temperature effects on the peak and large-displacement

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250 Temperature Effects on the Peak and Large-Displacement Shear Strength of Needle-Punched Reinforced GCLs Shahin Ghazizadeh 1 and Christopher A. Bareither 2 1 Graduate Research Assistant, Civil & Environmental Engineering, Colorado State University, Fort Collins, CO 80523; [email protected] 2 Associate Professor, Civil & Environmental Engineering, Colorado State University, Fort Collins, CO 80523; [email protected] ABSTRACT The objective of this study was to evaluate the effect of temperature on the peak and large- displacement shear strength of needle-punched reinforced geosynthetic clay liners (NP GCLs). A series of displacement-controlled internal shear tests were performed at room temperature (20 °C) and elevated temperature (80 °C). Experiments were performed on two non-heat-treated NP GCLs with different peel strength. An increase in temperature changed the failure mode from reinforcement fiber disentanglement to fiber rupture at low normal stresses. The peak shear strength of both NP GCLs reduced at 80 °C, whereby the peak shear strength reduction was 36% to 42% for the lower peel strength NP GCL and 19% to 25% for the higher peel strength NP GCL. The large-displacement shear strength of both NP GCLs was comparable, and negligible change in large displacement shear strength was observed for shear tests at 20 °C and 80°C. INTRODUCTION Needle-punched geosynthetic clay liners (NP GCLs) are internally reinforced GCLs whereby fibers from a non-woven cover geotextile are punched through the bentonite layer and entangled into the carrier geotextile that can be woven or non-woven. A primary objective of the internal needle-punched reinforcement fibers is to increase the internal shear strength of GCLs above the internal friction angle of hydrated sodium bentonite, which can be ≤ 4° (Mesri and Olson 1970). The internal shear strength of NP GCLs is predominantly attributed to strength of the reinforcement fibers, which yields internal shear resistance via tensile strength of the fibers and frictional resistance of the connections between the reinforcement fibers and carrier geotextile (e.g., Müller et al. 2008; Fox and Stark 2015; Bareither et al. 2018). The use of GCLs in waste containment applications can expose GCLs to elevated temperatures due to exothermic chemical and biological processes. For example, temperatures in the liner system of heap leach pads can be as high as 45-50 °C in copper leaching and 75 °C in nickel leaching (Smith 2008). Geosynthetic clay liners used in municipal solid waste landfills can experiences temperatures above 60 °C (Koerner and Koerner 2006; Hanson et al. 2010, Stark et al. 2014; Yeşiller et al 2015). Previous studies have documented a decrease in the mechanical properties of geosynthetics and polymeric materials (e.g., tensile strength, tensile modulus,

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Page 1: Temperature Effects on the Peak and Large-Displacement

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Temperature Effects on the Peak and Large-Displacement Shear Strength of Needle-Punched Reinforced GCLs

Shahin Ghazizadeh1 and Christopher A. Bareither2

1Graduate Research Assistant, Civil & Environmental Engineering, Colorado State University, Fort Collins, CO 80523; [email protected] 2Associate Professor, Civil & Environmental Engineering, Colorado State University, Fort Collins, CO 80523; [email protected]

ABSTRACT The objective of this study was to evaluate the effect of temperature on the peak and large-displacement shear strength of needle-punched reinforced geosynthetic clay liners (NP GCLs). A series of displacement-controlled internal shear tests were performed at room temperature (20 °C) and elevated temperature (80 °C). Experiments were performed on two non-heat-treated NP GCLs with different peel strength. An increase in temperature changed the failure mode from reinforcement fiber disentanglement to fiber rupture at low normal stresses. The peak shear strength of both NP GCLs reduced at 80 °C, whereby the peak shear strength reduction was 36% to 42% for the lower peel strength NP GCL and 19% to 25% for the higher peel strength NP GCL. The large-displacement shear strength of both NP GCLs was comparable, and negligible change in large displacement shear strength was observed for shear tests at 20 °C and 80°C. INTRODUCTION Needle-punched geosynthetic clay liners (NP GCLs) are internally reinforced GCLs whereby fibers from a non-woven cover geotextile are punched through the bentonite layer and entangled into the carrier geotextile that can be woven or non-woven. A primary objective of the internal needle-punched reinforcement fibers is to increase the internal shear strength of GCLs above the internal friction angle of hydrated sodium bentonite, which can be ≤ 4° (Mesri and Olson 1970). The internal shear strength of NP GCLs is predominantly attributed to strength of the reinforcement fibers, which yields internal shear resistance via tensile strength of the fibers and frictional resistance of the connections between the reinforcement fibers and carrier geotextile (e.g., Müller et al. 2008; Fox and Stark 2015; Bareither et al. 2018).

