site visit report · gas volumetric flow rate (actual) m³/hr 435081.1 22093 - gas volumetric flow...

Site Visit Report

The site visit process is a sample on a particular day of an installation's compliance with some of its licence conditions. Where non-compliance against a particular condition has not been reported, this should not be construed to mean that there is full compliance with that condition of the licence.

Instructions and actions arising from the visit shall be addressed, or where applicable noted, by the licensee in order to ensure compliance, to improve the environmental performance of the installation and to provide clarification on certain issues.

The licensee shall take the actions specified to close out the non-compliances and observations raised in this Site Visit Report.

Licensee

Name of Installation Irish Cement Limited (Limerick)

Licensee Irish Cement Limited

Licence Register No. P0029-06

CRO Number 9212

Site Address Castlemungret, Limerick

Site Visit Reference No. SV16248

Report Detail

Issue Date 29/10/2019

Prepared By David Matthews

Site Visit Detail

Date Of Inspection 03/09/2019 Announced No

Time In 09:30 Time Out 17:00

Visited by on behalf of the EPA Socotec

Licensee Personnel and Role See report.

Photo Taken No Samples Taken Yes Video Taken No

Odour Assessment No

Site Visit Report - SV16248 - Irish Cement Limited of 152

Scope

This is a technical report containing the results of monitoring of emissions to air.

Media

Air.

Site Areas Inspected

See report.

Documents Inspected

N/A


STACK EMISSIONS MONITORING REPORT

Page 1 of 148

© 2019 SOCOTEC UK Ltd Opinions and interpretations expressed herein are outside the scope of UKAS accreditation. MCERTS accredited results will only be claimed where both the sampling and analytical stages are UKAS accredited. This test report shall not be reproduced, except in full, without written approval of SOCOTEC UK Ltd.

Carried Out By: SOCOTEC 2-4 Langlands Place Kelvin South Business Park East Kilbride G75 0YF

Carried Out For: Office of Environmental Enforcement Environmental Protection Agency McCumiskey House Richview Dublin 14

Monitoring Dates: 03 - 05/09/2019 Report No: P0029-05-CAR19-01 / Version 2 Permit Reference: P0029-05 Report Date: 21/10/2019 Emission Points Monitored:

A2-01 Kiln 6/Rawmill A3-12 (Homosilo 1) A3-13 (Homosilo 2) A3-15 Kiln Feed Bin

Date

Site Operator: Irish Cement Limited Castlemungret Limerick Co Limerick



Page 2 of 148

SECTION A Emission Point A2-01 Kiln 6/Rawmill

Date

Site Operator: Irish Cement Limited Castlemungret Limerick Co Limerick


SOCOTEC Job Number:Report Date:Version: 2Report By: Cameron RussellMCERTS Number: MM 18 1481MCERTS Level: MCERTS Level 1 - TechnicianTechnical Endorsements: -

Report Approved By: David DrylieMCERTS Number: MM 04 493Business Title: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4

Signature:

2-4 Langlands PlaceKelvin South Business Park

East KilbrideG75 0YF

Tel: 01355 246 730Fax: 01355 249 669

Permit Reference:IE Licence: P0029-05

David HayBusiness Manager - North

Tel: 01355 246 730Email: [email protected]

Your contact at SOCOTEC LTD

Operator & Address:

CastlemungretLimerick

Irish Cement Limited

Co Limerick

Release Point: A2-01 (Kiln)

Sampling Date(s):3rd September 2019

18th October 2019P0029-05CAR19-01 (LEK 11825)


SOCOTEC UK Reporting Template v5 Page 3 of 148


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EXECUTIVE SUMMARY

Stack Emissions Monitoring Objectives

- Plant

- Operator

- Stack Emissions Monitoring Test House

Emissions Summary

Monitoring Times

Process Details

Monitoring Methods

Analytical Methods

- Sampling Methods with Subsequent Analysis

- On-Site Testing

Sampling Location

- Sampling Plane Validation Criteria

- Duct Characteristics

- Sampling Lines & Sample Points

- Sampling Platform

- Sampling Location / Platform Improvement Recommendations

Sampling and Analytical Method Deviations

APPENDICES

APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team

APPENDIX 2 - Summaries, Calculations, Raw Data and Charts

APPENDIX 3 - Measurement Uncertainty Budget Calculations

APPENDIX 4 - Record of Report Amendments

CONTENTS

Page 4 of 148

Irish Cement LimitedLimerickA2-01 (Kiln)

P0029-05CAR19-01 (LEK 11825) / Version 23rd September 2019

IE Licence: P0029-05Site Visit Report - SV16248 - Irish Cement Limited of 152

SOCOTEC UK LTD

www.socotec.co.uk

Plant

A2-01 (Kiln)

Operator


Castlemungret

Limerick

Co Limerick

IE Licence: P0029-05

Stack Emissions Monitoring Test House

SOCOTEC - East Kilbride Laboratory2-4 Langlands PlaceKelvin South Business ParkEast KilbrideG75 0YFUKAS and MCERTS Accreditation Number: 1015

Opinions and interpretations expressed herein are outside the scope of UKAS accreditation.MCERTS accredited results will only be claimed where both the sampling and analytical stages are UKAS accredited.This test report shall not be reproduced, except in full, without written approval of SOCOTEC LTD.This test report replaces and supersedes version 1 dated 2nd October 2019. Please see APPENDIX 4 for the changes made.

MONITORING OBJECTIVES

SOCOTEC LTD were commissioned by The Environmental Protection Agency to carry out stack emissions monitoring to determine the release ofprescribed pollutants from the following Plant under normal operating conditions.

Irish Cement Limited operates a kiln process at Limerick which is subject to IE Licence P0029-05, under the EPA Act 1992.

EXECUTIVE SUMMARY

The results of these tests shall be used to demonstrate compliance with a set of emission limit values for prescribed pollutants as specified in the Plant'sIE Licence, P0029-05.

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Parameter Units Result Calculated Uncertainty

+/-Total Particulate Matter mg/m³ 0.61 0.52 20Particulate Emission Rate g/hr 144.8 123.4 -

Dioxins & Furans (NATO I-TEQ) ng/m³ 0.0009 0.0002 0.1Dioxins & Furans (NATO I-TEQ) Emission Rate µg/hr 0.2207 0.0512 -

Dioxins & Furans (NATO I-TEQ) ng/m³ 0.0007 0.0002 -Dioxins & Furans (NATO I-TEQ) Emission Rate µg/hr 0.1831 0.0425 -Cadmium & Thallium mg/m³ 0.0019 0.003 0.05Cadmium & Thallium Emission Rate g/hr 0.467 0.725 -Heavy Metals mg/m³ 0.06 0.01 0.5Heavy Metals Emission Rate g/hr 15.85 2.82 -

mg/m³ 0.002 0.003 0.05g/hr 0.538 0.830 -

Mercury - Run 1 mg/m³ 0.001 0.001 0.05Mercury - Run 1 Emission Rate g/hr 0.226 0.348 -Mercury - Run 2 mg/m³ 0.003 0.005 0.05Mercury - Run 2 Emission Rate g/hr 0.850 1.311 -Hydrogen Chloride mg/m³ 0.43 0.04 10Hydrogen Chloride Emission Rate g/hr 101.73 10.58 -Hydrogen Fluoride mg/m³ 0.42 0.06 1Hydrogen Fluoride Emission Rate g/hr 106.20 16.25 -Sulphur Dioxide mg/m³ 7.48 0.77 400Sulphur Dioxide Emission Rate g/hr 1894.98 195.18 -Ammonia mg/m³ 11.22 1.36 50Ammonia Emission Rate g/hr 2843.04 344.01 -Total Volatile Organic Compounds mg/m³ 2.46 1.30 -Total Volatile Organic Compounds Emission Rate g/hr 622.59 330.59 -Oxides of Nitrogen (as NO2) mg/m³ 419.7 10.5 500Oxides of Nitrogen (as NO2) Emission Rate g/hr 106361.1 2669.4 -Carbon Monoxide mg/m³ 318.5 11.8 1500Carbon Monoxide Emission Rate g/hr 80732.8 2991.1 -Carbon Dioxide % v/v 16.85 0.11 - P

Oxygen % v/v 10.7 0.36 - P

Moisture % 9.10 0.29 - P

Stack Gas Temperature oC 112 - -Stack Gas Velocity m/s 21.1 0.49 -Gas Volumetric Flow Rate (Actual) m³/hr 435081.1 22093 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 298955.2 15180 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 270727.8 13747 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 253451.4 12870 335000

Dioxins & Furans - UPPER Limits

Dioxins & Furans - LOWER Limits

P

P

P

P

P

P

MCERTS accredited

result

P

P

P

P

ND = None Detected,Results at or below the limit of detection are highlighted by bold italic text.The above volumetric flow rate is calculated using data from the preliminary survey. Mass emissions for non isokinetic tests are calculated using these values. For all isokinetic testing the mass emission is calculated using test specific flow data and not the above values.

P

EXECUTIVE SUMMARY

EMISSIONS SUMMARY

Reference conditions are 273K, 101.3kPa, dry gas 10% Oxygen.

P

P

Mercury - Average of TestsMercury - Average of Tests Emission Rate

P

P

P

Emission Limit Value (ELV)

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Total Particulate Matter Run 1

Cadmium & Thallium Run 1Heavy Metals Run 1Mercury Run 1Mercury Run 2Hydrogen Chloride Run 1Hydrogen Fluoride Run 1Sulphur Dioxide Run 1Ammonia Run 1Total Volatile Organic Compounds Run 1Combustion Gases and O2 Day 1Oxygen Day 2 05 September 2019

04 September 2019 15:52 - 17:00

04 September 2019 09:35 - 10:05

Preliminary Stack Traverse08:30 - 09:00

13:35 - 14:35

04 September 2019

04 September 201930 minutes

08:00 - 08:23

30 minutes

-

09:35 - 10:05

09:50 - 10:54 60 minutes

60 minutes30 minutes09:40 - 10:10

04 September 2019

05 September 201909:16 - 10:22

60 minutes

05 September 2019 09:50 - 10:54

Sampling TimesSampling Date(s)Parameter

EXECUTIVE SUMMARY

Sampling Duration

60 minutes04 September 2019 360 minutes10:20 - 16:29Dioxins & Furans Run 1

MONITORING TIMES

05 September 2019 60 minutes

04 September 2019 15:52 - 17:00 60 minutes

15:52 - 17:00 60 minutes04 September 2019

30 minutes

60 minutes08:09 - 09:0904 September 201905 September 2019

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Description of process Kiln

Continuous or batch Continuous

Product Details Cement

Clinker Source Kiln 6 (On Site)

Normal load, throughput or continuous rating 150 Tonnes / Hour

Fuel used during monitoring PET Coke (11 Tonnes / Hour)

Abatement Bag Filter & SRCN

Plume Appearance Visible

PROCESS DETAILS

Parameter

EXECUTIVE SUMMARY

Process Details

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Species SOCOTEC UKAS Lab MCERTS Limit of Calculated CalculatedTechnical Number Accredited Detection MU MU

Total Particulate Matter

AE 104 1015 Yes 0.26 mg/m³ 85.2% 2.6%

Dioxins & Furans AE 109 1015 Yes 0.0003 ng/m³ 23.2% 0.2%

Cadmium & Thallium

AE 108 1015 Yes 0.00145 mg/m³ 155.2% 5.9%

Heavy Metals AE 108 1015 Yes 0.005 mg/m³ 17.8% 2.3%

Mercury AE 107/AE 108 1015 Yes 0.0007 mg/m³ 154.2% 6.7%

Hydrogen Chloride

AE 111 1015 Yes 0.0015 mg/m³ 10.4% 0.44%

Hydrogen Fluoride

AE 113 1015 Yes 0.009 mg/m³ 15.3% 6.41%

Sulphur Dioxide AE 112 1015 Yes 0.026 mg/m³ 10.3% 0.19%

Ammonia AE 115 1015 Yes 0.007 mg/m³ 12.1 % 2.7 %

Total Volatile Organic Compounds AE 102 1015 Yes 0.37 mg/m³ 53.1% N/A - No ELV

Oxides of Nitrogen

AE 102 1015 Yes 1.09 mg/m³ 2.5% 2.1%

Carbon Monoxide AE 102 1015 Yes 1.47 mg/m³ 3.7% 0.7%

Carbon Dioxide AE 102 1015 Yes 0.002 % 0.7% N/A - No ELV

Oxygen AE 102 1015 Yes 0.01% 3.4% N/A - No ELV

Moisture AE 105 1015 Yes 0.02% 3.24% N/A - No ELV

Velocity AE 154 1015 Yes 5 Pa 2.3% N/A - No ELV

Volumetric Flow Rate

AE 154 1015 Yes - 5.1% 3.84

SRM - EN 13284-1

SRM - EN 12619:2013

EXECUTIVE SUMMARY

SRM - EN 1911

SRM - EN 14385

Monitoring Methods

SRM - EN 1948 - Part 1

SRM - ISO 12039

SRM - EN 14385

The selection of standard reference / alternative methods employed by SOCOTEC is determined, wherever possible by the hierarchy of method selectionoutlined in Environmental Protection Agency Technical Guidance Note (Monitoring) AG2.

SRM - EN 14791

SRM - EN ISO 16911-1

Method

AM - EN 14789:2017

SRM - ISO 15713

SRM - EN 14792:2017

Standard Reference Method /

SRM - EN 15058:2017

SRM - EN 13211 / MID 14385

SRM - EN 14790

SRM - EN 14791


MONITORING METHODS

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AE 106 1015 YesSOCOTEC (East

Kilbride)N/A 8 Weeks

Dioxins and Furans

2002a 1668 Yes Marchwood 7357/58 8 Weeks

Cadmium & Thallium

ASC/SOP/117 1252 YesSOCOTEC (Bretby)

ASC/40940 8 Weeks

Heavy Metals ASC/SOP/117 1252 YesSOCOTEC (Bretby)

ASC/40940 8 Weeks

Mercury ASC/SOP/117 1252 YesSOCOTEC (Bretby)

ASC/40940 8 Weeks

Hydrogen Chloride


ASC/40941 8 Weeks

Hydrogen Fluoride


ASC/40941 8 Weeks

Sulphur Dioxide ASC/SOP/110 1252 YesSOCOTEC (Bretby)

ASC/40941 8 Weeks

Ammonia ASC/SOP/108 1252 YesSOCOTEC (Bretby)

ASC/40941 8 Weeks

Species Analytical UKAS Lab MCERTS Laboratory Data ArchiveProcedure Number Accredited Archive Period

Analysis LocationTotal Volatile Orangic

Compounds AE 102 1015 YesSOCOTEC (East

Kilbride)SOCOTEC (East

Kilbride)5 years

Oxides of Nitrogen



Kilbride)5 years

Carbon Monoxide AE 102 1015 YesSOCOTEC (East


Kilbride)5 years

Carbon Dioxide AE 102 1015 YesSOCOTEC (East


Kilbride)5 years

Oxygen AE 102 1015 YesSOCOTEC (East


Kilbride)5 years

Moisture AE 105 1015 YesSOCOTEC (East

Kilbride)- -

Inductively coupled Plasma - Mass Spectrometry

EXECUTIVE SUMMARY

Analytical Technique

Analytical Methods


Chemiluminescence

Gravimetric

Ion Chromatography


Ion Chromatography

Ion Chromatography

Gas Chromatography - High Resolution Mass Spectometry

Ion Chromatography

Non Dispersive Infra Red

Flame Ionisation Detection

Gravimetric

The following tables list the analytical methods employed together with the custody details. Unless otherwise stated the samples are archived at the analysis lab location.

Analysis LabArchivePeriod

UKAS Lab Number

Analytical Procedure

Analytical TechniqueSpecies

Non Dispersive Infra Red

SAMPLING METHODS WITH SUBSEQUENT ANALYSISUKAS Accredited

Lab Analysis

Zirconia Cell

Analysis Report number

ON-SITE TESTING

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Sampling Plane Validation Criteria Value Units Requirement Compliant Method

Lowest Differential Pressure 235 Pa >= 5 Pa Yes EN 15259

Lowest Gas Velocity 20.3 m/s - - -

Highest Gas Velocity 21.6 m/s - - -

Ratio of Gas Velocities 1.1 : 1 < 3 : 1 Yes EN 15259

Mean Velocity 21.1 m/s - - -

Maximum angle of flow with regard to duct axis <15 o < 15o Yes EN 15259

No local negative flow Yes - - Yes EN 15259

Value Units IsokineticShape Circular -

Depth 2.70 m Sample port size 4" BSP 4" BSP

Width - m Number of lines used 2 1

Area 5.73 m2 Number of points / line 10 1

Port Depth 100 mm Duct orientation Vertical VerticalFiltration - In Stack

In Stack -

General Platform Information

Permanent / Temporary Platform / Ground level / Floor Level / Roof

Inside / Outside

AG1 Platform requirements

Is there a sufficient working area so work can be performed in a compliant manner

Platform has 2 levels of handrails (approximately 0.5 m & 1.0 m high)

Platform has vertical base boards (approximately 0.25 m high)

Platform has removable chains / self closing gates at the top of ladders

Handrail / obstructions do not hamper insertion of sampling equipmentDepth of Platform = >Stack depth / diameter + wall and port thickness + 1.5m

Sampling Platform Improvement Recommendations (if applicable)

SAMPLING PLATFORM

Non-Iso & Gases

No

DUCT CHARACTERISTICS

EXECUTIVE SUMMARY

Permanent

It is recommended that the platform is extended behind the sample ports to allow clearance for the probe to be inserted into the stack and that all pointsacross the stack are available to be sampled at as in accordance with EN 13284-1 & EA Guidance Note AG1.

SAMPLING LOCATION

Yes

Filtration for TPM

No

SAMPLING LINES & POINTS

Yes

N/A

Outside

No

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Sample Points

Nozzle Diameter

Sampling & Analytical Method Deviations

EXECUTIVE SUMMARY

The diameter of the nozzle used for the isokinetic sampling was below the recommended minimum stated in the standard in order to ensure isokineticconditions could be achieved throughout the test.

