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StrongOxidizingAgentsChemicalClassStandardOperatingProcedure

Rev.Date:2017-03-28

StrongOxidizingAgents(SOAs)H270H271H272

ThisSOPisnotasubstituteforhands-ontraining.PrintacopyandinsertintoyourlaboratorySOPbinder.

Department: Chemistry

DateSOPwaswritten: Thursday,March23,2017

DateSOPwasapprovedbyPI/labsupervisor: Friday,March24,2017

PrincipalInvestigator:Name:F.Fischer

Signature:______________________________

InternalLabSafetyCoordinatororLabManager:Name:StephenvonKugelgen

LabPhone:510.301.1058

OfficePhone:510.642.8252

EmergencyContact:Name:StephenvonKugelgen

PhoneNumber:510.301.1058

Location(s)coveredbythisSOP: TanHall674,675,676,679,680,683,684

1.Purpose

ThisSOPcoverstheprecautionsandsafehandlingproceduresfortheuseofStrongOxidizingAgents(SOAs).

ForalistofSOAscoveredbythisSOPandtheiruse(s),seethe“ListofChemicals”.ProceduresdescribedinSection12applytoallmaterialscoveredinthisSOP.Achangetothe“ListofChemicals”doesnotconstituteachangeintheSOPrequiringrevieworretraining.Ifyouhavequestionsconcerningtheapplicabilityofanyrecommendationorrequirementlistedinthisprocedure,contactthePrincipalInvestigator/LaboratorySupervisororthecampusChemicalHygieneOfficeratucbcho@berkeley.edu.

2.Physical&ChemicalProperties/DefinitionofChemicalGroup

Oxidizingchemicalsarematerialsthatpromote/supportcombustionorspontaneouslyevolveoxygenatroomtemperatureorwithslightheating.TherateofO2evolutionincreasesrapidlyasthetemperatureincreases,oftenleadingtoafireorexplosion.Thisclassofchemicalsincludesperoxides,chlorates,


Rev.Date:2017-03-28

perchlorates,nitrates,andpermanganates.Strongoxidizersarecapableofformingexplosivemixtureswhenmixedwithcombustible,organicoreasilyoxidizedmaterials.

3.PotentialHazards/Toxicity

Strongoxidizingagentscanpresentfireandexplosivehazards.Thishazardishighestwhenthereisapossibilityofanoxidizingagentcomingincontactwithareducingagent,afuel,orsomeothercombustible.TheNFPAdefinesfourcategoriesofstrongoxidizers,dividedbytheseverityofriskwhenmixedwithothercompounds:

•Class1.Anoxidizerthatdoesnotmoderatelyincreasetheburnrateofanothermaterial.•Class2.Anoxidizerthatwillmoderatelyincreasetheburnrate.•Class3.Anoxidizerthatwillcauseasevereincreaseinburnrate.•Class4.Anoxidizerthathasthepotentialtoleadtoanexplosiveoxidationwhencombinedwithothermaterials.

TheGloballyHarmonizedSystemofClassificationandLabelingofChemicals(GHS)designatesacutelytoxicchemicalsbyoneormoreofthefollowingHcodes:

H270Maycauseorintensifyfire;oxidizerH271Maycausefireorexplosion;strongoxidizerH272Mayintensifyfire;oxidizer

Strongoxidizingagentsmayalsohaveotherhazardouspropertiesinadditiontheiroxidizingproperties.Safeuserequiresassessingallpotentialhazards.ItisthePrincipal Investigator’s responsibility toensureactivity-specific laboratoryproceduresand/orprocessesaretakenintoaccountwhenusingthisChemicalClassSOP.Please,reviewtheSDSofanychemicalbeforeuse(seeSection11–SDSLocation).

4.EngineeringControls

Usetheengineeringcontrolslistedbelowunlessotherlab-specificinformationisincludedinSection12-Protocol/Procedure.

