spectroscopic measurement of the vapour pressure of ice by k. bielska, d. k. havey, g. e. scace, d....

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Spectroscopic measurement of the vapour pressure of ice by K. Bielska, D. K. Havey, G. E. Scace, D. Lisak, and J. T. Hodges Philosophical Transactions A Volume 370(1968):2509-2519 June 13, 2012 ©2012 by The Royal Society

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Page 1: Spectroscopic measurement of the vapour pressure of ice by K. Bielska, D. K. Havey, G. E. Scace, D. Lisak, and J. T. Hodges Philosophical Transactions

Spectroscopic measurement of the vapour pressure of ice

by K. Bielska, D. K. Havey, G. E. Scace, D. Lisak, and J. T. Hodges

Philosophical Transactions AVolume 370(1968):2509-2519

June 13, 2012

©2012 by The Royal Society

Page 2: Spectroscopic measurement of the vapour pressure of ice by K. Bielska, D. K. Havey, G. E. Scace, D. Lisak, and J. T. Hodges Philosophical Transactions

Calculated water vapour absorption coefficient (based on Voigt profiles) at T=296 K, a total pressure of 13.3 kPa and molar fraction of 10−3 water vapour in air.

K. Bielska et al. Phil. Trans. R. Soc. A 2012;370:2509-2519

©2012 by The Royal Society

Page 3: Spectroscopic measurement of the vapour pressure of ice by K. Bielska, D. K. Havey, G. E. Scace, D. Lisak, and J. T. Hodges Philosophical Transactions

(a) Measured spectrum (circles) and least-squares fit of the SDNGP (solid line) for transition 2 at x=2.22×10−4, p=13.3 kPa.

K. Bielska et al. Phil. Trans. R. Soc. A 2012;370:2509-2519

©2012 by The Royal Society

Page 4: Spectroscopic measurement of the vapour pressure of ice by K. Bielska, D. K. Havey, G. E. Scace, D. Lisak, and J. T. Hodges Philosophical Transactions

Temperature dependence of the fractional difference between our measured vapour pressure, ew,m, and the literature values, ew,lit, reported by Wexler [15] (circles) and Marti &

Mauersberger [4] (triangles).

K. Bielska et al. Phil. Trans. R. Soc. A 2012;370:2509-2519

©2012 by The Royal Society