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The following list contains the Material Safety Data Sheets you requested. Please scoll down to view the requested MSDS(s). Product MSDS Distributor Format Language Quantity 2106069 N/A Hach Company OSHA English 1 2106069 N/A Hach Company ROWGHS English 1 __________________________________________________________________________________________________________ Total Enclosures: 2

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Page 1: The following list contains the Material Safety Data ... MSDS.pdf · The following list contains the Material Safety Data Sheets you requested. Please scoll down to view the requested

The following list contains the Material Safety Data Sheets you requested. Please scoll down to view the requested MSDS(s).

Product MSDS Distributor Format Language Quantity

2106069 N/A Hach Company OSHA English 12106069 N/A Hach Company ROWGHS English 1__________________________________________________________________________________________________________Total Enclosures: 2

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World HeadquartersHach CompanyP.O.Box 389 MSDS No: M00035Loveland, CO USA 80539(970) 669-3050

MATERIAL SAFETY DATA SHEET_____________________________________________________________________________1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: PhosVer ® 3 Phosphate ReagentCatalog Number: 2106069

Hach Company Emergency Telephone Numbers:P.O.Box 389 (Medical and Transportation)Loveland, CO USA 80539 (303) 623-5716 24 Hour Service(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M00035Chemical Name: Not applicableCAS No.: Not applicableChemical Formula: Not applicableChemical Family: MixtureHazard: Causes eye burns.Date of MSDS Preparation:

Day: 11Month: AprilYear: 2014

_____________________________________________________________________________2. COMPOSITION / INFORMATION ON INGREDIENTS

Potassium PyrosulfateCAS No.: 7790-62-7 TSCA CAS Number: 7790-62-7 Percent Range: 75.0 - 85.0Percent Range Units: weight / weightLD50: Oral rat LD50 = 2340 mg/kgLC50: None reportedTLV: 10 mg/m3 as inhalable dust; 3 mg/m3 as respirable dustPEL: 15 mg/m3 as inhalable dust; 5 mg/m3 as respirable dustHazard: Causes eye burns.

Ascorbic AcidCAS No.: 50-81-7 TSCA CAS Number: 50-81-7 Percent Range: 15 - 20Percent Range Units: weight / weightLD50: Oral rat LD50 = 11900 mg/kgLC50: None reportedTLV: 10 mg/m3 as inhalable dust; 3 mg/m3 as respirable dustPEL: 15 mg/m3 as total dust; 5 mg/m3 as respirable dustHazard: Practically non-toxic.

Potassium Antimonyl TartrateCAS No.: 28300-74-5 TSCA CAS Number: 11071-15-1 Percent Range: <0.2Percent Range Units: weight / weightLD50: Oral rat LD50 = 115 mg/kg; Oral human LDLo = 2 mg/kg.LC50: None reported.TLV: 0.5 mg/m³ (as Sb)

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PEL: 0.5 mg/m³ (as Sb)Hazard: Toxic.Experimental mutagen.

Sodium MolybdateCAS No.: 7631-95-0 TSCA CAS Number: 7631-95-0 Percent Range: <2Percent Range Units: weight / weightLD50: Oral Rat LD50 = 250-4000 mg/kg; Oral Guinea Pig LD50 = 310 mg/kgLC50: Inhalation Rat LC50 > 2080 mg/m³/4 hrs (2.08 mg/L/4 hr)TLV: 5 mg/m³ (as Mo)PEL: 5 mg/m³ (as Mo)Hazard: Harmful if swallowedHarmful if inhaled.May cause eye irritation.

EDTA Tetrasodium SaltCAS No.: 64-02-8 TSCA CAS Number: 64-02-8 Percent Range: < 0.5Percent Range Units: weight / weightLD50: Oral Rat: 1700 to 2700 mg/kg; LD50 Oral rat = 630-1,260 mg/kgLC50: None reportedTLV: 10 mg/m3 as inhalable dust; 3 mg/m3 as respirable dustPEL: 15 mg/m3 as total dust; 5 mg/m3 as respirable dustHazard: Harmful if swallowedCauses eye burns.

_____________________________________________________________________________3. HAZARDS IDENTIFICATION

Emergency Overview:Appearance: White to off-white powderOdor: OdorlessCAUSES EYE BURNS MAY CAUSE RESPIRATORY TRACT IRRITATION

HMIS:Health: 1Flammability: 1Reactivity: 0Protective Equipment: X - See protective equipment, Section 8.

