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In cooperation with the Spirit Lake Tribe Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation, North Dakota Open-File Report 2006–1144 U.S. Department of the Interior U.S. Geological Survey

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Page 1: Summary of Surface-Water Quality, Ground-Water Quality ... · Weather Service cooperative stations (Golden Gate Weather Services, 2001). Average monthly precipitation for the reserva

Vining and Cates—Sum

mary of Surface-W

ater Quality, G

round-Water Q

uality, and Water W

ithdrawals

for the Spirit Lake Reservation, North D

akota—Open-File Report 2006–1144

In cooperation with the Spirit Lake Tribe

Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation, North Dakota

Open-File Report 2006–1144

U.S. Department of the InteriorU.S. Geological SurveyPrinted on recycled paper

Page 2: Summary of Surface-Water Quality, Ground-Water Quality ... · Weather Service cooperative stations (Golden Gate Weather Services, 2001). Average monthly precipitation for the reserva

Report Documentation Page Form ApprovedOMB No. 0704-0188

Public reporting burden for the collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources, gathering andmaintaining the data needed, and completing and reviewing the collection of information. Send comments regarding this burden estimate or any other aspect of this collection of information,including suggestions for reducing this burden, to Washington Headquarters Services, Directorate for Information Operations and Reports, 1215 Jefferson Davis Highway, Suite 1204, ArlingtonVA 22202-4302. Respondents should be aware that notwithstanding any other provision of law, no person shall be subject to a penalty for failing to comply with a collection of information if itdoes not display a currently valid OMB control number.

1. REPORT DATE 2006

2. REPORT TYPE N/A

3. DATES COVERED -

4. TITLE AND SUBTITLE Summary of Surface-Water Quality, Ground-Water Quality, and WaterWithdrawals for the Spirit Lake Reservation, North Dakota

5a. CONTRACT NUMBER

5b. GRANT NUMBER

5c. PROGRAM ELEMENT NUMBER

6. AUTHOR(S) 5d. PROJECT NUMBER

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11. SPONSOR/MONITOR’S REPORT NUMBER(S)

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13. SUPPLEMENTARY NOTES The original document contains color images.

14. ABSTRACT

15. SUBJECT TERMS

16. SECURITY CLASSIFICATION OF: 17. LIMITATION OF ABSTRACT

SAR

18. NUMBEROF PAGES

28

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a. REPORT unclassified

b. ABSTRACT unclassified

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Standard Form 298 (Rev. 8-98) Prescribed by ANSI Std Z39-18

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Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation, North Dakota

By Kevin C. Vining and Steven W. Cates

U.S. Department of the Interior U.S. Geological Survey

In cooperation with the Spirit Lake Tribe

Open-File Report 2006–1144

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U.S. Department of the InteriorDirk Kempthorne, Secretary

U.S. Geological SurveyP. Patrick Leahy, Acting Director

U.S. Geological Survey, Reston, Virginia: 2006

For sale by U.S. Geological Survey, Information Services Box 25286, Denver Federal Center Denver, CO 80225

For more information about the USGS and its products: Telephone: 1-888-ASK-USGS World Wide Web: http://www.usgs.gov/

Any use of trade, product, or firm names in this publication is for descriptive purposes only and does not imply endorsement by the U.S. Government.

Although this report is in the public domain, permission must be secured from the individual copyright owners to reproduce any copyrighted materials contained within this report.

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iii

Contents

Abstract. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

1.0 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

2.0 Climate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

3.0 Topography and Land Use. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

4.0 Basic Surficial Geology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

5.0 Surface-Water Quality—Major Constituents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

6.0 Surface-Water Quality-—Trace Elements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

7.0 Ground-Water Quality-—Major Constituents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

8.0 Ground-Water Quality-—Trace Elements. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

9.0 Water Withdrawals. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

10.0 Selected References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

Appendix 1. Drinking-water regulations, common sources, and significant effects for selected properties and constituents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

Conversion Factors and Datum

Temperature in degrees Fahrenheit (°F) may be converted to degrees Celsius (°C) as follows: °C = (°F - 32) / 1.8

Vertical coordinate information is referenced to the North American Vertical Datum of 1988 (NAVD 88).

Horizontal coordinate information is referenced to the North American Datum of 1983 (NAD 83).

Elevation, as used in this report, refers to distance above the vertical datum.

Concentrations of chemical constituents in water are given either in milligrams per liter (mg/L) or micrograms per liter (µg/L).