• WorkwithSOAs–theworkmustbeconductedinafumehoodunlessothercontrolsaredesignatedinthelab-specificProtocol/Proceduresection.Sashheightmustbekeptaslowaspossibletoavoidescapingfumesandprovideaphysicalbarrier.

• LaboratoriesandroomswhereSOAsareusedmusthavegeneralroomventilationthatisnegativepressurewithrespecttothecorridorsandexternalenvironment.Thelaboratory/roomdoormustbekeptclosedatalltimes.

5.PersonalProtectiveEquipment

Ataminimum,thefollowingPPEmustbewornatalltimes.EyeandFaceProtection

A. ANSIZ87.1-compliantsafetyglasseswithsideshields,orchemicalsplashgoggles.


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• Ordinary prescription glasses will NOT provide adequate protection unless they alsomeetANSIstandardandhavecompliantsideshields.

B. Ifthepotentialforexplosion/splashingexists,andadequatecoverageisnotprovidedbythehoodsash,afaceshieldmustbeworn.

SkinandBodyProtectionA. Glovesarerequiredwhenhandlinghazardouschemicals.

• RefertospecificchemicalSDSforinformationongloveselection.• Foradditionalinformationongloveselection,goto:

http://ehs.berkeley.edu/hs/63-laboratory-safety/94-glove-selection-and-usage.htmlB. Labcoatsarerequiredwhenhandlinghazardouschemicalsinthelab.Selectthetypeoflabcoat

accordingtothehazardsatthespecificworkplace.C. Longpants,closed-toe/closed-heelshoes,coveredlegs,andankles.

RespiratoryProtectionRespiratoryprotectionisnormallynotrequiredforUCBerkeleylaboratoryactivities.Anylabpersonnelconsideringtheuseofarespirator(e.g.N-95respirator,dustmask)mustcontactEH&Sforaworkplaceassessment.

6.FirstAidProceduresandMedicalEmergencies

Intheeventofaninjury,notifyyoursupervisorimmediatelyandEH&Swithin8hours.

GototheOccupationalHealthFacility(TangHealthCenter,oncampus); ifafterhours,gotothenearestemergencyroom(AltaBates,2450AshbyAveinBerkeley);or

Call911(fromacellphone:510-642-3333)if:

• itisalifethreateningemergency;or

• younotareconfidentinyourabilitytofullyassesstheconditionsoftheenvironmentand/orthe condition of the contaminated/injured person, or you cannot be assured of your ownsafety;or

• thecontaminated/injuredpersonisnotbreathingorisunconscious.

Please remember to provide a copy of the appropriate manufacturer SDS (if available) to theemergency responders or physician. At a minimum, be ready to provide the identity/name of anyhazardousmaterialsinvolved.

Incaseofskincontact

Ifskincontactoccurs,and/orskinorclothingareonfire,immediatelydrenchinthesafetyshowerwithcopious amounts of water for no less than 15 minutes to remove any remaining contaminants. Ifpossibletodosowithoutfurtherinjury,removeanyremainingjewelryorclothing.

Incaseofeyecontact

Rinse thoroughlywith plenty ofwater using an eyewash station for at least 15minutes, occasionallyliftingtheupperandlowereyelids.Removecontactlensesifpossible.


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Ifswallowed

DoNOT induce vomiting unless directed otherwise by the SDS. Never give anything bymouth to anunconsciousperson.Rinsemouthwithwater.

Ifinhaled

Moveintofreshair.

Needlestick/punctureexposure

Washtheaffectedareawithantisepticsoapandwarmwaterfor15minutes.

7.SpecialHandling,StorageandDisposalRequirements

Lab-specificinformationonhandlingandstoragemaybeincludedintheProtocol/Proceduresection.Precautionsforsafehandling

• Removeflammablesandreducingagentsfromimmediateworkarea.• Strongoxidizergases(e.g.,chlorine,oxygen)canreactstronglywithmetals.Useonlycompatible

cylinderfittings,regulatorsandpiping.Ifotherchemicalshaverecentlybeenusedwitharegulator,extensivelyflushtheregulatorwithaninertgasbeforeuse.