NFPA:Health: 3Flammability: 1Reactivity: 0Symbol: Not applicable

Potential Health Effects:Eye Contact: May cause irritiationSkin Contact: No effects are anticipatedSkin Absorption: None reported

Target Organs: None reportedIngestion: May be harmful if swallowed May cause: copper deficiency anemia gout loss of appetite loss ofcoordination listlessness diarrhea liver damage May effect enzyme activity.

Target Organs: Blood LiverInhalation: Large doses may cause: Effects similar to those of ingestion.

Target Organs: Blood LiverMedical Conditions Aggravated: Pre-existing: Eye conditions Respiratory conditions GoutChronic Effects: Chronic overexposure may cause copper deficiency enzyme activity effects liver damageMolybdenum poisoning signs include loss of appetite, listlessness and reduced growth rate. Excessive exposure tomolybdenum compounds may cause gout and anemia.Cancer / Reproductive Toxicity Information:This product does NOT contain any OSHA listed carcinogens.This product does NOT contain any IARC listed chemicals.This product does NOT contain any NTP listed chemicals.

Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.Toxicologically Synergistic Products: None reported

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_____________________________________________________________________________4. FIRST AID

Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician if irritation develops.Skin Contact (First Aid): Wash skin with plenty of water.Ingestion (First Aid): Never give anything by mouth to an unconscious person. Do not induce vomiting. Give 1-2 glassesof water. If you feel unwell, contact a physician.Inhalation: Remove to fresh air. Give artificial respiration if necessary.

_____________________________________________________________________________5. FIRE FIGHTING MEASURES

Flammable Properties: Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHScriteria.Flash Point: Not applicableMethod: Not applicableFlammability Limits:

Lower Explosion Limits: Not applicableUpper Explosion Limits: Not applicable

Autoignition Temperature: Not determinedHazardous Combustion Products: Toxic fumes of: sulfur oxides. carbon monoxide, carbon dioxide. sodium monoxidepotassium oxidesFire / Explosion Hazards: None reported

Static Discharge: None reported.Mechanical Impact: None reported

Extinguishing Media: Use media appropriate to surrounding fire conditionsFire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.

_____________________________________________________________________________6. ACCIDENTAL RELEASE MEASURES

Spill Response Notice:Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill

according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only personsproperly qualified according to state or local regulations should respond to a spill involving chemicals.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: Sweep up material. Dispose of in accordance with local, state and federal regulations or laws.Decontaminate the area of the spill with a soap solution.Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan) when:any quantity is spilled.Special Instructions (for accidental release): Not applicable304 EHS RQ (40 CFR 355): Not applicableD.O.T. Emergency Response Guide Number: None

_____________________________________________________________________________7. HANDLING / STORAGE

Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrialhygiene practices when using this product.Storage: Store between 10° and 25°C.

Flammability Class: Not applicable_____________________________________________________________________________8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT

Engineering Controls: Maintain general industrial hygiene practices when using this product.Personal Protective Equipment:

Eye Protection: safety glasses with top and side shieldsSkin Protection: nitrile gloves In the EU, the selected gloves must satisfy the specifications of EU Directive89/686/EEC and standard EN 374 derived from it. lab coatInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling.

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TLV: Not establishedPEL: Not established

_____________________________________________________________________________9. PHYSICAL / CHEMICAL PROPERTIES

Appearance: White to off-white powderPhysical State: SolidMolecular Weight: Not applicableOdor: OdorlesspH: of a 5% solution = 1.5Vapor Pressure: Not applicableVapor Density (air = 1): Not applicableBoiling Point: Not determinedMelting Point: 105 °C (221 °F)Specific Gravity/ Relative Density (water = 1; air =1): 2.22Evaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: Not applicablePartition Coefficient (n-octanol / water): Not applicableSolubility:

Water: SolubleAcid: SolubleOther: Not determined

Metal Corrosivity:Steel: Not applicableAluminum: Not applicable

_____________________________________________________________________________10. STABILITY / REACTIVITY

Chemical Stability: Stable when stored under proper conditions.Conditions to Avoid: Extreme temperaturesReactivity / Incompatibility: Incompatible with: oxidizers dyes alkalies iron copperHazardous Decomposition: Heating to decomposition releases: carbon dioxide carbon monoxide sulfur oxides potassiumoxide sodium oxidesHazardous Polymerization: Will not occur.

