study of hollow fibres modified by dimethylolurea polymers

1
News and Views researchers suggested that this was probably due to the acidic cleaning agent's ability to dissolve inorganic deposits on the membrane. After cleaning with the acidic cleaning agent the cake of deposits on the membrane became more porous. During filtration of pure water the cake was compressed, hence the flux was time-dependent. However, the researchers stated that alkaline cleaning agents not only dissolve organic deposits, but have a positive effect on the membrane itself. Further information from: A.-S. donsson, Department of Chemical Engineering I, Lund University, P.O. Box 124, S-221 OO Lund, Sweden. Study of hollow fibres modified by dimethylolurea polymers The synthesis of modified polysulphone ultrafiltration hollow fibre membranes and studies on these membranes by XPS spectroscopy are described in a paper in J. Appl. Polym. Scl. (51, pp 1183-1187, 1994). The most serious operational constraint in the use of biological solution ultrafiltration with polysulphone membranes is that of fouling. This behaviour is often assigned to the hydrophobic character of the polysulphone that involves nonselective adsorption of proteins onto the membranes. To limit this problem the surface hydrophflicity is increased, for example by sulphonation of polysulphone, or coating with hydrophilie components or surfactant. Polymers obtained by polycondensation of dimethylolurea (DMU) coated onto polysulphone membranes should give good hydrophfliclty because DMU has carbonyl and hydroxy functional groups. Depending on the reaction conditions, polymers on the surface present a gel or a film form, called 'gel-supported' and 'coated', respectively. The aim of these studies was to determine if polyeondensation on the membrane modified the final form of the polymer. Modified and unmodified polysulphone membranes were analysed by XPS spectroscopy. The modification observed on a modified membrane was studied by reference to a previous article dealing with XPS analysis of gel and film DMU polymers (also published in J. Appl. Polym. Sci.). The researchers found that gel-supported membranes are modified by a polymer of film-type chemical structure. Also, they concluded that the nature of the support, polysulphone, does not affect the final form of the polymer. Further information from: P. Rouzies, Laboratoire de Traitements Physico-Chimiques des Eaux / Departement GPI, INSA, Complexe Scientifique de Rangueil, 31 077 Toulouse Cedex, France. Call for papers for biofunctional membranes conference The first announcement and call for papers has been published for the International Conference on Biofunctional Membranes to be held from 9-11 October 1994, at the University of Kentucky Center of Membrane Sciences in Lexington, Kentucky, USA. Biofunctional membranes are entities in which a biomolecule, a collection of biomolecules or cells, are incorporated into a polymeric matrix cast in the form of membranes. The conference will highlight the most current insights into the structure, function, and applications of biofunctional membranes including synthesis, structure, and applications to catalysis (bioreactors), bioseparations (affinity membranes), recognition and bioanalysis (biosensors and membrane-based imprinting), and to medical uses (artificial organs, etc). On 9 October, a tutorial on biofunctional membranes will be held. Various topics will be covered, among which are: structure and function relationships in biofunctional membranes, biosensors, affinity membranes, radiopharmaceutlcal uses of biofunctional membranes, and biofouling. The deadline for receipt of abstracts is 1 July 1994. Further information from: Prof D. Allan Butte[field, International Conference on Membranes, c / o Conferences and Institutes, 218 Peterson Service Building, University of Kentucky, Lexington, KY 40506-0005, USA. Tel: +1 606 257 5875. Fax: +1 606 323 1053. Services provided for whey processing plants Ionics has finalized a contract to provide whey processing services to Mid-America Dairymen, Inc, one of the USA's largest dairy cooperatives. Under the contract Ionics will provide equipment and services including oversight of whey processing operations, at Mid-America's whey processing plants located at Monett, Missouri and Fergus Falls, Minnesota. Ionics' Chairman and CEO said that the agreement with Mid-America presented the first opportunity for Ionics to use its expertise in membrane-based systems to provide processing services to the whey industry. Further information from: Ionlcs Inc, 65 Grove Street, Watertown, MA 021 72, USA. Tel: +1 617 926 2500. 2 Membrane Technology No. 46

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Page 1: Study of hollow fibres modified by dimethylolurea polymers

N e w s a n d V i e w s

researchers sugges ted tha t this was probably due to the acidic c leaning agent ' s abil i ty to dissolve inorganic deposi ts on the membrane . After cleaning with the acidic cleaning agent the cake of deposi ts on the m e m b r a n e became more porous. Dur ing filtration of pure water the cake was compressed, hence the flux was t ime-dependent .

