous sediments in otherwells in the Danish Basin prior to diagenetic alteration.

Geochemistry

The TOC values are shown in Figure 2 and the S, Fe2O3and K2O values in Figure 13. Peak values of TOC inthe Haldager Sand Formation are related to brown coallayers. Intermediate values of TOC are usually foundin brownish/black layers dominated by silt-sized par-ticles, normally with relatively abundant muscovite, orin sand layers with scattered lignite clasts, such as inthe middle of the Fjerritslev Formation section. LowTOC values are mainly restricted to layers dominatedby clay or coarse-grained quartz sand. The K2O con-tent generally reflects the amount of illite, whereas Sand Fe2O3 reflect the pyrite and to some extent thesiderite contents. The percentage of Fe, excluding thatincorporated in pyrite or siderite, is relatively uniform.

The analyses were used to calculate a normativemineralogical composition, which was then comparedwith the XRD mineralogy and used to improve thequantification of the bulk mineralogy from the XRDdata. The Anholt borehole is well-suited to such a pro-cedure as: (1) many core-samples have been analysed,(2) the number of different minerals is limited, and (3)the minerals present are rather stable.

Differential thermal analysis (DTA) and step-heated XRD

The result of the step-wise heating of the sediment forone hour followed by XRD is shown in Figure 14. In sam-

ples from the top of the Jurassic section down to a depthof about 230 m, the 7Å kaolinite peak on X-ray diffract-ograms is totally destroyed by heating to 500°C for onehour; indeed, kaolinite from sand layers in the HaldagerSand Formation is already destroyed at a temperature of450°C. From 230 m down to the base of the borehole at306 m, the kaolinite structure is only partly destroyed byheating for one hour. The higher the heating tempera-ture and the longer the sample is exposed to this tem-perature, the greater the destruction. Measurements ofdifferent size fractions clearly demonstrated that largergrains were more heat resistant than smaller grains, prob-ably due to a greater proportion of grains with crystallattice imperfections amongst the smaller size fractions;such size-dependent thermal stability has been noted inmany previous studies (e.g. Norton 1939).

With the exception of a single sample at about 250m, there is a slight tendency for kaolinites in memberF-III to be more heat resistant with increasing depth,even if the total amount of kaolinite decreases (Figs 11,15) and the particle size of the mineral grains decreases(Fig. 8). Figure 15 shows the relationship between coredepth and time to destruction of half of the kaoliniteparticles at 468°C, i.e. the release of OH-groups corre-sponding to half of the weight loss observed at thistemperature. Generally, the time needed for this destruc-tion increases with increasing depth.

This tendency towards a down-section increase inthermal resistance of kaolinite has been observed else-where in Mesozoic sediments of the North Sea Basin.Holdridge & Vaughan (1957) found the temperature forthe onset of dehydroxylation to be 477°C for kaolinites(average of 48 samples) and 522.5°C for pure dickite(average of 18 samples) through measurement onDifferential Temperature Analysis (DTA) equipment ata heating rate of 10°C per minute. The lower thresholdtemperature observed in these Anholt data (468°C), isprobably due to the lower heating rate (2°C/min.) usedin the present study.

The crystal order presumably increases with the influ-ence of progressive diagenesis. In deeper diagene-sis/incipient metamorphism, kaolinites may convert todickite and further to nacrite with the same chemicalcomposition as kaolinite, but with a higher degree oforder in the crystal lattice (Dunoyer de Segonzac 1970).The results of the analysis of the thermal stability ofkaolinites from the Anholt borehole indicate that thethermal stabilisation of kaolinites during progressivediagenesis is a gradual process. The process seems toinitiate at a relatively early diagenetic stage; thermalstabilisation is detectable at diagenetic stages reached

599

at a depth of approximately 1 km. It also seems possi-ble to differentiate the thermal stability of kaoliniteswithin a depth range of 100–200 m. Kaolinite in sandsof the Haldager Sand Formation is commonly seen asa whitish powder on the quartz grains. The very lowthermal resistance of this kaolinite might be explainedby a later, probably post-uplift, formation in the porespaces of the sand. The formation of kaolinite is pos-sibly due to reactions between a migrating diluted acidicporewater and feldspar grains (Nielsen & Friis 1985).