• Whenusingperchloratesalts,ifthepossibilityofthereleaseofperchloricacidfumesexists,theprocessmustbedoneinahooddesignedforperchloricacidrelease(seePECSOP).

• Eliminateorsubstituteforalesshazardousmaterialwhenpossible.• Designyourexperimenttousetheleastamountofmaterialpossibletoachievethedesired

result.• DonotexceedthescaleofproceduresspecifiedinProtocol/Proceduresectionwithoutapproval

ofthePI.• Verifyyourexperimentalset-upandprocedurepriortouse.• Knowthelocationofthenearesteyewash,safetyshowerandfireextinguisherbeforebeginning

work.• Uponleavingtheworkarea,removeanypersonalprotectiveequipmentwornandwashhands.• Attheendofeachproject,thoroughlydecontaminatetheworkareaaccordingtothematerial

beinghandled.Conditionsforsafestorage

• Oxidizersmustbestoredseparatelyfromflammablesandreducingagents,andwithconsiderationtootherhazardouspropertiesoftheparticularoxidizer.

• GasCylinders:Cylindersmustbestoredupright,withvalveprotectioncapinplace,andfirmlysecuredtopreventfallingorbeingknockedover.Cylindertemperaturesnottoexceed52°C(125°F).

Disposal● Wastematerialsgeneratedmustbetreatedasahazardouswaste.● TheemptycontainermustberinsedthreetimeswithaCOMPATIBLEsolvent;leaveitopen

inthebackofthehoodovernight.Solventrinsesandwaterrinsemustbedisposedofashazardouswaste.

● Asanalternative,unrinsedemptycontainerscanbedisposedofthroughEH&Sashazardouswaste.Theunrinsedemptycontainersmustbecapped.


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● Donotmixwithincompatiblewastestreams.● Decontaminationofcontainersinordertousethemforotherpurposesisnotpermitted.

8.ChemicalSpill

Spill–Assesstheextentofdanger;ifnecessaryrequesthelpbycalling911(fromacellphone:510-642-3333)foremergencyassistanceor510-642-3073fornon-lifethreateningsituations.Ifyoucannotassesstheconditionsoftheenvironmentwellenoughtobesureofyourownsafety,donotenterthearea.Ifpossiblehelpcontaminatedorinjuredpersons.Evacuatethespillarea.Avoidbreathingvaporsfromspill.Ifpossible,confinethespilltoasmallareausingaspillkitorabsorbentmaterial.Keepothersfromenteringcontaminatedarea.

• MinorSpill–Intheeventofaminorspill,ifthereisnopotentialforhazardouschemicalexposure,reportthespillto510-642-3073andproceedtocleanit,ifyouaretrained.Useappropriatepersonalprotectiveequipmentandclean-upmaterialforchemicalspilled.Doublebagspillwasteinclearplasticbags,labelandrequestpick-up.

• MajorSpill–Anyhazardouschemicalspillthatinvolveschemicalexposure,anychemicalspillthatduetosizeand/orhazardrequirescapabilitiesbeyondyourtraining,oranychemicalspillthatgivestheperception(becauseofodor,forexample)thattherehasbeenahazardousrelease.Call911or510-642-3073forassistance.

9.CleaningandDecontamination

Lab-specificinformationondecontaminationmaybeincludedinSection12-Protocol/Procedure.• WearingproperPPE,laboratoryworksurfacesmustbecleanedattheconclusionofeach

procedureandattheendofeachworkday.• Decontaminateallequipmentbeforeremovingfromadesignatedarea.

10.HazardousWasteDisposal

LabelWaste

• Labelallwastecontainers.SeetheEH&SFactSheet,“HazardousWasteManagement”forgeneralinstructionsonproceduresfordisposingofhazardouswaste.

DisposeofWaste

• Disposeofregularlygeneratedchemicalwastewithin6months.

• ContactEH&Sat642-3076ifyouneedassistance.

