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Star Global Conference - Vienna 2014 Dr. David Wenger Simulation of the hydrogen fueling process 18.03.14

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Page 1: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Star Global Conference - Vienna 2014

Dr. David Wenger

Simulation of the hydrogen fueling process

18.03.14

Page 2: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Key Facts

• Engineering company with 15 employees

• Location: Ulm, Germany

• CEO: Dr.-Ing. David Wenger

• Services:

Thermodynamics

CFD Simulation

Refueling Simulation (H2 and CNG)

COMSOL Multiphysics Consulting

MATLAB Programming

Simulation Software Development

• Software: MATLAB, Simulink, COMSOL

Multiphysics, Star-CCM+

2 Simulation of the hydrogen fueling process 27.03.2014

Page 3: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Our customers

3 27.03.2014 Simulation of the hydrogen fueling process

Page 4: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Hydrogen fueling: Overview

• Hydrogen powered fuel cell vehicles

will enter the commercial market in the

next few years.

• Hydrogen is stored on board in high

pressure gas tanks.

• Pressure level: 70 MPa at 15°C

• Fueling of FCV is possible in three

minutes thanks to world wide standard

SAE J2601 (vs. battery electric

vehicles: several hours)

• Typical range of fuel cell vehicle: 400-

600 km (vs. battery electric vehicles

100-200 km)

27.03.2014 4 Simulation of the hydrogen fueling process

Page 5: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Hydrogen fueling storage: Challenges

• State of Charge (SoC) of gas tank is f(p,T).

• Thermodynamic behavior of hydrogen is challenging

– Very high pressure of up to 87.5 MPa

– Compression during fueling leads to fast temperature rise

• Maximum allowed temperature of tank material of 85°C must

not be exceeded

• Therefore gas is precooled at station to -40°C in order to

compensate the heat of compression

• This leads to temperature gradients in components of

T_ambient -40°C +85°C in a few minutes

– High gas velocities of >300 m/s in fueling line, therefore high

pressure drop

27.03.2014 5 Simulation of the hydrogen fueling process

Custumer expectation: All vehicles have to be filled to 98-100% in 3

min regardless of initial and ambient conditions.

Page 6: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Consequences for tank development and modeling

• Real gas behavior: User-defined equations are needed for every

property such as density, heat capacity, viscosity etc.

• Different vehicles have different tank volumes and therefore different

storage capacities.

• Different tank geometries have different surface to volume ratios.

• Tank volume and tank conditions are not known to the station, so a

wide range of conditions has to be analyzed in order to understand

physics.

• Critical: Internal Heat Transfer Coefficient (gas tank wall)

– Different inlet geometries lead to different inlet velocities

– Different inlet velocities lead to different wall velocities and

therefore different heat transfer coefficients

27.03.2014 6 Simulation of the hydrogen fueling process

The model is needed to understand the correlation between initial and

inlet conditions and the heat transfer coefficient gas-wall

Page 7: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Simulation model with Star-CCM+

• The fueling process was simulated with Star-CCM+

• The model only included the vessel, no other components such as

pipes etc. were taken into account.

• Target values are the temperature and the velocity distribution.

• The material properties were added as field functions.

• The incoming hydrogen flow is defined as a mass flow boundary

condition (angle can be defined). Other option: pressure ramp

27.03.2014 7 Simulation of the hydrogen fueling process

Hydrogen

Inlet Plastic or aluminum liner Composite wrap

Picture simplified

due to NDAs

Page 8: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Mesh

• The geometry was meshed with polyhedral elements and prism layers

near the wall.

• Additionally volumetric control entities were added for refining the mesh

around the inlet.

• The mesh was verified by a sensitivity study.

• The whole mesh consists of ~200.000 cells.

27.03.2014 8 Simulation of the hydrogen fueling process

Volumetric

control entity

Prism layer

Polyhedral elements

Picture simplified

due to NDAs

Page 9: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Results of the simulation - Velocity

• With the simulation it is possible to

generate temperature and velocity

plots for every time step.

• The mass flow is given by the

shown ramp function. Because

the pressure and therefore the

density are changing, the

maximum velocity at the inlet

varies between 0 and 670 m/s.

27.03.2014 9 Simulation of the hydrogen fueling process

~ 1m

0

5

10

15

20

25

0 50 100 150

m_in

let

(g/s

)

time (s)

Page 10: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Results of the simulation – Temperature

• The plots show a correlation between

temperature and velocity.

• Highest gas temperature during fueling:

at the back end of the tank

• Highest gas temperature after fueling:

upper part of the tank

• The differences in local gas temperature

are up to 50K

• Depending on the inlet geometry and

angle, the hot spot at the rear end of the

tank can be reduced

27.03.2014 10 Simulation of the hydrogen fueling process

It is obvious that the position of the

temperature sensor is crucial as no “bulk

temperature” exists during fueling

Page 11: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Improvement in inlet geometry

• An optimum inlet angle leads to high velocities at the tank wall instead

of „chaotic turbulence“

• This leads to lower temperature gradients in the tank and to lower end

temperatures

• An example is shown here:

27.03.2014 11 Simulation of the hydrogen fueling process

Page 12: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Conclusion

• The fueling process is extremely challenging, the most difficult question

is the internal heat transfer coefficient.

• This question was answered with our Star-CCM+ model, giving a good

prediction for the heat transfer coefficient as a function of inlet velocity

and initial conditions (1).

• The results were validated with tests at Powertech Labs, Vancouver

• These results were accepted by the whole automotive and gas industry

and used to define the standard.

• SAE J2601 is the world wide standard for fueling hydrogen powered

fuel cell vehicles.

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(1) Chakkrit Na Ranong, Steffen Maus, Jobst Hapke, Georg Fieg, David

Wenger: Approach for the Determination of Heat Transfer Coefficients for

Filling Processes of Pressure Vessels With Compressed Gaseous Media,

Heat Transfer Engineering

Volume 32, Issue 2, 2010, Pages 127-132

Page 13: Star Global Conference - Vienna 2014 Simulation of the ...mdx2.plm.automation.siemens.com/sites/default/files... · generate temperature and velocity plots for every time step. •

Kontakt:

Dr.-Ing. David Wenger

Wenger Engineering GmbH

Einsteinstr. 55

89077 Ulm

0731-159 37 500

[email protected]

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