Organic petrology and geochemistryA total of 46 samples from the Anholt borehole wereselected for TOC and Rock-Eval screening. The sam-ples were selected mainly from the darker grey, brown-ish or black sediment levels where higher organiccontents were expected. From the screening results, 23samples were selected for organic petrographical analy-ses, i.e. measurements of vitrinite reflectance and flu-orescence, and compositional description.

35

30

25

20

15

10

5

090 110 130 150 170 190 210 230 250 270 290 310

Depth (m b.s.)

Perc

ent

Quat. Haldager Sand Fm Fjerritslev Fm

K2OFe2O3S

Fig. 13. The content (%) of K2O, Fe2O3,and S determined from the bulkgeochemical analysis. Quat., Quaternary;m b.s., metres below surface.

Fig. 14. Peak ratios (peak height ofheated samples/peak height of ethylene-glycol-treated samples) for 7Å kaoliniteheated to 500°C, 525°C and 550°C.m b.s., metres below surface.

2200.00

0.02

0.04

0.06

0.08

0.10

Rat

io

0.12

0.14

0.16

230 240 250 260 270

Depth (m b.s.)

280 290 300 310

500°C/glycol525°C/glycol550°C/glycol

600

TOC and Rock-Eval screeningMost of the samples are very poor in total organic car-bon (TOC). The hydrocarbon potential (HC) is also low(S2 values are low; Table 1). S2 values (S2: hydrocar-bons generated during Rock-Eval pyrolysis) of < 0.5mg hydrocarbon (HC)/g rock are considered to giveunreliable Tmax values (Tmax: Temperature of maximumhydrocarbon generation during Rock-Eval pyrolysis).The highest TOC values are from the upper sandy sec-tion of the Haldager Sand Formation from a depth ofabout 190–105 m, whereas the values from the under-lying greenish clays of the Fjerritslev Formation are lowto very low. The varying content of organic/coaly debrisin the sediments is confirmed by the wide range ofvariation in TOC values. The highest value (38%) wasobtained from a thin lignite layer.

The Tmax varies in the range 410–433°C, with mostof the values around 420–425°C (Table 1). The lowestvalue of 387°C from the brown coal bed is consideredto be unreliable. The highest value of 433°C is most likelydue to the presence of slightly oxidised or reworkedmaterial and not due to maturation.

The dominant Tmax values of about 420–425°C arewithin the expected range for sediments with the mea-sured vitrinite reflectance values (see below) of about0.4 %Ro (Tissot et al. 1987). The HI (hydrogen index)below or just above 100 mg HC/gTOC (Table 1) is typ-ical of kerogen types III–IV. Only one sample yieldeda higher HI value (276 mg HC/g TOC).

Coal petrographyThe samples selected for coal petrographic descriptionwere embedded in cold synthetic resin, and were groundand polished after hardening. All samples were stud-ied in normal reflected light combined with blue light-induced fluorescence. The organic material was de-scribed and the maceral composition was estimatedsemi-quantitatively in the following groups: vitrinite,pseudovitrinite, inertinite and liptinite. The main focuswas on the degree of oxidation and the liptinite com-position. Point counting was not performed; the resultsof the coal petrographic analysis are given in Table 2.

The organic material in all samples is, in general,dominated by terrestrial material. Most samples arecharacterised by humic material (vitrinite) showing vary-ing degrees of oxidation and/or reworking (pseudo-vitrinite and inertinite). Samples 3 and 8, from 121.6 mand 170.9 m respectively, are composed entirely of largefragments of ulminitic vitrinite with almost no indicationof oxidation. In contrast, sample 10 (184.48 m) containshumic material composed almost entirely of oxidisedinertinite, mainly tiny small fusinite fragments, or pseudo-vitrinite.

In general, the liptinitic content is low, but the iden-tifiable part shows a high abundance of macerals of ter-restrial origin, such as sporinite, resinite and cutinite,sometimes even with possible fluorinite. Only very fewalgae were identified. In the upper part of the section,a few of the Botryococcus-type occur, indicating depo-sition in (or derivation from) fresh to brackish water,and a Tasmanites was observed in sample 10 (184.48 m).Marine organic material, such as tiny fragments ofdinocysts or acritarchs, is present only in the lowermost

100 120 140 160 180

Depth (m b.s.)