11.SafetyDataSheet(SDS)Location

SDScanbeaccessedonlineathttp://ucsds.com


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12.Protocol/Procedure–StrongOxidizingAgents

Procedure/Use Scale EngineeringControls/Equipment

PPE(eye,face,gloves,clothes) ProcedureStepsandPrecautions

1.UseSOAinoxidationsorasareagentinchemicalreactions.

Upto10gor200mLassuppliedinthereagentbottle.RemembertoobtainPIapprovalifhigherscaleisnecessary.Documentthisapprovalinyournotebook

Allreactionsusingthesematerialsmustbeperformedinaproperlyoperatingfumehoodwiththesashaslowaspossible.

Eyeprotection:WearANSIApprovedtight-fittingsafetygogglesorsafetyglasseswithsideshields.FaceProtection:Faceshieldsaretobeusedwhenthereisnoprotectionfromthehoodsash.HandProtection:Confirmcompatibilityofglovematerialwithchemicalbeingused.Generalguidance(unlessotherwisespecifiedinthespecificSDS):Nitrileglovesmustbeusedtopreventincidentalcontact.Forspillhandlingorforpotentialcontactwithlargerquantities,usedoublenitrileorheaviergaugenitrileorneoprenegloves.Glovesmustbeinspectedpriortouse.Washanddryhandsafteruse.Clothing:Wearlabcoat;fulllengthpantsorequivalent;andclose-toed,close-heeledshoes.

Usethesmallestamountnecessarytocompletetheexperiment.

Iffollowingaliteratureprocedure,donotmodifyitwithoutapprovalfromPI.ConsultPIonprocessbeforebeginning.

Eliminateanyincompatiblematerialsfrompotentialspillarea.

Carefullyweighmaterials.Useofenclosedbalanceortaredmethodwithsecondarycontainmentisrecommendedforsolidoxidizers.

Avoidspillnearthebalanceorcreatinganydust.

Avoidheatingorflameswhenhandlingthecompound.

Keepcontainersclosedwhennotinuse.

Cleanupanypowderthatmayhavespilledanddiscardeverythingaccordingtothechemicaldisposalprocedure.

Authorizedpersonusingastrongoxidizingagentisresponsibleforthesafecollectionanddisposalofwaste.Neverdisposeintocontainerwithincompatiblematerials.Neverdisposeintosinkdrain.

SpecialRemarksonExplosionHazards:StrongOxidizingAgentsreactEXPLOSIVELY


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withreducingagentsandoxidizablesolvents.DonotuseoxidizablesolventsTemperaturecontroloverthereactionsisrequiredtominimizepotentialexplosions.Caremustbetakentominimizeviolentreactionswithreducingagentsespeciallyunderacidicconditions.Gaseousoxygencanbeemitteduponreactionbetweenperoxideandsomemetalsorbysimplyheatingthusadequateventilation(pressurebubbleronaSchlenkmanifold,oranequilibratingballoon)hastobeusedtopreventdangerousoverpressurization.

Notes AnydeviationfromthisSOPrequiresapprovalfromPI.


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13.DocumentationofTraining(signatureofallusersisrequired)

• PriortoconductinganyworkwithSOAs,designatedpersonnelmustprovidetrainingtohis/herlaboratorypersonnelspecifictothehazardsinvolvedinworkingwiththissubstance,workareadecontamination,andemergencyprocedures.

• ThePrincipalInvestigatormustprovidehis/herlaboratorypersonnelwithacopyofthisSOPandacopyoftheSDSprovidedbythemanufacturer.