Due to the restrictive access to the sample ports, sample points 1 - 3 on each line are not accessible.

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CONTENTS

APPENDICES

Page 13 of 148




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SOCOTEC UKAS Lab MCERTSTechnical Number Accredited

AE 104 1015 Yes 1AE 109 1015 Yes 1AE 108 1015 Yes 1AE 108 1015 Yes 1

AE 107/AE 108 1015 Yes 2AE 111 1015 Yes 1AE 113 1015 Yes 1AE 112 1015 Yes 1AE 115 1015 Yes 1AE 102 1015 Yes 1AE 102 1015 Yes 1AE 102 1015 Yes 1AE 102 1015 Yes 1AE 102 1015 Yes 1AE 105 1015 Yes 2AE 154 1015 Yes 1

OxygenMoistureVelocity

Species

MONITORING SCHEDULE

Total Particulate MatterDioxins & FuransCadmium & ThalliumHeavy MetalsMercury

AM - EN 14789:2017

SRM - EN 13284-1

SRM - ISO 12039

SRM - EN 1911

SRM - EN 15058:2017

SRM - EN 14385

SRM - EN 14791

SRM - EN 12619:2013

SRM - EN ISO 16911-1SRM - EN 14790

Oxides of Nitrogen

Standard Reference Method /

SRM - EN 14385

Number of Samples

Carbon MonoxideCarbon Dioxide

SRM - ISO 15713

SRM - EN 14791Total Volatile Organic Compounds

SRM - EN 13211 / MID 14385


SRM - EN 1948 - Part 1

Hydrogen ChlorideHydrogen FluorideSulphur DioxideAmmonia

SRM - EN 14792:2017

Method

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Equipment I.D. Equipment I.D. Equipment I.D.

LEK 9.28 / 9.41 LEK 12.7 LEK 15.21

LEK 9.25 / 9.42 - LEK 20.31

LEK 9.25 / 9.42 - LEK 17.1

LEK 9.25 / 9.42 - -

LEK 17.11 / 17.23 - LEK 16.12

LEK 13.23 - LEK 1.14

LEK 6.43 - LEK LNO 03-CD

LEK 3.114 LEK 8.11 LEK 3.138

LEK 6.29 - -

LEK 3.145 - -

LEK 6.17 - LEK 8.36

- - -

LEK 23.18 LEK 12.20 -

LEK 3.212 LEK 8.26 -

LEK 3.209 LEK 8.36 -

LEK 15.1G - -

- - -

- - LEK 8.26

LEK 24.7 - -

NOTE: If the equipment I.D is represented by a dash (-), then this piece of equipment has not been used for this test.

Cylinder I.D Number

Supplier ppm %Analytical

Tolerance +/- %

Oxygen LEK 175 BOC - 11 2.0

Propane LEK 183 BOC 12.35 - 2.0

Nitric Oxide LEK 197 BOC 384.8 - 2.0

Carbon Monoxide LEK 194 BOC 764.3 - 2.0

Carbon Dioxide 16644 BOC - 16 2.0- - - - -

Level Expiry TE1 TE2 TE3 TE4 H&S

Andrew O'Neill MM 08 985MCERTS Level

2Mar 20 Sep 20 Mar 22 Mar 20 Sep 20 Oct 23

Callum Montgomery

MM 16 1399MCERTS Level

1Nov 22 Mar 24 - - - Nov 22

10m Heated Line (2)

15m Heated Line (1)

20m Heated Line (1)

Gas (traceable to ISO 17025)

Barometer

Equipment

Ecophysics NOx Analyser

Heater Controller

Last Impinger Arm

S-Pitot

FT-IR Gasmet

Meter In Thermocouple Stopwatch

MCERTS Number

TE / H&S Qualifications and Expiry DateMCERTS

Probe

Probe Thermocouple

Stackmaster

Meter Out Thermocouple

Control Box Timer

Stack Thermocouple

1m Heated Line (1)

L-Pitot

Oven Box

Probe JCT Heated Head Filter

Digital Micromanometer

Bernath 3006 FID Protractor

FT-IR Oven Box

Signal 3030 FID

-

Personnel

FTIR Heater Box for Heated Line

1m Heated Line (3)

Callipers

20m Heated Line (2)

Anemometer

Dioxins Cond. Thermocouple 10m Heated Line (1)

MONITORING TEAM

Heated Line Controller (2)

Instrumental Analyser/s


CALIBRATEABLE EQUIPMENT CHECKLISTMiscellaneous

Control Box DGM Laboratory Balance

Equipment

Horiba PG-250 Analyser

1m Heated Line (2)

Mass Flow Controller

Thermo FID

Digital Temperature Meter

Servomex

Probe Thermocouple

MFC Display module

Box Thermocouples Tape Measure

Extractive Sampling

Equipment

Chiller (JCT/MAK 10)Site Balance

5m Heated Line (1)

Small DGM


Site temperature Logger

Inclinometer (Swirl Device)

STACK EMISSIONS MONITORING TEAM

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Uncertainty ELV Emissionmg/m³ mg/m³ Rate g/hr

0.52 20 144.8

Blank - - -


TestFilter & Probe Rinse Number

Filter Start Weight

Filter End Weight

Mass Gained on Filter

Probe Rinse Start Weight

Probe Rinse End Weight

Mass Gained on Probe

Combined Total Mass Gained

g g g g g g gRun 1 AC 10429 0.09496 0.09513 0.00017 148.11830 148.11860 0.00030 0.00047If total mass gained is less than the LOD then the LOD is reported

TestFilter & Probe

NumberFilter Start

WeightFilter End

WeightMass Gained

FilterProbe Start

WeightProbe End

WeightMass Gained

ProbeCombined Total

Mass Gained

g g g g g g gRun 1 AC 0175 0.09638 0.09633 -0.00005 202.86930 202.86930 0.00000 0.00020If total mass gained is less than the LOD then the LOD is reported

-

Acetone Blank Value


Run 1

Concentration

0.23

mg/m³Sampling Times

2.0 10

FILTER INFORMATION

09:50 - 10:5405 September 2019

0.61

TOTAL PARTICULATE MATTER SUMMARYParameter

mg/lAcceptable Value

mg/l

BLANKS

SAMPLES

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ISOKINETIC SAMPLING EQUATIONS - RUN 1 TPM

Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md

Barometric pressure, Pb Kpa 100.9 CO2 % 16.85Stack static pressure, Pstatic pa -231 O2 % 11.27Ps = Pb + Pstatic Kpa 100.7 Total % 28.12

N2 (100 -Total) % 71.88Vol. of water vapour collected, Vwstd Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 31.15

g - Molecular weight of wet gas, Ms

Vwstd = (0.001246)(Vlc) m3 - Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 29.95Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa

Volume of gas sample through gas meter, Vm m3 1.049 Area of stack, As m2 5.73

Gas meter correction factor, Yd 0.916 Qa = (60)(As)(Vs) m³/min 7134.4Mean dry gas meter temperature, Tm K 301 Total flow of stack gas, QMean pressure drop across orifice, DH mmH2O 34.125 Conversion factor (K/mm.Hg) 0.3592Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 0.872 Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 4478.4

(Ts)Volume of gas metered wet, Vmstw @O2ref 3963.09Vmstw = Vmstd + Vwstd m3 0.9594 (Ts)

Qstw = (Qa)Ps(0.3592) Wet 4926.49 (Ts)

No Percent isokinetic, %INozzle diameter, Dn mm 4.90

% oxygen measured in gas stream, act%O2 11.27 Nozzle area, An mm2 18.83% oxygen reference condition 10 Total sampling time, q min 60

0.88 %I = (4.6398E6)(Ts)(Vmstd) % 98.7 (Ps)(Vs)(An)(q)(1-Bwo)

Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 0.7718 Acceptable isokinetic range 95% to 115% YesMoisture content, Bwo Particulate Concentration, CBwo = Vwstd 0.0910 Mass collected on filter, Mf g 0.00017

% 9.10 Mass collected in probe, Mp g 0.00030Moisture by FTIR % - Total mass collected, Mn g 0.00047Velocity of stack gas, Vs Cwet = Mn mg/m³ 0.490Velocity pressure coefficient, Cp 0.86 Vmstw

Mean of velocity heads, DPavg Pa 267.30 Cdry = Mn mg/m³ 0.539Mean stack gas temperature, Ts K 393 Vmstd

Gas density (wet, ambient), p Cdry@X%O2 = Mn mg/m³ 0.609p=(Ms*Ps)/(8.314*Ts) kg/m3 0.923Stack Velocity, Vs Particulate Emission Rates, E

m/s 20.76 E = [(Cwet)(Qstw)(60)] / 1000 144.80

Vmstd@X%oxygen

QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)


Is the process burning hazardous waste? (If yes, no favourable oxygen correction)

O2 Reference Factor

Moisture trap weight increase,Vlc

Tm

Vmstd + Vwstd

O2 Ref = 21.0 - act%O2

21.0 - ref%O2

Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2

𝑉𝑠 = 𝐶𝑝∆𝐷𝑃𝑎𝑣𝑔

𝑝

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litre/min litre/min litre/min mm Hg litre/minRun 1 16.02 0.05 0.07 -228.6 0.32 Yes

% mg/m³ mg/m³Run 1 98.68 Yes Run 1 0.26 1.0 Yes

Acceptable isokinetic range 95% to 115% The above is based on both the Filter and rinse uncertainty

mg/m3 mg/m3 mg/m3 mg/m3

mm °CRun 1 Glass Fibre 47 121 180

Maximum Vacuum

Acceptable Blank Value

Yes

5% ELV

160

20

Pre-use Filter Conditioning Temperature

Max Filtration Temperature

°C

BLANK VALUE

0.23

WEIGHING BALANCE UNCERTAINTYISOKINETICITYAcceptable Isokineticity

Filter SizeFilter MaterialRun Post-use Filter Conditioning Temperature


2.0

Acceptable Leak Rate

Blank 1

Leak Tests Acceptable?

Run

Run

LEAK RATEPost-sampling

Leak Rate

°C

Result

FILTERS

Daily Emission Limit Value

Isokinetic Variation

LOD < 5% ELV

Overall Blank Value

Run

Overall Blank AcceptableRun

Pre-sampling Leak Rate

Mean Sampling Rate

TOTAL PARTICULATE MATTER QUALITY ASSURANCE CHECKLIST

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LOD ELV Emissionng/m³ ng/m³ Rate µg/hr

Run 1 0.0003 0.1 0.22

Field Blanks Run 1 0.0001 - -


Run 1 0.0004 - 0.24



Run 1 0.0004 - 0.23



Run 1 0.0005 - 0.41



08:45 - 08:46 04 September 2019

0.0009

10:20 - 16:29 04 September 2019

WHO TEQ (Humans / Mammals)

10:20 - 16:29 04 September 2019

WHO TEQ (Birds)

ng/m³

08:45 - 08:46 04 September 2019

Concentration

0.0009

ng/m³

10:20 - 16:29 04 September 2019

Test Concentration

ConcentrationTest

DIOXINS & FURANS SUMMARY - UPPER LIMIT

ng/m³

0.0001

0.0001

Test


Sampling Times NATO I-TEQ

ng/m³

Sampling Times Concentration

0.0016

0.0001

WHO TEQ (Fish)

0.0009

Sampling Times

Test

10:20 - 16:29 04 September 2019

08:45 - 08:46 04 September 2019

Sampling Times

0.000108:45 - 08:46

04 September 2019

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Run 1 - 0.1 0.18

Field Blanks Run 1 - - -


Run 1 - - 0.20



Run 1 - - 0.19



Run 1 - - 0.37



08:45 - 08:46 04 September 2019

Sampling Times

WHO TEQ (Humans / Mammals)

Sampling Times NATO I-TEQ

Concentration

Sampling Times

08:45 - 08:46 04 September 2019

08:45 - 08:46 04 September 2019

0.0007

DIOXINS & FURANS SUMMARY - LOWER LIMIT

10:20 - 16:29 04 September 2019

Sampling Times

0.000003

ConcentrationWHO TEQ (Birds)

ng/m³10:20 - 16:29

04 September 2019

ng/m³


Test

0.000002

Test

Concentration

10:20 - 16:29 04 September 2019

ng/m³

ng/m³

08:45 - 08:46 04 September 2019

0.000810:20 - 16:29

04 September 2019

0.0007

Test

0.000003

Concentration

0.000002

0.0014

WHO TEQ (Fish)

Test

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Congener Result NATO WHOI-TEQ TEQ Actual Permitted Actual Permitted

ng ng ng % % % %Dioxins2378 Tetra CDD < 0.0007 0.0007 0.0007 79 50% - 130%12378 Penta CDD 0.0014 0.0007 0.0014 69 50% - 130%123478 Hexa CDD 0.0014 0.0001 0.0001 84 50% - 130%123678 Hexa CDD 0.006 0.0006 0.0006 87 50% - 130%123789 Hexa CDD 0.003 0.0003 0.0003 -1234678 Hepta CDD 0.0164 0.0002 0.0002 77 40% - 130%OCDD Octa CDD 0.0136 0.00001 0.000004 67 40% - 130%Total -Dioxins 0.0425 0.0026 0.0033Furans2378 Tetra CDF 0.0037 0.0004 0.0004 66 50% - 130%12378 Penta CDF 0.0015 0.0001 0.00005 - 105 >=5023478 Penta CDF 0.0015 0.0008 0.0005 67 50% - 130%123478 Hexa CDF 0.0009 0.0001 0.0001 78 50% - 130%123678 Hexa CDF 0.0014 0.0001 0.0001 83 50% - 130%234678 Hexa CDF 0.0018 0.0002 0.0002 82 50% - 130%123789 Hexa CDF < 0.0003 0.00003 0.00003 - 103 >=501234678 Hepta CDF 0.0035 0.00004 0.00004 71 40% - 130%1234789 Hepta CDF < 0.0001 0.000001 0.000001 - 92 >=50OCDF Octa CDF 0.0028 0.000003 0.000001 61 40% - 130%Total -Furans 0.0175 0.0017 0.0013Mean Recoveries (%) 75 100Total Isomers 0.06 0.0043 0.0046Total ITEQ (<LOD = 0) 0.0036 0.0039

NOTE: The Total Isomers result includes all isomers below the limit of detection. This gives a "worst case" Dioxins & Furans result.

Sampling RecoveryNATO I-TEQ & WHO TEQ (Humans / Mammals)

Extraction Recovery

DIOXINS & FURANS ANALYSIS SUMMARY - RUN 1


Humans / Mammals

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Congener Result WHO WHOTEQ TEQ Actual Permitted Actual PermittedFish Birds

ng ng ng % % % %Dioxins2378 Tetra CDD < 0.0007 0.0007 0.0007 79 50% - 130%12378 Penta CDD 0.0014 0.0014 0.0014 69 50% - 130%123478 Hexa CDD 0.0014 0.0007 0.0001 84 50% - 130%123678 Hexa CDD 0.006 0.0001 0.0001 87 50% - 130%123789 Hexa CDD 0.003 0.00003 0.00003 -1234678 Hepta CDD 0.0164 0.00002 0.00002 77 40% - 130%OCDD Octa CDD 0.0136 - - 67 40% - 130%Total -Dioxins 0.0425 0.0029 0.0023Furans2378 Tetra CDF 0.0037 0.0002 0.0037 66 50% - 130%12378 Penta CDF 0.0015 0.0001 0.00002 - 105 >=5023478 Penta CDF 0.0015 0.0008 0.0015 67 50% - 130%123478 Hexa CDF 0.0009 0.0001 0.0001 78 50% - 130%123678 Hexa CDF 0.0014 0.0001 0.0001 83 50% - 130%234678 Hexa CDF 0.0018 0.0002 0.0002 82 50% - 130%123789 Hexa CDF < 0.0003 0.00003 0.00003 - 103 >=501234678 Hepta CDF 0.0035 0.00004 0.00004 71 40% - 130%1234789 Hepta CDF < 0.0001 0.000001 0.000001 - 92 >=50OCDF Octa CDF 0.0028 0.0000003 0.0000003 61 40% - 130%Total -Furans 0.0175 0.0015 0.0057Mean Recoveries (%) 75 100Total Isomers 0.06 0.0044 0.0080Total ITEQ (<LOD = 0) 0.0037 0.0072


Sampling RecoveryWHO TEQ (Fish) & WHO TEQ (Birds)

Extraction Recovery

DIOXINS & FURANS ANALYSIS SUMMARY - RUN 1


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Congener Result NATO WHOI-TEQ TEQ Actual Permitted Actual Permitted

ng ng ng % % % %Dioxins2378 Tetra CDD < 0.0001 0.0001 0.0001 75 50% - 130%12378 Penta CDD < 0.0002 0.0001 0.0002 77 50% - 130%123478 Hexa CDD < 0.0003 0.00003 0.00003 92 50% - 130%123678 Hexa CDD < 0.0003 0.00003 0.00003 88 50% - 130%123789 Hexa CDD < 0.0003 0.00003 0.00003 -1234678 Hepta CDD < 0.0002 0.000002 0.000002 85 40% - 130%OCDD Octa CDD 0.0035 0.000004 0.000001 77 40% - 130%Total -Dioxins 0.0049 0.0003 0.0004Furans2378 Tetra CDF < 0.0002 0.00002 0.00002 73 50% - 130%12378 Penta CDF < 0.0001 0.00001 0.000003 - 101 >=5023478 Penta CDF < 0.0001 0.0001 0.00003 75 50% - 130%123478 Hexa CDF < 0.0002 0.00002 0.00002 77 50% - 130%123678 Hexa CDF < 0.0002 0.00002 0.00002 80 50% - 130%234678 Hexa CDF < 0.0002 0.00002 0.00002 84 50% - 130%123789 Hexa CDF < 0.0002 0.00002 0.00002 - 103 >=501234678 Hepta CDF 0.0011 0.00001 0.00001 76 40% - 130%1234789 Hepta CDF < 0.0001 0.000001 0.000001 - 96 >=50OCDF Octa CDF 0.0015 0.000002 0.0000005 72 40% - 130%Total -Furans 0.0039 0.0002 0.0001Mean Recoveries (%) 79 100Total Isomers 0.0088 0.0005 0.0005Total ITEQ (<LOD = 0) 0.00002 0.00001