The use of GCLs in waste containment applications can expose GCLs to elevated temperatures due to exothermic chemical and biological processes. For example, temperatures in the liner system of heap leach pads can be as high as 45-50 °C in copper leaching and 75 °C in nickel leaching (Smith 2008). Geosynthetic clay liners used in municipal solid waste landfills can experiences temperatures above 60 °C (Koerner and Koerner 2006; Hanson et al. 2010, Stark et al. 2014; Yeşiller et al 2015). Previous studies have documented a decrease in the mechanical properties of geosynthetics and polymeric materials (e.g., tensile strength, tensile modulus,

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elongation) with an increase in temperature (e.g., Andrawes et al. 1984, Ariyama et al. 1997, Kongkitkul et al. 2012, Karademir and Frost 2014). Considering that the internal shear strength of reinforced GCLs is predominantly attributed to polymeric reinforcement fibers, Bareither et al. (2018) recently demonstrated that the peak shear strength (τp) of NP GCLs measured in displacement-controlled shear tests reduced when the temperature was increased from 20 °C and 80°C. This reduced τp agrees with other research on NP GCLs in stress-controlled shear boxes whereby elevated temperatures were used to facilitate failure at shorter elapsed times or under lower applied stress conditions (Müller et al 2008; Zanzinger and Saathoff 2012; Zanzinger 2016; Ghazizadeh and Bareither 2018a,b).

The objective of this study was to expand the current understanding of the effects of elevated temperature on internal shear strength of NP GCLs. To this extent, two non-heat-treated NP GCLs with different peel strength were evaluated via displacement-controlled direct shear testing. Testing was conducted at room temperature (20 °C) and an elevated temperature of 80 °C. In addition to τp, large-displacement shear strength (τld) was also evaluated to assess the influence of temperature on peak (φp) and large-displacement (φld) friction angles for NP GCLs. MATERIALS Characteristics and properties of the two NP GCLs used in this study, herein referred to as GCL-A and GCL-B, are tabulated in Table 1. These two NP GCLs were commercially available, non-heat-treated NP GCLs that included different geotextile characteristics (i.e., geotextile mass per area) and peel strength. GCL-A had peel strength = 2180 N/m and was a representative of NP GCLs typically used in high stress applications, whereas GCL-B had lower peel strength = 790 N/m and was representative of a NP GCL used in low stress applications.

Table 1. Characteristics and properties of non-heat-treated NP GCLs. Properties Standard GCL-A GCL-B Peel strength (N/m) ASTM D 6496 2180 790 Heat Treatment Method ― NHT NHT Carrier geotextile type ― W W Cover geotextile type ― NW NW Carrier geotextile mass/area (g/m2) ASTM D5261 130 110 Cover geotextile mass/area (g/m2) ASTM D5261 230 130 Bentonite mass per area (g/m2) ASTM D5993 4910 5220 Notes: NHT = non-heat-treated, NW = non-woven; W = woven

EXPERIMENTAL PROCEDURE Displacement-controlled direct shear tests were performed at 20 °C and 80 °C in a direct shear apparatus capable of controlling elevated temperatures throughout the duration of shear. All direct shear tests were conducted on 150 mm x 150 mm GCL specimens that were aligned with the machine direction in the direction of shear. Design details of the direct shear apparatus and verification of the ability to test smaller-size GCL specimens that yield representative shear strength to recommendations in ASTM D 6243 are in Bareither et al. (2018).