However, the r e sea rcher s s ta ted tha t alkal ine cleaning agents not only dissolve organic deposits , bu t have a positive effect on the m e m b r a n e itself.

Further information from: A.-S. donsson, Department of Chemical Engineering I, Lund University, P.O. Box 124, S-221 OO Lund, Sweden.

Study of hollow fibres modif ied by dimethylolurea polymers The syn thes i s of modified polysu lphone ul t raf i l t rat ion hollow fibre m e m b r a n e s and s tudies on these m e m b r a n e s by XPS spect roscopy are descr ibed in a paper in J. Appl. Polym. Scl. (51, pp 1183-1187, 1994).

The mos t ser ious operat ional cons t ra in t in the use of biological solut ion ul t raf i l t rat ion with polysulphone m e m b r a n e s is tha t of fouling. This behaviour is often ass igned to the hydrophobic charac te r of the polysulphone tha t involves nonselect ive adsorpt ion of prote ins onto the membranes . To limit th is problem the surface hydrophfl ici ty is increased, for example by su lphona t ion of polysulphone, or coat ing with hydrophil ie components or surfac tant .

Polymers obta ined by po lycondensa t ion of d imethylo lurea (DMU) coated onto polysulphone m e m b r a n e s should give good hydrophfl icl ty because DMU has carbonyl and hydroxy funct ional groups. Depending on the react ion conditions, polymers on the surface p resen t a gel or a film form, called 'ge l -suppor ted ' and 'coated' , respectively. The aim of these s tudies was to de te rmine if po lyeondensa t ion on the m e m b r a n e modified the final form of the polymer. Modified and unmodif ied polysulphone m e m b r a n e s were ana lysed by XPS spectroscopy.

The modificat ion observed on a modified m e m b r a n e was s tudied by reference to a previous article deal ing with XPS analys is of gel and film DMU polymers (also pub l i shed in J. Appl. Polym. Sci.). The resea rchers found tha t ge l - suppor ted m e m b r a n e s are modified by a polymer of fi lm-type chemical s t ructure . Also, they concluded tha t the na tu re of the support , polysulphone, does not affect the final form of the polymer.

Further information from: P. Rouzies, Laboratoire de Traitements Physico-Chimiques des Eaux / Departement GPI, INSA, Complexe Scientifique de Rangueil, 31 077 Toulouse Cedex, France.

Call for papers for biofunctional membranes conference The first a nnounc e m e n t and call for pape r s has been pub l i shed for the In te rna t iona l Conference on Biofunctional Membranes to be held from 9-11 October 1994, a t the Universi ty of Kentucky Center of Membrane Sciences in Lexington, Kentucky, USA.

Biofunctional m e m b r a n e s are enti t ies in which a biomolecule, a collection of biomolecules or cells, are incorpora ted into a polymeric mat r ix cas t in the form of membranes . The conference will highlight the mos t cur ren t ins ights into the s t ruc ture , function, and appl ica t ions of biofunct ional m e m b r a n e s including synthesis , s t ruc ture , and appl ica t ions to catalysis (bioreactors), b iosepara t ions (affinity membranes) , recognit ion and b ioanalys is (biosensors and m e m b r a n e - b a s e d imprinting), and to medical uses (artificial organs, etc).

On 9 October, a tutor ial on biofunct ional membranes will be held. Various topics will be covered, among which are: s t ruc tu re and function re la t ionships in biofunct ional membranes , biosensors , affinity membranes , r ad iopha rmaceu t l ca l uses of biofunct ional membranes , a n d biofouling.

The deadl ine for receipt of abs t r ac t s is 1 Ju ly 1994. Further information from: Prof D. Allan Butte[field,

International Conference on Membranes, c / o Conferences and Institutes, 218 Peterson Service Building, University of Kentucky, Lexington, KY 40506-0005, USA. Tel: +1 606 257 5875. Fax: +1 606 323 1053.

Services provided for whey process ing plants Ionics has finalized a contract to provide whey process ing services to Mid-America Dairymen, Inc, one of the USA's largest dai ry cooperatives. Under the contract Ionics will provide equ ipment and services including oversight of whey process ing operat ions, at Mid-America 's whey process ing p lan t s located at Monett, Missouri and Fergus Falls, Minnesota.

Ionics' Cha i rman and CEO said tha t the agreement with Mid-America p resen ted the first oppor tuni ty for Ionics to use its expert ise in m e m b r a n e - b a s e d sys tems to provide process ing services to the whey industry.

Further information from: Ionlcs Inc, 65 Grove Street, Watertown, MA 021 72, USA. Tel: +1 617 926 2500.

2 M e m b r a n e Technology No. 46