Min

utes

at

468°

C

Kao

linite

(%

)

200 220 240 260 280

60

50

40

30

20

10

0

1/2 weight at 468°CKaolinite

100

90

80

70

60

50

40

30

20

10

0

Fig. 15. The proportion of kaolinite (%)relative to the total clay mineral contentof the clay fraction (< 2 µm) and the timetaken in minutes for the release of half ofthe OH-groups in kaolinite at 468°C,measured by differential thermalgravimetry. m b.s., metres below surface.

part of the succession. A very small amount of bitumi-nite was also recognised in these samples. Sample 22(300.88 m) has the highest proportion of what may beconsidered to be marine material. The organic mater-ial in the uppermost part of the Fjerritslev Formation isof very poor quality compared to data from other wellsin the Danish area (Thomsen et al. 1987).

Vitrinite reflectance and fluorescence dataReflectance measurements were performed on the samepolished specimens as used for description of the organiccomposition. The photomultiplier attached to the ‘ZeissPhotomicroscope’ was calibrated by measurements ona polished optical glass standard of constant known

601

1 113.6 0.30 522 119.82–119.85 11.00 417 1.08 12.17 0.08 1.10 111 0.33 513 121.59–121.60 38.00 387 5.70 31.07 0.16 3.05 82 0.32 634 124.6–127.6 3.74 427 0.19 3.15 0.06 0.28 84 0.33 39

130.6–133.6 2.02 426 0.11 1.25 0.08 0.11 625 133.6–136.6 2.11 423 0.07 0.97 0.07 0.09 46 0.37 49

137.4–139.6 0.17 424 0.01 0.01 0.50 0.00 6142.6–145.6 0.17 404 0.03 0.05 0.38 0.01 30145.6–147.1 1.35 425 0.01 0.11 0.08 0.01 8147.1–148.6 2.43 424 0.05 0.91 0.05 0.08 37

6 149.90 0.70 426 0.12 1.94 0.06 0.17 276 0.35 50154.6–157.6 2.44 423 0.03 0.23 0.12 0.02 9

7 159.59–159.74 2.40 424 0.13 1.74 0.07 0.16 73 0.35 528 170.8–170.90 5.89 410 0.35 2.67 0.12 0.25 45 0.32 559 175.55 1.81 423 0.03 0.79 0.04 0.07 44 0.43 43

184.09–184.10 0.77 427 0.01 0.24 0.04 0.02 3110 184.80 9.50 427 0.46 5.94 0.07 0.53 63 0.34 7

184.98 1.73 421 0.07 1.32 0.05 0.12 7611 187.82 1.50 418 0.03 0.59 0.05 0.05 39 0.34 3012 189.65 0.49 431 0.00 0.07 14 0.32 27

194.6–197.6 0.12 0.01 0.0013 206.6–209.6 0.63 424 0.03 0.36 0.08 0.03 57 0.34 30

209.6–210.3 0.38 425 0.03 0.15 0.17 0.01 40212.6–215.6 0.31 422 0.03 0.13 0.19 0.01 42

14 218.6–221.6 0.31 425 0.05 0.13 0.28 0.01 42 0.32 50221.6–224.6 0.28 422 0.05 0.11 0.31 0.01 40

15 230.53 1.19 422 0.03 0.50 0.05 0.05 50 0.33 51234.36 0.16 431 0.00 0.07 44

16 239.28 0.72 429 0.01 0.42 0.02 0.04 58 0.31 14244.15 1.20 427 0.01 1.31 0.01 0.11 109

17 249.68 0.24 429 0.00 0.17 69 0.29 8255.16 0.22 432 0.00 0.07 32260.59 0.21 434 0.00 0.13 61264.20 0.28 420 0.00 0.17 60