Geosynthetic clay liner test specimens were cut from a sample roll in accordance with ASTM D6072. A two-stage hydration and consolidation procedure was used to prepare all GCL

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test specimens for shear testing (e.g., Fox et al. 1998; Fox and Ross 2011; Bareither et al. 2018). In Stage I (i.e., hydration stage), specimens were hydrated for 48 h with de-ionized water under a normal stress (σn) = 20 kPa. After completion of Stage I, specimens were transferred to the direct shear apparatus and σn = 20 kPa was reapplied to represent the end-state conditions of Stage I. Normal stress was increased in Stage II (i.e., consolidation stage) via doubling the σn every 4-6 h until the target normal stress for shearing (σn-s) was obtained. After reaching σn-s, specimens were equilibrated under σn-s for at least 24 h before the start of shearing. In elevated temperature experiments, the temperature was increased to 80 °C approximately 6 hr prior to the start of shearing to allow temperature equilibration within the GCL.

All direct shear tests were performed at a displacement rate = 0.1 mm/min as suggested in ASTM D 6243. Specimens were sheared to a maximum horizontal displacement (δh) ≥ 70 mm to capture τp and τld. Large-displacement shear strength was defined in this study as the shear stress at δh = 70 mm and is denoted as τ70. Furthermore, since the shearing area of the GCL reduced during the shear tests, an area-corrected shear strength at δh = 70 mm (AC τ70) was computed to more accurately represent large-displacement shear strength. An area-corrected σn-s (AC σn-s) was also computed to plot large-displacement shear strengths on a conventional shear strength envelope to assess φld. However, nominal shear and normal stresses (i.e., non-area corrected) were used for τp and σn-s since needle-punched reinforcement fibers within the initial shear plane area of the specimen remained in contact with the carrier geotextile at peak shear strength.

The range of σn-s for the direct shear tests was 80 kPa to 2000 kPa for GCL-A; however, shear tests on GCL-B were limited to a maximum σn-s of 500 kPa. A lower maximum σn-s was used for GCL-B since the GCL had lower peel strength and lower density geotextiles. The lower peel strength corresponds to lower normal stress applications, and the lower density geotextiles can lead to interference problems within the GCL gripping systems at σn-s > 500 kPa, which can damage the gripping plates. Therefore, GCL-B specimens were tested with σn-s = 80, 160, 250, and 500 kPa, whereas GCL-A were a tested with σn-s = 100, 500, 1000, and 2000 kPa. RESULTS A summary of the direct shear tests performed in this study is in Table 2. The summary includes the GCL, test temperature, σn-s, τp, τp reduction, horizontal displacement at peak shear strength (δh-

p), secant friction angle at peak shear strength (φs-p), AC σn-s, and AC τ70. The τp reduction in Table 2 represents the percent τp reduced for direct shear tests conducted at 80 °C relative to direct shear tests conducted on the same GCL and same σn-s at 20 °C.

Relationships of shear stress (τ) versus δh for shear tests performed on GCL-A and GCL-B at 20 °C are shown in Figure 1a and Figure 1c, respectively. The observed τ-δh relationships for both GCLs represent typical τ-δh behavior for non-heat-treated NP GCLs (e.g., Fox et al. 1998; Fox and Stark 2015; Bareither et al. 2018). This shear behavior is characterized by an increase in shear stress to a peak that represents the peak internal shear strength of the GCL (τp), followed by a decrease in shear stress with increasing δh to an approximately constant value. The displacement softening behavior observed for GCL-A and GCL-B was attributed to the failure of the reinforcement fibers due to (i) disentanglement of fibers from the carrier geotextile, (b) tensile rupture of the fibers, or (iii) a combination of both mechanisms.

An increase in σn-s resulted in an increase in shear stress adopted for τp (Figure 1a,1c) and the area corrected shear stress adopted for AC τ70 (Table 2) for GCL-A and GCL-B. The increase

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in τp for both GCLs with increasing σn-s was attributed to the frictional behavior of the reinforcement fiber-carrier geotextile connections. Within a comparable range of σn-s for both GCLs (i.e., σn-s ≤ 500 kPa), τp of GCL-A was higher than GCL-B. The higher τp was due to the higher peel strength of GCL-A (Table 1), which corresponded to a higher intensity of needle-punching that resulted in higher internal shear strength.