IhavereadandunderstandthecontentofthisSOP:

Name Signature Identifier Date


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Appendix–ListofStrongOxidizingAgents(non-exhaustivelist)TheNationalFireProtectionAssociation(NFPA)Code430(1995)"CodefortheStorageofLiquidandSolidOxidizers"providesmanyexamplesoftypicaloxidizingmaterialslistedaccordingtotheNFPAclassificationsystem.Someoftheseexamplesinclude:

ChemicalName Formula CAS# ClassAmmoniumperchlorate NH4ClO4 7790-98-9 4Ammoniumpermanganate NH4MnO4 13446-10-1 4Bariumperoxide BaO2 1304-29-6 1Calciumchlorate CaClO3 10043-53-4 2Calciumhypochlorite Ca(OCl)2 7778-54-3 2(50%orlessbyweight)Chromicacid H2Cr2O7 7738-94-5 2

Hydrogenperoxide H2O2 7722-84-1>27.5-52%Class2,>52-91%Class3

Magnesiumperoxide MgO2 1335-26-8 1

NitricAcid HNO3 <40%Class1,>40-86%Class2,>86%Class3

Perchloricacid HClO4 7601-90-3>50-60%Class2,>60-72%Class3,>72%Class4

Potassiumbromate KBrO3 7758-01-2 3Potassiumchlorate KClO3 3811-04-9 3Potassiumperoxide K2O2 17014-71-0 2Sodiumchlorate NaClO3 7775-09-9 3Sodiumchlorite NaOCl 7758-19-2 >40%Class3Sodiumperchlorate NaClO4 7601-89-0 2Sodiumperoxide Na2O2 1313-60-6 2


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ListofChemicals

Chemical(s) Chemical(s) Chemical(s)((S)-(−)-2,2ʹ-Bis(diphenylphosphino)-1,1ʹ-binaphth

([2S,3S]-Bis[Diphenylphosphino]butane)(η3-allyl)

([R]-[+]-2,2ʹ-Bis[diphenylphosphino]-1,1ʹ-binaphth

(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphen

(Bicyclo[2.2.1]hepta-2,5-diene)[1,1ʹ-bis(diphenylp

1,1ʹ,3,3,3ʹ,3ʹ-Hexamethylindotricarbocyanineperch

1,1ʹ-Dioctadecyl-4,4ʹ-bipyridiniumdiperchlorate

1,3-Dibromo-5,5-dimethylhydantoin 1,3-Dichloro-5,5-dimethylhydantoin

1,3-Diiodo-5,5-dimethylhydantoin 1-Bromo-2,3,4-tribenzoyl-L-rhamnopyranose

1-Butyl-3-methylimidazoliumnitrate

1-Ethyl-3-methylimidazoliumnitrate 2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide

2,2'-Bipyridiniumchlorochromate

3-Bromo-1-chloro-5,5-dimethylhydantoin

4-(Dimethylamino)pyridiniumchlorochromate

4-Carboxypyridiniumdichromate

4-Methoxybenzyloxycarbonylazide 9-Mesityl-10-methylacridiniumperchlorate

Aluminumperchloratenonahydrate

Aminoguanidinenitrate Ammoniumcerium(IV)nitrate AmmoniumchromateAmmoniumdichromate Ammoniumiodate AmmoniumnitrateAmmoniumnitrate-15N Ammoniumnitrate-15N2 AmmoniumperchlorateAmmoniumperrhenate Ammoniumpersulfate Ammonium-15NnitrateBariumbromate Bariumchloratemonohydrate BariumchromateBariumiodatemonohydrate Bariummanganate BariumnitrateBariumnitritehydrate Bariumperchlorate BariumperchloratehydrateBariumperchloratetrihydrate Bariumperiodate BariumperoxideBerylliumnitratesolution Bis(2,2,6,6-tetramethyl-3,5-

heptanedionato)lead(IIBis(bicyclo[2.2.1]hepta-2,5-diene)rhodium(I)perch

Bis(tetrabutylammonium)dichromate

Bis(triphenylphosphoranylidene)ammoniumnitrite

Bis[(R)-(−)-2,2ʹ-bis(diphenylphosphino)-1,1ʹ-binap

Bis[5-[[4-(dimethylamino)phenyl]imino]-8(5H)-quino

Bismuthnitrateoxide Bismuthsubnitrate

Bismuth(III)nitratepentahydrate Bismuth(III)subnitratemonohydrate Bismuth(V)fluorideBromodiethylsulfoniumbromopentachloroantimonate(V