NATO I-TEQ & WHO TEQ (Humans / Mammals)Extraction Recovery Sampling Recovery


Humans / Mammals

DIOXINS & FURANS ANALYSIS SUMMARY - FIELD BLANK RUN 1

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Congener Result WHO WHOTEQ TEQ Actual Permitted Actual PermittedFish Birds

ng ng ng % % % %Dioxins2378 Tetra CDD < 0.0001 0.0001 0.0001 75 50% - 130%12378 Penta CDD < 0.0002 0.0002 0.0002 77 50% - 130%123478 Hexa CDD < 0.0003 0.0002 0.00002 92 50% - 130%123678 Hexa CDD < 0.0003 0.000003 0.000003 88 50% - 130%123789 Hexa CDD < 0.0003 0.000003 0.000003 -1234678 Hepta CDD < 0.0002 0.0000002 0.0000002 85 40% - 130%OCDD Octa CDD 0.0035 - - 77 40% - 130%Total -Dioxins 0.0049 0.0005 0.0003Furans2378 Tetra CDF < 0.0002 0.00001 0.0002 73 50% - 130%12378 Penta CDF < 0.0001 0.00001 0.000001 - 101 >=5023478 Penta CDF < 0.0001 0.0001 0.0001 75 50% - 130%123478 Hexa CDF < 0.0002 0.00002 0.00002 77 50% - 130%123678 Hexa CDF < 0.0002 0.00002 0.00002 80 50% - 130%234678 Hexa CDF < 0.0002 0.00002 0.00002 84 50% - 130%123789 Hexa CDF < 0.0002 0.00002 0.00002 - 103 >=501234678 Hepta CDF 0.0011 0.00001 0.00001 76 40% - 130%1234789 Hepta CDF < 0.0001 0.000001 0.000001 - 96 >=50OCDF Octa CDF 0.0015 0.0000002 0.0000002 72 40% - 130%Total -Furans 0.0039 0.0002 0.0004Mean Recoveries (%) 79 100Total Isomers 0.0088 0.0006 0.0007Total ITEQ (<LOD = 0) 0.00001 0.00001


WHO TEQ (Fish) & WHO TEQ (Birds)

DIOXINS & FURANS ANALYSIS SUMMARY - FIELD BLANK RUN 1


Sampling RecoveryExtraction Recovery

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ISOKINETIC SAMPLING EQUATIONS - RUN 1 Dioxins & Furans


Barometric pressure, Pb kPa 98.50 CO2 % 16.85Stack static pressure, Pstatic Pa -238.00 O2 % 10.70Ps = Pb + (Pstatic) kPa 98.26 Total % 27.55

N2 (100 -Total) % 72.45Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 31.12

Vol. of water vapour collected, Vwstd Molecular weight of wet gas, Ms

g H₂0 by Non Iso Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 29.93Vwstd = (0.001246)(Vlc) m3 - Velocity of stack gas, Vs

Volume of gas metered dry, Vmstd Velocity pressure coefficient, Cp 0.895Mean of velocity heads, DPavg Pa 264.23

Volume of gas sample through gas meter, Vm m3 6.45 Mean stack gas temperature, Ts K 391.75

Gas meter correction factor, Yd 0.92 Gas density (wet, ambient), pMean dry gas meter temperature, Tm K 294.85 p=(Ms*Ps)/(8.314*Ts) kg/m3 0.903Mean pressure drop across orifice, DH mmH2O 30.43 Stack Velocity, Vs

m/s 21.65Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 5.33 Actual flow of stack gas, Qa

Area of stack, As m2 5.73Volume of gas metered wet, Vmstw Qa = (60)(As)(Vs) m³/min 7439.0

Total flow of stack gas, QVmstw = Vmstd + Vwstd m3 5.8660 Conversion factor (K/mm.Hg)

Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 4569.6 (Ts)

No @O2ref 4278 (Ts)

% oxygen measured in gas stream, act%O2 10.70 Qstw = (Qa)Ps(0.3592) Wet 5027% oxygen reference condition 10 (Ts)

O2 Ref = 21.0 - act%O2 0.94 Percent isokinetic, %I 21.0 - ref%O2 Nozzle diameter, Dn mm 4.7

Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 4.99 Nozzle area, An mm2 17.7Moisture content, Bwo Total sampling time, q min 360.0

%I = (4.6398E6)(Ts)(Vmstd) % 105.0Bwo = Vwstd 0.0910 (Ps)(Vs)(An)(q)(1-Bwo)

% 9.10Moisture by FTIR % - Acceptable isokinetic range 95% to 115% Yes

Tm + 273



Vmstd + Vwstd

O2 Reference Factor





𝑝

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litre/min litre/min litre/min mm Hg litre/min litre/min

16.41 0.07 0.08 -279.4 Yes 0.82

mm °C

Glass Fibre 47 124

Critical Sampling Requirement

Run 1 Yes

-

.

%

105.0 Yes

Isokinetic Variation Acceptable Isokineticity%

Run 1

16

< 20°C < 25°CAcceptance Criteria

Temperature during storage / transit <25°C

°C

DIOXINS & FURANS QUALITY ASSURANCE CHECKLIST


Maximum Vacuum

Yes



Leak Tests Acceptable

Maximum Filtration

Temperature

Acceptable isokinetic range 95% to 115%

Maximum Temperature at Condenser / Adsorber

Acceptable Temperature?

Post-sampling Leak Rate

Run 1

Mean Sampling Rate

Leak Test Results

Filter MaterialFiltration

Run 1

Isokinetic Criterion Compliance

Filter Size

Page 26 of 148




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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr

0.0015 0.05 0.47

- - -


0.0047 0.5 15.85

- - -


Metals LOD Concentration Emission Uncertainty UKASmg/m³ mg/m³ Rate g/hr % Accredited

0.00067 0.00108 0.266 119% P

0.00080 0.00083 0.204 186% P

0.00145 0.00191 0.470 155.2% -

LOD Concentration Emission Uncertainty UKASmg/m³ mg/m³ Rate g/hr % Accredited

0.00054 0.00057 0.140 180% P

0.00054 0.00274 0.676 39% P

0.00044 0.03550 8.745 21% P

0.00028 0.00031 0.076 167% P

0.00067 0.00174 0.430 76% P

0.00067 0.00106 0.261 121% P

0.00057 0.01536 3.784 14% P

0.00057 0.00694 1.710 22% P

- - - - -0.00041 0.00050 0.124 153% P

- - - - -

0.00470 0.06472 15.944 17.8% -


Chromium

Sum of Heavy Metals (Excluding Cd / Tl)

Copper

-

-

Lead

Field Blank

15:52 - 17:00 04 September 2019

0.0015

mg/m³

14:50 - 14:51 04 September 2019

Antimony

0.007114:50 - 14:51

04 September 2019

CadmiumThallium

Manganese

Run 1

Sampling Times


Field Blank

Concentration

HEAVY METALS SOLID & VAPOUR PHASES COMBINED

Cadmium & Thallium

Arsenic

Testmg/m³

Vanadium

0.0647

0.0019

Metals

INDIVIDUAL METALS SUMMARY - SOLID & VAPOUR PHASES COMBINED

Sampling Times Test

Nickel

TOTAL HEAVY METALS COMBINED

15:52 - 17:00 04 September 2019

Run 1

Concentration

Cobalt

CADMIUM & THALLIUM COMBINED

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MetalsStack LOD Concentration Stack LOD Concentration

mg/m³ mg/m³ug mg/m³ ug mg/m³

0.00065 0.50 0.00065 0.00002 0.33 0.000430.00078 0.60 0.00078 0.00002 0.04 0.000050.00143 1.10 0.00143 0.00002 0.37 0.00048

Volume Sampled m3


Stack LOD Concentration Stack LOD Concentrationmg/m³ mg/m³

ug mg/m³ ug mg/m³0.00052 0.40 0.00052 0.00002 0.03600 0.000050.00052 0.40 0.00052 0.00002 1.71000 0.002220.00039 4.40 0.00572 0.00005 22.89600 0.029780.00026 0.20 0.00026 0.00002 0.03600 0.000050.00065 0.60 0.00078 0.00002 0.74160 0.000960.00065 0.50 0.00065 0.00002 0.31320 0.000410.00052 11.00 0.01431 0.00005 0.81000 0.001050.00052 4.70 0.00611 0.00005 0.63720 0.00083

- - - - - -0.00039 0.30 0.00039 0.00002 0.08640 0.00011

- - - - - -

0.00442 22.50 0.02926 0.00028 27.26640 0.03546

Volume Sampled m3



AntimonyChromium

Cadmium & ThalliumThallium

VAPOUR PHASE

0.7690

Arsenic

-

PARTICULATE PHASE

0.7690

Nickel

Laboratory Result

Cobalt

-

ManganeseLead

Laboratory Result

Copper

Laboratory Result

VAPOUR PHASE

HEAVY METALS - RUN 1 SUMMARY

Metals

PARTICULATE PHASE

Vanadium

0.76900.7690

Cadmium


Laboratory Result

Page 28 of 148




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MetalsStack LOD Concentration Stack LOD Concentration

mg/m³ mg/m³ug mg/m³ ug mg/m³

0.00065 0.50 0.00065 0.00002 0.05 0.000070.00065 0.60 0.00078 0.00002 0.03 0.000030.00130 1.10 0.00143 0.00002 0.08 0.00010

Volume Sampled m3


Stack LOD Concentration Stack LOD Concentrationmg/m³ mg/m³

ug mg/m³ ug mg/m³0.00052 0.40 0.00052 0.00002 0.03 0.000030.00052 0.40 0.00052 0.00002 0.05 0.000070.00039 0.60 0.00078 0.00005 0.53 0.000680.00026 0.20 0.00026 0.00002 0.03 0.000030.00065 0.50 0.00065 0.00002 0.16 0.000210.00065 0.50 0.00065 0.00002 0.13 0.000170.00052 0.40 0.00052 0.00005 0.13 0.000170.00052 1.00 0.00130 0.00005 0.08 0.00010

- - - - - -0.00039 0.30 0.00039 0.00002 0.03 0.00003

- - - - - -

0.00442 4.30 0.00559 0.00028 1.16 0.00150

Volume Sampled m3


Cadmium & Thallium

Cadmium

Copper

Chromium

Manganese

PARTICULATE PHASE

VAPOUR PHASE

VAPOUR PHASE

Laboratory Result

Cobalt

0.7690

-

0.7690

Metals

Lead

0.7690

HEAVY METALS - BLANK SUMMARY

Laboratory Result


Antimony

PARTICULATE PHASE


Nickel

0.7690

Arsenic

Thallium

Laboratory Result

Laboratory Result

Vanadium-

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0.001 0.05 0.226

0.001 0.05 0.850

- - -

Stack LOD Lab Result Concentration Stack LOD Lab Result Concentrationmean ug mg/m³ mean ug mg/m³

mg/m³ mg/m³

Run 1 0.00065 0.50 0.00065 0.00002 0.21 0.000

Run 2 0.0006 0.50 0.0006 0.00002 2.21 0.003

Field Blank - 0.50 0.00064 - 0.10 0.0001


0.001

0.7690

0.7690

mg/m³

0.001

Field Blank

Volume Sampled m3

09:16 - 10:22 05 September 2019

Run 2

0.7690

0.7895

ConcentrationSampling Times

0.79

Mercury

Run 1

Volume Sampled m3

Volume Sampled m3

MERCURY SUMMARY - PARTICULATE & VAPOUR PHASES COMBINED

0.7792


Test

PARTICULATE PHASE

0.003

VAPOUR PHASE

15:52 - 17:00 04 September 2019

14:50 - 14:51 04 September 2019

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ISOKINETIC SAMPLING EQUATIONS RUN 1 Cd, Tl, Heavy Metals & Mercury



N2 (100 -Total) % 72.45Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 31.12










No @O2ref 4082 (Ts)








Tm + 273


Vmstd + Vwstd


O2 Reference Factor



𝑝

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ISOKINETIC SAMPLING EQUATIONS RUN 2 Mercury



N2 (100 -Total) % 71.88Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 31.15










No @O2ref 4130 (Ts)







Vmstd + Vwstd



Tm + 273



O2 Reference Factor


𝑝

Page 32 of 148




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litre/min litre/min litre/min mm Hg litre/min litre/min15.5 0.07 0.07 -304.8 0.31 Yes16.3 0.05 0.05 -279.4 0.33 Yes

Isokinetic Criterion Compliance

mm °CQuartz Fibre 47 180 YesQuartz Fibre 47 180 Yes

Glass

95.5Yes

Run 2

Mean Sampling Rate

Glass



Run 1 3.3% Nitric Acid, 1.5% Hydrogen Peroxide

Absorption Solutions - Mercury

Filter Size

Type of Absorbers - Metals

Run 1

Mercury

Run 1

%

Filtration / Temp

Type of Absorbers - Mercury

HEAVY METALS QA CHECKLIST

Filter Material


Leak Tests Acceptable

Maximum Vacuum

Metals

Post-sampling Leak Rate

Run 2

Acceptable Isokineticity

Run 2Run 1

103.2Run 1 Yes

Absorption Solutions - Metals

Leak Test Results

4% Potassium Dichromate, 20% Nitric Acid


4% Potassium Dichromate, 20% Nitric Acid

Temperature during storage /

transit <25°C

Run 2

Glass

Maximum Filtration

Temperature

Page 33 of 148




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Parameter Total 3rd Absorber Absorption Required Pass / Failug ug Efficiency (%) %

Cadmium Run 1 0.83120 0.13 84 90 N/A <30% ELVThallium Run 1 1.46720 ND 100 90 N/A <30% ELVArsenic Run 1 0.43600 ND 100 90 N/A <30% ELVAntimony Run 1 2.11000 0.10 95 90 N/A <30% ELVChromium Run 1 27.29600 0.22 99 90 N/A <30% ELVCobalt Run 1 0.23600 ND 100 90 N/A <30% ELVCopper Run 1 1.34160 0.09 94 90 N/A <30% ELVLead Run 1 0.81320 0.09 89 90 N/A <30% ELVManganese Run 1 11.81000 0.05 100 90 N/A <30% ELVNickel Run 1 5.33720 0.03 99 90 N/A <30% ELV- - - - - - -Vanadium Run 1 0.38640 ND 100 90 N/A <30% ELV- - - - - - -

Parameter Total 5th Absorber Absorption Required Pass / Failug ug Efficiency

Mercury Run 1 0.71 0.02 97 95 N/A <30% ELVRun 2 2.71 0.00 100 95 N/A <30% ELV

HEAVY METALS ABSORBTION EFFICIENCY


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0.002 10 101.73

Field Blank - - -


Leak Test Results

m³ l/min l/min l/min l/min

Run 1 0.7718 16.0 0.05 0.07 0.32 Yes

Filter Material Filter Sizemm

°C

Run 1 Glass Fibre 47 121 N/A Glass

Parameter Total IMP C Absorptionug ug Efficiency %

330.19 1.19 100


HYDROGEN CHLORIDE ABSORPTION EFFICIENCY

Test

Absorption Efficiency

Pre sampling leak rate

HYDROGEN CHLORIDE QUALITY ASSURANCE CHECKLIST

Total Sample Volume @ ref

Conditions

Type of Absorbers

Max. Filtration Temp.


Acceptable Absorption

95

Absorption Solutions

ND - None Detected

Post sampling leak rate

Sampling Times

Acceptable ?Efficiency %

HPLC Water

-

Acceptable leak rate


HYDROGEN CHLORIDE SUMMARY

Yes

0.43

0.01

Run 1

09:50 - 10:5405 September 2019

Concentration

Mean Sampling Rate

mg/m³

Run 1

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ISOKINETIC SAMPLING EQUATIONS 1 Hydrogen Chloride

Absolute pressure of stack gas, Ps Velocity of stack gas, Vs

Barometric pressure, Pb kPa 100.9 Velocity pressure coefficient, Cp 0.863Stack static pressure, Pstatic Pa -231 Mean of velocity heads, DPavg Pa 267.30Ps = Pb + (Pstatic) kPa 100.67 Mean stack gas temperature, Ts K 392.75

Gas density (wet, ambient), pVol. of water vapour collected, Vwstd p=(Ms*Ps)/(8.314*Ts) kg/m3 0.923

g H₂0 by Non Iso Stack Velocity, VsVwstd = (0.001246)(Vlc) m3 - m/s 20.76

Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa


Gas meter correction factor, Yd 0.916 Qa = (60)(As)(Vs) m³/min 7134Mean dry gas meter temperature, Tm K 300.50 Dry total flow of stack gas, Qstd

Mean pressure drop across orifice, DH mmH2O 34.12 Conversion factor (K/mm.Hg) 0.3592Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 0.87 Qstd = (Qa)Ps(0.3592)(1-Bwo) m³/min 4478

(Ts)Volume of gas metered wet, Vmstw Wet total flow of stack gas, Qstw

Vmstw = Vmstd + Vwstd m3 0.9594 Qstw = (Qa)Ps(0.3592) m³/min 4926 (Ts)

Nom³/min 3963

% oxygen measured in gas stream, act%O2 11.27 (Ts)% oxygen reference condition 10 Percent isokinetic, %I

O2 Ref = 21.0 - act%O2 0.88 Nozzle diameter, Dn mm 4.90 21.0 - ref%O2 Nozzle area, An mm2 18.83

Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 0.7718 Total sampling time, q min 60Moisture content, Bwo %I = (4.6398E6)(Ts)(Vmstd) % 99Bwo = Vwstd 0.0910 (Ps)(Vs)(An)(q)(1-Bwo)

% 9.10 Acceptable isokinetic range 95% to 115% YesMoisture by FTIR % -Molecular weight of dry gas, Md Mass collected , M ug 330CO2 16.85 Cwet = Mn mg/m³ 0.344O2 11.27 Vmstw

Total 28.12 Cdry = Mn mg/m³ 0.379N2 (100 -Total) 71.88 Vmstd

Cdry@X%O2 = Mn mg/m³ 0.428Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 31.15Molecular weight of wet gas, Ms Hydrogen Chloride Emission Rates, EMs = Md(1 - Bwo) + 18(Bwo) g/gmol 30.0 E = [(Cwet)(Qstw)(60)] / 1000 g/hr 101.73

O2 Reference Factor


Tm


Dry total flow of stack gas at X% O2, QstdO2


Hydrogen Chloride Concentration, C Vmstd + Vwstd


Vmstd@X%oxygen



𝑝

Page 36 of 148




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0.01 1 106.20

Field Blank - - -


Leak Test Results


Run 1 0.782 14.7 0.02 0.02 0.29 Yes


°C

Run 1 Quartz Fibre 47 150 N/A PE

Additional Test Information Barometric Orifice Setting

kPa mmH2O °C m3 %Run 1 100.9 30.0 1.021 21 0.883 11.27


327.48 ND 100

Mean Sampling Rate

HYDROGEN FLUORIDE QUALITY ASSURANCE CHECKLIST

Acceptable ?

