tfie analysis and fate of acrylamide monomer...

36
TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER IN AQUEOUS ENVIRONMENTS. L'b/l/ FINAL REPORT, OCTOBER, 1980 Contract DGR 480/306. Dr. L. Brown, Dr. M. M. Rhead Room 544, Faculty of Science, Department of Environmental Sciences, John Graymore Chemistry Laboratory, Plymouth Polytechnic, Drake Circus Plymouth. Preface The use of acrylamide based polymers for various water treatments is increasing. Concern has been expressed at this prospect as these polymers contain the neurotoxin acrylamide as a contaminant. A potential therefore exists for the pollution of water supplies. This research project, which was carried out for and funded by the Department of the Environment, was established to achieve the following objectives:- 1. To produce an analytical procedure for the determination of mono acrylamide in aqueous solutions capable of being used on a variety of effluents and UK waters without interference. 2. To assess the extent ofadsorptionofasrylamide monomer onto sludge and sediments. 3. To study-the rate and extent of degradation or change of monoacrylamide in natural water samples and sediments (laboratory and in situ) -- The ensuing report details information obtained at Plymouth Polytechnic during the successful completion of this project.

Upload: nguyennhu

Post on 24-Mar-2018

219 views

Category:

Documents


2 download

TRANSCRIPT

Page 1: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory

TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER IN AQUEOUS ENVIRONMENTS. L'b/l/

FINAL REPORT, OCTOBER, 1980

Contract DGR 480/306.

Dr. L. Brown, Dr. M. M. Rhead

Room 544, Faculty of Science, Department of Environmental Sciences,

John Graymore Chemistry Laboratory, Plymouth Polytechnic, Drake Circus

Plymouth.

Preface

The use of acrylamide based polymers for various water treatments is

increasing. Concern has been expressed at this prospect as these polymers

contain the neurotoxin acrylamide as a contaminant. A potential therefore

exists for the pollution of water supplies. This research project, which

was carried out for and funded by the Department of the Environment, was

established to achieve the following objectives:-

1. To produce an analytical procedure for the determination of mono

acrylamide in aqueous solutions capable of being used on a variety

of effluents and UK waters without interference.

2. To assess the extent ofadsorptionofasrylamide monomer onto sludge

and sediments.

3. To study-the rate and extent of degradation or change of monoacrylamide

in natural water samples and sediments (laboratory and in situ) --

The ensuing report details information obtained at Plymouth Polytechnic

during the successful completion of this project.

Page 2: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 3: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 4: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 5: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 6: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 7: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 8: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 9: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 10: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 11: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 12: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 13: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 14: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 15: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 16: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 17: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 18: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 19: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 20: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 21: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 22: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 23: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 24: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 25: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 26: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 27: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 28: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 29: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 30: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 31: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 32: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 33: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 34: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 35: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory
Page 36: TFIE ANALYSIS AND FATE OF ACRYLAMIDE MONOMER …dwi.defra.gov.uk/research/completed-research/reports/dwi0084.pdf · Preface The use of ... in natural water samples and sediments (laboratory