Multiply By To obtain

Length

foot (ft) 0.3048 meter (m)

inch (in.) 25.4 millimeter (mm)

mile (mi) 1.609 kilometer (km)

Area

square mile (mi2) 2.590 square kilometer (km2)

Volume

million gallons (Mgal) 3,785 cubic meter (m3)

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iv

Glossary

Alluvial Having been deposited by a stream or running water

Aquifer Body of rock that has enough saturated permeable material to permit ground-water movement and yield economical amounts of water from wells

Coulee Small stream that often flows intermittently

Glacial outwash Coarse sediment material, mostly sand and gravel, that has been removed from a glacier by meltwater streams and deposited beyond the margin of the glacier

Glacial till Unsorted materials deposited directly by a glacier without having been reworked by glacial meltwater

Loam soil Soil that consists of nearly equal parts of sand, silt, and clay particles

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Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation, North Dakota

By Kevin C. Vining and Steven W. Cates1

Abstract

Available surface-water quality, ground-water quality, and water-withdrawal data for the Spirit Lake Reservation were summarized. The data were collected intermittently from 1948 through 2004 and were compiled from U.S. Geological Survey databases, North Dakota State Water Commission databases, and Spirit Lake Nation tribal agencies. Although the quality of

surface water on the reservation generally is satisfactory, no surface-water sources are used for consumable water supplies.

Ground water on the reservation is of sufficient quality for most

uses. The Tokio and Warwick aquifers have better overall water

quality than the Spiritwood aquifer. Water from the Spiritwood

aquifer is used mostly for irrigation. The Warwick aquifer pro-

vides most of the consumable water for the reservation and for

the city of Devils Lake. Annual water withdrawals from the

Warwick aquifer by the Spirit Lake Nation ranged from 71 mil-

lion gallons to 122 million gallons during 2000-04.1Cates Earth Science Technologies.

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2 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

1.0 Introduction

Water-quality and water-withdrawal data for the Spirit Lake Reservation are summarized

Data for the reservation were provided by State, Federal, and tribal agencies.

Knowledge about water resources on the Spirit Lake Res-ervation is needed to help tribal leaders make informed deci-sions about water-resources management. Therefore, the U.S. Geological Survey, in cooperation with the Spirit Lake Reser-vation, conducted a study to compile available surface-water quality, ground-water quality, and water-withdrawal data for the reservation. The data, which are summarized in this report, were collected intermittently from 1948 through 2004 and were compiled from U.S. Geological Survey databases, North Dakota State Water Commission databases, and Spirit Lake Nation tribal agencies. Results of the study will provide an improved understanding of water quality and water withdrawals on the reservation.

The Spirit Lake Reservation is located in northeastern North Dakota (fig. 1). The reservation encompasses an area of about 405 square miles in parts of Benson, Eddy, Nelson, and Ramsey Counties (Spirit Lake Dakotah Sioux Nation, 2005) and is bordered on the north by Devils Lake and on the south by the Sheyenne River. About 4,435 people reside on the reserva-tion, and about 3,320 of those people are members of the Spirit Lake Nation (North Dakota Indian Affairs Commission, 2005).

Thanks are given to Silas Ironheart, Jr., Constance Baker, Oliver Gourd, Jr., David Azure, Jr., Frank Black Cloud, Sean Gourd, and Lorna Walking Eagle from the Spirit Lake Tribal EPA office and to Dave Cavanaugh and R. J. Yankton from the Spirit Lake Water Resource Management office for providing information and assisting in the preparation of this report.

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47°4

4

Figure 1. Location of Spirit Lake Reservation in North Dakota.

U.S. Army Corps of Engineers modifed thelake boundary of Devils Lake in 1997

1.0 INTRODUCTION

Photograph courtesy of Spirit Lake Tribal EPA

1.0 Introduction 3

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4 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

2.0 Climate

Long, cold winters and short, mild summers characterize the climate of the Spirit Lake Reservation

Average annual temperature was about 40 degrees Fahrenheit, and average annual precipitation was about 19.1 inches.

Average monthly and annual temperatures for the Spirit Lake Reservation were calculated from the distribution of 1971-2000 average monthly temperature data for selected National Weather Service cooperative stations (Golden Gate Weather Services, 2001). Average monthly temperatures for the reservation ranged from about 4 degrees Fahrenheit in January to about 70 degrees Fahrenheit in July, and the average annual temperature for 1971-2000 was about 40 degrees Fahrenheit (fig. 2). High temperatures at the National Weather Service cooperative station at Devils Lake have exceeded 110 degrees Fahrenheit, and low temperatures have reached - 45 degrees Fahrenheit (High Plains Regional Climate Center, 2005).