_____________________________________________________________________________11. TOXICOLOGICAL INFORMATION

Product Toxicological Data:LD50: ATE Oral Rat LD50 = 2367 mg/kgLC50: ATE Inhalation Rat LC50 > 87 mg/L/4 hrDermal Toxicity Data: None reportedSkin and Eye Irritation Data: Not corrosive to skin, no erythemaMutation Data: None reportedReproductive Effects Data: None reported

Ingredient Toxicological Data: Potassium Pyrosulfate: Oral Rat LD50 = 2340 mg/kg. Sodium Molybdate: Oral Rat LD50= 250-4000 mg/kg; Inhalation Rat LC50 > 2.08 mg/L/4 hr. EDTA Tetrasodium salt: Oral Rat LD50 = 1780 mg/kg.Potassium Antimonyl Tartrate: Oral Rat LD50 = 115 mg/kg.

_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: --No ecological data available for this product. No bioaccumulation potential Mobility in soil: High Based on classification

principles, not classified as hazardous to the environment.Ingredient Ecological Information: Potassium Antimonyl Tartrate: 96 hr Fish LC50 = 12.5 mg/L; 48 hr Daphnia magnaEC50 = 5 mg/LCEPA categorization for ingredients are as follows:Potassium antimonyl tartrate: Persistent and inherently toxic to aquatic organisms.

_____________________________________________________________________________13. DISPOSAL CONSIDERATIONS

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EPA Waste ID Number: NoneSpecial Instructions (Disposal): Work in an approved fume hood. Dilute material with excess water making a weaker than5% solution. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. If permitted byregulation, Open cold water tap completely, slowly pour the reacted material to the drain. Allow cold water to run for 5minutes to completely flush the system. Otherwise, Check with national, local municipal and state authorities and wastecontractors for pertinent local information on the disposal of this article.Empty Containers: Rinse three times with an appropriate solvent. Collect rinsate and dispose of according to local, state orfederal regulations. In the US, rinsate from empty containers is classified as hazardous waste and should be disposed of atan E.P. A. approved facility. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information.

_____________________________________________________________________________14. TRANSPORT INFORMATION

D.O.T.:D.O.T. Proper Shipping Name: Not Currently Regulated--

DOT Hazard Class: NADOT Subsidiary Risk: NADOT ID Number: NADOT Packing Group: NA

I.C.A.O.:I.C.A.O. Proper Shipping Name: Not Currently Regulated--

ICAO Hazard Class: NAICAO Subsidiary Risk: NAICAO ID Number: NAICAO Packing Group: NA

I.M.O.:I.M.O. Proper Shipping Name: Not Currently Regulated--

I.M.O. Hazard Class: NAI.M.O. Subsidiary Risk: NAI.M.O. ID Number: NAI.M.O. Packing Group: NA

Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed ofvarious compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies. If the item ISpart of a set or kit, the classification would change to the following: UN3316 Chemical Kit, Class 9, PG II or III. If the itemis not regulated, the Chemical Kit classification does not apply.

_____________________________________________________________________________15. REGULATORY INFORMATION

U.S. Federal Regulations:O.S.H.A.: This product meets the criteria for a hazardous substance as defined in the Hazard Communication Standard.(29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health Hazard Delayed(Chronic) Health HazardS.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject to the reportingrequirements of Section 313 of Title III of SARA.--

302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Not applicable304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Not applicableRCRA: Contains no RCRA regulated substances.

C.P.S.C.: Not applicableState Regulations:

California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s): None

California Perchlorate Rule CCR Title 22 Chap 33: Not applicable

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Trade Secret Registry: Not applicableNational Inventories:

U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).TSCA CAS Number: Not applicable

_____________________________________________________________________________16. OTHER INFORMATION

Intended Use: Laboratory Use Phosphate determinationReferences: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference ofGovernmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,1989. pp. 2332-2983. In-house information. Technical Judgment. Outside Testing. NIOSH/OSHA Occupational HealthGuidelines for Chemical Hazards. Cincinnati: Department of Health and Human Services, 1981. Sax, N. Irving.Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al.Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. VendorInformation. Patty, Frank A. Industrial Hygiene and Toxicology, 3rd Revised Edition. Volume 2. New York: A Wiley-Interscience Publication, 1981.Revision Summary: Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (ST/SG/AC.10/36/Add.3).