Bromonitromethane Cadmiumperchloratehydrate

Calciumhypochlorite Calciumiodate CalciumnitratehydrateCalciumnitrate-15N2 Calciumperchloratetetrahydrate CalciumperoxideCalciumperrhenate Cerium(III)nitratehexahydrate CesiumdichromateCesiumnitrate Cesiumperchlorate CesiumpermanganateChloricacid Chlorine Chromium(III)nitratenonahydrate


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Chromium(III)nitratesolution Chromium(VI)oxide ChromylchlorideCobalt(II)nitratehexahydrate Cobalt(II)perchloratehexahydrate CopperchromiteCopper(II)nitratehemi(pentahydrate)

Copper(II)nitratehydrate Copper(II)nitratetrihydrate

Copper(II)perchloratehexahydrate Dess-Martinperiodinane DibromoisocyanuricacidDichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazol

Dinitrato(1,10-phenanthroline)copper(II)

Dinitrogentrioxide(gas)(unlabelledN2O3)

Diphenyliodoniumnitrate Dysprosium(III)nitratehydrate Erbium(III)nitratepentahydrateErbium(III)perchloratesolution Europium(III)nitratehydrate Europium(III)nitratepentahydrateGadolinium(III)nitratehexahydrate Gallium(III)nitratehydrate Gallium(III)perchloratehydrateGuanidinenitrate Holmium(III)nitratepentahydrate Holmium(III)perchloratesolutionHydrogenperoxidesolution Hydrogenperoxide-Ureaadduct ImidazoliumdichromateIndium(III)nitratehydrate Indium(III)perchloratehydrate IodicacidIodinetrichloride Iodopentoxide Iron(II)perchloratehydrateIron(III)perchloratehydrate Lanthanum(III)nitratehexahydrate Lanthanum(III)nitratehydrateLeadoxide Lead(II)iodate Lead(II)nitrateLead(II)perchloratehydrate Lead(II)perchloratetrihydrate LithiumdichromatehydrateLithiumhypochlorite Lithiumiodate LithiumnitrateLithiumperchlorate Lithiumperchloratetrihydrate LithiumperoxideLithium-6Linitrate Lutetium(III)nitratehydrate MagnesiumiodatetetrahydrateMagnesiumnitrate Magnesiumperchlorate Magnesiumperchlorate

hexahydrateMagnesiumperchloratehydrate Magnesiumpermanganatehydrate MagnesiumperoxidecomplexMagnesiumperoxidelight Manganese(II)nitratehydrate Manganese(II)nitratesolutionManganese(II)nitratetetrahydrate Manganese(II)perchloratehydrate Manganese(III)fluorideMercury(II)perchloratehydrate N,N-Dichloro-p-toluenesulfonamide N,N-Dimethyl-2,4,6-trinitroaniline

solutionNeodymium(III)nitratehexahydrate Neodymium(III)nitratehydrate NickelperoxideNickel(II)nitratehexahydrate Nickel(II)peroxidehydrate NitricacidNitricacid-dsolution Nitricoxide Nitric-15NacidsolutionNitric-15Nacid-18O3solution Nitric-15Noxide-18O NitrogendioxideNitrosylsulfuricacidsolution Nitrousoxide Nitrousoxide-15N2Nitrousoxide-15N2,18O N-tert-Butyl-N-(2-methyl-1-

phenylpropyl)-O-(1-phenN-tert-Butyl-O-[1-[4-(chloromethyl)phenyl]ethyl]-N

Oxygen Oxygen-17O2 Oxygen-18O2Palladium(II)nitratedihydrate Palladium(II)nitratehydrate Pentaamminecarbonatocobalt(III)

nitratePerchloricacid Perchloricacid-dsolution PeriodicacidPhenylselenozincchloride Phosphomolybdicacidhydrate Platinum(IV)oxidePlatinum(IV)oxidehydrate Platinum(IV)oxidemonohydrate PotassiumbromatePotassiumchlorate Potassiumchlorochromate Potassiumdichromate