Average monthly and annual precipitation for the Spirit Lake Reservation was calculated from the distribution of 1971-2000 average monthly precipitation data for selected National Weather Service cooperative stations (Golden Gate Weather Services, 2001). Average monthly precipitation for the reserva-tion ranged from about 0.60 inch in January to about 3.25 inches in July, and average annual precipitation for 1971-2000 was about 19.1 inches (fig. 2). Annual precipitation on the reserva-tion ranged from about 13.1 inches in 1988 to about 26.4 inches in 1994 (High Plains Regional Climate Center, 2005).

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47°4

4

.

.

47°4

4

T. 151 N.

T. 152 N.

T. 153 N.

T. 154 N.

T. 150 N.

R. 62 W. R. 61 W.R. 63 W.R. 64 W.R. 65 W.R. 66 W.R. 67 W.

Devils Lake

RA

MSE

YC

O.

NE

LSO

NC

O.

BENSON CO.

EDDY CO.

RA

MSE

YC

O.

BE

NSO

NC

O.

RAMSEYCO.

BENSONCO.

DEVILS LAKE

(East Bay)

DEVILS LAKE(West Bay) DEVILS LAKE

(Main Bay)

SHEYENNE

RIVER

DEVILS LAKE(East Bay)

EAST

DEVILS

LAKE

RoundLake

TwinLake

Court LakeSweetwater

LakeMallard

Lake

Mission

Bay

Black

Tige

r Bay

SpringLake

Free PeopleLake

ElbowLake

SquareLakeWood

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BigCoulee

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HorseshoeLake

Shin BoneLake

BlackSlough

BattleLake

ZiebachPass

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PelicanLake

Six

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Bay

Cre

elB

ay

SPIRIT

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RESERVATION

19

281

281

281

57

20

20

202

15

15

2

Figure 2. Average annual temperature (A), in degrees Fahrenheit, and average annualprecipitation (B), in inches, for the Spirit Lake Reservation for 1971-2000.

19

19.5

18.5

39

40

(A)

(B)

Base from U.S. Geological Survey digital dataUniversal Transverse Mercator projectionNorth American Datum of 1983U.S. Army Corps of Engineers modifed thelake boundary of Devils Lake in 1997

2.0 CLIMATE

2.0 Climate 5

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6 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

3.0 Topography and Land Use

Landforms on the Spirit Lake Reservation were created by glacial action

Most of the unforested land on the reservation is used for grazing and agriculture.

Landforms on the Spirit Lake Reservation were created by glacial erosion and deposition during several glacial periods. Land-surface elevations range from about 1,400 feet above the North American Vertical Datum of 1988 along the Sheyenne River to about 1,735 feet above the North American Vertical Datum of 1988 near Fort Totten (U.S. Geological Survey, 1950, 1951, 1962, 1994). Low rolling hills dominate the landscape throughout most of the reservation, and occasional forested areas occur among the grasslands and agricultural lands on the reservation and in the surrounding counties (Wright and Sweeney, 1977; Strum and others, 1979). Numerous semiper-manent and permanent water bodies that vary in size are located

throughout the reservation. The concentration of these water bodies is highest in the eastern part of the reservation.

Most of the land on the reservation is used for grazing and agriculture as shown by the regular pattern of the land surface in figure 3. However, some land is used only for grazing, and some land, especially near Devils Lake, is forested. Soil charac-teristics of the agricultural areas indicate the soils are mostly good to fair for agricultural production (Strum and others, 1979). Wheat, barley, corn, soybeans, sunflowers, and hay are the major crops on the reservation, and some irrigation occurs in the southeastern part of the reservation (U.S. Department of Agriculture, 2006).

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47°4

4

Figure 3. Satellite photograph of the Spirit Lake Reservation.

3.0 TOPOGRAPHY AND LAND USE

3.0 Topography and Land Use 7

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8 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

4.0 Basic Surficial Geology

The surficial geology of the Spirit Lake Reservation was defined by glacial activity

Surface materials on the reservation consist of a mixture of clay, silt, sand, gravel, and boulders.

The geology of the Spirit Lake Reservation was defined by glacial activity (Bluemle, 1965, 1973; Carlson and Freers, 1975; Hobbs and Bluemle, 1987). Glaciers moved from north to south across the northeastern part of North Dakota and pushed rocks, soils, and other materials onto the area of the reservation. Rock materials underlying the area of glaciation were mixed with clays, silts, sands, gravels, and boulders carried by the gla-ciers in the form of glacial till. As the glaciers melted and

retreated, the glacial till was left behind and meltwater moved and redeposited some of the glacial sands and gravels as glacial-outwash and silt and clay alluvial deposits (fig. 4). A few areas of silt and clay lake deposits formed along Devils Lake and in a large depression in the southwestern corner of the reservation. Many of the glacial and alluvial deposits are several hundred feet thick. Some windblown deposits of fine sand also occur on the surface in the southeastern part of the reservation.