95




0.01

HYDROGEN FLUORIDE ABSORPTION EFFICIENCY

Efficiency %

ND - None Detected

Acceptable Absorption Absorption Efficiency



Conditions

HYDROGEN FLUORIDE SUMMARY


07:41 - 07:4205 September 2019


Run 1

Yes

Test

08:09 - 09:0905 September 2019

Run 1

DGM Corr Factor (Yd)

DGM Temp DGM Total Volume


Sampling Times

0.1N Sodium Hydroxide

Type of Absorbers

Concentrationmg/m³


0.42

Oxygen Measured Value

Page 37 of 148




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0.03 400 1894.98

Field Blank - - -


Leak Test Results


Run 1 0.436 15.5 0.08 0.07 0.31 Yes


°C

Run 1 Quartz Fibre 47 150 N/A Glass


kPa mmH2O °C m3 %Run 1 98.4 30.0 1.021 27 0.466 10.70


3259 ND 100 95

Efficiency %

ND - None Detected


Sampling Times

SULPHUR DIOXIDE QUALITY ASSURANCE CHECKLIST

0.3% Hydrogen Peroxide


SULPHUR DIOXIDE ABSORPTION EFFICIENCY


Run 1 Yes





Acceptable ?


Test



7.48

mg/m³

SULPHUR DIOXIDE SUMMARY

Type of Absorbers

09:40 - 10:1004 September 2019

Run 1

Concentration

09:10 - 09:1104 September 2019

0.05



Conditions

Mean Sampling Rate



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0.007 50 2843.04

Field Blank - - -


Leak Test Results


Run 1 0.893 15.9 0.04 0.05 0.32 Yes


°C

Run 1 Quartz Fibre 47 150 N/A Glass


kPa mmH2O °C m3 %Run 1 98.4 30.0 1.021 27 0.954 10.70


10018.41 13.41 99.87



mg/m³

ND - None Detected

Run 1


Efficiency % Acceptable ?


Sampling Times

95

TestConcentration

Type of Absorbers


11.22Run 1

AMMONIA SUMMARY

Mean Sampling Rate

Yes






Conditions

AMMONIA QUALITY ASSURANCE CHECKLIST


0.1M Sulphuric Acid

0.01



13:35 - 14:3504 September 2019

13:10 - 13:1104 September 2019

AMMONIA ABSORPTION EFFICIENCY


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0.40 - 622.59

Reference conditions are 273K, 101.3kPa, dry gas 10% Oxygen.The raw data can be found at the end of the report - APPENDIX 5 - Raw Gases Data.

DateStart TimeEnd Time

Gas Gas Conc Range Instrument Instrument Instrument Zero Down Span down Leak Rate(ppm) Zero Reading Span Reading Zero Reading line reading line reading (%)

Propane 12.35 100 0.402 12.34 0.394 0.568 12.56 -1.78Zero and Span gas contained 21.4% Oxygen

DateStart TimeEnd Time

GasMean Raw

Value Zero down Span down Zero Drift Span Drift Corrected Values

ppm line reading line reading (%) (%) ppm / %

Propane 1.30 0.227 12.42 -0.02 -0.22 O ON/A - not corrected


mg/m³

TOTAL VOLATILE ORGANIC COMPOUNDS SUMMARY

TOTAL VOLATILE ORGANIC COMPOUNDS EMISSIONS CHART

Run 1

08:53

09:35 - 10:05 04 September 2019

04 September 2019

09:26

2.46

INSTRUMENTAL SPAN & ZERO CHECKS

Test

Corrected for Zero Drift

Corrected for Span Drift

POST-SAMPLING CALIBRATION CHECKS04 September 201910:1510:24


Sampling Times

PRE-SAMPLING CALIBRATION CHECKS

Concentration

2.1

2.2

2.3

2.4

2.5

2.6

2.7

09

:35

09

:36

09

:37

09

:38

09

:39

09

:40

09

:41

09

:42

09

:43

09

:44

09

:45

09

:46

09

:47

09

:48

09

:49

09

:50

09

:51

09

:52

09

:53

09

:54

09

:55

09

:56

09

:57

09

:58

09

:59

10

:00

10

:01

10

:02

10

:03

10

:04

10

:05

Co

nce

ntr

atio

n m

g/m

³

Time

Concentration

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1.09 500 106361.13

1.47 1500 80732.79

LOD%

0.002

0.01

Reference conditions are 273K, 101.3kPa, dry gas 10% Oxygen.The raw data can be found at the end of the report - APPENDIX 5 - Raw Gases Data.

Date Chiller Temperature (°C) 2.8

Start Time Requirement < 4°C

End Time Compliant Yes

Gas Range Zero Reading Span Reading Zero Check Zero Check Span Check Response Leak Rate(ppm / %) at analyser at analyser at analyser down line down line Time (Secs) %

Nitric Oxide 500 0.0 384.8 0.1 0.3 382.9 69 0.49

Carbon Monoxide 1000 0.0 764.0 0.1 0.3 766.0 57 -0.26

Carbon Dioxide 20 0.00 16.00 0.00 0.02 16.02 46 -0.12

Oxygen 25 0.00 11.00 0.00 0.01 11.01 52 -0.09

Date Chiller Temperature (°C) 2.9

Start Time Requirement < 4°C

End Time Compliant Yes

Zero Check Span Check Zero Drift Span Drift Corrected Valuesat Analyser at Analyser (%) (%) ppm / %

0.2 382.3 0.03 -0.68 O ON/A - not corrected

1.0 769.0 0.12 0.54 O ON/A - not corrected



Gas

Nitric Oxide

Carbon Monoxide

Carbon Dioxide

Oxygen

Corrected for Zero Drift


Carbon Monoxide

Sampling Time and Date

318.53

09:35 - 10:05 04 September 2019

09:35 - 10:05 04 September 2019

Oxides of Nitrogen 419.7


16.85

08:50

%Test

PRE-SAMPLING CALIBRATION DATA

10:07

Carbon Dioxide

09:35 - 10:05 04 September 2019

10:18

09:30

Concentration

10.70Oxygen

POST-SAMPLING CALIBRATION DATA

04 September 2019

Corrected for Span Drift

09:35 - 10:05 04 September 2019

Concentration

04 September 2019

Testmg/m³

COMBUSTION GASES SUMMARY

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OXIDES OF NITROGEN (as NO2) EMISSIONS CHARTAPPENDIX 2 - Summaries, Calculations, Raw Data and Charts

CARBON MONOXIDE EMISSIONS CHART

0.0

100.0

200.0

300.0

400.0

500.0

600.0

09

:35

09

:36

09

:37

09

:38

09

:39

09

:40

09

:41

09

:42

09

:43

09

:44

09

:45

09

:46

09

:47

09

:48

09

:49

09

:50

09

:51

09

:52

09

:53

09

:54

09

:55

09

:56

09

:57

09

:58

09

:59

10

:00

10

:01

10

:02

10

:03

10

:04

10

:05

Co

nce

ntr

atio

n m

g/m

³

Time

Oxides of Nitrogen NOx

ELV

0.0

200.0

400.0

600.0

800.0

1000.0

1200.0

1400.0

1600.0

09

:35

09

:36

09

:37

09

:38

09

:39

09

:40

09

:41

09

:42

09

:43

09

:44

09

:45

09

:46

09

:47

09

:48

09

:49

09

:50

09

:51

09

:52

09

:53

09

:54

09

:55

09

:56

09

:57

09

:58

09

:59

10

:00

10

:01

10

:02

10

:03

10

:04

10

:05

Co

nce

ntr

atio

n m

g/m

³

Time

Carbon Monoxide CO

ELV

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OXYGEN EMISSIONS CHART

CARBON DIOXIDE EMISSIONS CHART

0.0

5.0

10.0

15.0

20.0

25.0

09

:35

09

:36

09

:37

09

:38

09

:39

09

:40

09

:41

09

:42

09

:43

09

:44

09

:45

09

:46

09

:47

09

:48

09

:49

09

:50

09

:51

09

:52

09

:53

09

:54

09

:55

09

:56

09

:57

09

:58

09

:59

10

:00

10

:01

10

:02

10

:03

10

:04

10

:05

Co

nce

ntr

atio

n %

v/v

Time

O2

O2

0.0

2.0

4.0

6.0

8.0

10.0

12.0

14.0

16.0

18.0

09

:35

09

:36

09

:37

09

:38

09

:39

09

:40

09

:41

09

:42

09

:43

09

:44

09

:45

09

:46

09

:47

09

:48

09

:49

09

:50

09

:51

09

:52

09

:53

09

:54

09

:55

09

:56

09

:57

09

:58

09

:59

10

:00

10

:01

10

:02

10

:03

10

:04

10

:05

Co

nce

ntr

atio

n %

v/v

Time

Carbon Dioxide

CO2

Page 43 of 148




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LOD%

0.01

Date Range Zero Reading Span Reading Zero Check Zero Check Span Check Leak Rate

(%) at analyser at analyser at analyser down line down line %

05 September 2019 08:03 - 08:16 25 0.00 11.00 0.00 -0.02 10.99 -0.09

Date Zero Check Span Check Zero Drift Span Drift

down line down line (%) (%)

05 September 2019 09:04 - 09:17 0.00 11.02 0.00 0.18


08:30 - 09:0005 September 2019

PRE SAMPLING CALIBRATION DATA

Time of Analyser Checks

DAILY OXYGEN SUMMARY

11.27

Concentration

POST SAMPLING CALIBRATION DATA

Time of Analyser Checks

Sampling Times %

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Test Number Start Weight End Weight Total gain Concentration LOD Uncertainty

kg kg kg % % %

Run 1 3.1801 3.2241 0.0440 9.4 0.02 3.2

Run 2 3.3782 3.4515 0.0733 8.7 0.01 3.2

Test NumberSampling Duration

Total Volume Sampled

Sampling Rate Start Leak Rate End Leak RateAcceptable Leak Rate

mins l l/min l/min l/min l/min

Run 1 30 525.82 17.5 0.08 0.07 0.35 Yes

Run 2 60 952.59 15.9 0.02 0.02 0.32 Yes

Stack Diameter / Depth, D 2.70 m

Stack Width, W - m

Stack Area, A 5.73 m2

Average stack gas temperature 112 oC

Stack static pressure -0.238 kPa

Barometric Pressure 98.4 kPa

Component Molar Density Conc Dry Volume Dry Conc Conc Wet Volume Wet ConcMass kg/m3 Dry Fraction kg/m3 Wet Fraction kg/m3

M p % Vol r pi % Vol r pi

CO2 44 1.963059 16.851129 0.168511 0.330798 15.260044 0.152600 0.299564

O2 32 1.427679 10.701962 0.107020 0.152790 9.691482 0.096915 0.138363

N2 28 1.249219 72.446909 0.724469 0.905021 65.606463 0.656065 0.819569

H2O 18 0.803070 - - - 9.442011 0.094420 0.075826

Where: p = M / 22.41 pi = r x p

Determinand

Dry Density (STP), P STD

Wet Density (STP), P STW

Dry Density (Actual), P Actual

Average Wet Density (Actual), P ActualW

Where:

P STD = sum of component concentrations, kg/m3 (not including water vapour) P Actual = P STD x (Ts / Ps) x (Pa / Ta)

P STW = (P STD + pi of H2O) / (1 + (pi of H2O / 0.8036)) P ActualW = P STW x (Ts / Ps) x (Pa / Ta)

Stack Gas Composition & Molecular Weights

Moisture Determination - Non Isokinetic

Stack Characteristics

Calculation of Stack Gas Densities


0.9541

08:09 - 09:09 05 September 2019

09:40 - 10:10 04 September 2019

Result

kg/m3

MOISTURE CALCULATIONS

PRELIMINARY STACK SURVEY


0.916

kg/m3

Units


1.3333

kg/m31.3886

kg/m3

Moisture Quality Assurance

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TRAVERSE 1

Traverse Distance DP pt DP pt Temp Velocity O2 Angle

Point into Pa mmH2O oC m/s % of Swirl

duct (m)(average of 3

readings)(average of 3

readings)m³/s Vol o

1 0.07 236.8 24.2 112 20.3 116.4 - <152 0.22 248.3 25.3 112 20.8 119.2 - <153 0.40 247.5 25.3 112 20.8 119.0 - <154 0.61 256.4 26.2 112 21.2 121.1 - <155 0.92 257.3 26.3 112 21.2 121.3 - <156 1.78 258.9 26.4 112 21.3 121.7 - <157 2.09 263.0 26.8 112 21.4 122.7 - <158 2.30 267.1 27.3 112 21.6 123.6 - <159 2.48 262.2 26.8 112 21.4 122.5 - <15

10 2.63 247.5 25.3 112 20.8 119.0 - <15Mean - 254.5 26.0 112 21.1 120.7 - -






1 0.07 239.1 24.4 112 20.4 117.0 - <152 0.22 249.1 25.4 112 20.9 119.4 - <153 0.40 254.0 25.9 112 21.1 120.6 - <154 0.61 260.5 26.6 112 21.3 122.1 - <155 0.92 258.1 26.3 112 21.2 121.5 - <156 1.78 263.0 26.8 112 21.4 122.7 - <157 2.09 265.4 27.1 112 21.5 123.2 - <158 2.30 265.4 27.1 112 21.5 123.2 - <159 2.48 258.1 26.3 112 21.2 121.5 - <15

10 2.63 248.3 25.3 112 20.8 119.2 - <15Mean - 256.1 26.1 112 21.1 121.0 - -

Start Value End Value Difference Start Value End Value DifferencemmH2O mmH2O % mmH2O mmH2O %

Run 1 115 114 0.9 Pass 122 121 0.8 Pass

RunStagnation

(Pa)Reference

(Pa)Difference

(Pa)

Outcome(Permitted +/- 10 Pa)

Run 1 -235 -238 3.0 Pass

PRELIMINARY STACK SURVEY QUALITY ASSURANCE CHECKLIST

Date of SurveyTime of Survey


(actual)



(actual)

Velocity Measurement Device: S-Type Pitot

Sampling Line B

08:00 - 08:2304 September 2019

Sampling Line A

Outcome


Post Traverse Leak RateRun

PITOT LEAK CHECK

To complete a compliant pitot leak check a pressure of over 80 mmH₂O (or 800 Pa) is applied and the pressure drop monitored over 5 mins. A drop of less than 5% must be observed.