_____________________________________________________________________________

Legend:NA - Not Applicable w/w - weight/weightND - Not Determined w/v - weight/volumeNV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safetyprograms in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATAOR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

HACH COMPANY ©2014

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World HeadquartersHach CompanyP.O.Box 389 MSDS No: M00035Loveland, CO USA 80539(970) 669-3050

MATERIAL SAFETY DATA SHEET_____________________________________________________________________________1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: PhosVer ® 3 Phosphate ReagentCatalog Number: 2106069

Hach Company Emergency Telephone Numbers:P.O.Box 389 (Medical and Transportation)Loveland, CO USA 80539 (303) 623-5716 24 Hour Service(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M00035Chemical Name: Not applicableCAS Number: Not applicableAdditional CAS No. (for hydrated forms): Not applicableChemical Formula: Not applicableChemical Family: MixtureIntended Use: Laboratory Use Phosphate determination

_____________________________________________________________________________2. HAZARDS IDENTIFICATION

GHS Classification:Hazard categories: Serious Eye Damage/Eye Irritation:Eye Irrit. 2 Not applicable

GHS Label Elements:WARNING

Hazard statements: H: Not applicable Causes serious eye irritation.Precautionary statements: Wear protective gloves / protective clothing / eye protection / face protection. Washthoroughly after handling. Call a POISON CENTER or doctor/physician if you feel unwell. Wear eye protection. IF INEYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. If eye irritation persists: Get medical advice/attention.

HMIS:Health: 1Flammability: 1Reactivity: 0Protective Equipment: X - See protective equipment, Section 8.

NFPA:Health: 3Flammability: 1Reactivity: 0Symbol: Not applicable

WHMIS Hazard Classification: Class D, Division 2, Subdivision B - Toxic material (other toxic effects)WHMIS Symbols: Other Toxic Effects

_____________________________________________________________________________3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Components according to GHS:

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Potassium Pyrosulfate

CAS Number: 7790-62-7 Chemical Formula: K2S2O7

GHS Classification: Eye Irrit. 2, H319Percent Range: 75.0 - 85.0Percent Range Units: weight / weightPEL:TLV:

WHMIS Symbols: Other Toxic EffectsSodium Molybdate

CAS Number: 7631-95-0 Chemical Formula: Na2MoO4 · 2H2OGHS Classification: Acute Tox. Inh. 4, H332; Acute Tox. Orl. 4, H302; Eye Irrit. 2, H319Percent Range: <2Percent Range Units: weight / weightPEL: 5 mg/m³ (as Mo)TLV: 5 mg/m³ (as Mo)

WHMIS Symbols: Acute PoisonOther Toxic EffectsEDTA Tetrasodium Salt

CAS Number: 64-02-8 Chemical Formula: C10H12N2Na4O8 2H2OGHS Classification: Acute Tox. 4-Orl, H302; Eye Dam. 1, H318Percent Range: < 0.5Percent Range Units: weight / weightPEL: 15 mg/m3 as total dust; 5 mg/m3 as respirable dustTLV: 10 mg/m3 as inhalable dust; 3 mg/m3 as respirable dust

WHMIS Symbols: Other Toxic EffectsPotassium Antimonyl Tartrate

CAS Number: 11071-15-1 Chemical Formula: C8H4K2O12Sb2

. 3H2OGHS Classification: Acute Tox. Inh 4, H332; Acute Tox. Orl. 4, H302; Aquat. Chron. 2, H411Percent Range: <0.2Percent Range Units: weight / weightPEL: 0.5 mg/m³ (as Sb)TLV: 0.5 mg/m³ (as Sb)

WHMIS Symbols: Acute PoisonHazardous Components according to GHS: No

Ascorbic Acid

CAS Number: 50-81-7 Chemical Formula: C6H8O6

GHS Classification: Not applicablePercent Range: 15 - 20Percent Range Units: weight / weightPEL: 15 mg/m3 as total dust; 5 mg/m3 as respirable dustTLV: 10 mg/m3 as inhalable dust; 3 mg/m3 as respirable dust

WHMIS Symbols: Not applicable_____________________________________________________________________________4. FIRST AID MEASURES

General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to adoctor.Advice to doctor: Treat symptomatically.

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Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician if irritation develops.Skin Contact (First Aid): Wash skin with plenty of water.Inhalation: Remove to fresh air. Give artificial respiration if necessary.Ingestion (First Aid): Never give anything by mouth to an unconscious person. Do not induce vomiting. Give 1-2 glassesof water. If you feel unwell, contact a physician.