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Potassiumdioxide Potassiumferrate(VI) PotassiumhydrogendiiodatePotassiumiodate Potassiummanganate PotassiumnitratePotassiumnitrate-14N Potassiumnitrate-15N Potassiumnitrate-15N,18O3Potassiumnitrite Potassiumnitrite-15N PotassiumperchloratePotassiumperiodate Potassiumpermanganate PotassiumperoxydiphosphatePotassiumperrhenate Potassiumperruthenate PraseodymiumnitratepentahydratePraseodymium(III)nitratehexahydrate

Pyridiniumchlorochromate Pyridiniumdichromate

Pyridiniumfluorochromate Rhodium(III)nitratehydrate RubidiumchromateRubidiumnitrate Rubidiumperchlorate Ruthenium(III)nitrosylnitrate

solutionSamarium(III)nitratehexahydrate Scandium(III)nitratehydrate Scandium(III)perchloratesolutionSilverbromate Silverchlorate SilverchromateSilveriodate Silvernitrite SilveroxideSilverperchlorate Silverperchloratehydrate SilverperchloratemonohydrateSilver(I)oxide Silver(II)fluoride Sodium(meta)periodateSodium(para)periodate Sodiumbis(2-hydroxy-2-

methylbutyrato)oxochromate(Sodiumbromate

Sodiumchlorate Sodiumchlorite SodiumdichloroisocyanurateSodiumdichromate Sodiumdichromatedihydrate Sodiumhexanitrocobaltate(III)Sodiumiodate Sodiumnitrate Sodiumnitrate-15NSodiumnitrite Sodiumnitrite-15N SodiumperboratemonohydrateSodiumperboratetetrahydrate Sodiumpercarbonate SodiumperchlorateSodiumperchloratemonohydrate Sodiumperchlorate-18O4 SodiumpermanganatemonohydrateSodiumpermanganatesolution Sodiumperoxide SodiumperrhenateSodiumpersulfate Strontiummanganate(VI) StrontiumnitrateStrontiumperoxide Terbium(III)nitratehexahydrate Terbium(III)nitratepentahydratetert-Butylhypochlorite Tetraamminepalladium(II)nitrate

solutionTetraammineplatinum(II)hydrogencarbonate

Tetraammineplatinum(II)nitrate Tetrabutylammonium(meta)periodate

Tetrabutylammoniumchlorochromate

Tetrabutylammoniumnitrate Tetrabutylammoniumperchlorate TetraethylammoniumnitrateTetrahexadecylammoniumperchlorate

Tetrahexylammoniumperchlorate Tetrakis(pyridine)silver(I)dichromate

Tetramethylammoniumnitrate Tetramethylammoniumperchlorate TetranitromethaneTetrapentylammoniumperchlorate Tetraphenylphosphonium

acetatodichlorodioxoruthenaTetrapropylammoniumperchlorate

Tetrapropylammoniumperruthenate Thallium(I)nitrate Thallium(I)perrhenateThallium(III)nitratetrihydrate Thallium(III)perchloratehydrate ThoriumnitratehydrateThulium(III)nitratepentahydrate Tin(IV)nitrate Titanium(IV)nitrateTrichloroisocyanuricacid Trichloromelamine Tris(ethylenediamine)cobalt(III)


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nitrateTris(ethylenediamine)rhodium(III)nitrate

Tris[trinitratocerium(IV)]paraperiodate

Uranylnitratehexahydrate

Woodward’sreagentL Xenondifluoride Ytterbium(III)nitratepentahydrateYttrium(III)nitratehexahydrate Yttrium(III)nitratetetrahydrate Yttrium(III)perchloratesolutionZincnitratehexahydrate Zincnitratehydrate ZincperchloratehexahydrateZincperoxide Zirconium(IV)nitrate Zirconium(IV)oxynitratehydrateZirconylnitratesolution

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