Table 2. Summary of stressed-controlled direct shear tests performed in this study.

GCL Temp. (°C)

σn-s (kPa)

τp (kPa)

τp Red. (%) φs-p (°) δh-p

(mm) AC σn-s (kPa)

AC τ70 (kPa)

GCL-A

20 100 164 ― 58.7 20.7 185 17 20 500 416 ― 39.8 16.7 925 85 20 1000 483 ― 25.8 16.5 1850 101 20 2000 672 ― 18.6 15.4 3699 150

GCL-A

80 100 132 19.5 52.9 18.7 185 32 80 500 313 24.8 32.0 19.1 925 60 80 1000 390 19.1 21.3 18.0 1850 127 80 2000 542 19.4 15.2 17.4 3699 116

GCL-A

20 80 100 ― 51.4 25.8 150 22 20 160 136 ― 40.3 26.2 300 30 20 250 169 ― 34.0 22.2 469 58 20 500 260 ― 27.4 18.6 938 98

GCL-B

80 80 64 36.0 38.7 24.9 150 58 80 160 78 42.5 26.0 23.9 300 53 80 250 102 39.6 22.2 24.5 469 76 80 500 159 38.8 17.6 22.2 938 105

Notes: Temp. = temperature during shear; σn-s = nominal normal stress; τp = nominal shear stress at peak; τp Red. = reduction in τp at 80 °C relative to 20 °C; φs-p = secant friction angle at peak; δh-p = horizontal deformation at peak shear strength; AC σn-s = area-corrected normal stress; AC τ70 = area-corrected shear stress at horizontal deformation = 70 mm.

The τ-δh relationships for direct shear tests on GCL-A and GCL-B at 80 °C are shown in

Figure 1b and Figure 1d, respectively. The τ-δh relationships at 80 °C were similar to τ-δh relationships at 20 °C, whereby τp increased with σn-s for a given GCL and τp were consistently higher for GCL-A relative to GCL-B at comparable σn-s. However, τp at 80 °C measured for both GCLs reduced relative to τp measured on the same GCL at the same σn-s at 20 °C (Table 2). Peak shear strength reduced 19% to 24% in GCL-A with an increase in temperature from 20 °C to 80 °C, and τp reduced 36% to 42% on GCL-B with a similar increase in temperature. In contrast, the magnitude of the AC τ70 tabulated in Table 2 were approximately consistent between direct shear tests at 20 °C for 80 °C for a given GCL. Thus, the reduction in τp with an increase in temperature represents strength loss within the needle-punched reinforcement fibers through a reduction in friction resistance of the fiber-carrier geotextile connections, tensile strength of the reinforcement fibers, or a combination of both.

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0

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Nom

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Horizontal Displacement (mm)

Figure 1. Relationships of shear stress (τ) versus horizontal displacement (δh) for displacement-controlled internal direct shear tests performed on (a) GCL-A at 20 °C, (b)

GCL-A at 80 °C, (c) GCL-B at 20 °C, and (d) GCL-B at 80 °C. ANALYSIS

The relationship between horizontal displacement at peak shear strength (δh-p) and σn-s is shown in Figure 2 for GCL-A and GCL-B at test temperatures of 20 °C and 80 °C. Evaluation of δh-p-σn-s relationships can lend insight to the mechanisms of internal GCL failure. Considering the shear tests at 20 °C, a decreasing trend of δh-p with σn-s was observed for σn-s ≤ 500 kPa for both GCLs;

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however, for σn-s ≥ 500 kPa, δh-p of GCL-A remained approximately constant. Bareither et al. (2018) observed that for non-heat-treated NP GCLs the δh-p decreased with increasing σn-s to approximately 500 kPa, whereupon δh-p remained nearly constant with subsequent σn-s increase. The change in δh-p-σn-s behavior at approximately 500 kPa was identified as a shift in internal failure mechanism from fiber bundle disentanglement at σn-s ≤ 500 kPa to tensile rupture of reinforcement fibers at σn-s ≥ 500 kPa. Considering that internal failure of NP GCLs is due to the combination of fiber bundle disentanglement and tensile rupture of fibers, the decrease in δh-p for σn-s ≤ 500 kPa was attributed to the transition in failure mechanisms. Similar δh-p-σn-s relationships and internal shear behavior for non-heat-treated NP GCLs has been reported by others (e.g., Fox et al. 1998; Fox and Ross 2011; Theilmann et al. 2016).