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47°

4

Figure 4. Basic surficial geology of the Spirit Lake Reservation.

North American Datum of 1983U.S. Army Corps of Engineers modifed thelake boundary of Devils Lake in 1997

4.0 BASIC SURFICIAL GEOLOGY

Photograph courtesy of Spirit Lake Tribal EPA

4.0 Basic Surficial Geology 9

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10 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

5.0 Surface-Water Quality—Major Constituents

Average major-constituent concentrations are given for surface-water bodies on the Spirit Lake Reservation

Surface-water quality on the reservation generally is satisfactory.

Surface-water quality data compiled from U.S. Geological Survey databases were used to describe the quality of surface water on and near the Spirit Lake Reservation. Surface-water locations that were sampled include Devils Lake, the Sheyenne River, and the numerous small lakes and wetlands that occur on the reservation. The water-quality data, which were collected intermittently from 1948 through 2004, were divided into five groups—data for Devils Lake, data for the Sheyenne River, data for small lakes and wetlands in the western and northern parts of the reservation, data for small lakes and wetlands overlying the Tokio aquifer, and data for small lakes and wetlands overly-ing the Warwick aquifer. For each of the five groups, average calcium, magnesium, sodium, sulfate, and chloride concentra-

tions were determined without consideration for the time of sample collection, the location of the sampling site, or the num-ber of samples collected.

Devils Lake, the small lakes and wetlands in the western and northern parts of the reservation, and the small lakes and wetlands overlying the Warwick aquifer had similar average dissolved-solids concentrations (fig. 5). The Sheyenne River had average concentrations that were generally lower than those for the remaining four groups (fig. 5). Although the quality of surface water on the reservation generally is satisfactory, no surface-water sources are used for consumable water supplies.

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5 MILES

T.151N.

T.152N.

T.153N.

T.154N.

T.150N.

61 W.

2

Figure 5. Average calcium, magnesium, sodium, sulfate, and chloride concentrations for Devils Lake, the Sheyenne River, andsmall lakes and wetlands on the Spirit Lake Reservation. (Data were collected intermittently from 1948 through 2004.)

NE

LSO

NC

O.

iet

s

s

ifer

902

Base from U.S. Geological Survey digital dataUniversal Transverse Mercator projectionNorth American Datum of 1983U.S. Army Corps of Engineers modifed thelake boundary of Devils Lake in 1997

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5.0 SURFACE-WATER QUALITY--MAJOR CONSTITUENTS

5.0 Surface-Water Quality—Major Constituents 11

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12 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

6.0 Surface-Water Quality—Trace Elements

Trace-element concentrations are given for surface-water bodies on the Spirit Lake Reservation

Many concentrations were greater than U.S. Environmental Protection Agency regulations.

Surface-water quality data compiled from U.S. Geological Survey databases were used to describe the quality of surface water on and near the Spirit Lake Reservation. The water-qual-ity data, which were collected intermittently from 1948 through 2004, were divided into five groups—data for Devils Lake, data for the Sheyenne River, data for small lakes and wetlands in the western and northern parts of the reservation, data for small lakes and wetlands overlying the Tokio aquifer, and data for small lakes and wetlands overlying the Warwick aquifer. Arsenic, boron, manganese, mercury, and selenium concentra-tions for surface-water samples collected from surface-water bodies in the five groups are shown in figure 6.

The five groups had many arsenic, boron, and manganese concentrations that exceeded U.S. Environmental Protection Agency (2004) regulations for those constituents but no sele-nium concentrations that exceeded the regulation for that con-stituent. The Sheyenne River had a few mercury concentrations that exceeded the U.S. Environmental Protection Agency (2004) regulation for that constituent. Arsenic, boron, manga-nese, mercury, and selenium probably occur naturally, to some extent, in the rocks and soils in North Dakota and on the Spirit Lake Reservation, and some trace elements may be released during the burning of coal. Other trace elements have been detected in surface-water bodies on the reservation, but too few data were available to include figures for those elements.

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Boron

NO

DATA

NO

DATA

Mercury

Figure 6. Arsenic, boron, manganese, mercury, and selenium concentrations for surface-water samples collected from DevilsLake, the Sheyenne River, and small lakes and wetlands on the Spirit Lake Reservation.