S-Type Pitot Stagnation Check

OutcomePre Traverse Leak Rate

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EA Technical Guidance Note (Monitoring) M1 Units Requirement Compliant

Lowest Differential Pressure Pa >= 5 Pa Yes

Lowest Gas Velocity m/s - -

Highest Gas Velocity m/s - -

Ratio of Gas Velocities - < 3 : 1 Yes

Maximum angle of flow with regard to duct axis o < 15o Yes

No local negative flow - - Yes

Velocity at Traverse Point, V = Kpt x (1-e) * Ö(2 * DP pt / P ActualW)

Where:Kpt = Pitot tube calibration coefficient(1-e) = Compressibility correction factor, assumed at a constant 0.998

Average Stack Gas Velocity, Va 21.1 m/s

Duct gas flow conditions Actual Reference UnitsTemperature 112 0 oCTotal Pressure 98.162 101.3 kPaOxygen 10.7 10 %Moisture 9.44 0.00 %Pitot tube calibration coefficient, Kpt 0.90

Gas Volumetric Flowrate UnitsAverage Stack Gas Velocity (Va) m/sStack Area (A) m2

Gas Volumetric Flowrate (Actual), QActual m3/hr

Gas Volumetric Flowrate (STP, Wet), QSTP m3/hr

Gas Volumetric Flowrate (STP, Dry), QSTP,Dry m3/hr

Gas Volumetric Flowrate (REF), QRef m3/hr

Where:QActual = Va x A x 3600QSTP = Q (Actual) x (Ts / Ta) x (Pa / Ps) x 3600QSTP,Dry = Q (STP) / (100 - (100 / Ma)) x 3600QRef = Q (STP) x ((100 - Ma) / (100 - Ms)) x ((21 - O2a) / (21 - O2s))

Nomenclature:Ts = Absolute Temperature, Standard Conditions, 273 KPs = Absolute Pressure, Standard Conditions, 101.3 kPaTa = Absolute Temperature, Actual Conditions, KPa = Absolute Pressure, Actual Conditions, kPaMa = Water vapour, Actual Conditions, % VolMs = Water vapour, Reference Conditions, % VolO2a = Oxygen, Actual Conditions, % VolO2s = Oxygen, Reference Conditions, % Vol

5.73

Result

Yes

21.6

237

Result

298955

253451

20.3

1.1

PRELIMINARY STACK SURVEY (CONTINUED)

<15

Calculation of Stack Gas Velocity, V

Calculation of Stack Gas Volumetric Flowrate, Q

435081


Sampling Plane Validation Criteria

21.11

270728

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Value UnitsStack Depth 2.70 m Sampling Distance Distance into UnitsStack Width - m Point (% of Depth) StackArea 5.73 m2 A 40 1.08 m

Circular 2 line 20 Points

Sampling Distance Distance into SwirlPoint (% of Depth) Stack (m) o

1 2.6 0.07 < 152 8.2 0.22 < 153 14.6 0.40 < 154 22.6 0.61 < 15

5 34.2 0.92 < 15

6 65.8 1.78 < 15

7 77.4 2.09 < 15

8 85.4 2.30 < 159 91.8 2.48 < 15

10 97.4 2.63 < 1511 2.6 0.07 < 1512 8.2 0.22 < 15

13 14.6 0.40 < 15

14 22.6 0.61 < 1515 34.2 0.92 < 1516 65.8 1.78 < 15

Isokinetic sampling point 17 77.4 2.09 < 15Isokinetic sampling points not used 18 85.4 2.30 < 15Non Isokinetic/Gases sampling point 19 91.8 2.48 < 15

20 97.4 2.63 < 15


Isokinetic Sampling

STACK DIAGRAM

Non-Isokinetic/Gases Sampling

SAMPLING LOCATION

1

2

3

4

5

6

7

8

9

10

20

19

14

17 15 13

12

11

18 16 Sampling Line

B

Sampling Line A

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Run Sampled Volume

Sampled Gas Temp

Sampled Gas Pressure

Sampled Gas Humidity

Oxygen Content

Limit of Detection

Leak Uncollected Mass

m³ K kPa % by volume % by volume % by mass % mgMU required < 2% < 2% < 1% < 1% < 10% < 5% of ELV < 2% < 10% of ELVRun 1 0.001 2.0 0.50 1.0 0.1 0.2000 - -as a % 0.11 0.51 0.50 1.0 0.89 1.2957 0.44 0.001compliant? Yes Yes Yes Yes Yes Yes Yes Yes

Run UncollectedMass

m³ mg - mg/m³ mgRun 1 0.60 0.4700 1.1 0.002 0.0001 -MU as mg/m3 0.01 0.2591 0.01 0.002 0.0001 0.26MU as % 1.24 42.5532 - 0.252 0.0246 -

0.52 mg/m³ 85.17 % Result 2.59 % ELV

(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement

LeakO2 Correction


Combined uncertainty

Volume (STP) Mass of particulate

MEASUREMENT UNCERTAINTY BUDGET - TOTAL PARTICULATE MATTER

R1 - Uncertainty expressed at a 95% confidence level (where k = 2)

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Run Sampled Volume

Sampled Gas Temp



Oxygen Content


m³ K kPa % by volume % by volume % ng/m3

MU required < 2% < 2% < 1% < 1% < 10% < 5% < 10% ELVRun 1 0.001 2.0 0.50 1.0 0.1 - 9.29461E-05as a % 0.02 0.7 0.51 1.0 0.93 0.49 0.09compliant? Yes Yes Yes Yes Yes Yes N/A

Run Uncollected LaboratoryMass analysis

m³ - ng ng/m³ ng/m3 -Run 1 4.4944 1.1 0.0600 0.000002 0.0001 - -MU as ng/m3 0.00001 0.00001 0.00005 0.000002 0.0000033 0.0001 0.0001MU as % 1.3108 - 5.6667 0.2815 0.3897 10.00 -

0.0002 ng/m³ 23.2 % Result 0.20 % ELV


Volume (STP) Mass of Dioxin & Furan

O2 Correction Leak

MEASUREMENT UNCERTAINTY BUDGET - DIOXINS & FURANS




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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Concentration in impinger

Leak

m³ K kPa % by volume % by volume mg %MU required <=2% <2.5 k <=1% <=1% <=5% <5% <=2%Run 1 0.001 2.0 0.50 1.0 0.1 0.00 -as a % 0.13 0.7 0.51 1.0 0.93 3.00 0.45compliant? Yes Yes Yes Yes Yes Yes Yes

Run LabUncertainty

m³ - mg mg/m³ mgRun 1 0.6782 1.0682 1.4672 0.000005 - -MU as mg 0.00003 0.00002 0.0015 0.000005 0.00009 0.0015MU as % 1.3118 0.9711 77.4264 0.2610 4.85417 -

0.003 mg/m³ 155.19 % Result 5.92 % ELV


Mass of Cadmium &

Thallium


Volume (STP) O2 Correction


Leak

MEASUREMENT UNCERTAINTY BUDGET - CADMIUM & THALLIUM


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Run Sampled Volume

Sampled Gas Temp



Oxygen Content


Leak

m³ K kPa % by volume % by volume mg %MU required <=2% <2.5 k <=1% <=1% <=5% <5% <=2%Run 1 0.001 2.0 0.50 1.0 0.10 0.002 -as a % 0.13 0.73 0.51 1.0 0.93 3.00 0.45compliant? Yes Yes Yes Yes Yes Yes Yes

Run LabUncertainty

m³ - mg mg/m³ mgRun 1 0.7477 1.0682 49.7664 0.0002 - -MU as mg/m3

0.0009 0.0006 0.0047 0.0002 0.00314 0.0058MU as % 1.3462 0.9711 7.2659 0.2610 4.85417 -

0.01 mg/m³ 17.80 % Result 2.30 % ELV




Mass of Heavy Metals

Volume (STP) LeakO2 Correction

MEASUREMENT UNCERTAINTY BUDGET - HEAVY METALS


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Run Sampled Volume

Sampled Gas Temp



Oxygen Content


Leak

m³ K kPa % by volume % by volume mg %MU required <=2% <2.5 k <=1% <=1% <=5% <5% <=2%

Run 1 0.001 2.0 0.50 1.0 0.10 1.02353E-05 -as a % 0.13 0.7 0.51 1.0 0.93 3.00 0.45

compliant? Yes Yes Yes Yes Yes Yes YesRun 2 0.001 2.0 0.50 1.0 0.10 0.000126 -as a % 0.13 0.7 0.50 1.0 0.89 3.00 0.31

compliant? Yes Yes Yes Yes Yes Yes Yes

Run Lab Combined uncertaintyUncertainty

m³ - mg mg/m³ mgRun 1 0.6782 1.0682 0.7088 0.000002 - -MU as mg/m3

0.00001 0.00001 0.0007 0.000002 0.00004 0.0007MU as % 1.3118 0.9711 78.1744 0.2610 4.85417 -Run 2 0.717 1.130 0.678 0.00001 - -MU as mg/m3

0.00004 0.00004 0.003 0.00001 0.00017 0.003MU as % 1.308 1.027 75.684 0.177 4.85417 -

0.001 mg/m³ 156.68 % Result 2.89 % ELV

0.005 mg/m³ 151.72 % Result 10.41 % ELV


Volume (STP) Mass of Mercury

O2 Correction


MEASUREMENT UNCERTAINTY BUDGET - MERCURY



Leak

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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Limit of Detection

Leak

m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 0.7718 300.50 98.59 1.0 11.266 0.452 -as a % 0.13 0.67 0.51 1.0 0.89 0.04 0.44compliant? Yes Yes Yes Yes Yes Yes Yes

Run LabUncertainty

m³ mg - mg/m³ mgRun 1 0.6824 0.4525 1.1300 0.0011 - -MU as mg/m3

0.0056 0.0043 0.0044 0.0011 0.0205 0.0222MU as % 1.3121 1.0149 1.0273 0.2523 4.8 -

0.04 mg/m³ 10.38 % Result 0.44 % ELV


Mass of Hydrogen Chloride

Leak Combined uncertainty


Volume (STP)


O2 Correction

MEASUREMENT UNCERTAINTY BUDGET - ISOKINETIC HYDROGEN CHLORIDE

Page 54 of 148




SOCOTEC UK LTD

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Run LabUncertainty


0.0055 0.0180 0.0043 0.0003 0.0256 0.0321MU as % 1.3077 4.3051 1.0273 0.0784 6.1 -

0.06 mg/m³ 15.30 % Result 6.41 % ELV


Run

O2 Correction Leak


Oxygen Content


Volume (STP) Mass of Hydrogen Fluoride


Sampled Gas Temp

Sampled Volume

MEASUREMENT UNCERTAINTY BUDGET - NON-ISOKINETIC HYDROGEN FLUORIDE



LeakLimit of Detection

Page 55 of 148




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Run LabUncertainty


0.0977 0.0574 0.0726 0.0195 0.3589 0.384MU as % 1.3073 0.7671 0.9711 0.2604 4.8 -

0.77 mg/m³ 10.27 % Result 0.19 % ELV


Mass of Sulphur Dioxide

O2 Correction



Sampled Gas Temp

Sampled Volume

Run Oxygen Content

Limit of Detection



Volume (STP)

Leak

MEASUREMENT UNCERTAINTY BUDGET - NON-ISOKINETIC SULPHUR DIOXIDE


Leak

Page 56 of 148




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Run LabUncertainty


0.1464 0.0275 0.1089 0.0204 0.6506 0.677MU as % 1.3055 0.2447 0.9711 0.1816 5.8 -

1.35 mg/m³ 12.06 % Result 2.71 % ELV


Oxygen Content


Sampled Gas Temp


Sampled Volume

Run

Leak

LeakLimit of Detection

Volume (STP)


O2 CorrectionMass of Ammonia

MEASUREMENT UNCERTAINTY BUDGET - NON-ISOKINETIC AMMONIA



Page 57 of 148




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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Leak

m³ K kPa % by volume % by volume %

MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.0004 2.0 0.50 1.0 0.1 -as a % 0.07 0.52 0.51 1.0 0.93 0.46compliant? Yes Yes Yes Yes Yes YesRun 2 0.00032 2.0 0.50 1.0 0.1 -as a % 0.03 0.52 0.51 1.0 0.93 0.13compliant? Yes Yes Yes Yes Yes Yes

Run UncollectedMass

m³ mg - mg/m³ mgRun 1 0.361 44000 1.1 220.5 58 -MU as % v/v 0.13 0.02 0.004 0.03 0.01 0.14MU as % 1.2 0.2 0.97 0.3 0.1 -Run 2 0.65 73300 1.1 56 58 -MU as % v/v 0.12 0.0132 0.003 0.007 0.01 0.12MU as % 1.2 0.1364 1.0 0.073 0.08 -

0.27 % v/v 3.24 %

0.24 % v/v 3.17 %Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement

Mass Gained


O2 Correction


Leak Combined uncertainty

MEASUREMENT UNCERTAINTY BUDGET - MOISTURE

Volume (STP)


Page 58 of 148




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2.5 mg/m3

- mg/m3

19.76 mg/m3

160 mg/m3

Performance characteristics Value MU Met?14 Yes60 -30 -30 -

0.25 Yes0.15 Yes0.70 Yes-0.02 Yes-0.22 Yes0.02 Yes0.80 Yes0.01 Yes0.10 Yes-1.78 Yes1.0 Yes

Uncertaintyur0ursufit

u0druspresuapresutempuvoltuleakucalib

uf

2.46 mg/m3

0.67 mg/m3

1.30 mg/m3

- % ELV

1.30 mg/m3

53.11 % valueReference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement

specification

< 0.1%vol /10 volt

% of full scale/3 kPa

Drift

-

Expanded uncertainty expressed with a level of confidence of 95%

Uncertainty in factor

% full scale/10K

Expanded uncertainty

Units

Number of readings in measurement

Measured Concentration


< 2% of valueUncertainty of calibration gaslosses in the line (leak) < 2% of span gas value

losses in the line (leak)

ambient temperature dependence

seconds

Zero drift

Repeatability at zero

Performance characteristic

<1 % range

MEASUREMENT UNCERTAINTY BUDGET - VOLATILE ORGANIC COMPOUNDS RUN 1

% of full scale/2 kPaatmospheric pressure dependence

-

Logger sampling interval

Repeatability at span levelDeviation from linearity

<2% range / 24hr

Lack of fit


% full scale/10V

<3% / 2 kPa

minutes

volume or pressure flow dependence

0.04

<2 % range

atmopsheric pressure dependence

% of value

Standard deviation of repeatability at zero

<2 % / 3 kPa

% of valuedependence on voltage

<3% range / 10 K

<2% range / 24hr% full scale

<180

Range

% of value

secondsResponse time

0.001

% full scale


Measurement period-

<2 % range

Calibration Gas ConcentrationLimit

-

Span drift

% full scale

0.03Standard deviation of repeatability at span level

% full scale

0.04

0.65

Value of uncertainty quantity

Uncertainty of calibration gas



0.00001Dependence on voltage 0.14

-0.03

Measurement uncertainty Measured Concentration


0.03

-0.03

0.01

Page 59 of 148




SOCOTEC UK LTD

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500 mg/m3

419.7 mg/m3

789 mg/m3

1025 mg/m3

Value MU Met?69 Yes60 -30 -30 -

0.11 Yes0.1 Yes

-0.40 Yes0.03 Yes-0.68 Yes0.5 Yes

0.50 Yes0.00 Yes-2.60 Yes0.14 YesN/A -0.14 Yes

UncertaintyU r = S r

U lof

U d,z

U d,s

U t,z

U t,s

U p

U fit

U v

U i

U adj

419.65 mg/m3

5.37 mg/m3

10.53 mg/m3

2.1 % ELV

10.5 mg/m3

2.5 % value

atmospheric pressure dependence

Zero drift

<2%

influence of Ambient Temp at Span0.000

0.000

Combined uncertaintyExpanded at a 95% confidence interval

influence of supply voltageinfluence of sample gas flow


lack of fit

0.845

-0.231

-0.390

Concentration @ Ref conditions

% of value


influence of Ambient Temp at Zero

-

% full scale/10V

Value of uncertainty quantity0.004

0.346

% full scale

Measurement uncertainty (Concentration Measured)


Influence of Vibrationdependence on voltage

Uncertainty of Cal gas 3.848

<3% range / 10 K

short term span drift

Deviation from linearity

% full scale

repeatability

seconds

< 0.1%vol /10 volt

Repeatability at span level

losses in the line (leak) % of value

-180


Developed for the STA by R Robinson, NPL

influence of sample gas pressure

Span drift

minutes


% range

% full scale

Combined interference

3.609

seconds

<2 % range


Repeatability at zero % full scale

Combined Interfence

<2% range/24hr

-

-0.002

<1 % range

% of upper limit of Cal range

short term zero drift 0.015

% full scale/10K<4% of Range

Number of readings in measurementMeasurement period

-

<3% / 2 kPa

< 2% of value

Response time

ambient temperature dependence zero / span

Analyser Full Scale

% of full scale/3 kPa <2 % / 3 kPa

<2% range / 24hr

Limit value

Cal gas conc

Units specification


MEASUREMENT UNCERTAINTY BUDGET - OXIDES OF NITROGEN

Performance characteristic

<2 % range

Page 60 of 148




SOCOTEC UK LTD

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1500 mg/m3

318.5 mg/m3

955.4 mg/m3

1250 mg/m3

Value MU Met?57 Yes60 -30 -30 -0.1 Yes0.2 Yes

0.61 Yes0.12 Yes0.54 Yes

1 Yes2.2 Yes-4 Yes

-0.01 Yes-0.32 YesN/A N/A0.00 Yes1.00 Yes

N/A - Horiba's are not effected by Vibration


U lof

U d,z U d,s

U t,z

U t,s

U p

U fit

U v

U i

U adj

298.3 mg/m3

5.6 mg/m3

11.1 mg/m3

0.7 % ELV

11.1 mg/m3

3.7 % value

-2.86Uncertainty of Cal gas 3.82


Expanded uncertainty expressed with a level of confidence of 95%Developed for the STA by R Robinson, NPL


Cal gas conc

% of value

-2.30influence of supply voltage

Combined uncertaintyExpanded uncertainty

influence of Ambient Temp span



-1.60

Combined Interfence

influence of sample gas pressure0.72

influence of Ambient Temp zero

Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement


0.000.69

% of value

<2% range / 24hr

Performance characteristic0.003

influence of sample gas flow

% of upper limit of Cal rangelosses in the line (leak)

<2 % / 3 kPa

< 0.1%vol /10 volt<4% of Range

0.12


Influence of Vibration

atmospheric pressure dependenceambient temperature dependence zero / span

repeatability


<2%

<3% / 2 kPa


0.07

% of value < 2% of value< 2% of value

lack of fitshort term zero drift

% full scale

0.35

Analyser Full Scale

Limit value

MEASUREMENT UNCERTAINTY BUDGET - CARBON MONOXIDE

% of Range% full scale/10K

% full scale


volume or pressure flow dependence<2% range/24hr

-<1 % rangeRepeatability at zero

Concentration @ Ref conditions

Measurement period


secondsPerformance characteristicsResponse time


Zero drift

Number of readings in measurement--

specification

% full scale

% full scale/10V

Span drift

<2 % range

minutes

% full scale

180

-

Units

<3% range / 10 KCombined interferencedependence on voltage

<2 % range

secondsLogger sampling interval

Page 61 of 148




SOCOTEC UK LTD

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-16.85

1620

Performance characteristics Value MU Met?46 Yes60 -30 -30 -

0.015 Yes0.014 Yes0.13 Yes0.01 Yes0.04 Yes0.02 Yes0.8 Yes

0.01 Yes0.56 Yes0.1 Yes

-0.125 Yes1 Yes

Performance characteristic UncertaintyStandard deviation of repeatability at zero ur0Standard deviation of repeatability at span level ursLack of fit ufitDrift u0drvolume or pressure flow dependence uspresatmospheric pressure dependence uapresambient temperature dependence utempCombined interference (from mcerts) -dependence on voltage uvoltlosses in the line (leak) uleakUncertainty of calibration gas ucalib