10

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GCL-A, 20 oCGCL-A, 80 oC

GCL-B, 20 oCGCL-B, 80 oC

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th (m

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Shearing Normal Stress (kPa) Figure 2. Relationships between horizontal displacement at peak shear strength (δh-p) and shearing normal stress (σn-s) in direct shear tests on GCL-A and GCL-B at test

temperatures of 20 °C and 80 °C.

The δh-p-σn-s relationships at 80 °C exhibit different trends for both GCLs relative to the δh-

p-σn-s relationships at 20 °C. The δh-p-σn-s relationship for GCL-A was nearly constant at 80 °C for the entire range of σn-s, which suggests a single internal failure mechanism likely controlled internal failure for GCL-A at 80 °C. This failure mechanism is hypothesized to be tensile rupture for the high peel strength GCL. The decrease in δh-p at σn-s = 100 kPa as temperature increased from 20 °C to 80 °C was attributed to a transition from reinforcement fiber disentanglement to rupture as temperature increased. The higher δh-p at 80 °C relative to 20 °C σn-s ≥ 500 kPa was attributed to a decrease in the mechanical properties (e.g., tensile modulus) of the reinforcement fibers with an increase in temperature such that larger tensile fiber deformations occurred prior to failure. This rationale is supported based on a decrease in the tensile modulus of polymeric fibers with increasing temperature reported by Karademir and Frost (2014).

Similar arguments for the change in δh-p-σn-s relationships of GCL-A as a function of temperature can be made for GCL-B. However, the lower peel strength of GCL-B was believed to have allowed fiber bundle disentanglement to develop such that a transition in the internal failure mechanism from disentanglement to tensile rupture of the reinforcement fibers occurred as σn-s

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increased. At σn-s = 500 kPa, the δh-p for GCL-B was larger at 80 °C relative to 20 °C, which was also observed for GCL-A. Thus, both the low and high peel strength GCLs tested in this study yielded a consistent shift to higher δh-p when internal failure is predominantly tensile rupture of reinforcement fibers. This increase in δh-p was likely due to increased tensile elongation of the polymeric reinforcement fibers as temperature increased, which is justified mechanically via a decrease in the reinforcement fiber tensile modulus (e.g., Karademir and Frost 2014). Further research is needed to understand the impacts of elevated temperatures on the internal shear mechanisms of NP GCLs as a function of peel strength.

Peak shear strength envelopes for GCL-A and GCL-B at 20 °C and 80 °C are shown in Figure 3. An increase in test temperature reduced τp for both GCLs such that the τp envelopes for 80 °C consistently plotted below the τp envelopes for 20 °C for both GCLs. Linear regression of the shear strength data for σn-s ≤ 500 kPa and σn-s ≥ 500 kPa was completed to determine shear strength parameters (φp and a cohesion intercept, cp) to further assess changes in shear strength as a function of temperature. The shear strength parameters determined for GCL-A and GCL-B at σn-s ≤ 500 kPa show a reduction in φp and cp. Considering that internal shear strength of NP GCLs at σn-s ≤ 500 kPa is due entanglement strength between reinforcement fibers and the carrier geotextile plus tensile strength of reinforcement fibers, increasing temperature appears to reduce both mechanisms of internal shear strength. In contrast, shear strength parameters for GCL-A at σn-s ≥ 500 kPa yield comparable φp at 20 °C and 80 °C, but a pronounced reduction in cp. The nearly parallel strength envelopes of GCL-A at σn-s ≥ 500 kPa provide additional support to the hypothesis that tensile rupture is the governing internal shear resistance mechanism of non-heat-treated NP GCLs at higher normal stress. The reduction in cp was attributed to the reduced tensile strength of the reinforcement fibers as temperature increased, which agrees with previous studies that report reduced mechanical properties of polymeric materials, geosynthetics, and reinforcement fibers at elevated temperatures (e.g., Andrawes et al. 1984; Ariyama et al. 1997; Kongkitkul et al. 2012).