_____________________________________________________________________________5. FIRE FIGHTING MEASURES

Flammable Properties: Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHScriteria.Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protectivegear.Extinguishing Media: Use media appropriate to surrounding fire conditionsExtinguishing Media NOT To Be Used: Not applicableFire / Explosion Hazards: None reportedHazardous Combustion Products: Toxic fumes of: sulfur oxides. carbon monoxide, carbon dioxide. sodium monoxidepotassium oxides

_____________________________________________________________________________6. ACCIDENTAL RELEASE MEASURES

Spill Response Notice:Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill

according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan andguidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only personsproperly qualified according to state or local regulations should respond to a spill involving chemicals.Containment Technique: Stop spilled material from being released to the environment.Clean-up Technique: Sweep up material. Dispose of in accordance with local, state and federal regulations or laws.Decontaminate the area of the spill with a soap solution.Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan) when:any quantity is spilled.DOT Emergency Response Guide Number: Not applicable

_____________________________________________________________________________7. HANDLING AND STORAGE

Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrialhygiene practices when using this product.Storage: Store between 10° and 25°C.Flammability Class: Not applicable

_____________________________________________________________________________8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls: Maintain general industrial hygiene practices when using this product.Personal Protective Equipment:

Eye Protection: safety glasses with top and side shieldsSkin Protection: nitrile gloves In the EU, the selected gloves must satisfy the specifications of EU Directive89/686/EEC and standard EN 374 derived from it. lab coatInhalation Protection: adequate ventilation

Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Wash thoroughly after handling.TLV: Not establishedPEL: Not establishedFor Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:

_____________________________________________________________________________9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: White to off-white powderPhysical State: SolidMolecular Weight: Not applicableOdor: OdorlessOdor Threshold: Not applicablepH: of a 5% solution = 1.5

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Metal Corrosivity:Corrosivity Classification:Steel: Not ApplicableAluminum: Not Applicable

Specific Gravity/ Relative Density (water = 1; air =1): 2.22Viscosity: Not applicableSolubility:

Water: SolubleAcid: SolubleOther: Not determined

Partition Coefficient (n-octanol / water): Not applicableCoefficient of Water / Oil: Not applicableMelting Point: 105 °C (221 °F)Decomposition Temperature: Not availableBoiling Point: Not determinedVapor Pressure: Not applicableVapor Density (air = 1): Not applicableEvaporation Rate (water = 1): Not applicableVolatile Organic Compounds Content: Not applicableFlammable Properties: Can burn in fire, releasing toxic vapors. Material is not classified as flammable according to GHScriteria.Flash Point: Not applicable

Method: Not applicableFlammability Limits:

Lower Explosion Limits: Not applicableUpper Explosion Limits: Not applicable

Autoignition Temperature: Not determinedExplosive Properties:Not classified according to GHS criteria.

Oxidizing Properties:Not classified according to GHS criteria.

Reactivity Properties:Not classifed as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according to GHS

criteria.Gas under Pressure:Not classified according to GHS criteria.Not classified according to GHS criteria.

_____________________________________________________________________________10. STABILITY AND REACTIVITY

Chemical Stability: Stable when stored under proper conditions.Mechanical Impact: None reportedStatic Discharge: None reported.Reactivity / Incompatibility: Incompatible with: oxidizers dyes alkalies iron copperHazardous Decomposition: Heating to decomposition releases: carbon dioxide carbon monoxide sulfur oxides potassiumoxide sodium oxidesConditions to Avoid: Extreme temperatures

_____________________________________________________________________________11. TOXICOLOGICAL INFORMATION

Toxicokinetics, Metabolism and Distribution: No information available for mixture.Toxicologically Synergistic Products: None reportedAcute Toxicity: Acute Toxicity Estimate (ATE) - Calculated from Ingredient Toxicity Data Route Data Given BelowOral Rato LD50 = 2367 mg / kgInalação Rato LC50 = 87 mg/l/4 hr

Specific Target Organ Toxicity - Single Exposure (STOT-SE): Based on classification principles, the classification criteriaare not met.Specific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classificationcriteria are not met.Skin Corrosion/Irritation: Based on classification principles, the classification criteria are not met.Hach Company testing data: 80% mixture of potassium pyrosulfate - NOT corrosive to to skin.

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Eye Damage: Irritating to eyes.Sensitization: Based on classification principles, the classification criteria are not met.CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): Based on classification principles, theclassification criteria are not met.