0

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20

30

40

50

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U.S. Environmental Protection Agency health advisory

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U.S. Environmental Protection Agencydrinking-water regulation

U.S. Environmental Protection Agencysecondary drinking-water regulation

U.S. Environmental Protection Agencydrinking-water regulation

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6.0 SURFACE-WATER QUALITY--TRACE ELEMENTS

6.0 Surface-Water Quality—Trace Elements 13

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14 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

7.0 Ground-Water Quality—Major Constituents

Average major-constituent concentrations are given for three major aquifers underlyingthe Spirit Lake Reservation

Ground water on the reservation is of sufficient quality for most uses.

Ground-water quality data compiled from U.S. Geological Survey databases were used to describe the quality of ground water underlying the Spirit Lake Reservation. Ground-water samples were obtained from the Tokio and Warwick aquifers, which underlie areas in the southeastern part of the reservation, and from the Spiritwood aquifer, which underlies areas in the northern and eastern parts of the reservation (fig. 7). The water-quality data, which were collected intermittently from 1948 through 2004, were divided into three groups—data for the Tokio aquifer, data for the Warwick aquifer, and data for the Spiritwood aquifer. Average calcium, magnesium, sodium, sul-fate, and chloride concentrations were determined without con-

sideration for the time of sample collection, the location of the sampling site, or the number of samples collected.

The Tokio and Warwick aquifers have better overall water quality than the Spiritwood aquifer as indicated by the lower average concentrations for those aquifers (fig. 7). Therefore, water from the Spiritwood aquifer appears to be less desirable as a consumable water supply. Water from the Tokio aquifer and from the Warwick aquifer has a lower average sodium con-centration than water from the Spiritwood aquifer (fig. 7), mak-ing water from the Tokio and Warwick aquifers more desirable for irrigation.

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Figure 7. Average calcium, magnesium, sodium, sulfate, and chloride concentrations for ground-water samplescollected from the Tokio, Warwick, and Spiritwood aquifers underlying the Spirit Lake Reservation. (Data werecollected intermittently from 1948 through 2004.)

3

2

1

Base from U.S. Geological Survey digital dataUniversal Transverse Mercator projectionNorth American Datum of 1983U.S. Army Corps of Engineers modifed thelake boundary of Devils Lake in 1997

Ca

Mg

Na

SO4

Cl

CON

CEN

TRAT

ION

,IN

MIL

LIGR

AMS

PER

LITE

R

0

300

200

100

CON

CEN

TRAT

ION

,IN

MIL

LIGR

AMS

PER

LITE

R

0

300

200

100

CON

CEN

TRAT

ION

,IN

MIL

LIGR

AMS

PER

LITE

R

EXPLANATION

Calcium--No regulation has been established

Magnesium--No regulation has been established

Sodium--U.S. Environmental Protection Agency secondary drinking-waterregulation is 20 milligrams per liter for individuals on a restricted sodium diet

Sulfate--U.S. Environmental Protection Agency regulation is 250 milligramsper liter

Chloride--U.S. Environmental Protection Agency regulation is 250 milligramsper liter

7.0 GROUND-WATER QUALITY--MAJOR CONSTITUENTS

7.0 Ground-Water Quality—Major Constituents 15

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16 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

8.0 Ground-Water Quality—Trace Elements

Trace-element concentrations are given for three major aquifers underlying the Spirit Lake Reservation

Many concentrations were greater than U.S. Environmental Protection Agency standards.

Ground-water quality data compiled from U.S. Geological Survey databases were used to describe the quality of ground water underlying the Spirit Lake Reservation. The water-qual-ity data, which were collected intermittently from 1948 through 2004, were divided into three groups—data for the Tokio aqui-fer, data for the Warwick aquifer, and data for the Spiritwood aquifer. Arsenic, boron, manganese, mercury, and selenium concentrations for ground-water samples collected from the three aquifers are shown in figure 8.

The three groups had many arsenic, boron, and manganese concentrations that exceeded U.S. Environmental Protection Agency (2004) regulations for those constituents but no mer-cury and selenium concentrations that exceeded the regulations for those constituents. Arsenic, boron, manganese, mercury, and selenium probably occur naturally, to some extent, in the rocks and soils in North Dakota and on the Spirit Lake Reserva-tion, and some trace elements may be released during the burn-ing of coal. Other trace elements have been detected in ground-water aquifers underlying the reservation, but too few data were available to include figures for those elements.

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NO

DATA

Figure 8. Arsenic, boron, manganese, mercury, and selenium concentrations for water samples collected from the Tokio, Warwick,and Spiritwood aquifers underlying the Spirit Lake Reservation.