16.85 %vol0.17 %vol0.65 %

0.65 % of value

3.88 % vol



Measurement uncertainty

0.0646632

-0.0025560

< 2% of value


< 2% of value

<0.3% volume 10 K% of fs/kPa

% range

<1% range



Losses in the line (leak)

0.0862168


0.0005000

< 1.5 % range


Measurement period

Span drift (during measurement period)

0.03009600.00002310.0097762

% by volume

0.0750555


% by volume /10K

-0.0121613

% of value% of value


Response time

-


% vol at zero level




<0.3 % volume

<2% range< 0.1%vol /10 volt


Dependence on voltage

0.0972900

<2% volume/24hr

Repeatability at zero <0.2 % range<0.4 % range

% vol

% of fs / 10l/h

% by volume

Zero drift (during measurement period) <2% of volume / 24hr% vol at span level

-

seconds

% by volume /10V

Calibration gasAnalyser Full Scale

specification

Logger sampling interval-

Limit value

Units< 200 s

seconds -minutes

MEASUREMENT UNCERTAINTY BUDGET - CARBON DIOXIDE

Measured concentration


Page 62 of 148




SOCOTEC UK LTD

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10 %vol10.70 %vol

11 %vol25 %vol


0.25 Yes0.15 Yes0.13 Yes0.27 Yes0.00 Yes0.03 Yes0.05 Yes-0.05 Yes0.01 Yes0.00 Yes0.01 Yes0.0 Yes


U lof

U d,z

U d,s

U t,z

U t,s

U p

U fit

U v

U i

U adj

10.70 %0.18 %0.36 %

0.4 %

3.37 % vol

<2% range / 24hr


losses in the line (leak)Uncertainty of calibration gas


Zero drift % full scale

<2 % / 3 kPa

% full scale <2 % rangeRepeatability at zero

-

-

<2 % range

<1 % range-

Analyser Full Scale

<3% / 2 kPa

0.15750.0000


short term zero drift



Uncertainty of Cal gas

0.0001

influence of Ambient Temp at Zeroinfluence of Ambient Temp at Span





specification

secondsResponse time

Reported ConcentrationCalibration gas

Span drift % full scale

180

% of value

% full scale

minutesMeasurement period -

MEASUREMENT UNCERTAINTY BUDGET - OXYGEN


< 2% of value

Performance characteristicrepeatability


Developed for the STA by R Robinson, NPL

0.0004

0.0751


% range <4% of Range

< 2% of value% of value

0.0000influence of sample gas pressure

lack of fit




0.0017

-0.0036

seconds

Reference

Units

% of full scale/3 kPavolume or pressure flow dependence

% full scale/10K <3% range / 10 K



influence of supply voltageCombined Interfence

0.0083

0.0173

% full scale/10V < 0.1%vol /10 volt

0.0550

% of valuedependence on voltage

<2% range/24hr

Page 63 of 148




SOCOTEC UK LTD

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10 %vol11.27 %vol

11 %vol25 %vol


0.25 Yes0.15 Yes0.1 Yes

0.00 Yes0.18 Yes

-0.0425 Yes0.0475 Yes0.0025 Yes

0.00 Yes0.00 Yes-0.09 Yes1.00 Yes

11.27 %0.14 %0.27 %

0.27 %

2.35 % vol

180

volume or pressure flow dependence % of full scale/3 kPa <2 % / 3 kPa

U adj

U r = S r

Expanded uncertainty as percentage of the result

0.0550

Combined interference % range% full scale/10K <3% range / 10 K

Span drift

influence of Ambient Temp at Zero

lack of fit U lof 0.0577short term zero drift


- -

Response time

% of value

secondsLogger sampling interval seconds

<2 % range

Measured concentrationReference

MEASUREMENT UNCERTAINTY BUDGET - OXYGEN

influence of supply voltage

minutes

0.0000

Analyser Full Scale

Repeatability at zero % full scale

--

0.0000U p

U fit

Deviation from linearityRepeatability at span level % full scale

U v

dependence on voltage

0.0000

losses in the line (leak) Uncertainty < 2% of value

<3% / 2 kPa

% of value% full scale/10V

Calibration gas

losses in the line (leak)

ambient temperature dependenceatmospheric pressure dependence

% full scale <2% range/24hr

Day 2 - 05 September 2019


U d,z

U t,z

U i 0.0000

-0.0294

<2 % range

Uncertainty of calibration gas % of value < 2% of value

repeatability

<4% of Range

Zero drift

U t,s

Combined Interfence

% full scale <2% range / 24hr


0.0083

Measurement uncertainty (Concentration Measured)Combined InterfenceUncertainty of Cal gas

Uncertainty of Cal gas

0.0001

short term span drift U d,s

influence of Ambient Temp at Span

0.00000.1050

specification


< 2% of value

<1 % range

Measurement period


influence of sample gas pressure

< 0.1%vol /10 volt

Units


Page 64 of 148




SOCOTEC UK LTD

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21.1 m/s435081 m³/hr

Performance Characteristics & Source of Value Units Values Requirement CompliantUncertainty of Local Gas Velocity Determination

Uncertainty of pitot tube coefficient - 0.010

Uncertainty of mean local dynamic pressures - 2.00

Factor loading, function of the number of measurements. 3 readings 0.591 minimum 3 Yes

Range of measurment device pa 1000

Resolution pa 1.00

Calibration uncertainty pa 38.74<1% of Value or 20

Pa whichever is greater

Yes

Drift % range 0.10

Linearity % range 0.06 <2% of value Yes

Uncertainty of gas density determination

Uncertainty of molar mass determination kg/mol 0.00008Uncertainty of temperature measurement K 1.96 <1% of value Yes

Uncertainty of absolute pressure in the duct pa 501

Uncertainty associated with the estimate of density - 0.008

Uncertainty associated with the measurement of local velocity - 0.0001Uncertainty associated with the measurement of mean velocity - 0.0001

m/s0.250.49

%1.22.3

m³/hr11271.822092.7

%2.65.1

Expanded Measurement Uncertainty of Volumetric Flow Rate at a 95% Confidence IntervalExpressed as a % of the Measured Volumetric Flow RateExpanded uncertainty at a 95% Confidence Interval

Measured Velocity at Actual Conditions Measured Volumetric Flow rate at Actual Conditions

Measurement Uncertainty - VelocityCombined uncertaintyExpanded uncertainty at a 95% Confidence Interval

Note - The expanded uncertainty uses a coverage factor of k = 2.

Expanded Measurement Uncertainty of Velocity at a 95% Confidence IntervalExpressed as a % of the Measured VelocityExpanded uncertainty at a 95% Confidence Interval

Measurement Uncertainty Volumetric Flow Rate

Expanded uncertainty at a 95% Confidence IntervalCombined uncertainty



MEASUREMENT UNCERTAINTY BUDGET - VELOCITY & VOLUMETRIC FLOW RATE


Page 65 of 148




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Version Issue Date


18 October 2019

AmendmentsO2 cylinder reference ID updated.

2Title of table on page 32 updated to mention Hg only.

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END OF REPORT

Thank you for choosing SOCOTEC for your environmental monitoring needs. We hope our services have met your requirements and that you are fully satisfied with your experience of working with us, we really do value your custom and would welcome your feedback. We would appreciate it if you could take a moment to complete a short online questionnaire so that we can improve our operations and address any areas that have not met with your expectations, by clicking on

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Page 67 of 148




Time

hh:mmActual ppm

Corr ppmActual ppm

Corr ppmActual ppm

Corr ppm Actual %Corr

%Actual %

Corr %

Averages 191.364 - - - 238.621 - 16.8511 - 10.702 -09:35 192.50 - - - 264.92 - 17.13 - 10.84 -09:36 193.56 - - - 264.00 - 17.07 - 10.56 -09:37 189.95 - - - 259.00 - 17.02 - 10.75 -09:38 188.74 - - - 260.75 - 17.00 - 10.60 -09:39 190.05 - - - 248.08 - 16.90 - 10.65 -09:40 190.49 - - - 260.58 - 16.95 - 10.63 -09:41 181.85 - - - 267.08 - 17.03 - 10.59 -09:42 178.97 - - - 257.33 - 17.12 - 10.53 -09:43 196.90 - - - 244.08 - 17.06 - 10.56 -09:44 202.88 - - - 231.75 - 16.84 - 10.68 -09:45 199.13 - - - 237.83 - 16.87 - 10.65 -09:46 197.88 - - - 236.33 - 16.95 - 10.59 -09:47 203.43 - - - 234.75 - 16.83 - 10.64 -09:48 205.28 - - - 238.58 - 16.76 - 10.69 -09:49 193.17 - - - 229.00 - 16.76 - 10.70 -09:50 189.13 - - - 235.58 - 16.73 - 10.73 -09:51 177.87 - - - 236.67 - 16.70 - 10.77 -09:52 174.12 - - - 246.25 - 16.83 - 10.72 -09:53 192.96 - - - 237.58 - 16.85 - 10.68 -09:54 199.24 - - - 234.58 - 16.84 - 10.67 -09:55 199.96 - - - 237.83 - 16.83 - 10.68 -09:56 200.20 - - - 231.08 - 16.74 - 10.73 -09:57 187.24 - - - 226.25 - 16.70 - 10.78 -09:58 182.92 - - - 217.75 - 16.60 - 10.85 -09:59 185.59 - - - 226.92 - 16.69 - 10.81 -10:00 186.48 - - - 220.33 - 16.73 - 10.79 -10:01 193.31 - - - 225.50 - 16.75 - 10.79 -10:02 195.59 - - - 225.00 - 16.81 - 10.77 -10:03 191.40 - - - 217.25 - 16.77 - 10.79 -10:04 190.00 - - - 228.92 - 16.77 - 10.78 -10:05 181.51 - - - 215.67 - 16.77 - 10.77 -

- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -

Summary of Raw Gases Data

APPENDIX 5 - Raw Gases Data

OxygenOxides of Nitrogen Sulphur Dioxide Carbon Monxide Carbon Dioxide


Limerick

A2-01 (Kiln 6 / Rawmill) Page 68 of 144

P0029-05CAR19-01 (LEK 11825) / Version 1

3rd September 2019


Timehh:mm

Actual ppm

Corrppm

Oxygen%

Timehh:mm

Actual ppm

Corrppm

Oxygen%

Timehh:mm

Actual ppm

Corrppm

Oxygen%

Averages 1.29581 - 10.702 Averages - - - Averages - - -09:35 1.38 - 10.84 - - - - - - - -09:36 1.37 - 10.56 - - - - - - - -09:37 1.38 - 10.75 - - - - - - - -09:38 1.33 - 10.60 - - - - - - - -09:39 1.34 - 10.65 - - - - - - - -09:40 1.31 - 10.63 - - - - - - - -09:41 1.32 - 10.59 - - - - - - - -09:42 1.29 - 10.53 - - - - - - - -09:43 1.31 - 10.56 - - - - - - - -09:44 1.30 - 10.68 - - - - - - - -09:45 1.27 - 10.65 - - - - - - - -09:46 1.30 - 10.59 - - - - - - - -09:47 1.31 - 10.64 - - - - - - - -09:48 1.29 - 10.69 - - - - - - - -09:49 1.31 - 10.70 - - - - - - - -09:50 1.32 - 10.73 - - - - - - - -09:51 1.31 - 10.77 - - - - - - - -09:52 1.28 - 10.72 - - - - - - - -09:53 1.27 - 10.68 - - - - - - - -09:54 1.28 - 10.67 - - - - - - - -09:55 1.29 - 10.68 - - - - - - - -09:56 1.34 - 10.73 - - - - - - - -09:57 1.29 - 10.78 - - - - - - - -09:58 1.29 - 10.85 - - - - - - - -09:59 1.26 - 10.81 - - - - - - - -10:00 1.29 - 10.79 - - - - - - - -10:01 1.25 - 10.79 - - - - - - - -10:02 1.23 - 10.77 - - - - - - - -10:03 1.24 - 10.79 - - - - - - - -10:04 1.22 - 10.78 - - - - - - - -10:05 1.22 - 10.77 - - - - - - - -

- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -- - - - - - - - - - - -

Summary of Raw Gases Data


TVOC Run 2TVOC Run 1 TVOC Run 3

Irish Cement LimitedLimerickA2-01 (Kiln 6 / Rawmill) Page 69 of 144

P0029-05CAR19-01 (LEK 11825) / Version 1

3rd September 2019


Time

hh:mmActual ppm

Corr ppmActual ppm

Corr ppmActual ppm

Corr ppm Actual %Corr

%Actual %

Corr %

Averages - - - - - - - - 11.2657 -08:30 - - - - - - - - 10.98 -08:31 - - - - - - - - 10.94 -08:32 - - - - - - - - 10.98 -08:33 - - - - - - - - 11.05 -08:34 - - - - - - - - 11.12 -08:35 - - - - - - - - 11.32 -08:36 - - - - - - - - 11.52 -08:37 - - - - - - - - 11.57 -08:38 - - - - - - - - 11.53 -08:39 - - - - - - - - 11.49 -08:40 - - - - - - - - 11.45 -08:41 - - - - - - - - 11.32 -08:42 - - - - - - - - 11.26 -08:43 - - - - - - - - 11.36 -08:44 - - - - - - - - 11.40 -08:45 - - - - - - - - 11.36 -08:46 - - - - - - - - 11.34 -08:47 - - - - - - - - 11.29 -08:48 - - - - - - - - 11.28 -08:49 - - - - - - - - 11.26 -08:50 - - - - - - - - 11.30 -08:51 - - - - - - - - 11.31 -08:52 - - - - - - - - 11.21 -08:53 - - - - - - - - 11.24 -08:54 - - - - - - - - 11.23 -08:55 - - - - - - - - 11.19 -08:56 - - - - - - - - 11.21 -08:57 - - - - - - - - 11.19 -08:58 - - - - - - - - 11.17 -08:59 - - - - - - - - 11.16 -09:00 - - - - - - - - 11.19 -

- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -- - - - - - - - - - -


Summary of Raw Gases Data - Oxygen Day 2Oxides of Nitrogen Sulphur Dioxide Carbon Monxide Carbon Dioxide Oxygen


Limerick

A2-01 (Kiln 6 / Rawmill) Page 70 of 144

P0029-05CAR19-01 (LEK 11825) / Version 1

3rd September 2019



Page 71 of 148

SECTION B Emission Point A3-12 (Homosilo 1)

Date

Site Operator: Irish Cement Limerick Castlemungret Limerick Co Limerick


SOCOTEC Job Number:Report Date:Version: 2Report By: Andrew O'NeillMCERTS Number: MM 08 985MCERTS Level: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4


Signature:



Limerick


Co Limerick

Release Point: A3-12 (Homosilo 1)


Operator & Address:

Castlemungret



Tel: 01355 246 730Fax: 01355 249 669



Tel: 01355 246 730Email: [email protected]




SOCOTEC UK LTD

www.socotec.co.uk

EXECUTIVE SUMMARY


- Plant

- Operator


Emissions Summary

Monitoring Times

Process Details

Monitoring Methods

Analytical Methods


- On-Site Testing

Sampling Location




- Sampling Platform



APPENDICES





CONTENTS

Page 73 of 148

Irish Cement LimitedLimerickA3-12 (Homosilo 1)



SOCOTEC UK LTD

www.socotec.co.uk

Plant

A3-12 (Homosilo 1)

Operator


Castlemungret

Limerick

Co Limerick







Irish Cement Limited operates a bag house process at Limerick which is subject to IE Licence P0029-05, under the EPA Act 1992.

EXECUTIVE SUMMARY

The results of these tests shall be used to demonstrate compliance with a set of emission limit values for prescribed pollutants as specified in thePlant's IE Licence, P0029-05.

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+/-Total Particulate Matter mg/m³ 0.78 0.34 10Particulate Emission Rate g/hr 12.3 5.3 -Moisture % 0.40 0.03 - P

Stack Gas Temperature oC 27 - -Stack Gas Velocity m/s 30.6 0.67 -Gas Volumetric Flow Rate (Actual) m³/hr 18230.1 1005.5 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 16142.6 890.4 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 16078.3 886.8 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 16142.6 890.4 -


P

EMISSIONS SUMMARY

Reference conditions are 273K, 101.3kPa without correction for water vapour

P

EXECUTIVE SUMMARY


MCERTS accredited

result

Page 75 of 148




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Total Particulate Matter Run 1

MONITORING TIMES

60 minutes03 September 2019 13:27 - 14:30


EXECUTIVE SUMMARY

Sampling Duration

12:47 - 13:10 -03 September 2019Preliminary Stack Traverse

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Description of process Bag House



Part of batch to be monitored (if applicable) Rawmeal

Normal load, throughput or continuous rating 12000 Nm3/hr

Fuel used during monitoring N/A

Abatement Bag Filters

Plume Appearance Not Visible From Sampling Location

Process Details

EXECUTIVE SUMMARY

PROCESS DETAILS

Parameter

Page 77 of 148




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Species SOCOTEC UKAS Lab MCERTS Limit of Calculated CalculatedTechnical Number Accredited Detection MU MUProcedure Method (LOD) +/- % Result +/- % ELV


AE 104 1015 Yes 0.17 mg/m³ 43.3% 3.4%




AE 154 1015 Yes - 5.5% N/A - No ELV

MONITORING METHODS



MethodStandard Reference Method /

Alternative Method

SRM - EN 14790

The selection of standard reference / alternative methods employed by SOCOTEC is determined, wherever possible by the hierarchy of methodselection outlined in Environmental Protection Agency Technical Guidance Note (Monitoring) AG2.