18 270.70 0.50 420 0.01 0.25 0.04 0.02 50274.80 0.19 419 0.00 0.07 38

19 280.09 0.17 414 0.01 0.07 0.13 0.01 41285.70 0.20 416 0.00 0.07 36

20 290.08 0.45 420 0.01 0.30 0.03 0.03 67 0.31 821 295.08 0.42 416 0.01 0.25 0.04 0.02 5922 300.08 1.08 420 0.05 1.01 0.05 0.09 94 0.34 3823 304.08 0.66 423 0.01 0.34 0.03 0.03 52 0.35 36

Sample Depth(m)

TOC(wt%)

Tmax(°C)

S1(mg

HC/grock)

S2(mg

HC/grock)

PI PC(wt%)

HI %Ro n

Table 1. Rock-Eval screening results and vitrinite reflectance

TOC : Total organic carbon.Tmax: Temperature of maximum hydrocarbon generation during pyrolysis.S1: Thermally-extracted hydrocarbons.S2: Hydrocarbons generated during Rock-Eval pyrolysis.Pl: Production index [S1/(S1+S2)], derived from Rock-Eval pyrolysis.

PC: Pyrolysable carbon [0.083 (S1+S2)].Hl: Hydrogen index [100 x S2/TOC].%Ro: Vitrinite reflectance.n: Number of measurements.

reflectance. The reflectance measurements are reportedas the percentage (%Ro) of the incident light reflectedfrom the plane surface of the vitrinite surface whenimmersed in oil.

The abundance of vitrinite particles is good forreflectance measurements, even in the lean samples, asmost samples are dominated by humic material. In gen-eral, as many measurements as allowed by the availablematerial were performed, and the quality of the datawas noted. The average values shown in Table 1 arebased on reflectance measurements that were consid-ered to be reliable. The most reliable data are consid-ered to be from the coaly samples where the particlesare so large that a detailed maceral identification is pos-sible, and therefore the results are more reliable com-

pared with samples containing fine-grained dispersedorganic matter.

In sample 3 (121.6 m), the organic material is rep-resented entirely by large particles of woody tissue andthe measurements were performed on texto-ulminite.The range of values is very narrow (0.25–0.40 %Ro)with an average of 0.32 %Ro from a total of 62 mea-surements. Reflectance values from corpohuminite,which is also common, have the same range and almostthe same average (0.31 %Ro).

The range of values in the other samples is some-what larger, though still between 0.2 and 0.5 %Ro. Thebest data quality is generally obtained from the uppercoaly samples, whereas the quality decreases in someof the lowermost samples where the particle size of the

602

Table 2. Composition of the organic material

Vitr

inite

Pseu

dovi

trin

ite

Iner

tinite

Lipt

inite

Sample Maximumdepth(m)

Organiccontent

Maceral composition Liptinite composition

Din

ofla

gella

tes/

acri

tarc

hs

Tasm

anite

s

Botr

yoco

ccus

Bitu

min

ite

Lipt

odet

rini

te

Spor

inite

Cut

inite

Fluo

rini

te

Res

inite

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

113.6

119.85

121.60

127.60

136.60

149.90

159.70

170.90

175.55

184.48

187.82

189.65

209.60

221.60

230.53

239.28

249.68

270.70

280.09

290.08

295.08

300.88

304.08

Moderate

High

Very high

Moderate

Moderate

Moderate

Moderate

High

Moderate

High

Moderate

Low

Low

Low

Low

Low

Low

Very low

Very low

Low

Low

Low

Low

XXXX

XXX

XXXXX

XX

X

XXX

XXX

XXXXX

XXX

X

XXXX

XXX

XXX

XXXX

XX

XXXX

XXX

XXXX

XXX

X

X

XX

XXX

X

XX

XX

XXX

XX

XX

XX

XX

X

X

XX

X

XX

X

X

X

X

XX

XX

X

XX

X

X

XX

XX

X

X

X

X

XXXX

X

X

X

X

XX

X

X

X

XX

XX

X

X

-

X

-

X

-

X

X

-

-

X

X

-

-

-

X

XX

-

-

-

X

XX

XXX

X

-

-

X

X

X

-

X

X

-

X

X

X

X

X

X

-

X

XX

X

-

-

X

X

-

-

-

X

XX

X

X

X

XX

XX

X

XX

X

X

X

X

X

X

X

X

X

X

XX

XX

-

X

X

XX

XX

X

XX

-

-

-

-

-

-

- X

X

X

X

X

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vitrinite is smaller and the morphological affinity of thevitrinite less obvious. The poorer quality is indicatedby the wider range of the reflectance data. In samples18, 19 and 21, it was not possible to perform mea-surements but the range of reflectance data in Table 1is considered reliable, due to the relatively large num-ber of measurements on each sample.

