synthesis and applications of 3-[6-(hydroxymethyl)pyridin-2-yl]-1,1′-bi-2-naphthols or...

2007 Alcohols Q 0230 Synthesis and Applications of 3-[6-(Hydroxymethyl)pyridin-2-yl]-1,1'-bi-2-naphthols or 3,3'-Bis[6-(hydroxymethyl)pyridin-2-yl]-1,1'-bi-2-naphthols. — A series of novel BINOL-derivatives is prepared and tested as ligands in the asymmetric addi- tion of diethylzinc to aromatic aldehydes. Best results are obtained using the menth- yl-substituted compound (Sax)-(IIc). — (MA, L.; JIN, R.-Z.; LUE, G.-H.; BIAN, Z.; DING, M.-X.; GAO*, L.-X.; Synthesis 2007, 16, 2461-2470; State Key Lab. Polym. Phys. Chem., Changchun Inst. Appl. Chem., Chin. Acad. Sci., Changchun 130022, Peop. Rep. China; Eng.) — Nuesgen 51- 088

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Page 1: Synthesis and Applications of 3-[6-(Hydroxymethyl)pyridin-2-yl]-1,1′-bi-2-naphthols or 3,3′-Bis[6-(hydroxymethyl)pyridin-2-yl]-1,1′-bi-2-naphthols

2007

AlcoholsQ 0230 Synthesis and Applications of 3-[6-(Hydroxymethyl)pyridin-2-yl]-1,1'-bi-2-naph-

thols or 3,3'-Bis[6-(hydroxymethyl)pyridin-2-yl]-1,1'-bi-2-naphthols. — A series of novel BINOL-derivatives is prepared and tested as ligands in the asymmetric addi-tion of diethylzinc to aromatic aldehydes. Best results are obtained using the menth-yl-substituted compound (Sax)-(IIc). — (MA, L.; JIN, R.-Z.; LUE, G.-H.; BIAN, Z.; DING, M.-X.; GAO*, L.-X.; Synthesis 2007, 16, 2461-2470; State Key Lab. Polym. Phys. Chem., Changchun Inst. Appl. Chem., Chin. Acad. Sci., Changchun 130022, Peop. Rep. China; Eng.) — Nuesgen

51- 088

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