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    PETE 310

    Lecture # 14

    Wet GasSpecific Gravity & Z-factor

    (Chapter 7: pages 195-205)

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    Learning Objectives

    Calculate the specific gravity of a wet gasmixture, given producing GOR (at separator(s)and stock tank and:

    compositions liquid and gas from stock tankand separator gas

    or, separator compositions (gas & liquid)

    or, properties of the separator gas and stockvent gas

    Define the two-phase z-factor and understand the

    uses of this in reservoir engineering

    Explain the shape of a typical two-phase z-factorisotherm.

    Calculate values of two-phase z-factor using

    Rayes etal. correlation (SPE paper).

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    Separators

    iSTx

    )STB/scf(GORand

    yiST

    )STB/scf(GORand

    yiSP

    iSTx

    Wellhead

    iSPx

    SToilgasSTgas

    v

    SToilgasSPoil

    SPoilgas

    SPgas

    v

    molelbmolelb

    molelbf

    molelbmolelbmolelb

    molelbmolelb

    molelb

    f

    ST

    SP

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    Key Points

    What matters is the molar ratio of gas to oil

    so lets assume one barrel of oil produced

    Methods to evaluate oil density will be

    discussed in Chapter 11 (here it will beprovided)

    To convert oAPI to oil density

    w

    o

    o

    o

    o5.131

    5.141API

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    Key Points

    The expression [=] means has the units of Forexample

    You are responsible for reading the material thatcannot be covered in this lecture

    Rework ALL the example problems in the book Procedure 1 - explained in detail here - is simpler

    and takes less time to solve than the methodexplained in the book

    3o ftlb

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    Recombination procedure when

    separator gas yiSP and tock tank

    compositions (xiSTO, yiST) areknown

    (Procedure 1.)

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    Procedure 1.

    Calculate molecular weight of stock tank

    liquid

    Calculate lb-moles of separator gas produced

    per barrel of STO from separator

    Nc

    1iwiiwo MxM

    volume)molargas(idealmole-b380.7scf/lV

    /STOmole-lbmole-scf/lb

    scf/STB

    V

    GOR

    id

    m

    gasid

    m

    SP

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    Procedure 1.

    Calculate lb-moles of stock gas vented per

    STO

    Calculate moles of oil in 1 barrel of stock tank

    (need to use molar density)

    /STOmole-lb

    bbl

    ft615.5

    ft

    mole-lb

    ft

    mole-lb

    mole-lb/lb

    lb/ft

    M

    oil

    3

    3

    oil

    3

    oil3

    wo

    oil

    /STOmole-lbmole-scf/lb

    scf/STBV

    GORgasid

    m

    ST

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    Procedure 1.

    STO

    molelbmolelbSTO

    molelb

    f

    molelbmolelbmolelb

    STO

    molelbmolelbSTO

    molelb

    f

    SToilgas

    STgas

    v

    SToilgasSPoil

    SPoilgas

    SPgas

    v

    ST

    SP

    iST

    x

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    Procedure 1.

    Determine reservoir gas composition fromfundamental mole balance

    Once reservoir composition is known determine z-factor and specific gravity

    STSTSTSP

    STST

    SPSP

    vvSTivSTivSPii

    vSTivSTiSPi

    vSPivSPii

    f1f1xfyfyz

    f1xfyx

    f1xfyz

    iST

    x

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    Example for Procedure 1.

    Yi SEP Yi STOX i STO

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    Recombination procedure when

    separator gas yiSP and liquid

    compositions xiSP are known

    (Procedure 2.)

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    Example for Procedure 2.

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    Procedure 2.

    Additional information given is the separator/stocktank volume ratio as

    Use this to convert from scf/STO scf/ST

    Proceed as in procedure 1.

    Rework example 7.2 in textbook

    )conditionsstandardat(STBbbl

    separator)ofP(T,atiloSPbbl

    f1xfyzSPSP vSPivSPii

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    Recombination procedure when

    only separator gas and stock vent

    gas properties are known

    (Procedure 3.)

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    Procedure 3.

    For two-stage separators

    For three-stage separators derive

    expressions

    STSP

    gSTSTgSPSP

    gRR

    RR

    STSP RRR

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    Procedure 3.

    Moles in one stock tank barrel

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    Procedure 3.

    Mass of one stock tank barrel

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    Procedure 3.

    And the gas gravity at reservoir conditions

    is

    An approximation for Mo (when not given is)

    oo

    og

    gRM/300,133R

    600,4R

    STO

    STO

    oo 008.1

    43.42

    8.8API

    954,5M

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    Procedure 3.

    For two-stage separators

    For three-stage separators deriveexpressions

    STSP

    gSTSTgSPSP

    g RR

    RR

    STSP

    RRR

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    Once Gas Specific Gravity is

    Known

    Evaluate Tpc and Ppc (previous paperusing K and J and including correctionsfor impurities N2, CO2, H2S)

    If dew-point pressure is not knownUse dry-gas z-factor when C7+ < 4%

    Or when wellstream gravity < 0.911

    If pdis known

    if reservoir p is lower than pdevaluate z-2phase using equation from SPE 20055 paper

    If reservoir p is greater than pd , evaluate z asfor a dry gas (single-phase)

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    Correlation of Specific Gravities

    for a wet gas

    READ - SPE 20055

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    Ranges of Compositions

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    Single vs Two-phase z-factor

    p/z-2phase vs z-2phase

    0.6

    0.8

    1

    1.2

    0 1000 2000 3000 4000 5000

    Pressure (psia)

    z,

    z-2phase

    z-gas (one phase)

    z-2phases

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    Estimates of the Gas in Place (G)

    When p/z = 0 Gp= G (PETE 323)

    Exercise: verify these calculations using

    information from next slide

    G

    G1

    z

    p

    z

    p p

    i

    i

    From single phase z G = 644640 MMSCF

    From two-phase z G = 679522 MMSCF

    5.13328 % difference

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    Estimates of Reserves

    Gas in Place Prediction

    P/z_1phase = -9.359752E-03x + 6.033670E+03

    R2= 9.979569E-01

    P/z_2phase = -8.405311E-03x + 5.711591E+03

    R2= 9.979049E-01

    0

    1000

    2000

    3000

    4000

    5000

    6000

    7000

    0 100000 200000 300000 400000 500000 600000 700000 800000

    Gp (MMSCF)

    p

    /z

    ,p/z-2phase

    (p

    sia)

    p/z-2phase

    p/z-gas

    Linear (p/z-gas)Linear (p/z-2phase)