stoichiometry introduction: mole-mole relationships

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Stoichiometry Introduction: Mole-Mole Relationships

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Take a look at this “recipe” for the formation of ammonia gas. N 2 (g) + 3 H 2 (g) → 2 NH 3 (g) We can combine 1 part N 2 and 3 parts H 2 to produce 2 parts NH 3. We would typically state that we can combine 1 mole N 2 and 3 moles H 2 to produce 2 moles NH 3.

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Page 1: Stoichiometry Introduction: Mole-Mole Relationships

StoichiometryIntroduction:

Mole-Mole Relationships

Page 2: Stoichiometry Introduction: Mole-Mole Relationships

Significance of Coefficients

What do the coefficients in a chemical reaction represent?

Ratio of molecules that react Ratio of moles that react

Page 3: Stoichiometry Introduction: Mole-Mole Relationships

Take a look at this “recipe” for the formation of ammonia gas.N2(g) + 3 H2(g) → 2 NH3(g)

We can combine 1 part N2 and 3 parts H2 to produce 2 parts NH3.

We would typically state that we can combine 1 mole N2 and 3 moles H2 to produce 2 moles NH3.

Page 4: Stoichiometry Introduction: Mole-Mole Relationships

This is the recipe for making sandwiches...

What do you need to make a plain and ordinary ham sandwich?

2 Bread + 1 Ham → 1 Sandwich

Page 5: Stoichiometry Introduction: Mole-Mole Relationships

Stoichiometry allows us to compare any two of the substances in a “recipe” at a time.

Typical queries might be:How many sandwiches can I prepare with 12 pieces of bread?How much bread is needed to completely use 8 slices of ham when making sandwiches?If only 4 slices of ham are in my refrigerator, how many sandwiches can I make?

Page 6: Stoichiometry Introduction: Mole-Mole Relationships

How many sandwiches can I prepare with 12 pieces of bread?

2 Bread + 1 Ham → 1 Sandwich

x12 BreadBreadSandwich

21

6 Sandwiches=

Page 7: Stoichiometry Introduction: Mole-Mole Relationships

How much bread is needed to completely use 8 slices of ham when making

sandwiches?

2 Bread + 1 Ham → 1 Sandwich

8 Ham x

HamBread

12

= 16 Bread

Page 8: Stoichiometry Introduction: Mole-Mole Relationships

If only 4 slices of ham are in my refrigerator, how many sandwiches can I make?

2 Bread + 1 Ham → 1 Sandwich

4 Ham xHam

Sandwich=

1

14 Sandwiches

“Mole Ratio” conversion

step

Page 9: Stoichiometry Introduction: Mole-Mole Relationships

Now, back to the reaction for the production of ammonia.

N2(g) + 3 H2(g) → 2 NH3(g)

How many moles of NH3 can be produced by the complete reaction of 4.0 moles of N2?

4.0 mol N2xmol N2

mol NH3

1

2=8.0 moles NH3

“Mole Ratio” conversion

step

Page 10: Stoichiometry Introduction: Mole-Mole Relationships

Lets take a look at another example.

N2(g) + 3 H2(g) → 2 NH3(g)

How many moles of N2 are needed to react with 6.0 moles of H2?6.0 mol H2x

mol H2

mol N2

3

1= 2.0 moles N2

“Mole Ratio” conversion

step

Page 11: Stoichiometry Introduction: Mole-Mole Relationships

A stoichiometry example with mass relationships.

N2(g) + 3 H2(g) → 2 NH3(g)

What mass of NH3 can be produced by the complete reaction of 15.0 g of H2?15.0 g H2 x

mol H2

mol NH3

2.02 2

=

84.4 g NH3

mole H2

g H2

1x

3x

mol NH3

g NH3

117.04