Spectral fluorescence measurements were performedon a Leitz Orthoplan microscope equipped with a Hama-matsu photomultiplier and a Ploemopak for measure-ments and observations. The spectra were measured andtheir Q value recorded (Q = relative fluorescence inten-sity at 650 nm / relative fluorescence intensity at 500 nm).It was only possible to make fluorescence measure-ments on a few samples containing alginite, i.e. sam-ples 4, 6, 7, 10, 21 and 22. The mainly yellowish-greenfluorescence colours of the algal bodies indicate theirdegree of immaturity and correspond to their vitrinitereflectance values. All average Q values are between0.4 and 0.5, corresponding to the measured vitrinitereflectance values (Schmidt 1989).

UpliftThe increase in vitrinite reflectance down-section is theresult of chemical processes controlled by time andtemperature; the increase is linear with respect to timeand exponential with respect to temperature (Waples1985). The changes to the chemical structure of the vit-rinite are irreversible, and therefore the vitrinite re-flectance reflects the maximum temperature to whichthe sediment has been exposed during burial. Uplift willconsequently not cause any change in the vitrinitereflectance. A difference between measured reflectancevalues from a certain depth and estimated reflectancevalues for that depth can therefore be used as an indi-cation of the magnitude of uplift.

A reflectance value of 0.20 %Ro is normal for zerocoalification at the depositional surface (Teichmüller &Teichmüller 1979). Reflectance values above 0.3 %Ro mayfirst be expected at a depth of at least 1000 m in areasof the North Sea with no uplift but a similar tempera-ture history (Hansen & Thomsen 1990; Schmidt 1990).The range of reflectance values slightly above 0.3 %Rosuggests that some uplift and erosion has taken place.The uplift is estimated to have been about 1000 m; acomparable value (975 m) was obtained by Petersenet al. (2003, this volume) who utilised the reflectancedata reported here but applied a coalification curvederived from the Danish Basin.

Study of the organic material has thus indicated that:

1. The degree of diagenetic maturation is relatively low,but higher than expected for sediments at a depthrange of approximately 100–300 m.

2. The ranges of Tmax, vitrinite reflectance and Q val-ues suggest that the deposits have been exposed totemperatures that are commonly present at c. 1000m depth.

3. The HI values and the coal petrographic interpreta-tion indicate a terrestrial origin for most of the organicmaterial.

4. The content of marine organic material is very low,and restricted to the lowermost few metres of thecored section.

Discussion

PalaeoenvironmentNodosarid foraminifera, such as those found in the low-ermost part of the borehole in foraminiferal zone FAfrom 306–304 m, referred to member F-III of theFjerritslev Formation, were typical of normal marineshelf conditions during the Jurassic period (e.g. Nagyet al. 1990). The nodosarid assemblage combined withthe abundant dinoflagellate cysts of low diversity, theoccurrence of ammonites, fish remains, bioturbation, thealternating clay and fine-grained sand lithology, andthe low TOC content (below 1%; Fig. 2) suggest that amarine, inner shelf environment with well-oxygenatedbottom conditions prevailed during the late Pliens-bachian (Seidenkrantz et al. 1993; Nagy & Seiden-krantz in press). Storm sands are common and relativelycoarse-grained in the lowermost levels of the borehole(306–300 m). In contrast to this basal interval, the stormsands become less abundant and finer-grained above300 m, although their abundance and grain-size varies,with a slight tendency to become more abundant andcoarser upwards between 300 m and 260 m.