0

10

20

30

40

50

60

Selenium

0

500

1,000

1,500

2,000

2,500

3,000

3,500

4,000

Arsenic

Tokio aquifer Warwick aquifer Spiritwood aquifer

Tokio aquifer Warwick aquifer Spiritwood aquifer

0

400

800

1,200

1,600

2,000

2,400Boron

U.S. Environmental Protection Agency health advisory

0

0.1

0.2

0.3

0.4

0.5

0.6

NO

DATA

MercuryManganese

U.S. Environmental Protection Agencysecondary drinking-water regulation

U.S. Environmental Protection Agencydrinking-water regulation

00

1

2

3

4

5

6

7

CON

CEN

TRAT

ION

,IN

MIC

ROGR

AMS

PER

LITE

RCO

NCE

NTR

ATIO

N,I

NM

ICRO

GRAM

SPE

RLI

TER

CON

CEN

TRAT

ION

,IN

MIC

ROGR

AMS

PER

LITE

R

8.0 GROUND-WATER QUALITY--TRACE ELEMENTS

8.0 Ground-Water Quality—Trace Elements 17

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18 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

9.0 Water Withdrawals

Water withdrawals from aquifers underlying the Spirit Lake Reservation vary with weather conditions

Water use by the Spirit Lake Nation has been slowly increasing since 2000.

Irrigation water on the reservation is withdrawn mostly from the Warwick and Spiritwood aquifers. The amounts of water withdrawn for irrigation have varied considerably from year to year because of varying amounts of rainfall (fig. 9). Withdrawals for irrigation were large during 1988-89 because of dry weather conditions during that period. However, gener-ally wet weather conditions since 1992 have resulted in decreased withdrawals for irrigation because greater amounts of rainfall usually result in less irrigation demand. According to Schuh (1999), a significant amount of acreage suitable for addi-tional irrigation development overlies the Warwick aquifer. Most of the acreage consists of sand and loam soils that are con-sidered potentially suitable for irrigation.

Annual water withdrawals from the Warwick aquifer for consumption by the city of Devils Lake ranged from 256 mil-lion gallons to 432 million gallons during 1981-2004 (fig. 9). Withdrawals peaked in 1992 and 1993 and then generally decreased from 1995 through 2004.

Annual water withdrawals from the Warwick aquifer by the Spirit Lake Nation ranged from 71 million gallons to 122 million gallons during 2000-04 (fig. 9) (R. J. Yankton, Spirit Lake Water Resource Management, written commun., 2005). According to R. J. Yankton with the Spirit Lake Water Resource Management office, the larger amount of water with-drawn in 2003 probably resulted from a leak in the reservation water system.

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WIT

HDRA

WAL

S,IN

MIL

LION

GALL

ONS

Water withdrawals fromthe Warwick aquifer

City of Devils Lake

Spirit Lake Nation

Water withdrawals fromaquifers for irrigation onthe reservation

Warwick

Spiritwood

Tokio

Figure 9. Annual water withdrawals from the Tokio, Warwick, and Spiritwood aquifers underlying the Spirit Lake Reservation.

0

50

100

150

200

250

300

350

400

450

500

WIT

HDRA

WAL

S,IN

MIL

LION

GALL

ONS

0

50

100

150

200

250

300

350

400

450

500

1981 1982 1983 1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004

1981 1982 1983 1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004

546 536

9.0 WATER WITHDRAWALS

9.0 Water Withdrawals 19

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20 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

10.0 Selected ReferencesBluemle, J.P., 1965, Geology and ground water resources of

Eddy and Foster Counties, North Dakota, Part I, Geology: North Dakota Geological Survey 44 and North Dakota State Water Commission County Ground Water Studies 5, 66 p.

Bluemle, J.P., 1973, Geology of Nelson and Walsh Counties, North Dakota Geological Survey Bulletin 57, pt. I, and North Dakota State Water Commission County Ground Water Studies 17, pt. I, 69 p.

Carlson, C.G., and Freers, T.F., 1975, Geology of Benson and Pierce Counties, North Dakota: North Dakota Geological Survey Bulletin 59, pt. I, and North Dakota State Water Com-mission County Ground Water Studies 18, pt. I, 32 p.

Downey, J.S., 1971, Ground-water basic data, Nelson and Walsh Counties, North Dakota: North Dakota Geological Survey Bulletin 57, pt. II, and North Dakota State Water Commission County Ground-Water Studies 17, pt. II, 459 p.

Downey, J.S., 1973, Ground-water resources, Nelson and Walsh Counties, North Dakota: North Dakota Geological Survey Bulletin 57, pt. III, and North Dakota State Water Commission County Ground-Water Studies 17, pt. III, 67 p.