Monitoring Methods

EXECUTIVE SUMMARY

SRM - EN 13284-1

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Analysis Location


Kilbride)- -

ON-SITE TESTING


UKAS Accredited Lab Analysis



UKAS Lab Number



SAMPLING METHODS WITH SUBSEQUENT ANALYSIS

Gravimetric

Analytical Methods

Gravimetric


EXECUTIVE SUMMARY

Page 79 of 148




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Value Units Isokinetic

Shape Rectangular -

Depth 0.36 m Sample port size 5" BSP -

Width 0.46 m Number of lines used 2 -

Area 0.17 m2 Number of points / line 2 -

Port Depth 100 mm Duct orientation Horizontal -In Stack -



Inside / Outside








N/A

Inside

Yes

N/A

Filtration for TPM

Yes


Yes


EXECUTIVE SUMMARY

Ground Level

The sampling location meets all the requirements as specified in EA Guidance Note AG1.

SAMPLING LOCATION

N/A

SAMPLING PLATFORM

Non-Iso & Gases

Page 80 of 148




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Nozzle Size

Due to the high stack gas velocities found during the preliminary stack traverse, it was necessary to use a nozzle smaller than the recommendedminimum nozzle size as stated in EN 13284-1. This allowed isokinetic sampling to be carried out.


EXECUTIVE SUMMARY

Page 81 of 148




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APPENDICES

CONTENTS

Page 82 of 148




SOCOTEC UK LTD

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SOCOTEC UKAS Lab MCERTSTechnical Number AccreditedProcedure Method

AE 104 1015 Yes 1AE 105 1015 Yes 1AE 154 1015 Yes 1

Method


Number of Samples

Standard Reference Method / Alternative Method

SRM - EN ISO 16911-1SRM - EN 14790

SRM - EN 13284-1MoistureVelocity

Species

MONITORING SCHEDULE


Page 83 of 148




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LEK 9.28 - LEK 15.21

LEK 9.25 - LEK 20.31

LEK 9.25 - LEK 17.1

LEK 9.25 - -

LEK 17.11 - LEK 16.12

- - LEK 1.14


LEK 3.36 - LEK 3.127

- - -

- - -

LEK 6.17 - -

- - -

LEK 23.18 - -

- - -

- - -

LEK 15.1G - -

- - -

- - -

LEK 24.7 - -


Cylinder I.D Number


Tolerance +/- %

- - - - -




Callum Montgomery


1Nov 22 Mar 24 - - - Nov 22

Site Balance

5m Heated Line (1)

Small DGM





Chiller (JCT/MAK 10)

1m Heated Line (2)


Thermo FID


Servomex

Probe Thermocouple

MFC Display module


Extractive Sampling

Equipment Equipment

Horiba PG-250 AnalyserControl Box DGM Laboratory Balance




Personnel

CALIBRATION GASES


1m Heated Line (3)

Callipers

20m Heated Line (2)

Anemometer


MONITORING TEAM



MCERTS Number


Probe

Probe Thermocouple

Stackmaster


Control Box Timer

Stack Thermocouple

1m Heated Line (1)

L-Pitot

Oven Box




FT-IR Oven Box

Signal 3030 FID

-

S-Pitot

FT-IR Gasmet

Barometer

Equipment


Heater Controller

Last Impinger Arm


10m Heated Line (2)

15m Heated Line (1)

20m Heated Line (1)

Page 84 of 148




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0.34 10 12.3

Blank - - -



Filter Start Weight

Filter End Weight






g g g g g g gRun 1 AC 0059 0.10065 0.10043 -0.00022 215.16910 215.17020 0.00110 0.00088If total mass gained is less than the LOD then the LOD is reported

TestFilter & Probe

NumberFilter Start

WeightFilter End

WeightMass Gained

FilterProbe Start

WeightProbe End

WeightMass Gained

ProbeCombined Total

Mass Gained


mg/l

BLANKS

SAMPLES

Sampling Times

2.0 10

FILTER INFORMATION

13:27 - 14:3003 September 2019

0.78



mg/m³

0.71

Concentration


Run 1

-

Acetone Blank Value

Page 85 of 148




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g 3.6 Molecular weight of wet gas, Ms

Vwstd = (0.001246)(Vlc) m3 0.0044856 Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 28.80Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa



(Ts)Volume of gas metered wet, Vmstw @O2ref No O2 RefVmstw = Vmstd + Vwstd m3 1.1247 (Ts)

Qstw = (Qa)Ps(0.3592) Wet 261.08 (Ts)



No O2 Ref %I = (4.6398E6)(Ts)(Vmstd) % 103.4 (Ps)(Vs)(An)(q)(1-Bwo)

Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 No O2 Ref Acceptable isokinetic range 95% to 115% YesMoisture content, Bwo Particulate Concentration, CBwo = Vwstd 0.0040 Mass collected on filter, Mf g -0.00022



Gas density (wet, ambient), p Cdry@X%O2 = Mn mg/m³ No O2 Refp=(Ms*Ps)/(8.314*Ts) kg/m3 1.138Stack Velocity, Vs Particulate Emission Rates, E

m/s 29.68 E = [(Cwet)(Qstw)(60)] / 1000 12.26

Vmstd + Vwstd

O2 Ref = 21.0 - act%O2

21.0 - ref%O2



Tm




O2 Reference Factor

Vmstd@X%oxygen


𝑝

Page 86 of 148




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mm °CRun 1 Glass Fibre 47 27

10

LOD < 5% ELV

Overall Blank Value

Run

Overall Blank Acceptable


Mean Sampling Rate



Result

FILTERS




Leak Rate

°C

1.0


Blank 1


Run

Post-use Filter Conditioning Temperature

Run

Filter SizeFilter Material Pre-use Filter Conditioning Temperature


°C

BLANK VALUE

0.71


Run

180

Maximum Vacuum

Run

5% ELV

160

Yes


Page 87 of 148




SOCOTEC UK LTD

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kg kg kg % % %

Run 1 2.2851 2.2887 0.0036 0.4 0.01 6.9





Run 1 60 1125 20.9 0.05 0.05 0.42 Yes


Stack Width, W 0.46 m







CO2 44 1.963059 0.028571 0.000286 0.000561 0.028457 0.000285 0.000559

O2 32 1.427679 20.900000 0.209000 0.298385 20.816643 0.208166 0.297195

N2 28 1.249219 79.071429 0.790714 0.987775 78.756062 0.787561 0.983836

H2O 18 0.803070 - - - 0.398838 0.003988 0.003203

Where: p = M / 22.41 pi = r x p

Determinand





Where:





1.138

kg/m3

Units




1.2848

kg/m31.2867

kg/m3


Moisture Determination - Isokinetic

13:27 - 14:3003 September 2019

Result

kg/m3




1.1394

Page 88 of 148




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TRAVERSE 1






1 0.02 522.7 53.3 27 28.6 4.7 - <152 0.05 561.9 57.3 27 29.7 4.9 - <153 0.09 614.1 62.7 27 31.0 5.1 - <154 0.13 623.9 63.7 27 31.3 5.2 - <155 0.16 686.0 70.0 27 32.8 5.4 - <156 0.20 715.4 73.0 27 33.5 5.5 - <157 0.23 672.9 68.7 27 32.5 5.4 - <158 0.27 584.7 59.7 27 30.3 5.0 - <159 0.31 539.0 55.0 27 29.1 4.8 - <15

10 0.34 535.7 54.7 27 29.0 4.8 - <15Mean - 605.6 61.8 27 30.8 5.1 - -






1 0.02 509.6 52.0 27 28.2 4.7 - <152 0.05 552.1 56.3 27 29.4 4.9 - <153 0.09 532.5 54.3 27 28.9 4.8 - <154 0.13 594.5 60.7 27 30.5 5.1 - <155 0.16 623.9 63.7 27 31.3 5.2 - <156 0.20 672.9 68.7 27 32.5 5.4 - <157 0.23 650.1 66.3 27 31.9 5.3 - <158 0.27 689.3 70.3 27 32.9 5.4 - <159 0.31 574.9 58.7 27 30.0 5.0 - <15

10 0.34 519.4 53.0 27 28.5 4.7 - <15Mean - 591.9 60.4 27 30.4 5.0 - -


Run 1 115 114 0.9 Pass 122 121 0.8 Pass

RunStagnation

(Pa)Reference

(Pa)Difference

(Pa)


Run 1 -444 -448 4.0 Pass

Sampling Line B

12:47 - 13:1003 September 2019




Run

PITOT LEAK CHECKPost Traverse Leak Rate

Sampling Line A

Outcome



(actual)

Date of Survey



(actual)


Time of Survey


Page 89 of 148




SOCOTEC UK LTD

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30.58

16078



<15



1823016143

16143

28.2

1.2


Yes

33.5

510

Result

0.17

Result

Page 90 of 148




SOCOTEC UK LTD

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Value UnitsStack Depth 0.36 m Sampling Distance Distance into UnitsStack Width 0.46 m Point (% of Depth) StackArea 0.17 m2 - - - -


1 25.0 0.09 < 152 75.0 0.27 < 153 25.0 0.09 < 154 75.0 0.27 < 15

- - - -

- - - -

- - - -

- - - -- - - -- - - -- - - -- - - -

- - - -

- - - -- - - -- - - -

Isokinetic sampling point - - - -Isokinetic sampling points not used - - - -Non Isokinetic/Gases sampling point - - - -

- - - -


Isokinetic Sampling

STACK DIAGRAMAPPENDIX 2 - Summaries, Calculations, Raw Data and Charts

1

2

Sampling Line A

3

4

Sampling Line B

Page 91 of 148




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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Limit of Detection


m³ K kPa % by volume % by volume % by mass % mgMU required < 2% < 2% < 1% < 1% < 10% < 5% of ELV < 2% < 10% of ELVRun 1 0.001 2.0 0.50 1.0 N/A 0.1900 - -as a % 0.09 0.67 0.51 1.0 N/A 1.68939 0.24 0.008compliant? Yes Yes Yes Yes N/A Yes Yes Yes

Run UncollectedMass

m³ mg - mg/m³ mgRun 1 0.99 0.8800 1.0 0.001 0.0005 -MU as mg/m3 0.01 0.1689 - 0.001 0.0004 0.17MU as % 1.31 21.5909 - 0.138 0.0525 -

0.34 mg/m³ 43.26 % Result 3.39 % ELV




O2 Correction




Leak

Page 92 of 148




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Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Leak

m³ K kPa % by volume % by volume %MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.001 2.0 0.50 1.0 N/A -as a % 0.09 0.67 0.51 1.0 N/A 0.24compliant? Yes Yes Yes Yes N/A Yes

Run UncollectedMass

m³ mg - mg/m³ mgRun 1 0.99 3600 1.0 4.44 58 -MU as % v/v 0.01 0.01 - 0.001 0.006 0.01MU as % 1.31 2.78 - 0.14 1.60 -

0.03 % v/v 6.93 %R1 - Uncertainty expressed at a 95% confidence level (where k = 2)


Volume (STP) Mass Gained O2 Correction Leak



Page 93 of 148




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30.6 m/s18230 m³/hr






Resolution pa 1.00



Yes

Drift % range 0.10







m/s0.340.67

%1.12.2

m³/hr513

1006

%2.85.5












Expanded uncertainty at a 95% Confidence Interval

Page 94 of 148




SOCOTEC UK LTD

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Version Issue Date Amendments

Stack name updated.Production Information updated from version 1 report.

2


18 October 2019

Page 95 of 148




SOCOTEC UK LTD

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END OF REPORT


the following

Page 96 of 148





Page 97 of 148

SECTION C Emission Point A3-13 (Homosilo 2)

Date





Signature:

Email: [email protected]



Tel: 01355 246 730Fax: 01355 249 669



Tel: 01355 246 730


Operator & Address:



Co Limerick

Release Point: A3-13 (Homosilo 2)






SOCOTEC UK LTD

www.socotec.co.uk

EXECUTIVE SUMMARY


- Plant

- Operator


Emissions Summary

Monitoring Times

Process Details

Monitoring Methods

Analytical Methods


- On-Site Testing

Sampling Location




- Sampling Platform



APPENDICES





CONTENTS

Page 99 of 148




SOCOTEC UK LTD

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Plant

A3-13 (Homosilo 2)

Operator


Castlemungret

Limerick

Co Limerick








EXECUTIVE SUMMARY


Page 100 of 148




SOCOTEC UK LTD

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Stack Gas Temperature oC 31 - -Stack Gas Velocity m/s 43.9 0.96 -Gas Volumetric Flow Rate (Actual) m³/hr 19846.6 998.3 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 17305.2 870.4 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 17194.5 864.9 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 17305.2 870.4 -

MCERTS accredited

result


EXECUTIVE SUMMARY

EMISSIONS SUMMARY


P

P


Page 101 of 148




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Total Particulate Matter Run 1Preliminary Stack Traverse 03 September 2019 11:05 - 11:25 -

03 September 2019 11:49 - 12:52


EXECUTIVE SUMMARY

Sampling Duration

60 minutes

MONITORING TIMES

Page 102 of 148




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PROCESS DETAILS

Parameter

EXECUTIVE SUMMARY

Process Details

Page 103 of 148




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AE 104 1015 Yes 0.13 mg/m³ 25.3% 2.5%




AE 154 1015 Yes - 5.0% N/A - No ELV

SRM - EN 13284-1

EXECUTIVE SUMMARY

Monitoring Methods

The selection of standard reference / alternative methods employed by SOCOTEC is determined, wherever possible by the hierarchy of methodselection outlined in Environmental Protection Agency Technical Guidance Note (Monitoring) AG2.



Alternative Method

SRM - EN 14790


MONITORING METHODS

Page 104 of 148




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Analysis Location


Kilbride)- -

EXECUTIVE SUMMARY


Analytical Methods

Gravimetric

Gravimetric



UKAS Lab Number






ON-SITE TESTING

Page 105 of 148




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Value Units Isokinetic

Shape Circular -


Width - m Number of lines used 2 -





Inside / Outside








SAMPLING PLATFORM

Non-Iso & Gases

Yes


EXECUTIVE SUMMARY

Ground Level


SAMPLING LOCATION

N/A

Filtration for TPM

Yes


N/A

N/A

Inside

Yes

Page 106 of 148




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Nozzle Size


EXECUTIVE SUMMARY

Due to the high stack gas velocities found during the preliminary stack traverse, it was necessary to use a nozzle smaller than the recommendedminimum nozzle size as stated in EN 13284-1. This allowed isokinetic sampling to be carried out.

Page 107 of 148




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CONTENTS

APPENDICES

Page 108 of 148




SOCOTEC UK LTD

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MoistureVelocity

Species

MONITORING SCHEDULE

Total Particulate Matter SRM - EN 13284-1

SRM - EN ISO 16911-1SRM - EN 14790



Number of Samples

Method

Page 109 of 148




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LEK 9.28 - LEK 15.21

LEK 9.25 - LEK 20.31

LEK 9.25 - LEK 17.1

LEK 9.25 - -

LEK 17.11 - LEK 16.12

- - LEK 1.14


LEK 3.36 - LEK 3.127

- - -

- - -

LEK 6.17 - -

- - -

LEK 23.18 - -

- - -

- - -

LEK 15.1G - -

- - -

- - -

LEK 24.7 - -


Cylinder I.D Number


Tolerance +/- %

- - - - -




Callum Montgomery


1Nov 22 Mar 24 - - - Nov 22

10m Heated Line (2)

15m Heated Line (1)

20m Heated Line (1)


Barometer

Equipment


Heater Controller

Last Impinger Arm

S-Pitot

FT-IR Gasmet


MCERTS Number


Probe

Probe Thermocouple

Stackmaster


Control Box Timer

Stack Thermocouple

1m Heated Line (1)

L-Pitot

Oven Box




FT-IR Oven Box

Signal 3030 FID

-

Personnel

CALIBRATION GASES


1m Heated Line (3)

Callipers

20m Heated Line (2)

Anemometer


MONITORING TEAM






Equipment


1m Heated Line (2)


Thermo FID


Servomex

Probe Thermocouple

MFC Display module


Extractive Sampling

Equipment


5m Heated Line (1)

Small DGM





Page 110 of 148




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0.25 10 16.1

Blank - - -



Filter Start Weight

Filter End Weight







TestFilter & Probe

NumberFilter Start

WeightFilter End

WeightMass Gained

FilterProbe Start

WeightProbe End

WeightMass Gained

ProbeCombined Total

Mass Gained


-

Acetone Blank Value


Run 1

Concentration

0.53


2.0 10

FILTER INFORMATION

11:49 - 12:5203 September 2019

1.01



mg/l

BLANKS

SAMPLES

Page 111 of 148




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Qstw = (Qa)Ps(0.3592) Wet 266.44 (Ts)




Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 No O2 Ref Acceptable isokinetic range 95% to 115% YesMoisture content, Bwo Particulate Concentration, CBwo = Vwstd 0.0064 Mass collected on filter, Mf g 0.00041




m/s 40.54 E = [(Cwet)(Qstw)(60)] / 1000 16.10

Vmstd@X%oxygen




O2 Reference Factor


Tm

Vmstd + Vwstd

O2 Ref = 21.0 - act%O2

21.0 - ref%O2



𝑝

Page 112 of 148




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Yes

Run

180

Maximum Vacuum

Run

5% ELV

160



°C

BLANK VALUE

0.53


Filter SizeFilter Material

Run


1.0


Blank 1


Run


Leak Rate

°C


Result

FILTERS




Mean Sampling Rate


10

LOD < 5% ELV

Overall Blank Value

Run


Page 113 of 148




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kg kg kg % % %

Run 1 2.2774 2.2851 0.0077 0.6 0.01 4.0





Run 1 60 1500 27.4 0.06 0.06 0.55 Yes


Stack Width, W - m







CO2 44 1.963059 0.028571 0.000286 0.000561 0.028389 0.000284 0.000557

O2 32 1.427679 20.900000 0.209000 0.298385 20.766289 0.207663 0.296476

N2 28 1.249219 79.071429 0.790714 0.987775 78.565555 0.785656 0.981456

H2O 18 0.803070 - - - 0.639767 0.006398 0.005138

Where: p = M / 22.41 pi = r x p

Determinand





Where:





1.1220



11:49 - 12:5203 September 2019

Result

kg/m3



1.2836

kg/m31.2867

kg/m3





1.119

kg/m3

Units

Page 114 of 148




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TRAVERSE 1






1 0.01 1084.5 110.7 31 41.5 5.2 - <152 0.03 1205.4 123.0 31 43.8 5.5 - <153 0.06 1205.4 123.0 31 43.8 5.5 - <154 0.09 1264.2 129.0 31 44.9 5.6 - <155 0.14 1211.9 123.7 31 43.9 5.5 - <156 0.26 1345.9 137.3 31 46.3 5.8 - <157 0.31 1303.4 133.0 31 45.5 5.7 - <158 0.34 1417.7 144.7 31 47.5 6.0 - <159 0.37 1277.3 130.3 31 45.1 5.7 - <15

10 0.39 1097.6 112.0 31 41.8 5.3 - <15Mean - 1241.3 126.7 31 44.4 5.6 - -






1 0.01 1019.2 104.0 31 40.3 5.1 - <152 0.03 1094.3 111.7 31 41.7 5.2 - <153 0.06 1211.9 123.7 31 43.9 5.5 - <154 0.09 1146.6 117.0 31 42.7 5.4 - <155 0.14 1241.3 126.7 31 44.5 5.6 - <156 0.26 1221.7 124.7 31 44.1 5.5 - <157 0.31 1332.8 136.0 31 46.1 5.8 - <158 0.34 1296.9 132.3 31 45.4 5.7 - <159 0.37 1189.1 121.3 31 43.5 5.5 - <15

10 0.39 1051.9 107.3 31 40.9 5.1 - <15Mean - 1180.6 120.5 31 43.3 5.4 - -


Run 1 122 120 1.6 Pass 118 117 0.8 Pass

RunStagnation

(Pa)Reference

(Pa)Difference

(Pa)


Run 1 -444 -448 4.0 Pass




(actual)


Time of Survey


(actual)

Date of Survey

Sampling Line A

Outcome


Post Traverse Leak RateRun

PITOT LEAK CHECK




Sampling Line B

11:05 - 11:2503 September 2019

Page 115 of 148




SOCOTEC UK LTD

www.socotec.co.uk



















0.13

Result

Yes

47.5

1019

Result

17305

17305

40.3

1.2


<15



19847



43.86

17195

Page 116 of 148




SOCOTEC UK LTD

www.socotec.co.uk

Value UnitsStack Depth 0.40 m Sampling Distance Distance into UnitsStack Width - m Point (% of Depth) StackArea 0.13 m2 - - - -


1 14.6 0.06 < 152 85.4 0.34 < 153 14.6 0.06 < 154 85.4 0.34 < 15

- - - -

- - - -

- - - -

- - - -- - - -- - - -- - - -- - - -

- - - -

- - - -- - - -- - - -


- - - -


Isokinetic Sampling

STACK DIAGRAM


Sampling Line A

1

2

Sampling Line B 3

4

Page 117 of 148




SOCOTEC UK LTD

www.socotec.co.uk

Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Limit of Detection



Run UncollectedMass


0.25 mg/m³ 25.30 % Result 2.55 % ELV


LeakO2 Correction






Page 118 of 148




SOCOTEC UK LTD

www.socotec.co.uk

Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Leak


Run UncollectedMass


0.03 % v/v 3.98 %



LeakO2 CorrectionMass GainedVolume (STP)



Page 119 of 148




SOCOTEC UK LTD

www.socotec.co.uk

43.9 m/s19847 m³/hr






Resolution pa 1.00



Yes

Drift % range 0.10







m/s0.490.96

%1.12.2

m³/hr509998

%2.65.0













Page 120 of 148




SOCOTEC UK LTD

www.socotec.co.uk

Version Issue Date


18 October 2019

Production Information updated from version 1 report.

2Stack name updated.

Amendments

Page 121 of 148




SOCOTEC UK LTD

www.socotec.co.uk


END OF REPORT


the following

Page 122 of 148





Page 123 of 148

SECTION D Emission Point A3-15 Kiln Feed Bin

Date





Signature:

Email: [email protected]



Tel: 01355 246 730Fax: 01355 249 669



Tel: 01355 246 730


Operator & Address:



Co Limerick

Release Point: A3-15 (Kiln Feed Bin)






SOCOTEC UK LTD

www.socotec.co.uk

EXECUTIVE SUMMARY


- Plant

- Operator


Emissions Summary

Monitoring Times

Process Details

Monitoring Methods

Analytical Methods


- On-Site Testing

Sampling Location




- Sampling Platform



APPENDICES





CONTENTS

Page 125 of 148

Irish Cement LimitedLimerickA3-15 (Kiln Feed Bin)



SOCOTEC UK LTD

www.socotec.co.uk

Plant

A3-15 (Kiln Feed Bin)

Operator


Castlemungret

Limerick

Co Limerick








EXECUTIVE SUMMARY


Page 126 of 148




SOCOTEC UK LTD

www.socotec.co.uk



Stack Gas Temperature oC 49 - -Stack Gas Velocity m/s 10.5 0.23 -Gas Volumetric Flow Rate (Actual) m³/hr 4755 239 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 3833 193 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 3816 192 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 3833 193 -

MCERTS accredited

result


EXECUTIVE SUMMARY

EMISSIONS SUMMARY


P

P


Page 127 of 148




SOCOTEC UK LTD

www.socotec.co.uk

Total Particulate Matter Run 1Preliminary Stack Traverse 03 September 2019 14:12 - 14:34 -

03 September 2019 14:50 - 15:53


EXECUTIVE SUMMARY

Sampling Duration

60 minutes

MONITORING TIMES

Page 128 of 148




SOCOTEC UK LTD

www.socotec.co.uk









PROCESS DETAILS

Parameter

EXECUTIVE SUMMARY

Process Details

Page 129 of 148




SOCOTEC UK LTD

www.socotec.co.uk



AE 104 1015 Yes 0.15 mg/m³ 28.7% 3%




AE 154 1015 Yes - 5.0% N/A - No ELV

SRM - EN 13284-1

EXECUTIVE SUMMARY

Monitoring Methods

The selection of standard reference / alternative methods employed by SOCOTEC is determined, wherever possible by the hierarchy of method selectionoutlined in Environmental Protection Agency Technical Guidance Note (Monitoring) AG2.



Alternative Method

SRM - EN 14790


MONITORING METHODS

Page 130 of 148




SOCOTEC UK LTD

www.socotec.co.uk





Analysis Location


Kilbride)- -

EXECUTIVE SUMMARY


Analytical Methods

Gravimetric

Gravimetric



UKAS Lab Number






ON-SITE TESTING

Page 131 of 148




SOCOTEC UK LTD

www.socotec.co.uk









Value Units IsokineticShape Circular -


Width - m Number of lines used 2 -





Inside / Outside








SAMPLING PLATFORM

Non-Iso & Gases

Yes


EXECUTIVE SUMMARY

Ground Level


SAMPLING LOCATION

N/A

Filtration for TPM

Yes


N/A

N/A

Inside

Yes

Page 132 of 148




SOCOTEC UK LTD

www.socotec.co.uk

In this instance there were no deviations from the sampling and analytical methods employed.


EXECUTIVE SUMMARY

Page 133 of 148




SOCOTEC UK LTD

www.socotec.co.uk





CONTENTS

APPENDICES

Page 134 of 148




SOCOTEC UK LTD

www.socotec.co.uk



MoistureVelocity

Species

MONITORING SCHEDULE

Total Particulate Matter SRM - EN 13284-1

SRM - EN ISO 16911-1SRM - EN 14790



Number of Samples

Method

Page 135 of 148




SOCOTEC UK LTD

www.socotec.co.uk


LEK 9.28 - LEK 15.21

LEK 9.25 - LEK 20.31

LEK 9.25 - LEK 17.1

LEK 9.25 - -

LEK 17.11 - LEK 16.12

- - LEK 1.14


LEK 3.36 - LEK 3.127

- - -

- - -

LEK 6.17 - -

- - -

LEK 23.18 - -

- - -

- - -

LEK 15.1G - -

- - -

- - -

LEK 24.7 - -


Cylinder I.D Number


Tolerance +/- %

- - - - -


Andrew O'Neill MM 08 985MCERTS Level 2

Mar 20 Sep 20 Mar 22 Mar 20 Sep 20 Oct 23

Callum Montgomery

MM 16 1399MCERTS Level 1

Nov 22 Mar 24 - - - Nov 22

10m Heated Line (2)

15m Heated Line (1)

20m Heated Line (1)


Barometer

Equipment


Heater Controller

Last Impinger Arm

S-Pitot

FT-IR Gasmet


MCERTS Number


Probe

Probe Thermocouple

Stackmaster


Control Box Timer

Stack Thermocouple

1m Heated Line (1)

L-Pitot

Oven Box




FT-IR Oven Box

Signal 3030 FID

-

Personnel

CALIBRATION GASES


1m Heated Line (3)

Callipers

20m Heated Line (2)

Anemometer


MONITORING TEAM






Equipment


1m Heated Line (2)


Thermo FID


Servomex

Probe Thermocouple

MFC Display module


Extractive Sampling

Equipment


5m Heated Line (1)

Small DGM





Page 136 of 148




SOCOTEC UK LTD

www.socotec.co.uk


0.30 10 4.1

Blank - - -



Filter Start Weight

Filter End Weight







TestFilter & Probe

NumberFilter Start

WeightFilter End

WeightMass Gained

FilterProbe Start

WeightProbe End

WeightMass Gained

ProbeCombined Total

Mass Gained


-

Acetone Blank Value


Run 1

Concentration

0.63


2.0 10

FILTER INFORMATION

14:50 - 15:5303 September 2019

1.04



mg/l

BLANKS

SAMPLES

Page 137 of 148




SOCOTEC UK LTD

www.socotec.co.uk










Qstw = (Qa)Ps(0.3592) Wet 65.14 (Ts)




Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 No O2 Ref Acceptable isokinetic range 95% to 115% YesMoisture content, Bwo Particulate Concentration, CBwo = Vwstd 0.0047 Mass collected on filter, Mf g 0.00023




m/s 10.45 E = [(Cwet)(Qstw)(60)] / 1000 4.06

Vmstd@X%oxygen



Is the process burning hazardous waste? (If yes, no

favourable oxygen correction)

O2 Reference Factor


Tm

Vmstd + Vwstd

O2 Ref = 21.0 - act%O2

21.0 - ref%O2



𝑝

Page 138 of 148




SOCOTEC UK LTD

www.socotec.co.uk







Yes

Run

180

Maximum Vacuum

Run

5% ELV

160



°C

BLANK VALUE

0.63


Filter SizeFilter Material

Run


1.0


Blank 1


Run


Leak Rate

°C


Result

FILTERS




Mean Sampling Rate


10

LOD < 5% ELV

Overall Blank Value

Run


Page 139 of 148




SOCOTEC UK LTD

www.socotec.co.uk


kg kg kg % % %

Run 1 2.2887 2.2935 0.0048 0.5 0.01 5.5





Run 1 60 1279 24.1 0.05 0.05 0.48 Yes


Stack Width, W - m







CO2 44 1.963059 0.028571 0.000286 0.000561 0.028438 0.000284 0.000558

O2 32 1.427679 20.90 0.209000 0.298385 20.802262 0.208023 0.296990

N2 28 1.249219 79.071429 0.790714 0.987775 78.701654 0.787017 0.983156

H2O 18 0.803070 - - - 0.467646 0.004676 0.003756

Where: p = M / 22.41 pi = r x p

Determinand





Where:





1.0373



14:50 - 15:5303 September 2019

Result

kg/m3



1.2845

kg/m31.2867

kg/m3





1.035kg/m3

Units

Page 140 of 148




SOCOTEC UK LTD

www.socotec.co.uk

TRAVERSE 1






1 0.01 54.7 5.6 49 9.7 1.2 - <152 0.03 58.8 6.0 49 10.1 1.3 - <153 0.06 62.9 6.4 49 10.4 1.3 - <154 0.09 63.7 6.5 49 10.5 1.3 - <155 0.14 61.3 6.3 49 10.3 1.3 - <156 0.26 68.6 7.0 49 10.9 1.4 - <157 0.31 69.4 7.1 49 10.9 1.4 - <158 0.34 72.7 7.4 49 11.2 1.4 - <159 0.37 70.2 7.2 49 11.0 1.4 - <15

10 0.39 61.3 6.3 49 10.3 1.3 - <15Mean - 64.4 6.6 49 10.5 1.3 - -






1 0.01 54.5 5.6 49 9.7 1.2 - <152 0.03 58.7 6.0 49 10.0 1.3 - <153 0.06 62.4 6.4 49 10.4 1.3 - <154 0.09 63.8 6.5 49 10.5 1.3 - <155 0.14 61.1 6.2 49 10.3 1.3 - <156 0.26 68.7 7.0 49 10.9 1.4 - <157 0.31 69.5 7.1 49 10.9 1.4 - <158 0.34 72.8 7.4 49 11.2 1.4 - <159 0.37 70.3 7.2 49 11.0 1.4 - <15

10 0.39 61.1 6.2 49 10.3 1.3 - <15Mean - 64.3 6.6 49 10.5 1.3 - -


Run 1 136 136 0.0 Pass 130 129 0.8 Pass

RunStagnation

(Pa)Reference

(Pa)Difference

(Pa)


Run 1 -2470 -2478 8.0 Pass




(actual)



(actual)

Date of Survey

Sampling Line A

Outcome


Post Traverse Leak Rate

Time of Survey

Run

PITOT LEAK CHECK




Sampling Line B

14:12 - 14:3403 September 2019

Page 141 of 148




SOCOTEC UK LTD

www.socotec.co.uk



















0.13

Result

Yes

11.2

54

Result

3833

3833

9.7

1.2


<15



4755



10.51

3816

Page 142 of 148




SOCOTEC UK LTD

www.socotec.co.uk

Value UnitsStack Depth 0.40 m Sampling Distance Distance into UnitsStack Width - m Point (% of Depth) StackArea 0.13 m2 - - - -


1 14.6 0.06 < 152 85.4 0.34 < 153 14.6 0.06 < 154 85.4 0.34 < 15

- - - -

- - - -

- - - -

- - - -- - - -- - - -- - - -- - - -

- - - -

- - - -- - - -- - - -


- - - -


Isokinetic Sampling

STACK DIAGRAM


Sampling Line A

1

2

Sampling Line B 3

4

Page 143 of 148




SOCOTEC UK LTD

www.socotec.co.uk

Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Limit of Detection



Run UncollectedMass


0.30 mg/m³ 28.69 % Result 2.98 % ELV


LeakO2 Correction






Page 144 of 148




SOCOTEC UK LTD

www.socotec.co.uk

Run Sampled Volume

Sampled Gas Temp



Oxygen Content

Leak


Run UncollectedMass


0.03 % v/v 5.46 %



LeakO2 CorrectionMass GainedVolume (STP)



Page 145 of 148




SOCOTEC UK LTD

www.socotec.co.uk

10.5 m/s4755 m³/hr






Resolution pa 1.00



Yes

Drift % range 0.10







m/s0.120.23

%1.12.2

m³/hr122239

%2.65.0













Page 146 of 148




SOCOTEC UK LTD

www.socotec.co.uk

Version Issue Date


18 October 2019

Production Information updated from version 1 report.

2Stack name updated.

Amendments

Page 147 of 148




SOCOTEC UK LTD

www.socotec.co.uk


END OF REPORT

Thank you for choosing SOCOTEC for your environmental monitoring needs. We hope our services have met your requirements and that you are fully satisfied with your experience of working with us, we really do value your custom and would welcome your feedback. We would appreciate it if you could take a moment to

complete a short online questionnaire so that we can improve our operations and address any areas that have not met with your expectations, by clicking on the following

Page 148 of 148




Summary

See report.

FOLLOW-UP ACTIONS

You are required to complete the instructions and actions, as outlined in this report, within the specified timeframe. Where required, you shall respond to actions specified in Compliance Investigations within the required timeframe.The licensee shall maintain documentary evidence, for review by the EPA, that the prescribed corrective actions were completed within the required timeframe.

(i) Compliance Investigations

You are not required to respond directly to items contained in this EPA site visit report; where an issue requires a direct response, the EPA will generate a Compliance Investigation through the EDEN system. You will receive notification when a Compliance Investigation instruction or action is generated.

(ii) Publication of reports and licensee response.

Please note that this Site Visit Report will be made available for public viewing via the EPA’s Licence Enforcement Access Portal within one day of the issue date and will be published on the Licence Details Page of the EPA’s website, www.epa.ie, that relates to your licence 60 calendar days after the issue date.

You may if you choose submit, within 45 calendar days of the issue date of this Site Visit Report, a Licensee Public Response that will be published alongside the Site Visit Report. This Response, should you wish to avail of it, provides you with an opportunity to inform the public about how you are implementing the actions set out in the report, activities underway, timescales and target completion dates. Please be aware that the content of your Licensee Public Response must be factual and should not breach the EPAs stated online publication standards.

If you wish to submit a Licensee Public Response to an EPA Site Visit Report, you should do this by clicking on the ‘Make a Response’ link on the Site Visits page in EDEN. A .pdf document containing your response can be attached and submitted from here.

(iii) Response to Site visit report

Where you do wish to respond directly to a site visit report, you should do this by generating a ‘Licensee Return’ of the type ‘Site Updates/Notifications’ and the sub-type ‘Response to EPA Report’ in EDEN.

Please note that you are required to comply with the conditions of your licence at all times, and where noncompliance occurs you must restore compliance within the shortest possible time. These actions will be verified during subsequent EPA visits.

Please quote the above Inspection Reference Number in any future correspondence in relation to this Report.


http://www.epa.ie/