In the uppermost Pliensbachian – Toarcian, biotur-bation is less prominent and the clay-rich sediment con-tains an upwards increasing proportion of storm sandlaminae, especially from 260 m. The thickness and grainsize of the sand laminae also increase upwards, sug-gesting a gradual decrease in water depth through theToarcian. This is supported by the low abundance of

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marine dinoflagellates, decreasing up-section, and thelow-diversity agglutinated foraminiferal fauna (Seiden-krantz et al. 1993; Nagy & Seidenkrantz in press). Suchforaminiferal assemblages may reflect low salinity, oxy-gen deficiency, turbulent conditions or rapid sedimen-tation and were characteristic of deltaic or prodeltaicenvironments in the Jurassic (Løfaldli & Nagy 1980;Nagy et al. 1988, 1990, 1995). Thus, the dominance ofAmmobaculites, Bulbobaculites, Kutsevella and Haplo-phragmoides, as well as the low diversity (cf. Nagyet al. 1984, 1990; Nagy 1992) suggest that the upper-most Pliensbachian – Toarcian sediments at Anholtrecord progressive shallowing of the environment. Thepresence of a few ammonite fragments and some dinofla-gellate cysts show that marine influence persisted. Theabsence of ostracods, the scarcity of burrows and therelatively common occurrence of Haplophragmoidesmay reflect reduced oxygen conditions at the sea floor.

During the following main part of the Toarcian suc-cession (upper palynomorph zone PB, 288–231 m) thesparse agglutinated foraminifera (Ammobaculites andBulbobaculites) and the marine dinoflagellate cystsgradually disappear. Upwards, storm-generated sandlayers become more frequent, thicker and coarser and,especially above 260 m, these sands have erosionalbases and show cross-lamination. This supports theinterpretation of a progressive shallowing, indicated bythe palaeobiological data. In the upper part of the inter-val, the presence of scattered lignite clasts and theincreased proportion of reworked palynomorphs sug-gest an increasing supply of particles from a shallowerpart of the coastal zone, temporarily exposed to ero-sion, and/or from a neighbouring coastal plain. Thecoal petrographic interpretation indicates that most ofthe organic material has a terrestrial origin.

Member F-IV of the Fjerritslev Formation (231–201 m)is broadly referred to the Aalenian Stage. There areonly few cores in this section, but the presence of lay-ers with relatively low total gamma-ray signals, indicatesthat substantial parts of the unit consist of sand and siltysand and were deposited under higher energy condi-tions than the sediments below. The palynomorphassemblage contains a significant proportion of fresh-water algae (palynomorph zone PC), which, combinedwith the occurrence of brackish-marine dinoflagellatesand acritarchs, indicates a brackish-marine influence inthe deltaic environment.

The remaining part of the Jurassic section, the upper-most Aalenian – Bajocian/Bathonian Haldager SandFormation (201–104 m), represents a delta plain envi-ronment with only occasional brackish water influence

in the lower part. This is shown by the absence offoraminifera and dinoflagellates, by the occurrence ofacritarchs only in the lower part, and by the presenceof brackish to freshwater algae throughout the section.The coal petrographic analysis indicates a marked dom-inance of terrestrial material, commonly with a varyingdegree of oxidation of the organic material. The cyclicalteration of sand, pebbly sand, clay, and lignite sup-ports the delta plain interpretation. In the lowermostHaldager Sand Formation, however, discrete thin fine-grained sand beds are significantly enriched in Th andU (Fig. 7), probably reflecting concentration of heavyminerals under high-energy (beach?) conditions.

Comparison with the central Danish BasinOur data indicate that at Anholt most of the Toarcianperiod was characterised by decreasing water depths. Inthe lower part of the Toarcian section, evidence of shal-lowing is less pronounced, but is very distinct in themid-Toarcian section. In the central Danish Basin, muchof the Toarcian was characterised by an increase in waterdepth (Michelsen 1978, 1989a), which may be correlatedwith a global sea-level rise (Hallam 1988). The sea-levelrise led to the establishment of stagnant bottom condi-tions (Pedersen 1986; Michelsen 1989a). In the centralpart of the Danish Basin, the shallowing of the basin firstbegan in the Late Toarcian (Michelsen 1989a, b).

Although the biostratigraphic data from Anholt doesnot prove the presence of a complete Toarcian section,we believe that most of the Toarcian Stage is represented,at least within the section of complete recovery below248 m, as no indications of hiatuses have been observedhere. It is deemed likely, therefore, that the regressive,shallowing event was initiated earlier at Anholt than inthe central parts of the Danish Basin.