Golden Gate Weather Services, 2001, North Dakota climate normals (1971-2000): accessed June 2005 at http://ggweather.com/normals/ND.htm

High Plains Regional Climate Center, 2005, Climate data—Holdings and services: accessed June 2005 at http://www.hrpcc.unl.edu/data.htm

Hobbs, H.C., and Bluemle, J.P., 1987, Geology of Ramsey County, North Dakota: North Dakota Geological Survey Bulletin 71, pt. I, and North Dakota State Water Commission County Ground Water Studies 26, pt. I, 69 p.

Hutchinson, R.D., 1977, Ground-water basic data for Ramsey County, North Dakota: North Dakota Geological Survey Bulletin 71, pt. II, and North Dakota State Water Commis-sion County Ground-Water Studies 26, pt. II, 344 p.

Hutchinson, R.D., and Klausing, R.L., 1980, Ground-water resources of Ramsey County, North Dakota: North Dakota Geological Survey Bulletin 71, pt. III, and North Dakota State Water Commission County Ground-Water Studies 26, pt. III, 36 p.

North Dakota Department of Health, 1994, Public water supply systems in North Dakota, chapter 33-17-01: Bismarck, North Dakota, 43 p.

North Dakota Indian Affairs Commission, 2005, Statistics— North Dakota's first nations: accessed December 2005 at http://www.health.state.nd.us/ndiac/statistics.htm

Paulson, Q.F., and Akin, P.D., 1964, Ground-water resources of the Devils Lake area, Benson, Ramsey, and Eddy Counties, North Dakota, N.D.S.W.C. Project No. 747: North Dakota Ground-Water Studies No. 56, 211 p.

Pusc, S.W., 1992a, Ground-water data: The interaction between ground water and a large terminal lake, Devils Lake, North Dakota: North Dakota State Water Commission Water-Resources Investigation 13, p. 65.

Pusc, S.W., 1992b, Water supply investigation for the Ramsey rural water project portions of Benson, Ramsey, Eddy, and Nelson Counties, North Dakota: North Dakota State Water Commission Ground-Water Studies Number 100, p. 441.

Radig, S.A., 1997, Warwick aquifer—LEPA irrigation moni-toring project: North Dakota Department of Health Division of Water Quality, 48 p.

Randich, P.G., 1971, Ground-water basic data, Benson and Pierce Counties, North Dakota: North Dakota Geological Survey Bulletin 59, pt. II, and North Dakota State Water Commission County Ground-Water Studies 18, pt. II, 360 p.

Randich, P.G., 1977, Ground-water resources of Benson and Pierce Counties, North Dakota: North Dakota Geological Survey Bulletin 59, pt. III, and North Dakota State Water Commission County Ground-Water Studies 18, pt. III, 76 p.

Reed, T.B., 1997, Digital simulation of ground-water flow in the Warwick aquifer, Fort Totten Indian Reservation, North Dakota: U.S. Geological Survey Water-Resources Investiga-tions 97-4114, 51 p.

Reed, T.B., 1998, Vulnerability of ground water in the Tokio and Warwick aquifers to surface contamination, Fort Totten Indian Reservation, North Dakota: U.S. Geological Survey Water-Resources Investigations 98-4152, 30 p.

Schuh, W.M., 1999, Assessment of potentially irrigable land in the area of the Warwick aquifer in Benson, Eddy, and Nelson Counties, North Dakota: North Dakota State Water Commis-sion, 53 p.

Spirit Lake Dakotah Sioux Nation, 2005, Spirit Lake Tribe: accessed December 2005 at http://www.spiritlakena-tion.com/about.htm

Strum, J.F., Heidt, C.J., and Bigler, R.J., 1979, Soil survey of Benson County area, North Dakota: U.S. Department of Agriculture, Soil Conservation Service, and U.S. Department of the Interior, Bureau of Indian Affairs, 245 p.

Trapp, H., Jr., 1966, Geology and ground water resources of Eddy and Foster Counties, North Dakota, Part II, Ground water basic data: North Dakota Geological Survey Bulletin 44 and North Dakota State Water Conservation Commission County Ground Water Studies 5, 243 p.

Trapp, H., Jr., 1968, Geology and ground water resources of Eddy and Foster Counties, North Dakota, Part III, Ground water resources: North Dakota Geological Survey Bulletin 44 and North Dakota State Water Conservation Commission County Ground Water Studies 5, 110 p.

