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TEGOMER ® AntiScratch 100 Make your plastic tough enough Scratch resistance for PP/talc

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TEGOMER®

AntiScratch 100 Make your plastic tough enough

Scratch resistance for PP/talc

Page | 2

Automotive Applications of PP/talc with

High Importance of Scratch Resistance

Dashboards

Interior door panels

Page | 3

Customer’s Expectations for Interior

Surfaces & Materials are Very High

To meet customer‘s expectations the following parameters for materials need

to be fulfilled:

Design (color, structure of surface, „leather like“ appearance)

Haptic, „Touch“ (soft, hard, sticky, smooth)

Durability (is it sensitive to damage by UV light or heat ?)

Odor free (new car smell vs. new car malodor)

No fogging („smeary window“)

The quality impression of the interior determines the quality

impression of the total car!

All p

rop

ert

ies a

re e

ffecte

d

by a

nti

scra

tch

ad

dit

ives

Page | 4

Door Panels are a Typical Application

for Antiscratch Additives

K 09

Grained surface of VW

moulded in our lab

Antiscratch properties are needed

because

Car customers & designers like grained

surfaces (“leather style”)

These surfaces are very sensitive to

scratch, e.g. damages of door panels

Industry standards for grained

surfaces

K 09: strongly grained (standard of VW)

K 31: smoothly grained (standard of GM)

Page | 5

A Durable Scratch Resistance Ensures

a High Perceived Quality

An unscratched interior after extensive

use

Creates a high value brand recognition

especially with rental cars or taxis

Influences positively the decision when a

new cars is bought towards the current

brand

Allows a higher selling price when a used

car is sold

Makes it more likely that the customer will

buy a new car from the same brand/OEM

Page | 6

Perfect Long Lasting Scratch

Resistance for Less than 10 EUR

Calculation

Amount of PP/talc used in a standard mid size car: 55 kg

Thereof PP/talc parts with need for antiscratch properties: 15 kg

Amount of TEGOMER® AntiScratch 100 needed (at 2%): 0.3 kg = < 10 EUR

Families would buy it!

Extra equipment Cla

ssic

Dyn

am

ic

Fam

ily

Price

in €

Trunk baggage net 50 ○ ○ ○

cutoff net 140 ○ ○ ○

Child Car Seat 1 child car seat with integrated belt pretensioner 210 ○ ○ ○

2 child car seats with integrated belt pretensioner 420 ○ ○ ○

Folding Table in back sheet of front seat with integrated cup holder 80 - ○ ●

Scratch Resistant Interior permanent scratch resistant door and side panels and dashboard 40 ○ ○ ●

Page | 7

TEGOMER® AntiScratch 100 Works

in a Broad Variety of Formulations

Polypropylene 75.8% (Borealis BE 170 MO)

Pigment masterbatch 3.0% (30% carbon black)

Talc 18.0% (IMIFABI HTP1c)

TEGOMER® AntiScratch 100 2.0%

Calcium stearate 0.2%

Other additives 1.0% (antioxidants; UV stabilizer)

Polypropylene 63.4% (Exxon 7064 L1)

TPO 12.0% (Engage 8100)

Pigment masterbatch 2.0% (30% carbon black)

Talc 20.0% (IMIFABI HTP1c)

TEGOMER® AntiScratch 100 2.0%

Calcium stearate 0.1%

Other additives 0.5% (antioxidants; UV stabilizer)

Example formulation for

PP/TPO/talc

Example formulation for

PP/talc

Page | 8

TEGOMER® AntiScratch 100

outperforming standard additives

No additive

• Strong scratches visible

• Talc particles at surface

2% silicone oil masterbatch

• Some scratches visible

• Cow like surface

2% TEGOMER® AntiScratch 100

• No scratches visible

• Homogeneous appearance

Page | 9

In-house capabilities

Erichsen equipment for evaluation of scratch resistance

Moulding devices for grained surfaces (e.g. K09 & K31)

Other automotive norms such as Crockmaster or Multifinger scratch tester

available

We offer our technical equipment and our knowledge in evaluating the

scratch resistance of compounds modified with our additives. This can

be PP/talc, PP/wollastonite or other polymers.

As a reliable partner we offer all

Standard Tests In-house

Page | 10

A chemically bond

Permanent Slip Enhancer

Polymer matrix (dashboard)

Anchorage

groups

Siloxane

backbone

TEGOMER®

AntiScratch 100

The anchorage groups of Tegomer® Antiscratch 100 ensure in contrast

to standard additives a durable & permanent set

No migration, no fogging, no property change over time, no impact

on surface haptics

Page | 11

Exclusively TEGOMER® AntiScratch 100

Generates a Long Lasting Effect

0,0

2,0

4,0

6,0

8,0

10,0

12,0 Compound: PP with 20% talc

Test method: Erichsen 10 N

Graining: K31

ΔL 24 h ΔL 1 W 80°C

ΔL (

scra

tch

re

sis

tan

ce

)

poor

perfect

without Additive

2% HMW amide PP-MAA based

2% Silicone oil masterbatch

1% Fatty acid amide

2% TEGOMER® AntiScratch 100

before

ageing

after

ageing

Page | 12

Ageing is Crucial to Evaluate Additives

for Car Interior Applications

Temperatures in summer in a (closed) car after 1 hour in the sun:

Dashboard:

up to 80 °C

Head room:

up to 70 °C

Foot space:

up to 60 °C

To simulate the conditions in a car we do the following testing:

Scratch resistance test of sample with additives direct after molding

Same test with sample that was aged for 7 days at 80 °C or QUV test

Page | 13

Additive with Long Lasting Effect

Tackiness after UV Irradiation

+ 0.5% fatty

acid amide

+ 3% high molecular

amide PP-MAA based

+ 3% TEGOMER®

AntiScratch 100 without Additive

Q-Sun Xe-1-B

The PV 1306 test method of VW/Germany

is used to analyze interior automotive parts

based on PP and PP/Talc compounds

regarding their tackiness and migration after

UV irradiation (5 x 96 h).

TEGOMER® AntiScratch 100 does not show any migration and tackiness

in the PV 1306 test. It stays in the bulk phase of plastics compounds and

provides a long lasting scratch resistance.

Page | 14

TEGOMER® AntiScratch 100 – Yields

Outstanding Properties in Performance

TEGOMER®

AntiScratch 100

Fatty acid

amide

Silicone oil

Masterbatch

HMW amide

PP-MAA based

Scratch 1d / RT ++ ++ ++ +

Scratch 7d / 80 °C ++ 0 + +

Migration no yes yes yes

Odor no yes no yes

Fogging no yes yes yes

Notched impact + 0 0 0

Use in moulding operations

++ 0 - -

Addition in % 1-3 0.1-1 2-3 2-4

Page | 15

TEGOMER® AntiScratch 100...

is a compound based on organic modified siloxane

guarantees long term, durable antiscratch properties

does not loose antiscratch properties after ageing as competitor‘s products do

is non-fogging, non-migrating & odorless

has no impact on surface haptics

improves the mechanical properties of PP/talc and PP/TPO/talc filled systems

can enhance melt flow properties

TEGOMER® AntiScratch 100

Summary of Properties

Care & Surface Specialties | Goldschmidt Industrial Specialties Page | 16

Scratch me – if you can!

TEGOMER® AntiScratch 100

Make Your Plastic Tough Enough.