We suggest that such an early regressive tendencyat Anholt may be explained by the palaeogeograph-ical position of the site. Anholt is located in a marginalposition relative to the Danish Basin and it is possiblethat progradation of the delta plain that characterisedthe entire Danish Basin in the Middle Jurassic (Michelsen1978), may have influenced Anholt earlier than elsewherein the basin. Another possible explanation may besought in local tectonic uplift in the FennoscandianBorder Zone, but we have no other indications of suchan Early Jurassic uplift in the area.

The boundary between the Fjerritslev and HaldagerSand Formations in the Danish Basin has previously beenconsidered to coincide with the Lower–Middle Jurassic

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boundary (Michelsen 1978, 1989b) although Michelsen& Nielsen (1991) suggested that the uppermost part ofthe Fjerritslev Formation may be Aalenian in age. Ouranalyses have shown that member F-IV of the FjerritslevFormation was deposited in Aalenian time. At Anholt,the Toarcian–Aalenian boundary (i.e. the Lower–MiddleJurassic boundary) is thought to correspond broadly tothe boundary between members F-III and F-IV of theFjerritslev Formation (Fig. 3).

Post-depositional history and diagenesisThe depth interval with vitrinite reflectance data is onlyabout 200 m thick and a depth-related trend in re-flectance is not evident. Nevertheless, a tentative esti-mate of uplift has been derived, suggesting that about1000 m of overburden are missing; this figure is com-patible with that derived by Petersen et al. (2003, thisvolume). This indicates that the maximum post-depo-

sitional subsidence of the Jurassic sediments at Anholtwas about 1100–1300 m. This value is not very accu-rate, but the range seems to fit well with data obtainedfrom other methods for quantification of uplift and ero-sion such as shale compaction, where sonic and den-sity logs are used to estimate the magnitude of uplift(Strømnes 1991; Japsen 1992; Jensen & Michelsen 1992;Jensen & Schmidt 1992, 1993; Lykke-Andersen et al.1993). The range of uplift values is compatible with val-ues estimated from the northernmost part of Jylland(Japsen 1992; Jensen & Michelsen 1992; Jensen & Schmidt1992, 1993). Together they define a regional uplift trendalmost parallel to the Fennoscandian Border Zone.

The regional trend in uplift for the Danish area showsthat no uplift or erosion has occurred in the CentralGraben, whereas increasing uplift took place in a north-easterly direction towards the Norwegian–Swedish coast,reaching a maximum of about 1500 m. Figure 16 showshow the data from Anholt fit into this overall trend.Though the magnitude of uplift estimated from differ-

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ent methods differs somewhat (Japsen 1992, 1993), theoverall trend in regional uplift superimposed by inver-sion along the Sorgenfrei–Tornquist Zone is clear.

Anholt is situated close to the Sorgenfrei–TornquistZone which was inverted during Late Cretaceous –Early Tertiary times. This zone is characterised by veryhigh total uplift values reaching about 2000 m (e.g. forthe Terne-1 well; B.J. Schmidt and L.N. Jensen, person-al communications 1994) representing an addition of600–700 m to the regional uplift. However, the upliftat Anholt does not reach a magnitude which demandsa contribution from Late Cretaceous – Early Paleoceneuplift within the inversion zone (Fig. 16). A structuralmap of the Top Chalk Group (Ter-Borch 1987) showsthat Upper Cretaceous sediments are found at depthsof 150–250 m below sea level both to the NE and SWof Anholt. On Anholt, Lower–Middle Jurassic sedimentsoccur at this depth, indicating differential uplift of theAnholt site of at least this magnitude relative to theareas to the NE and SW. This uplift might have takenplace during the inversion of the Sorgenfrei–TornquistZone. Thus, part of the uplift probably took place dur-ing the Late Cretaceous – Paleocene inversion, but themain uplift of the area took place in Oligocene–Recenttimes as part of the regional uplift of Scandinavia.