_____________________________________________________________________________12. ECOLOGICAL INFORMATION

Product Ecological Information: --No ecological data available for this product. No bioaccumulation potential Mobility in soil: Highly mobile Based on

classification principles, not classified as hazardous to the environment.Ingredient Ecological Information: Potassium Antimonyl Tartrate: 96 hr Fish LC50 = 12.5 mg/L; 48 hr Daphnia magnaEC50 = 5 mg/L

_____________________________________________________________________________13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: Not applicableSpecial Instructions (Disposal): Work in an approved fume hood. Dilute material with excess water making a weaker than5% solution. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. If permitted byregulation, Open cold water tap completely, slowly pour the reacted material to the drain. Allow cold water to run for 5minutes to completely flush the system. Otherwise, Check with national, local municipal and state authorities and wastecontractors for pertinent local information on the disposal of this article.Empty Containers: Rinse three times with an appropriate solvent. Collect rinsate and dispose of according to local, state orfederal regulations. In the US, rinsate from empty containers is classified as hazardous waste and should be disposed of atan E.P. A. approved facility. Dispose of empty container as normal trash.NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringentstate or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemicaland analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging mustbe disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.

_____________________________________________________________________________14. TRANSPORT INFORMATION

D.O.T.:D.O.T. Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAID Number: NAPacking Group: NA

T.D.G.:Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAUN Number/PIN: NAPacking Group: NA

I.C.A.O.:I.C.A.O. Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAID Number: NAPacking Group: NA

I.M.O.:Proper Shipping Name: Not Currently Regulated--

Hazard Class: NASubsidiary Risk: NAID Number: NAPacking Group: NA

Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed ofvarious compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies. If the item IS

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part of a set or kit, the classification would change to the following: UN3316 Chemical Kit, Class 9, PG II or III. If the itemis not regulated, the Chemical Kit classification does not apply.

_____________________________________________________________________________15. REGULATORY INFORMATION

U.S. Federal Regulations:O.S.H.A.: This product meets the criteria for a hazardous substance as defined in the Hazard Communication Standard.(29 CFR 1910.1200)E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health Hazard Delayed(Chronic) Health HazardS.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject to the reportingrequirements of Section 313 of Title III of SARA.--

302 (EHS) TPQ (40 CFR 355): Not applicable304 CERCLA RQ (40 CFR 302.4): Not applicable304 EHS RQ (40 CFR 355): Not applicableClean Water Act (40 CFR 116.4): Not applicableRCRA: Contains no RCRA regulated substances.

State Regulations:California Prop. 65: No Prop. 65 listed chemicals are present in this product.Identification of Prop. 65 Ingredient(s): NoneCalifornia Perchlorate Rule CCR Title 22 Chap 33: Not applicableTrade Secret Registry: Not applicable

National Inventories:U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).

CAS Number: Not applicableCanadian Inventory Status: All ingredients of this product are DSL Listed.EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.Australian Inventory (AICS) Status: All ingredients are listed.New Zealand Inventory (NZIoC) Status: All components either listed or exempt.Korean Inventory (KECI) Status: Not listed - exempt. Quantity < 100 kg per annum.Japan (ENCS) Inventory Status: All components either listed or exempt.China (PRC) Inventory (MEP) Status: All components either listed or exempt.

_____________________________________________________________________________16. OTHER INFORMATION

References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference ofGovernmental Industrial Hygienists, 1992. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,1989. pp. 2332-2983. In-house information. Technical Judgment. Outside Testing. NIOSH/OSHA Occupational HealthGuidelines for Chemical Hazards. Cincinnati: Department of Health and Human Services, 1981. Sax, N. Irving.Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al.Clinical Toxicology of Commercial Products, 5th Ed. Baltimore: The Williams and Wilkins Co., 1984. VendorInformation. Patty, Frank A. Industrial Hygiene and Toxicology, 3rd Revised Edition. Volume 2. New York: A Wiley-Interscience Publication, 1981.Complete Text of H phrases referred to in Section 3: H319 Causes serious eye irritation. H332 Harmful if inhaled. H302Harmful if swallowed.Revision Summary: Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS (ST/SG/AC.10/36/Add.3).Date of MSDS Preparation:

Day: 11Month: AprilYear: 2014

MSDS Prepared: MSDS prepared by Product Compliance Department extension 3350CCOHS Evaluation Note: It is offered under the interim policy that was established by Health Canada permitting use ofGHS-formatted safety data sheets in Canada prior to revision of CPR to GHS. This product has been classified and labeledin accordance with the requirements of GHS (ST/SG/AC.10/36/Add.3).

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Legend:NA - Not Applicable w/w - weight/weight

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ND - Not Determined w/v - weight/volumeNV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safetyprograms in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATAOR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

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