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10.0 Selected References 21

U.S. Department of Agriculture, 2006, North Dakota county data--Crops: accessed May 2006 at http://www.nass.usda.gov:8080/QuickStats/Create_County_All.jsp

U.S. Environmental Protection Agency, 2004, 2004 edition of the drinking water standards and health advisories: Washing-ton, D.C., Office of Water, U.S. Environmental Protection Agency, EPA 822-R-04-005, 20 p.

U.S. Geological Survey, 1950, 1951, 1962, 1994, Topographic maps 1:24,000 scale: Series V871.

Vining, K.C., 1997, Water-quality assessments of ground water and surface water in the Warwick aquifer area, Fort Totten Indian Reservation, North Dakota: U.S. Geological Survey Open-File Report 97-201, 18 p.

Wright, M.R., and Sweeney, M.D., 1977, Soil survey of Eddy County and parts of Benson and Nelson Counties, North Dakota: U.S. Department of Agriculture, Soil Conservation Service, and U.S. Department of the Interior, Bureau of Indian Affairs, 202 p.

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22 Summary of Surface-Water Quality, Ground-Water Quality, and Water Withdrawals for the Spirit Lake Reservation

Appendix 1. Drinking-water regulations, common sources, and significant effects for selected properties and constituents.

[Regulations are from U.S. Environmental Protection Agency, 2004; mg/L, milligrams per liter; µg/L, micrograms per liter]

Property orconstituent

Drinking-waterregulation Common sources Significant effects

pH 6.5 to 8.5 standard units1

A measure of hydrogen-ion activity. Can be affected by geologic setting, biological activ-ity, municipal and industrial wastewater dis-charge, and atmospheric conditions.

Low pH water can cause corrosion, enhance release of other metals into water, and cause metallic taste. High pH water can give water a soda taste and result in accumulation of depos-its.

Dissolved solids

500 mg/L1 A result of rock weathering, agricultural runoff, and industrial discharge.

Excess dissolved solids can harm aquatic organ-isms and cause water to be unsuitable as a pub-lic, agriculture, and industry supply.

Sulfate 250 mg/L1 Occurs in some rocks. Also occurs in mine run-off, industrial wastewater discharge, and atmospheric deposition.

Excess amounts can harm aquatic organisms.

Chloride 250 mg/L1 Occurs in some rocks and ground-water dis-charge. Also occurs in road deicers, industrial and urban wastewater discharge, and atmo-spheric deposition.

Excess amounts can cause water to be unsuitable as a public, agriculture, and industry supply. Can harm aquatic organisms.

Arsenic 10 µg/L Found in sulfide ore deposits, volcanic gases, and geothermal water. Is used in some pesti-cides.

Causes problems with skin and circulatory system. Increases risk of cancer.

Barium 2 mg/L Erosion of natural deposits. Occurs in mine run-off and refinery wastewater discharge.

Causes increase in blood pressure.

Boron 600 µg/L2 Found in volcanic gases, geothermal springs, and minerals associated with some igneous rocks. Used in fertilizers and cleaning prod-ucts.

Small amounts are essential in plant growth.

Cadmium 5 µg/L Present in zinc ore minerals. Produced by metal refineries and discarded batteries.

May cause kidney damage.

Chromium 100 µg/L Produced by erosion from natural deposits, fos-sil fuel combustion, and discharge from steel and pulp mills.

Binds to soil sediments. Accumulates in living tis-sue. Causes dermatitis and liver and kidney damage.

Lead 15 µg/L3 Occurs from erosion of natural deposits. Had been used as gasoline additive.

Causes mental development problems in children and kidney damage in adults.

Manganese 50 µg/L1 Found in many igneous and metamorphic min-erals, organic deposits, and geothermal springs. Also used in fertilizers.

Essential element in plant metabolism. Can dis-color water and produce a bitter, metallic taste.

Mercury 2 µg/L Once used in pesticides. Also a byproduct of smelting and fossil-fuel combustion.

Causes kidney damage. Can accumulate in animals high in the food chain such as predatory fish and birds.

Selenium 50 µg/L Produced by erosion of natural deposits, petro-leum refining, and mining.

Accumulates in tissues, causing nervous and circu-latory problems. Becomes more available for plant uptake in alkaline soils.

1U.S. Environmental Protection Agency (2004) secondary drinking-water regulation.2U.S. Environmental Protection Agency (2004) health advisory.3U.S. Environmental Protection Agency (2004) treatment technique action level.

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Vining and Cates—Sum

mary of Surface-W

ater Quality, G

round-Water Q

uality, and Water W

ithdrawals

for the Spirit Lake Reservation, North D

akota—Open-File Report 2006–1144

In cooperation with the Spirit Lake Tribe

Printed on recycled paper