The mineralogical composition, dominated by detri-tal quartz, muscovite/illite and kaolinite, with a subor-dinate smectite contribution increasing down-section,indicates that the source areas for the Jurassic sedi-ments had been exposed to intense weathering.Diagenetic minerals such as chlorite are present in thelower part, but the presence of smectite demonstratesthat the illitisation process, seen in most other wells inthe Danish Basin, has not been significant. This is inaccordance with the relatively minor post-Jurassic sub-sidence of the Anholt area. The thermal stability of thekaolinite increases down-section. The well-crystallisedauthigenic kaolinite in the sand layers of the HaldagerSand Formation is less thermally stable than the detri-tal kaolinite. This indicates that the authigenic kaolin-ite formed after or during the Late Cretaceous – Tertiaryuplift and thus was not thermally stabilised during thesubsidence-related progressive diagenesis.

The Spectral Natural Gamma-ray log has enabledbetter definition of the lithological boundaries, especial-ly in sections with poor core recovery. In the transitionbetween the marine clays and the non-marine sands,very high concentrations of Th and U are present in rel-atively thin and well-defined layers. The origin of theselayers is not yet fully known, but concentration of Th-

and U-rich heavy minerals in a beach setting is thoughtto have been the dominant process.

ConclusionsThe present study has shown that member F-III of theFjerritslev Formation in the Anholt borehole is ofPliensbachian–Toarcian age, member F-IV is of Aalenianage and the Haldager Sand Formation is of latest Aalenian– Bajocian/Bathonian age.

The sediments of the Fjerritslev Formation are mostlymarine clays with varying proportions of storm sand lam-inae that generally increase up-section in abundance,thickness and grain-size. The Haldager Sand Formationconsists of an alteration of non-marine sand, clay anda few lignite layers. The sand layers are dominated byquartz and muscovite and, in the Haldager Sand For-mation, authigenic kaolinite and lignite clasts. The claysare dominated by kaolinite and illite with subordinatesmectite, increasing in proportion down-section, andmuscovite. In the lowermost Haldager Sand Formation,the presence of heavy mineral-enriched fine-grainedsand layers is inferred from geochemical anomalies.

Siderite and pyrite are commonly present as con-cretions, whereas calcite is only found in one concre-tion. The sand layers are unconsolidated and the claysstill plastic. The diagenetic maturation of the organicmaterial indicates that the sediments have been buriedto a depth of about 1100–1300 m, and later uplifted totheir present position, probably partly during LateCretaceous – Paleocene inversion and partly during thepost-Eocene regional uplift of parts of Scandinavia.

The detrital kaolinite exhibits a greater thermal sta-bility (increasing down-section) than that expected inkaolinite at depths between 100 and 300 m. It is believedthat the increased thermal stability was reached duringprogressive diagenesis, resulting from burial to a depthof 1200–1400 m. The progressive diagenesis did notreach the stage of complete illitisation of the originaldetrital smectite minerals.

The lowermost part of the section, member F-III ofthe Fjerritslev Formation, was deposited in a storm-influenced, marine, well-oxygenated environment. Theinfluence of storms decreased somewhat in the latestPliensbachian and earliest Toarcian, and the bottomconditions became more oxygen-deficient. Throughoutthe remaining part of the Toarcian, anoxic conditionsprevailed and the environment shallowed progressively,probably due to localised, marginal high sedimenta-tion rates despite the regional relative sea-level rise.

Deltaic environments dominated in latest Toarcian –Aalenian times, represented by the uppermost part ofmember F-III and member F-IV of the FjerritslevFormation. The Bajocian/Bathonian Haldager SandFormation is interpreted as a delta-plain deposit.

AcknowledgementsWe thank Henrik Friis for critically reading the manu-script, Jette Gissel Nielsen who processed the foram-iniferal samples and drafted some of the illustrations,Bitten Larsen and Yvonne Desezar for processing thepalynological samples, and Ulla Bjerring, Jette GrejsPedersen, Bente Winsløv Jensen and Terese K. Rasmus-sen for performing the sediment-analysis. Lis Olesen isthanked for drafting assistance. This work was sup-ported by the Danish Natural Science Research Council(GEOKAT and MAGKAT projects and an Ole Rømerstipendium to M.-S.S.) and the Carlsberg Foundation.

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