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Figure 3. Peak shear strength (τp) envelopes for GCL-A and GCL-B at 20 °C and 80 °C. Peak friction angles (φp) and cohesion intercept (cp) are included for linear regression of

shear strength data for shearing normal stress (σn-s) ≤ 500 kPa and σn-s ≥ 500 kPa. Area-corrected shear stresses and normal stresses at δh = 70 mm for GCL-A and GCL-B

at 20 °C and 80 °C are shown in Figure 4. Dashed lines representing a range of friction angles from 2° to 8° are included in Figure 4 to capture the range of potential φld for the direct shear tests conducted in this study. The majority of the data points for AC σn-s ≤ 1000 kPa plot within the range of φld from 4° to 8°, which agrees with φld for GCLs reported in literature (e.g., Fox and Stark 2015). The trend towards lower φld at higher σn-s can be attributed to generation of positive excess pore pressure during shear that reduced φld of the bentonite and φld along the interface between the bentonite and geotextile. Positive pore pressures likely developed in the direct shear tests at large shear displacements due to the progressively increasing normal stress, which was amplified at higher initial σn-s (Table 2).

Figure 4. Mohr-coulomb strength envelope for large-displacement shear strength (AC τ70)

of GCL-A and GCL-B at room temperature as well elevated temperature = 80 °C.

Limited influence of temperature on the magnitude of the AC τ70 was observed for the two GCLs tested in this study (Figure 4). However, a consistent bias towards higher AC τ70 for GCL-B at 80 °C was observed. Considering that the frictional internal strength mechanism of reinforcement fiber disentanglement from the carrier geotextile was likely present at low σn-s in GCL-B (i.e., low peel strength GCL), the higher AC τ70 can be interpreted as increased frictional resistance with increased temperature. This increase in frictional resistance with increased temperature agrees with increased interface friction between geosynthetics with increasing temperature reported by Akpinar and Benson (2005) and Karademir and Frost (2013). Although the modest increase in AC τ70 for GCL-B is systematic and explainable, the strength increase is relatively minor and will have negligible influence on GCL design considering the pronounced reductions in peak shear strength observed with an increase in temperature.

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CONCLUSIONS The effect of temperature on peak and large-displacement shear strength of NP GCLs was evaluated via displacement-controlled direct shear tests conducted at 20 °C and 80 °C on two NP GCLs with different peel strength. An increased in temperature decreased τp of both NP GCLs. However, the reduction in τp was lower for the higher peel strength NP GCL (19-25%) compared to the lower peel strength GCL (36-42%). Contrary to τp, limited differences were observed in large-displacement shear strength with an increase in temperature. The increase in temperature appeared to aid the transition in failure mode from fiber bundle disentanglement to fiber rupture at low σn-s. Comparable peak shear strength friction angles, but reduced cohesion intercepts were observed for the high peel strength NP GCL with an increase in temperature for normal stress greater than 500 kPa. Furthermore, an increase in temperature resulted in larger displacement to peak shear strength for the high peel strength NP GCL. The reduced shear strength and increased deformation with an increase in temperature measured in the high peel strength GCL was explained via reduced mechanical properties of polymeric reinforcement fibers at elevated temperatures.

ACKNOWLEDGEMENTS Support for this study was provided by Colorado State University (CSU) and the Colloid Environmental Technologies Company LLC (CETCO). The opinions, findings, conclusions, and/or recommendations expressed herein are those of the authors and do not necessarily represent the views of CSU or CETCO. REFERENCES Akpinar, M. V. & Benson, C. H. (2005). Effect of temperature on shear strength of two

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